JPH01139511A - Production of composition containing chlorinated isocyanuric acid having high compounding stability - Google Patents
Production of composition containing chlorinated isocyanuric acid having high compounding stabilityInfo
- Publication number
- JPH01139511A JPH01139511A JP29901387A JP29901387A JPH01139511A JP H01139511 A JPH01139511 A JP H01139511A JP 29901387 A JP29901387 A JP 29901387A JP 29901387 A JP29901387 A JP 29901387A JP H01139511 A JPH01139511 A JP H01139511A
- Authority
- JP
- Japan
- Prior art keywords
- isocyanuric acid
- chlorinated isocyanuric
- sodium
- mesh
- granules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 150000007973 cyanuric acids Chemical class 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 238000013329 compounding Methods 0.000 title 1
- 239000008187 granular material Substances 0.000 claims abstract description 15
- 150000001447 alkali salts Chemical class 0.000 claims abstract description 11
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 7
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 6
- 235000011151 potassium sulphates Nutrition 0.000 claims abstract description 6
- 238000007906 compression Methods 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 7
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005469 granulation Methods 0.000 abstract description 2
- 230000003179 granulation Effects 0.000 abstract description 2
- 238000007873 sieving Methods 0.000 abstract description 2
- 229950009390 symclosene Drugs 0.000 abstract description 2
- 238000000748 compression moulding Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 abstract 1
- -1 chlorinated isocyanuric acid compound Chemical class 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- UNWRHVZXVVTASG-UHFFFAOYSA-N 1,3-dichloro-1,3,5-triazinane-2,4,6-trione;sodium Chemical compound [Na].ClN1C(=O)NC(=O)N(Cl)C1=O UNWRHVZXVVTASG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- IFIDXBCRSWOUSB-UHFFFAOYSA-M potassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate Chemical compound [K+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
この発明は殺菌、消毒性能を有する洗浄剤の使用に好適
な顆粒状塩素化イソシアヌル酸含有組成物の製法に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application This invention relates to a method for producing a granular chlorinated isocyanuric acid-containing composition suitable for use as a cleaning agent having sterilizing and disinfecting properties.
塩素化イソシアヌル酸及びそのアルカリ塩は洗浄剤組成
物のようなアルカリ性の雰囲気、特にソーダ灰や、苛性
ソーダ、メタ硅酸ナトリウムの接触あるいはアニオン、
カチオン、ノニオンなどの界面活性剤との接触により比
較的短期のうちに活性塩素が消失する欠陥があった。Chlorinated isocyanuric acid and its alkali salts are used in alkaline atmospheres such as detergent compositions, especially in contact with soda ash, caustic soda, sodium metasilicate, or anions.
There was a defect that active chlorine disappeared in a relatively short period of time due to contact with surfactants such as cations and nonions.
本発明者等はこのような難点を克服するために、既に顆
粒状に成型されたジクロロイソシアヌル酸ナトリウムに
有機高分子化合物を含有する水溶液を接触して造ったジ
クロロイソシアヌル酸ナトリウム水和物を用いることを
提案した。（特公昭６１−３６８３２号公報）
発明が解決しようとする問題点
しかしながら、塩素化イソシアヌル酸化合物に有機高分
子化合物をコーティングした前記顆粒状組成物は、塩素
化イソシアヌル酸化合物と有機高分子化合物との間で徐
々に反応が進行し、その活性塩素が消化されて長期間の
保存ができない難点があった。In order to overcome these difficulties, the present inventors used sodium dichloroisocyanurate hydrate, which was produced by contacting sodium dichloroisocyanurate, which had already been formed into granules, with an aqueous solution containing an organic polymer compound. I suggested that. (Japanese Patent Publication No. 61-36832) Problems to be Solved by the Invention However, the above-mentioned granular composition in which a chlorinated isocyanuric acid compound is coated with an organic polymer compound has a problem in that the chlorinated isocyanuric acid compound and the organic polymer compound are coated together. The problem was that the reaction progressed gradually between the two, and the active chlorine was digested, making it impossible to store it for a long time.
