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JPH11199973A - Composite structure high-strength cold-rolled steel sheet excellent in fatigue properties and method for producing the same - Google Patents

Composite structure high-strength cold-rolled steel sheet excellent in fatigue properties and method for producing the same

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Publication number
JPH11199973A
JPH11199973A JP760998A JP760998A JPH11199973A JP H11199973 A JPH11199973 A JP H11199973A JP 760998 A JP760998 A JP 760998A JP 760998 A JP760998 A JP 760998A JP H11199973 A JPH11199973 A JP H11199973A
Authority
JP
Japan
Prior art keywords
steel sheet
composite structure
less
phase
rolled steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP760998A
Other languages
Japanese (ja)
Other versions
JP3619359B2 (en
Inventor
Tatsuo Yokoi
龍雄 横井
Hiroyuki Tanahashi
浩之 棚橋
Koji Kishida
宏司 岸田
Toshiyasu Ukiana
俊康 浮穴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
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Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP00760998A priority Critical patent/JP3619359B2/en
Publication of JPH11199973A publication Critical patent/JPH11199973A/en
Application granted granted Critical
Publication of JP3619359B2 publication Critical patent/JP3619359B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

(57)【要約】 【課題】 疲労特性に優れた複合組織高強度冷延鋼板と
その製造方法を提供する。 【解決手段】 C:0.03〜0.20%、Cu:0.
2〜2.0%、B:2〜20ppmを含むフェライト−
マルテンサイト複合組織鋼板であり、フェライト相での
Cuの存在状態は、Cu単独で構成される粒子の大きさ
が2nm以下の固溶状態および/または析出状態である
ことを特徴とする疲労特性に優れた複合組織高強度冷延
鋼板、および上記成分の鋼の熱間圧延を、Ar3 変態点
以上で仕上圧延を行う以外は常法に従って行い、引き続
き常法に従って、酸洗、冷間圧延を行った後、連続焼鈍
するに際し、Ac1 変態点以上、Ac3 変態点以下の二
相域で30〜150秒間保持した後、20℃/s以上の
冷却速度で400℃以下の温度域まで冷却することを特
徴とする上記鋼板の製造方法。
(57) [Summary] [PROBLEMS] To provide a composite structure high-strength cold-rolled steel sheet excellent in fatigue characteristics and a method for producing the same. SOLUTION: C: 0.03 to 0.20%, Cu: 0.
Ferrite containing 2 to 2.0%, B: 2 to 20 ppm
A martensitic composite structure steel sheet, in which the presence state of Cu in the ferrite phase is characterized by the fact that the size of particles composed solely of Cu is 2 nm or less in a solid solution state and / or a precipitation state. An excellent composite structure high-strength cold-rolled steel sheet, and hot rolling of the steel of the above-described components, are performed according to a conventional method except that finish rolling is performed at an Ar 3 transformation point or higher, and subsequently according to a conventional method, pickling and cold rolling. After the annealing, when performing continuous annealing, after holding for 30 to 150 seconds in a two-phase region of not less than Ac 1 transformation point and not more than Ac 3 transformation point, it is cooled to a temperature region of 400 ° C. or less at a cooling rate of 20 ° C./s or more. A method for producing the above steel sheet.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、疲労特性に優れた
複合組織高強度冷延鋼板およびその製造方法に関するも
のであり、特に、自動車の構造部材等の耐久性と加工性
の両立が求められる素材として好適な疲労特性に優れた
複合組織高強度冷延鋼板およびその製造方法に関するも
のである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-strength cold-rolled steel sheet having a composite structure excellent in fatigue properties and a method for producing the same. The present invention relates to a composite structure high-strength cold-rolled steel sheet excellent in fatigue characteristics suitable as a material and a method for producing the same.

【0002】[0002]

【従来の技術】近年、自動車の燃費向上などのために、
軽量化を目的として、Al合金等の軽金属や高強度鋼板
の自動車部材への適用が進められている。ただし、Al
合金等の軽金属は、比強度が高いという利点があるもの
の、鋼に比較して著しく高価であるため、その使用は特
殊な用途に限られてきた。より広い範囲で自動車の軽量
化を推進するためには、安価な高強度鋼板の適用が強く
求められている。
2. Description of the Related Art In recent years, in order to improve fuel efficiency of automobiles,
For the purpose of weight reduction, application of light metals such as Al alloys and high-strength steel sheets to automobile members has been promoted. Where Al
Light metals such as alloys have the advantage of high specific strength, but are significantly more expensive than steel, so their use has been limited to special applications. In order to reduce the weight of automobiles in a wider range, there is a strong demand for the use of inexpensive high-strength steel sheets.

【0003】一般に、材料は、高強度になるほど延性が
低下して加工性(成形性)が悪くなるばかりでなく、切
り欠き感受性も高くなる。そのため、走行中の振動等に
より疲労破壊が生じる危険性のある部品への高強度鋼板
の適用には、成形性の検討だけでなく、切り欠き、溶接
部等の応力集中部の応力集中係数を低減する配慮に加え
て、鋼板そのものの疲労耐久性も重要な検討課題とな
る。
In general, the higher the strength of a material, the lower the ductility and workability (formability) as well as the notch sensitivity. Therefore, when applying high-strength steel sheets to parts that may cause fatigue failure due to vibrations during running, not only study the formability but also the stress concentration coefficient of the stress concentration parts such as notches and welds. In addition to the reduction considerations, the fatigue durability of the steel sheet itself is also an important consideration.

【0004】加工性に優れた高強度冷延鋼板としては、
例えば低降伏比で延性の優れた変態組織強化型(複合組
織)高強度冷延鋼板の発明が、特開昭62−74024
号公報等に開示されている。さらに、この種のフェライ
ト、マルテンサイト、あるいは一部に残留オーステナイ
トを含む複合組織を有する高強度冷延鋼板について、冷
延、焼鈍をする前の熱延板でのミクロ組織を最適化する
ことにより疲労特性を向上させる発明が、特開昭63−
105930号公報や特開昭64−79322号公報で
開示されている。
[0004] As a high-strength cold-rolled steel sheet excellent in workability,
For example, the invention of a high-strength cold-rolled steel sheet having a transformed structure with a low yield ratio and excellent ductility (composite structure) has been disclosed in JP-A-62-74024.
No. 6,009,036. Furthermore, for high-strength cold-rolled steel sheets having this type of ferrite, martensite, or a composite structure containing partially retained austenite, by optimizing the microstructure of the hot-rolled sheet before cold rolling and annealing. The invention to improve the fatigue characteristics is disclosed in
No. 105930 and JP-A-64-79322.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、走行中
の振動等により疲労破壊が生じる危険性のある自動車部
品の一部の部品においては、伸び、低降伏比等の加工性
と疲労耐久性の両立が大変重要であり、上記従来技術に
おいても、なおその両立が十分ではなく、さらなる特性
改善の要求が高まっている。
However, in some parts of automobile parts that may cause fatigue failure due to vibrations during running, etc., it is necessary to achieve both workability such as elongation, low yield ratio, and fatigue durability. Is very important, and even in the above-mentioned prior art, the compatibility is still insufficient, and a demand for further improvement in characteristics is increasing.

