JPH11106573A - Master Badge - Google Patents
Master BadgeInfo
- Publication number
- JPH11106573A JPH11106573A JP26602797A JP26602797A JPH11106573A JP H11106573 A JPH11106573 A JP H11106573A JP 26602797 A JP26602797 A JP 26602797A JP 26602797 A JP26602797 A JP 26602797A JP H11106573 A JPH11106573 A JP H11106573A
- Authority
- JP
- Japan
- Prior art keywords
- color
- density
- molecular weight
- pigment
- masterbatch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 19
- -1 polyethylene Polymers 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000004698 Polyethylene Substances 0.000 claims abstract description 13
- 229920000573 polyethylene Polymers 0.000 claims abstract description 13
- 239000006229 carbon black Substances 0.000 claims description 6
- 239000012968 metallocene catalyst Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 229920005989 resin Polymers 0.000 abstract description 15
- 239000011347 resin Substances 0.000 abstract description 15
- 239000003973 paint Substances 0.000 abstract description 8
- 239000000976 ink Substances 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 description 17
- 238000000576 coating method Methods 0.000 description 17
- 239000004595 color masterbatch Substances 0.000 description 12
- 210000003298 dental enamel Anatomy 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 235000010746 mayonnaise Nutrition 0.000 description 5
- 239000008268 mayonnaise Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
- IICCLYANAQEHCI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3',6'-dihydroxy-2',4',5',7'-tetraiodospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 IICCLYANAQEHCI-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001561902 Chaetodon citrinellus Species 0.000 description 1
- XKTMIJODWOEBKO-UHFFFAOYSA-M Guinee green B Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 XKTMIJODWOEBKO-UHFFFAOYSA-M 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 1
- PPKVREKQVQREQD-UHFFFAOYSA-N antimony pentasulfide Chemical compound S=[Sb](=S)S[Sb](=S)=S PPKVREKQVQREQD-UHFFFAOYSA-N 0.000 description 1
- 229960001283 antimony pentasulfide Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- ZJEQXMBWVSQUCP-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn].[Zn] ZJEQXMBWVSQUCP-UHFFFAOYSA-N 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 229940081623 rose bengal Drugs 0.000 description 1
- 229930187593 rose bengal Natural products 0.000 description 1
- STRXNPAVPKGJQR-UHFFFAOYSA-N rose bengal A Natural products O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 STRXNPAVPKGJQR-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
(57)【要約】
【課題】 汚染性が少なく、分散性に優れたインク、塗
料、着色樹脂の調色用に好適に使用することができるマ
スターバッチを提供する。
【解決手段】 密度０．９００ｇ／ｃｍ3以下、分子
量１００００以上のポリエチレンと、顔料とを含むマス
ターバッチ。PROBLEM TO BE SOLVED: To provide a masterbatch which is suitable for use in toning inks, paints, and colored resins which are less contaminated and have excellent dispersibility. SOLUTION: A master batch containing polyethylene having a density of 0.900 g / cm 3 or less, a molecular weight of 10,000 or more, and a pigment.
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、汚染性が少なく、
分散性に優れたインク、塗料、着色樹脂の調色用に好適
に使用することができるマスターバッチに関するもので
ある。TECHNICAL FIELD The present invention relates to a low-contamination,
The present invention relates to a masterbatch that can be suitably used for toning inks, paints, and colored resins having excellent dispersibility.
【０００２】[0002]
【従来技術】従来より、着色した熱可塑性樹脂、インク
や塗料の微妙な色合わせ方法として調色がおこなわれて
いる。調色材料として必要な特性として、ベースとなる
樹脂やワニスとの相溶性に優れている事、調色後の塗膜
性能、たとえば耐溶剤性、耐水性、基材との密着性を損
なわない事、調色後の平滑性や光沢の低下を招かない事
等が重要である。また、作業性の点からは、調色剤の飛
散による汚染性が低い事、ベース樹脂やワニスとの溶解
性が高い事等が求められている。2. Description of the Related Art Conventionally, toning has been performed as a delicate color matching method for colored thermoplastic resins, inks and paints. Characteristics required as a toning material include: excellent compatibility with the base resin and varnish, and coating performance after toning, such as solvent resistance, water resistance, and adhesion to the substrate. It is important that smoothness and gloss after toning do not decrease. Further, from the viewpoint of workability, it is required to have low contamination due to scattering of the toning agent and high solubility with the base resin and varnish.
