JPH081183A - Organic waste treatment method - Google Patents

Abstract

(57) [Summary] [Purpose] Sludge can be decomposed efficiently with low ozone consumption and aerobic biological treatment can be performed, which can suppress the production of excess sludge and, in some cases, excess sludge. We propose a method for treating organic effluent that can reduce the generation to zero. [Structure] The liquid to be treated 6 is placed in the aeration tank 2 of the activated sludge treatment system 1,
Introduced return sludge 7 and heat treatment sludge 19, and aerated tank 2
Mix with the activated sludge inside to perform aerobic biological treatment. The mixed liquid 10 is subjected to solid-liquid separation in the solid-liquid separation unit 3, part of the separated sludge 12 is returned to the aeration tank 2 as return sludge 7, and the other part is introduced into the ozone treatment tank 4 as drawn-out sludge 13. Ozone treatment is performed. The ozone-treated sludge 17 was introduced into the heat treatment tank 5 and
Heat treatment is performed at 0 to 100 ° C., and the heat-treated sludge 19 is introduced into the aeration tank 2 to perform aerobic biological treatment.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for biologically treating organic waste liquid in an activated sludge treatment system, and more particularly to a method for treating organic waste liquid capable of reducing the volume of excess sludge in the activated sludge treatment system. .

[0002]

2. Description of the Related Art An aerobic biological treatment method, such as an activated sludge treatment method, which treats an organic waste liquid under aerobic conditions by utilizing the action of aerobic microorganisms has a low treatment cost and a high treatment performance. It is widely used because it is excellent, but it produces a large amount of surplus sludge that is difficult to dehydrate. This excess sludge reaches about 30 to 60% of the treated BOD amount, and its treatment is difficult. Conventionally, such excess sludge has been disposed of, but it is difficult to secure a disposal site for it, and it is necessary to reduce the volume of sludge.

In order to reduce the volume of sludge, a method for reducing the volume of surplus sludge produced by performing ordinary aerobic biological treatment has been used. Anaerobic digestion methods and aerobic digestion methods are generally used as such sludge volume reduction methods. In these methods, a sludge anaerobic digestion apparatus or an aerobic digestion apparatus is provided separately from an aerobic treatment apparatus for organic wastewater, and sludge is digested under anaerobic or aerobic conditions. However, in these methods, only about 50% of the treated sludge is decomposed, and the rest is discharged as digested sludge. This digested sludge is a biologically inactive substance and cannot be reduced in volume any further,
It must be incinerated or discarded.

In addition to this, Japanese Patent Publication No. 57-19719, Japanese Patent Laid-Open No. 59-105897 and Japanese Patent Laid-Open No. 59-112899.
JP-A-2-222798 and JP-A-2-222798 describe a sludge treatment method in which excess sludge is oxidatively decomposed by ozone and then aerobically or anaerobically biologically treated, and the volume of the excess sludge is reduced by ozone treatment. It is disclosed that the degree is improved or the digestion period can be shortened. However, in the above-mentioned conventional method, ozone treatment is performed to convert sludge into BOD, and there is a problem that a large amount of ozone is required to completely convert sludge into BOD.

[0005]

SUMMARY OF THE INVENTION In order to solve the above problems, an object of the present invention is to decompose sludge with a small amount of ozone used to increase biodegradability, thereby effectively reducing excess sludge volume. The purpose is to propose a method for treating organic waste liquid that can be converted into organic matter.

[0006]

The present invention is a method for biologically treating an organic waste liquid in an activated sludge treatment system, wherein activated sludge in the activated sludge treatment system is extracted, and after the extracted sludge is treated with ozone, It is a method for treating organic wastewater, which comprises performing heat treatment at 50 to 100 ° C. and introducing the heat treatment liquid into an activated sludge treatment system for biological treatment.