【0006】本発明は、疲労特性と加工性を両立させる
ための鋼板特性とその製造方法を明らかにして、疲労特
性に優れた複合組織高強度冷延鋼板およびその製造方法
を提供することを目的とするものである。
An object of the present invention is to clarify the properties of a steel sheet for achieving both fatigue properties and workability and a method for producing the same, and to provide a composite structure high-strength cold-rolled steel sheet having excellent fatigue properties and a method for producing the same. It is assumed that.

【0007】[0007]

【課題を解決するための手段】本発明者らは、現在通常
に採用されている連続熱間圧延、それに続く酸洗、冷間
圧延、連続焼鈍設備により工業的規模で生産されている
高強度冷延鋼板の製造プロセスを念頭において、高強度
冷延鋼板の疲労特性と加工性の両立を達成すべく、鋭意
研究を重ねた。その結果、固溶しているCuもしくはC
u単独で構成される粒子サイズが2nm以下のCu析出
物が疲労特性向上に非常に有効であり、かつ加工性も損
なわないことを見出し、本発明をなしたものである。
SUMMARY OF THE INVENTION The present inventors have developed high-strength steels produced on an industrial scale by continuous hot rolling, followed by pickling, cold rolling, and continuous annealing equipment which are now commonly employed. With the manufacturing process of cold-rolled steel sheets in mind, we conducted intensive research to achieve both fatigue properties and workability of high-strength cold-rolled steel sheets. As a result, Cu or C
The present invention has been found that a Cu precipitate composed of u alone and having a particle size of 2 nm or less is very effective in improving fatigue characteristics and does not impair workability.

【0008】以下、本発明に至った基礎研究結果につい
て説明する。まず、フェライト相におけるCu単独で構
成される粒子サイズの疲労特性に及ぼす効果についての
調査を行った。そのための供試材は、次のようにして準
備した。すなわち、0.05%C−1.0%Si−1.
4%Mn−1.0%Cu−0.5%Ni−0.0003
%Bに成分調整して溶製した鋳片を、熱間圧延して常温
で巻取り、さらに、酸洗後、3.0mmから1.2mm
まで60%の冷間圧延を行った冷延鋼板を、800℃で
60秒保持した後、水冷する焼鈍処理を施した供試材を
準備した。さらに、100〜600℃で1時間保持した
後、炉冷する熱処理を施すことで、ミクロ組織が、フェ
ライトを主相とし、マルテンサイトを第二相とする複合
組織を有し、フェライト相におけるCu単独で構成され
る粒子のサイズを変化させた鋼板を得た。なお、ここで
の第二相は、主としてマルテンサイトであるが、一部残
留オーステナイトを含むことも許容されるものである。
これらの鋼板について疲労試験を行った結果を図1に示
す。この結果より、フェライト相とマルテンサイト相お
よび一部残留オーステナイト相を含む複合組織からなる
鋼板において、そのフェライト相におけるCu単独で構
成される粒子の平均サイズと疲労限度比には強い相関が
あり、フェライト相におけるCu単独で構成される粒子
の平均サイズが2nm以下で疲労限度比が著しく向上す
ることを新たに見出した。また、熱間圧延条件、冷間圧
延率、焼鈍条件等を制限することによって、フェライト
相におけるCu単独で構成される粒子の平均サイズが2
nm以下という鋼板を製造できることも新たに見出し
た。
Hereinafter, the results of basic research that led to the present invention will be described. First, an investigation was made on the effect of the size of a particle composed of Cu alone in the ferrite phase on fatigue characteristics. The test material for that was prepared as follows. That is, 0.05% C-1.0% Si-1.
4% Mn-1.0% Cu-0.5% Ni-0.0003
% B, the slab was melted and hot-rolled, wound at room temperature, pickled, and then 3.0 to 1.2 mm.
After the cold-rolled steel sheet which had been cold-rolled by 60% to 800 ° C. was maintained at 800 ° C. for 60 seconds, a test material subjected to an annealing treatment of water cooling was prepared. Further, after holding at 100 to 600 ° C. for 1 hour, a heat treatment of furnace cooling is performed, whereby the microstructure has a composite structure including ferrite as a main phase and martensite as a second phase. A steel sheet was obtained in which the size of a single particle was varied. Note that the second phase here is mainly martensite, but may partially contain retained austenite.
FIG. 1 shows the results of a fatigue test performed on these steel sheets. From these results, in the steel sheet having a composite structure including a ferrite phase and a martensite phase and a partly retained austenite phase, there is a strong correlation between the average size of the particles composed solely of Cu in the ferrite phase and the fatigue limit ratio, It has been newly found that the fatigue limit ratio is remarkably improved when the average size of the particles composed of Cu alone in the ferrite phase is 2 nm or less. Further, by restricting the hot rolling conditions, the cold rolling reduction, the annealing conditions, and the like, the average size of the particles composed solely of Cu in the ferrite phase is 2%.
It was also newly found that a steel plate having a thickness of nm or less can be manufactured.

【0009】次に、B元素の疲労特性に及ぼす効果につ
いての調査を行った。そのための供試材は、次のように
して準備した。すなわち、0.05%C−1.0%Si
−1.4%Mn−0.5%Ni鋼をベースとして、1.
0%のCuを添加した鋼とCuを添加しない鋼に、さら
に、B含有濃度を変化させた鋼を成分調整して溶製した
鋳片を、熱間圧延して常温で巻取り、さらに、酸洗後、
3.0mmから1.2mmまで60%の冷間圧延を行っ
た冷延鋼板を、800℃で60秒保持した後、水冷する
焼鈍処理を施して、ミクロ組織が、フェライトを主相と
し、マルテンサイトを第二相とする複合組織を有する鋼
板を得た。これらの鋼板について疲労試験を行った結果
を図2に示す。この結果より、1.0%のCuを添加し
た鋼に限り、B含有濃度と疲労限度比に強い相関があ
り、さらに、Bの含有濃度が2ppm以上で疲労限度比
が著しく向上することを新たに見出した。
Next, the effect of element B on the fatigue characteristics was investigated. The test material for that was prepared as follows. That is, 0.05% C-1.0% Si
Based on -1.4% Mn-0.5% Ni steel.
To a steel to which 0% Cu has been added and a steel to which Cu has not been added, a slab obtained by adjusting the composition of a steel having a changed B content concentration is hot-rolled and wound at room temperature. After pickling,
A cold-rolled steel sheet that has been cold-rolled by 60% from 3.0 mm to 1.2 mm is kept at 800 ° C. for 60 seconds, and then subjected to an annealing treatment of water cooling, so that the microstructure has a ferrite main phase and a A steel sheet having a composite structure having the site as the second phase was obtained. FIG. 2 shows the results of a fatigue test performed on these steel sheets. The results show that there is a strong correlation between the B content concentration and the fatigue limit ratio only for steel to which 1.0% Cu is added, and that the fatigue limit ratio is significantly improved when the B content concentration is 2 ppm or more. Headlined.

