JPH09136818A - Aerosol type foamy oxidation hair dye composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain an aerosol type foamy oxidation hair dye composition, excellent in stability, good in foam conditions, having good hair dyeing power and hardly causing skin fouling. SOLUTION: The characteristic of this aerosol type foamy oxidation hair dye composition comprises a stock solution for the oxidation hair dye containing (A) 0.01-3wt.% higher alcohol, (B) 0.1-10wt.% nonionic surfactant, (C) 0.5-10wt.% solvent and (D) 72-95wt.% water at (97:3) to (93:7) weight ratio of the stock solution of the oxidation hair dye to a propellant in the aerosol type oxidation hair dye containing the oxidation hair dye.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oxidative hair dye composition, and more particularly to an aerosol foam oxidative hair dye composition having excellent stability, good foam condition and good hair dyeing power. .

[0002]

2. Description of the Related Art Conventionally, as a hair dye, a two-pack type oxidative hair dye comprising a first agent containing an oxidative dye intermediate and a second agent containing an oxidant has been widely used. This hair dye is one in which a colorless, low-molecular weight oxidative dye intermediate is permeated into the hair, and oxidative polymerization is carried out in the hair to generate a dye, thereby dyeing the hair. These oxidative hair dyes are capable of dyeing hair in various color tones as desired, and have very excellent hair dyeing power, and are generally widely used.

Further, in order to obtain good hair dyeing power, which is an advantage of these oxidative hair dyes, it is necessary to apply it uniformly on the entire hair, and therefore various dosage forms have been devised, liquid and cream. , Jelly-like products have been put on the market.

Further, a foam-like dosage form has been studied for easy and uniform application. Compared with conventional hair dyes, this aerosol type foam hair dye has simple operability such as easy ejection of a dyeing liquid at the push of a button, and deterioration of the oxidative dye due to no contact with outside air. It is also economically superior because it can be used over and over again.

[0005]

However, in the aerosol type foam hair oxidative hair dye, the total amount of application at the time of hair dyeing is reduced due to the volume of the foam, so that it is more sufficient than the conventional hair dye oxidant hair dye. As a solution to this problem, a new problem that the bubbles are scattered and the dye dripping occurs when the foam-breaking property on the hair is increased.

Regarding the aerosol foam hair dye, Japanese Patent Publication No. 58-30282 proposes an aerosol hair dye containing a surfactant and a solvent in a high concentration. However, in this method, since the foaming property at the time of application is low and a sufficient application amount cannot be obtained, good dyeing is not obtained as compared with the conventional hair dye, and a large amount of a surfactant is added. Therefore, there are drawbacks such as irritation of the scalp and a large change in viscosity over time.

[0007] Therefore, there is still nothing satisfying all of the hair dyeing power, dyeing finish, safety, foam condition and stability.
There was an urgent need to develop an aerosol foam hair dye that can solve these problems.

[0008]

[Means and Actions for Solving the Problems] As a result of intensive investigations, the present inventors have found that an oxidizing hair dye stock solution containing a specific amount of a higher alcohol, a nonionic surfactant, a solvent, and water has a specific ratio. It has been found that by adding a propellant to obtain an aerosol foam oxidation hair dye, a hair dye having excellent stability, good foam condition, and good hair dyeing power can be obtained. Furthermore, they have found the effect of less soiling on the background and have completed the present invention.

That is, according to the present invention, in the aerosol type oxidative hair dye containing an oxidative dye, the stock solution of the oxidative hair dye is 0.01 to 3% by weight of the component (A) higher alcohol and the component (B) nonionic. 0.1 to 10% by weight of a surface active agent, 0.5 to 10% by weight of a component (C) solvent and 72 to a component (D) water.
The present invention provides an aerosol-type oxidative hair dye composition in the form of aerosol, which contains 95% by weight and the ratio of the stock solution of oxidative hair dye and the propellant is 97: 3 to 93: 7.