【０００３】調色用着色剤には、これらの要望を満たす
べくいくつかの方式がある。最も一般的に使用されてい
るのは、ドライカラーである。ドライカラーは常温の撹
拌混合のみで製造が可能であるので低価格であるのがそ
の理由である。しかし、ドライカラーは微粉である為、
飛散・汚染性が大きいだけでなく、分散不良を生じやす
く物性低下や色むら等が発生しやすい傾向にあった。こ
れらの問題点を解決すべく特開昭６２−１９２３５号公
報や特開平５−２３０２２７号公報では液体カラーやペ
ーストカラーが提案されている。液体カラーは分散性に
優れるものの、液状物の飛散や漏れ、加工機械への付
着、それに伴う計量ミス等の問題点があった。[0003] There are several types of toning colorants to meet these needs. The most commonly used is dry color. The reason for this is that the dry color can be produced only by stirring and mixing at room temperature, and is therefore inexpensive. However, since dry color is fine powder,
In addition to the large scattering and contamination properties, there was a tendency that poor dispersion was liable to occur and physical properties were reduced and color unevenness was likely to occur. In order to solve these problems, Japanese Patent Application Laid-Open Nos. 62-19235 and 5-230227 propose liquid colors and paste colors. Although the liquid color is excellent in dispersibility, there are problems such as scattering and leakage of the liquid material, adhesion to a processing machine, and weighing error.
【０００４】[0004]
【発明が解決しようとする課題】これらの他に、カラー
マスターバッチが提案されている。カラーマスターバッ
チは顔料と樹脂とを高温で溶融混合した樹脂組成物であ
り、環境汚染性は低いが、製造コストが高価であり、ま
た液状カラーやペーストカラーに比べてベース樹脂やワ
ニスへの分散に時間がかかる、すなわち分散性に劣ると
いう欠点があった。In addition to these, a color master batch has been proposed. A color masterbatch is a resin composition in which a pigment and a resin are melt-mixed at a high temperature.The environmental pollution is low, but the production cost is high. , It takes a long time, that is, it is inferior in dispersibility.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、カラーマ
スターバッチの易分散化に関して鋭意研究した結果、特
定物性を有するポリエチレンを樹脂成分として用いるこ
とにより、得られるマスターバッチは特に優れた分散性
上を示し、インク、塗料、樹脂への分散性が飛躍的に向
上することを見いだし、本発明に到達した。すなわち、
本発明は、密度０．９００ｇ／ｃｍ3以下、分子量１０
０００以上のポリエチレンと、顔料とを含有するマスタ
ーバッチに存する。Means for Solving the Problems The inventors of the present invention have conducted intensive studies on easy dispersion of a color masterbatch. As a result, a masterbatch obtained by using polyethylene having specific physical properties as a resin component has a particularly excellent dispersion. The present invention has been found to show remarkable improvement in dispersibility in ink, paint, and resin, and has reached the present invention. That is,
The present invention has a density of 0.900 g / cm 3 or less and a molecular weight of 10
In a masterbatch containing more than 000 polyethylene and a pigment.
【０００６】[0006]
【発明の実施の形態】以下、本発明を詳細に説明する。
本発明におけるマスターバッチは、樹脂成分と顔料とを
含有するものである。これらの成分が主成分であるが、
必要に応じてその他の成分を含有することも可能であ
る。例えば酸化防止剤、界面活性剤、等の添加剤が挙げ
られ、通常２０重量％以下が適当である。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.
The masterbatch in the present invention contains a resin component and a pigment. These components are the main components,
If necessary, other components can be contained. For example, additives such as an antioxidant and a surfactant may be mentioned, and usually 20% by weight or less is appropriate.