【0010】なお、引張試験による機械的性質について
は、JIS Z 2201記載の5号試験片にて、JI
S Z 2241記載の試験方法で測定した。また、鋼
板の疲労特性は、図3に示すような板厚1.2mm、長
さ90mm、幅18mm、最小断面部の幅が10mm、
切り欠きの曲率半径が30mmである平面曲げ疲労試験
片を用い、完全両振りの平面曲げ疲労試験によって得ら
れた2×106 回での疲労強度σWを鋼板の引張り強さ
σBで除した値(疲労限度比σW/σB)で評価した。
[0010] Regarding the mechanical properties by the tensile test, the test piece No. 5 described in JIS Z 2201 was measured by JI
It was measured by the test method described in SZ2241. Further, the fatigue properties of the steel sheet are as shown in FIG. 3, the thickness is 1.2 mm, the length is 90 mm, the width is 18 mm, the width of the minimum cross section is 10 mm,
A value obtained by dividing the fatigue strength σW at 2 × 10 6 times obtained by the plane bending fatigue test in which the notch has a curvature radius of 30 mm using a plane bending fatigue test piece having a notch radius of curvature of 30 mm by the tensile strength σB of the steel sheet. (Fatigue limit ratio σW / σB).

【0011】また、フェライト相におけるCu単独で構
成される粒子は、供試鋼の1/4厚のところから透過型
電子顕微鏡サンプルを採取し、エネルギー分散型X線分
光(Energy Dispersive X−ray
Spectroscope:EDS)や電子エネルギ
ー損失分光(Electron Energy Los
s Spectroscope:EELS)の組成分析
機能を加えた、200kVの加速電圧の電界放射型電子
銃(Field Emission Gun:FEG)
を搭載した透過型電子顕微鏡によって観察した。観察さ
れる粒子の組成は、上記EDSおよびEELSによりC
u単独であることを確認した。また、本発明で規定する
フェライト相におけるCu単独で構成される粒子のサイ
ズは、観察される粒子のサイズをそれぞれ測定したもの
のその一視野での平均の値である。
[0011] For particles composed of Cu alone in the ferrite phase, a transmission electron microscope sample was taken from a quarter of the thickness of the test steel and subjected to energy dispersive X-ray spectroscopy (Energy Dispersive X-ray).
Spectroscope (EDS) or electron energy loss spectroscopy (Electron Energy Loss)
Field emission electron gun (Field Emission Gun: FEG) with an accelerating voltage of 200 kV, which has a composition analysis function of s Spectroscope (EELS).
Observed by a transmission electron microscope equipped with. The composition of the observed particles was determined by EDS and EELS.
u alone. Further, the size of the particles composed solely of Cu in the ferrite phase defined in the present invention is an average value in one field of view of each of the measured particle sizes.

【0012】本発明は、上記知見に基づいてなされたも
のであり、その要旨とするところは以下のとおりであ
る。 (1)質量%にて、C:0.03〜0.20%、Si:
0.1〜2.0%、Mn:0.5〜3.0%、P≦0.
02%、S≦0.01%、Al:0.005〜0.1
%、Cu:0.2〜2.0%、B:0.0002〜0.
0020%を含み、残部がFeおよび不可避的不純物か
らなる鋼であって、そのミクロ組織が、フェライトを主
相とし、マルテンサイトを第二相とする複合組織であ
り、フェライト相におけるCuの存在状態は、Cu単独
で構成される粒子の大きさが2nm以下の固溶状態およ
び/または析出状態であることを特徴とする疲労特性に
優れた複合組織高強度冷延鋼板。
The present invention has been made based on the above findings, and the gist thereof is as follows. (1) In mass%, C: 0.03 to 0.20%, Si:
0.1-2.0%, Mn: 0.5-3.0%, P ≦ 0.
02%, S ≦ 0.01%, Al: 0.005 to 0.1
%, Cu: 0.2-2.0%, B: 0.0002-0.
0020%, the balance being Fe and unavoidable impurities, the microstructure of which is a composite structure having ferrite as a main phase and martensite as a second phase, and the state of existence of Cu in the ferrite phase. Is a composite-structure high-strength cold-rolled steel sheet excellent in fatigue characteristics, characterized in that particles composed of Cu alone are in a solid solution state and / or a precipitation state of 2 nm or less.

【0013】(2)前記鋼が、さらに、質量%にて、N
i:0.1〜1.0%を含有することを特徴とする前記
(1)記載の疲労特性に優れた複合組織高強度冷延鋼
板。 (3)前記鋼が、さらに、質量%にて、Ca:0.00
5〜0.02%、REM:0.005〜0.2%の1種
または2種を含有することを特徴とする前記(1)また
は(2)記載の疲労特性に優れた複合組織高強度冷延鋼
板。
(2) The steel further comprises N
i: The composite structure high-strength cold-rolled steel sheet according to the above (1), which contains 0.1 to 1.0%. (3) The steel further contains, by mass%, Ca: 0.00
The composite structure having high fatigue strength according to the above (1) or (2), comprising one or two of 5 to 0.02% and REM: 0.005 to 0.2%. Cold rolled steel sheet.

【0014】(4)前記鋼が、さらに、質量%にて、M
o:0.05〜0.2%、V:0.02〜0.2%、T
i:0.01〜0.2%、Nb:0.01〜0.1%、
Cr:0.01〜0.3%、Zr:0.02〜0.2%
の1種または2種以上を含有することを特徴とする前記
(1)〜(3)のいずれかに記載の疲労特性に優れた複
合組織高強度冷延鋼板。
(4) The steel further comprises, by mass%, M
o: 0.05-0.2%, V: 0.02-0.2%, T
i: 0.01 to 0.2%, Nb: 0.01 to 0.1%,
Cr: 0.01-0.3%, Zr: 0.02-0.2%
The high-strength cold-rolled steel sheet with a composite structure excellent in fatigue properties according to any one of the above (1) to (3), comprising one or more of the following.

