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KR870007124A - 신규 제초제 피리디늄 내부염 및 일이드와 그들의 제조방법 및 식생 저해 방법 - Google Patents

신규 제초제 피리디늄 내부염 및 일이드와 그들의 제조방법 및 식생 저해 방법 Download PDF

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KR870007124A
KR870007124A KR1019870000541A KR870000541A KR870007124A KR 870007124 A KR870007124 A KR 870007124A KR 1019870000541 A KR1019870000541 A KR 1019870000541A KR 870000541 A KR870000541 A KR 870000541A KR 870007124 A KR870007124 A KR 870007124A
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alkyl
optionally substituted
methyl
imidazo
pyridine
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로스 머라이너스
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아메리칸 사이아나밋드 캄파니
원본미기재
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/46Oxygen atoms
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/12Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains three hetero rings
    • C07D487/14Ortho-condensed systems
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D471/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/12Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains three hetero rings
    • C07D471/14Ortho-condensed systems

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  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
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Abstract

내용 없음

Description

신규 제초제 피리디늄 내부염 및 일이드와 그들의 제조방법 및 식생 저해 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식(Ⅱ) 및 (Ⅲ)의 신규 (2-이미다졸린-2-일)피리딘 및 퀴놀린카르복실산, 에스테르 내부염, 일이드와 그들의 토오토머 및 R1과 R2가 다를 경우 그들의 광학 이성질체.
    상기식에서,
    X는 H, 할로겐 혹은 메틸이고 ; Y 및 Z는 각각 수소, 할로겐, C1-C6알킬, 히드록시저급알킬,C1-C6알콕시, C1-C4알킬티오, 페녹시, C1-C4할로알킬, 니트로, 시아노, C1-C4알킬아미노, 디저급알킬아미노 혹은 C1-C4알킬설포닐기, 또는 한개의 C1-C4알킬, C1-C4알콕시 혹은 할로겐으로 임의치환된 페닐, 디플루오로메톡시, 트리플루오로 메톡시, 1,1,2,2-테트라플루오로에톡시, 하나에서 세개의 할로겐으로 임의 치환된 C3-C8직쇄 혹은 측쇄 알키닐옥시이고, 또는 하나에서 세개의 할로겐으로 임의치환된 C3-C8직쇄 혹은 측쇄 알키닐오시이고 : 함께 결합했을 때는 Y및 Z는 임의로 치환될 수 있는 고리를 형성할 수 있는데, 이때의 YZ는-(CH2)n-(여기서 n는 3 또는 4의 정수) 또는-(CH)4-로 나타나고 ; R1은 C1-C4알킬이고 ; R2는 C1-C4알킬 혹은 C3-C6시클로 알킬이고 R1과 R2가 그들의 소속된 탄소와 함께 결합했을 때는 메틸로 임의 치환된 C3-C6시클로알킬로 나타날 수 있고 : R3는 수소이거나 COOR3는 그 산의 에스테르를 나타내고 ; R4및 R5은 각각 C1-C4알킬 혹은 페닐이거나, 함께 결합해 C5혹은 C6시클로 알킬을 형성할 수 있다.
  2. 제 1 항에 있어서, 메틸 10-카르복시-5-(디메틸아미노)-2,3-디히드로-2-이소프로필-2-메틸-3-옥소-5H-이미다조[2',1' : 4,3]-이미다조[1,5-a] 피리딘-6-이엄-5-일이드 및 그 R 이성질체인 화합물.
  3. 제 1 항에 있어서, 메틸 10-카르복시-2,3-디히드로-2-이소프로필-2-메틸-3-옥소-5-(1-피롤리디닐)-5H-이미다조[2',1' : 4,3]-이미다조[1,5-a] 피리딘-6-이엄-5-일이드 및 그 R 이성질체인 화합물.