問題点を解決するための手段
本発明者等は、このような事情に鑑み克明な試験を重ね
た結果、−船釣に用いられている洗浄剤成分のなかで、
トリポリ燐酸ナトリウム、テトラポリ燐酸ナトリウム、
硫酸ナトリウム及び硫酸カリは、塩素化イソシアヌル酸
に対し全く不活性であり、これらと塩素化イソシアヌル
酸化合物を配合したものは長期に亘って安定であること
を知見し、６０メツシュ篩を通過する大きさの塩素化イ
ソシアヌル酸またはそのアルカリ塩に、３５メツシュ篩
を通過するトリポリ燐酸ナトリウム、テトラポリ燐酸ナ
トリウム、硫酸ナトリウムまたは硫酸カリウムから選ば
れる水溶性無機塩を５重量％ないし９０重量％の割合で
均一に混合し、これを圧縮成形したのち破砕、篩分して
１２メツシュないし６０メツシュの大きさの顆粒とする
ことによって、所期の目的を達成したものである。Means to Solve the Problems In view of the above circumstances, the inventors of the present invention have conducted thorough tests and found that - Among the cleaning agent components used for boat fishing,
Sodium tripolyphosphate, sodium tetrapolyphosphate,
It was discovered that sodium sulfate and potassium sulfate are completely inert to chlorinated isocyanuric acid, and that a mixture of these and a chlorinated isocyanuric acid compound is stable over a long period of time. A water-soluble inorganic salt selected from sodium tripolyphosphate, sodium tetrapolyphosphate, sodium sulfate, or potassium sulfate that passes through a 35-mesh sieve is uniformly added to the chlorinated isocyanuric acid or its alkali salt in a proportion of 5% to 90% by weight. The desired purpose was achieved by mixing the mixture into granules, compressing it, crushing it, and sieving it into granules with a size of 12 to 60 meshes.
本発明方法において用いる塩素化イソシアヌル酸または
そのアルカリ塩としては、トリクロロイソシアヌル酸、
シクロロイシアヌル酸ナトリウム塩及びその１水和物並
びに２水和物、ジクロロイソシアヌル酸カリウムが代表
的なものであり、これらの大きさは顆粒の内部に均一に
分散させるために６０メツシュ以下の粒径とすべきであ
る。The chlorinated isocyanuric acid or its alkali salt used in the method of the present invention includes trichloroisocyanuric acid,
Typical examples include sodium cycloleucyanurate, its monohydrate and dihydrate, and potassium dichloroisocyanurate, and the size of these particles is 60 mesh or less in order to uniformly disperse them inside the granules. It should be the diameter.
本発明方法において使用する水溶性無機塩類としては、
トリポリ燐酸ナトリウム、テトラポリ燐酸ナトリウム、
硫酸ナトリウム、硫酸カリウムであり、塩化ナトリウム
は塩素化イソシアヌル酸と反応するので好ましくない。The water-soluble inorganic salts used in the method of the present invention include:
Sodium tripolyphosphate, sodium tetrapolyphosphate,
These are sodium sulfate and potassium sulfate, and sodium chloride is not preferred because it reacts with chlorinated isocyanuric acid.
本発明において用いる水溶性無機塩類は、塩素化イソシ
アヌル酸化合物との配合性を高めるために、３５メツシ
ュ以下の粒度とすべきである。The water-soluble inorganic salt used in the present invention should have a particle size of 35 mesh or less in order to improve compatibility with the chlorinated isocyanuric acid compound.
本発明の実施において、塩素化イソシアヌル酸化合物に
対する前記水溶性無機塩類の配合比率が多くなれば、顆
粒表面の塩素化イソシアヌル酸またはそのアルカリ塩が
少なくなり、洗浄剤組成物に配合した際の塩素安定性が
向上するが、顆粒物中の活性塩素が抵下するので９０重
量％までの範囲に留めるべきである。In the practice of the present invention, if the blending ratio of the water-soluble inorganic salts to the chlorinated isocyanuric acid compound increases, the amount of chlorinated isocyanuric acid or its alkali salt on the surface of the granules will decrease, and the amount of chlorine added to the cleaning composition will decrease. Although stability is improved, active chlorine in the granules is reduced, so the content should be kept within a range of up to 90% by weight.
また水溶性無機塩類の配合比率が５重量％より少ない範
囲では洗剤組成物中での安定性が改善されない。Furthermore, if the blending ratio of water-soluble inorganic salts is less than 5% by weight, the stability in the detergent composition will not be improved.
本発明における顆粒化は、不安定な塩素化イソシアヌル
酸またはそのアルカリ塩を安定な無機塩の内部に閉じ込
め、分離しないようにするためのものであり、顆粒物の
硬度はあまり問題としない。The granulation in the present invention is to confine unstable chlorinated isocyanuric acid or its alkali salt inside a stable inorganic salt and prevent it from separating, and the hardness of the granules does not matter much.
従って、加圧成形品の破砕時、歩留まりがあまり悪くな
らない範囲の圧縮圧力でよく、通常１５０ｋｇ／ｃｒＡ
ないし２０００ｋｇ／ＣＩＩＮの面圧が適当であり、ま
た二つの回転ロール間で加圧する場合は１４００ｋｇ／
Ｃｍ±５０％の圧力が適している。Therefore, when crushing a pressure-molded product, the compression pressure may be within a range that does not significantly deteriorate the yield, and is usually 150 kg/crA.