【0015】(5)前記(1)〜(4)のいずれかに記
載の成分を有する鋼片の熱間圧延を、Ar3 変態点以上
で仕上圧延を行う以外は常法に従って行い、引き続き常
法に従って、酸洗、冷間圧延を行った後、連続焼鈍する
に際し、Ac1 変態点以上、Ac3 変態点以下の二相域
で30〜150秒間保持した後、20℃/s以上の冷却
速度で400℃以下の温度域まで冷却することを特徴と
する、そのミクロ組織が、フェライトを主相とし、マル
テンサイトを第二相とする複合組織であり、フェライト
相におけるCu単独で構成される粒子の大きさが2nm
以下である疲労特性に優れた複合組織高強度冷延鋼板の
製造方法。
(5) The hot rolling of the slab having the components described in any of the above (1) to (4) is carried out according to a conventional method except that the finish rolling is carried out at the Ar 3 transformation point or higher. After performing pickling and cold rolling according to the method, when performing continuous annealing, after holding for 30 to 150 seconds in a two-phase region from the Ac 1 transformation point to the Ac 3 transformation point, cooling at 20 ° C./s or more The microstructure is characterized by cooling to a temperature range of 400 ° C. or less at a speed, and the microstructure is a composite structure having ferrite as a main phase and martensite as a second phase, and is composed of Cu alone in the ferrite phase. 2nm particle size
A method for producing a composite structure high-strength cold-rolled steel sheet having excellent fatigue characteristics as described below.

【0016】[0016]

【発明の実施の形態】以下、本発明を詳細に説明する。
まず、本発明の鋼板ミクロ組織およびCuの存在状態に
ついて説明する。鋼板のミクロ組織は、優れた加工性を
確保するために、フェライトを主相とし、マルテンサイ
トを第二相とする複合組織とする。ただし、第二相に
は、一部に残留オーステナイトを含むことを許容するも
のである。なお、良好な加工性を保証する良好な延性や
70%以下の低降伏比を確保するためには、フェライト
の体積分率が50%以上でかつ残留オーステナイトの体
積分率が5%未満が好ましい。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.
First, the microstructure of the steel sheet and the existing state of Cu according to the present invention will be described. The microstructure of the steel sheet is a composite structure having ferrite as a main phase and martensite as a second phase in order to ensure excellent workability. However, the second phase permits to partially contain retained austenite. In order to secure good ductility for guaranteeing good workability and a low yield ratio of 70% or less, the volume fraction of ferrite is preferably 50% or more and the volume fraction of retained austenite is preferably less than 5%. .

【0017】また、フェライト相におけるCuの存在状
態は、Cu単独で構成される粒子の大きさが2nm以下
の固溶状態および/または析出状態とする。これによ
り、加工性の劣化につながる静的強度の上昇を抑えつ
つ、すなわちフェライトとマルテンサイトの複合組織鋼
板の優れた加工性を損なうことなく、疲労特性を向上さ
せることができる。一方、フェライト相におけるCu単
独で構成される粒子の大きさが2nm超であると、Cu
の析出強化により鋼板の静的強度が著しく上昇するた
め、加工性が著しく劣化することになる。また、このよ
うなCuの析出強化では、疲労限は静的強度の上昇ほど
には上昇しないので疲労限度比が低下してしまう。その
ため、フェライト相におけるCu単独で構成される粒子
の大きさは、2nm以下とする必要がある。
The presence state of Cu in the ferrite phase is a solid solution state and / or a precipitation state in which the size of the particle composed of Cu alone is 2 nm or less. This makes it possible to improve the fatigue properties while suppressing an increase in static strength that leads to deterioration in workability, that is, without impairing the excellent workability of the composite structure steel sheet of ferrite and martensite. On the other hand, if the size of the particle composed of Cu alone in the ferrite phase is more than 2 nm, Cu
Since the precipitation strengthening of the steel significantly increases the static strength of the steel sheet, the workability is significantly deteriorated. In addition, in such precipitation strengthening of Cu, the fatigue limit does not increase as much as the static strength increases, so that the fatigue limit ratio decreases. Therefore, the size of the particle composed of Cu alone in the ferrite phase needs to be 2 nm or less.

【0018】次に、本発明の化学成分の限定理由につい
て説明する。Cは0.20%超含有していると加工性お
よび溶接性が劣化するので、0.20%以下とする。ま
た、0.03%未満であると組織中のマルテンサイトの
体積率が減少して強度が低下するので、0.03%以上
とする。Siはフェライト変態の促進と未変態オーステ
ナイト中のC濃度を上げて複合組織を生成するため、
0.1%以上の添加が必要である。一方、2.0%超添
加するとスケールオフ量が増加して歩留りの低下を招く
ため、上限は2.0%とする。
Next, the reasons for limiting the chemical components of the present invention will be described. If the content of C exceeds 0.20%, the workability and the weldability deteriorate, so the content is made 0.20% or less. Further, when the content is less than 0.03%, the volume ratio of martensite in the structure is reduced and the strength is reduced. Si promotes ferrite transformation and raises the C concentration in untransformed austenite to form a composite structure.
It is necessary to add 0.1% or more. On the other hand, if more than 2.0% is added, the scale-off amount increases and the yield decreases, so the upper limit is made 2.0%.

【0019】Mnは目的とする第二相であるマルテンサ
イトを得るために0.5%以上必要である。また、3.
0%超添加するとスラブ割れを生ずるため、3.0%以
下とする。Pは0.02%超添加すると加工性や溶接性
に悪影響を及ぼすだけでなく、粒界に偏析して粒界強度
を低下させ、粒界脆化を起こすので、0.02%以下と
する。
Mn is required to be 0.5% or more in order to obtain the desired second phase, martensite. Also, 3.
If more than 0% is added, slab cracks occur, so the content is made 3.0% or less. If P is added in excess of 0.02%, it not only adversely affects the workability and weldability, but also segregates at the grain boundaries, lowering the grain boundary strength and causing grain boundary embrittlement. .

【0020】Sは多すぎると熱間圧延時の割れを引き起
こすので極力低減させるべきであるが、0.01%以下
ならば許容できる範囲である。Alは溶鋼脱酸のために
0.005%以上添加する必要があるが、あまり多量に
添加すると、非金属介在物を増大させ、伸びを劣化させ
るだけでなく、コストの上昇を招くため、その上限を
0.1%とする。
If S is too large, it causes cracking during hot rolling, so it should be reduced as much as possible, but if it is 0.01% or less, it is in an acceptable range. Al must be added in an amount of 0.005% or more for the deoxidation of molten steel. However, if added in a large amount, not only increases nonmetallic inclusions and deteriorates elongation, but also causes an increase in cost. The upper limit is set to 0.1%.

