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KR900017903A - 건조, 고순도 질소 생성공정 및 시스템 - Google Patents

건조, 고순도 질소 생성공정 및 시스템 Download PDF

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KR900017903A
KR900017903A KR1019900006681A KR900006681A KR900017903A KR 900017903 A KR900017903 A KR 900017903A KR 1019900006681 A KR1019900006681 A KR 1019900006681A KR 900006681 A KR900006681 A KR 900006681A KR 900017903 A KR900017903 A KR 900017903A
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drying
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KR950007915B1 (ko
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프레이세드 라비
윌리암 하스 오스카
충 해리
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티모티 엔. 비숍
유니온 카바이드 인더스트리얼 개시즈 테크놀로지 코포레이션
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04636Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a hybrid air separation unit, e.g. combined process by cryogenic separation and non-cryogenic separation techniques
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/225Multiple stage diffusion
    • B01D53/226Multiple stage diffusion in serial connexion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/268Drying gases or vapours by diffusion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/40Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/60Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/80Processes or apparatus using other separation and/or other processing means using membrane, i.e. including a permeation step
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Drying Of Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Treating Waste Gases (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

내용 없음

Description

건조, 고순도 질소 생성공정 및 시스템
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 저온 공급 가스 분리 시스템으로부터 페가스가 저온 시스템으로의 공급 가스를 건조하기위한 막 시스템용 퍼어즈 가스로 사용된, 본 발명이 구현예를 나타내는 개략도, 제2도는 저온 시스템용 흡착 베드 예비정제지로부터 제거된 퍼어즈 가스가 공급 가스 건조용 막 시스템용 퍼어즈 가스로 사용된, 본 발명의 구현예를 나타내는 개략도.

Claims (17)

