JPH032690A - Deuterium collection material for nuclear fusion - Google Patents
Deuterium collection material for nuclear fusionInfo
- Publication number
- JPH032690A JPH032690A JP1138088A JP13808889A JPH032690A JP H032690 A JPH032690 A JP H032690A JP 1138088 A JP1138088 A JP 1138088A JP 13808889 A JP13808889 A JP 13808889A JP H032690 A JPH032690 A JP H032690A
- Authority
- JP
- Japan
- Prior art keywords
- palladium
- deuterium
- coupling
- amorphous
- atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000004927 fusion Effects 0.000 title claims abstract description 24
- 229910052805 deuterium Inorganic materials 0.000 title claims abstract description 22
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 title claims abstract description 16
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract description 75
- 229910052763 palladium Inorganic materials 0.000 abstract description 31
- 125000004431 deuterium atom Chemical group 0.000 abstract description 13
- 125000004429 atom Chemical group 0.000 abstract description 9
- 230000001788 irregular Effects 0.000 abstract description 2
- 230000008878 coupling Effects 0.000 abstract 8
- 238000010168 coupling process Methods 0.000 abstract 8
- 238000005859 coupling reaction Methods 0.000 abstract 8
- 239000013078 crystal Substances 0.000 description 16
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 3
- 150000001975 deuterium Chemical group 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000006123 lithium glass Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052722 tritium Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- -1 deuterium cations Chemical class 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- SWQJXJOGLNCZEY-BJUDXGSMSA-N helium-3 atom Chemical compound [3He] SWQJXJOGLNCZEY-BJUDXGSMSA-N 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/10—Nuclear fusion reactors
Landscapes
- Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
この発明は、常温核融合を実現するための重水素取り込
み材料に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) This invention relates to a deuterium-capturing material for realizing cold fusion.
(従来の技術)
1989年3月に、常温核融合の可能性を示唆する研究
結果がアメリカのユタ大学化学部のスタンレー・ポンス
学部長とイギリスのサラサンプトン大学のマルチン・フ
ライシュマン教授のグループ及び、同じくユタ州プリガ
ムヤング大学のスチーブン・ジョーンズ教授とアリシナ
大学の研究グループから発表された。その後、世界各地
でその検証実験が行なわれ、常温核融合が有望であると
の報告も多くなされている。例としてはアメリカのロス
アラモス国立研究所のハワード・メンラブ博士らの超低
温に冷やした重水素ガスに高圧をかけるとユタ大グルー
プのように電流をかけなくても核融合を示唆する中性子
発生があることを確認したと報告がある。(Prior technology) In March 1989, research results suggesting the possibility of cold fusion were reported by a group led by Stanley Pons, Dean of the Department of Chemistry at the University of Utah in the United States, and Professor Martin Fleischmann at the University of Sarathampton in the United Kingdom. It was also published by Professor Stephen Jones of Prigham Young University in Utah and a research group at Alisina University. Since then, verification experiments have been carried out around the world, and many reports have been made that cold fusion is promising. For example, Dr. Howard Menlove and his colleagues at Los Alamos National Laboratory in the United States have shown that when high pressure is applied to deuterium gas cooled to ultra-cold temperatures, neutrons are generated, suggesting nuclear fusion, even without the application of electric current, as demonstrated by the Utah group. There are reports that it has been confirmed.
核反応は、核分裂と同じ核反応の一つである。Nuclear reaction is one of the nuclear reactions, same as nuclear fission.
核分裂は、ウランなどの質量の大きい原子核が分裂して
2つの新しい原子核を生成する現象である。Nuclear fission is a phenomenon in which a heavy atomic nucleus, such as uranium, splits to form two new atomic nuclei.
その2つの原子核の質量の和は、分裂前の質量の和より
小さい。その小さくなった質量をエネルギーとして放出
する。The sum of the masses of the two nuclei is smaller than the sum of their masses before splitting. The reduced mass is released as energy.