【0021】Cuは本発明で最も重要な元素の一つであ
り、固溶もしくは2nm以下の粒子サイズに析出させる
ことにより疲労特性を改善する効果がある。ただし、
0.2%未満では、その効果は少なく、2.0%を超え
て添加しても効果が飽和するので、0.2〜2.0%と
添加範囲を限定する。Bは本発明で最も重要な元素の一
つであり、Cuと複合添加されることによって疲労限を
上昇させる効果がある。ただし、0.0002%未満で
はその効果を得るために不十分であり、0.0020%
超添加するとスラブ割れが起こる。よって、Bの添加は
0.0002%以上、0.0020%以下とする。
Cu is one of the most important elements in the present invention, and has the effect of improving the fatigue properties by forming a solid solution or a precipitate having a particle size of 2 nm or less. However,
If it is less than 0.2%, the effect is small, and even if it is added more than 2.0%, the effect is saturated. Therefore, the addition range is limited to 0.2 to 2.0%. B is one of the most important elements in the present invention, and has an effect of increasing the fatigue limit by being combined with Cu. However, if it is less than 0.0002%, it is insufficient to obtain the effect, and 0.0020%
If added excessively, slab cracking occurs. Therefore, the addition of B is set to 0.0002% or more and 0.0020% or less.

【0022】Niはフェライトの生成も促進する元素で
あると共に、Cu含有による熱間脆性防止のために添加
する。ただし、0.1%未満ではその効果が少なく、
1.0%を超えて添加してもその効果が飽和するので、
0.1〜1.0%とする。CaおよびREMは、破壊の
起点となったり、加工性を劣化させる非金属介在物の形
態を変化させて無害化する元素である。ただし、それぞ
れ0.005%未満添加してもその効果がなく、Caな
らば0.02%超、REMならば0.2%超添加しても
その効果が飽和するので、Ca:0.005〜0.02
%、REM:0.005〜0.2%とする。
Ni is an element that also promotes the formation of ferrite, and is added to prevent hot brittleness due to the inclusion of Cu. However, if it is less than 0.1%, the effect is small,
Even if added in excess of 1.0%, the effect is saturated,
0.1 to 1.0%. Ca and REM are elements that become the starting point of destruction or change the form of nonmetallic inclusions that degrade workability and render them harmless. However, even if each is added less than 0.005%, there is no effect. If Ca is added more than 0.02%, and if REM is added more than 0.2%, the effect is saturated. ~ 0.02
%, REM: 0.005 to 0.2%.

【0023】さらに、強度を付与するために、Mo、
V、Ti、Nb、Cr、Zrの析出強化もしくは固溶強
化元素の1種または2種以上を添加してもよい。ただ
し、Mo:0.05%未満、V:0.02%未満、T
i:0.01%未満、Nb:0.01%未満、Cr:
0.01%未満、Zr:0.02%未満ではその効果を
得ることができない。また、Mo:0.2%超、V:
0.2%超、Ti:0.2%超、Nb:0.1%超、C
r:0.3%超、Zr:0.2%超添加してもその効果
は飽和する。
Further, in order to impart strength, Mo,
One or two or more elements of precipitation strengthening or solid solution strengthening of V, Ti, Nb, Cr and Zr may be added. However, Mo: less than 0.05%, V: less than 0.02%, T
i: less than 0.01%, Nb: less than 0.01%, Cr:
If it is less than 0.01% and Zr: less than 0.02%, the effect cannot be obtained. Mo: more than 0.2%, V:
More than 0.2%, Ti: more than 0.2%, Nb: more than 0.1%, C
Even if r: more than 0.3% and Zr: more than 0.2%, the effect is saturated.

【0024】次に、本発明の製造方法の限定理由につい
て、以下に詳細に述べる本発明では、目的の成分含有量
になるように成分調整した溶鋼を鋳込むことによって得
たスラブを、高温鋳片のまま熱間圧延機に直送してもよ
いし、室温まで冷却後に加熱炉にて再加熱して熱間圧延
してもよい。再加熱温度については特に制限はないが、
1350℃以上であると、スケールオフ量が多量にな
り、歩留りが低下するので、再加熱温度は1350℃未
満が望ましい。
Next, the reason for limiting the production method of the present invention will be described in detail below. In the present invention, a slab obtained by casting molten steel whose components are adjusted to the target component content is subjected to high-temperature casting. The pieces may be directly sent to a hot rolling mill, or may be cooled to room temperature and then reheated in a heating furnace for hot rolling. There is no particular limitation on the reheating temperature,
If the temperature is 1350 ° C. or more, the scale-off amount becomes large and the yield decreases, so the reheating temperature is desirably less than 1350 ° C.

【0025】熱間圧延工程は、仕上圧延最終パス温度
(FT)がAr3 点以上の温度域で終了する必要があ
る。これは、熱間圧延中に圧延温度がAr3 点を切る
と、フェライト粒にひずみが残留して強度が上昇し、後
の冷間圧延で支障をきたすためである。仕上圧延後の冷
却と巻取温度(CT)については、組織制御、析出物制
御等を冷延後の焼鈍工程において行うため特に規定しな
い。なお、焼鈍後にフェライト−マルテンサイトの複合
ミクロ組織を得やすくするために熱延板段階においてそ
の組成配分が完了していることが望ましいので、仕上圧
延を終了した後の冷却は、Ar3 変態点からAr1 変態
点までの温度域で1〜10秒間空冷することが好まし
い。また、その後の冷却および巻取温度については、焼
鈍時に、Cuを固溶状態にするために、熱延板段階にお
いもCuを固溶状態にしておくことが望ましいので、巻
取温度は350℃以下で、その温度域までの冷却速度は
20℃/s以上が好ましい。
The hot rolling step needs to be completed in a temperature range where the final rolling final pass temperature (FT) is equal to or higher than the Ar 3 point. This is because, if the rolling temperature falls below the Ar 3 point during hot rolling, strain remains in the ferrite grains and the strength increases, which hinders subsequent cold rolling. Cooling after finish rolling and winding temperature (CT) are not particularly defined because structure control, precipitate control, and the like are performed in the annealing step after cold rolling. In order to make it easier to obtain a ferrite-martensite composite microstructure after annealing, it is desirable that the composition distribution be completed in the hot-rolled sheet stage. Therefore, cooling after finishing rolling is completed at the Ar 3 transformation point. It is preferable to air-cool for 1 to 10 seconds in the temperature range from to the Ar 1 transformation point. Regarding the subsequent cooling and winding temperatures, it is desirable to keep Cu in a solid solution state even in the hot-rolled sheet stage in order to bring Cu into a solid solution state during annealing. Below, the cooling rate to the temperature range is preferably 20 ° C./s or more.

