KR850005411A - α-메틸-(6-펜옥시)-2- 피콜릴 사이클로프로판 카복실 레이트의 제조방법 - Google Patents
α-메틸-(6-펜옥시)-2- 피콜릴 사이클로프로판 카복실 레이트의 제조방법 Download PDFInfo
- Publication number
- KR850005411A KR850005411A KR1019850000147A KR850000147A KR850005411A KR 850005411 A KR850005411 A KR 850005411A KR 1019850000147 A KR1019850000147 A KR 1019850000147A KR 850000147 A KR850000147 A KR 850000147A KR 850005411 A KR850005411 A KR 850005411A
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- compound
- methyl
- halogen
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims 18
- NHNDTZMCAPTHLA-UHFFFAOYSA-N N1C(OC=2C=CC=CC=2)=CC=CC1(C)COC(=O)C1CC1 Chemical compound N1C(OC=2C=CC=CC=2)=CC=CC1(C)COC(=O)C1CC1 NHNDTZMCAPTHLA-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims 20
- 229910052736 halogen Inorganic materials 0.000 claims 6
- 150000002367 halogens Chemical class 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 125000004414 alkyl thio group Chemical group 0.000 claims 2
- 229910052801 chlorine Chemical group 0.000 claims 2
- 239000000460 chlorine Chemical group 0.000 claims 2
- -1 α-methyl- (6-phenoxy) -2-picolinyl cyclopropane Chemical compound 0.000 claims 2
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims 1
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 125000004093 cyano group Chemical group *C#N 0.000 claims 1
- 125000004438 haloalkoxy group Chemical group 0.000 claims 1
- 125000001188 haloalkyl group Chemical group 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
- C07D213/647—One oxygen atom attached in position 2 or 6 and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (19)
- 일반식(Ⅱ)의 화합물을 산 수용체의 존재하에서, 일반식(Ⅲ)의 화합물과 반응시킴을 특징으로 하여 일반식(Ⅰ)α-메틸-(6-펜옥시)-2-피콜릴 사이클로프로판 카복실 레이트를 제조하는 방법.상기식에서, X₁은 메틸 또는 할로겐이고, R₁은 수소 또는 할로겐이며, R₂는 수소, 할로겐, C₁-C₄알킬, C₁-C₄알콕시, C₁-C₄알킬티오, C₁-C₄할로알킬, C₁-C₄할로알콕시, C₁-C₄할로알킬티오, C2-C₄알케닐, C2-C₄알키닐, 니트로 또는 시아노이고, X및 X'중의 하나는 하이드록실 그룹이고 다른 하나는 할로겐 원자이다.
- 제1항에 있어서, X₁이 메틸 또는 염소이고, R₁이 수소 또는 할로겐이며, R₂가 수소, 할로겐, C1-C₄알킬, C1-C₄알콕시, C1-C₄알킬티오, 비닐 또는 이티닐인 일반식(Ⅰ)의 화합물을 제조하는 방법.
- 제2항에 있어서,X₁이 메틸 또는 염소이고, R1이 수소이며, R2가 수소 또는 할로겐인 일반식(Ⅰ)의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제3항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.
- 제2항에 있어서, 다음 구조식의 화합물을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH14084 | 1984-01-12 | ||
| CH140/84-5? | 1984-01-12 | ||
| CH571384 | 1984-11-30 | ||
| CH5713/84-7? | 1984-11-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR850005411A true KR850005411A (ko) | 1985-08-26 |
Family
ID=25683637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019850000147A Withdrawn KR850005411A (ko) | 1984-01-12 | 1985-01-11 | α-메틸-(6-펜옥시)-2- 피콜릴 사이클로프로판 카복실 레이트의 제조방법 |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US4661497A (ko) |
| EP (1) | EP0150678B1 (ko) |
| KR (1) | KR850005411A (ko) |
| AU (1) | AU566278B2 (ko) |
| BR (1) | BR8500095A (ko) |
| CA (1) | CA1234820A (ko) |
| DE (1) | DE3476878D1 (ko) |
| DK (1) | DK14085A (ko) |
| ES (1) | ES539487A0 (ko) |
| GB (1) | GB2152928B (ko) |
| IL (1) | IL74032A (ko) |
| NZ (1) | NZ210811A (ko) |
| PH (1) | PH21543A (ko) |
| ZW (1) | ZW685A1 (ko) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4694013A (en) * | 1985-11-08 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Insecticidal and acaricidal phenoxypyrdinyl esters and intermediates |
| US5194438A (en) * | 1988-07-15 | 1993-03-16 | Basf Aktiengesellschaft | α-arylacrylates substituted by a trifluoromethylpyrimidinyloxy radical, fungicidal compositions and methods |
