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KR101778273B1 - Bubble foam type cleanser for make-up remove and fresh wash up - Google Patents

Bubble foam type cleanser for make-up remove and fresh wash up Download PDF

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KR101778273B1
KR101778273B1 KR1020110005752A KR20110005752A KR101778273B1 KR 101778273 B1 KR101778273 B1 KR 101778273B1 KR 1020110005752 A KR1020110005752 A KR 1020110005752A KR 20110005752 A KR20110005752 A KR 20110005752A KR 101778273 B1 KR101778273 B1 KR 101778273B1
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surfactant
fatty acid
bubble
polyol
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KR20120084405A (en
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김현나
정창조
김대경
이존환
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(주)아모레퍼시픽
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations

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  • Emergency Medicine (AREA)
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  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 메이크업 제거와 개운한 세안이 가능한 버블폼 타입 세안제 조성물에 관한 것으로, 보다 상세하게는 실리콘 양 말단에 PEG를 부가하여 친수성을 높인 화합물 및 거품 형성능이 있는 계면활성제를 유효성분으로 함유하여 포밍 컨테이너(버블폼 용기)를 통해 거품 형태로 토출되는 버블폼 타입의 메이크업 제거 및 세안을 동시에 할 수 있는 세안제 조성물에 관한 것이다.The present invention relates to a bubble foam type cleanser composition capable of removing makeup and cleansing, and more particularly, to a foam cleansing composition which comprises a compound having enhanced hydrophilicity by adding PEG to both ends of silicon and a surfactant having foamability as an active ingredient, The present invention relates to a cleanser composition capable of simultaneous removal of make-up and cleansing of a bubble-foam type which is discharged in the form of a foam through a bubble form container (bubble form container).

Description

메이크업 제거와 개운한 세안이 가능한 버블폼 타입 세안제{Bubble foam type cleanser for make-up remove and fresh wash up}{Bubble foam type cleanser for make-up removal and fresh wash up}

본 발명은 메이크업 제거와 개운한 세안이 가능한 버블폼 타입 세안제 조성물에 관한 것으로, 보다 상세하게는 실리콘 양 말단에 PEG를 부가하여 친수성을 높인 화합물 및 거품 형성능이 있는 계면활성제를 유효성분으로 함유하여 포밍 컨테이너(버블폼 용기)를 통해 거품 형태로 토출되는 버블폼 타입의 메이크업 제거 및 세안을 동시에 할 수 있는 세안제 조성물에 관한 것이다.The present invention relates to a bubble foam type cleanser composition capable of removing makeup and cleansing, and more particularly, to a foam cleansing composition which comprises a compound having enhanced hydrophilicity by adding PEG to both ends of silicon and a surfactant having foamability as an active ingredient, The present invention relates to a cleanser composition capable of simultaneous removal of make-up and cleansing of a bubble-foam type which is discharged in the form of a foam through a bubble form container (bubble form container).

화장을 하는 여성들이 점점 늘어남에 따라 화장을 하는 것 보다 지우는 것이 점점 중요한 요소로 대두되고 있다. 일반적으로 메이크업을 하는 사용자들은 메이크업을 지울 때 클렌징 크림이나 오일 등을 사용하여 메이크업을 지운 후 다시 비누나 클렌징폼 등의 세안제를 사용하는 이중 세안을 해 왔다. 따라서 이러한 이중 세안의 번거러움을 해결하기 위해 그 동안 비이온 계면활성제 베이스의 클렌징 워터나 워시오프 타입의 클렌징 오일 등이 개발되어 왔다. 하지만 이러한 제품들은 메이크업 제거와 개운한 세안의 두 가지 목적을 한번에 해결하기는 어려웠기 때문에 한가지 측면에 보다 집중하여 개발되어 왔다. As the number of women who wear makeup increases, it becomes more and more important to erase rather than makeup. In general, users who make up makeup use a cleansing cream or oil to remove the make-up, and then use a cleanser such as soap or cleansing foam. Therefore, in order to solve the troubles of the double cleansing, a nonionic surfactant based cleansing water or a wash-off type cleansing oil has been developed. However, these products have been developed more focused on one aspect because it was difficult to solve the two purposes of makeup removal and refreshing cleansing at once.

