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JPH01228703A - Surface coated cutting tip provided with al or al alloy cutting breaker - Google Patents

Surface coated cutting tip provided with al or al alloy cutting breaker

Info

Publication number
JPH01228703A
JPH01228703A JP5326588A JP5326588A JPH01228703A JP H01228703 A JPH01228703 A JP H01228703A JP 5326588 A JP5326588 A JP 5326588A JP 5326588 A JP5326588 A JP 5326588A JP H01228703 A JPH01228703 A JP H01228703A
Authority
JP
Japan
Prior art keywords
cutting
breaker
tungsten carbide
rake
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5326588A
Other languages
Japanese (ja)
Other versions
JP2556086B2 (en
Inventor
Hironori Yoshimura
吉村 寛範
Hiroshi Nakahara
中原 啓
Noribumi Kikuchi
菊池 則文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP63053265A priority Critical patent/JP2556086B2/en
Publication of JPH01228703A publication Critical patent/JPH01228703A/en
Application granted granted Critical
Publication of JP2556086B2 publication Critical patent/JP2556086B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

PURPOSE:To aim at prolonging the life of a cutting tip by setting the content of Co in a tungsten carbide group ultrahard alloy base to a value between 0.5-3.5%, by forming a diamond coated layer on the surface of the base, and by setting the rake angle of the breaker to an angle between 20-35 deg.. CONSTITUTION:The content of Co in a tungsten carbide group ultrahard base in a cutting tool is set to a value between 0.5 and 3.5, and the rake angle of a breaker formed on the rake surface of a cutting blade of the tool is set to an angle between 20 deg. and 35 deg.. A diamond coated layer is formed on the outer surface of the cutting tool by a chemical evaporation process. With this arrangement, it is possible to remarkably restrain Al or Al alloy chip from being fused to the rake surface of the cutting blade so as to prevent occurrence of microchipping, thereby it is possible to enhance the life of the cutting tool.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、AjおよびM合金の切削に用いた場合に、
これらの切削屑に対してすぐれた耐溶着性を示し、この
結果すぐれた耐摩耗性を長期に亘って発揮するようKな
るブレーカ−付表面被覆切削チップに関するものである
[Detailed Description of the Invention] [Industrial Field of Application] When this invention is used for cutting Aj and M alloys,
The present invention relates to a surface-coated cutting tip with a breaker, which exhibits excellent adhesion resistance to these cutting chips and, as a result, exhibits excellent wear resistance over a long period of time.

〔従来の技術〕[Conventional technology]

従来、一般に、A1および試合金の切削には1重量−で
(以下−は重量−を示す)、Co:4〜6%を含有し、
さらに必要に応じてTi、Ta、およびNbの炭化物お
よび窒化物(以下、 (Ti、 Ta、 Nb )C・
Nで示す)のうちの1種または2種以上=0.5〜3、
5 %を含有し、残シが炭化タングステン(以下weで
示す)と不可避不純物からなる組成を有するWCC超超
硬合金構成され、かつ切刃のすくい面に15゜〜18°
のすくい角でブレーカ−が形成された切削チップが用い
られている。
Conventionally, in general, for cutting A1 and match gold, 1 weight - (hereinafter - indicates weight) contains Co: 4 to 6%,
Furthermore, carbides and nitrides of Ti, Ta, and Nb (hereinafter, (Ti, Ta, Nb)C.
one or more of the following (indicated by N) = 0.5 to 3,
5%, the remainder is composed of tungsten carbide (hereinafter referred to as we) and unavoidable impurities, and the rake face of the cutting edge is 15° to 18°.
A cutting tip with a breaker formed at a rake angle is used.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし、上記の従来切削チップにおいては、Alおよび
Al合金の切削時に発生した切削屑が切刃のすくい面に
溶着し、かつこれの溶着刃はきわめて強く、この結果切
削中に溶着し九切削屑がすくい面から剥がされる時に、
切刃の一部をもぎ去り。
However, with the conventional cutting tips mentioned above, cutting chips generated during cutting of Al and Al alloys are welded to the rake face of the cutting edge, and the welded edges are extremely strong, resulting in welding during cutting. When it is peeled off from the rake surface,
Remove part of the cutting edge.

