JPH0754697B2 - Labeled dry cell - Google Patents
Labeled dry cellInfo
- Publication number
- JPH0754697B2 JPH0754697B2 JP58057489A JP5748983A JPH0754697B2 JP H0754697 B2 JPH0754697 B2 JP H0754697B2 JP 58057489 A JP58057489 A JP 58057489A JP 5748983 A JP5748983 A JP 5748983A JP H0754697 B2 JPH0754697 B2 JP H0754697B2
- Authority
- JP
- Japan
- Prior art keywords
- label
- dry battery
- vapor deposition
- metal
- shrink film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
- H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
- H01M50/129—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers with two or more layers of only organic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Description
【発明の詳細な説明】 本発明はラベル付き乾電池に関する。The present invention relates to a dry battery with a label.
従来の乾電池はメタルジャケットの外装によりその胴部
を覆われている。A conventional dry battery has its body covered with a metal jacket.
乾電池の外周は日本工業規格で統一されているから、こ
のメタルジャケットに代えて金属蒸着層を有するラベル
を用いれば、金属印刷やメタルジャケットをかしめるな
どの工程が不要となり、内容量も多くできる。Since the outer circumference of the dry battery is standardized by Japanese Industrial Standards, if you use a label with a metal deposition layer instead of this metal jacket, steps such as metal printing and caulking the metal jacket are unnecessary, and the internal capacity can be increased. .
もっとも、メタルジャケットを用いない時には、乾電池
の上下端から電解液が漏出し易く、漏出した電解液は電
気機器を損傷するから、ラベルはこの乾電池の上下端に
密着して電解液の漏出を防止できるものではなくてはな
らない。このようなラベルはシュリンクラベルに限られ
る。すなわち、ラベルが収縮して乾電池の上下端に密着
することが不可欠である。However, when the metal jacket is not used, the electrolyte easily leaks from the upper and lower ends of the dry battery, and the leaked electrolyte damages electrical equipment. Therefore, the label adheres to the upper and lower ends of this dry battery to prevent the electrolyte from leaking. It must be possible. Such labels are limited to shrink labels. That is, it is essential that the label shrinks and adheres to the upper and lower ends of the dry battery.
乾電池を筒状のシュリンクラベルに挿入し、シュリンク
して密着すると共に、乾電池の上下の端部を密封したも
のも従来から知られていたが、金属蒸着を有するラベル
は用いられたことがなかった。収縮時に金属蒸着層にク
ラックが生じて白化し、金属光沢を失ってしまうからで
ある。It has been known that a dry battery is inserted into a cylindrical shrink label, shrinks and adheres tightly, and the upper and lower ends of the dry battery are sealed, but a label having metal vapor deposition has never been used. . This is because cracks occur in the metal vapor deposition layer at the time of contraction and whitening occurs, and the metallic luster is lost.
本発明はこれを解決したもので、すなわち、金属蒸着層
を有し、片面に感圧粘着剤層を有するラベルを乾電池胴
部に胴巻きにすると共に接着し、加熱収縮させてなるラ
ベル付き乾電池である。The present invention solves this problem, that is, a labeled dry battery having a metal vapor-deposited layer and a label having a pressure-sensitive adhesive layer on one side is wound around the dry battery body and bonded and is heat-shrinkable. is there.
以下、図面を用いて本発明を詳細に説明する。図面は本
発明の実施例を示し、第１図〜第４図は離型紙から剥離
する前の本発明に係るラベルの断面図、第５図（ａ）〜
（ｂ）は本発明に係るラベルを乾電池に適用する方法を
説明する断面図（ただし第５図（ａ）〜（ｂ）において
乾電池内部の構造は省略してある。）第６図は第５図の
結果得られたラベル付き乾電池の斜視図である。Hereinafter, the present invention will be described in detail with reference to the drawings. The drawings show an embodiment of the present invention, and FIGS. 1 to 4 are sectional views of a label according to the present invention before being peeled from a release paper, and FIG.
FIG. 6B is a sectional view for explaining a method of applying the label according to the present invention to a dry battery (however, the internal structure of the dry battery is omitted in FIGS. 5A to 5B). It is a perspective view of the dry battery with a label obtained as a result of the figure.
図面の第１図において、（１）はシュリンクフィルムを
示している。この材質は任意のもので良いが例えば一軸
延伸した収縮塩ビフィルムが使用できる。後述するよう
に乾電池に適用する際の便から一軸延伸したシュリンク
フィルム、特に縦方向（フィルムを押し出し成形する際
の押し出し方向）に延伸したシュリンクフィルムが好ま
しい。In FIG. 1 of the drawings, (1) indicates a shrink film. This material may be arbitrary, but for example, a uniaxially stretched shrinkable vinyl chloride film can be used. As will be described later, a shrink film stretched uniaxially from the stool when applied to a dry battery, particularly a shrink film stretched in the longitudinal direction (extrusion direction when the film is extruded) is preferable.