【0026】巻取り後の酸洗、冷間圧延工程について
は、常法に従えばよく、本発明では特に規定しない。た
だし、冷間圧延の圧下率が30%未満であると、その後
の焼鈍工程において再結晶が完全に生じず、延性が劣化
しやすいため、また80%超の圧下率では冷間圧延機に
大きな負荷がかかるため、冷間圧延の圧下率は30%以
上、80%以下が好ましい。
The pickling and cold rolling steps after winding may be performed according to a conventional method, and are not particularly defined in the present invention. However, if the rolling reduction of the cold rolling is less than 30%, recrystallization does not completely occur in the subsequent annealing step, and the ductility is likely to be deteriorated. Since a load is applied, the rolling reduction of the cold rolling is preferably 30% or more and 80% or less.

【0027】焼鈍工程は、本発明では連続焼鈍を前提と
する。連続焼鈍における加熱温度は、Ac1 変態点以
上、Ac3 変態点以下の二相域で行う。なお、その温度
範囲内でも低温すぎると、熱延板段階でセメンタイトや
Cuが析出していた場合、セメンタイトやCuが再固溶
するのに時間がかかりすぎ、また逆に高温すぎるとオー
ステナイトの体積率が大きくなりすぎてオーステナイト
中のC濃度が低下し、その後の冷却の際にベイナイトも
しくはパーライト変態のノーズにかかりやすくなり、所
定のミクロ組織を得ることができなくなるため、780
℃以上、850℃以下で加熱するのが好ましい。
In the present invention, the annealing step is based on continuous annealing. The heating temperature in the continuous annealing is in a two-phase range from the Ac 1 transformation point to the Ac 3 transformation point. If the temperature is too low even within the temperature range, if cementite or Cu is precipitated in the hot-rolled sheet stage, it takes too much time for cementite or Cu to re-dissolve in solid solution. The C content in the austenite decreases due to the rate of being too large, and the nose of bainite or pearlite transformation is liable to occur in the subsequent cooling, so that a predetermined microstructure cannot be obtained.
The heating is preferably performed at a temperature of not less than 850 ° C and not less than 850 ° C.

【0028】また、加熱温度での保持時間は、30秒未
満では、熱延板段階でセメンタイトやCuが析出してい
た場合、セメンタイトやCuが完全に再固溶するのに不
十分であり、また逆に150秒超では、通板速度を低下
させなければならず操業上好ましくないので、保持時間
は30〜150秒間とする。加熱保持後の冷却速度は、
20℃/s未満では、ベイナイトもしくはパーライト変
態のノーズにかかるおそれがあり、所定のミクロ組織を
得られなくなるため、20℃/s以上の冷却速度とす
る。
On the other hand, if the holding time at the heating temperature is less than 30 seconds, if cementite or Cu is precipitated in the hot-rolled sheet stage, it is insufficient to completely re-dissolve cementite or Cu. On the other hand, if it exceeds 150 seconds, the sheet passing speed must be reduced, which is not preferable in terms of operation. Therefore, the holding time is set to 30 to 150 seconds. The cooling rate after heating and holding
If the temperature is less than 20 ° C./s, there is a possibility that the nose of bainite or pearlite transformation occurs, and a predetermined microstructure cannot be obtained.

【0029】冷却終了温度は、400℃超では、ベイナ
イトが生成して目的とするフェライト−マルテンサイト
の複合ミクロ組織が得られない。さらに、Cuの析出が
促進されて粗大なCuの析出が起こり、目的としている
疲労特性が得られないので、400℃以下の温度域まで
冷却する必要がある。
If the cooling end temperature is higher than 400 ° C., bainite is formed and the desired ferrite-martensite composite microstructure cannot be obtained. Further, since the precipitation of Cu is promoted to cause coarse precipitation of Cu and the intended fatigue characteristics cannot be obtained, it is necessary to cool to a temperature range of 400 ° C. or lower.

【0030】[0030]

【実施例】以下に、実施例により本発明をさらに説明す
る。表1、表2(表1のつづき)に示す化学成分を有す
るA〜Yの鋼は、転炉にて溶製して、連続鋳造後、加熱
温度1230℃で再加熱し、仕上温度790〜830℃
で熱間圧延を行い、室温〜450℃で巻取った後、酸洗
し、さらに、圧延率60〜80%で0.7〜1.6mm
の板厚に冷間圧延した後、表3、表5(表3のつづき−
2)に示す条件で焼鈍を行った。なお、表1、表2中の
化学組成についての表示は質量%である。
The present invention will be further described below with reference to examples. Steels A to Y having the chemical components shown in Tables 1 and 2 (continued from Table 1) were melted in a converter, continuously cast, reheated at a heating temperature of 1230 ° C., and finished at a temperature of 790 to 790 ° C. 830 ° C
After hot rolling at room temperature to 450 ° C., pickling, and further, at a rolling reduction of 60 to 80%, 0.7 to 1.6 mm
After cold rolling to a sheet thickness of Table 3, Table 3 and Table 5 (continuation of Table 3-
Annealing was performed under the conditions shown in 2). In addition, the indication of the chemical composition in Tables 1 and 2 is% by mass.

【0031】このようにして得られた焼鈍板の引張試験
は、供試材を、まずJIS Z 2201記載の5号試
験片に加工し、JIS Z 2241記載の試験方法に
従って行った。表3、表4(表3のつづき−1)、表5
(表3のつづき−2)、表6(表3のつづき−3)にそ
の試験結果を示す。また、さらに図3に示すような長さ
90mm、幅18mm、最小断面部の幅が10mm、切
り欠きの曲率半径が30mmである平面曲げ疲労試験片
にて、完全両振りの平面曲げ疲労試験を行った。鋼板の
疲労特性は、2×106 回での疲労強度σWを鋼板の引
張り強さσBで除した値(疲労限度比σW/σB)で評
価した。
The tensile test of the annealed plate thus obtained was performed by first processing the test material into a No. 5 test piece described in JIS Z 2201 and following the test method described in JIS Z 2241. Table 3, Table 4 (continuation of Table 3-1), Table 5
(Continued in Table 3-2) and Table 6 (Continued in Table 3-3) show the test results. Further, a plane bending fatigue test of complete swinging was performed on a plane bending fatigue test piece having a length of 90 mm, a width of 18 mm, a width of a minimum cross section of 10 mm, and a radius of curvature of a notch of 30 mm as shown in FIG. went. The fatigue properties of the steel sheet were evaluated by the value obtained by dividing the fatigue strength σW at 2 × 10 6 times by the tensile strength σB of the steel sheet (fatigue limit ratio σW / σB).

