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KR870011168A - 폴리에테르 수지의 제조 방법 - Google Patents

폴리에테르 수지의 제조 방법 Download PDF

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Publication number
KR870011168A
KR870011168A KR870004343A KR870004343A KR870011168A KR 870011168 A KR870011168 A KR 870011168A KR 870004343 A KR870004343 A KR 870004343A KR 870004343 A KR870004343 A KR 870004343A KR 870011168 A KR870011168 A KR 870011168A
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KR
South Korea
Prior art keywords
epoxy
formula
less
polyether resin
diglycidyl ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR870004343A
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English (en)
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KR960016469B1 (ko
Inventor
파울루스 후베르투스 숄텐 헨리쿠스
얀 디익스트라 테테
반 이페렌 뢰란트
Original Assignee
오노 알버어스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 오노 알버어스, 셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR870011168A publication Critical patent/KR870011168A/ko
Application granted granted Critical
Publication of KR960016469B1 publication Critical patent/KR960016469B1/ko
Anticipated expiration legal-status Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/56—Polyhydroxyethers, e.g. phenoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyethers (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Insulating Materials (AREA)
  • Laminated Bodies (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

내용 없음

Description

폴리에테르 수지의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 평균적으로 분자당 2개 이하의 에폭시기를 함유하는, 이가 페놀의 디글리시딜 에테르와 하기 일반식(A)의 알코올올, 당량 비율(여기서eOH는 일반식(A)의 알코올에 의해 도입된 총 수산 당량수이고 e에폭시는 디글리시딜 에테르에 의해 도입된 총 에폭시 당량수이다)가 1보다 큰 것을 사용하고 P의 값을 하기 식(Ⅰ)의 도움으로 계산한 바 1.05보다 큰 값을 선택하여, 에테르화촉매의 존재하에서, 얻어진 반응 생성물이 실질적으로 에폭시기를 갖지 않을 때까지 반응시키는 것으로 구성되는 폴리에테르 수지의 제조방법 :
    상기식에서 R은 5개 보다 적은 탄소원자를 함유하는 알킬기를 나타낸다.
    상기식에서eOH와e에폭시는 앞에서 정의된 바와 같고, F에폭시는
    로 정의되고, “a”와 “b”는 각각 출발 디글리시딜 에테르내의 에폭시기의 농도와 총말단기의 농도이다.
  2. 제 1 항에 있어서, 일반식(A)의 R이 메틸 또는 에틸 기인 방법.
  3. 제 2 항에 있어서, 일반식(A)의 알코올이 1,1,1-트리(하이드록시메틸)프로판인 방법.
  4. 제 1 항 내지 제 3 항중 여느 한 항에 있어서, 이가 페놀이 2,2-비스(4-하이드록시 페닐)프로판인 방법.
  5. 제 1 항 내지 제 4 항중 여느 한 항에 있어서, 디글리시틸 에테르내의 에폭시기에 대한 일반식(A)내의 수산기 당량 비율이 5이하로 사용되는 방법.
  6. 제 1 항 내지 제 5 항 중 여느 한 항에 있어서, P의 값이 3.0이하로 선택되는 방법.
  7. 제 1 항 내지 제 6 항중 여느 한 항에 있어서, 100℃내지 250℃ 범위 내의 온도에서 실시되는 방법.
  8. 제 1 항에 내지 제 7 항중 여느 한 항에 따르는 방법으로 제조된 폴리에테르 수지.
  9. 제 8 항에 따르는 폴리에테르 수지와 가교수지로 구성되는 경화성 피복조성물.
  10. 제 9 항에 따르는 경화성 피복 조성물을 표면에 적용하여, 열 작용으로 조성물을 경화시키는 것으로 구성되는 표면 피복방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870004343A 1986-05-06 1987-05-04 폴리에테르 수지의 제조 방법 Expired - Fee Related KR960016469B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB868611013A GB8611013D0 (en) 1986-05-06 1986-05-06 Polyether resin
GB8611013 1986-05-06

Publications (2)

Publication Number Publication Date
KR870011168A true KR870011168A (ko) 1987-12-21
KR960016469B1 KR960016469B1 (ko) 1996-12-12

Family

ID=10597396

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870004343A Expired - Fee Related KR960016469B1 (ko) 1986-05-06 1987-05-04 폴리에테르 수지의 제조 방법

Country Status (12)