ミクロのチッピングとなることから、比較的短かい使用
寿命しか示さないのが現状である。
Currently, it only has a relatively short service life due to micro-chipping.

〔課題を解決するための手段〕[Means to solve the problem]

そこで1本発明者等は、上述のような観点から。 Therefore, the inventors of the present invention, etc., from the above-mentioned viewpoint.

AlおよびAl合金を切削し九場合に、切削屑の切刃す
くい面への溶着かなく、すぐれた耐摩耗性を示す切削チ
ップを開発すべく、特に上記の従来切削チップに着目し
研究を行なった結果、従来切削チップにおけるWCC超
超硬合金基体Co含有量な0.5〜3.5 ’IIに低
減すると共に、切刃のすくい面に形成されるブレーカー
のすくい角を一段と大きい20゜〜35°とし、かつ切
削チップの表面に1通常の化学蒸着法を用い、ダイヤモ
ンド被覆層を形成すると1AlおよびAl合金切削層の
切刃すくい面への溶着が著しく抑制されるようになって
、ミクロチッピングの発生がなくなり、さらに上記基体
にrs。
In order to develop a cutting tip that exhibits excellent wear resistance without welding of cutting chips to the rake surface of the cutting edge when cutting Al and Al alloys, we conducted research with a particular focus on the conventional cutting tips mentioned above. As a result, the Co content of the WCC cemented carbide base material in conventional cutting inserts was reduced to 0.5 to 3.5'II, and the rake angle of the breaker formed on the rake face of the cutting edge was increased to 20° to 20°. 35°, and a diamond coating layer is formed on the surface of the cutting tip using a normal chemical vapor deposition method, the adhesion of the Al and Al alloy cutting layer to the rake surface of the cutting edge is significantly suppressed, and the micro- The occurrence of chipping is eliminated, and the above substrate is further coated with rs.

(InternalonatStandarizati
on Organization)規格でC01〜CO
Sの微量の遊離炭素を均一に分散含有させておくと、こ
れの表面に形成されるダイヤモンド被覆層の密着性が一
段と向上するよう罠なって、よシー層の使用寿命の延命
化がはかれるようになるという知見を得たのである。
(Internal standard)
on Organization) standard C01~CO
By uniformly dispersing a small amount of free carbon in S, it becomes a trap that further improves the adhesion of the diamond coating layer formed on the surface, thereby extending the service life of the diamond coating layer. We have obtained the knowledge that

この発明は、上記知見にもとづいてなされたものであっ
て。
This invention was made based on the above findings.

Co  二  0.5 〜3.5  To  hを含有
し、さらに必要に応じて。
Contains Co 2 0.5 to 3.5 To h, and further if necessary.

(a)ISO規格でCO1〜C08の微量の遊離炭素。(a) Trace amounts of free carbon from CO1 to CO8 according to ISO standards.

fbJ  (Ti、 Ta、 Nb) C−Nのうちの
1種または2種以上:0.5〜3.51s。
fbJ (Ti, Ta, Nb) One or more of CN: 0.5 to 3.51 s.

以上(alおよび(b)のいずれか、あるいは両方゛を
含有し、残シがweと不可避不純物からなる組成(上記
遊離炭素を含有する場合には、遊離炭素が微細均一に分
散した組織をもつようになる)を有するWCC超超硬合
金基体の表面に、ダイヤモンド被覆層を形成し、かつ切
刃のすくい面に形成されたブレーカーのすくい角を20
@〜35°としたAlおよびAl合金切削用ブレーカ−
付表面被覆切削チップに特徴を有するものである。
A composition containing either or both of the above (al and (b)), with the remainder consisting of we and unavoidable impurities (if it contains the above free carbon, it has a structure in which the free carbon is finely and uniformly dispersed). A diamond coating layer is formed on the surface of the WCC cemented carbide base material, and the rake angle of the breaker formed on the rake face of the cutting edge is set to 20.
Breaker for cutting Al and Al alloys at ~35°
It is characterized by a surface-coated cutting tip.