한편, 스크럽 비드 등을 이용하여 물리적인 힘에 의해 메이크업 제거가 가능한 세안제 개발도 진행되어 왔는데 이러한 제품들은 물리적인 자극에 의해 메이크업과 각질을 제거하지만 반복해서 사용할 경우 피지선을 자극하게 되어 뾰루지 및 얼굴 붉어짐 등의 증상이 나타난다. 또한 눈에 들어가기가 쉽고, 눈에 들어가게 되면 씻어내기 힘들어 통증을 유발시키는 문제가 있다. On the other hand, the development of a facial cleanser that can remove make-up by physical force using scrub beads has been carried out. These products remove makeup and keratin due to physical stimulation. However, when used repeatedly, they stimulate sebaceous glands, And the like. Also, it is easy to get into the eyes, and it is difficult to wash it if it gets in the eyes, which causes pain.

이에, 메이크업 제거와 개운한 세안이 가능하면서 점도가 낮아 버블폼으로 적용 가능한 신규 물질을 찾기 위한 연구를 거듭하던 중, 실리콘의 양 말단에 PEG를 부가하여 친수성을 높인 화합물은 기포 유지 능력이 우수하면서 메이크업 제거 효과가 있는 것을 확인하고, 본 발명을 완성하였다. Therefore, while researching new materials that can apply makeup removal and refreshing cleansing and viscosity is low and can be applied as bubble foams, it has been found that a compound having high hydrophilicity by adding PEG to both ends of silicone has excellent bubble retention ability, And the present invention has been completed.

따라서, 본 발명의 목적은 메이크업 제거와 개운한 세안이 동시에 가능한 버블폼 타입의 세안제 조성물을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a bubble foam type cleanser composition which is capable of removing make-up and cleansing at the same time.

상기한 목적을 달성하기 위하여, 본 발명은 실리콘 양 말단에 PEG를 부가하여 친수성을 높인 화합물 및 거품 형성능이 있는 계면활성제를 유효성분으로 포함하는 세안제 조성물을 제공한다.In order to accomplish the above object, the present invention provides a cleanser composition comprising, as an active ingredient, a compound having enhanced hydrophilicity by adding PEG to both ends of silicon and a surfactant having foamability.

본 발명에 따른 세안제 조성물은 메이크업 제거와 개운한 세안이 가능한 메이크업 세안제로 활용이 가능하며, 이중 세안의 번거로움을 해소할 수 있다.The cleanser composition according to the present invention can be used as a make-up cleanser which can remove make-up and clean cleanser, thereby eliminating the troublesome facial cleansing.

도 1은 본 발명에 따른 버블폼 타입 세안제 조성물의 기포력을 나타낸 그래프이다.
도 2는 본 발명에 따른 버블폼 타입 세안제 조성물의 메이크업 제거력을 나타낸 사진이다.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graph showing foam force of a bubble foam type cleanser composition according to the present invention. FIG.
2 is a photograph showing the makeup removing power of the bubble foam type cleanser composition according to the present invention.

본 발명은 실리콘 양 말단에 폴리에틸렌 글라이콜(polyethyleneglycol, PEG)를 부가하여 친수성을 높인 화합물 및 거품 형성능이 있는 계면활성제를 유효성분으로 포함하는 세안제 조성물을 제공한다.The present invention provides a cleanser composition comprising, as an active ingredient, a compound having increased hydrophilicity by adding polyethyleneglycol (PEG) to both ends of silicon and a surfactant having foamability.

이하, 본 발명을 보다 상세히 설명한다.
Hereinafter, the present invention will be described in more detail.