The structure of the present invention will be described in detail below. Examples of the component (A) higher alcohol to be blended in the aerosol foam hair dye of the present invention include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, isostearyl alcohol,
Oleyl alcohol, 2-hexyldecanol and 2-
Octyldodecanol and the like, 1 type or 2
Mix and combine more than one type. Of these, straight chain higher saturated alcohols such as cetyl alcohol, stearyl alcohol, cetostearyl alcohol and behenyl alcohol are preferable from the viewpoint of hair dyeing power. The blending amount of the higher alcohol is 0.01 to 3% by weight, and if it is less than 0.01% by weight, good dyeing cannot be obtained, and when jetted to a comb or the like, the foam stability on the comb is poor, When applied to hair, bubbles tend to scatter. On the other hand, if it exceeds 3% by weight, when applied to the hair, bubbles are unlikely to be crushed, good dyeing is not obtained, and the viscosity changes with time. The lower limit of the blending amount is particularly preferably 0.1% by weight or more,
By blending 0.1% by weight or more, the foam stability after ejection is dramatically improved and liquid dripping does not occur. The upper limit is preferably 2.5% by weight, and when it exceeds 2.5% by weight, the improvement in foam stability is small.

The component (B) nonionic surfactant includes the following. 1. Polyoxyethylene (hereinafter abbreviated as POE) alkyl ether POE cetyl ether, POE stearyl ether, P
OE behenyl ether, POE oleyl ether, PO
1. E lauryl ether, etc. POE alkyl phenyl ether POE nonyl phenyl ether, POE octyl phenyl ether, etc. POE sorbitan fatty acid ester POE sorbitan monooleate, monostearic acid P
OE sorbitan, POE sorbitan monopalmitate,
POE sorbitan monolaurate, PO trioleate
E-sorbitan, etc. 4. 4. POE glyceryl monofatty acid ester, POE glycerin monostearate, POE glycerin monomyristic acid, etc. 5. POE sorbitol fatty acid ester POE sorbite tetraoleate, POE sorbite hexastearate, POE sorbite monolaurate, bee wax of POE sorbitol, etc. 6. Castor oil, hydrogenated castor oil derivatives POE hydrogenated castor oil, POE castor oil, etc. 7. POE fatty acid ester Polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate, etc. 8. Higher fatty acid glycerin ester Lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, self-emulsifying glyceryl monostearate, and the like. 9. Sorbitan fatty acid ester Sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, etc. 10. Lanolin derivatives POE lanolin, POE lanolin alcohol, POE sorbitol lanolin, etc. 11. Alkylolamide lauric acid diethanolamide, coconut oil fatty acid diethanolamide, etc. POE fatty acid amide POE stearic acid amide, etc. 13. 13. Sucrose fatty acid ester Alkylamine oxide Dimethyllaurylamine oxide, etc. These nonionic surfactants are blended alone or in combination of two or more. The blending amount of the nonionic surfactant is 0.1 to 10% by weight, and if it is less than 0.1% by weight, the foaming property is insufficient and the stability of the foam after jetting is poor when it is discharged onto a comb or the like. Bubbles may splash during application. On the other hand, if the amount exceeds 10% by weight, bubbles are not crushed when applied to hair, and good dyeing cannot be obtained. In addition, the change in viscosity with time may increase. The lower limit of the blending amount is particularly preferably 0.5% by weight or more, and 0.5% by weight
By blending the above components, the foam stability after ejection is dramatically improved and liquid dripping does not occur. The upper limit is 6% by weight
Is preferable, and when it exceeds 6% by weight, the improvement in dyeing is small.

A nonionic surfactant which is liquid at room temperature is particularly preferable because it can be dyed well, the stability of the foam, the foam breaking property and the viscosity stability can be obtained, and the background stain is reduced. As the nonionic surfactant which is liquid at room temperature, for example, POE having an addition mole number of oxyethylene of 40 or less.
Hydrogenated castor oil, POE octyl phenyl ether having 15 or less addition moles of oxyethylene, POE nonyl phenyl ether, POE stearylamine and POE oleylamine, P having 9 or less addition moles of oxyethylene
Examples thereof include OE oleyl ether, POE lauryl ether, and POE sorbitan fatty acid ester having 20 or less moles of oxyethylene added.

Examples of the solvent as the component (C) include ethanol, glycerin, diglycerin, propylene glycol, polyethylene glycol, 1,3-butanediol and polyoxypropylene diglyceryl ether. The blending amount is 0.5 to 10% by weight,
If it is less than 0.5% by weight, good dyeing cannot be obtained, and bubbles may scatter during application. If it exceeds 10% by weight, good dyeing cannot be obtained, which is not economical. The lower limit of the blending amount is particularly preferably 1% by weight or more, and by blending 1% by weight or more, dyeing is drastically improved and liquid dripping does not occur. 8 for the upper limit
% Is preferable, and when it exceeds 8% by weight, the improvement in dyeing is small.