つぎに、この発明の切削チップにおいて、基体の成分組
成、およびブレーカ−のすくい角を上記の通りに限定し
た理由を説明する。
Next, in the cutting tip of the present invention, the composition of the base and the reason why the rake angle of the breaker is limited as described above will be explained.

(a)  Co含有量 CO酸成分、結合相を形成し、基体の靭性な向上させる
作用をもつが、その含有量がCL 5%未満では所望の
靭性な確保することができず、切刃に欠損が発生し易く
なり、一方その含有量が3.5%を越えると、Alおよ
びAl合金切削屑が溶着し易くなるtlか、ダイヤモン
ド被覆層の密着性が低下するようになることから、その
含有量を0,5〜3.5 %と定めた。
(a) Co content CO acid component forms a binder phase and has the effect of improving the toughness of the substrate, but if the content is less than 5% CL, the desired toughness cannot be secured and the cutting edge On the other hand, if the content exceeds 3.5%, the adhesion of the diamond coating layer will decrease, and the adhesion of the diamond coating layer will decrease. The content was set at 0.5-3.5%.

(b)  遊離炭素含有量 遊離炭素には、基体表面に蒸着したダイヤモンドの黒鉛
化を阻止すると共に、これの基体への密着性を一段と向
上させる作用があるので、必要に応じて含有されるが、
その含有割合がrsoで001未満では前記作用に所望
の効果が得られず。
(b) Free carbon content Free carbon has the effect of preventing graphitization of diamond deposited on the surface of the substrate and further improving its adhesion to the substrate, so it may be included as necessary. ,
If the content ratio is less than 001 in terms of rso, the desired effect cannot be obtained.

一方その含有割合が同COSを越えると基体の靭性が低
下するようになることから、その含有割合をISO規格
でC’O1〜C08の微景とした。
On the other hand, if the content exceeds the same COS, the toughness of the substrate will decrease, so the content is defined as C'O1 to C08 according to the ISO standard.

(c)  (Ti、 Ta、 Nb ) C−N(Ti
、 Ta、 Nb )C−Nには、基体の硬さを高め。
(c) (Ti, Ta, Nb) C-N(Ti
, Ta, Nb) For C-N, increase the hardness of the base.

耐摩耗性を向上させる作用があるので必要に応じて含有
されるが、その含有量が0.5 %未満では前記作用に
所望の効果が得られず、一方その含有量が3.5%を越
えると、靭性が低下し、切刃にチッピングが発生し易く
なることから、その含有量を0、5〜3.5%と定めた
It is included as necessary because it has the effect of improving wear resistance, but if the content is less than 0.5%, the desired effect cannot be obtained; on the other hand, if the content is less than 3.5%, If it exceeds the content, the toughness decreases and chipping is likely to occur on the cutting edge, so the content was set at 0.5 to 3.5%.

(dl  ブレーカ−のすくい角 そのすくい角が20°未満では、切削屑の流れがスムー
ズに行かず、溶層が起シ易くなシ、ダイヤモンド被覆層
に剥離が生じるようKなり、一方そのすくい角が35°
を越えると、切刃に欠損が発生し易くなることから、ブ
レーカ−のすくい角を20゜〜35°と定めた。
(dl Rake angle of the breaker If the rake angle is less than 20°, the flow of cutting chips will not go smoothly, a melt layer will easily occur, and the diamond coating layer will peel off. On the other hand, the rake angle is 35°
The rake angle of the breaker was set at 20° to 35° because if the angle exceeds 20°, the cutting edge is likely to be damaged.

〔実施例〕〔Example〕

つぎに、この発明の切削チップを実施例により具体的に
説明する。
Next, the cutting tip of the present invention will be specifically explained using examples.

原料粉末として、いずれもO18〜3.2μ冨の範囲内
の平均粒径な有するWC粉末、 TaC粉末。
As raw material powders, WC powder and TaC powder both have an average particle size within the range of O18 to 3.2 μm.