본 발명의 세안제 조성물은 메이크업 제거가 가능한 실리콘계 계면활성제 중에서 실리콘 양 말단에 PEG를 부가하여 친수성을 높인 화합물을 유효성분으로 함유하며, 보다 바람직하게는 클렌징력과 기포 유지력이 뛰어난 비스-피이지-18 디메틸 에테르 디메치콘(Bis-PEG-18 dimethyl ether dimethicone)을 함유한다.The cleanser composition of the present invention is a silicone surfactant capable of removing makeup, and contains as an active ingredient a compound having hydrophilicity enhanced by adding PEG to both ends of silicon, more preferably a bis-phage-18 having excellent cleansing power and bubble retention It contains dimethyl ether dimethicone (Bis-PEG-18 dimethyl ether dimethicone).

본 발명의 세안제 조성물에서 유효성분으로 사용되는 실리콘 양 말단에 PEG를 부가하여 친수성을 높인 화합물은 조성물 총 중량에 대하여 5~30중량%로 함유된다. 이는 5중량% 미만이면 메이크업 제거력이 떨어지며, 30중량% 초과의 경우 제형화가 어렵고, 안자극을 유발할 수 있기 때문에 상기와 같이 함량을 한정하였다.The compound having PEG added to both terminals of the silicone used as an active ingredient in the inventive cleaner composition to increase the hydrophilicity is contained in an amount of 5 to 30% by weight based on the total weight of the composition. If the amount is less than 5% by weight, the makeup removing ability is lowered. If the amount is more than 30% by weight, it is difficult to formulate the composition and cause an irritation.

본 발명에 따른 버블폼 타입의 메이크업제거 세안제 조성물은 지방산 비누, 소듐 라우릴 설페이트, 소듐 라우레스 설페이트, 암모늄 라우릴 설페이트, 암모늄 라우레스 설페이트, 라우릴 글루코스 카르복실레이트, 포타슘 글리시네이트, 라우릴 글루코사이드, 데실 글루코사이드, 코코 글루코사이드, 코카미도프로필베타인 및 코카미도프로필 하이드록시 술테인 등과 같은 음이온, 비이온 또는 양쪽성 이온 중에 거품 형성능이 있는 계면활성제 1종 이상을 조성물 총 중량에 대하여 5~30 중량%로 함유한다. 그 함량이 5중량% 미만이면 세정력이 나빠지고, 30중량% 초과이면 눈에 들어갔을 때 안자극을 유발할 수 있으며 점도가 높아 버블폼을 만들기 어렵기 때문에 바람직하지 않다.The makeup removing composition for bubble-foam according to the present invention may contain fatty acid soap, sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, lauryl glucosecarboxylate, potassium glycinate, At least one surfactant capable of forming a foam in an anionic, nonionic or amphoteric ion such as glucoside, decyl glucoside, coco glucoside, cocamidopropyl betaine, and cocamidopropyl hydroxysultain is added to the composition in an amount of 5 to 30 By weight. If the content is less than 5% by weight, the detergency will deteriorate. If the content is more than 30% by weight, an eye irritation may be caused, and it is not preferable because it is difficult to make bubble foam because of high viscosity.

본 발명의 세안제 조성물은 개운한 세안을 위해서 지방산 비누를 주로 사용하였으며, 이는 지방산과 알칼리제의 중화반응에 의해 생성된 지방산 염을 말한다. 보다 상세하게는, 지방산으로부터 지방산 비누를 형성시키는 탄소수 12 내지 탄소수 22의 포화 지방산을 사용할 수 있으며, 구체적인 예를 들면, 라우릭애씨드, 미리스틱애씨드, 팔미틱애씨드, 스테아릭애씨드, 베헤닉애씨드 등이 있다.The cleanser composition of the present invention mainly uses a fatty acid soap for cleansing the face, which refers to a fatty acid salt produced by a neutralization reaction between a fatty acid and an alkali agent. More specifically, a saturated fatty acid having 12 to 22 carbon atoms for forming a fatty acid soap from a fatty acid can be used. Specific examples thereof include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, etc. .