【０００７】本発明のマスターバッチに用いられる樹脂
は、密度０．９００ｇ／ｃｍ3以下、分子量１００００
以上のポリエチレンである。この密度領域のポリエチレ
ンを使用することにより、得られる樹脂組成物はインク
や塗料に極めて低温度で容易に溶解し、マスターバッチ
として好適に用いることができることを本発明者らは見
いだしたものである。なお、分子量１００００未満のも
のは通常ワックスとして取り扱われるが、分子量が１０
０００未満では皮膜の光沢、硬度、耐候性が充分ではな
い。密度は０．９００ｇ／ｃｍ3以下であればよいが、
特に好ましくは０．８８０ｇ／ｃｍ3以下とすることに
より、インクや塗料のビヒクルへの溶解性が極めて優れ
ている。分子量は、１００００以上であればよいが、特
に好ましくは１５０００以上とすることにより、得られ
る皮膜の皮膜硬度を極めて高いものとすることができ
る。The resin used in the masterbatch of the present invention has a density of 0.900 g / cm 3 or less and a molecular weight of 10,000.
The above is polyethylene. The present inventors have found that the use of polyethylene in this density range allows the obtained resin composition to be easily dissolved in inks and paints at an extremely low temperature and can be suitably used as a master batch. . Incidentally, those having a molecular weight of less than 10,000 are usually treated as waxes,
If it is less than 000, the gloss, hardness and weather resistance of the film are not sufficient. The density may be 0.900 g / cm 3 or less,
Particularly preferably, when the content is 0.880 g / cm 3 or less, the solubility of the ink or the coating material in the vehicle is extremely excellent. The molecular weight may be 10,000 or more, and particularly preferably 15,000 or more, whereby the hardness of the obtained film can be extremely high.
【０００８】本発明においては上記の密度範囲及び分子
量範囲のポリエチレンであれば特に限定されず用いるこ
とができるが、例えば、メタロセン触媒を用いて合成さ
れた超低密度ポリエチレン、即ち、ポリエチレン主鎖に
長鎖分岐を持つポリエチレンが特に好適である。なお、
マスターバッチ全体の２０重量％以下の割合で他の樹脂
やワックスを加えてもよい。In the present invention, any polyethylene can be used without particular limitation as long as it has the above-mentioned density range and molecular weight range. For example, ultra-low density polyethylene synthesized using a metallocene catalyst, that is, Polyethylenes with long chain branches are particularly preferred. In addition,
Another resin or wax may be added at a ratio of 20% by weight or less of the entire master batch.
【０００９】なお本発明における密度とは、ＪＩＳ Ｋ
６７６０に従って測定した値を言い、、分子量とはゲル
浸透クロマトグラフ（ＧＰＣ）法により測定した数平均
分子量を言う。顔料としては、特に限定されないが、例
えば、酸化チタン（Ｒ形）、酸化チタン（Ａ形）、亜鉛
華、硫化亜鉛、リトボン、鉛白、硫酸鉛、塩基性硫酸
鉛、ランプブラック、アセチレンブラック、カーボンブ
ラック、黒鉛、ボーンブラック、鉄黒、べんがら、アン
チモンレッド、カドミウムレッド、モリブデンレッド、
銀朱、鉛丹、亜鉛化銅、黄鉛（赤口）、黄鉛（黄口）、
カドミウムイエロー、亜鉛黄、ストロンチウムイエロ
ー、バリウムイエロー、リサージ、黄土、黄色酸化鉄、
ガンマヘマタイト、アンバー、シエナ、ギネーグリー
ン、酸化クロム、コバルトグリーン、フタロシアニング
リーン、紺青、群青、コバルトブルー、フタロシアニン
ブルー、亜鉛末、アルミニウム粉、金粉、硫酸バリウ
ム、炭酸バリウム、炭酸カルシウム、白亜、炭酸マグネ
シウム、セッコウ、アルミナホワイト、カオリンクレ
ー、マイカ、タルク、シリカ、けいそう土、合成ダイヤ
モンド、パーマネントレッド４Ｒ、ウオッチングレッ
ド、ファストイエロー１０Ｇ、ジスアゾイエロー、ボル
ドー１０Ｂ、トルイジンマルーン、ピーコックブルー、
ナイロン粉体、ポリエチレン粉体等が使用できる。The density in the present invention is defined by JIS K
The value refers to the value measured according to 6760, and the molecular weight refers to the number average molecular weight measured by gel permeation chromatography (GPC). Examples of the pigment include, but are not particularly limited to, titanium oxide (R type), titanium oxide (A type), zinc white, zinc sulfide, lithopone, lead white, lead sulfate, basic lead sulfate, lamp black, acetylene black, Carbon black, graphite, bone black, iron black, red iron, antimony red, cadmium red, molybdenum red,
Silver vermilion, lead red, zinc zinc copper, graphite (red mouth), graphite (yellow mouth),
Cadmium yellow, zinc yellow, strontium yellow, barium yellow, litharge, loess, yellow iron oxide,
Gamma hematite, amber, siena, guinea green, chromium oxide, cobalt green, phthalocyanine green, navy blue, ultramarine, cobalt blue, phthalocyanine blue, zinc dust, aluminum powder, gold powder, barium sulfate, barium carbonate, calcium carbonate, chalk, magnesium carbonate, Gypsum, alumina white, kaolin clay, mica, talc, silica, diatomaceous earth, synthetic diamond, permanent red 4R, watching red, fast yellow 10G, disazo yellow, Bordeaux 10B, toluidine maroon, peacock blue,
Nylon powder, polyethylene powder and the like can be used.