【0032】また、フェライト相におけるCu単独で構
成される粒子は、供試鋼の1/4厚のところから透過型
電子顕微鏡サンプルを採取し、エネルギー分散型X線分
光(EDS)や電子エネルギー損失分光(EELS)の
組成分析機能を加えた、200kVの加速電圧の電界放
射型電子銃(FEG)を搭載した透過型電子顕微鏡によ
って観察した。観察される粒子の組成は、上記EDSお
よびEELSによりCu単独であることを確認した。ま
た、本発明で規定するフェライト相におけるCu単独で
構成される粒子のサイズは、観察される粒子のサイズを
それぞれ測定したもののその一視野での平均の値であ
る。
As for the particles composed solely of Cu in the ferrite phase, a transmission electron microscope sample was taken from a quarter of the thickness of the test steel and subjected to energy dispersive X-ray spectroscopy (EDS) and electron energy loss. Observation was made with a transmission electron microscope equipped with a field emission electron gun (FEG) having an accelerating voltage of 200 kV and having a composition analysis function of spectroscopy (EELS). The observed composition of the particles was confirmed to be solely Cu by EDS and EELS. Further, the size of the particles composed solely of Cu in the ferrite phase defined in the present invention is an average value in one field of view of each of the measured particle sizes.

【0033】[0033]

【表1】 [Table 1]

【0034】[0034]

【表2】 [Table 2]

【0035】[0035]

【表3】 [Table 3]

【0036】[0036]

【表4】 [Table 4]

【0037】[0037]

【表5】 [Table 5]

【0038】[0038]

【表6】 [Table 6]

【0039】本発明に沿うものは、鋼A−1、B−1、
C−1、D−1、F−1、H−1、I−1、J−1、K
−1、L−1、N−1、O−1、P−1、Q−1、R−
1、U−1、V−1、X−1、Y−1の19鋼であり、
主相であるフェライトにおけるCu単独で構成される粒
子の大きさが2nm以下の疲労特性に優れた複合組織高
強度冷延鋼板が得られている。
According to the present invention, steels A-1, B-1,
C-1, D-1, F-1, H-1, I-1, J-1, K
-1, L-1, N-1, O-1, P-1, Q-1, R-
1, U-1, V-1, X-1, Y-1 19 steels,
A multi-structure high-strength cold-rolled steel sheet having excellent fatigue characteristics in which the size of particles composed solely of Cu in ferrite, which is the main phase, is 2 nm or less has been obtained.

【0040】上記以外の鋼は、以下の理由によって本発
明の範囲外である。すなわち、鋼A−2は、加熱温度
(ST)が本発明範囲より低いので、セメンタイトの再
固溶が不十分で、焼鈍後に目的とするフェライト−マル
テンサイトの複合ミクロ組織が得られず、加工性の指標
の一つである低降伏比(YR)および十分な疲労限度比
(σW/σB)が得られていない。
Other steels are outside the scope of the present invention for the following reasons. That is, since the heating temperature (ST) of the steel A-2 is lower than the range of the present invention, re-dissolution of cementite is insufficient, and a desired composite microstructure of ferrite-martensite cannot be obtained after annealing. A low yield ratio (YR) and a sufficient fatigue limit ratio (σW / σB), which are one of the indexes of the properties, are not obtained.

【0041】鋼A−3は、保持時間が本発明範囲より短
いので、セメンタイトやCuの再固溶が不十分となり、
十分な疲労限度比が得られていない。鋼E−1は、Pの
含有量が本発明範囲より多いので、Pが粒界に偏析して
粒界強度を低下させてしまい、十分な疲労限度比が得ら
れていない。鋼G−1は、Cuの含有量が本発明範囲よ
り少ないので、疲労特性を改善する効果が少なく、十分
な疲労限度比が得られていない。
Since the retention time of steel A-3 is shorter than the range of the present invention, re-dissolution of cementite and Cu becomes insufficient,
Sufficient fatigue limit ratio has not been obtained. In steel E-1, since the content of P is larger than the range of the present invention, P segregates at the grain boundary to lower the grain boundary strength, and a sufficient fatigue limit ratio is not obtained. Since steel G-1 has a Cu content lower than the range of the present invention, the effect of improving the fatigue properties is small, and a sufficient fatigue limit ratio has not been obtained.

【0042】鋼J−2は、加熱後の冷却速度が本発明範
囲より遅いので、パーライトとベイナイトが生成してし
まい、目的とするフェライト−マルテンサイトの複合ミ
クロ組織が得られず、低降伏比および十分な疲労限度比
が得られていない。鋼J−3は、冷却終了温度が本発明
範囲より高いので、ベイナイトが生成して目的とするフ
ェライト−マルテンサイトの複合ミクロ組織が得られな
い。さらにCuの析出が促進されて粗大なCuの析出が
起こるため、低降伏比および十分な疲労限度比が得られ
ていない。
In steel J-2, the cooling rate after heating is lower than the range of the present invention, so that pearlite and bainite are formed, the desired composite microstructure of ferrite-martensite cannot be obtained, and a low yield ratio is obtained. And a sufficient fatigue limit ratio has not been obtained. Since steel J-3 has a cooling end temperature higher than the range of the present invention, bainite is formed and a desired ferrite-martensite composite microstructure cannot be obtained. Further, since precipitation of Cu is promoted and coarse Cu is deposited, a low yield ratio and a sufficient fatigue limit ratio cannot be obtained.

【0043】鋼M−1は、Bの含有量が本発明範囲より
少ないので、Cuと複合添加されることによって疲労限
を上昇させる効果が不十分であるため、十分な疲労限度
比が得られていない。鋼S−1は、Siの含有量が本発
明範囲より少ないので、フェライト変態の促進と未変態
オーステナイト中のC濃度を上げて複合組織を生成する
効果が失われ、目的とするフェライト−マルテンサイト
の複合ミクロ組織が得られず、十分な疲労限度比が得ら
れていない。
Since the content of B in the steel M-1 is less than the range of the present invention, the effect of increasing the fatigue limit by the combined addition with Cu is insufficient, so that a sufficient fatigue limit ratio can be obtained. Not. Since the steel S-1 has a Si content lower than the range of the present invention, the effect of accelerating ferrite transformation and increasing the C concentration in untransformed austenite to form a composite structure is lost, and the desired ferrite-martensite is lost. Cannot be obtained, and a sufficient fatigue limit ratio has not been obtained.

【0044】鋼T−1は、Mnの含有量が本発明範囲よ
り少ないので、目的とする第二相であるマルテンサイト
を十分に得られず、低降伏比が得られていない。W−1
は、Cの含有量が本発明範囲より少ないので、組織中の
マルテンサイトの体積率が十分ではなく、低降伏比およ
び十分な疲労限度比が得られていない。
Since the content of Mn in the steel T-1 is less than the range of the present invention, the desired second phase, martensite, cannot be sufficiently obtained, and a low yield ratio has not been obtained. W-1
Since the content of C is smaller than the range of the present invention, the volume ratio of martensite in the structure is not sufficient, and a low yield ratio and a sufficient fatigue limit ratio are not obtained.