The amount of the component (D) water blended greatly affects the hair dyeing power. The blending amount is 72 to 95% by weight, and when it is less than 72% by weight, the hair dyeing power is lowered, and when it exceeds 95% by weight, the penetrating power to hair is lowered and the hair dyeing power is remarkably lowered. Moreover, by adding the specific amount of the component (D) water and the above components (A), (B) and (C) in a specific ratio, the synergistic effect of improving the adhesion to hair and remarkably increasing the hair dyeing power. In addition, the effect of reducing the background stain can be obtained. The lower limit of the blending amount is particularly preferably 77% by weight or more, and the blending amount of 77% by weight or more significantly improves the hair dyeing power. The upper limit is preferably 90% by weight or less, and when it exceeds 90% by weight, the improvement in hair dyeing power is reduced.

Examples of the propellant include LPG, dimethyl ether, nitrogen and carbon dioxide. The weight ratio of the stock solution to the propellant is 97: 3 to 93: 7, and the propellant is 9
If it is less than 7: 3, the foaming property is poor, and the liquid may be scattered during application. When the amount of propellant is more than 93: 7, the volume of the foam is large and a sufficient coating amount cannot be obtained, resulting in non-staining or uneven dyeing. The propellant to be blended is particularly preferably LPG and dimethyl ether from the viewpoint of foamability.

The stock solution to be blended in the aerosol foam oxidative hair dye composition of the present invention has a viscosity measured at 25 ° C. with a B type viscometer when the gas is not enclosed, and when it is 100 cps to 3000 cps, the stock solution is filled. Not only will work efficiency increase,
It is preferable in that good foam stability and foam breaking property can be obtained and scattering of dye liquor and dripping are not caused.

The aerosol type foamy oxidative hair dye composition of the present invention contains an anionic surfactant, an amphoteric surfactant or a cationic surfactant in combination with the nonionic surfactant as the component (B). By doing so, more excellent dyeing, foam stability, foam breaking property and viscosity stability can be obtained. Examples of the anionic surfactant, amphoteric surfactant and cationic surfactant include the following.

Examples of the anionic surfactant include the following. 1. Sulfate ester salt 1-1) Alkyl sulfate ester salt Sodium lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, etc. 1-2) Alkyl and alkyl allyl ether sulfate ester salt POE sodium lauryl ether sulfate, POE lauryl ether sulfate triethanolamine, POE lauryl ether sulfate ammonium, POE alkyl ether sulfate sodium, POE alkyl ether sulfate triethanolamine, POE alkyl ether sulfate diethanolamine, POE alkyl ether sulfate ammonium, etc. 1-3) Sulfate ester salt of higher fatty acid ester salt Hardened coconut oil fatty acid sodium glyceryl sulfate, etc. 1-4) Sulfurized higher fatty acid alkylolamide Acid ester salt 1-5) Sulfated oil Sulfated castor oil, etc. 2. Phosphate ester POE lauryl ether phosphoric acid, POE oleyl ether phosphoric acid, POE cetyl ether phosphoric acid, POE stearyl ether phosphoric acid, POE alkyl ether phosphoric acid,
2. POE alkyl phenyl ether phosphoric acid and its salts (sodium salt, triethanolamine salt), etc. Sulfonate 3-1) α-Olefin sulfonate 3-2) Sulfonate of higher fatty acid ester 3-3) Sulfonate of higher fatty acid amide Coconut oil fatty acid methyl taurine sodium, lauroyl rotyl taurine sodium, etc. 3- 4) Alkylbenzene sulfonate Dodecylbenzene sulfonate Triethanolamine etc. 3-5) Sulfosuccinate sodium sulfosuccinate, disodium lauryl sulfosuccinate, POE disodium sulfosuccinate, PO
3. Disodium lauryl sulfosuccinate, disodium POE lauroyl ethanolamide sulfosuccinate, disodium undecylenoylamidoethyl sulfosuccinate, etc. Carboxylate 4-1) Condensation product of higher fatty acid and amino acid N-acyl sarcosine salt such as sodium lauroyl sarcosine, sodium N-lauroyl-L-glutamate, disodium N-stearoyl-L-glutamate, N-myristoyl-L- N-acyl glutamate such as sodium glutamate 4-2) Fatty acid soap Sodium salt, potassium salt, triethanolamine salt or ammonium salt of oleic acid, stearic acid, lauric acid, palmitic acid and the like