【００１０】また、これらの顔料を各種の酸化剤等で後
処理したものを使用することもできる。更に、上記顔料
に極性制御性や調色の為の染料を混合して使用する事も
可能である。例えば、アルカリブルー、スピリットブラ
ック、アニリンブラック、オイルブルー、オイルブラッ
ク、ファストレッド、メチルオレンジ、クリッスタルバ
イオレット、エオシン、ローズベンガル、ローダミンＢ
およびチオインジゴ系染料等の染料が例示される。Further, those obtained by post-treating these pigments with various oxidizing agents or the like can also be used. Furthermore, it is also possible to use a mixture of the above pigment with a dye for polarity control and toning. For example, alkali blue, spirit black, aniline black, oil blue, oil black, fast red, methyl orange, crystal violet, eosin, rose bengal, rhodamine B
And dyes such as thioindigo dyes.
【００１１】更に、樹脂と顔料を混練する際の混合性を
良くするた為の界面活性剤や酸化防止剤を添加すること
も可能である。これらの樹脂、顔料、添加剤等を混合し
てマスターバッチを製造する。使用する混合機は、通常
熱可塑性樹脂を溶融混練に使用するものであれば良い。
例えば、単軸押出機、二軸押出機、バンバリーミキサ
ー、加圧ニーダー等が使用できる。Further, it is also possible to add a surfactant or an antioxidant for improving the mixing property when kneading the resin and the pigment. A masterbatch is manufactured by mixing these resins, pigments, additives and the like. The mixer to be used may be any one that normally uses a thermoplastic resin for melt-kneading.
For example, a single screw extruder, a twin screw extruder, a Banbury mixer, a pressure kneader and the like can be used.
【００１２】樹脂と顔料との混合比は、好ましくは上述
の特定の密度範囲及び分子量範囲のポリエチレンを３０
重量％以上含有させ、顔料を５〜７０重量％、特に好ま
しくは２０〜６０重量％含有させるのが好ましい。マス
ターバッチの形状としては特に限定されず、例えばペレ
ット状、板状等の形状に加工して使用することができ
る。The mixing ratio of the resin and the pigment is preferably such that the polyethylene having the above-mentioned specific density range and molecular weight range is 30%.
%, More preferably 5 to 70% by weight, particularly preferably 20 to 60% by weight. The shape of the master batch is not particularly limited. For example, the master batch can be used after being processed into a shape such as a pellet or a plate.
【００１３】（実施例１） （１）カラーマスターバッチの作製 東洋精機製作所製バンバリーミキサー（Ｂー２５０型）
に三菱化学（株）製ポリエチレン樹脂（「Ｋｅｒｎｅ
ｌ」、密度０．８８０ｇ／ｃｃ、分子量３６０００）１
４１．８ｇ、Ｃｉｂａ−Ｇｅｉｇｙ社製老化防止剤（イ
ルガノックス１０１０）１．４ｇ、三菱化学社製カーボ
ンブラック（「ＭＡ１００」）を５６．７ｇを投入し
た。ミキサー温度を１３５℃に設定して、１２分間混練
し、カーボンブラック濃度が４０ｗｔ％のマスターバッ
チを作製した。(Example 1) (1) Production of color master batch Banbury mixer (Model B-250) manufactured by Toyo Seiki Seisaku-sho, Ltd.