NbC粉末、TiN粉末、 TaN粉末、 N1)N粉
末、(W、Ti)・C粉末、およびCOC粉末用意し、
さらに微細なカーボンブラックを用意し、これら原料粉
末を所定の配合組成に配合し、混合した後、圧粉体にプ
レス成形し、この圧粉体のうち、 Co配合量が2−以
上のものは真空中、温度:1460℃に2時間保持の条
件で焼結し、またCo配合量が2チ未滴のものは、真空
中、温度:1460℃に1時間保持の条件で焼結し、さ
らに1400℃でHIP処理を行なって、それぞれ第1
表に示される成分組成をもった基体素材とし、この基体
素材に研磨加工にて同じく第1表に示されるすくい角の
ブレーカ−を形成して基体とし、引続いてこれら基体K
Prepare NbC powder, TiN powder, TaN powder, N1)N powder, (W, Ti)・C powder, and COC powder,
Furthermore, finer carbon black is prepared, and these raw material powders are blended into a predetermined composition, mixed, and then press-molded into a green compact. Sintered in a vacuum at a temperature of 1460°C for 2 hours, and those containing less than 2 drops of Co were sintered in a vacuum at a temperature of 1460°C for 1 hour, and then HIP treatment was performed at 1400°C, and the first
A base material having the composition shown in the table is used, a breaker with a rake angle also shown in Table 1 is formed on this base material by polishing, and then these base materials are
.

熱電子放射材法を用い、基体表面から3cIt離れて置
かれた金属タングステンフィラメントを2000℃に加
熱し、C)f4とH2(D混合反応ガス(cH4/H2
:容量比でl/99)を炉内圧力を20 torrに保
持しながら、 300 dlmの割合で導入し、気相析
出反応をそれぞれ所定時間行なわしめて、第1表に示さ
れる平均層厚のダイヤモンド層を形成することKよって
本発明ブレーカ−付表面被覆切削チップ(以下本発明被
覆チップという)1〜20および比較ブレーカ−付表面
被覆切削チップ(以下比較被覆チップという)l−4を
それぞれ製造した。
Using the thermionic emitter method, a metallic tungsten filament placed 3 cIt away from the substrate surface was heated to 2000°C, and C) f4 and H2 (D mixed reaction gas (cH4/H2
: 1/99 in volume ratio) was introduced at a rate of 300 dlm while maintaining the pressure in the furnace at 20 torr, and the vapor phase precipitation reaction was carried out for a predetermined period of time to produce diamond with the average layer thickness shown in Table 1. By forming a layer, surface-coated cutting chips with a breaker of the present invention (hereinafter referred to as the present invention coated chip) 1 to 20 and comparative surface-coated cutting chips with a breaker (hereinafter referred to as the comparative coated chip) 1-4 were manufactured, respectively. .

なお、比較被覆チップ1〜4は、いずれも成分組成およ
びブレーカ−のすくい角のうちのいずれかの条件(第1
表で東部を付した条件)がこの発明の範囲から外れたも
のである。
In addition, comparative coated chips 1 to 4 were all tested under one of the conditions of component composition and rake angle of the breaker (first
Conditions marked with "Eastern" in the table) are outside the scope of this invention.

また、比較の目的で、切削チップの成分組成およびブレ
ーカーのすくい角を第1表に示されるものとし、かつダ
イヤモンド被覆層の形成を行なわない以外は同一の条件
で従来ブレーカ−付切削チップ(以下従来チップという
)l−4を製造した。
For comparison purposes, the chemical composition of the cutting tip and the rake angle of the breaker were as shown in Table 1, and a conventional cutting tip with a breaker (hereinafter referred to as A conventional chip (referred to as conventional chip) l-4 was manufactured.

ついで、これらの各種のチップについて。Next, let's talk about these various chips.

被削材: AM −11%8i合金。Work material: AM-11% 8i alloy.

切削速度: 500 */m、送1) : O,1si
a*/rev、。
Cutting speed: 500 */m, feed 1): O, 1si
a*/rev,.

切込み=2B。Depth of cut = 2B.

の条件でM合金の連続乾式切削試験を行ない、使用寿命
に至るまでの切削時間を測定すると共K。
A continuous dry cutting test was conducted on M alloy under the following conditions, and the cutting time until the end of its service life was measured.