Examples of the amphoteric surfactant include carboxylic acid type, sulfuric acid ester type, sulfonic acid type and phosphoric acid ester type. For example, 2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium. Betaine, lauryl dimethylaminoacetate betaine, undecinoyl-carboxymethoxyethyl carboxymethyl imidazolinium betaine sodium, undecyl hydroxyethyl imidazolinium betaine sodium, undecyl-N-hydroxyethyl-N-carboxymethyl imidazolinium betaine, alkyldiamino hydrochloride Ethylglycine solution, stearyldihydroxyethylbetaine, stearyldimethylaminoacetic acid betaine, stearyldimethylbetaine sodium solution, bis (stearyl-
N-hydroxyethylimidazoline) chloroacetic acid complex,
Coconut oil alkyl-N-carboxyethyl-N-hydroxyethylimidazolinium betaine sodium, Coconut oil alkyl-N-carboxyethoxyethyl-N-carboxyethylimidazolinium disodium hydroxide, Coconut oil alkyl-N-carboxymethoxyethyl −
N-carboxyethyl imidazolinium disodium hydroxide, coconut oil alkyl-N-carboxymethoxyethyl-N-carboxyethylimidazolinium disodium lauryl sulfate, coconut oil betaine, coconut fatty acid amidopropyl betaine, coconut fatty acid- N-carboxymethoxyethyl-N-carboxyethylimidazolinium betaine sodium, triethanolamine laurylaminopropionate, sodium β-laurylaminopropionate, lauryl N-carboxymethoxyethyl-N-carboxymethylimidazolinium disodium dodecanoyl Sarcosine, sodium lauryl diaminoethyl glycine, amidopropyl betaine laurate and the like.

As the cationic surfactant, those represented by the general formula shown in the following formula (1) are used.
For example, alkyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, lauryl trimethyl ammonium bromide, dialkyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride , Distearyldimethylammonium chloride, dicocoyldimethylammonium chloride, myristyldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride and the like.

[0021]

Embedded image In the formula (1), ₁ to _{2 of} R ₁ , R ₂ , R ₃ and R ₄ represent a linear or branched long-chain alkyl group having 8 to 20 carbon atoms or a long-chain hydroxyalkyl group, The rest represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, and X represents a halogen atom or an alkylsulfate group having 1 to 2 carbon atoms.

The amount of the anionic surfactant and / or the amphoteric surfactant and / or the cationic surfactant blended is preferably 0.1 to 20% by weight, and the nonionic surfactant and the anionic surfactant and The compounding ratio of the amphoteric surfactant and / or the cationic surfactant is 0.02: 1 to 1: 0.0 in weight ratio in consideration of the texture of the finish.
It is desirable to blend in 2.

Further, cationized cellulose derivative, cationic starch, cationized guar gum derivative, diallyl 4
When a cationized polymer such as a quaternary ammonium salt / acrylamide copolymer and a quaternized polyvinylpyrrolidone derivative is blended, dyeing is further improved, foam stability is improved,
A foam breaking property and a feel are obtained. The blending amount is 0.01 to 1
It is 0% by weight, and if it is less than 0.01% by weight, a sufficient effect cannot be obtained, and if it exceeds 10% by weight, the effect is not changed and it is not economical. Regarding the lower limit of the blending amount,
0.1 wt% is particularly preferable, and by blending 0.1 wt% or more, better dyeing, foam stability and foam breaking property can be obtained. Regarding the upper limit, 2% by weight is preferable, and when it exceeds 2% by weight, the increase in the effect is small.

Further, an alkaline agent such as ammonia or alkanolamine can be added, and the pH is adjusted to 6 to 1
Adjusting to 0.5 gives good dyeing, foam stability,
Foam-breaking property and viscosity stability are obtained.

Further, by adding salts such as ammonium chloride, sodium chloride, potassium chloride, sodium carbonate, and sodium hydrogencarbonate, better dyeing, foam stability, foam breaking property and viscosity stability can be obtained. To be The blending amount is 0.01 to 10% by weight,
If the amount is less than 01% by weight, a sufficient effect cannot be obtained and 10
Even if it exceeds the weight%, the effect is not changed and it is not economical.
The lower limit of the blending amount is preferably 0.5% by weight, and by blending 0.5% by weight or more, better dyeing stability and foam stability and foam breaking property can be obtained. Regarding the upper limit, 5% by weight is preferable, and if it exceeds 5% by weight, the increase in the effect is small.

