KR900009936A - 광학활성 화합물, 이 화합물을 함유하는 액정조성물 및 이 조성물을 사용한 액정 광 변조장치 - Google Patents
광학활성 화합물, 이 화합물을 함유하는 액정조성물 및 이 조성물을 사용한 액정 광 변조장치 Download PDFInfo
- Publication number
- KR900009936A KR900009936A KR1019890019775A KR890019775A KR900009936A KR 900009936 A KR900009936 A KR 900009936A KR 1019890019775 A KR1019890019775 A KR 1019890019775A KR 890019775 A KR890019775 A KR 890019775A KR 900009936 A KR900009936 A KR 900009936A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- carbon atoms
- optically active
- active compound
- liquid crystal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims description 6
- 150000001875 compounds Chemical class 0.000 title claims 13
- 125000004432 carbon atom Chemical group C* 0.000 claims 15
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 125000004185 ester group Chemical group 0.000 claims 5
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical group S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims 5
- 125000003342 alkenyl group Chemical group 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 3
- 150000001733 carboxylic acid esters Chemical group 0.000 claims 3
- 125000000304 alkynyl group Chemical group 0.000 claims 2
- -1 carbonyldioxy group Chemical group 0.000 claims 2
- 125000005842 heteroatom Chemical group 0.000 claims 2
- 125000005699 methyleneoxy group Chemical group [H]C([H])([*:1])O[*:2] 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 208000035217 Ring chromosome 1 syndrome Diseases 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- SQQWBSBBCSFQGC-JLHYYAGUSA-N ubiquinone-2 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CCC=C(C)C)=C(C)C1=O SQQWBSBBCSFQGC-JLHYYAGUSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3491—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having sulfur as hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/38—One sulfur atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Liquid Crystal Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (10)
- 다음 일반식(Ⅰ)로 표시되는 광학 활성 화합물.(Ⅰ)상기식에서, R1은 각기 탄소수 3내지 14의 알킬그룹, 알케닐 그룹 또는 알키닐 그룹이고, R2는 탄소수 1내지 10의 알킬 그룹, 탄소수 2내지 10의 알케닐 그룹 또는 탄소수 2내지 10의 알키닐 그룹이고,는 헤테로 원자(들) 또는 이중결합(들)을 함유할 수 있는 5내지 8원 환이고, Q1은 단일결합, (티오)에테르 그룹, 카복실산 에스테르 그룹, 카보닐 그룹 또는 카보닐디옥시 그룹이고, Q2및 Q3는 독립적으로 단일결합, (티오)에테르 그룹, 카복실산 에스테르 그룹, 카보닐 그룹, 카보닐디옥시 그룹 또는 메틸렌옥시 그룹이고, M은또는(X 및 Y는 독립적으로 단일 결합, 카복실산 에스테르 그룹, 메틸렌옥시 그룹 도는 에틸렌 그룹이고,및는 독립적으로 환형성 원자로서 1내지 2의 산소 또는 질소원자를 함유할 수 있는 6원환 -1, 4-디일 그룹이다)이고, *가 있는 탄소원자는 부제탄소원자를 나타낸다.
- 제1항에 있어서,로 표시되는 5내지 8원환의 부제 탄소원자에 결합한 두 개의 극성 그룹이 동일방향의 배좌를 형성하고 있는 광학 활성 화합물.
- 제1항에 있어서, 부재 탄소원자가 서로 인접하여 있고 부재 탄소원자에 각기 결합되어 있는 Q2및 Q3는 시스 형태로 존재하는 광학 활성 화합물.
- 제1항에 있어서, R1은 탄소수 6내지 11의 알킬 그룹이고, R2는 탄소수 1내지 8의 알킬 그룹인 광학 활성 화합물.
- 제1항에 있어서, Q1은 단일 결합, (티오)에테르 그룹 또는에스테르 그룹이고, Q2는에스테르 그룹,에스테르 그룹 또는 에테르 그룹이고, Q3는 (티오)에테르 그룹,에스테르 그룹 또는에스테르 그룹인 광학 활성 화합물.
- 제1항에 있어서, M은이고, X 및 Y 중 하나는 단일 결합이고, 다른하나는 카복실산 에스테르 그룹이고,및는 모두 P-페닐렌이거나 또는 이들중 적어도 하나는 2.5-피리미딘디일인 광학 활성 화합물.
- 제1항에 있어서, M이이고, X는 단일 결합이고,및둘다 P-페닐렌이거나 또는 이들중 하나가 2.5-피리미딘디일인 광학 활성 화합물.
- 다음 일반식으로 표시되는 광학 활성 화합물.상기식에서, R2는 탄소수 1내지 10의 알킬 그룹, 탄소수 2내지 10의 알케닐 그룹 또는 탄소수 2내지 10의 알키닐 그룹이고, Q3는 단일 결합, (티오)에테르 그룹, 카보닐 그룹 또는 메틸렌 옥시 그룹이고, Z는 히드록실그룹 또는 -COOZ' (여기에서 Z'는 수소 또는 탄소수 2내지 10의 알킬 그룹이다)이고,는 헤테로원자(들) 도는 이중결합(들)을 함유할 수 있는 5내지 8원 환이다.
- 제1항 내지 제7항중 어느 하나에 따른 광학 활성 화합물 적어도 1종과 임의로 모체 액정을 포함하는 액정조성물.
