JPH11256237A - Production of cold rolled steel strip or hot dip plated steel strip excellent in workability - Google Patents
Production of cold rolled steel strip or hot dip plated steel strip excellent in workabilityInfo
- Publication number
- JPH11256237A JPH11256237A JP5690498A JP5690498A JPH11256237A JP H11256237 A JPH11256237 A JP H11256237A JP 5690498 A JP5690498 A JP 5690498A JP 5690498 A JP5690498 A JP 5690498A JP H11256237 A JPH11256237 A JP H11256237A
- Authority
- JP
- Japan
- Prior art keywords
- steel strip
- weight
- cold rolling
- hot
- cold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 84
- 239000010959 steel Substances 0.000 title claims abstract description 84
- 239000010960 cold rolled steel Substances 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 238000005097 cold rolling Methods 0.000 claims abstract description 75
- 238000000137 annealing Methods 0.000 claims abstract description 21
- 238000005098 hot rolling Methods 0.000 claims abstract description 16
- 238000001953 recrystallisation Methods 0.000 claims abstract description 12
- 238000005096 rolling process Methods 0.000 claims abstract description 11
- 230000009466 transformation Effects 0.000 claims abstract description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- 238000005554 pickling Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 20
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 6
- 239000008397 galvanized steel Substances 0.000 claims description 6
- 238000007747 plating Methods 0.000 abstract description 12
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 229910052758 niobium Inorganic materials 0.000 abstract description 3
- 229910052748 manganese Inorganic materials 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 24
- 238000004804 winding Methods 0.000 description 16
- 230000009467 reduction Effects 0.000 description 14
- 239000000047 product Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 238000005728 strengthening Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 238000003618 dip coating Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 239000002436 steel type Substances 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000012776 electronic material Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 230000003796 beauty Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000010299 mechanically pulverizing process Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、自動車用鋼板,家電製
品,電機,電子材料等の用途に適した加工性に優れた冷
延鋼帯又は溶融めっき鋼帯を製造する方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a cold-rolled steel strip or a hot-dip galvanized steel strip which is excellent in workability and suitable for use in automobile steel sheets, home electric appliances, electric machines, electronic materials and the like.
【0002】[0002]
【従来の技術】Cuを添加した冷延鋼帯では、比較的低
い温度の熱処理を施すだけでCuの析出強化作用が発現
される。Cu添加冷延鋼帯は、この性質を利用して従来
の高強度冷延鋼帯以上の高強度が得られる材料として、
自動車,家電製品,電機,電子材料等の広範な分野で多
用されている。この種の用途では、過酷なプレス加工が
施されることもあるため優れた深絞り性が要求されてい
る。また、製品の美麗さが問題にされている昨今の市場
を考慮すると、良好な表面性状をもつことも製品価値を
高める上で重要な要件になる。2. Description of the Related Art In a cold-rolled steel strip to which Cu is added, the effect of strengthening the precipitation of Cu is exhibited only by performing a heat treatment at a relatively low temperature. Cu-added cold-rolled steel strip is a material that can take advantage of this property to obtain higher strength than conventional high-strength cold-rolled steel strip.
It is widely used in a wide range of fields such as automobiles, home appliances, electric machines, and electronic materials. In this type of application, excellent deep drawability is required because severe press working may be performed. In addition, considering the recent market where the beauty of products is a problem, having good surface properties is also an important requirement for increasing the product value.
【0003】この種の冷延鋼帯は、成分が特定された鋼
を厚さ250mm程度の連鋳スラブ又は分塊スラブと
し、連鋳スラブ又は分塊スラブを2〜6mm程度の厚み
に熱間圧延し、得られた熱延鋼帯を酸洗でデスケールし
た後、冷間圧延を施し、次いで再結晶焼鈍を施すことに
より製造されている。また、溶融めっき鋼帯は、再結晶
焼鈍後に溶融めっきすることにより製造されている。製
造された冷延鋼帯や溶融めっき鋼帯は、引張試験で求め
た伸びや深絞り性の指標となるランクフォード値で加工
性が評価される。しかし、伸びやランクフォード値は、
鋼成分の外に製造条件によっても大きな影響を受ける。
そのため、必要とする加工性を確保するため、従来から
種々の製造条件が設定されている。[0003] In this type of cold-rolled steel strip, a steel whose composition is specified is made into a continuous cast slab or a solid slab having a thickness of about 250 mm, and the continuous cast slab or the solid slab is hot-rolled to a thickness of about 2 to 6 mm. It is manufactured by rolling, descaled by hot-rolled steel strip, pickling, cold rolling, and then recrystallization annealing. The hot-dip coated steel strip is manufactured by hot-dip plating after recrystallization annealing. The workability of the manufactured cold-rolled steel strip and hot-dip coated steel strip is evaluated based on the elongation obtained by a tensile test and the Rankford value which is an index of deep drawability. However, growth and Rankford values,
In addition to steel components, it is greatly affected by manufacturing conditions.
Therefore, various manufacturing conditions have been conventionally set in order to secure required workability.
【0004】[0004]
【発明が解決しようとする課題】なかでも、熱間圧延時
の巻取り温度は、鋼帯の伸びやランクフォード値に大き
く影響する。巻取り温度を高めに設定すると伸びやラン
クフォード値が向上するが、過度に高い温度で熱延鋼帯
を巻き取ると、巻取り後の冷却過程で鋼帯表面の酸化が
進行し、厚い酸化スケールが生成する。その結果、後続
の酸洗工程においてデスケール性が低下し、生産性が大
きく阻害されるばかりでなく、鋼帯の表面性状にも悪影
響を及ぼす。特に、Cu添加鋼帯では、デスケール性の
低下が著しい。そのため、巻取り温度を高めに設定する
ことには実用的な面から制約が加わり、巻取り温度の上
昇によって伸びやランクフォード値を向上させることに
は限界があった。In particular, the coiling temperature during hot rolling greatly affects the elongation of the steel strip and the Rankford value. If the winding temperature is set higher, the elongation and the Rankford value increase, but if the hot-rolled steel strip is wound at an excessively high temperature, the oxidation of the steel strip surface proceeds during the cooling process after winding, resulting in thicker oxidation. Scale generated. As a result, in the subsequent pickling step, the descalability is reduced, and not only is productivity significantly impaired, but also the surface properties of the steel strip are adversely affected. In particular, in the Cu-added steel strip, the descaling property is significantly reduced. For this reason, setting the winding temperature to a higher value imposes restrictions from a practical point of view, and there is a limit in improving the elongation and the Rankford value by increasing the winding temperature.
