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KR870008926A - 비닐치환 방향족 탄화수소/테르펜/페놀로 구성된 삼중합체의 제조방법 - Google Patents

비닐치환 방향족 탄화수소/테르펜/페놀로 구성된 삼중합체의 제조방법 Download PDF

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Publication number
KR870008926A
KR870008926A KR870002240A KR870002240A KR870008926A KR 870008926 A KR870008926 A KR 870008926A KR 870002240 A KR870002240 A KR 870002240A KR 870002240 A KR870002240 A KR 870002240A KR 870008926 A KR870008926 A KR 870008926A
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South Korea
Prior art keywords
vinyl
substituted aromatic
phenols
preparing
terpene
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KR870002240A
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KR910001601B1 (ko
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주니어 놀만 에드워드 다우겐바우
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마이클 비. 키한
헐큘레스 인코오포레이티드
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/24Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with mixtures of two or more phenols which are not covered by only one of the groups C08G8/10 - C08G8/20
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J165/00Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G6/00Condensation polymers of aldehydes or ketones only
    • C08G6/02Condensation polymers of aldehydes or ketones only of aldehydes with ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31801Of wax or waxy material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31938Polymer of monoethylenically unsaturated hydrocarbon

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

내용 없음

Description

비닐치환 방향족 탄화수소/테르펜/페놀로 구성된 상중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 페놀, 테르펜, 비닐치환 방향족 성분에서 중합 생성물을 제조하는 방법에 있어서, 함량을 100%로 기준으로 할 때
    (1) 하기식으로 표현되는 비닐 치환 방향족 화합물 약 12중량% 내지 95중량%와,
    (2) 모노 테르핀 탄화수소 약 5중량% 내지 약 75중량%와,
    (3) 페놀류 약 0.75중량% 내지 약 50중량% 구성된 혼합물 중에 존재하는 모노머들은 촉매 존재하에 용매중에서 동시에 중합화되어 환구 연화점이 약 69℃ 내지 약 130℃인 비닐 치환인 방향족 탄화수소/테르펜/페놀 삼중합체를 생성하는 것을 특징으로 하는 비닐 치환 방향족 탄화수소/테르펜/페놀 삼중합체의 제조방법.
    상기식에서 R'는 수소 또는 -CH3, R"는 수소, -CH=CH2기 또는 1-10 탄소수의 알킬기이다.
  2. 제1항에 있어서, 비닐 치환 방향족 탄화수소(1)은 스티렌인 것을 특징으로하여 삼중합체를 제조하는 방법.
  3. 제1항 또는 제2항에 있어서, 모노테르펜 탄화수소(2)는 알파-피넨인 것을 특징으로하여 삼중합체를 제조하는 방법.
  4. 제1항, 제2항 또는 제3항에 있어서 페놀류(3)는 페놀인 것을 특징으로하여 삼중합체를 제조하는 방법.
  5. 전항중 어는 한 항에 있어서, 촉매는 BF3인 것을 특징으로 하여 삼중합체를 제조하는 방법.
  6. 전항중 어는 한 항에 있어서, 반응은 약 -15℃ 내지 약 65°의 온도에서 수행되는 것을 특징으로하여 삼중합체를 제조하는 방법.
    ※참고상항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870002240A 1986-03-13 1987-03-13 비닐치환 방향족 탄화수소/테르펜/페놀로 구성된 삼원중합체의 제조방법 Expired KR910001601B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US839,841 1986-03-13
US839841 1986-03-13
US06/839,841 US4701517A (en) 1986-03-13 1986-03-13 Vinyl aromatic/terpene/phenol terpolymer

Publications (2)

Publication Number Publication Date
KR870008926A true KR870008926A (ko) 1987-10-22
KR910001601B1 KR910001601B1 (ko) 1991-03-16

Family

ID=25280763

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870002240A Expired KR910001601B1 (ko) 1986-03-13 1987-03-13 비닐치환 방향족 탄화수소/테르펜/페놀로 구성된 삼원중합체의 제조방법

Country Status (9)

