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KR870006098A - 다격자상(polynetwork) EPDM고무 - Google Patents

다격자상(polynetwork) EPDM고무 Download PDF

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Publication number
KR870006098A
KR870006098A KR860011193A KR860011193A KR870006098A KR 870006098 A KR870006098 A KR 870006098A KR 860011193 A KR860011193 A KR 860011193A KR 860011193 A KR860011193 A KR 860011193A KR 870006098 A KR870006098 A KR 870006098A
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South Korea
Prior art keywords
rubber
epdm rubber
epdm
lattice
composition
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KR860011193A
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KR890004329B1 (ko
Inventor
야우커 코란 웨버트
캐드린 엔터 신디아
Original Assignee
루이스 맥 깁슨
몬산토 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/903—Interpenetrating network
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/919—Ionomer resins, carboxylate salt-containing copolymers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Insulating Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)
  • Materials For Medical Uses (AREA)
  • Peptides Or Proteins (AREA)
  • Lubricants (AREA)

Abstract

내용 없음

Description

다격자상(polynetwork) EPDM고무
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 이온결합성과 공유결합성 가교결합으로 구성된 다격자상 EPDM고무.
  2. 제1항에 있어서, 이온결합성 가교결합은 금속산화믈, 금속수산화물 또는 약산염으로 EPDM 분자에 펜던트된 숙신산기들을 중화함에 따라 형성된 것임을 특징으로 하는 다격자상 EPDM고무.
  3. EPDM고무를 말레산, 말레산무수물 또는 푸말산으로 처리하여 부가물을 형성시키고 이를 다가금속염, 수산화물 또는 산화물로 처리하여 이오노머를 형성시킨 다음, 연속 또는 동시공정으로 공유결합을 이오노머에 도입시키기 위하여 가황제를 사용, 이오노머를 가교결합시켜 형성된 것임을 특징으로 하는 다격자상 EPDM고무.
  4. 제3항에 있어서, 부가물은 EPDM고무를 말레산 무수물과 혼련 처리하여 얻어진 것이며, 이오노머는 부가물을 징크옥사이드로 처리하여 얻어진 것이고 가교결합은 황, 메틸올페놀성수지 및 유기과산화물로부터 선택된 가황제로 이오노머를 가황하므로써 얻어짐을 특징으로 하는 다격자상 EPDM고무.
  5. 제4항에 있어서, 자유라디칼 개시제는 부가물을 얻기 위해 EPDM고무를 말레산 무수물과 혼련하는 공정 중에 존재시킴를 특징으로 하는 다격자상 EPDM고무.
  6. 제5항에 있어서, 자유라디칼 개시제는 MBTS임을 특징으로 하는 다격자상 EPDM고무.
  7. 특허청구의 범위 제1항의 다격자상 EPDM고무와 조성물 중에 포함된 전체 고무에 대하여 고디엔탄화수소고무를 5∼500중량부 포함함을 특징으로 하는 고무 조성물.
  8. 특허청구의 범위 제1항의 다격자상 EPDM고무와 조성물 중에 포함된 전체고무에 대하여 카본블랙을 0∼200중량부 포함함을 특징으로 하는 고무 조성물.
  9. 특허청구의 범위 제1항의 다격자상 EPDM고무와 조성물 중에 포함된 전체 고무에 대하여 고무 프로세싱오일을 0∼200중량부 포함함을 특징으로 하는 고무조성물.
  10. 특허청구의 범위 제2항의 다격자상 EPDM고무와 조성물 중에 포함된 전체 고무에 대하여 카본블랙과 고무프로세싱오일을 각각 0∼200중량부 포함함을 특징으로 하는 고무 조성물.
  11. 제7항에 있어서, 카본블랙과 고무프로세싱오일을 다격자상 EPDM고무와 고디엔 탄화수소고무의 전체무게에 대하여 각각 10-200중량부 포함함을 특징으로 하는고무 조성물.
  12. 제1항에 있어서, 이온결합성가교결합은 N-카르복시알킬, N-카르복시아릴-치환-숙시남산 또는 숙신이미드기들로 구성된 것임을 특징으로 하는 다격자상 EPDM고무.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860011193A 1985-12-30 1986-12-24 다격자상(polynetwork) EPDM고무 Expired KR890004329B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/814,475 US4661554A (en) 1985-12-30 1985-12-30 Polynetwork EPDM rubber
US814475 1985-12-30