【0045】[0045]

【発明の効果】以上詳述したように、本発明は、疲労特
性に優れた複合組織高強度冷延鋼板およびその製造方法
を提供するものであり、これらの複合組織高強度冷延鋼
板を用いることにより、伸びを始めとする加工性を十分
に確保しつつ疲労特性の大幅な改善が期待できるため、
工業的価値が高い発明であると言える。
As described in detail above, the present invention provides a composite structure high-strength cold-rolled steel sheet having excellent fatigue properties and a method for producing the same. By doing so, a significant improvement in fatigue properties can be expected while ensuring sufficient workability including elongation.
It can be said that the invention has high industrial value.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に至る予備実験の結果を、Cu単独で構
成される粒子の大きさと疲労限度比の関係で示す図であ
る。
FIG. 1 is a diagram showing the results of preliminary experiments leading to the present invention in the relationship between the size of particles composed of Cu alone and the fatigue limit ratio.

【図2】本発明に至る予備実験の結果を、B元素の濃度
と疲労限度比の関係で示す図である。
FIG. 2 is a diagram showing the results of preliminary experiments leading to the present invention in the relationship between the concentration of B element and the fatigue limit ratio.

【図3】疲労試験片の形状を説明する図である。FIG. 3 is a diagram illustrating the shape of a fatigue test piece.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 浮穴 俊康 東京都千代田区大手町2−6−3 新日本 製鐵株式会社内 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Toshiyasu Ukibo 2-6-3 Otemachi, Chiyoda-ku, Tokyo Inside Nippon Steel Corporation

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 質量%にて、 C:0.03〜0.20%、 Si:0.1〜2.0%、 Mn:0.5〜3.0%、 P≦0.02%、 S≦0.01%、 Al:0.005〜0.1%、 Cu:0.2〜2.0%、 B:0.0002〜0.0020% を含み、残部がFeおよび不可避的不純物からなる鋼で
あって、そのミクロ組織が、フェライトを主相とし、マ
ルテンサイトを第二相とする複合組織であり、フェライ
ト相におけるCuの存在状態は、Cu単独で構成される
粒子の大きさが2nm以下の固溶状態および/または析
出状態であることを特徴とする疲労特性に優れた複合組
織高強度冷延鋼板。
1. mass%, C: 0.03 to 0.20%, Si: 0.1 to 2.0%, Mn: 0.5 to 3.0%, P ≦ 0.02%, S ≦ 0.01%, Al: 0.005 to 0.1%, Cu: 0.2 to 2.0%, B: 0.0002 to 0.0020%, with the balance being Fe and unavoidable impurities Steel, the microstructure of which is a composite structure having ferrite as a main phase and martensite as a second phase, and the presence state of Cu in the ferrite phase is such that the size of particles composed solely of Cu is A high-strength cold-rolled steel sheet with a composite structure excellent in fatigue characteristics, which is in a solid solution state and / or a precipitate state of 2 nm or less.
【請求項2】 前記鋼が、さらに、質量%にて、 Ni:0.1〜1.0% を含有することを特徴とする請求項1記載の疲労特性に
優れた複合組織高強度冷延鋼板。
2. The high-strength composite structure high-strength cold-rolled steel according to claim 1, wherein the steel further contains Ni: 0.1 to 1.0% by mass%. steel sheet.
【請求項3】 前記鋼が、さらに、質量%にて、 Ca:0.005〜0.02%、 REM:0.005〜0.2% の1種または2種を含有することを特徴とする請求項1
または2記載の疲労特性に優れた複合組織高強度冷延鋼
板。
3. The steel according to claim 1, further comprising one or two of Ca: 0.005 to 0.02% and REM: 0.005 to 0.2% by mass%. Claim 1
Or a composite structure high-strength cold-rolled steel sheet having excellent fatigue properties according to 2.
【請求項4】 前記鋼が、さらに、質量%にて、 Mo:0.05〜0.2%、 V:0.02〜0.2%、 Ti:0.01〜0.2%、 Nb:0.01〜0.1%、 Cr:0.01〜0.3%、 Zr:0.02〜0.2% の1種または2種以上を含有することを特徴とする請求
項1〜3のいずれか1項に記載の疲労特性に優れた複合
組織高強度冷延鋼板。
4. The steel further comprises, by mass%, Mo: 0.05 to 0.2%, V: 0.02 to 0.2%, Ti: 0.01 to 0.2%, Nb : 0.01 to 0.1%; Cr: 0.01 to 0.3%; Zr: 0.02 to 0.2%. 3. A high-strength composite structure high-strength cold-rolled steel sheet having excellent fatigue properties according to any one of 3.
【請求項5】 請求項1〜4のいずれか1項に記載の成
分を有する鋼片の熱間圧延を、Ar3 変態点以上で仕上
圧延を行う以外は常法に従って行い、引き続き常法に従
って、酸洗、冷間圧延を行った後、連続焼鈍するに際
し、Ac1 変態点以上、Ac3 変態点以下の二相域で3
0〜150秒間保持した後、20℃/s以上の冷却速度
で400℃以下の温度域まで冷却することを特徴とす
る、そのミクロ組織が、フェライトを主相とし、マルテ
ンサイトを第二相とする複合組織であり、フェライト相
におけるCu単独で構成される粒子の大きさが2nm以
下である疲労特性に優れた複合組織高強度冷延鋼板の製
造方法。
5. A hot rolling of a steel slab having the component according to any one of claims 1 to 4 is performed in accordance with a conventional method except that a finish rolling is performed at an Ar 3 transformation point or higher, and then in accordance with a conventional method. , Pickling, and cold rolling, and then performing continuous annealing, in the two-phase region of not less than the Ac 1 transformation point and not more than the Ac 3 transformation point.
After holding for 0 to 150 seconds, the microstructure is characterized by cooling to a temperature range of 400 ° C. or lower at a cooling rate of 20 ° C./s or higher. The microstructure has ferrite as a main phase and martensite as a second phase. A method for producing a composite structure high-strength cold-rolled steel sheet having excellent fatigue characteristics, wherein the size of particles composed of Cu alone in the ferrite phase is 2 nm or less.
JP00760998A 1998-01-19 1998-01-19 Composite structure high-strength cold-rolled steel sheet with excellent fatigue characteristics and method for producing the same Expired - Fee Related JP3619359B2 (en)

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JPH11199973A true JPH11199973A (en) 1999-07-27
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