試験後の切刃の状態を観察し、第1表に示した。The state of the cutting edge after the test was observed and is shown in Table 1.

〔発明の効果〕〔Effect of the invention〕

第1表に示される結果から1本発明被覆チップ1〜20
は、いずれもM合金切削屑に対してすぐれた耐溶着性を
示し、かつダイヤモンド被覆層のもつすぐれた耐摩耗性
と含まって著しく長い切削寿命を示すのに対して、従来
チップ1〜4では。
From the results shown in Table 1, 1 coated chips of the present invention 1 to 20
In contrast, conventional chips 1 to 4 have excellent adhesion resistance against M alloy cutting chips and a significantly long cutting life due to the excellent wear resistance of the diamond coating layer. Well then.

M合金切削層の切刃ブレーカ−面への溶着が著しく、こ
れが原因でミクロチッピングを起し、短かい切削寿命し
か示さず、また比較被覆チップ1〜番に見られるように
、基体の成分組成あるいはブレーカーのすくい角のいず
れでも、この発明の範囲から外れると、所望の切削寿命
を示さないことが明らかである。
The welding of the M alloy cutting layer to the cutting edge breaker surface is significant, which causes microchipping and shows only a short cutting life. It is clear that if the rake angle of the breaker is outside the scope of the present invention, the desired cutting life will not be exhibited.

上述のように、この発明のブレーカー付表面被覆切削チ
ップは、特にAlおよびAl合金の切削に用いた場合に
、著しく長期に亘ってすぐれた切削性能を発揮するので
ある。
As mentioned above, the surface-coated cutting tip with a breaker of the present invention exhibits excellent cutting performance over a long period of time, especially when used for cutting Al and Al alloys.

Claims (4)

【特許請求の範囲】[Claims] (1)Co:0.5〜3.5重量%を含有し、残りが炭
化タングステンと不可避不純物からなる組成を有する炭
化タングステン基超硬合金の基体の表面に、ダイヤモン
ド被覆層を形成し、かつ切刃のすくい面に形成されたブ
レーカーのすくい角を20゜〜35゜としたことを特徴
とするAlおよびAl合金切削用ブレーカー付表面被覆
切削チップ。
(1) A diamond coating layer is formed on the surface of a tungsten carbide-based cemented carbide substrate containing 0.5 to 3.5% by weight of Co, with the remainder consisting of tungsten carbide and unavoidable impurities, and A surface-coated cutting tip with a breaker for cutting Al and Al alloys, characterized in that the rake angle of the breaker formed on the rake face of the cutting blade is 20° to 35°.
(2)Co:0.5〜3.5重量%、およびISO規格
でC01〜C08の微量の遊離炭素を含有し、残りが炭
化タングステンと不可避不純物からなる組成、並びに上
記遊離炭素が微細均一に分散した組織を有する炭化タン
グステン基超硬合金の基体の表面に、ダイヤモンド被覆
層を形成し、かつ切刃のすくい面に形成されたブレーカ
ーのすくい角を20゜〜35゜としたことを特徴とする
AlおよびAl合金切削用ブレーカー付表面被覆切削チ
ップ。
(2) Co: 0.5 to 3.5% by weight, and contains a trace amount of free carbon of C01 to C08 according to ISO standards, with the remainder consisting of tungsten carbide and unavoidable impurities, and the free carbon is fine and uniform. A diamond coating layer is formed on the surface of a tungsten carbide-based cemented carbide base body having a dispersed structure, and the rake angle of the breaker formed on the rake face of the cutting blade is 20° to 35°. Surface-coated cutting tip with breaker for cutting Al and Al alloys.
(3)Co:0.5〜3.5重量%を含有し、さらにT
i、Ta、およびNbの炭化物および窒化物のうちの1
種または2種以上:0.5〜3.5重量%を含有し、残
りが炭化タングステンと不可避不純物からなる組成を有
する炭化タングステン基超硬合金の基体の表面に、ダイ
ヤモンド被覆層を形成し、かつ切刃のすくい面に形成さ
れたブレーカーのすくい角を20゜〜35゜としたこと
を特徴とするAlおよびAl合金切削用ブレーカー付表
面被覆切削チップ。
(3) Contains Co: 0.5 to 3.5% by weight, and further contains T
one of carbides and nitrides of i, Ta, and Nb
Forming a diamond coating layer on the surface of a tungsten carbide-based cemented carbide substrate containing 0.5 to 3.5% by weight of one or more species, with the remainder consisting of tungsten carbide and unavoidable impurities; A surface-coated cutting tip with a breaker for cutting Al and Al alloys, characterized in that the breaker formed on the rake face of the cutting edge has a rake angle of 20° to 35°.
(4)Co:0.6〜3.5重量%、およびISO規格
で、C01〜C08の微量の遊離炭素を含有し、さらに
Ti、Ta、およびNbの炭化物および窒化物のうちの
1種または2種以上:0.5〜3.5重量%を含有し、
残りが炭化タングステンと不可避不純物からなる組成、
並びに上記遊離炭素が微細均一に分散した組織を有する
炭化タングステン基超硬合金の表面に、ダイヤモンド被
覆層を形成し、かつ切刃のすくい面に形成されたブレー
カーのすくい角を20゜〜35゜としたことを特徴とす
るAlおよびAl合金切削用ブレーカー付表面被覆切削
チップ。
(4) Co: 0.6 to 3.5% by weight, and contains a trace amount of free carbon of C01 to C08 according to ISO standards, and further contains one of carbides and nitrides of Ti, Ta, and Nb or Two or more types: Contains 0.5 to 3.5% by weight,
The remainder consists of tungsten carbide and unavoidable impurities,
In addition, a diamond coating layer is formed on the surface of the tungsten carbide-based cemented carbide having a structure in which free carbon is finely and uniformly dispersed, and the rake angle of the breaker formed on the rake face of the cutting blade is set to 20° to 35°. A surface-coated cutting tip with a breaker for cutting Al and Al alloys.
JP63053265A 1988-03-07 1988-03-07 A-l and A-l alloy surface cutting tip with a breaker for cutting alloys Expired - Lifetime JP2556086B2 (en)