【0005】本発明は、このような問題を解消すべく案
出されたものであり、鋼成分及び製造条件を総合的に調
整して巻取り温度を比較的高く設定すると共に、酸洗前
工程としてデスケール性を高める冷間圧延を施すことに
より、生産性を阻害することなく、良好な表面性状をも
ち、しかも加工性に優れた冷延鋼帯及び溶融めっき鋼帯
を製造することを目的とする。The present invention has been devised in order to solve such a problem. The steel composition and the manufacturing conditions are comprehensively adjusted to set a relatively high winding temperature, and the pre-pickling process is performed. By performing cold rolling to increase the descaling property, it is intended to produce a cold rolled steel strip and a hot-dip steel strip having good surface properties and excellent workability without impairing productivity. I do.
【0006】[0006]
【課題を解決するための手段】本発明の製造方法は、そ
の目的を達成するため、C:0.0005〜0.01重
量%,Si:2.0重量%以下,Mn:0.05〜3.
0重量%,P:0.2重量%以下,S:0.0005〜
0.02重量%,Cu:0.5〜3.0重量%,酸可溶
Al:0.005〜0.1重量%,N:0.007重量
%以下,Ti:0.01〜0.1重量%及び/又はN
b:0.01〜0.1重量%を含む組成をもつ鋼スラブ
を再加熱又は直送し、仕上げ圧延温度Ar3変態点以上,
巻取り温度650〜800℃の熱間圧延を施し、得られ
た熱延鋼帯に冷延率10〜60%の一次冷間圧延を施
し、酸洗後、更に冷延率20%以上で且つ一次冷間圧延
と合計した全冷延率が60〜95%となるように二次冷
間圧延を施し、得られた冷延鋼帯を再結晶温度以上90
0℃以下で焼鈍又は焼鈍後に溶融めっきすることを特徴
とする。使用する鋼スラブとしては、更にNi:0.2
〜2.0重量%を含むことができる。また、B:0.0
002〜0.002重量%,Zr:0.01〜0.1重
量%,V:0.01〜0.1重量%の1種又は2種以上
を含む鋼スラブも使用可能である。According to the production method of the present invention, to achieve the object, C: 0.0005 to 0.01% by weight, Si: 2.0% by weight or less, Mn: 0.05 to 0.05% by weight. 3.
0% by weight, P: 0.2% by weight or less, S: 0.0005-
0.02% by weight, Cu: 0.5-3.0% by weight, acid-soluble Al: 0.005-0.1% by weight, N: 0.007% by weight or less, Ti: 0.01-0. 1% by weight and / or N
b: A steel slab having a composition containing 0.01 to 0.1% by weight is reheated or directly fed, and is subjected to a finish rolling temperature Ar 3 transformation point or higher,
The hot-rolled steel strip is subjected to hot rolling at a winding temperature of 650 to 800 ° C., and the obtained hot-rolled steel strip is subjected to primary cold rolling at a cold rolling rate of 10 to 60%. The secondary cold rolling is performed so that the total cold rolling rate combined with the primary cold rolling is 60 to 95%, and the obtained cold rolled steel strip is heated to a recrystallization temperature of 90% or more.
Annealing at 0 ° C. or lower or hot-dip plating after annealing is characterized. The steel slab to be used is further Ni: 0.2
2.02.0% by weight. B: 0.0
Steel slabs containing one or more of 002 to 0.002% by weight, Zr: 0.01 to 0.1% by weight, and V: 0.01 to 0.1% by weight can also be used.
【0007】[0007]
【実施の形態】本発明では、冷延鋼帯又は溶融めっき鋼
帯の強度に応じて合金設計された鋼スラブから熱延鋼帯
を製造する際、比較的高い温度で熱延鋼帯をコイルに巻
き取ることにより、冷延鋼帯又は溶融めっき鋼帯で高い
伸びやランクフォード値を確保している。高めに設定さ
れた巻取り温度のために酸化スケールが生成し易い傾向
にあるが、酸洗前工程において冷延率10〜60%の冷
間圧延を施すことにより、デスケール性を向上させてい
る。したがって、たとえ酸化スケールが厚く成長するよ
うな場合があっても、通常の酸洗条件で鋼帯表面から酸
化スケールが容易に除去される。また、酸洗前の冷間圧
延は、得られる冷延鋼帯や溶融めっき鋼帯の表面性状を
改善する上でも有効である。DESCRIPTION OF THE PREFERRED EMBODIMENTS According to the present invention, when a hot-rolled steel strip is manufactured from a steel slab alloy-designed according to the strength of a cold-rolled steel strip or hot-dip steel strip, the hot-rolled steel strip is coiled at a relatively high temperature. The high elongation and Rankford value of the cold-rolled steel strip or hot-dip coated steel strip are ensured. Oxidation scale tends to be easily generated due to a relatively high winding temperature, but the descaling property is improved by performing cold rolling at a cold rolling rate of 10 to 60% in a pre-pickling process. . Therefore, even if the oxide scale grows thickly, the oxide scale is easily removed from the surface of the steel strip under ordinary pickling conditions. Cold rolling before pickling is also effective in improving the surface properties of the obtained cold rolled steel strip or hot-dip steel strip.
【0008】以下、本発明が対象とする鋼に含まれる合
金成分,含有量,製造条件等を説明する。 C:0.0005〜0.01重量% 本発明の鋼におけるCは、TiC,NbC等の炭化物と
して固定される成分であるが、C含有量が低いほどラン
クフォード値や伸びが改善され、しかも固定化元素とし
てのTi,Nbの含有量を低減できる。そのため、C含
有量の上限を0.01重量%に規制する。しかし、0.
0005重量%未満のC含有量は、製鋼工程で過度の脱
炭精錬を必要とし、製造コストの上昇を招く。Hereinafter, alloy components, contents, production conditions, and the like contained in steel to which the present invention is applied will be described. C: 0.0005 to 0.01% by weight C in the steel of the present invention is a component fixed as a carbide such as TiC and NbC. The lower the C content, the more the Rankford value and elongation are improved. The contents of Ti and Nb as the fixing elements can be reduced. Therefore, the upper limit of the C content is restricted to 0.01% by weight. However, 0.
If the C content is less than 0005% by weight, excessive decarburization refining is required in the steel making process, resulting in an increase in production costs.
【0009】Si:2.0重量%以下 加工性やめっき性に悪影響を及ぼす元素であり、Si含
有量の増加に従って伸びやランクフォード値が低下する
方向にある。しかし、強度改善の割りには加工性の低下
がそれほど大きくないことから、鋼の強化元素として有
効な合金成分として使用することもできる。高強度鋼板
として要求される強度を得るためには、0.2重量%以
上のSi含有が好ましい。しかし、2.0重量%を超え
る多量のSiが含まれると、酸洗前工程としての冷間圧
延を施しても表面性状が改善されず、加工性も低下す
る。Si: 2.0% by weight or less Si is an element that has an adverse effect on workability and plating property, and the elongation and the Rankford value tend to decrease as the Si content increases. However, since the reduction in workability is not so large compared to the improvement in strength, it can be used as an effective alloy component as a strengthening element for steel. In order to obtain the strength required as a high-strength steel sheet, it is preferable to contain 0.2% by weight or more of Si. However, when a large amount of Si exceeding 2.0% by weight is contained, even if cold rolling is performed as a pre-pickling step, the surface properties are not improved, and the workability is also reduced.