A surface pressure of 2000kg/CIIN to 2000kg/CIIN is appropriate, and 1400kg/CIIN when applying pressure between two rotating rolls.
A pressure of Cm±50% is suitable.
破砕により得られる顆粒の粒子は大きいほど比表面積が
小さく、洗浄剤の安定性が優れるので、篩分けによって
１２メツシュないし６０メツシュの範囲として、洗剤や
他のビルグーとの配合性を保つことが望ましい。The larger the particles of the granules obtained by crushing, the smaller the specific surface area, and the better the stability of the detergent. Therefore, it is desirable to sieve the granules to a range of 12 to 60 mesh to maintain compatibility with detergents and other virgoos. .
作用
本発明方法によって製造された顆粒状塩素化イソシアヌ
ル酸またはそのアルカリ塩を含有する組成物が洗浄剤中
で極めて安定となる理由は、塩素化イソシアヌル酸また
はそのアルカリ塩を、活性塩素に対して不活性な無機塩
中に独立して分散させることにより、塩素化イソシアヌ
ル酸化合物に対して活性な他の配合成分との接触による
分解が顆粒の表面部のみで起こり、無機塩に遮断されて
内部まで連鎖的に移行しないためと考えられる。Effect The reason why the composition containing granular chlorinated isocyanuric acid or its alkali salt produced by the method of the present invention is extremely stable in detergents is that the composition containing granular chlorinated isocyanuric acid or its alkali salt is By independently dispersing the chlorinated isocyanuric acid compound in an inert inorganic salt, decomposition due to contact with other ingredients active against the chlorinated isocyanuric acid compound occurs only on the surface of the granules, and is blocked by the inorganic salt and disintegrates inside the granules. This is thought to be because there is no chain reaction.
また本発明方法によって、かねてより可燃性とされてい
たジクロロイソシアヌル酸ナトリウム及びカリウム塩も
、自己消失性となり、大量の貯蔵及び使用、輸送におい
て火災による危険性を大幅に減少しうるちのである。Furthermore, by the method of the present invention, dichloroisocyanuric acid sodium and potassium salts, which have long been thought to be flammable, become self-disappearing, which can greatly reduce the risk of fire during storage, use, and transportation in large quantities.
参考例１
洗浄剤組成物として一般的に用いられている無機化合物
９０重量部との塩素化イソシアヌル酸化合物１０重量部
を混合し、その配合物５ｇを３０ｍ ｌのサンプル瓶に
採り、５０μのＰＥフィルムで蓋をしたのち、４０’Ｃ
，ＲＨ８５％の恒温恒温下に６週間放置して活性塩素の
低下率を調べたところ、第１表に示した結果かえられ、
特にトリポリ燐酸ナトリウム、テトラポリ燐酸ナトリウ
ム、硫酸ナトリウム及び硫酸カリウムとの配合安定性が
良いものと認められた。Reference Example 1 10 parts by weight of a chlorinated isocyanuric acid compound was mixed with 90 parts by weight of an inorganic compound commonly used as a cleaning composition, 5 g of the mixture was placed in a 30 ml sample bottle, and 50 μm of PE was added. After covering with film, heat at 40'C.
, The rate of decrease in active chlorine was investigated by leaving it at a constant temperature of 85% RH for 6 weeks, and the results shown in Table 1 were changed.
In particular, it was recognized that the combination stability with sodium tripolyphosphate, sodium tetrapolyphosphate, sodium sulfate, and potassium sulfate was good.
第１表
参考例２
メタ硅酸ソーダ５水塩３５部、トリポリ燐酸ソーダ３０
部、炭酸ナトリウム１５部、硫酸ナトリウム１゜部、ノ
ニオン界面活性剤（花王アトラス製ｐｐ２３０ ’）１
部及び１４〜６０メツシュの粒径をもつ顆粒状塩素化イ
ソシアヌル酸又はそのアルカリ金属塩９部を均一に混合
し、その配合物５ｇを採り参考例１と同一条件で２ケ月
放置し、活性塩素の減少率を測定した結果は第２表のと
おりであった。Table 1 Reference Example 2 Sodium metasilicate pentahydrate 35 parts, sodium tripolyphosphate 30
1 part, sodium carbonate 15 parts, sodium sulfate 1 part, nonionic surfactant (Kao Atlas pp230') 1 part
and 9 parts of granular chlorinated isocyanuric acid or its alkali metal salt having a particle size of 14 to 60 mesh were mixed uniformly, 5 g of the mixture was taken, and left to stand for 2 months under the same conditions as in Reference Example 1. The results of measuring the rate of decrease are shown in Table 2.