본 발명의 세안제 조성물은 기포 유지력에 도움을 주고자 글리세린, 부틸렌글라이콜 및 프로필렌글라이콜로 이루어진 군에서 선택된 1종 이상의 폴리올을 더 함유할 수 있으며, 이는 메이크업 제거력을 부가적으로 상승시킬 뿐 아니라, 기포의 배수(drainage)를 방지하여 기포력 유지에 도움을 준다.The detergent composition of the present invention may further contain at least one polyol selected from the group consisting of glycerin, butylene glycol and propylene glycol to help maintain bubble retention, which not only enhances makeup removing power , It prevents drainage of bubbles and helps to maintain bubble power.

본 발명의 세안제 조성물에 사용되는 폴리올은 조성물 총 중량에 대하여 5~20중량%로 함유된다. 5중량% 미만에서는 그 효과가 미미하고, 20중량% 초과에서는 점도 상승으로 거품 형성이 오히려 저하되므로 상기와 같이 함량을 한정하였다.The polyol used in the cleanser composition of the present invention is contained in an amount of 5 to 20% by weight based on the total weight of the composition. When the content is less than 5% by weight, the effect is insignificant. When the content is more than 20% by weight, the viscosity is increased and the foam formation is rather lowered.

본 발명의 일 실시예에서는 조성물 총 중량에 대하여 거품 형성능이 있는 계면활성제 1종 이상 5~30 중량%, 비스-피이지-18 디메틸 에테르 디메치콘 5~30 중량%, 폴리올 5~20 중량% 및 정제수 20~85중량%로 이루어진 버블폼 타입의 세안제 조성물을 제공한다.In one embodiment of the present invention, 5 to 30% by weight of at least one surfactant having foam-forming ability, 5 to 30% by weight of bis-phage-18 dimethylether dimethicone, 5 to 20% by weight of polyol, And 20 to 85% by weight of purified water.

본 발명의 세안제 조성물은 메이크업 제거와 세안이 동시에 이뤄지는 것을 특징으로 한다.The cleanser composition of the present invention is characterized in that make-up removal and cleansing are simultaneously performed.

본 발명의 세안제 조성물은 포밍 컨테이너(버블폼 용기)를 통해 거품 형태로 토출되는 버블폼 타입이 바람직하다.The cleanser composition of the present invention is preferably a bubble foam type which is discharged in the form of a foam through a foaming container (bubble foam container).

하기 실시예 및 시험예를 들어 본 발명을 보다 구체적으로 설명하지만, 본 발명이 이에만 한정되는 것은 아니다.The present invention will be described in more detail with reference to the following examples and test examples, but the present invention is not limited thereto.

[실시예 1~3 및 비교예 1~2][Examples 1 to 3 and Comparative Examples 1 to 2]

하기 표 1의 조성으로 실시예 1~3 및 비교예 1~2를 제조하였다. 비교예 1은 일반 버블 클렌징 폼 조성물이고, 비교예 2는 피이지-7 디메치콘 이소스테아레이트를 함유하는 버블 클렌징 폼 조성물이고, 실시예 1~3은 본 발명의 비스-피이지-18 디메틸 에테르 디메치콘을 함유하는 버블 클렌징 폼 조성물이다. 또한, 비교예 1~2 및 실시예 1은 지방산 비누의 함량이 조성물 총 중량에 대하여 20중량%이고, 실시예 2~3은 지방산 비누 함량을 절반인 10중량%로 줄이고, 대신에 기포력을 향상시킬 수 있는 보조 계면활성제로 코카미도프로필 하이드록시 술테인 또는 폴리올로 글리세린, 부틸렌글라이콜을 사용하였다.Examples 1 to 3 and Comparative Examples 1 and 2 were prepared with the compositions shown in Table 1 below. Comparative Example 1 is a general bubble cleansing foam composition, Comparative Example 2 is a bubble cleansing foam composition containing phage-7 dimethicone isostearate, Examples 1 to 3 are bis-phage-18 dimethyl ether It is a bubble cleansing foam composition containing dimethicone. In Comparative Examples 1 and 2 and Example 1, the content of fatty acid soap was 20% by weight based on the total weight of the composition. Examples 2 and 3 reduced the content of fatty acid soap to 10% by weight, As an auxiliary surfactant that can be improved, glycerin or butyleneglycol was used as cocamidopropylhydroxysultaine or polyol.