【0010】Mn:0.05〜3.0重量% 熱間圧延時にSに誘起される熱間脆性を防止し、鋼を高
強度化する上で有効な成分である。熱間脆性の防止に
は、0.05重量%以上のMn含有量が必要である。ま
た、Mn含有量が0.50重量%以上になると、Siと
同様に鋼板の強度を改善する作用が顕著になる。しか
し、3.0重量%を超える多量のMnが含まれると、加
工性が劣化する。 P:0.2重量%以下 Siと同様に、加工性を大きく劣化させない強化元素で
あり、製品に要求される強度に応じた必要量が添加され
る。しかし、0.2重量%を超える多量のP含有量で
は、耐二次加工脆性を低下させる傾向がみられる。Mn: 0.05 to 3.0% by weight An effective component for preventing hot brittleness induced by S during hot rolling and increasing the strength of steel. To prevent hot brittleness, a Mn content of 0.05% by weight or more is required. When the Mn content is 0.50% by weight or more, the effect of improving the strength of the steel sheet becomes remarkable as in the case of Si. However, when a large amount of Mn exceeding 3.0% by weight is contained, workability is deteriorated. P: 0.2% by weight or less Like Si, it is a strengthening element that does not significantly deteriorate workability, and a necessary amount according to the strength required for a product is added. However, a large P content exceeding 0.2% by weight tends to reduce the secondary work brittleness resistance.
【0011】S:0.0005〜0.02重量% 熱間加工時に割れを誘発させる成分であるため、上限を
0.02重量%に規制した。しかし、Mn,Ti等と硫
化物を形成し、炭化物系析出物の生成に影響を及ぼし、
ランクフォード値を向上させる作用をもつ。また、0.
0005重量%未満にS含有量を低減することは、製鋼
工程で脱硫精錬に多大な費用をを要することになる。こ
のようなことから、本発明では、S含有量の下限を0.
0005重量%に規制した。S: 0.0005 to 0.02% by weight Since the component induces cracking during hot working, the upper limit is restricted to 0.02% by weight. However, it forms sulfides with Mn, Ti, etc., affecting the formation of carbide-based precipitates,
Has the effect of improving the Rankford value. Also, 0.
Reducing the S content to less than 0005% by weight would require enormous costs for desulfurization refining in the steelmaking process. For this reason, in the present invention, the lower limit of the S content is set to 0.1.
0005% by weight.
【0012】Cu:0.5〜3.0重量% 鋼の強度を向上させる上で重要な合金成分であり、要求
強度に応じた必要量が添加される。Cuは、比較的低い
温度の熱処理によっても析出し、マトリックスを強化す
る作用を呈する。このような作用は、0.5重量%以上
のCu含有量で顕著になる。しかし、熱間加工時に熱間
脆性を誘発させる成分でもあることから、Cu含有量を
3.0重量%以下に規制する。3.0重量%を超える多
量のCuが含まれると、熱間脆性防止に有効なNiを添
加しても、Cuに起因する弊害が阻止できない。Cu: 0.5-3.0% by weight Cu is an important alloy component for improving the strength of steel, and a necessary amount corresponding to the required strength is added. Cu is precipitated even by heat treatment at a relatively low temperature, and has an effect of strengthening the matrix. Such an effect becomes remarkable at a Cu content of 0.5% by weight or more. However, since it is also a component that induces hot embrittlement during hot working, the Cu content is restricted to 3.0% by weight or less. When a large amount of Cu exceeding 3.0% by weight is contained, even if Ni effective for preventing hot brittleness is added, the adverse effects caused by Cu cannot be prevented.
【0013】Al:0.005〜0.10重量% 脱酸剤として添加されると共に、Nを固定する作用を呈
する。このような作用は、0.005重量%以上のAl
含有量で顕著になる。しかし、0.10重量%を超える
多量のAlが含まれると、酸化物系介在物が増加し、加
工性や表面性状が劣化する。 N:0.007重量%以下 不可避的に含まれる成分であり、Ti等で固定される。
しかし、0.007重量%を超える多量のNが含まれる
と、Nの固定に必要なTi,Nb等の増量が要求され、
析出物の増加に起因して加工性が劣化する。Al: 0.005 to 0.10 wt% Al is added as a deoxidizing agent and has an effect of fixing N. Such an effect is obtained when the Al content is 0.005% by weight or more.
It becomes remarkable in the content. However, when a large amount of Al exceeding 0.10% by weight is contained, oxide inclusions increase and workability and surface properties deteriorate. N: 0.007% by weight or less N is an unavoidable component and is fixed with Ti or the like.
However, when a large amount of N exceeding 0.007% by weight is contained, an increase in the amount of Ti, Nb, etc. necessary for fixing N is required,
Workability is degraded due to the increase in precipitates.
【0014】Ti:0.01〜0.1重量% 鋼中に侵入型として固溶するC及びNを炭窒化物として
固定すると共に、Sと結合して硫化物を形成する成分で
ある。硫化物を形成し、固溶C及び固溶Nを十分に減少
させることにより加工性の向上を図るためには、0.0
1重量%以上のTi含有量が必要とされる。しかし、
0.1重量%を超える多量のTiを含ませても、Ti添
加による性質改善効果は飽和し、却って製造コストの上
昇を招く。Nb:0.01〜0.1重量% Tiと同様の炭窒化物形成元素であり、鋼中のC及びN
を固定して加工性を向上させる作用を呈する。また、T
iと複合添加するとき、複合析出物を形成し、比較的大
きな析出物とすることにより加工性が改善される。この
ような効果は、0.01重量%以上のNb含有量で顕著
になり、0.1重量%で飽和する。Ti: 0.01 to 0.1% by weight C and N, which form a solid solution in steel as an interstitial type, are fixed as carbonitrides and are combined with S to form sulfides. In order to improve the workability by forming sulfides and sufficiently reducing solid solution C and solid solution N, 0.03
A Ti content of 1% by weight or more is required. But,
Even if a large amount of Ti exceeding 0.1% by weight is contained, the effect of improving properties by adding Ti is saturated, and the production cost is rather increased. Nb: 0.01 to 0.1% by weight Carbonitride forming element similar to Ti, and C and N in steel
And has the effect of improving workability. Also, T
When added in combination with i, a composite precipitate is formed, and a relatively large precipitate is formed, thereby improving workability. Such effects become remarkable when the Nb content is 0.01% by weight or more, and is saturated at 0.1% by weight.