一方、核融合では重水素など質量の小さい原子核どうし
が衝突し互いに融合して新しい原子核を生成する。この
とき生まれる原子核の質量はもとの2つの原子核の質量
の和より小さく、その差がエネルギーとなる。太陽の中
心では膨大な圧力と高温のために原子核がむき出しにな
り、激しく衝突して融合する。それが太陽の光と熱の源
であり熱核融合と呼ばれている。もともと原子核は十の
電荷を持っている。同じ電荷どうしであるのでお互いに
反発しあい、通常ではぶつからない。そこであらかじめ
1億度C以上の超高温にして、原子核と電子をバラバラ
な状態(プラズマ)にしておく。さらにその数(プラズ
マ数)を1立方センチあたり3兆個以上にして、原子核
どうしがぶつかりやすくしてやらなければならない。し
かもその状態を最低でも1秒間は保つ必要がある。しか
しそんな超高温や超高密度には、どんな素材でも耐えら
れない。そこで地場で閉じ込めたり、レーザーで一種の
宙吊り状態にしてやったりしなければならない。この熱
核融合については、いずれも国家規模の巨大プロジェク
トとして研究が進められている。On the other hand, in nuclear fusion, atomic nuclei with low mass such as deuterium collide with each other and fuse together to create new atomic nuclei. The mass of the resulting nucleus is smaller than the sum of the masses of the two original nuclei, and the difference is energy. At the center of the sun, the enormous pressure and high temperatures expose the atomic nuclei, which violently collide and fuse together. This is the source of sunlight and heat and is called thermonuclear fusion. Originally, an atomic nucleus has a charge of 10. Since they have the same charge, they repel each other and normally do not collide. Therefore, the temperature is raised to an extremely high temperature of over 100 million degrees Celsius, and the atomic nuclei and electrons are made into a disjointed state (plasma). Furthermore, we need to increase the number (plasma number) to more than 3 trillion per cubic centimeter to make it easier for atomic nuclei to collide with each other. Moreover, it is necessary to maintain this state for at least one second. However, no material can withstand such ultra-high temperatures and ultra-high density. So they have to be trapped on the ground or suspended in a kind of suspended state using lasers. Research into thermonuclear fusion is currently underway as a huge national project.
重水素どうしが核融合すると、ヘリウム−3と中性子、
三重水素(トリチウム)と陽子が発生し熱がでる。さら
に2次反応でガンマ線も出てくる。When deuterium fuses together, it produces helium-3 and neutrons.
Tritium and protons are generated and heat is produced. Furthermore, gamma rays are also emitted as a result of secondary reactions.
そこでこれらを測定することにより核融合が起きたかど
うかを判断できる。しかしトリチウムはもともと重水に
含まれており、それとの区別が難しい。中性子を測定す
るのが最も確実である。なお核融合の場合2.45メガ
電子ボルトの領域の中性子が多く出ることが分かってい
る。By measuring these, it is possible to determine whether nuclear fusion has occurred. However, tritium is originally contained in heavy water, and it is difficult to distinguish it from heavy water. Measuring neutrons is the most reliable method. In the case of nuclear fusion, it is known that many neutrons in the 2.45 megaelectron volt region are emitted.
常温核融合について、ジョーンズ教授らが成功したとい
う実験装置を一例として、第3図に示す。Figure 3 shows an example of the experimental equipment that Professor Jones and his colleagues have succeeded in using for cold fusion.
これは電気分解と同じ仕組みである。たたし水のかわり
に重水11を用い、電極は陽極には金8または白金、陰
極にはパラジウム9やチタン10を用いる。重水11は
絶縁物なので塩化リチウムなどの塩基物を少し混ぜであ
る。陰極にチタン10とパラジウム9を用い比べてみた
ところチタン10の方が効率が良かったとの報告がなさ
れている。This is the same mechanism as electrolysis. Heavy water 11 is used instead of tap water, gold 8 or platinum is used for the anode, and palladium 9 or titanium 10 is used for the cathode. Since heavy water 11 is an insulator, it is mixed with a small amount of a base such as lithium chloride. It has been reported that when titanium 10 and palladium 9 were compared for the cathode, titanium 10 was more efficient.