성분 ingredient 비교예1
(중량%)
Comparative Example 1
(weight%)
비교예2
(중량%)
Comparative Example 2
(weight%)
실시예1
(중량%)
Example 1
(weight%)
실시예2
(중량%)
Example 2
(weight%)
실시예3
(중량%)
Example 3
(weight%)
정제수Purified water To 100To 100 To 100To 100 To 100To 100 To 100To 100 To 100To 100 글리세린glycerin 1010 1010 -- 1010 55 부틸렌글라이콜Butylene glycol -- -- -- -- 55 라우릭애씨드Laurick Acid 1414 1414 1414 77 77 미리스틱애씨드Myristic acid 66 66 66 33 33 수산화칼륨(45%)Potassium hydroxide (45%) 1212 1212 1212 66 66 코카미도프로필 하이드록시 술테인Cocamidopropylhydroxysultaine -- -- -- 2.52.5 -- 피이지-7 디메치콘 이소스테아레이트Phage-7 dimethicone isostearate -- 1010 -- -- -- 비스-피이지-18 디메틸 에테르 디메치콘Bis-phage-18 dimethyl ether dimethicone -- -- 1010 1010 1010 킬레이트제Chelating agent 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount 방부제antiseptic 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount incense 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount

<비교예 1의 제조방법>&Lt; Production method of Comparative Example 1 >

우선, 킬레이트제를 정제수에 투입하고, 여기에 지방산, 폴리올 등을 투입하여 약 70℃로 가열 용해하고 알칼리를 첨가하여 중화한 후, 향과 방부제를 넣어 혼합하고 냉각하여 제조하였다.First, a chelating agent was added to purified water, and a fatty acid, a polyol or the like was added thereto, heated and dissolved at about 70 ° C, neutralized by adding alkali, mixed with fragrance and preservative, and cooled.

<비교예 2 및 실시예 1~3의 제조방법>&Lt; Production method of Comparative Example 2 and Examples 1 to 3 >

우선, 킬레이트제를 정제수에 투입하고, 여기에 폴리올, 지방산을 투입하여 약 70℃에서 가열 용해하고 알칼리를 첨가하여 중화한 후, 비스-피이지-18 디메틸 에테르 디메치콘 또는 피이지-7 디메치콘 이소스테아레이트를 투입하여 용해하였다. 이어서, 향과 방부제 등의 첨가제를 넣어 혼합하고 냉각하여 제조하였다.
First, a chelating agent is added to purified water, and a polyol and a fatty acid are added thereto. The mixture is heated and dissolved at about 70 ° C, neutralized by adding alkali, and then bis-phage-18 dimethyl ether dimethicone or phage- Isostearate was added to dissolve. Next, additives such as fragrance and preservative were added, mixed and cooled.

[시험예 1] 기포력 테스트 [Test Example 1] Bubble strength test

폼 형성 능력을 비교하기 위해서 폼 테스터(foam tester, SITA foam tester R-2000)를 이용하였다. 시료를 증류수에 희석하여 0.5%의 수용액을 만든 후, 250㎖의 용액을 10회에 걸쳐 교반(stirring)하여 일어난 거품의 부피를 측정하였으며, 교반 속도는 800rpm으로 10초간 유지되었다. 측정은 3회 반복하여 평균값을 구하였다. 그 결과는 도 1에 나타내었다.A foam tester (SITA foam tester R-2000) was used to compare foam formability. The sample was diluted with distilled water to make an aqueous solution of 0.5%, and 250 ml of the solution was stirred for 10 times to measure the volume of the foam. The stirring speed was maintained at 800 rpm for 10 seconds. The measurement was repeated three times to obtain an average value. The results are shown in Fig.

