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KR900006499A - 액상 세탁제에서 부분 에스테르화 공중합체의 용도 - Google Patents

액상 세탁제에서 부분 에스테르화 공중합체의 용도 Download PDF

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Publication number
KR900006499A
KR900006499A KR1019890015678A KR890015678A KR900006499A KR 900006499 A KR900006499 A KR 900006499A KR 1019890015678 A KR1019890015678 A KR 1019890015678A KR 890015678 A KR890015678 A KR 890015678A KR 900006499 A KR900006499 A KR 900006499A
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KR
South Korea
Prior art keywords
copolymer
partially esterified
olefin
molar ratio
esterified
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KR1019890015678A
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KR970001226B1 (ko
Inventor
디이셀 파울
페르너 요한네스
덴찡어 발터
하르트만 하인리히
라우벤하임머 한스-위르겐
Original Assignee
하우프터.라이싱어
바스프 악티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

액상 세탁제에서 부분 에스테르화 공중합체의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 주성분으로서, (1) 1종이상의 음이온성 계면활성제, 1종 이상의 비이온성 계면활성제, 또는 이들의 혼합물, (2) (a) 1종 이상의 C4-C28-올레핀 또는 1종 이상의 C4-C28-올레핀과 20몰%이하의 C1-C4-알킬 비닐 에테르의 혼합물과 (b) 에틸렌계 불포화된 탄소수 4 내지 8의 디카르복실산 무수물을 몰비율 1:1로 공중합하여 K=6 내지 100(1중량%의 중합체 및 25℃, 테트라히드로푸란 중에서 H.Fikentscher의 방법으로 측정)인 공중합체를 수득한후, 상기 공중합체를 (A) C1-C30-알코올, C8-C22-지방산, C1-C12-알킬페놀, 2차 C2-C30-아민 또는 이들의 혼합물을 (B) 1종 이상의 C2-C4-알킬렌 옥시드 또는 테트라히드로 푸란과 (A) : (B)의 몰비 1 : 2 내지 1 : 50으로 반응시켜 생성된 반응 생성물로 공중합체의 카르복실기의 5-50%이상이 전환될때까지 부분에스테르화시키고 공중합체의 무수물기를 카르복실기로 가수분해 시킴으로써 수득가능한 부분 에스테르화 공중합체 0.1-20중량%, 및 (3) 물을 함유함을 특징으로 하는, 액상 알칼리성 세탁제제.
  2. 제1항에 있어서, 부분 에스테르화 공중합체가 먼저 (a) 측쇄 C6-C18-올레핀 또는 측쇄 C6-C18-올레핀 혼합물과 (b) 말레산 무수물 또는 이타콘산 무수물을 공중합시켜 생성된 공중합체를 (A) C1-C30-알코올, C8-C18-지방산, C1-C12-알킬페놀 또는 2차 C2-C30-아민과 (B) 에틸렌 옥시드 또는 프로필렌 옥시드((A) : (B)몰비 1 : 2 내지 1 : 50)의 반응 생성물로 공중합체의 카르복실기 9-30%가 에스테르화될 때까지 부분 에스테르화 시킴으로써 제조되는, 액상 알칼리성 세탁제제.
  3. 제1항에 있어서, 부분 에스테르화 공중합체가 (a) 성분으로서 2,4,4'-트리메틸-1-펜텐과 2,4,4'-트리메틸-2-펜텐의 혼합물 및 (b) 또다른 성분으로서 말레산 무수물을 사용하여 제조되는, 액상 알칼리성 세탁제제.
  4. 제1항에 있어서, 부분에스테르화 공중합체가 (a) 1종 이상의 C1-C30-알코올 또는 2차 C2-C30-아민과 (B) 에틸렌 옥시드 또는 에틸렌 옥시드 및 프로필렌 옥시드의 반응생성물로 부분 에스테르화 됨으로서 수득가능한, 액상 알칼리성 세탁제제.
  5. 제1항에 있어서, 부분 에스테르화 공중합체가 (a) 1종 이상의 C4-C28-올레핀 또는 1종 이상의 C4-C28-올레핀과 20몰%이하의 C1-C28-알킬 비닐 에테르의 혼합물을 (b)(b1)에틸렌계 불포화된 탄소수 4 내지 8의 디카르복실산무수물과 (b2)(A) C1-C30-알코올, C8-C22-지방산, C1-C12-알킬페놀 또는 2차 C2-C30-아민과 (B) 1종이상의 C2-C4-알킬렌 옥시드 도는 테트라히드로 푸란((A) : (B)의 몰비 = 1 : 2 내지 1 : 50)의 반응 생성물(무수물기의 5내지 50%가 에스테르화됨)을 반응시켜 생성된 반응 생성물과 (a) : (b)의 몰비 1 : 1로 공중합시켜 K=6 내지 100인 공중합체를 수득하고 공중합체의 미전환 무수물기를 카르복실기 또는 그의 염으로 가수분해함으로써 수득가능한, 액상 알칼리성 세탁제제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890015678A 1988-10-31 1989-10-31 액체 알칼리성 세정 제제 Expired - Fee Related KR970001226B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3837013A DE3837013A1 (de) 1988-10-31 1988-10-31 Verwendung von partiell veresterten copolymerisaten in fluessigwaschmitteln
DEP3837013.1 1988-10-31

Publications (2)

Publication Number Publication Date
KR900006499A true KR900006499A (ko) 1990-05-08
KR970001226B1 KR970001226B1 (ko) 1997-02-04

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KR1019890015678A Expired - Fee Related KR970001226B1 (ko) 1988-10-31 1989-10-31 액체 알칼리성 세정 제제

Country Status (9)

Country Link
US (1) US5008032A (ko)
EP (1) EP0367049B1 (ko)
JP (1) JP2636938B2 (ko)
KR (1) KR970001226B1 (ko)
AT (1) ATE101192T1 (ko)
AU (1) AU617888B2 (ko)
CA (1) CA2000731A1 (ko)
DE (2) DE3837013A1 (ko)
ES (1) ES2048810T3 (ko)

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Also Published As

Publication number Publication date
DE3837013A1 (de) 1990-05-03
EP0367049B1 (de) 1994-02-02
CA2000731A1 (en) 1990-04-30
JP2636938B2 (ja) 1997-08-06
ES2048810T3 (es) 1994-04-01
AU4384089A (en) 1990-05-03
JPH02170897A (ja) 1990-07-02
EP0367049A3 (en) 1990-11-07
DE58906888D1 (de) 1994-03-17
US5008032A (en) 1991-04-16
ATE101192T1 (de) 1994-02-15
EP0367049A2 (de) 1990-05-09
AU617888B2 (en) 1991-12-05
KR970001226B1 (ko) 1997-02-04

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St.27 status event code: A-4-4-P10-P22-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000