また水12とリチウムガラス14から成る高精度の中性
子測定装置13を備え、2.45メガ電子ボルト領域の
中性子を確かに捉え、発生したエネルギーは10兆分の
1ワツトであったとのことである。It was also equipped with a high-precision neutron measuring device 13 made of water 12 and lithium glass 14, and was able to reliably capture neutrons in the 2.45 megaelectron volt range, with the energy generated being 1/10 trillionth of a watt. .
メンラブ博士らの実験は、外部と遮蔽された容器の中に
チタンをおき、そこに重水素ガスを注入。In Dr. Menlove's experiment, titanium was placed in a container that was shielded from the outside, and deuterium gas was injected into it.
さらに、容器内部に20〜50気圧の圧力をかけるとと
もに、液体窒素を使って温度をマイナス摂氏193度ま
で下げる。この状態でしばらく放置し、次第に温度が上
がっていく過程で内部の変化を調べたところ、チタンに
重水素ガスが吸収されて、ごくわずかながら中性子の発
生が断続的に検知された。またマイナス30度になった
ところで急激に中性子が噴出される現象が確認された。Furthermore, a pressure of 20 to 50 atmospheres is applied inside the container, and the temperature is lowered to minus 193 degrees Celsius using liquid nitrogen. After leaving it in this state for a while and examining the internal changes as the temperature gradually rose, we found that deuterium gas was absorbed by the titanium, and the generation of very small neutrons was detected intermittently. Furthermore, a sudden ejection of neutrons was observed when the temperature reached minus 30 degrees Celsius.
この時間は5千分の1秒間でこの際の中性子の量は、自
然放射能より数桁多い規模であったという。This time was 1/5000th of a second, and the amount of neutrons at this time was several orders of magnitude greater than natural radioactivity.
第2図に従来の金属結晶型重水素取り込み材料に重水素
原子が取り込まれる様子を示した原理図を示す。この図
を用いて常温核融合の起きる原理を、ジョーンズ教授の
実験例で電極にパラジウムを用いた場合で説明する。6
は陰極に用いられているパラジウム金属結晶である。パ
ラジウム金属結晶6は、パラジウム原子2がパラジウム
原子間結合3により規則正しく格子状にならんで、金属
結晶を構成している。重水が電気分解されると、重水素
の陽イオン(重水素原子5)が陰極のパラジウム金属結
晶6に引き寄せられる。パラジウムは軽い元素を取り込
む性質があるので、重水素原子5はどんどんパラジウム
金属結晶6に入り込んでしまう。やがてパラジウム金属
結晶6の結晶格子の中に重水素原子間の距離が、トンネ
ル効果が起きる距離まで近ずくことにより融合し、質量
欠損によるエネルギーが生じるとされている。トンネル
効果とは粒子が障壁を通りぬけて、もれだすことである
。FIG. 2 shows a principle diagram showing how deuterium atoms are incorporated into a conventional metal crystal type deuterium-incorporating material. Using this diagram, we will explain the principle behind cold fusion using Professor Jones' experimental example in which palladium is used as an electrode. 6
is a palladium metal crystal used in the cathode. In the palladium metal crystal 6, palladium atoms 2 are regularly arranged in a lattice shape due to palladium interatomic bonds 3, forming a metal crystal. When heavy water is electrolyzed, deuterium cations (deuterium atoms 5) are attracted to the palladium metal crystal 6 at the cathode. Since palladium has the property of taking in light elements, the deuterium atoms 5 gradually enter the palladium metal crystal 6. Eventually, the distance between the deuterium atoms in the crystal lattice of the palladium metal crystal 6 becomes close enough to cause a tunnel effect, so that they fuse, and energy is generated due to mass defects. Tunneling is when particles pass through a barrier and leak out.