Publications (2)

Publication Number Publication Date
KR870006098A true KR870006098A (ko) 1987-07-09
KR890004329B1 KR890004329B1 (ko) 1989-10-31

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ID=25215150

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Application Number Title Priority Date Filing Date
KR1019860011193A Expired KR890004329B1 (ko) 1985-12-30 1986-12-24 다격자상(polynetwork) EPDM고무

Country Status (12)

Country Link
US (1) US4661554A (ko)
EP (1) EP0235497B1 (ko)
JP (1) JPH075651B2 (ko)
KR (1) KR890004329B1 (ko)
AT (1) ATE94892T1 (ko)
AU (1) AU590372B2 (ko)
BR (1) BR8606441A (ko)
CA (1) CA1250994A (ko)
DE (1) DE3689070T2 (ko)
ES (1) ES2059309T3 (ko)
MX (1) MX163316A (ko)
ZA (1) ZA869681B (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2635110B1 (fr) * 1988-08-05 1990-11-09 Saim Adhesifs Insonorisants Mo Adhesif pregelifiable
US6169134B1 (en) 1997-12-12 2001-01-02 Nalco/Exxon Energy Chemicals, L.P. Viscosifying hydrocarbon liquids
US6849581B1 (en) 1999-03-30 2005-02-01 Bj Services Company Gelled hydrocarbon compositions and methods for use thereof
KR100394547B1 (ko) * 2000-12-19 2003-08-14 동일고무벨트주식회사 이피디엠(epdm)고무의 물성을 향상시키는 방법
US7148279B2 (en) * 2001-04-13 2006-12-12 Acushnet Company Golf ball compositions comprising dynamically vulcanized blends of highly neutralized polymers and diene rubber
KR100468641B1 (ko) 2001-10-12 2005-01-27 금호폴리켐 주식회사 화학적 개질에 의한 폴리올레핀 탄성체 조성물
US8288467B2 (en) 2008-12-08 2012-10-16 Nike, Inc. Zinc ionomer rubber activator
WO2022010622A1 (en) 2020-07-07 2022-01-13 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polyethylene and polar polymers
CN117327351B (zh) * 2023-09-13 2024-04-26 江苏多肯新材料有限公司 一种车用密封圈橡胶材料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL134120C (ko) * 1961-11-24 1900-01-01
US3897405A (en) * 1973-01-02 1975-07-29 Goodrich Co B F EPDM polymers grafted with vulcanization accelerators
US4010223A (en) * 1973-01-10 1977-03-01 E. I. Du Pont De Nemours And Company Adducts containing succinic groups attached to elastomeric copolymers
US3901860A (en) * 1973-04-27 1975-08-26 Du Pont Functionally substituted terpolymers and tetrapolymers of ' -olefins and process for manufacturing functional substituted copolymers
US4244843A (en) * 1973-04-28 1981-01-13 Mitsubishi Belting, Ltd. Covulcanized rubber
NL7900503A (nl) * 1979-01-23 1980-07-25 Stamicarbon Werkwijze voor het bereiden van thermoplastisch elastomeer.
US4410656A (en) * 1982-05-03 1983-10-18 Monsanto Company Method for rubber treatment

Also Published As

Publication number Publication date
AU6697386A (en) 1987-07-02
JPH075651B2 (ja) 1995-01-25
EP0235497B1 (en) 1993-09-22
EP0235497A3 (en) 1989-10-18
AU590372B2 (en) 1989-11-02
ZA869681B (en) 1987-09-30
BR8606441A (pt) 1987-10-20
KR890004329B1 (ko) 1989-10-31
ATE94892T1 (de) 1993-10-15
US4661554A (en) 1987-04-28
DE3689070T2 (de) 1994-04-21
ES2059309T3 (es) 1994-11-16
EP0235497A2 (en) 1987-09-09
CA1250994A (en) 1989-03-07
DE3689070D1 (de) 1993-10-28
MX163316A (es) 1992-04-20
JPS62177002A (ja) 1987-08-03

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