【0015】Ni:0.2〜2.0重量% 必要に応じて添加される合金成分であり、Cuに起因し
た熱間脆性を防止する作用を呈し、Cuを添加した系に
おいては特に有効である。このような効果を得るために
は、Cu含有量の少なくとも1/3程度以上のNi含有
量が必要であり、0.2重量%以上でNi添加の効果が
顕著になる。しかし、2.0重量%を超える多量のNi
を添加すると、再結晶焼鈍された鋼帯が硬質のミクロ組
織を呈するようになり、加工性が劣化する。Ni: 0.2 to 2.0% by weight An alloy component added as necessary, exhibits an action of preventing hot brittleness caused by Cu, and is particularly effective in a system to which Cu is added. is there. In order to obtain such an effect, the Ni content is required to be at least about 1/3 or more of the Cu content, and when the content is 0.2% by weight or more, the effect of Ni addition becomes remarkable. However, a large amount of Ni exceeding 2.0% by weight
When the steel is added, the recrystallization-annealed steel strip has a hard microstructure, and the workability deteriorates.
【0016】B:0.0002〜0.002重量% 必要に応じて添加される合金成分であり、優先的に結晶
粒界に偏析し、Pに起因した粒界脆化を抑制する作用を
呈する。また、プレス成形時における二次加工割れを防
止する作用もある。このような作用は、0.0002重
量%以上のB含有量で顕著になる。しかし、0.002
重量%を超える多量のB含有量は、結晶粒の成長を阻害
し、加工性の低下を招く。 Zr,V:0.01〜0.1重量% 必要に応じて添加される合金成分であり、炭窒化物を形
成してC及びNを固定する作用を呈する。また、Ti,
Nbと複合添加するとき、加工性を更に向上させる作用
も呈する。これらの作用は、0.01重量%以上のZr
及び/又はV含有量で顕著になるが、0.1重量%で飽
和する。B: 0.0002 to 0.002% by weight An alloy component added as necessary, which segregates preferentially at crystal grain boundaries and exhibits an effect of suppressing grain boundary embrittlement caused by P. . It also has the effect of preventing secondary processing cracks during press forming. Such an effect becomes remarkable at a B content of 0.0002% by weight or more. However, 0.002
A large B content exceeding% by weight impairs the growth of crystal grains and causes a reduction in workability. Zr, V: 0.01 to 0.1% by weight An alloy component added as necessary, and has an effect of forming carbonitride and fixing C and N. Also, Ti,
When combined with Nb, it also has the effect of further improving workability. These effects can be obtained by using 0.01% by weight or more of Zr.
And / or V content, but saturates at 0.1% by weight.
【0017】熱延条件:仕上げ圧延温度Ar3変態点以
上,巻取り温度650〜800℃ 本発明では、連鋳スラブ及び分塊スラブの何れをも使用
できる。また、連鋳後又は分塊後の熱間スラブを直接熱
延工程に搬送し、或いは熱延工程前に再加熱を施しても
よい。再加熱温度は鋼成分や要求特性等に応じて設定さ
れるべきものであり、本発明では特に規定するものでは
ないが、伸びやランクフォード値を向上させる上では1
100℃近傍の低温加熱が好ましい。熱間圧延は、仕上
げ圧延温度Ar3変態点以上で行われる。仕上げ圧延温度
がAr3変態点より低くなると、ランクフォード値にとっ
て不利となる熱延集合組織が形成されるばかりでなく、
本発明で規定している温度範囲で巻き取ることが困難に
なる。熱延された鋼帯は、比較的高い650〜800℃
の温度範囲で巻き取られる。巻取り温度を650℃以上
と高く設定することにより、Ti系炭化物等の析出物の
粗大化等の作用によって伸びやランクフォード値が向上
する。また、冷間圧延と組み合わせた機械的デスケール
を行う場合、巻取り後の酸化の進行によってスケール厚
がある一定の範囲で増加し、デスケール性が向上する。
しかし、800℃を超える高温巻取りでは、スケール厚
が大きくなりすぎ、後続工程における酸洗前の一次冷延
を施してもデスケール性が著しく劣化する。Hot rolling condition: finishing rolling temperature A r3 transformation point or higher, winding temperature 650 to 800 ° C. In the present invention, both continuous casting slabs and bulk slabs can be used. Further, the hot slab after the continuous casting or the ingot may be directly conveyed to the hot rolling step, or may be reheated before the hot rolling step. The reheating temperature is to be set according to the steel composition, required characteristics, and the like, and is not particularly specified in the present invention.
Low temperature heating around 100 ° C. is preferred. Hot rolling is performed at a finish rolling temperature of Ar3 transformation point or higher. When the finish rolling temperature is lower than the Ar 3 transformation point, not only a hot-rolled texture disadvantageous to the Rankford value is formed, but also
It becomes difficult to wind up in the temperature range specified in the present invention. Hot rolled steel strip is relatively high 650-800 ° C
It is wound up in the temperature range. By setting the winding temperature as high as 650 ° C. or higher, elongation and Rankford value are improved by actions such as coarsening of precipitates such as Ti-based carbides. Further, when performing mechanical descale in combination with cold rolling, the scale thickness increases within a certain range due to the progress of oxidation after winding, and the descalability is improved.
However, in high-temperature winding exceeding 800 ° C., the scale thickness becomes too large, and even if primary cold rolling is performed before pickling in a subsequent process, the descaleability is significantly deteriorated.
【0018】一次冷間圧延:冷延率10〜60% 650〜800℃の温度で巻き取られた熱延コイルは、
巻取り後に酸化が進行するため、通常の酸洗のみ、或い
はテンションレベラー等を組み合わせた酸洗ではデスケ
ールが困難になる。そのため、酸洗後に残存するスケー
ルによって製品鋼板の表面品質が大きく劣化し、或いは
十分なデスケールを得るために酸洗時の通板速度を著し
く下げる必要が生じ、生産性が低下する。本発明では、
生産性の低下を招くことなく良好な表面品質をもつ製品
を得るために、酸洗前に冷間圧延を施し、スケールを機
械的に粉砕しながら層間剥離させておく。その結果、通
常の酸洗条件で十分デスケールされる。酸洗によるデス
ケール性を向上させるためには、10%以上の冷延率で
熱延鋼帯を一次冷間圧延することが必要である。10%
以上の冷延率は、製品の伸びやランクフォード値を向上
させる上でも有効である。しかし、冷延率が60%を超
える一次冷間圧延では、伸びやランクフォード値の向上
が期待されるものの、冷延率の上昇に見合ったデスケー
ル性の改善がみられない。しかも、冷間圧延機にかかる
負荷が大きくなるため、製造コストを上昇させる原因と
もなる。Primary cold rolling: Cold rolling rate 10 to 60% A hot rolled coil wound at a temperature of 650 to 800 ° C.