Country Link
US (1) US4701517A (ko)
EP (1) EP0240762B2 (ko)
JP (1) JP2619868B2 (ko)
KR (1) KR910001601B1 (ko)
AU (1) AU586541B2 (ko)
BR (1) BR8701139A (ko)
DE (1) DE3770312D1 (ko)
ES (1) ES2021624T5 (ko)
MX (1) MX163444B (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
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DE3635742A1 (de) * 1986-10-21 1988-05-05 Bayer Ag Hydroxycarbonsaeurederivate und ihre verwendung in aufzeichnungsmaterialien
US4927905A (en) * 1988-11-14 1990-05-22 The Dow Chemical Company Process for the production of aromatic hydroxyl-containing compound-hydrocarbon resins
EP0610632A1 (en) * 1993-02-11 1994-08-17 Dsm N.V. Resinous copolymer
US5844063A (en) * 1993-08-10 1998-12-01 Arizona Chemical, S.A. Resinous copolymer comprising monomer units of each of the groups of phenol compounds and olefinically unsaturated non-acidic terpene compounds
US5457175A (en) * 1995-01-11 1995-10-10 Arizona Chemical Company Low softening point terpene-phenol resins
US5674970A (en) * 1995-07-12 1997-10-07 Georgia-Pacific Resins, Inc. Phenolic polymers made by aralkylation reactions
US5756655A (en) * 1997-01-10 1998-05-26 Georgia-Pacific Resins, Inc. Preparation of phenolic polymers by aralkylation reactions
US7019060B1 (en) * 1999-11-12 2006-03-28 National Starch And Chemical Investment Holding Corporation Low application temperature hot melt adhesive
US20040045666A1 (en) * 2002-09-06 2004-03-11 Lie-Zhong Gong Hot melt adhesive and use thereof
US7404875B2 (en) * 2004-04-28 2008-07-29 Georgia-Pacific Consumer Products Lp Modified creping adhesive composition and method of use thereof
CN101522731B (zh) 2006-10-11 2011-05-11 安原化学股份有限公司 β-蒎烯聚合物及其制造方法
WO2010144890A2 (en) * 2009-06-11 2010-12-16 Arizona Chemical Company, Llc Tires and tread formed from phenol-aromatic-terpene resin
CN103450395B (zh) * 2013-08-28 2016-01-06 梧州市嘉盈树胶有限公司 萜烯树脂的制备方法
CN109553727A (zh) * 2018-12-05 2019-04-02 江苏麒祥高新材料有限公司 一种高抗湿滑/低滚动阻力增长苯乙烯改性萜烯酚树脂及其制备方法
CN113316597A (zh) * 2019-01-24 2021-08-27 昭和电工株式会社 热固性树脂组合物
CN116162196A (zh) * 2022-12-26 2023-05-26 广西民族大学 浅色高稳定性氢化萜烯酚苯乙烯树脂及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
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US3692844A (en) * 1968-06-24 1972-09-19 Pennsylvania Ind Chem Corp Process for preparing a terpene phenolic condensation product
SE7412816L (ko) * 1973-10-23 1975-04-24 Minnesota Mining & Mfg
JPS54123143A (en) * 1978-03-17 1979-09-25 Nippon Zeon Co Ltd Improved coating composition
JPS5560539A (en) * 1978-10-27 1980-05-07 Bridgestone Corp Improved rubber composition for tread
JPS5565248A (en) * 1978-11-10 1980-05-16 Nippon Oil Co Ltd Hot-melt composition
DE3066399D1 (en) * 1979-08-31 1984-03-08 Dsm Resins Bv Production of resins based on alpha-methyl styrene, styrene and a phenol as constituents, and their use in adhesives
US4412030A (en) * 1979-08-31 1983-10-25 National Starch And Chemical Corporation Hot melt adhesive compositions employing resins based on 2-methyl styrene, styrene and a phenol
JPS5736108A (ja) * 1980-08-14 1982-02-26 Mitsubishi Petrochem Co Ltd Nenchakuseijushinoseizohoho
DE3138180A1 (de) * 1981-09-25 1983-04-14 Bayer Ag, 5090 Leverkusen Neue phenole, verfahren zu ihrer herstellung und ihre verwendung als stabilisatoren fuer polymere
NL8502135A (nl) * 1985-07-26 1987-02-16 Dsm Resins Bv Harsachtige copolymeersamenstelling op basis van koolwaterstoffen en toepassing daarvan in lijmen.
NL8502134A (nl) * 1985-07-26 1987-02-16 Dsm Resins Bv Gehydrogeneerde koolwaterstofhars en toepassing daarvan in lijmen.

Also Published As

Publication number Publication date
MX163444B (es) 1992-05-14
ES2021624T5 (es) 1995-08-16
US4701517A (en) 1987-10-20
EP0240762A1 (en) 1987-10-14
KR910001601B1 (ko) 1991-03-16
JPS62253606A (ja) 1987-11-05
ES2021624B3 (es) 1991-11-16
AU6995687A (en) 1987-09-17
DE3770312D1 (de) 1991-07-04
EP0240762B1 (en) 1991-05-29
JP2619868B2 (ja) 1997-06-11
AU586541B2 (en) 1989-07-13
EP0240762B2 (en) 1994-08-10
BR8701139A (pt) 1988-01-05

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