Sulfurous acid, ascorbic acid, thioglycolic acid, phosphoric acid, condensed phosphoric acid and salts thereof may be added as a stabilizer.

Examples of oxidative dye intermediates include paraphenylenediamines, paratoluylenediamines, aminophenols, aminonitrophenols, diphenylamines, diaminophenylamines, N-phenylphenylenediamines, diaminopyridines, and the like. Those salts are mentioned. The blending amount is, for example, 0.01 to 10% by weight based on the total weight of the stock solution of hair dye composition. Further, as a coupler, pyrogallol, catechol, metaphenylenediamine, or the like can be blended. In addition to the above substances, those listed in "Standards for Quasi-drug Raw Materials" (Yakuji Nipposha, published in June 1991) can be used. Furthermore, an acid dye can also be added.

In addition, thickeners such as carboxymethyl cellulose, xanthan gum, polyacrylic acid and salts thereof,
Silicon, a fragrance, etc. can be appropriately blended as necessary.

Further, the aerosol type foamy oxidative hair dye composition of the present invention is used by mixing with an oxidant immediately before hair dyeing. Examples of the oxidizing agent include hydrogen peroxide and urea peroxide. As a dosage form, an aerosol-type foamy oxidizing agent is particularly preferable from the viewpoint of compatibility. In addition, phenacetin and EDT
Stabilizers such as A, nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, cationized polymers, higher alcohols, hydrocarbons, fatty acids,
Waxes, oils and fats, solvents, acids, pH adjusters, fragrances and the like can be appropriately added as necessary.

Next, the present invention will be described more specifically by way of examples, but the present invention is not limited to the following examples unless it exceeds the gist.

[0031]

Example 1 Stock solution of this first agent (pH 9.0, viscosity 1000 cps)
And undiluted solution: propellant (LPG (5.0 Kg / cm ³ , 2
5 ° C.)) at a weight ratio of 95: 5 was filled with a propellant to obtain an aerosol type foamy oxidative hair dye first agent.

<Second Agent> Wt% Hydrogen Peroxide (35%) 15.0 EDTA 0.5 Cetanol 2.0 Stearyltrimethylammonium Chloride 1.0 Propylene Glycol 1.0 Phenacetin 0.1 Polyoxyethylene (20 ) Oleyl ether 0.9 Bring to 100% with purified water. This second agent is used as the stock solution, and the stock solution: propellant (LPG (5.0
(Kg / cm ³ , 25 ° C.)) in a weight ratio of 95: 5 to fill a propellant to obtain an aerosol type foamy oxidative hair dye second agent.

<Comparative Experiment 1> A fixed amount of the first agent of Example 1 and Comparative Examples 1 to 4 in Table 1 was put on a comb for hair dyeing, and the foam retention on the comb was evaluated. Further, this sample was stored at 40 ° C. for 3 months and the change with time of viscosity was also evaluated, and the results are shown in Table 2.

(Evaluation Criteria) ・ Foam retention on comb ◎: Foam does not disappear and does not drip from the comb for one day and night. ○: Bubbles do not disappear and do not drip up to 2 to 3 hours. Δ: Bubbles disappear within 30 minutes, and liquid drips from the comb. X: Bubbles disappear immediately and liquid immediately drips from the comb.・ Change in viscosity with time ○: No change in viscosity. Δ: The viscosity slightly increases. X: Viscosity increases and bubbles do not occur.

<Comparative Experiment 2> Comparative Example 1 of Example 1 and Table 1
A certain amount of the first agent of Nos. 4 to 4 was applied to a hair-dyeing comb and applied to the model hair to evaluate the defoaming property and the scattering of the liquid, and the results are shown in Table 2.

(Evaluation Criteria) ・ Foam-breaking property ◯: Bubbles collapse when combing through. Δ: Bubbles do not easily collapse even if they are comb-throughed. X: Bubbles are not crushed at all even when combing through.・ Liquid splatter ○: No liquid splattered. Δ: The liquid slightly scatters. X: Liquid is considerably scattered.

<Comparative Experiment 3> The hair of five panelists was divided into left and right halves at the crown, and one of them was used as the first aerosol type oxidative hair dye of Example 1 and Comparative Examples 1 to 4 in Table 1. Second
1: 1 mixture of the agents was applied, and 1: 1 mixture of the first and second creamy hair dyes of Comparative Example 5 was applied to the other. Then, after standing at room temperature for 20 minutes, the hair of each panelist was thoroughly washed with warm water at 40 ° C. and dried. Then, Comparative Example 5 and Example 1 and Comparative Examples 1 to 4 were compared and evaluated according to the following evaluation criteria regarding dyeing and background stain, and the results are shown in Table 2.