도 1의 결과에서 알 수 있듯이, 비스-피이지-18 디메틸 에테르 디메치콘을 함유하는 실시예 1은 기포력이 일반 버븜폼인 비교예 1과 유사하게 높았다. 한편, 피이지-7 디메치콘 이소스테아레이트를 함유하는 비교예 2는 기포력이 실시예1~3 보다 낮았으며, 점도가 높아 거품이 잘 형성되지 않고 쉽게 사그라들기 때문에 버블폼에 적용할 경우에는 거품으로 토출이 잘 되지 않고 토출되어도 금방 사그라들어지게 됨을 알 수 있었다. 또한, 실시예 2는 실시예 1보다 지방산 비누의 함량을 절반으로 줄이고, 대신 양쪽성 계면활성제인 코카미도프로필 하이드록시 술테인과 폴리올을 사용하여 기포력을 향상시킴으로써 실시예 1과 유사한 기포력을 얻을 수 있었다. 실시예 3은 실시예 2와 동일하게 지방산 비누를 조성물 총 중량에 대하여 10중량%로 함유하며, 글리세린과 부틸렌글라이콜의 폴리올 혼합물을 추가로 함유하여 기포력을 향상시킬 수 있었으나, 실시예 2보다는 기포력이 낮았다.
As can be seen from the results of FIG. 1, Example 1 containing bis-phage-18 dimethyl ether dimethicone was higher than that of Comparative Example 1 in which the foaming power was a general foam foam. On the other hand, in Comparative Example 2 containing phage-7 dimethicone isostearate, the foaming power was lower than those of Examples 1 to 3, and the foaming was not easily formed due to the high viscosity, It can be seen that the bubbles can not be discharged easily, and even if the bubbles are ejected, the bubbles are quickly faded. In Example 2, the content of fatty acid soap was reduced to half and the foamability similar to that of Example 1 was improved by using the amphoteric surfactant cocamidopropylhydroxysultaine and a polyol in place of the fatty acid soap in Example 1 . Example 3 contained 10 wt% of fatty acid soap in the total weight of the composition as in Example 2, and further contained a polyol mixture of glycerin and butyleneglycol to improve foaming power. In Example 2 The bubble power was lower.

[시험예 2] 메이크업 제거력 테스트[Test Example 2] Makeup removal test

메이크업제거 테스트는 바이오스킨(bioskin, beaulax 社)에 립스틱을 일정량 도포한 후 5분간 드라이 건조하여 표면이 완전히 굳은 후, 포밍 컨테이너에 넣은 시료(비교예 1~2 및 실시예 1~3)를 각각 3회 펌핑하고 중지를 이용하여, 20회 문지른 후, 물로 헹궈 클렌징력을 비교하였다. 그 결과는 도 2에 나타내었다. The makeup removal test was carried out by applying a predetermined amount of lipstick to a bioskin (beaulax), drying it for 5 minutes to completely harden the surface, and then placing the samples (Comparative Examples 1 to 2 and Examples 1 to 3) in a foaming container Three times pumped and rubbed 20 times using pause, then rinsed with water to compare the cleansing power. The results are shown in Fig.

도 2의 결과에서 알 수 있듯이, 비교예 1의 일반 버블폼과 비교하여 실시예 1~3의 경우 립스틱 제거력이 유의하게 우수하였다. 특히, 실시예 2 및 실시예 3은 실시예 1보다 지방산 비누의 함량이 적음에도 불구하고 보조 계면활성제 및 폴리올을 추가로 함유함으로써 기포력과 클렌징력이 동시에 우수하여, 메이크업 제거와 세안이 동시에 가능한 버블폼으로서 효과가 우수하였다.
As can be seen from the results of FIG. 2, in the case of Examples 1 to 3, the lipstick removing power was significantly superior to that of the general bubble foam of Comparative Example 1. [ In particular, Example 2 and Example 3 are superior in foaming power and cleansing power by containing an auxiliary surfactant and polyol even though the content of fatty acid soap is smaller than that of Example 1, and makeup removal and cleansing are both possible The effect was excellent as a bubble form.