- 적어도 한쌍의 기판과 이들 기판 사이에 배치된 제9항에 따른 1종의 엑정 조성물로 이루어진 액정 광변조 장치.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33523988 | 1988-12-28 | ||
| JP88-335239 | 1988-12-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR900009936A true KR900009936A (ko) | 1990-07-06 |
Family
ID=18286305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890019775A Ceased KR900009936A (ko) | 1988-12-28 | 1989-12-28 | 광학활성 화합물, 이 화합물을 함유하는 액정조성물 및 이 조성물을 사용한 액정 광 변조장치 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5370821A (ko) |
| EP (1) | EP0376294B1 (ko) |
| KR (1) | KR900009936A (ko) |
| DE (1) | DE68925954T2 (ko) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4211692A1 (de) * | 1992-04-08 | 1993-10-14 | Basf Ag | Verwendung der chiralen Gruppe (1S,4R)-1,4-Dihydroxy-2-cyclopentenyl zur Herstellung von polaren, flüssigkristallinen Materialien |
| GB9412709D0 (en) * | 1994-06-29 | 1994-08-17 | Secr Defence | Novel chiral cyclohexyl compounds |
| US5759443A (en) * | 1996-07-26 | 1998-06-02 | Rolic Ag | Cyclopentyl derivatives |
| GB2362504A (en) * | 2000-04-20 | 2001-11-21 | Pixel Fusion Ltd | Pin contacts |
| EP2258760B1 (en) | 2001-09-25 | 2014-06-25 | ExxonMobil Chemical Patents Inc. | Plasticised polyvinyl chloride |
| EP1798228B1 (en) | 2004-10-04 | 2012-11-14 | JNC Corporation | Tetrahydropyran compounds, liquid crystal compositions, and liquid crystal displays containing the compositions |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3333677A1 (de) * | 1983-09-17 | 1985-04-04 | Merck Patent Gmbh, 6100 Darmstadt | Fluessigkristall-phase |
| EP0191600B1 (en) * | 1985-02-08 | 1991-12-27 | Ajinomoto Co., Inc. | Polyphenyl-based ester compounds and liquid crystal compositions containing same |
| DE3510434A1 (de) * | 1985-03-22 | 1986-09-25 | Merck Patent Gmbh, 6100 Darmstadt | Cyclohexanderivate |
| JPH0779621B2 (ja) * | 1985-03-25 | 1995-08-30 | 花王株式会社 | カカオバタ−代用組成物 |
| DE3534777A1 (de) * | 1985-09-30 | 1987-04-02 | Hoechst Ag | Fluessigkristall-phase mit eine temperaturkompensation bewirkenden dotierstoffen |
| DE3604899A1 (de) * | 1986-02-17 | 1987-08-20 | Hoechst Ag | Chirale umsetzungsprodukte aus mesogenen molekuelbausteinen und bifunktionell reaktionsfaehigen butantetraolderivaten und ihre verwendung als dotierstoff in fluessigkristall-phasen |
| JPH0784411B2 (ja) * | 1986-08-12 | 1995-09-13 | チッソ株式会社 | 光学活性−2−メチル−1,3−プロパンジオ−ル誘導体 |
| JP2562606B2 (ja) * | 1986-09-08 | 1996-12-11 | ダイセル化学工業株式会社 | 光学活性化合物 |
| DD253632A1 (de) * | 1986-11-13 | 1988-01-27 | Univ Halle Wittenberg | Anwendung fluessiger kristalle |
| DE3739588A1 (de) * | 1986-12-20 | 1988-07-28 | Merck Patent Gmbh | Cyclopentanabkoemmlinge |
| JPH068265B2 (ja) * | 1987-09-16 | 1994-02-02 | 高砂香料工業株式会社 | 液晶性化合物 |
| US5167863A (en) * | 1987-12-24 | 1992-12-01 | Hitachi, Ltd. | Optically active compound, liquid crystal composition containing said compound, and liquid crystal optical modulator using said composition |
| US5167855A (en) * | 1988-03-04 | 1992-12-01 | University Research Corporation | Ferroelectric liquid crystal compositions chiral haloalkoxy tail units |
| US5130048A (en) * | 1988-03-04 | 1992-07-14 | Displaytech, Inc. | Ferroelectric liquid crystal compositions containing chiral haloalkoxy tails units |
| CA1341098C (en) * | 1988-08-25 | 2000-09-12 | Kazuhiko Sakaguchi | Liquid crystal composition and use thereof |
| JP2732269B2 (ja) * | 1988-10-27 | 1998-03-25 | 旭電化工業株式会社 | 光学活性エステル化合物および該化合物を含有する液晶組成物 |
| US5269965A (en) * | 1988-12-28 | 1993-12-14 | Takeda Chemical Industries | Optically active compounds, liquid crystal compositions comprising said compounds and liquid crystal optical modulators using said compositions |
| KR900014300A (ko) * | 1989-03-22 | 1990-10-23 | 우메모토 요시마사 | 광학활성 화합물, 이 화합물을 함유한 액정 조성물 및 이조성물을 사용한 액정 광변조 장치 |
-
1989
- 1989-12-28 DE DE68925954T patent/DE68925954T2/de not_active Expired - Fee Related
- 1989-12-28 EP EP89124043A patent/EP0376294B1/en not_active Expired - Lifetime
- 1989-12-28 KR KR1019890019775A patent/KR900009936A/ko not_active Ceased
-
1993
- 1993-01-11 US US08/002,966 patent/US5370821A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0376294A1 (en) | 1990-07-04 |
| DE68925954T2 (de) | 1996-10-17 |
| EP0376294B1 (en) | 1996-03-13 |
| US5370821A (en) | 1994-12-06 |
| DE68925954D1 (de) | 1996-04-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19891228 |
|
| PG1501 | Laying open of application | ||
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