The organic drainage to be treated in the present invention is a drainage containing an organic substance treated by a usual aerobic biological treatment method, but it contains a hardly biodegradable organic substance or an inorganic substance. May be. Examples of such organic effluents include sewage, night soil, food factory effluents and other industrial effluents.

The activated sludge treatment system in the present invention is a treatment system for treating an organic waste liquid with aerobic organisms in the presence of activated sludge. As such a treatment system, the standard is to mix the organic waste liquid with the activated sludge in the aeration tank for aeration, to separate the mixed liquid in the solid-liquid separation tank for solid-liquid separation, and to return part of the separated sludge to the aeration tank. A treatment system based on the activated sludge treatment method is generally used, but another treatment system obtained by modifying this may be used.

In the present invention, in the treatment by such an activated sludge treatment system, the activated sludge is extracted from the activated sludge treatment system, the extracted sludge is subjected to ozone treatment, and then heat treated to be introduced into the activated sludge treatment system. Perform aerobic treatment. When extracting the activated sludge from the activated sludge treatment system, it is preferable to withdraw a part of the separated sludge separated in the solid-liquid separation section in a system in which the activated sludge treatment system includes an aeration tank and a solid-liquid separation section. Alternatively, the liquid mixture may be withdrawn from the aeration tank. When extracting from separated sludge, part or all of the part discharged as excess sludge can be extracted as extracted sludge, but in addition to excess sludge, part of the sludge returned to the aeration tank as return sludge Further, it is preferable to perform extraction and ozone treatment. In this case, the amount of excess sludge generated can be further reduced, and depending on the conditions, the amount of excess sludge generated can be made zero.

The ozone treatment can be carried out by bringing drawn sludge into contact with ozone. As a contact method,
A method of introducing drawn sludge into the ozone treatment tank to blow ozone, a method of mechanical stirring, a method of utilizing a packed bed, and the like can be adopted. As ozone, ozone-containing air, ozonized air, or the like can be used in addition to ozone gas. The amount of ozone _{0.005~0.04g-O 3 / g-VSS} , preferably it is desirable to _{0.01~0.03g-O 3 / g-VSS} .

The ozone-treated sludge thus treated with ozone is heat-treated as it is or after being concentrated by a centrifuge or the like if necessary. As the heat treatment, a method of introducing ozone-treated sludge into a heat treatment tank and heating it with steam or an electric heater, or another method can be adopted. The condition of the heat treatment is that the temperature is 50 to 100 ° C., preferably 60 to 90 ° C.,
The treatment time is 0.1 to 2 hours, preferably 0.5 to 1 hour. It should be noted that heating above 100 ° C. produces chromaticity components that are difficult to remove, so heat treatment under such conditions is not preferable.

In the present invention, after the drawn sludge is treated with ozone,
The heat treatment can reduce the amount of ozone used to obtain the same volume reduction rate of excess sludge as compared with the case of treating ozone alone. It is presumed that this is because the microorganisms and polymer substances in the drawn-out sludge are hydrolyzed by the ozone treatment into a low molecular weight state and further decomposed by the heat treatment, which increases the microbial degradability.

The heated heat-treated sludge is treated as it is or, if necessary, after treatment such as concentration, is introduced into an activated sludge treatment system for aerobic biological treatment. If the activated sludge treatment system consists of an aeration tank and a solid-liquid separation unit, introduce it into the aeration tank. In this case, it is preferable to return the heat-treated sludge to the activated sludge treatment system of the previous step for aerobic biological treatment, but it is also possible to introduce it into another activated sludge treatment system to perform aerobic biological treatment. In this way, by treating the heat-treated sludge with aerobic organisms, the heat-treated sludge is mineralized into carbon dioxide gas and reduced in volume.

Normally, C which is hardly biodegradable by ozone treatment is used.
Although a small amount of OD component is generated, such a biodegradable COD component is decomposed by a method such as adding a carrier such as sponge to an aeration tank and supporting sludge on the carrier to prolong the SRT. be able to.