  4. 제 1 항에 있어서, 벤질 10-카르복시-5-(디메틸 아미노)-2,3-디히드로-2-이소프로필-2-메틸-3-옥소-5H-이미다조 [2',1' : 4,3]-이미다조 [1,5-a] 피리딘-6-이엄-5-일이드 및 그 R 이성질체인 화합물.
  5. 제 1 항에 있어서, 10-카르복시-5-(디메틸아미노)-2-디히드로-2-이소프로필-2-메틸-3-옥소-5H-이미다조 [2',1' : 4,3]-이미다조 [1,5-a] 피리딘-6-이엄 히드록시드 내부염 및 그 R 이성질체인 화합물.
  6. 제 1 항에 있어서, 10-카르복시-5-(디메틸아미노)-2-디히드로-2-이소프로필-2-메틸-3-옥소-5H-이미다조 [2',1' : 4,3]-이미다조 [1,5-a] 피리딘-6-이엄 히드록시드 내부염 및 그 R 이성질체인 화합물.
  7. 제 1 항에 있어서, 10-카르복시-5-(디메틸아미노)-2-디히드로-2-이소프로필-(2,8-디메틸)-3-옥소-5H-이미다조 [2',1' : 4,3]-이미다조 [1,5-a] 피리딘-6-이엄 히드록시드 내부염 및 그 R 이성질체인 화합물.
  8. 하기 일반식(Ⅱ) 및 (Ⅲ)의 화합물 및 R1과 R2가 같지 않은 경우 그 광학 이성질체를 제초제로서 유효한 양만큼, 식물의 군엽이나 종자나 다른 증식 기관을 함유하는 토양이나 물에 적용하는 것으로 구성되는, 단자엽/쌍자엽, 일년생/다년생, 수생 식물종의 제어방법.
    상기식에서,
    X는 H, 할로겐 혹은 메틸이고 ; Y 및 Z는 각각 수소, 할로겐, C1-C6알킬, 히드록시저급알킬, C1-C6알콕시, C1-C4알킬티오, 페녹시, C1-C4할로알킬, 니트로, 시아노, C1-C4알킬아미노, 디저급 알킬아미노 혹은 C1-C4알킬설포닐기, 또는 한개의 C1-C4알킬, C1-C4알콕시 혹은 할로겐으로 임의 치환된 페닐, 디플루오로메톡시, 트리플루오로메톡시, 1,1,2,2-테트라플루오로에톡시, 하나에서 세개의 할로겐으로 임의 치환된 C3-C8직쇄 혹은 측쇄 알케닐옥시, 또는 하나에서 세개의 할로겐으로 임의치환된 C3-C8직쇄 혹은 측쇄 알키닐옥시이고 ; 함께 결합했을 때는 Y 및 Z는 임의로 치환될 수 있는 고리를 형성할 수 있는데, 이때의 YZ는-(CH2)n-(여기서 n는 3 또는 4의 정수) 또는-(CH)4-로 나타나고 R1은 C1-C4알킬이고 ; R2는 C1-C4알킬 혹은 C3-C6시클로알킬이고 ; R1과 R2가 그들이 소속된 탄소와 함께 결합했을 때는 메틸로 임의 치환된 C3-C6시클로알킬로 나타날 수 있고 ; R3는 수소이거나 COOR|3는 그 산의 에스테르를 나타내고 ; R4및 R5은 각각 C1-C4알킬 혹은 페닐이거나, 함께 결합해 C5혹은 C6시클로 알킬을 형성할 수 있다.
  9. 제 8 항에 있어서, R1이 C1-C4알킬이고 ; R2가 C1-C|4알킬이고 ; R3가 수소, 페닐로 임의 치환된 저급 알킬이고 ; R4가 C1-C4알킬이고 ; R5이 C1-C4알킬 혹은 페닐이고 ; R4와 R5이 함께 결합하면, C5-C6시클로알킬을 나타낼 수 있고 ; X는 H이고 ; Y는 수소 혹은 C1-C4저급알킬이고 ; Z는 수소이고 ; Y와 Z가 함께 결합하면, -(CH2)4-혹은-(CH)4-로 나타나는 고리를 형성할 수 있는 방법.
  10. 이미다졸린-2-일 피리딘 혹은 퀴놀린 카르복실산 에스테르 또는 카르바모일 피리딘 혹은 퀴놀린 카르복실산 에스테르와 빌스메이어(Vilsmeir) 시약을 거의 동몰량으로 반응시키고, 결과 생성물을 알코올성 염기로 임의 처리한 후, 산성화시키고 생성물을 분리하는 것으로 구성되는, 하기 일반식(Ⅱ) 및 (Ⅲ)의 신규(2-이미다졸린-2-일)피리딘 과 퀴놀린 카르복실산, 에스테르 내부염, 일이드 및 R1과 R2가 같지않을 때 그 광학 이성질체의 제조 방법.
    상기식에서 X는 H, 할로겐 혹은 메틸이고 ; Y 및 Z는 각각 수소, 할로겐, C1-C6알킬, 히드록시저급알킬, C1-C6알콕시, C1-C4알킬티오, 페녹시, C1-C4할로알킬, 니트로, 시아노, C1-C4알킬아미노, 디저급알킬아미노 혹은 C1-C4알킬설포닐기, 또는 한개의 C1-C4알킬, C1-C4알콕시 혹은 할로겐으로 임의 치환된 페닐, 디플루오로메톡시, 트리플루오로메톡시, 1,1,2,2-테트라플루오로에톡시, 하나에서 세개의 할로겐으로 임의 치환된 C3-C8직쇄 혹은 측쇄 알케닐옥시, 또는 하나에서 세개의 할로겐으로 임의치환된 C3-C8직쇄 혹은 측쇄 알키닐옥시이고 ; 함께 결합했을 때는 Y및 Z는 임의로 치환될 수 있는 고리를 형성할 수 있는데, 이때의 YZ는-(CH2)n-(여기서 n는 3 또는 4의 정수) 또는-(CH)4-로 나타나고 R1은 C1-C4알킬이고 ; R2는 C1-C4알킬 혹은 C3-C6시클로알킬이고 ; R1과 R2가 그들이 소속된 탄소와 함께 결합했을 때는 메틸로 임의 치환된 C3-C6시클로알킬로 나타날 수 있고 ; R3는 수소이거나 COOR3는 그 산의 에스테르를 나타내고 ; R4및 R5은 각각 C1-C4알킬 혹은 페닐이거나, 함께 결합해 C5혹은 C6시클로 알킬을 형성할 수 있다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870000541A 1986-01-24 1987-01-23 신규 제초제 피리디늄 내부염 및 일이드와 그들의 제조방법 Expired KR900005517B1 (ko)