(Evaluation Criteria) Dyeing ◎: Uniform and natural dyeing. ◯: Some unevenness was observed. (Similar to Comparative Example 5) Δ: uneven dyeing. X: Almost not dyed.・ Background stain ◎: Almost no adhesion. ◯: Adhesion was not noticeable. Δ: Adhered. (Similar to Comparative Example 5) x: Adhered considerably.

[0039]

[Table 1]

<Comparative Example 5> Conventional cream hair dye <First agent> wt% p-phenylenediamine 1.0 m-aminophenol 0.6 resorcin 0.1 1-amino-4-methylanthraquinone 0. 1 Polyoxyethylene (21) lauryl ether 5.0 Polyoxyethylene (5) cetyl ether 5.0 Sodium cetyl sulfate 2.0 Cetyl alcohol 5.0 Vaseline 5.0 Stearic acid 2.0 Propylene glycol 3.0 Hydroxyethyl cellulose Hydroxypropyl trimethylammonium chloride ether 0.2 Sodium sulfite 0.1 28% ammonia water 4.0 Make up to 100% with purified water. <Second agent> Wt% hydrogen peroxide solution (35%) 15.0 Cetanol 2.0 Sodium lauryl sulfate 0.5 Phenacetin 0.1 EDTA 0.5 100% with purified water.

[0041]

[Table 2]

Example 2 First agent wt% p-toluylenediamine 3.0 2-chloro-p-phenylenediamine sulfate 0.5 p-methylaminophenol 0.2 4-nitro-o-phenylenediamine 1. 0 1-Amino-4-methylanthraquinone 0.1 Polyoxyethylene (9) lauryl ether 1.0 Sodium cetyl sulfate 0.5 Cetyl alcohol 1.0 Vaseline 0.5 Stearic acid 1.0 Propylene glycol 8.0 Hydroxyethyl cellulose Hydroxypropyl trimethylammonium chloride ether 0.2 Edetate disodium 0.1 Ascorbic acid 0.5 28% Ammonia water 6.0 Purified water 76.4 (total purified water amount 80.72%) .8, viscosity 1500),
Stock solution: propellant (dimethyl ether: LPG (5.0 kg
/ Cm ³ , 25 ° C.) = 20:80) at a weight ratio of 94: 6 to fill a propellant to obtain a first aerosol type foamy oxidative hair dye. Second agent wt% hydrogen peroxide solution (35%) 15.0 EDTA 0.5 cetanol 2.0 stearyl trimethyl ammonium chloride 1.0 propylene glycol 1.0 phenacetin 0.1 polyoxyethylene (20) oleyl ether 0. 9. Bring to 100% with purified water. This second agent is used as the stock solution, and the stock solution: propellant (dimethyl ether: LPG (5.0 Kg / cm ³ , 25 ° C.) = 20: 8
0) was filled with a propellant in a weight ratio of 94: 6 to obtain an aerosol type foamy oxidative hair dye second agent.

Embodiment 3 This first agent was made into a stock solution (pH 9.2, viscosity 200 cps), and stock solution: propellant (dimethyl ether: LPG (5.0
Kg / cm ³ , 25 ° C.) = 20:80) in a weight ratio of 96:
The propellant was filled at a ratio of 4 to obtain an aerosol type foamy oxidative hair dye first agent. Second agent wt% hydrogen peroxide solution (35%) 15.0 EDTA 0.5 cetanol 2.0 stearyl trimethyl ammonium chloride 1.0 propylene glycol 1.0 phenacetin 0.1 polyoxyethylene (20) oleyl ether 0. 9. Bring to 100% with purified water. This second agent is used as the stock solution, and the stock solution: propellant (dimethyl ether: LPG (5.0 Kg / cm ³ , 25 ° C.) = 20: 8
0) was filled with a propellant in a weight ratio of 96: 4 to obtain an aerosol type foamy oxidative hair dye second agent.