By subjecting the heat-treated sludge to aerobic biological treatment, organic substances in the ozone-treated and heat-treated sludge are easily biodegraded and removed, thereby reducing the amount of sludge discharged from the entire system. In this case, the larger the amount of sludge to be subjected to ozone treatment and heat treatment, the higher the sludge volume reduction rate. However, since the sludge grows when biodegrading the organic matter in the ozone-treated and heat-treated sludge, the excess sludge cannot be reduced to zero simply by treating the excess sludge by the method of the present invention, but it grows. When excess activated sludge is extracted from the activated sludge treatment system so that the amount of sludge is apparently zero and subjected to ozone treatment and heat treatment, the amount of excess sludge generated from the entire system can be reduced to zero. In this case, if the amount of sludge to be subjected to ozone treatment and heat treatment increases, the biological treatment performance may deteriorate.In such a case, a carrier for supporting sludge is provided in the aeration tank and a fixed amount of sludge is provided. By maintaining the amount, the biological treatment performance can be maintained high.

[0016] In the present invention, by performing heat treatment after ozone treatment, even if the amount of ozone used in the ozone treatment is halved compared to the case where only ozone treatment is performed on the drawn sludge, almost the same amount of excess sludge is produced. A volume reduction rate can be achieved. That is, the amount of ozone reaction to the drawn sludge is
As shown in FIG. 2, in the case of the ozone treatment alone, a sufficient volume reducing effect cannot be obtained unless 2% by weight or more of ozone is reacted with the drawn sludge, but the method of the present invention is clear from the examples described later. As described above, even when 1% by weight of ozone is reacted with the drawn sludge, a good volume reducing effect can be obtained.

[0017]

EXAMPLES Next, examples of the present invention will be described. FIG.
2 is a flow sheet showing a method for treating organic waste liquid according to an example. In FIG. 1, 1 is an activated sludge treatment system, which is composed of an aeration tank 2 and a solid-liquid separation section 3. Reference numeral 4 is an ozone treatment tank, and 5 is a heat treatment tank.

In the treatment method shown in FIG. 1, the liquid 6 to be treated and the return sludge 7 are introduced into the aeration tank 2 and mixed with the activated sludge in the aeration tank 2, air is sent from the air supply pipe 8 and air is sent from the air diffuser pipe 9. Aerate, mix and aerate and perform aerobic biological treatment.

A part of the mixed liquid 10 in the aeration tank 2 is guided to the solid-liquid separation section 3 and separated into a separated liquid and a separated sludge 12 by solid-liquid separation.
The separated liquid is discharged as the treatment liquid 11, and a part of the separated sludge 12 is returned to the aeration tank 2 as the returned sludge 7. Separation sludge 12
The other part is introduced into the ozone treatment tank 4 as drawn-out sludge 13, and the remaining part is discharged as excess sludge 14.

In the ozone treatment tank 4, ozone is supplied from the ozone supply pipe 15 and brought into contact with the drawn sludge 13 to perform ozone treatment, and ozone exhaust gas is discharged from the exhaust ozone pipe 16. As a result, the drawn-out sludge 13 is hydrolyzed to have a low molecular weight.

The ozone-treated sludge 17 taken out from the ozone treatment tank 4 is introduced into the heat treatment tank 5, heated by the heater 18 and kept at 50 to 100 ° C. for heat treatment. As a result, the biodegradability of the ozone-treated sludge 17 becomes high.

The heat-treated sludge 19 is introduced into the aeration tank 2 for aerobic biological treatment. Here, the organic matter in the heat-treated sludge 19 is biodegraded by the activated sludge to be mineralized and its volume is reduced. At this time, since the activated sludge grows, the amount of activated sludge even if ozone treatment and heat treatment are carried out by using all the portions conventionally discarded as surplus sludge, that is, the remaining sludge except the returned sludge 7 as drawn sludge 13. Continues to increase, and inevitably excess sludge 14 is generated. Therefore, when the amount of the drawn sludge 13 is determined so that the multiplied sludge and the mineralized portion are equal, the excess sludge 14 becomes substantially zero.