Oxidation proceeds after winding, so that descaling becomes difficult only by ordinary pickling or pickling combined with a tension leveler or the like. For this reason, the surface quality of the product steel sheet is greatly deteriorated by scale remaining after the pickling, or it is necessary to remarkably reduce the sheet passing speed at the time of pickling in order to obtain a sufficient descale, thereby lowering productivity. In the present invention,
In order to obtain a product having good surface quality without lowering the productivity, cold rolling is performed before pickling, and the scale is delaminated while mechanically pulverizing. As a result, descaling is sufficiently performed under ordinary pickling conditions. In order to improve the descalability by pickling, it is necessary to perform primary cold rolling of a hot-rolled steel strip at a cold rolling rate of 10% or more. 10%
The above cold rolling reduction is also effective in improving the product growth and Rankford value. However, in the primary cold rolling in which the cold rolling reduction exceeds 60%, although the elongation and the Rankford value are expected to be improved, the improvement of the descale property corresponding to the increase in the cold rolling reduction is not observed. In addition, the load on the cold rolling mill increases, which causes an increase in manufacturing cost.
【0019】酸洗 一次冷延により、鋼帯表面からスケールが部分的に除去
される。特に大きな冷延率で冷間圧延したものでは、ス
ケールの除去率が高くなる。しかし、一次冷延のみでは
デスケールが完全でなく、鋼帯表面にスケールが残存す
る。このままでは製品の表面品質が低下するため、一次
冷延したコイルを酸洗槽に通板し、酸洗によってスケー
ルを十分に除去する。Pickling By primary cold rolling, scale is partially removed from the surface of the steel strip. Particularly, in the case of cold rolling at a large cold rolling reduction, the scale removal rate is high. However, descale is not complete only by primary cold rolling, and scale remains on the steel strip surface. Since the surface quality of the product is deteriorated as it is, the primary cold-rolled coil is passed through a pickling tank, and the scale is sufficiently removed by pickling.
【0020】酸洗後の二次冷間圧延:冷延率20%以上 一次冷間圧延と合計した全冷延率60〜95% 酸洗後のコイル表面は、デスケールされているが、通常
の冷延鋼帯とは異なる酸洗肌を呈している。内質の面で
も、このまま仕上げ焼鈍を施しても、通常の冷延鋼帯製
品として要求される特性を満足しない。そのため、酸洗
後、更に二次冷間圧延を施すことが必要になる。通常の
冷延鋼帯製品と同等の品質をもつ表面肌を得るために
は、二次冷間圧延の冷延率を20%以上にすることが必
要である。また、製品としての加工性,深絞り性等に要
求される機械的性質に関しては、一次及び二次冷間圧延
を合わせた全冷延率が影響する。全冷延率が60%未満
では、低い冷延率のため、650〜800℃の巻取り温
度と組み合わせても良好な特性が得られない。しかし、
95%を超える全冷延率では、冷間圧延による加工性向
上効果が飽和し、或いは却って低下する傾向を示す。ま
た、過度に高い冷延率は、冷間圧延に過大な負荷がかか
り、製造コストを上昇させる原因になる。なお、本発明
における全冷延率は、熱延鋼帯の板厚から一次及び二次
冷間圧延を経た最終製品の板厚を差し引き、熱延鋼帯の
板厚で除した値で算出する。Secondary cold rolling after pickling: Cold rolling reduction of 20% or more Total cold rolling reduction of 60 to 95% combined with primary cold rolling The coil surface after pickling is descaled, but is usually used. It has pickling skin different from that of cold-rolled steel strip. Even in the aspect of the internal quality, even if the finish annealing is performed as it is, the properties required as ordinary cold rolled steel strip products are not satisfied. Therefore, after pickling, it is necessary to further perform secondary cold rolling. In order to obtain a surface skin having the same quality as that of a normal cold-rolled steel strip product, it is necessary to set the cold-rolling rate of the secondary cold rolling to 20% or more. Further, the mechanical properties required for workability, deep drawability, and the like as a product are affected by the total cold rolling ratio including the primary and secondary cold rolling. If the total cold rolling reduction is less than 60%, good characteristics cannot be obtained even when combined with a winding temperature of 650 to 800 ° C because of the low cold rolling reduction. But,
At a total cold rolling reduction of more than 95%, the effect of improving the workability by cold rolling tends to be saturated or rather reduced. On the other hand, an excessively high cold rolling rate causes an excessive load on the cold rolling, which causes an increase in manufacturing cost. Incidentally, the total cold rolling ratio in the present invention is calculated by subtracting the sheet thickness of the final product having undergone primary and secondary cold rolling from the sheet thickness of the hot-rolled steel strip, and dividing by the sheet thickness of the hot-rolled steel strip. .
【0021】二次冷間圧延後の焼鈍:再結晶温度以上で
900℃以下 冷間圧延された鋼帯は、加工硬化しており、加工性が著
しく低い状態にある。そこで、冷延鋼帯として要求され
る深絞り性を得るために再結晶温度以上で焼鈍が施され
る。焼鈍方式は、鋼成分や要求特性等に応じて設定され
るものであり、連続焼鈍,箱焼鈍の何れも採用できる。
しかし、何れの焼鈍方式においても、900℃を超える
焼鈍温度ではα→γ変態が生じて結晶方位がランダム化
するため、深絞り性が著しく劣化する。このようにして
製造された冷延鋼帯は、電気めっき,蒸着めっき等のめ
っき原板としても使用される。この場合にも、同様に加
工性に優れためっき鋼板が得られる。なお、本願明細書
では、この種のめっき原板としての用途を包含する意味
で「冷延鋼帯」を使用している。Annealing after secondary cold rolling: not less than the recrystallization temperature and not more than 900 ° C. The cold-rolled steel strip is work-hardened and has extremely low workability. Therefore, in order to obtain the deep drawability required for a cold-rolled steel strip, annealing is performed at a recrystallization temperature or higher. The annealing method is set according to the steel composition, required characteristics, and the like, and any of continuous annealing and box annealing can be employed.
However, in any of the annealing methods, at an annealing temperature exceeding 900 ° C., α → γ transformation occurs and the crystal orientation is randomized, so that the deep drawability is significantly deteriorated. The cold-rolled steel strip manufactured in this manner is also used as a base plate for plating such as electroplating and vapor deposition plating. Also in this case, a plated steel sheet having excellent workability can be obtained. In the specification of the present application, a “cold rolled steel strip” is used in a sense that it includes the use as a plating base sheet of this kind.