また、（２）はこのシュリンクフィルム（１）に蒸着さ
れた金属蒸着層を示している。この蒸着金属は鉄、銅、
ニッケルなど任意の金属を用いることができるが、アル
ミニウムが安価であり、また簡便である。Further, (2) shows a metal vapor deposition layer vapor-deposited on the shrink film (1). This evaporated metal is iron, copper,
Although any metal such as nickel can be used, aluminum is inexpensive and simple.
一方、シリコン加工などの離型加工を施した離型紙
（４）の離型加工面に、感圧粘着剤（３）を塗布し、充
分に乾燥して溶剤を除去する。この感圧粘着剤（３）面
に前記シュリンクフィルム（１）の金属蒸着層（２）面
を張り合せ、離型紙（４）をカットしない程度の深さに
切断刃を入れて、シュリンクフィルム（１）及び金属蒸
着層（２）をカットし、使用しない部分のシュリンクフ
ィルム（１）及び金属蒸着層（２）を粘着剤（３）と共
に除去する。こうして得られたものが第１図の断面図に
示すものである。なお、印刷インキ（５）は蒸着前のシ
ュリンクフィルム（１）に施しても良いし、離型紙
（４）に張合わせた後のシュリンクフィルム（１）に施
しても良い。On the other hand, the pressure-sensitive adhesive (3) is applied to the release-processed surface of the release paper (4) that has been subjected to a release process such as silicon processing, and dried sufficiently to remove the solvent. The pressure-sensitive adhesive (3) surface is adhered to the metal vapor deposition layer (2) surface of the shrink film (1), and a cutting blade is inserted to a depth that does not cut the release paper (4). 1) and the metal vapor deposition layer (2) are cut, and the shrink film (1) and the metal vapor deposition layer (2) in the unused portions are removed together with the adhesive (3). The one obtained in this way is shown in the sectional view of FIG. The printing ink (5) may be applied to the shrink film (1) before vapor deposition, or may be applied to the shrink film (1) after being attached to the release paper (4).
第２図に示すものは、シュリンクフィルム（１）に金属
蒸着するに先立って、例えば黄色の染料を混合した蒸着
アンダーニス（６）を塗布し、この後金属蒸着層（２）
を形成したもので、他の点は第１図と同様である。As shown in FIG. 2, before the metal deposition on the shrink film (1), a vapor deposition undervarnish (6) containing, for example, a yellow dye is applied, and then the metal deposition layer (2) is formed.
Is formed, and other points are the same as in FIG.
また、第３図に示すものは、シュリンクフィルム（１）
に金属蒸着した後、接着剤（７）を介してシュリンクフ
ィルム（８）を積層したもので、その他は第１図に示す
ものと同様である。なお、接着剤（７）は、粘着剤
（３）と異なってラベルとなった際に粘着性を有する必
要はないから、ノンソルベント型の接着剤を用いること
できる。The shrink film (1) shown in FIG.
After the metal vapor deposition, a shrink film (8) is laminated via an adhesive (7), and the others are the same as those shown in FIG. Unlike the adhesive (3), the adhesive (7) does not need to have adhesiveness when it becomes a label, and thus a non-solvent type adhesive can be used.
第４図に示すものは、蒸着前に黄色の染料を混合した蒸
着アンダーニス（６）を塗布したもので、他の点は第３
図と同様である。What is shown in FIG. 4 is the one in which the vapor deposition undervarnish (6) mixed with the yellow dye is applied before vapor deposition, and the other points are the third.
It is similar to the figure.
第１図第４図において、感圧粘着剤（３）としては、例
えば、アクリル酸エステル、アクリル酸共重合物、天然
ゴムなどの主材に、エステルガム、ロジン、クマロンな
どの粘着付与剤やポリブテン、ジオクチルフタレート、
ヒマシ油等の可塑剤などを配合したものが使用できる。In FIG. 1 and FIG. 4, as the pressure-sensitive adhesive (3), for example, a main material such as an acrylic ester, an acrylic acid copolymer, natural rubber or the like, a tackifier such as ester gum, rosin or coumarone, Polybutene, dioctyl phthalate,
A mixture of castor oil and other plasticizers can be used.
こうして得られたラベル（９）は、第５図（ａ）に示す
ように、離型紙（４）から剥離して、乾電池（10）胴部
の外周に接着する。このとき、シュリンクフィルム
（１）の延伸した方向（収縮する方向）が乾電池（10）
の外周方向になるようにすることが好ましい。この後加
熱してラベルを収縮させる。すると、第５図（ｂ）に示
すように、乾電池（10）胴部の両端ではその収縮が激し
く、従来のメタルジャケットをかしめたときと同様の状
態になる一方、胴部にはラベルが密着しているため、ほ
とんど収縮せず、金属光沢がそのまま維持される。この
ときの斜視図が第６図に示すものである。The label (9) thus obtained is peeled from the release paper (4) and adhered to the outer periphery of the body of the dry battery (10) as shown in FIG. 5 (a). At this time, the stretched direction (shrinking direction) of the shrink film (1) is the dry battery (10).