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JPH01228703A true JPH01228703A (en) 1989-09-12
JP2556086B2 JP2556086B2 (en) 1996-11-20

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03197664A (en) * 1989-12-26 1991-08-29 Toshiba Tungaloy Co Ltd High-toughness coated sintered hard alloy and its production
GB2363390A (en) * 2000-06-15 2001-12-19 Leica Microsystems Knife with blade of artificial diamond
WO2015075829A1 (en) * 2013-11-25 2015-05-28 オーエスジー株式会社 Diamond-coated super hard tool
CN110527891A (en) * 2019-09-16 2019-12-03 东华大学 Diamond coating on low-cobalt hard alloy surface and preparation method thereof
CN115011917A (en) * 2022-05-18 2022-09-06 湖南工业职业技术学院 Diamond particle surface modification method based on vacuum thermal evaporation

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5748405A (en) * 1980-09-03 1982-03-19 Nippon Oil & Fats Co Ltd Cutting tool

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5748405A (en) * 1980-09-03 1982-03-19 Nippon Oil & Fats Co Ltd Cutting tool

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03197664A (en) * 1989-12-26 1991-08-29 Toshiba Tungaloy Co Ltd High-toughness coated sintered hard alloy and its production
GB2363390A (en) * 2000-06-15 2001-12-19 Leica Microsystems Knife with blade of artificial diamond
GB2363390B (en) * 2000-06-15 2003-01-22 Leica Microsystems Knife
WO2015075829A1 (en) * 2013-11-25 2015-05-28 オーエスジー株式会社 Diamond-coated super hard tool
CN110527891A (en) * 2019-09-16 2019-12-03 东华大学 Diamond coating on low-cobalt hard alloy surface and preparation method thereof
CN110527891B (en) * 2019-09-16 2021-11-02 东华大学 Diamond coating on the surface of low cobalt cemented carbide and preparation method thereof
CN115011917A (en) * 2022-05-18 2022-09-06 湖南工业职业技术学院 Diamond particle surface modification method based on vacuum thermal evaporation

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