【0022】二次冷間圧延後の溶融めっき Zn,Al又はそれらの合金からなる溶融めっきを施す
ことにより、溶融めっき鋼帯が製造される。溶融めっき
設備においては、めっき浴に浸漬する前の鋼帯が再結晶
温度以上に加熱され、前述した冷延鋼帯の焼鈍と同様な
効果が得られる。しかし、何れの焼鈍方式においても、
900℃を超える焼鈍温度ではα→γ変態が生じて結晶
方位がランダム化するため、加工性が著しく劣化する。
この場合も、焼鈍条件やめっき条件等は特に規定される
ものではなく、工業的に通常採用されている条件が選定
される。Hot-dip coating after secondary cold rolling Hot-dip steel strip is manufactured by applying hot-dip plating made of Zn, Al or an alloy thereof. In the hot dip coating equipment, the steel strip before being immersed in the plating bath is heated to the recrystallization temperature or higher, and the same effect as the above-described annealing of the cold-rolled steel strip can be obtained. However, in any annealing method,
At an annealing temperature exceeding 900 ° C., α → γ transformation occurs and the crystal orientation is randomized, so that the workability is significantly deteriorated.
Also in this case, the annealing conditions, the plating conditions, and the like are not particularly limited, and conditions that are generally employed industrially are selected.
【0023】[0023]
【実施例】実施例1:表1で示した組成をもつ鋼を電気
炉で溶製し、50kgの鋼塊を得た。EXAMPLES Example 1 A steel having the composition shown in Table 1 was melted in an electric furnace to obtain a 50 kg steel ingot.
【0024】 [0024]
【0025】各鋼塊を厚さ35mmの鋼片に熱間鍛造
し、1130℃に加熱した後、熱間圧延した。熱間圧延
の仕上げ温度は、何れの鋼についてもAr3変態点以上と
なるように890〜950℃の範囲に設定した。仕上げ
板厚は、後続する冷間圧延工程での圧延率を勘案し、
2.2〜7.0mmの範囲に設定した。熱延仕上げ後、
495〜730℃に加熱したソルトバス炉中に装入し、
所定温度に2時間保持することにより、熱延鋼帯の巻取
りに相当する処理を施した。次いで、冷延率5〜45%
で一次冷間圧延し、酸洗によりデスケールした。更に、
冷延率40〜80%で二次冷間圧延し、板厚0.6〜
1.4mmの冷延鋼帯を製造した。この冷延鋼帯を再結
晶温度以上900℃以下の温度に加熱する焼鈍を施し
た。このときの製造条件を、鋼種ごとに表2に示す。Each ingot was hot forged into a 35 mm thick steel slab, heated to 1130 ° C., and then hot rolled. Finishing temperature of hot rolling was set in the range of as eight hundred ninety to nine hundred and fifty ° C. the A r3 transformation point or above for any of the steel. The finished sheet thickness takes into account the rolling rate in the subsequent cold rolling process,
It was set in the range of 2.2 to 7.0 mm. After hot rolling,
Into a salt bath furnace heated to 495-730 ° C,
By maintaining at a predetermined temperature for 2 hours, a treatment corresponding to the winding of the hot-rolled steel strip was performed. Next, the cold rolling rate is 5 to 45%.
For primary cold rolling and descaling by pickling. Furthermore,
Secondary cold rolling at a cold rolling reduction of 40 to 80%, and a sheet thickness of 0.6 to
A 1.4 mm cold rolled steel strip was manufactured. This cold-rolled steel strip was annealed to be heated to a temperature not lower than the recrystallization temperature and not higher than 900 ° C. The production conditions at this time are shown in Table 2 for each steel type.
【0026】 [0026]
【0027】焼鈍された冷延鋼帯の機械的性質及び表面
肌を表3に示す。機械的性質は、JIS 5号引張試験
片を使用して測定した。ランクフォード値は、15%引
張予歪みを与えた後、3点法で測定し、L方向(圧延方
向),T方向(圧延方向に45度傾斜する方向)及びD
方向(圧延方向に直交する方向)の平均値(rL +2r
T +rD )/4として求めた。表面肌は目視観察で判定
し、スケールが完全に除去された場合を良,スケール残
りが1か所以上認められた場合を不良と評価した。ま
た、二次加工割れ性を評価するための脆化温度として
は、次のように測定した温度を使用した。すなわち、直
径90mmに打ち抜いたブランクを絞り比2.7の三段
階の多段絞りで直径33mmの平底円筒カップに成形
し、液体窒素及び有機溶剤からなる各種温度の冷媒に浸
漬しながら、先端角60度のポンチを円筒上部から押し
込み、脆性割れが発生しない最低温度を測定した。Table 3 shows the mechanical properties and surface texture of the annealed cold-rolled steel strip. The mechanical properties were measured using JIS No. 5 tensile test pieces. The Rankford value was measured by a three-point method after 15% tensile prestrain was applied, and the L direction (rolling direction), the T direction (direction inclined 45 degrees to the rolling direction), and the D
Direction (direction perpendicular to the rolling direction) (r L + 2r)
It was determined as T + r D) / 4. The surface skin was judged by visual observation, and the case where the scale was completely removed was evaluated as good, and the case where one or more scale residues were recognized was evaluated as poor. In addition, as the embrittlement temperature for evaluating the secondary work cracking property, the temperature measured as follows was used. That is, a blank punched to a diameter of 90 mm is formed into a flat-bottomed cylindrical cup having a diameter of 33 mm by three-stage drawing with a drawing ratio of 2.7 at three stages, and immersed in refrigerants of various temperatures consisting of liquid nitrogen and an organic solvent, while having a tip angle of 60 mm. The punch was pushed in from the top of the cylinder, and the lowest temperature at which no brittle cracking occurred was measured.
【0028】 [0028]
【0029】表3の調査結果にみられるように、本発明
で規定した鋼組成及び製造条件を満足する冷延鋼帯で
は、何れも高い伸び及びランクフォード値を示してお
り、良好な深絞り性,加工性をもつ冷延鋼帯であること
が判る。これに対し、鋼組成が本発明で規定した範囲を
外れる鋼種番号Iを使用したものでは、低い伸び,ラン
クフォード値,高い二次加工割れ温度を示した。また、
組成的には本発明の条件を満足しても、製造条件が本発
明で規定した範囲を外れたものでは、伸び,ランクフォ
ード値,二次加工割れ温度の何れか一つ又は複数が悪い
値を示した。このことから、鋼組成及び製造条件を特定
した組合せにすることにより、加工性に優れた冷延鋼帯
が製造できることが確認された。As can be seen from the investigation results in Table 3, in the cold-rolled steel strip satisfying the steel composition and the production conditions specified in the present invention, all show high elongation and Rankford values, and show good deep drawing. It is clear that it is a cold-rolled steel strip with good workability and workability. On the other hand, those using steel type number I having a steel composition outside the range specified in the present invention exhibited low elongation, Rankford value, and high secondary working crack temperature. Also,
Even if the composition satisfies the conditions of the present invention, if the manufacturing conditions are out of the range specified in the present invention, one or more of elongation, Rankford value, and secondary cracking temperature are bad values. showed that. From this, it was confirmed that a cold-rolled steel strip excellent in workability can be manufactured by using a combination in which the steel composition and the manufacturing conditions are specified.