It is preferable to set it in the outer peripheral direction. This is followed by heating to shrink the label. Then, as shown in FIG. 5 (b), the shrinkage is severe at both ends of the dry battery (10) body, and the state is the same as when the conventional metal jacket is crimped, while the label is closely attached to the body. As a result, there is almost no shrinkage, and the metallic luster is maintained as it is. A perspective view at this time is shown in FIG.
本発明は以上述べた通りで、このため、以上（イ）〜
（ホ）の効果を有する。The present invention is as described above. Therefore, the above (a) to
It has the effect of (e).
（イ）シュリンクフィルムのシュリンク性を損なうこと
無く感圧粘着剤層を設けることができる。(A) The pressure-sensitive adhesive layer can be provided without impairing the shrinkability of the shrink film.
（ロ）電池の円周方向に収縮するラベルを用いるので、
端部が電池の端部に沿ってかしめられて電池の上下端に
密着し、電解液の漏出を防ぐとともに、胴部では収縮せ
ず、金属光沢が維持される。(B) Since a label that shrinks in the circumferential direction of the battery is used,
The ends are crimped along the ends of the battery and adhere to the upper and lower ends of the battery to prevent leakage of the electrolytic solution, and the body does not shrink and the metallic luster is maintained.
（ハ）従来のメタルジャケットに比べて安価であり、そ
の取り扱いもはるかに容易である。(C) It is cheaper than conventional metal jackets and much easier to handle.
（ニ）従来のメタルジャケットに比べて薄いので、それ
だけ電池の内容量を大きくすることができる。(D) Since it is thinner than the conventional metal jacket, the internal capacity of the battery can be increased accordingly.
（ホ）蒸着アンダーニスに混合する染料を、黄色に限ら
ず種々の色彩にすることにより、黄金色、青銅色等の金
属色を得ることができる。(E) The dye mixed in the vapor deposition undervarnish is not limited to yellow, and various colors can be used to obtain a metallic color such as golden or bronze.
以下、実施例により本発明を説明する。Hereinafter, the present invention will be described with reference to examples.
〈実施例〉 厚み30μのタテ収縮率50％の塩ビフィルムの片面に、黄
色の染料を含む透明なビニル系塗料を塗布し、50℃以下
の熱風で充分に乾燥させた後、アルミニウムをその塗工
面に400オングストロームの厚さに真空蒸着した。<Example> A transparent vinyl paint containing a yellow dye is applied to one side of a vinyl chloride film having a thickness shrinkage of 50% and a thickness of 30 μ, and is sufficiently dried with hot air at 50 ° C or less, and then aluminum is applied thereto. It was vacuum-deposited on the work surface to a thickness of 400 Å.
一方、80g/m2のグラシン紙にシリコン系離型剤を塗工焼
き付けしてなる離型紙に、オリバインBPS-1109（東洋イ
ンキ製造（株）製粘着剤）を塗工量30g/m2（Dry）塗工
し、充分に乾燥して溶剤を除去した後、厚さ30μのタテ
収縮率50％塩ビフィルムを張合わせた。このフィルム面
に更にオリバインBPS-3233（東洋インキ製造（株）製ノ
ンソルベント型接着剤）を塗工量25g/m2（Dry）塗工し
て、前記蒸着フィルムのアルミニウム蒸着面を張合わせ
た。こうして得られたラベル用原反の断面は第４図に示
すものと同様である。On the other hand, 80 g / m of a silicone release agent to the release paper obtained by baking the coating to 2 glassine paper, Oribain BPS-1109 (Toyo Ink Mfg. Co., Ltd. adhesive) the coating weight 30 g / m 2 ( After the coating was applied and the solvent was removed by sufficient drying, a PVC film with a vertical shrinkage of 50% and a thickness of 30 μ was laminated. Olivine BPS-3233 (a non-solvent type adhesive manufactured by Toyo Ink Mfg. Co., Ltd.) was applied to the film surface at a coating amount of 25 g / m 2 (Dry), and the aluminum vapor deposition surface of the vapor deposition film was bonded. . The cross section of the label original fabric thus obtained is similar to that shown in FIG.
このラベル用原反は６ヶ月放置してもその性能に変化が
なく、経時的に安定なものであった。The label stock was stable with time without any change in its performance even after being left for 6 months.