The aeration tank capacity in the activated sludge treatment system 1 is V, the activated sludge concentration of the whole activated sludge treatment system 1 for this V is X, the sludge yield is Y, the treated liquid flow rate (treatment liquid flow rate) is Q, and The organic matter concentration of the treatment liquid is Ci, the organic matter concentration of the treatment liquid is Ce, and the biologically treated organic matter concentration is (Ci-Ce),
Assuming that the sludge self-decomposition constant is Kd, the surplus sludge discharge amount is q, the sludge drawn into the ozone treatment tank 4 is Q ', and the ratio of the sludge subjected to ozone treatment and heat treatment to be converted back into activated sludge is k, the material balance is calculated. Is expressed by the following equation [1].

[Formula 1] V dX / dt = Y Q (Ci−Ce) −V Kd X−q X−Q′X + kQ′X [1]

In the equation [1], V dX / dt is the change amount of the activated sludge in the activated sludge treatment system 1, and Y Q (Ci
-Ce) is the amount of produced sludge, V Kd X is the amount of self-decomposition, qX is the amount of excess sludge 14 discharged, Q'X is the amount of 13 of drawn sludge, and kQ'X is the amount of produced sludge from drawn sludge. The amount is shown.

Here, Q (Ci-Ce) / V = LV (tank load), q / V = 1 / SRT (excess sludge retention time ratio),
If Q ′ / V = θ (circulation ratio of activated sludge to the ozone treatment tank 4) and (1−k) = δ (mineralization rate), in the steady state, the equation [1] is given by the following [2]. Is simplified as follows.

[Formula 2] Y LV / X = Kd + 1 / SRT + δθ [2]

In a normal activated sludge treatment system in which the ozone treatment tank 4 and the heat treatment tank 5 do not exist, the third term (δθ) of the formula [2] does not exist, so when the sludge load is constant, the surplus in the second term is exceeded. Sludge (X / SRT) is determined. On the other hand, in the treatment system in which the ozone treatment tank 4 and the heat treatment tank 5 are combined, as is apparent from the equation [2], the excess sludge is reduced in volume by the value of the third term. Then, under the condition that the value of the third term is equal to the value of the second term, it is possible to set the sludge load to a normal value without discharging the excess sludge (1 / SRT = 0). .

In the treatment method of FIG. 1, since the ozone treatment is followed by the heat treatment, the sludge is efficiently mineralized in the aeration tank 2 even if the amount of ozone used in the ozone treatment is reduced.

In the treatment method of FIG. 1, the solid-liquid separation unit 3
Although the separated sludge of No. 1 is used as the drawn-out sludge 13, the mixed liquid in the aeration tank 2 or the activated sludge separated therefrom may be used as the drawn-out sludge. Further, since the heat-treated sludge 19 is returned to the aeration tank 2 of the activated sludge treatment system 1, another activated sludge treatment system is not necessary, but in some cases, the heat-treated sludge 19 is aerobic in another activated sludge treatment system. It can also be treated biologically.
Further, although the above-mentioned embodiment adopts the standard activated sludge treatment method, other aerobic biological treatment such as a modified activated sludge treatment method or a combination with nitrification / denitrification treatment may be carried out.

Reference Example 1 Activated sludge treatment system 1 shown in FIG. 1 using the wastewater of a food factory of BOD = 1000 mg / l and SS = 100 mg / l as a liquid to be treated.
Was subjected to aerobic treatment (no ozone treatment or heat treatment). The treatment was carried out using an aeration tank 2 of 1 m ³ , tank load = 1 kg-BOD / m ³ , sludge load = 0.
It was performed at 2 kg-BOD / kg-MLSS / day. As a result, the treated water quality was 20 mg / l as COD _Mn , and the excess sludge was discharged at 0.4 kg per day.