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US06/822,098 US4698092A (en) 1986-01-24 1986-01-24 5H-imidazo[2',1':4,3]imidazo-[1,5a]pyridin-6-ium salts and their use as herbicidal agents
US822098 1986-01-24
US06/822,098 1986-01-24

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DK169105B1 (da) 1994-08-15
GR3007471T3 (ko) 1993-07-30
IL81330A0 (en) 1987-08-31
DE3784744D1 (de) 1993-04-22
IE59790B1 (en) 1994-04-06
EP0231800A2 (en) 1987-08-12
ZA87518B (en) 1987-09-30
DK38387D0 (da) 1987-01-23
AU6796787A (en) 1987-07-30
DK38387A (da) 1987-07-25
AU586730B2 (en) 1989-07-20
DE3784744T2 (de) 1993-10-07
FI84354B (fi) 1991-08-15
HUT44693A (en) 1988-04-28
JPS62228077A (ja) 1987-10-06
FI870292L (fi) 1987-07-25
YU45933B (sh) 1992-09-07
JP2502561B2 (ja) 1996-05-29
EP0231800A3 (en) 1988-10-19
YU8987A (en) 1988-08-31
KR900005517B1 (ko) 1990-07-30
FI84354C (fi) 1991-11-25
BR8700310A (pt) 1987-12-08
US4698092A (en) 1987-10-06
IE870181L (en) 1987-07-24
HU199417B (en) 1990-02-28
ATE86996T1 (de) 1993-04-15
FI870292A0 (fi) 1987-01-23
IL81330A (en) 1991-01-31
EP0231800B1 (en) 1993-03-17
ES2054624T3 (es) 1994-08-16
CA1329202C (en) 1994-05-03

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