Country Link
US (1) US4755583A (ko)
EP (1) EP0244897B1 (ko)
JP (1) JP2619639B2 (ko)
KR (1) KR960016469B1 (ko)
AT (1) ATE68796T1 (ko)
AU (1) AU595877B2 (ko)
CA (1) CA1276747C (ko)
DE (1) DE3773987D1 (ko)
ES (1) ES2025629T3 (ko)
GB (1) GB8611013D0 (ko)
GR (1) GR3003158T3 (ko)
ZA (1) ZA873168B (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8705264D0 (en) * 1987-03-06 1987-04-08 Shell Int Research Preparation of modified epoxy resin
GB8830176D0 (en) * 1988-12-23 1989-02-22 Shell Int Research Polyether resins,and process for preparing the same
GB8907487D0 (en) * 1989-04-03 1989-05-17 Shell Int Research Polyglycidyl polyether resins and process for preparing the same
GB8914161D0 (en) * 1989-06-20 1989-08-09 Shell Int Research Monoepoxide-polyol adducts,and process for preparing the same
GB9006577D0 (en) * 1990-03-23 1990-05-23 Shell Int Research Thermosetting polyol resins and coating compositions based upon such resins
JPH0436307A (ja) * 1990-06-01 1992-02-06 Yuka Shell Epoxy Kk 変性エポキシ樹脂及びエポキシ樹脂塗料
US5051492A (en) * 1990-06-19 1991-09-24 Shell Oil Company Polyether resins and process for preparing the same
GB9102421D0 (en) * 1991-02-05 1991-03-20 Shell Int Research Modified epoxy resins having a narrow molecular weight distribution
DE19823184A1 (de) * 1998-05-23 1999-11-25 Goldschmidt Ag Th Katalysatoren für die Herstellung kalt oder warm vernetzbarer Massen
IT1402349B1 (it) * 2010-09-15 2013-08-30 Lamberti Spa Composizioni per la patinatura della carta

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2731444A (en) * 1952-10-21 1956-01-17 Devoe & Raynolds Co Epoxide resin cured with a polyhydric aliphatic alcohol
NL120776C (ko) * 1958-07-22
US2911377A (en) * 1958-08-07 1959-11-03 Dow Chemical Co Process for the polymerization of olefin oxides
US3182099A (en) * 1961-04-28 1965-05-04 Union Carbide Corp Production of polymeric materials from polyoxyalkylene polyols and cycloaliphatic polyepoxy compounds
DE1495249A1 (de) * 1962-08-23 1969-01-16 Albert Ag Chem Werke Verfahren zur Herstellung von modifizierten Polyaetherharzen
US3576781A (en) * 1970-02-02 1971-04-27 Celanese Coatings Co Process for preparing fusible polyhydroxy-polyether resins
US4282387A (en) * 1979-12-26 1981-08-04 The Dow Chemical Company Process for preparing polyols
US4314923A (en) * 1980-06-04 1982-02-09 Ppg Industries, Inc. Coating compositions formulated from polyols modified by reaction with glycidyl ether
JPS5874714A (ja) * 1981-10-27 1983-05-06 Mitsui Petrochem Ind Ltd ポリエポキシド／脂肪族アルコ−ル付加物の製造方法
US4707535A (en) * 1983-10-27 1987-11-17 Union Carbide Corporation Low viscosity adducts of a poly(active hydrogen) organic compound and polyepoxide
US4684701A (en) * 1986-02-14 1987-08-04 The Dow Chemical Company Method for preparing advanced epoxy or phenoxy resins with low aliphatic halide content

Also Published As

Publication number Publication date
JP2619639B2 (ja) 1997-06-11
ZA873168B (en) 1987-10-28
GR3003158T3 (en) 1993-02-17
AU595877B2 (en) 1990-04-12
AU7247187A (en) 1987-11-12
EP0244897B1 (en) 1991-10-23
US4755583A (en) 1988-07-05
GB8611013D0 (en) 1986-06-11
ES2025629T3 (es) 1992-04-01
EP0244897A2 (en) 1987-11-11
DE3773987D1 (de) 1991-11-28
JPS62263222A (ja) 1987-11-16
KR960016469B1 (ko) 1996-12-12
CA1276747C (en) 1990-11-20
EP0244897A3 (en) 1988-01-20
ATE68796T1 (de) 1991-11-15

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