(発明が解決しようとする課題)
従来の例による実験結果ではその効率が低く、効率よく
常温核融合の起こる材料等が要求されていた。(Problems to be Solved by the Invention) Experimental results from conventional examples show that the efficiency is low, and there is a need for materials that can efficiently cause cold fusion.
(課題を解決するための手段)
この発明における重水素取り込み材料は、その構造をア
モルファスとしたものである。(Means for Solving the Problems) The deuterium uptake material in this invention has an amorphous structure.
(イ乍用)
従来のパラジウムやチタンなどの重水素取り込み材料は
その構造が結晶構造でありしたがって重水素原子は均一
に金属結晶中に広がっていた。その構造をアモルファス
とすることにより結晶を構成する原子間の距離に短い部
分と距離の長い部分とが生じる。このため入り込んでき
た重水素原子どうしの距離は、結晶原子間距離の短い部
分でより短くなり、重水素どうしが融合するための障壁
がちいさくなり、トンネル効果により通りぬけやすい部
分が生じる。このため重水素原子はそこで融合しやすく
なる。(For Ink) Conventional deuterium-capturing materials such as palladium and titanium have a crystalline structure, and therefore deuterium atoms are uniformly spread throughout the metal crystal. By making the structure amorphous, the distances between the atoms constituting the crystal include short portions and long distance portions. For this reason, the distance between deuterium atoms entering the crystal becomes shorter in areas where the distance between crystal atoms is short, and the barrier for deuterium molecules to fuse becomes smaller, creating areas where deuterium atoms can easily pass through due to the tunnel effect. This makes it easier for deuterium atoms to fuse there.
(実施例)
第1図はこの発明によるアモルファス重水素取り込み材
料の一実施例である。アモルファスとは規則正しく原子
が配列した結晶に対する言葉である。ここではアモルフ
ァスを固体に限定した不規則系物質であるとする。この
アモルファス重水素取り込み材料をパラジウムとした場
合の例を説明する。第1図において1はアモルファスパ
ラジウム、2はパラジウム原子、3はパラジウム原子間
結合、4は未結合手、5は重水素原子である。アモルフ
ァスパラジウム1は、パラジウム原子2がパラジウム原
子間結合3により結合されている。(Example) FIG. 1 shows an example of an amorphous deuterium uptake material according to the present invention. Amorphous is a term used to refer to crystals in which atoms are regularly arranged. Here, it is assumed that amorphous is a disordered substance limited to solid. An example in which palladium is used as the amorphous deuterium uptake material will be explained. In FIG. 1, 1 is amorphous palladium, 2 is a palladium atom, 3 is a bond between palladium atoms, 4 is a dangling bond, and 5 is a deuterium atom. In the amorphous palladium 1, palladium atoms 2 are bonded by palladium interatomic bonds 3.
このときパラジウム原子2の並び方が、不規則であり、
パラジウム原子間結合3に結合距離の長い部分と短い部
分が生じる。また、パラジウム原子2の結合手があまり
、未結合手4がアモルファスパラジウム1中に存在する
。重水素原子5はこのアモルファスパラジウム1の構造
中に次々取り込まれる。アモルファスパラジウムには結
晶を構成する原子間の距離に短い部分と距離の長い部分
とが生じる。このため入り込んできた重水素原子5どう
しの距離は、原子間結合距離の短い部分でより短くなる
。このため重水素どうしが融合するための障壁をトンネ
ル効果により通りぬけやすくなる。このためパラジウム
原子間結合3の距離の短いところで核融合が起こりやす
くなり、この材料をジョーンズ教授やメンラブ博士らの
実験に組み込むことにより常温核融合の実用化の可能性
が高まる。At this time, the arrangement of palladium atoms 2 is irregular,
A portion with a long bond distance and a portion with a short bond distance are generated in the bond 3 between palladium atoms. In addition, there are too many bonds of the palladium atom 2 and dangling bonds 4 present in the amorphous palladium 1. Deuterium atoms 5 are successively incorporated into the structure of this amorphous palladium 1. Amorphous palladium has short distances and long distances between the atoms that make up the crystal. Therefore, the distance between the incoming deuterium atoms 5 becomes shorter in the portion where the interatomic bond distance is short. This makes it easier for deuterium to pass through the fusion barrier due to the tunnel effect. For this reason, nuclear fusion is more likely to occur at short distances between palladium interatomic bonds 3, and incorporating this material into the experiments of Professor Jones and Dr. Menlove will increase the possibility of practical application of cold fusion.