To a polyethylene resin manufactured by Mitsubishi Chemical Corporation (Kerne
l ", density 0.880 g / cc, molecular weight 36000) 1
41.8 g, 1.4 g of an antioxidant (Irganox 1010) manufactured by Ciba-Geigy, and 56.7 g of carbon black (“MA100”) manufactured by Mitsubishi Chemical Corporation were charged. The mixer temperature was set to 135 ° C., and the mixture was kneaded for 12 minutes to prepare a master batch having a carbon black concentration of 40 wt%.
【００１４】(2)白色エナメルの調色 容量２００ｍｌのガラス製マヨネーズ瓶に、関西ペイン
ト（株）製白色エナメル塗料（アラミック１５３１ホワ
イト）を５０ｇと上記マスターバッチ０．７５ｇ、直径
２.５〜３.５ｍｍの東京ガラス（株）製ガラスビーズ９
０ｇを入れた。このマヨネーズ瓶をレッドデビル社製ペ
イントシェイカー「ＲＣ−５０００Ａ」にセットして２
１分間シェイクして、グレーエナメルを作製した。(2) Toning of white enamel In a glass mayonnaise bottle having a capacity of 200 ml, 50 g of white enamel paint (ALAMIC 1531 white) manufactured by Kansai Paint Co., Ltd., 0.75 g of the above master batch, and a diameter of 2.5 to 3 were prepared. 2.5mm glass beads 9 from Tokyo Glass Co., Ltd.
0 g was added. Set this mayonnaise bottle on Red Devil Paint Shaker “RC-5000A”
Shake for 1 minute to produce a gray enamel.
【００１５】(3)グレーエナメルの塗膜評価 このグレーエナメルの一部（約１ｃｃ）を分取して、富
士フィルム（株）製ＰＥＴフィルム（「トランシーＧ」
厚さ１８０μｍ）に乗せ、東洋精機（株）製バーコーダ
ー（「２４番」）で展色した。この展色したＰＥＴフィ
ルムを池田理化（株）製通風乾燥機（「Automatic Dryi
ng Oven SS-200N」）に２０分間入れ焼き付けを実施し
た。この焼き付けした塗膜黒度を日本電色（株）製色差
計（「Spectro Color Meter SE-2000」）で測定した。
塗膜黒度の指標であるＬ値は４３．８であった。また、
塗膜の硬度を三菱鉛筆（株）製鉛筆（「ユニ」）を用い
て判断した。硬度は３Ｈであった。また、調色に使用し
た器具、周囲の環境汚染は無かった。(3) Evaluation of coating film of gray enamel A part (about 1 cc) of this gray enamel was fractionated and PET film manufactured by Fuji Film Co., Ltd. (“TRANCY G”)
(Thickness: 180 μm) and developed with a bar coder (“No. 24”) manufactured by Toyo Seiki Co., Ltd. The developed PET film is then passed through a ventilation dryer ("Automatic Dryi" manufactured by Ikeda Rika Co., Ltd.).
ng Oven SS-200N ") for 20 minutes and baking was performed. The blackness of the baked coating film was measured with a color difference meter (“Spectro Color Meter SE-2000”) manufactured by Nippon Denshoku Co., Ltd.
The L value, which is an index of the coating blackness, was 43.8. Also,
The hardness of the coating film was determined using a pencil (“Uni”) manufactured by Mitsubishi Pencil Co., Ltd. The hardness was 3H. In addition, there was no pollution of the equipment used for toning and the surrounding environment.
【００１６】（比較例１）実施例１においてカラーマス
ターバッチを作製する際に使用する樹脂を日本ポリケム
（株）製低密度ポリエチレン（「ＬＦ２４０」密度０．
９２４ｇ／ｃｃ分子量２１４００）を使用し、ミキサー
温度を１６５℃とした以外は全く同様の方法でカラーマ
スターバッチを作製した。このカラーマスターバッチを
用いて実施例１と全く同様の方法でグレーエナメルを作
製し、塗膜の評価を実施した。その結果、塗膜黒度の指
標であるＬ値は６８．３であり、実施例１に比べてカラ
ーマスターバッチの分散性は悪かった。また、塗膜の硬
度は３Ｈであり実施例１と差が無かった。(Comparative Example 1) In Example 1, a resin used for producing a color masterbatch was a low-density polyethylene ("LF240" having a density of 0.1 mm) manufactured by Nippon Polychem Corporation.
924 g / cc molecular weight 21400) and a color masterbatch was prepared in exactly the same manner except that the mixer temperature was 165 ° C. Using this color master batch, gray enamel was produced in the same manner as in Example 1, and the coating film was evaluated. As a result, the L value, which is an index of the blackness of the coating film, was 68.3, and the dispersibility of the color master batch was poor as compared with Example 1. The hardness of the coating film was 3H, which was not different from that of Example 1.
【００１７】（比較例２）実施例１においてカラーマス
ターバッチを作製する際に使用する樹脂を三井石油化学
（株）製合成ワックス（「２００Ｐ」密度０．９７ｇ／
ｃｃ分子量２０００）を使用した以外は全く同様の方法
でカラーマスターバッチを作製した。このカラーマスタ
ーバッチを用いて実施例１と全く同様の方法でグレーエ
ナメルを作製し、塗膜の評価を実施した。その結果、塗
膜黒度の指標であるＬ値は４４．２であり、実施例１と
ほぼ同等であった。また、塗膜の硬度はＨであり実施例
１に比べて硬度は低下した。(Comparative Example 2) In Example 1, a resin used for preparing a color master batch was a synthetic wax manufactured by Mitsui Petrochemical Co., Ltd. (“200P” density 0.97 g /
A color masterbatch was prepared in exactly the same manner except that cc molecular weight of 2000) was used. Using this color master batch, gray enamel was produced in the same manner as in Example 1, and the coating film was evaluated. As a result, the L value as an index of the coating film blackness was 44.2, which was almost the same as that in Example 1. Further, the hardness of the coating film was H, which was lower than that of Example 1.
【００１８】（比較例３） （１）液体カラーの作製 １４０ｃｃのマヨネーズ瓶に直径２.５〜３.５ｍｍの東
京ガラス（株）製ガラスビーズを９０ｇ入れた。メラミ
ンアルキド樹脂ワニス（「アミラック１０２６」関西ペ
イント（株）製）を１６ｇとアミラックシンナー１０ｇ
（関西ペイント（株）製）と三菱化学（株）カーボンブ
ラック（「ＭＡ１００」）を入れた。Comparative Example 3 (1) Production of Liquid Color A 140 cc mayonnaise bottle was charged with 90 g of Tokyo Glass Co., Ltd. glass beads having a diameter of 2.5 to 3.5 mm. 16 g of melamine alkyd resin varnish (“Amirac 1026” manufactured by Kansai Paint Co., Ltd.) and 10 g of Amirac thinner
(Manufactured by Kansai Paint Co., Ltd.) and Mitsubishi Chemical Corporation carbon black ("MA100").
【００１９】このマヨネーズ瓶をレッドデビル（株）製
シングルタイプペイントシェイカー「ＲＣ−５０００
Ａ」にセットして１５分間振とうした。この黒色ワニス
を室温まで冷却した後、（株）上島製作所製グラインド
ゲージ（型式：「Ｒ１１１０」）で０〜５０μｍの範囲
の未分散塊カーボンブラックの大きさを測定した。グラ
インドゲージの測定結果は７μｍであった。This mayonnaise bottle was used as a single type paint shaker "RC-5000" manufactured by Red Devil Co., Ltd.
A "and shaken for 15 minutes. After the black varnish was cooled to room temperature, the size of the undispersed lump carbon black in the range of 0 to 50 μm was measured with a grind gauge (model: “R1110”) manufactured by Ueshima Seisakusho Co., Ltd. The measurement result of the grind gauge was 7 μm.