Claims (10)

실리콘 양 말단에 PEG를 부가하여 친수성을 높인 화합물, 계면활성제, 및 폴리올을 유효성분으로 함유하며,
상기 친수성을 높인 화합물은 비스-피이지-18 디메틸 에테르 디메치콘(Bis-PEG-18 dimethyl ether dimethicone)이고, 조성물 총 중량에 대하여 10~30중량%로 함유되며,
상기 계면활성제는 지방산 비누; 및 소듐 라우릴 설페이트, 소듐 라우레스 설페이트, 암모늄 라우릴 설페이트, 암모늄 라우레스 설페이트, 라우릴 글루코스 카르복실레이트, 포타슘 글리시네이트, 라우릴 글루코사이드, 데실 글루코사이드, 코코 글루코사이드, 코카미도프로필베타인 및 코카미도프로필 하이드록시 술테인으로 이루어진 군에서 선택된 1종 이상 화합물의 혼합물이고,
상기 폴리올은 글리세린, 부틸렌글라이콜 및 프로필렌글라이콜로 이루어진 군에서 선택된 2종 이상이며,
상기 친수성을 높인 화합물:지방산 비누의 중량비는 1:1~1:2인 세안제 조성물.
A surfactant, and a polyol as effective components by adding PEG to both terminals of silicon to increase hydrophilicity,
The hydrophilicity-enhancing compound is bis-PEG-18 dimethyl ether dimethicone, which is contained in an amount of 10 to 30% by weight based on the total weight of the composition,
The surfactant may be a fatty acid soap; And sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, lauryl glucosecarboxylate, potassium glycinate, lauryl glucoside, decyl glucoside, coco glucoside, cocamidopropyl betaine, and coca- Hydroxypropyl methacrylate, hydroxypropyl methacrylate, hydroxypropyl methacrylate,
The polyol is at least two selected from the group consisting of glycerin, butylene glycol and propylene glycol,
Wherein the weight ratio of the compound having a higher hydrophilicity to the fatty acid soap is 1: 1 to 1: 2.
삭제delete 삭제delete 제 1항에 있어서, 상기 계면활성제가 지방산 비누; 및 코카미도프로필 하이드록시 술테인의 혼합물인 것을 특징으로 하는 세안제 조성물.The composition of claim 1, wherein the surfactant is selected from the group consisting of fatty acid soap; And a mixture of cocamidopropylhydroxysultaines. 제 1항에 있어서, 상기 지방산 비누가 라우릭애씨드, 미리스틱애씨드, 팔미틱애씨드, 스테아릭애씨드 및 베헤닉애씨드로 이루어진 군에서 선택된 1종 이상인 것을 특징으로 하는 세안제 조성물.The cleanser composition according to claim 1, wherein the fatty acid soap is at least one selected from the group consisting of lauric acid, myristic acid, palmitic acid, stearic acid and behenic acid. 제 1항에 있어서, 상기 계면활성제가 조성물 총 중량에 대하여 5~30 중량%로 함유되는 것을 특징으로 하는 세안제 조성물.The cleansing composition according to claim 1, wherein the surfactant is contained in an amount of 5 to 30% by weight based on the total weight of the composition. 제 1항에 있어서, 상기 폴리올은 글리세린 및 부틸렌글라이콜의 혼합물인 것을 특징으로 하는 세안제 조성물.The cleanser composition of claim 1, wherein the polyol is a mixture of glycerin and butylene glycol. 제 1항에 있어서, 상기 폴리올은 조성물 총 중량에 대하여 5~20중량%로 함유되는 것을 특징으로 하는 세안제 조성물.The cleanser composition according to claim 1, wherein the polyol is contained in an amount of 5 to 20% by weight based on the total weight of the composition. 삭제delete 제 1항 및 제 4항 내지 제 8항 중 어느 한 항에 있어서, 상기 조성물은 버블폼 타입인 것을 특징으로 하는 세안제 조성물.9. The cleanser composition according to any one of claims 1 to 8, wherein the composition is a bubble foam type.
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JP2008531740A (en) 2005-03-07 2008-08-14 デブ ワールドワイド ヘルスケア インコーポレーテッド High alcohol content foamable composition containing a silicone based surfactant

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JP2008531740A (en) 2005-03-07 2008-08-14 デブ ワールドワイド ヘルスケア インコーポレーテッド High alcohol content foamable composition containing a silicone based surfactant
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