| DE3823991A1 (de) * | 1988-07-15 | 1990-02-15 | Basf Ag | Heterocyclisch substituierte (alpha)-aryl-acrylsaeureester und fungizide, die diese verbindungen enthalten |
| DE3824788A1 (de) * | 1988-07-21 | 1990-02-22 | Basf Ag | Cyclopropancarboxamide, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung von schaedlingen |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2829329A1 (de) * | 1977-07-05 | 1979-01-25 | Ciba Geigy Ag | Cyclopropankarbonsaeureester und ihre salze mit anorganischen und organischen saeuren, verfahren zu ihrer herstellung und ihre verwendung in der schaedlingsbekaempfung |
| EP0000508B1 (de) * | 1977-07-20 | 1981-09-02 | Ciba-Geigy Ag | Phenylacetate von 2-Oxy-Pyridyl, Verfahren zu deren Herstellung und deren Verwendung als Schädlingsbekämpfungsmittel |
| US4221799A (en) * | 1979-07-30 | 1980-09-09 | The Dow Chemical | Substituted pyridine methyl esters of tetramethyl cyclopropane carboxylic acids and their use as insecticides |
| US4323574A (en) * | 1980-11-24 | 1982-04-06 | Zoecon Corporation | Cis and trans isomers of α-methyl(6-phenoxy-2-pyridyl)methyl-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylates and derivatives thereof |
| DE3111644A1 (de) * | 1981-03-25 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Phenoxypyridylmethylester, verfahren zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln |
| US4587255A (en) * | 1982-12-14 | 1986-05-06 | Ciba-Geigy Corporation | Isomers of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid-α-methyl-(6-phenoxy-2-picolyl)ester, processes for producing them, and their use for controlling pests |
| JPS59152303A (ja) * | 1983-02-16 | 1984-08-31 | Yoshio Katsuta | 新規ビリジルメチル誘導体を含有する殺虫剤、殺ダニ剤及びその製造法 |
| JPS6011008B2 (ja) * | 1983-02-21 | 1985-03-22 | 農林水産省農業環境技術研究所長 | 農園芸作物病害防除組成物 |
-
1984
- 1984-12-19 DE DE8484810646T patent/DE3476878D1/de not_active Expired
- 1984-12-19 EP EP84810646A patent/EP0150678B1/de not_active Expired
- 1984-12-31 US US06/688,123 patent/US4661497A/en not_active Expired - Fee Related
-
1985
- 1985-01-09 GB GB08500484A patent/GB2152928B/en not_active Expired
- 1985-01-10 IL IL74032A patent/IL74032A/xx unknown
- 1985-01-10 ZW ZW6/85A patent/ZW685A1/xx unknown
- 1985-01-10 CA CA000471821A patent/CA1234820A/en not_active Expired
- 1985-01-10 PH PH31703A patent/PH21543A/en unknown
- 1985-01-10 BR BR8500095A patent/BR8500095A/pt unknown
- 1985-01-11 ES ES539487A patent/ES539487A0/es active Granted
- 1985-01-11 NZ NZ210811A patent/NZ210811A/xx unknown
- 1985-01-11 KR KR1019850000147A patent/KR850005411A/ko not_active Withdrawn
- 1985-01-11 DK DK14085A patent/DK14085A/da not_active Application Discontinuation
- 1985-01-11 AU AU37620/85A patent/AU566278B2/en not_active Ceased
-
1987
- 1987-01-12 US US07/002,370 patent/US4822806A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NZ210811A (en) | 1988-09-29 |
| CA1234820A (en) | 1988-04-05 |
| DK14085A (da) | 1985-07-13 |
| IL74032A0 (en) | 1985-04-30 |
| ZW685A1 (en) | 1985-08-07 |
| GB8500484D0 (en) | 1985-02-13 |
| EP0150678A1 (de) | 1985-08-07 |
| US4661497A (en) | 1987-04-28 |
| PH21543A (en) | 1987-11-16 |
| DK14085D0 (da) | 1985-01-11 |
| AU3762085A (en) | 1985-07-18 |
| US4822806A (en) | 1989-04-18 |
| GB2152928A (en) | 1985-08-14 |
| ES8602669A1 (es) | 1985-12-01 |
| ES539487A0 (es) | 1985-12-01 |
| DE3476878D1 (en) | 1989-04-06 |
| BR8500095A (pt) | 1985-08-20 |
| GB2152928B (en) | 1987-11-18 |
| AU566278B2 (en) | 1987-10-15 |
| IL74032A (en) | 1988-12-30 |
| EP0150678B1 (de) | 1989-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19850111 |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |