JPH11268977A - Enamel for pottery and pottery product using the same - Google Patents
Enamel for pottery and pottery product using the sameInfo
- Publication number
- JPH11268977A JPH11268977A JP9547998A JP9547998A JPH11268977A JP H11268977 A JPH11268977 A JP H11268977A JP 9547998 A JP9547998 A JP 9547998A JP 9547998 A JP9547998 A JP 9547998A JP H11268977 A JPH11268977 A JP H11268977A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- glaze
- enamel
- water
- pottery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000003298 dental enamel Anatomy 0.000 title abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 48
- 239000006185 dispersion Substances 0.000 claims abstract description 12
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 8
- 239000005871 repellent Substances 0.000 claims description 15
- 239000000919 ceramic Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 230000002940 repellent Effects 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 7
- 239000002245 particle Substances 0.000 abstract description 7
- 229920003169 water-soluble polymer Polymers 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 4
- 229910052777 Praseodymium Inorganic materials 0.000 abstract description 3
- 238000001354 calcination Methods 0.000 abstract description 3
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- 239000003792 electrolyte Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 229910052718 tin Inorganic materials 0.000 abstract description 3
- 229910052720 vanadium Inorganic materials 0.000 abstract description 3
- 239000003945 anionic surfactant Substances 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 230000002209 hydrophobic effect Effects 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- 238000004040 coloring Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000010433 feldspar Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000006028 limestone Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910052845 zircon Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は陶磁器の装飾技法に
係わり、特に焼成後表面に深み、透明感を兼ね備えたテ
クスチュアーを与えるのに好適な釉薬とそれを用いた陶
磁器製品に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a technique for decorating ceramics, and more particularly to a glaze suitable for providing a texture having a deep and transparent feeling after firing and a ceramic article using the same.
【０００２】[0002]
【従来の技術】釉薬とは陶磁器製品及びホウロウ製品の
表面部分にガラス質の被覆層を形成するために用いられ
るものであり、主として無機物質から成るものである。
その釉薬表面に斑点模様を与える技法としては、従来、
特開昭５５−４７２８４号に見られるように、素地面に
スプレーで小斑点に施釉し、この上に透明釉を流下法で
全面に施釉し、さらにこの上に大斑点などの部分施釉を
行う方法や、特開昭５７−２２１８７号に見られるよう
に、釉薬中に造粒した粒の大きいフリットを混合して斑
点模様とする方法がある。2. Description of the Related Art Glaze is used for forming a glassy coating layer on the surface of ceramic products and enamel products, and is mainly composed of an inorganic substance.
As a technique to give a spot pattern on the glaze surface,
As shown in JP-A-55-47284, a small spot is glazed on a bare ground by spraying, a transparent glaze is applied on the entire surface by a flowing method, and a partial glaze such as a large spot is applied thereon. As described in Japanese Patent Application Laid-Open No. 57-22187, there is a method in which large frit granulated in a glaze is mixed to form a spotted pattern.
【０００３】また凹凸模様を与える技法としては特開昭
５３−１４５８２１号に見られるように釉薬に有機含水
ゲルを添加することによって釉薬表面に凹凸模様を得る
方法や、特開昭５０−１５５５１１号に見られるように
融点の低い釉薬を施した後に異色の融点の高い釉薬を全
面または模様状に施し、融点の低い釉薬が沸騰して煮え
を起こす火度で焼成することによってクレーター状模様
を得る方法がある。As a technique for providing an uneven pattern, a method for obtaining an uneven pattern on the glaze surface by adding an organic hydrogel to the glaze as disclosed in JP-A-53-145821, and a technique disclosed in JP-A-50-155511 As shown in the above, a glaze with a low melting point is applied, and then a glaze with a different color and a high melting point is applied on the entire surface or in a pattern, and the glaze with a low melting point is boiled and fired to a boil to obtain a crater-like pattern. There is a way.
【０００４】[0004]
【発明が解決しようとする課題】従来の装飾技法におい
て斑点模様や凹凸模様を得ることは非常に手間がかかる
操作が必要であり、また顔料以外に別の添加物を混合し
たりしなければならなく、しかも斑点模様や凹凸模様等
様々な模様が組み合わさったテクスチュアーを得ること
は困難であった。Obtaining a spotted pattern or a concavo-convex pattern in the conventional decoration technique requires a very troublesome operation, and requires the addition of other additives in addition to the pigment. Moreover, it was difficult to obtain a texture in which various patterns such as a spot pattern and an uneven pattern were combined.
【０００５】本発明は、上記課題を解決するためになさ
れたもので、本発明の目的は、陶磁器製品の表面に斑点
模様、凹凸模様等が組み合わさり、しかも深み、透明感
を兼ね備えているテクスチュアーを容易に与えることが
できる陶磁器用釉薬及びそれを用いた陶磁器製品を提供
することにある。SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to provide a texture in which spots and irregularities are combined on the surface of a ceramic product, and which has a deep and transparent feeling. It is an object of the present invention to provide a ceramic glaze and a ceramic product using the same, which can easily give a glaze.
【０００６】[0006]
【課題を解決するための手段】上記目的を達成するため
に釉薬中への分散度の異なる顔料を使用する手段につい
て研究し、水系溶媒に対して自発的に分散する性質を有
する顔料（以下易分散顔料と記す）、及び撥水機能を有
する顔料（以下撥水顔料と記す）を使用することによ
り、上記課題を解決し得ることを見出し本発明を完成し
た。In order to achieve the above object, a study has been made on means of using pigments having different degrees of dispersion in glaze, and pigments having a property of spontaneously dispersing in an aqueous solvent (hereinafter referred to as easy-to-use pigments). It has been found that the above problem can be solved by using a pigment having a water-repellent function (hereinafter, referred to as a water-repellent pigment) and a pigment having a water-repellent function, thereby completing the present invention.
【０００７】[0007]
【発明の実施の形態】本発明に用いられる釉薬の種類、
組成には制限がなく、陶磁器に従来から使用されている
ものから任意に選択することができるが、一般にはＳｉ
Ｏ2、Ａｌ2Ｏ3、Ｋ2Ｏ、Ｎａ2Ｏ、ＣａＯ、ＭｇＯ、Ｚ
ｎＯ、ＺｒＯ2の中の１種以上を含むものが用いられ
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS The type of glaze used in the present invention,
The composition is not limited and can be arbitrarily selected from those conventionally used for ceramics.
O 2 , Al 2 O 3 , K 2 O, Na 2 O, CaO, MgO, Z
Those containing at least one of nO and ZrO 2 are used.
【０００８】本発明に用いられる易分散顔料としては、
Ｆｅ，Ｃｒ，Ｃｏ，Ｓｎ，Ｚｒ，Ｖ，Ｐｒ等の遷移元素
の化合物またはこれに他元素の化合物を混合し焼成して
得られる複合酸化物の顔料粒子を水系溶媒に対して分散
する性質を有する分散体に保持させたものが用いられ
る。分散体としては無機電解質と水溶性高分子またはア
ニオン性界面活性剤の内の少なくとも１種を使用したも
のが好ましい。The easily dispersible pigment used in the present invention includes:
The property of dispersing pigment particles of a composite oxide obtained by mixing a compound of a transition element such as Fe, Cr, Co, Sn, Zr, V, Pr or a compound of another element with the compound and calcining the same in an aqueous solvent. What was held by the dispersion which has it is used. As the dispersion, one using at least one of an inorganic electrolyte and a water-soluble polymer or an anionic surfactant is preferable.
【０００９】本発明に用いられる撥水顔料としては、Ｆ
ｅ，Ｃｒ，Ｃｏ，Ｓｎ，Ｚｒ，Ｖ，Ｐｒ等の遷移元素の
化合物またはこれに他元素の化合物を混合し焼成して得
られる複合酸化物の顔料粒子を撥水機能を有する撥水体
に保持させたものが用いられる。撥水体としては難水溶
性高分子を使用したものが好ましい。The water-repellent pigment used in the present invention includes F
e, Cr, Co, Sn, Zr, V, Pr, or other transition element compound, or a composite oxide pigment particle obtained by mixing and baking a compound of another element with a water-repellent material having a water-repellent function. Those that have been used are used. As the water repellent, those using a poorly water-soluble polymer are preferable.
【００１０】本発明では目的のテクスチュアーに応じて
釉薬と顔料の混合比率、混合方法、混合時間を適宜に選
択することができる。混合比率としては釉薬乾燥重量に
対して易分散顔料、分散性向上や撥水などの処理を行っ
ていない市販の顔料（以下通常顔料と記す）、撥水顔料
をそれぞれ０．０１〜１０％の範囲で任意に選択するこ
とができるが、好ましくは０．０１〜５％である。混合
比率が０．０１％未満であると、得られる釉薬面の模様
が顔料添加量不足のため発色しない場合があり、またそ
れが１０％以上であると得られる釉薬面が凹凸になりす
ぎて不良になる場合がある。混合方法としては、ボール
ミル、撹拌機等特に限定はしない。ボールミルの混合時
間については、０．１〜４８時間の範囲で任意に選択す
ることができるが、好ましくは０．１〜３時間である。
混合時間が４８時間より長くなると、撥水顔料が親水化
し水に分散してしまうため所望の模様が得られない場合
がある。撹拌機の混合時間については回転数との兼ね合
いで決定するのが好ましい。In the present invention, the mixing ratio of the glaze and the pigment, the mixing method, and the mixing time can be appropriately selected according to the target texture. The mixing ratio of the easily dispersed pigment, the commercially available pigment not subjected to the treatment of improving dispersibility or water repellency (hereinafter, usually referred to as pigment) and the water repellent pigment to the dry weight of the glaze is 0.01 to 10%, respectively. Although it can be arbitrarily selected within the range, it is preferably 0.01 to 5%. If the mixing ratio is less than 0.01%, the resulting glaze surface pattern may not be colored due to insufficient pigment addition, and if it is more than 10%, the resulting glaze surface may be too uneven. May be defective. The mixing method is not particularly limited, such as a ball mill and a stirrer. The mixing time of the ball mill can be arbitrarily selected within the range of 0.1 to 48 hours, but is preferably 0.1 to 3 hours.
If the mixing time is longer than 48 hours, the desired pattern may not be obtained because the water-repellent pigment becomes hydrophilic and disperses in water. The mixing time of the stirrer is preferably determined in consideration of the number of rotations.
【００１１】本発明で使用される易分散顔料は釉薬に混
合されると次第に釉薬中へ分散していく。その効果は分
散体中の水溶性高分子の親水基が水との水素結合をして
いく過程において顔料粒子が遊離されることによるもの
である。無機電解質は釉薬に添加した際に最初に溶解
し、添加直後の分散性を増加させる働きがある。The easily dispersed pigment used in the present invention gradually disperses into the glaze as it is mixed with the glaze. This effect is attributable to the release of pigment particles in the process in which the hydrophilic groups of the water-soluble polymer in the dispersion form hydrogen bonds with water. The inorganic electrolyte first dissolves when added to the glaze, and acts to increase the dispersibility immediately after the addition.
【００１２】一方、撥水顔料は釉薬に混合されても分散
は殆ど行われない。撥水体中の難水溶性高分子の疎水基
は水との結合を起こさないため、疎水基間の分子間力に
よって顔料粒子が凝集を起こす。しかし混合を続けてい
く内に徐々にその分子間に水分子が入り込み、やがては
分散が引き起こされる。それらの顔料の分散の度合は前
記混合方法、混合時間によって制御することができ、そ
の分散度合によって様々なテクスチュアーを表すことが
できるのである。On the other hand, the water-repellent pigment is hardly dispersed even when mixed with the glaze. Since the hydrophobic group of the poorly water-soluble polymer in the water repellent does not cause bonding with water, the pigment particles aggregate due to the intermolecular force between the hydrophobic groups. However, as the mixing is continued, water molecules gradually enter between the molecules and eventually cause dispersion. The degree of dispersion of these pigments can be controlled by the mixing method and the mixing time, and various textures can be represented by the degree of dispersion.
【００１３】[0013]
【実施例】以下本発明を実施例により詳細に説明する。 （実施例１） 長石 ２５重量％ 珪石 ４５重量％ 石灰石 １５重量％ 亜鉛華 ８重量％ カオリン ７重量％ 上記原料からなる釉薬１００重量％に対して水を５０％
加え、ボールミルにて１８時間粉砕したものを基礎釉薬
とした。この釉薬に分散度の異なるグレー系の同一色顔
料として易分散顔料（川村化学株式会社製）、通常顔
料、撥水顔料（川村化学株式会社製）を上記釉薬１００
重量％に対してそれぞれ０．５％添加し、ボールミルに
て３０分混合して目的釉薬を得た。この釉薬をタイル板
に口径２．５ｍｍΦのスプレーガンにて施釉しこれを１
１００℃で焼成し、グレー系の着色タイルを得た。着色
タイルには斑点模様、凹凸模様と透明感の組み合わさっ
たテクスチュアーが現れた。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail with reference to embodiments. (Example 1) Feldspar 25% by weight Silica stone 45% by weight Limestone 15% by weight Zinc flower 8% by weight Kaolin 7% by weight Water 50% with respect to 100% by weight of glaze composed of the above raw materials
In addition, what was ground with a ball mill for 18 hours was used as a base glaze. An easily dispersible pigment (manufactured by Kawamura Chemical Co., Ltd.), a normal pigment, and a water-repellent pigment (manufactured by Kawamura Chemical Co., Ltd.) are used as the same color pigment as the same color pigment of different dispersity in this glaze 100
0.5% of each was added to the weight%, and the mixture was mixed by a ball mill for 30 minutes to obtain a target glaze. This glaze is glazed on a tile plate with a spray gun with a diameter of 2.5 mmΦ.
It was fired at 100 ° C. to obtain a gray colored tile. Textures appeared on the colored tiles, combining spots, irregularities and transparency.
【００１４】（実施例２） 長石 ２１重量％ 珪石 ４２重量％ 石灰石 １５重量％ ジルコン １１重量％ 亜鉛華 ７重量％ カオリン ４重量％ 上記原料からなる釉薬１００重量％に対して水を５０％
加え、ボールミルにて１８時間粉砕したものを基礎釉薬
とした。この釉薬にアイボリー系の同一色顔料で分散度
の異なる顔料として通常顔料を前記釉薬１００重量％に
対して１％、撥水顔料を４％添加し、撹拌機にて６０分
混合して目的釉薬を得た。この釉薬をタイル板に口径
２．５ｍｍΦのスプレーガンにて施釉しこれを１１００
℃で焼成し、アイボリー系の着色タイルを得た。着色タ
イルには凹凸模様と透明感の組み合わさったテクスチュ
アーが現れた。(Example 2) Feldspar 21% by weight Silica stone 42% by weight Limestone 15% by weight Zircon 11% by weight Zinc white 7% by weight Kaolin 4% by weight Water is 50% with respect to 100% by weight of glaze composed of the above-mentioned raw materials.
In addition, what was ground with a ball mill for 18 hours was used as a base glaze. To the glaze, 1% of a normal pigment and 100% by weight of the above-mentioned glaze and 4% of a water-repellent pigment are added as ivory pigments of the same color and having different degrees of dispersion, and mixed with a stirrer for 60 minutes to mix the desired glaze. I got This glaze is applied to a tile plate with a spray gun having a diameter of 2.5 mmΦ,
C. to obtain an ivory colored tile. Textures appeared on the colored tiles, combining textures and clarity.
【００１５】（実施例３） 長石 ２１重量％ 珪石 ４２重量％ 石灰石 １５重量％ ジルコン １１重量％ 亜鉛華 ７重量％ カオリン ４重量％ 上記原料からなる釉薬１００重量％に対して水を５０重
量％加え、ボールミルにて１８時間粉砕したものを基礎
釉薬とした。この釉薬に分散度の異なる顔料としてグレ
ー系の易分散顔料（川村化学株式会社製）、ブルー系の
撥水顔料（川村化学株式会社製）を上記釉薬１００重量
％に対してそれぞれ５％添加し、撹拌機にて３０分混合
して目的釉薬を得た。この釉薬をタイル板に口径２．５
ｍｍΦのスプレーガンにて施釉しこれを１１００℃で焼
成し、着色タイルを得た。着色タイルにはグレー系の下
地にブルー系とグレー系の合わさった斑点模様と透明感
の組み合わさったテクスチュアーが現れた。(Example 3) Feldspar 21% by weight Silica 42% by weight Limestone 15% by weight Zircon 11% by weight Zinc white 7% by weight Kaolin 4% by weight Water was added by 50% by weight to 100% by weight of the glaze composed of the above raw materials. The product was ground with a ball mill for 18 hours to obtain a base glaze. To the glaze, 5% each of a gray easily dispersible pigment (manufactured by Kawamura Chemical Co., Ltd.) and a blue water-repellent pigment (manufactured by Kawamura Chemical Co., Ltd.) were added as pigments having different dispersities with respect to 100% by weight of the above glaze. The mixture was mixed with a stirrer for 30 minutes to obtain a target glaze. Apply this glaze to a tile plate with a caliber of 2.5
It was glazed with a spray gun of mmΦ and baked at 1100 ° C. to obtain a colored tile. On the colored tile, a texture with a combination of blue and gray spots combined with transparency appeared on a gray base.
【００１６】[0016]
【発明の効果】本発明は上記構成により次の効果を発揮
する。陶磁器用釉薬中への分散度の異なる２種類以上の
顔料を使用することにより、焼成後の陶磁器表面に従来
の装飾技法では為し得なかった斑点模様や凹凸模様に深
み、透明感が兼ね備わったテクスチュアーを発現させる
ことができる。According to the present invention, the following effects are exhibited by the above configuration. By using two or more kinds of pigments with different degrees of dispersion in ceramic glaze, the fired ceramic surface has deep spots and irregularities that could not be done with conventional decoration techniques, and also has a transparent feeling Texture can be expressed.
Claims (3)
以上使用することにより、焼成後の釉薬呈色に深み、透
明感を兼ね備えたテクスチュアーを与えることを特徴と
する陶磁器用釉薬。1. A glaze for ceramics, characterized in that by using two or more kinds of pigments having different degrees of dispersion in the glaze, the color of the glaze after firing is deepened and a texture having a transparency is provided.
に対して自発的に分散する性質を有する顔料、及び水系
溶媒に対して撥水機能を有する顔料を使用した陶磁器用
釉薬。2. A glaze for ceramics, wherein a pigment having a property of spontaneously dispersing in an aqueous solvent and a pigment having a water repellent function with respect to an aqueous solvent are used as the pigment for the glaze.
を用いた陶磁器製品。3. A ceramic product using the ceramic glaze according to claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9547998A JPH11268977A (en) | 1998-03-23 | 1998-03-23 | Enamel for pottery and pottery product using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9547998A JPH11268977A (en) | 1998-03-23 | 1998-03-23 | Enamel for pottery and pottery product using the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11268977A true JPH11268977A (en) | 1999-10-05 |
Family
ID=14138763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9547998A Pending JPH11268977A (en) | 1998-03-23 | 1998-03-23 | Enamel for pottery and pottery product using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11268977A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005272231A (en) * | 2004-03-25 | 2005-10-06 | Toto Ltd | Solid for hygiene porcelain glaze and manufacturing method of ceramic ware |
| JP2009143794A (en) * | 2007-11-21 | 2009-07-02 | Danto Holdings Corp | Low heat storage ceramics and manufacturing method thereof |
| JP2018518542A (en) * | 2015-04-20 | 2018-07-12 | 張利 | BZ high temperature painting |
| CN108529878A (en) * | 2018-06-14 | 2018-09-14 | 江西嘉顺瓷业有限公司 | A kind of low bulk sesame point glaze and preparation method thereof |
-
1998
- 1998-03-23 JP JP9547998A patent/JPH11268977A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005272231A (en) * | 2004-03-25 | 2005-10-06 | Toto Ltd | Solid for hygiene porcelain glaze and manufacturing method of ceramic ware |
| JP2009143794A (en) * | 2007-11-21 | 2009-07-02 | Danto Holdings Corp | Low heat storage ceramics and manufacturing method thereof |
| JP2018518542A (en) * | 2015-04-20 | 2018-07-12 | 張利 | BZ high temperature painting |
| CN108529878A (en) * | 2018-06-14 | 2018-09-14 | 江西嘉顺瓷业有限公司 | A kind of low bulk sesame point glaze and preparation method thereof |
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