Example 4 This first agent was made into a stock solution (pH 8.3, viscosity 2200),
Stock solution: propellant (dimethyl ether: LPG (5.0 kg
/ Cm ³ , 25 ° C.) = 20:80) at a weight ratio of 94: 6 to fill a propellant to obtain a first aerosol type foamy oxidative hair dye. Second agent wt% hydrogen peroxide solution (35%) 15.0 EDTA 0.5 cetanol 2.0 stearyl trimethyl ammonium chloride 1.0 propylene glycol 1.0 phenacetin 0.1 polyoxyethylene (20) oleyl ether 0. 9. Bring to 100% with purified water. This second agent is used as the stock solution, and the stock solution: propellant (dimethyl ether: LPG (5.0 Kg / cm ³ , 25 ° C.) = 20: 8
0) was filled with a propellant in a weight ratio of 94: 6 to obtain an aerosol type foamy oxidative hair dye second agent.

Example 5 First agent wt% p-phenylenediamine 0.8 p-toluylenediamine 0.5 p-aminophenol 0.3 m-phenylenediamine hydrochloride 0.01 polyoxyethylene (20) sorbitan oleyl Ether 0.9 polyoxyethylene (40) hydrogenated castor oil 0.9 coconut oil fatty acid propyl betaine 1.0 cetanol 0.8 ethanol 1.9 ammonium chloride 0.7 thioglycolic acid 0.3 28% ammonia water 7. 0 purified water 84.89 (total purified water amount 89.93%) This first agent was used as a stock solution (pH 10.5, 1000 cps), and stock solution: propellant (dimethyl ether: LPG (5.0
Kg / cm ³ , 25 ° C.) = 20:80) in a weight ratio of 93:
The propellant was filled in a ratio of 7 to obtain an aerosol type foamy oxidative hair dye first agent. Second agent wt% hydrogen peroxide solution (35%) 15.0 EDTA 0.5 cetanol 2.0 stearyltrimethylammonium chloride 1.0 propylene glycol 1.0 phenacetin 0.1 polyoxyethylene (20) oleyl ether 0. 9. Bring to 100% with purified water. This first agent is used as a stock solution, and the stock solution: propellant (dimethyl ether: LPG (5.0 Kg / cm ³ , 25 ° C.) = 20: 8
0) was filled with a propellant in a weight ratio of 93: 7 to obtain an aerosol type foamy oxidative hair dye second agent.

Example 6 First agent wt% p-toluylenediamine 3.0 resorcin 1.0 p-aminophenol 0.5 stearyl alcohol 2.5 polyoxyethylene (20) oleyl ether 2.0 polyoxyethylene ( 2) oleyl ether 2.0 diglycerin 5.0 polydimethylmethylene piperidinium chloride 1.0 sodium sulfite 0.5 28% ammonia water 5.0 made up to 100% with purified water. 77.5 (total purified water amount 81.1%) This first agent is a stock solution (pH 9.4, viscosity 2200 cps).
And stock solution: propellant (dimethyl ether: LPG (5.
0 kg / cm ³ , 25 ° C.) = 20:80) in a weight ratio of 9
The propellant was filled in a ratio of 3: 7 to obtain an aerosol type foamy oxidative hair dye first agent. Second agent wt% hydrogen peroxide solution (35%) 15.0 EDTA 0.5 cetanol 2.0 stearyl trimethyl ammonium chloride 1.0 propylene glycol 1.0 phenacetin 0.1 polyoxyethylene (20) oleyl ether 0. 9. Bring to 100% with purified water. This second agent is used as the stock solution, and the stock solution: propellant (dimethyl ether: LPG (5.0 Kg / cm ³ , 25 ° C.) = 20: 8
0) was filled with a propellant in a weight ratio of 93: 7 to obtain an aerosol type foamy oxidative hair dye second agent.

[0047]

EFFECT OF THE INVENTION By adding a propellant in a specific ratio to an oxidizing hair dye stock solution containing a specific amount of a higher alcohol, a nonionic surfactant, a solvent and water, an aerosol foam hair dye is obtained. , Excellent stability, good foam condition, good hair dyeing power, and less background stain.

Claims (1)

[Claims] 1. In an aerosol-type oxidative hair dye containing an oxidative dye, the stock solution of the oxidative hair dye comprises 0.01 to 3% by weight of component (A) higher alcohol and component (B) nonionic surfactant. 1 to 10% by weight, component (C) solvent 0.5 to 10
Wt% and component (D) water 72 to 95 wt%, and the weight ratio of the oxidative hair dye stock solution to the propellant is 97: 3 to 93:
7. The aerosol type foamy hair dye composition, which is No. 7.