  1. (a) 습기있는 공급 공기에 존재하는 물을 선택적으로 투과할 수 있는 건조용 막 시스템: (b) 건조용 막 시스템트로 부터 비투과 가스로서 회수된 건조 공급 공기로 부터 이산화 탄소, 잔류 물, 및 다른 오염물을 선택적으로 흡착할 수 있는 예비정제 흡착시스템: (c)공기의 저온 정류 및 건조폐가스와 더불어 고순도 질소 및/또는 산소 생성가스를 생성하기위한 저온공기분리 시스템: 및 (d) 막표면으로부터 떨어져서 수증기의 운반이 촉진되도록 그리고 향상된 수분 분리를 위해 공급공기류로 부터 막을 통해 수증기를 제거하기위한 구동력이 유지되도록, 비교적 건조한 퍼어즈 가스(이는 상기 저온공기분리 시스템 및/또는 예비정제 시스템 또는 주변 공기로 부터의 폐가스 또는 생성 가스로 이루어짐)를 건조용 막 시스템의 저압 투과 측부에 공급하기 위한 도관 장치를 포함하여, 건조용 막시스템의 투과 측부상에 퍼어즈 가스를 제공하면 원하는 습기 제거가 공급 공기의 최소 손실을 가지고서 달성되는 것을 특징으로 하는, 공기로 부터 건조한 고순도 질소 및/또는 산소 생성 시스템.
  2. 제1항에 있어서, 건조용 막 시스템이 습기있는 공급 공기의 흐름과 통상적으로 평행한 투과 가스의 흐름을 가지고서 역류 흐름 패턴으로 이용되는 막 다발을 포함하는 것을 특징으로 하는 시스템.
  3. 제1항에 있어서, 건조용 막 시스템을 위한 건조한 퍼어즈 가스가 저온 공기분리 시스템으로 부터의 폐가스로 이루어지는 것을 특징으로 하는 시스템.
  4. 제3항에 있어서, 저온 공기분리 시스템으로 부터 페가스중 일부분을 예비정제 흡착시스템에 퍼어즈가스로서 공급하기 위한 도관 장치를 더욱더 포함하는 것을 특징으로 하는 방법.
  5. 제1항에 있어서, 저온 공기분리 시스템으로 부터 페가스를 예비정제 시스템에 폐가스로서 공급하기 위한 도관 장치를 더욱더 포함하며, 예비 정제 시스템으로 부터 폐가스는 건조용 막 시스템을 위한 퍼어즈 가스로서 이루어지는 것을 특징으로 하는 시스템.
  6. 제5항에 있어서, 건조용막 시스템은 두단계 막 시스템으로 이루어져 있으며, 예비정제 흡착시스템으로 부터 페가스는 제1단계 건조용막 시스템에 퍼어즈가스로서 공급하는 것을 특징으로 하는 시스템.
  7. 제6항에 있어서, 저온 공기 분리 시스템 또는 팽창 공기로부터 폐가스 또는 생성가스를 제2단계 건조용막시스템에 퍼어즈 가스로서 공급하기 위한 추가의 도관 장치를 더욱더 포함하는 것을 특징으로 하는 시스템.
  8. 제5항에 있어서, 건조용 막 시스템이 습기있는 공급 공기의 흐름과 통상적으로 평행한 투과 가스의 흐름을 가지고서 역류 흐름 패턴으로 이용되는 막 다발을 포함하는 것을 특징으로 하는 시스템.
  9. (a) 습기있는 공급 공기를 물을 선택적으로 투과할 수 있는 건조용 막 시스템에 공급하고, (b) 건조한 공급공기를 건조용막 시스템으로부터 비투과 가스로서 회수된 건조 공급 공기로 부터 이산화 탄소, 잔류 물 및 다른오염물을 선택적으로 제거할 수 있는 예비정제 흡착시스템에 공급하고, (c) 예비정제 흡착 시스템으로 부터 건조하고 예비정제한 공급공기를 공기의 저온정류 및 건조한 산소함유 폐가스와 더불어 건조한 고순도 질소 생성가스를 생성하기위한 저온 공기부리 시스템에 공급하고, (d) 막표면으로 부터 떨어져서 수증기의 운반이 촉진되도록 그리고 향상된 수분 분리를 위해 공급공기류로 부터 막을 통해 수증기를 제거하기위한 구동력이 유지되도록, 비교적 건조한 퍼어즈 가스(이는 상기 저온공기분리 시스템 및/또는 예비정제 시스템 또는 주변 공기로 부터의 폐가스 또는 생성 가스로 이루어짐)를 건조용 막 시스템의 저압투과 측부에 공급하여, 건조용 막 시스템의 투과 측부상에 퍼어즈가스를 제공하면 원하는 습기 제거가 공급 공기의 최소 손실을 가기고서 달성되는 것을 특징으로하는, 공기로부터 건조한 고순도 질소 및/또는 산소 생성 공정.
  10. 제9항에 있어서, 건조용막 시스템이 습기있는 공급 공기의 흐름과 평행한 투과가스의 흐름을 가지고서 역류흐름 패턴으로 이용되는 막 다발을 포함하는 것을 특징으로 하는 공정.
  11. 제9항에 있어서, 건조용 막 시스템을 위한 건조한 퍼어즈 가스가 저온 공기분리 시스템으로 부터의 폐가스로 이루어지는 것을 특징으로 하는 공정.
  12. 제11항에 있어서, 저온 공기 분리 시스템으로 부터 페가스중 일부분을 예비정제 흡착 시스템에 퍼어즈 가스로서 공급함을 더욱더 포함하는 것을 특징으로 하는 공정.
  13. 제9항에 있어서, 저온 공기 분리 시스템으로 부터 폐가스를 예비정제 흡착 시스템에 퍼어즈가스로서 공급하는 것을 더욱더 포함하며, 예비정제 흡착 시스템으로부터 폐가스는 건조용 막 시스템을 위한 퍼어즈 가스로 이루어짐을 특징으로 하는 공정.
  14. 제13항에 있어서, 건조용 막 시스템이 두단계 막시스템으로 이루어지며, 예비정제 흡착시스템으로 부터 폐가스는 제1단계 건조용막 시스템에 퍼어즈가스로서 공급하는 것을 특징으로하는 공정.
  15. 제14항에 있어서, 저온 공기분리시스템 또는 팽창 공기로 부터 폐가스 또는 생성가스를 제2단계 건조용막시스템에 퍼어즈가스로서 공급함을 더욱더 포함하는 것을 특징으로 하는공정
  16. 제15항에 있어서, 저온 공기분리 시스템으로부터 폐가스는 제2단계 건조용막 시스템에 퍼어즈가스로서 공급하는 것을 특징으로 하는 공정
  17. 제13항에 있어서, 건조용 막 시스템이 습기있는 공급 공기의 흐름과 평행한 투과 가스의 흐름을 가지고서 역류 흐름 패턴으로 이용되는 막다발을 포함하는 것을 특징으로 하는 공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900006681A 1989-05-12 1990-05-11 건조, 고순도 질소 생성공정 및 시스템 Expired - Lifetime KR950007915B1 (ko)

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US350,848 1989-05-12
US07/350,848 US4934148A (en) 1989-05-12 1989-05-12 Dry, high purity nitrogen production process and system

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KR900017903A true KR900017903A (ko) 1990-12-20
KR950007915B1 KR950007915B1 (ko) 1995-07-21

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US (1) US4934148A (ko)
EP (1) EP0397192B2 (ko)
JP (2) JPH0317489A (ko)
KR (1) KR950007915B1 (ko)
CN (1) CN1023103C (ko)
AT (1) ATE108086T1 (ko)
BR (1) BR9002220A (ko)
CA (1) CA2016569A1 (ko)
DE (1) DE69010398T2 (ko)
ES (1) ES2056295T3 (ko)

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DE69010398D1 (de) 1994-08-11
ATE108086T1 (de) 1994-07-15
CN1023103C (zh) 1993-12-15
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JPH0732483U (ja) 1995-06-16
EP0397192A2 (en) 1990-11-14
EP0397192B1 (en) 1994-07-06
CA2016569A1 (en) 1990-11-12
DE69010398T2 (de) 1994-12-22
KR950007915B1 (ko) 1995-07-21
EP0397192B2 (en) 1996-12-18
US4934148A (en) 1990-06-19
EP0397192A3 (en) 1991-01-23
CN1048683A (zh) 1991-01-23
ES2056295T3 (es) 1994-10-01

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