Comparative Example 1 The food factory wastewater of Reference Example 1 was treated by the method of FIG. 1 but without heat treatment. Ozone treatment is withdrawn sludge 13
2% by weight of ozone was used to treat 0.4 kg of drawn sludge 13 per day (the daily ozone consumption was 8
g). The amount of excess sludge discharged outside the system to maintain the sludge load in the same manner as in Reference Example 1 was 0.26 kg per day. The treated water quality was 24 mg / l as COD _Mn .

Comparative Example 2 Comparative Example 1 was carried out in the same manner as Comparative Example 1 except that the amount of ozone used was 1% by weight with respect to the drawn sludge 13 (the amount of ozone used per day was 4 g). As a result, the amount of excess sludge discharged outside the system to maintain the sludge load in the same manner as in Reference Example 1 was 0.38 kg per day, and the volume reduction effect of the excess sludge amount was small. The treated water quality is 22 mg as COD _Mn
It was / l.

Example 1 The food factory wastewater of Reference Example 1 was treated by the method shown in FIG.
In the ozone treatment, 1% by weight of ozone was used with respect to the drawn sludge 13, and 0.4 kg of the drawn sludge 13 was processed per day (the daily ozone usage amount was 4 g). After ozone treatment, 80 ℃
And heat treated for 1 hour. As a result, the sludge load was changed to Reference Example 1.
The amount of excess sludge discharged outside the system to maintain the same as
It was 0.26 kg per day. The treated water quality was 22 mg / l as COD _Mn . In Example 1 in which the amount of ozone used was 1% by weight, Comparative Example 1 in which the amount of ozone used was 2% by weight
It was confirmed that the volume of excess sludge was reduced to the same extent as in

Example 2 The food factory wastewater of Reference Example 1 was treated by the method shown in FIG.
In the ozone treatment, 1% by weight of ozone was used with respect to the drawn sludge 13, and 0.8 kg of the drawn sludge 13 was treated per day (the amount of ozone used per day was 8 g). After ozone treatment, 60 ℃
And heat treated for 1 hour. As a result, the sludge load was changed to Reference Example 1.
The amount of excess sludge discharged outside the system to maintain the same as
It was 0.10 kg per day. The treated water quality was 25 mg / l as COD _Mn .

[0034]

According to the present invention, the activated sludge of the activated sludge treatment system is subjected to ozone treatment, then heated at 50 to 100 ° C. and introduced into the activated sludge treatment system for biological treatment. Sludge can be decomposed by increasing the amount of ozone used to increase biodegradability, which makes it possible to efficiently reduce the volume of excess sludge.

[Brief description of drawings]

FIG. 1 is a flow sheet showing a method for treating organic waste liquid according to an embodiment.

FIG. 2 is a graph showing a relationship between an ozone injection rate and a biodegradation rate.

[Explanation of symbols]

 1 Activated sludge treatment system 2 Aeration tank 3 Solid-liquid separation part 4 Ozone treatment tank 5 Heat treatment tank 6 Liquid to be treated 7 Returned sludge 8 Air supply pipe 9 Diffuser 10 Mixture 11 Treated liquid 12 Separation sludge 13 Extracted sludge 14 Excess sludge 15 Ozone Supply Pipe 16 Exhaust Ozone Pipe 17 Ozone Treated Sludge 18 Heater 19 Heat Treated Sludge

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[Procedure amendment]

[Submission date] July 29, 1994

[Procedure Amendment 1]

[Document name to be corrected] Drawing

[Name of item to be corrected] Figure 1

[Correction method] Change

[Correction content]

FIG.

Claims (1)

[Claims] 1. A method for biologically treating organic waste liquid in an activated sludge treatment system, comprising extracting activated sludge from the activated sludge treatment system, subjecting this extracted sludge to ozone treatment, and then heat treating at 50 to 100 ° C. A method for treating organic wastewater, comprising introducing the heat treatment liquid into an activated sludge treatment system for biological treatment.