【0030】実施例2:表4に示した組成をもつ鋼を転
炉及び脱ガス炉で精錬し、連続鋳造により厚み250m
m,単位重量13トンのスラブを製造した。Example 2 Steel having the composition shown in Table 4 was refined in a converter and a degassing furnace, and was continuously cast to a thickness of 250 m.
m, a slab having a unit weight of 13 tons was produced.
【0031】 [0031]
【0032】各スラブを加熱炉で1130℃に再加熱し
た後、熱間圧延機で熱間圧延し、890〜945℃の範
囲の仕上げ温度で板厚1.2〜7.7mmに仕上げた。
次いで、450〜730℃の温度範囲で熱延鋼帯をコイ
ルに巻き取った。この熱延鋼帯に、冷延率5〜55%で
一次冷間圧延を施した後、塩酸系の酸洗液槽をもつ連続
酸洗ラインに通板してデスケールした。次いで、鋼帯を
再び冷間圧延機に通し、冷延率40〜85%の二次冷間
圧延を行い、板厚0.6〜1.4mmの冷延鋼帯を製造
した。この冷延鋼帯を、焼鈍ラインに通板し再結晶温度
以上に加熱する焼鈍を施し、製品としての冷延鋼帯を得
た。このときの製造条件を表5に、得られた冷延鋼帯の
特性を表6に示す。表6から明らかなように、同じ鋼材
から製造された冷延鋼帯であっても、本発明に規定した
製造条件が満足されない試験番号16,24では低い伸
び,ランクフォード値及び高い二次加工割れ温度を示し
た。また、表面肌が悪く、酸洗速度の低下に起因して生
産性が低下した。他方、本発明に従って製造された冷延
鋼帯では、何れも高い伸び及びランクフォード値を示し
ており、良好な深絞り性,加工性をもっていた。After each slab was reheated to 1130 ° C. in a heating furnace, it was hot-rolled in a hot rolling mill, and finished to a sheet thickness of 1.2 to 7.7 mm at a finishing temperature in the range of 890 to 945 ° C.
Next, the hot-rolled steel strip was wound around a coil in a temperature range of 450 to 730 ° C. This hot-rolled steel strip was subjected to primary cold rolling at a cold-rolling rate of 5 to 55%, and then passed through a continuous pickling line having a hydrochloric acid-based pickling solution tank to be descaled. Next, the steel strip was again passed through a cold rolling mill and subjected to secondary cold rolling at a cold rolling reduction of 40 to 85% to produce a cold rolled steel strip having a thickness of 0.6 to 1.4 mm. This cold-rolled steel strip was passed through an annealing line and subjected to annealing by heating to a temperature higher than the recrystallization temperature to obtain a cold-rolled steel strip as a product. Table 5 shows the production conditions at this time, and Table 6 shows the properties of the obtained cold-rolled steel strip. As is clear from Table 6, even in the case of the cold rolled steel strip manufactured from the same steel material, in Test Nos. 16 and 24 in which the manufacturing conditions specified in the present invention are not satisfied, low elongation, Rankford value and high secondary working were obtained. The crack temperature was indicated. In addition, the surface skin was poor, and the productivity decreased due to the decrease in the pickling rate. On the other hand, the cold-rolled steel strips produced according to the present invention all exhibited high elongation and Rankford values, and had good deep drawability and workability.
【0033】 [0033]
【0034】 [0034]
【0035】実施例3:表7に示す各種鋼材を実施例1
と同様に熱延,一次冷延,酸洗,二次冷延した。このと
きの製造条件を表8に示す。Example 3: Various steel materials shown in Table 7 were used in Example 1.
Hot rolling, primary cold rolling, pickling, and secondary cold rolling were performed in the same manner as in the above. Table 8 shows the manufacturing conditions at this time.
【0036】 [0036]
【0037】 [0037]
【0038】各冷延鋼帯に再結晶温度以上900℃以下
の焼鈍を施した後、溶融めっきした。得られた溶融めっ
き鋼帯の特性を表9に示す。Each of the cold-rolled steel strips was annealed at a temperature not lower than the recrystallization temperature and not higher than 900 ° C., followed by hot-dip plating. Table 9 shows the properties of the obtained hot-dip steel strip.
【0039】 [0039]
【0040】表3の調査結果にみられるように、本発明
で規定した鋼組成及び製造条件を満足する溶融めっき鋼
帯では、何れも高い伸び及びランクフォード値を示して
おり、良好な深絞り性,加工性をもつ溶融めっき鋼帯で
あることが判る。これに対し、鋼組成が本発明で規定し
た範囲を外れる鋼種番号Tを使用したものでは、低い伸
び,ランクフォード値,高い二次加工割れ温度を示し
た。また、組成的には本発明の条件を満足しても、製造
条件が本発明で規定した範囲を外れたものでは、伸び,
ランクフォード値,二次加工割れ温度の何れか一つ又は
複数が悪い値を示した。このことから、鋼組成及び製造
条件を特定した組合せにすることにより、加工性に優れ
た溶融めっき鋼帯が製造できることが確認された。As can be seen from the investigation results in Table 3, all the hot-dip galvanized steel strips satisfying the steel composition and the production conditions specified in the present invention show high elongation and Rankford values, and show good deep drawing. It can be seen that it is a hot-dip galvanized steel strip having good workability. On the other hand, those using steel type number T whose steel composition is out of the range specified in the present invention exhibited low elongation, Rankford value, and high secondary working crack temperature. Even if the composition satisfies the conditions of the present invention, if the manufacturing conditions are out of the range specified in the present invention, the elongation,
Either one or more of the Rankford value and the secondary cracking temperature showed a bad value. From this, it was confirmed that a hot-dip steel strip excellent in workability can be manufactured by using a combination in which the steel composition and the manufacturing conditions are specified.
【0041】実施例4:表10に示した組成をもつ鋼を
転炉及び脱ガス炉で精錬し、連続鋳造により厚み250
mm,単位重量13トンのスラブを製造した。Example 4 A steel having the composition shown in Table 10 was refined in a converter and a degassing furnace, and was continuously cast to a thickness of 250.
A slab with a unit weight of 13 tons was manufactured.
【0042】 [0042]
【0043】各スラブから、実施例3と同様に熱延,一
次冷延,酸洗,二次冷延の工程を経て板厚0.6〜1.