＊ 特公昭６１−３６８３２号公報実施例１．実験番号
６の方法によるもの
実施例
６０メツシュ以下の塩素化イソシアヌル酸またはそのア
ルカリ金属塩に対し水溶性無機塩の割合を変えて混合し
、回転する２つのロール間に供給し、１５００ｋｇ ／
ＣＩの圧力で圧縮し、これを破砕して１４〜６０メツ
シュの顆粒に篩分けし、参考例２の方法と同様にして洗
剤配合組成物中で２ケ月後の活性塩素の減少率を調べた
ところ、第３表に示した結果かえられた。*Example 1 of Japanese Patent Publication No. 61-36832. According to the method of Experiment No. 6 Example 60 mesh or less of chlorinated isocyanuric acid or its alkali metal salt was mixed with varying proportions of water-soluble inorganic salt, and fed between two rotating rolls, 1500 kg/
It was compressed under the pressure of CI, crushed and sieved into granules of 14 to 60 meshes, and the reduction rate of active chlorine in the detergent formulation composition after 2 months was examined in the same manner as in Reference Example 2. However, the results shown in Table 3 were changed.
Claims (1)
酸またはそのアルカリ塩に、３５メッシュ篩を通過する
トリポリ燐酸ナトリウム、テトラポリ燐酸ナトリウム、
硫酸ナトリウムまたは硫酸カリウムから選ばれる水溶性
無機塩を５重量％ないし９０重量％の割合で均一に混合
し、これを圧縮成形したのち破砕、篩分して１２メッシ
ュないし６０メッシュの大きさの顆粒としたことを特徴
とする配合安定性の良い塩素化イソシアヌル酸含有組成
物の製法。Chlorinated isocyanuric acid or its alkali salt of a size that passes through a 60 mesh sieve, sodium tripolyphosphate, sodium tetrapolyphosphate, which passes through a 35 mesh sieve,
A water-soluble inorganic salt selected from sodium sulfate or potassium sulfate is uniformly mixed in a proportion of 5% to 90% by weight, and this is compression molded, then crushed and sieved to produce granules with a size of 12 mesh to 60 mesh. A method for producing a chlorinated isocyanuric acid-containing composition having good formulation stability.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29901387A JPH01139511A (en) | 1987-11-26 | 1987-11-26 | Production of composition containing chlorinated isocyanuric acid having high compounding stability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29901387A JPH01139511A (en) | 1987-11-26 | 1987-11-26 | Production of composition containing chlorinated isocyanuric acid having high compounding stability |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01139511A true JPH01139511A (en) | 1989-06-01 |
Family
ID=17867095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29901387A Pending JPH01139511A (en) | 1987-11-26 | 1987-11-26 | Production of composition containing chlorinated isocyanuric acid having high compounding stability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01139511A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7651628B2 (en) | 2003-08-06 | 2010-01-26 | Shikoku Chemicals Corporation | Compression molded product of effervescent chlorinated isocyanuric acid |
-
1987
- 1987-11-26 JP JP29901387A patent/JPH01139511A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7651628B2 (en) | 2003-08-06 | 2010-01-26 | Shikoku Chemicals Corporation | Compression molded product of effervescent chlorinated isocyanuric acid |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101424827B1 (en) | Chlorine dioxide based cleaner/sanitizer | |
| US7364669B2 (en) | Method for reducing reactivity of calcium hypochlorite | |
| CA1300341C (en) | Granular calcium hypochlorite composition and process for preparation thereof | |
| US2578270A (en) | Stable chlorinated melamine composition | |
| US7514019B2 (en) | Solvent-activated reactor including a gel layer | |
| JPS582400A (en) | Manufacture of solubility-improved powdery detergent | |
| US3213029A (en) | Granular compositions containing trichlorocyanuric acid | |
| JPH01139511A (en) | Production of composition containing chlorinated isocyanuric acid having high compounding stability | |
| US5230903A (en) | Chloroisocyanurate composition | |
| JP4356970B2 (en) | Fast-soluble chlorinated isocyanuric acid moldings | |
| JPS59219205A (en) | Production of expandable tablet | |
| JPS59155311A (en) | Production of foamed granules | |
| EP0394529B1 (en) | Chloroisocyanurate composition | |
| JPS6141487B2 (en) | ||
| JPS63130508A (en) | Calcium hypochlorite composition and production thereof | |
| JPS60112714A (en) | Production of foamable granular composition having storage stability | |
| CA1083917A (en) | Process for granulated water conditioner | |
| JPS6232747B2 (en) | ||
| JPS6412244B2 (en) | ||
| JPS6323812A (en) | Production of tablet | |
| JPH036142B2 (en) | ||
| JP2551409B2 (en) | Granular softener composition | |
| JPS60155505A (en) | Granular monoperoxosulfate and its manufacturing method | |
| JPS5951948B2 (en) | Rapidly disintegrating chlorinated isocyanuric acid molded product in water | |
| JPH0118903B2 (en) |