なおこの例の場合はパラジウムにて説明をしたが、チタ
ン等の他の金属及びセラミックでもその構造をアモルフ
ァスとすることにより同様の効果が期待できる。In this example, palladium was used in the explanation, but similar effects can be expected with other metals such as titanium and ceramics by making the structure amorphous.
(発明の効果)
以上のように、この発明によれば重水素取り込み材料の
構造をアモルファスとしたので、重水素どうしの融合す
る効率があがり常温核融合の実用化に役立ち、エネルギ
ー問題の解決に貢献するものである。(Effects of the Invention) As described above, according to the present invention, the structure of the deuterium uptake material is made amorphous, which increases the efficiency of deuterium fusion, which helps in the practical application of cold fusion and helps solve energy problems. It is something that contributes.
第1図はこの発明によるアモルファス重水素取り込基材
料に重水素原子が取り込まれる様子を示した原理図、第
2図は従来の金属結晶型重水素取り込み材料に重水素原
子が取り込まれる様子を示した原理図、第3図はジョー
ンズ教授の常温核融合装置の構成図。
1・・・アモルファスパラジウム、2・・・パラジウム
原子、3・・・パラジウム原子間結合、4・・・未結合
手、5・・・重水素原子、6・・・パラジウム金属結晶
、7・・・バッテリー、8・・・金、9・・・パラジウ
ム、10・・・チタン、11・・・重水、12・・・水
、13・・・中性子測定器、14・・・リチウムガラス
第1図
1・・・アモルファスパラジウム
2・・・パラジウム原子
3・・・パラジウム原子間結合
4・・・未結合手
5・・・重水素原子Figure 1 is a principle diagram showing how deuterium atoms are incorporated into the amorphous deuterium uptake material according to the present invention, and Figure 2 shows how deuterium atoms are incorporated into a conventional metal crystal type deuterium uptake material. The principle diagram shown in Figure 3 is the configuration diagram of Professor Jones' cold fusion device. DESCRIPTION OF SYMBOLS 1... Amorphous palladium, 2... Palladium atom, 3... Bond between palladium atoms, 4... Strand bond, 5... Deuterium atom, 6... Palladium metal crystal, 7...・Battery, 8... Gold, 9... Palladium, 10... Titanium, 11... Heavy water, 12... Water, 13... Neutron measuring device, 14... Lithium glass Figure 1 1... Amorphous palladium 2... Palladium atom 3... Bond between palladium atoms 4... Strand bond 5... Deuterium atom
Claims (1)
ルファスとしたことを特徴とする重水素取り込み材料A deuterium uptake material for nuclear fusion, characterized by an amorphous structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1138088A JPH032690A (en) | 1989-05-31 | 1989-05-31 | Deuterium collection material for nuclear fusion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1138088A JPH032690A (en) | 1989-05-31 | 1989-05-31 | Deuterium collection material for nuclear fusion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH032690A true JPH032690A (en) | 1991-01-09 |
Family
ID=15213675
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1138088A Withdrawn JPH032690A (en) | 1989-05-31 | 1989-05-31 | Deuterium collection material for nuclear fusion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH032690A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002083299A3 (en) * | 2001-04-12 | 2003-02-27 | Celanese Int Corp | Palladium catalyst and processes for using the same |
-
1989
- 1989-05-31 JP JP1138088A patent/JPH032690A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002083299A3 (en) * | 2001-04-12 | 2003-02-27 | Celanese Int Corp | Palladium catalyst and processes for using the same |
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| Date | Code | Title | Description |
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| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20040810 |