【００２０】更にこのマヨネーズ瓶に「アミラック１０
２６クリアー」を５０ｇ入れペイントシェイカーで１０
分間混合し黒色液体カラーを作製した。この液体カラー
１１．７ｇを分取して、実施例１と同様の操作で白色エ
ナメルの調色を実施した。更に、同様の操作でグレーエ
ナメルの塗膜を作製し塗膜の評価を実施した。塗膜黒度
の指標であるＬ値は４４．１であり、実施例１とほぼ同
等の値であった。塗膜の硬度は３Ｈであり実施例１と差
が無かった。しかし、液体カラーの計量に使用した器具
には液体カラーが付着して、作業性が低下した。実施例
及び比較例１〜３の結果を表−１にまとめた。Further, "Amirac 10" was added to this mayonnaise bottle.
26 Clear ”50g and 10 with a paint shaker
Mix for a minute to make a black liquid color. 11.7 g of this liquid color was fractionated and white enamel was toned in the same manner as in Example 1. Further, a coating film of gray enamel was prepared by the same operation, and the coating film was evaluated. The L value, which is an index of the blackness of the coating film, was 44.1, which was almost the same value as in Example 1. The hardness of the coating film was 3H, and there was no difference from Example 1. However, the liquid color adhered to the instrument used for measuring the liquid color, and the workability was reduced. Table 1 summarizes the results of Examples and Comparative Examples 1 to 3.
【００２１】[0021]
【表１】 [Table 1]
【００２２】[0022]
【発明の効果】密度０．９００ｇ／ｃｃ以下、数平均分
子量１００００以上のポリエチレンと顔料を混練して製
造したカラーマスターバッチを使用して調色すれば、器
具や環境汚染を防止できると共に、マスターバッチの分
散性が良いために良好な塗膜を作製する事が可能であ
る。According to the present invention, if a color masterbatch produced by kneading a polyethylene and a pigment having a density of 0.900 g / cc or less and a number average molecular weight of 10,000 or more and a pigment is used, it is possible to prevent pollution of equipment and the environment, A good coating film can be prepared because of good batch dispersibility.
Claims (5)
００００以上のポリエチレンと、顔料とを含むマスター
バッチ。1. A density of 0.900 g / cm 3 or less and a molecular weight of 1
A masterbatch containing 0000 or more polyethylene and a pigment.
００００以上のポリエチレンを４０重量％以上含む請求
項１記載のマスターバッチ。2. Density 0.900 g / cm 3 or less, molecular weight 1
2. The masterbatch according to claim 1, comprising at least 40% by weight of 0000 or more polyethylene.
記載のマスターバッチ。3. The method according to claim 1, wherein the pigment is contained in an amount of 5 to 70% by weight.
Master batch described.
００００以上のポリエチレンが、メタロセン触媒を用い
て合成されたものである請求項１〜３のいずれかに記載
のマスターバッチ。4. A density of 0.900 g / cm 3 or less and a molecular weight of 1
The masterbatch according to any one of claims 1 to 3, wherein 0000 or more polyethylenes are synthesized using a metallocene catalyst.
４のいずれかに記載のマスターバッチ。5. The pigment according to claim 1, wherein the pigment is carbon black.