4mmの冷延鋼帯を製造した。この冷延鋼帯をめっき浴
温450℃の連続溶融めっきラインに通板し、再結晶温
度以上の加熱で焼鈍効果を与えた後、溶融めっきを施
し、製品としての溶融めっき鋼帯を製造した。このとき
の製造条件を表11に、得られた溶融めっき鋼帯の特性
を表12に示す。表12から明らかなように、同じ鋼材
から製造された溶融めっき鋼帯であっても、本発明に規
定した製造条件が満足されない試験番号40,48では
低い伸び,ランクフォード値及び高い二次加工割れ温度
を示した。また、表面肌が悪く、酸洗速度の低下に起因
して生産性が低下した。他方、本発明に従って製造され
た溶融めっき鋼帯では、何れも高い伸び及びランクフォ
ード値を示しており、良好な深絞り性,加工性をもって
いた。Each slab was subjected to hot rolling, primary cold rolling, pickling, and secondary cold rolling in the same manner as in Example 3 to obtain a sheet thickness of 0.6-1.
A 4 mm cold rolled steel strip was manufactured. This cold-rolled steel strip was passed through a continuous hot-dip galvanizing line at a plating bath temperature of 450 ° C., and after giving an annealing effect by heating at a recrystallization temperature or higher, hot-dip coating was performed to produce a hot-dip coated steel strip as a product. . The production conditions at this time are shown in Table 11, and the characteristics of the obtained hot-dip galvanized steel strip are shown in Table 12. As is clear from Table 12, even in the hot-dip-coated steel strip manufactured from the same steel material, in Test Nos. 40 and 48 in which the manufacturing conditions specified in the present invention are not satisfied, low elongation, Rankford value, and high secondary working were obtained. The crack temperature was indicated. In addition, the surface skin was poor, and the productivity decreased due to the decrease in the pickling rate. On the other hand, the hot-dip galvanized steel strips produced according to the present invention all exhibited high elongation and Rankford values, and had good deep drawability and workability.
【0044】 [0044]
【0045】 [0045]
【0046】[0046]
【発明の効果】以上に説明したように、本発明において
は、鋼組成及び製造条件を特定された条件下で組み合
せ、深絞り性,加工性を改善するため熱延後の巻取り温
度を比較的高温に設定し、冷延率が特定された一次冷間
圧延を酸洗前に施している。酸洗前の一次冷間圧延によ
りスケールの剥離性が向上し、巻取り温度を比較的高温
に設定した熱延であっても、酸洗によるデスケール工程
での生産性の劣化を招くことなく、Cuの析出強化作用
を有効に活用し優れた加工性をもつ高強度冷延鋼板及び
高強度溶融めっき鋼板が製造される。As described above, in the present invention, the steel composition and the manufacturing conditions are combined under specified conditions, and the winding temperature after hot rolling is compared to improve the deep drawability and workability. The primary cold rolling is performed before pickling, with the temperature set to a relatively high temperature and the cold rolling reduction specified. Primary cold rolling before pickling improves scale releasability, even in hot rolling with a relatively high winding temperature, without causing deterioration in productivity in the descaling process due to pickling. A high-strength cold-rolled steel sheet and a high-strength hot-dip steel sheet having excellent workability by effectively utilizing the precipitation strengthening effect of Cu are manufactured.
フロントページの続き (51)Int.Cl.6 識別記号 FI C22C 38/16 C22C 38/16 Continued on the front page (51) Int.Cl. 6 Identification code FI C22C 38/16 C22C 38/16
Claims (3)
i:2.0重量%以下,Mn:0.05〜3.0重量
%,P:0.2重量%以下,S:0.0005〜0.0
2重量%,Cu:0.5〜3.0重量%,酸可溶Al:
0.005〜0.1重量%,N:0.007重量%以
下,Ti:0.01〜0.1重量%及び/又はNb:
0.01〜0.1重量%を含む組成をもつ鋼スラブを再
加熱又は直送し、仕上げ圧延温度Ar3変態点以上,巻取
り温度650〜800℃の熱間圧延を施し、得られた熱
延鋼帯に冷延率10〜60%の一次冷間圧延を施し、酸
洗後、更に冷延率20%以上で且つ一次冷間圧延と合計
した全冷延率が60〜95%となるように二次冷間圧延
を施し、得られた冷延鋼帯を再結晶温度以上900℃以
下で焼鈍又は焼鈍後に溶融めっきする加工性に優れた冷
延鋼帯又は溶融めっき鋼帯の製造方法。1. C: 0.0005 to 0.01% by weight, S
i: 2.0% by weight or less, Mn: 0.05 to 3.0% by weight, P: 0.2% by weight or less, S: 0.0005 to 0.0
2% by weight, Cu: 0.5 to 3.0% by weight, acid-soluble Al:
0.005 to 0.1% by weight, N: 0.007% by weight or less, Ti: 0.01 to 0.1% by weight and / or Nb:
0.01 reheated or direct a steel slab having a composition comprising by weight%, the finish rolling temperature A r3 transformation point or higher, subjected to a hot rolling coiling temperature 650 to 800 ° C., the resulting heat Primary cold rolling is performed on the rolled steel strip at a cold rolling rate of 10 to 60%, and after pickling, the cold rolling rate is 20% or more, and the total cold rolling rate combined with the primary cold rolling is 60 to 95%. Cold rolled steel strip or hot-dip galvanized steel strip with excellent workability to be subjected to secondary cold rolling in such a manner that the resulting cold-rolled steel strip is annealed at a recrystallization temperature of 900 ° C. or less and hot-dip after annealing. .
i:0.2〜2.0重量%を含む組成をもつ鋼スラブを
使用する加工性に優れた冷延鋼帯又は溶融めっき鋼帯の
製造方法。2. The steel slab according to claim 1, further comprising N
i: A method for producing a cold-rolled steel strip or hot-dip steel strip having excellent workability using a steel slab having a composition containing 0.2 to 2.0% by weight.
更にB:0.0002〜0.002重量%,Zr:0.
01〜0.1重量%,V:0.01〜0.1重量%の1
種又は2種以上を含む組成をもつ鋼スラブを使用する加
工性に優れた冷延鋼帯又は溶融めっき鋼帯の製造方法。3. The steel slab according to claim 1 or 2,
Further, B: 0.0002 to 0.002% by weight, Zr: 0.
01 to 0.1% by weight, V: 0.01 to 0.1% by weight
A method for producing a cold-rolled steel strip or a hot-dip steel strip having excellent workability using a steel slab having a composition containing one or more kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5690498A JPH11256237A (en) | 1998-03-09 | 1998-03-09 | Production of cold rolled steel strip or hot dip plated steel strip excellent in workability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5690498A JPH11256237A (en) | 1998-03-09 | 1998-03-09 | Production of cold rolled steel strip or hot dip plated steel strip excellent in workability |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11256237A true JPH11256237A (en) | 1999-09-21 |
Family
ID=13040447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5690498A Pending JPH11256237A (en) | 1998-03-09 | 1998-03-09 | Production of cold rolled steel strip or hot dip plated steel strip excellent in workability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11256237A (en) |
-
1998
- 1998-03-09 JP JP5690498A patent/JPH11256237A/en active Pending
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