4. The masterbatch according to any one of 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26602797A JPH11106573A (en) | 1997-09-30 | 1997-09-30 | Master Badge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26602797A JPH11106573A (en) | 1997-09-30 | 1997-09-30 | Master Badge |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11106573A true JPH11106573A (en) | 1999-04-20 |
Family
ID=17425378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26602797A Pending JPH11106573A (en) | 1997-09-30 | 1997-09-30 | Master Badge |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11106573A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001044387A3 (en) * | 1999-12-13 | 2001-12-20 | Basf Ag | Pigment concentrates and methods for production thereof |
| WO2001098415A3 (en) * | 2000-06-20 | 2002-04-04 | Basf Ag | Pigment concentrates and method for producing them |
| WO2002064669A1 (en) * | 2001-02-16 | 2002-08-22 | Toyo Ink Mfg. Co., Ltd. | Process for producing colored resin composition and utilization thereof |
| KR100805575B1 (en) * | 2000-06-21 | 2008-02-20 | 도요 잉키 세이조 가부시끼가이샤 | Colored resin composition and molded article |
| US7442742B1 (en) | 2007-04-04 | 2008-10-28 | Carolina Color Corporation | Masterbatch composition |
| WO2010058673A1 (en) * | 2008-11-21 | 2010-05-27 | 東洋アルミニウム株式会社 | Master batch for coloring synthetic resin |
| US8460590B2 (en) | 2001-07-25 | 2013-06-11 | Pirelli Pneumatici S.P.A. | Process for continuously producing an elastomeric composition |
| US9969881B2 (en) | 2014-07-18 | 2018-05-15 | Carolina Color Corporation | Process and composition for well-dispersed, highly loaded color masterbatch |
| US10428189B2 (en) | 2014-07-18 | 2019-10-01 | Chroma Color Corporation | Process and composition for well dispersed, highly loaded color masterbatch |
| WO2020190674A1 (en) | 2019-03-15 | 2020-09-24 | Chroma Color Corporation | Colorant and additive concentrate carrier system with efficacy over a wide range of polymeric processing temperatures |
| US11859061B2 (en) | 2019-03-15 | 2024-01-02 | Chroma Color Corporation | Colorant and additive concentrate carrier system with efficacy over a wide range of polymeric processing temperatures |
-
1997
- 1997-09-30 JP JP26602797A patent/JPH11106573A/en active Pending
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003517081A (en) * | 1999-12-13 | 2003-05-20 | ビーエーエスエフ アクチェンゲゼルシャフト | Pigment concentrate and method for producing the same |
| US6812274B2 (en) * | 1999-12-13 | 2004-11-02 | Basf Aktiengesellschaft | Pigment concentrates and their production |
| WO2001044387A3 (en) * | 1999-12-13 | 2001-12-20 | Basf Ag | Pigment concentrates and methods for production thereof |
| WO2001098415A3 (en) * | 2000-06-20 | 2002-04-04 | Basf Ag | Pigment concentrates and method for producing them |
| US6846356B2 (en) | 2000-06-20 | 2005-01-25 | Basf Aktiengesellschft | Pigment concentrates and method for producing them |
| KR100805575B1 (en) * | 2000-06-21 | 2008-02-20 | 도요 잉키 세이조 가부시끼가이샤 | Colored resin composition and molded article |
| WO2002064669A1 (en) * | 2001-02-16 | 2002-08-22 | Toyo Ink Mfg. Co., Ltd. | Process for producing colored resin composition and utilization thereof |
| US7001937B2 (en) | 2001-02-16 | 2006-02-21 | Toyo Ink Mfg. Co., Ltd. | Process for producing colored resin composition and utilization thereof |
| US8460590B2 (en) | 2001-07-25 | 2013-06-11 | Pirelli Pneumatici S.P.A. | Process for continuously producing an elastomeric composition |
| US7442742B1 (en) | 2007-04-04 | 2008-10-28 | Carolina Color Corporation | Masterbatch composition |
| WO2010058673A1 (en) * | 2008-11-21 | 2010-05-27 | 東洋アルミニウム株式会社 | Master batch for coloring synthetic resin |
| US8513344B2 (en) | 2008-11-21 | 2013-08-20 | Toyo Aluminium Kabushiki Kaisha | Masterbatch for coloring synthetic resin |
| US9969881B2 (en) | 2014-07-18 | 2018-05-15 | Carolina Color Corporation | Process and composition for well-dispersed, highly loaded color masterbatch |
| US10428189B2 (en) | 2014-07-18 | 2019-10-01 | Chroma Color Corporation | Process and composition for well dispersed, highly loaded color masterbatch |
| WO2020190674A1 (en) | 2019-03-15 | 2020-09-24 | Chroma Color Corporation | Colorant and additive concentrate carrier system with efficacy over a wide range of polymeric processing temperatures |
| US11053361B2 (en) | 2019-03-15 | 2021-07-06 | Chroma Color Corporation | Colorant and additive concentrate carrier system with efficacy over a wide range of polymeric processing temperatures |
| US11859061B2 (en) | 2019-03-15 | 2024-01-02 | Chroma Color Corporation | Colorant and additive concentrate carrier system with efficacy over a wide range of polymeric processing temperatures |
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