この後、この原反の塩ビフィルム面に、紫外線硬化型黒
インキで印刷し、紫外線乾燥機で乾燥硬化後、乾電池胴
部に比較して、円周方向で2mm、高さ方向で4mm（上方2m
m、下方2mm）それぞれ長い寸法で、切断刃により、離型
紙を切断しないようハーフカットした。After that, print on the vinyl chloride film surface of this material with UV curable black ink, dry and harden it with an ultraviolet dryer, and then compare it with the body of the dry cell by 2 mm in the circumferential direction and 4 mm in the height direction (upper direction). 2m
m, 2 mm downward), each of which has a long dimension, and the cutting blade is half-cut so as not to cut the release paper.
ラベルを、自動ラベラーで、アルカリマンガン乾電池の
胴部に胴巻きにして接着した。これを100℃の熱風乾燥
機中で１分間加熱処理したところ、ラベルが収縮して第
６図に示すように、ラベルの端部が乾電池の端部を巻き
込むと共に、乾電池胴部では蒸着金属の金属光沢が維持
されて、良好な外観を有する乾電池が得られた。The label was wrapped around the body of the alkaline manganese dry battery with an automatic labeler and bonded. When this was heat-treated in a hot-air dryer at 100 ° C for 1 minute, the label contracted and the end of the label wraps around the end of the dry battery, as shown in Fig. 6, and at the body of the dry battery, the deposited metal A dry cell having a good appearance with a metallic luster maintained was obtained.
図面は本発明の実施例を示し、第１図〜第４図は離型紙
から剥離する前のラベルの断面図、第５図（ａ）（ｂ）
は本発明のラベルを乾電池に適用する方法を説明するた
めの説明断面図（但し電池内部の構造は図示を省略して
ある）、第６図はラベル付き乾電池の斜視図である。 （１）……シュリンクフィルム （２）……金属蒸着層 （３）……感圧粘着剤 （４）……離型紙 （５）……印刷インキ （６）……蒸着アンダーニス （７）……接着剤 （８）……シュリンクフィルム （９）……ラベル （10）……乾電池The drawings show an embodiment of the present invention, and FIGS. 1 to 4 are sectional views of a label before being peeled from a release paper, and FIGS. 5 (a) and 5 (b).
Is an explanatory sectional view for explaining a method of applying the label of the present invention to a dry battery (however, the internal structure of the battery is omitted), and FIG. 6 is a perspective view of the dry battery with label. (1) …… Shrink film (2) …… Metal vapor deposition layer (3) …… Pressure sensitive adhesive (4) …… Release paper (5) …… Printing ink (6) …… Vapor deposition under varnish (7)… Adhesive (8) Shrink film (9) Label (10) Dry cell
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭52−131126（ＪＰ，Ａ) 特開 昭52−131124（ＪＰ，Ａ) 特開 昭52−25236（ＪＰ，Ａ) 特開 昭56−4675（ＪＰ，Ａ) 特開 昭57−210563（ＪＰ，Ａ) 特開 昭52−13566（ＪＰ，Ａ) 実開 昭54−178785（ＪＰ，Ｕ) ─────────────────────────────────────────────────── ─── Continuation of front page (56) References JP-A-52-131126 (JP, A) JP-A-52-131124 (JP, A) JP-A-52-25236 (JP, A) JP-A-56- 4675 (JP, A) JP-A-57-210563 (JP, A) JP-A-52-13566 (JP, A) Practical application Sho-54-178785 (JP, U)
Claims (1)
有するシュリンクラベルを乾電池胴部に胴巻きにすると
共に接着して胴部の収縮を防止し、加熱して上記胴部を
除く端部を収縮させてなるラベル付き乾電池。1. A shrink label having a vapor-deposited metal layer and having a pressure-sensitive adhesive layer on one surface is wrapped around a dry battery body and bonded to prevent shrinkage of the body, and heated to remove the body. A dry battery with a label that shrinks the excluding end.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58057489A JPH0754697B2 (en) | 1983-04-01 | 1983-04-01 | Labeled dry cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58057489A JPH0754697B2 (en) | 1983-04-01 | 1983-04-01 | Labeled dry cell |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57233087A Division JPH0754696B2 (en) | 1982-12-28 | 1982-12-28 | Dry battery exterior method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59123160A JPS59123160A (en) | 1984-07-16 |
| JPH0754697B2 true JPH0754697B2 (en) | 1995-06-07 |
Family
ID=13057129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58057489A Expired - Lifetime JPH0754697B2 (en) | 1983-04-01 | 1983-04-01 | Labeled dry cell |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0754697B2 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59158067A (en) * | 1983-02-28 | 1984-09-07 | Hitachi Maxell Ltd | Cell |
| CA1296891C (en) * | 1984-08-16 | 1992-03-10 | Rolf Will | Multilayer adhesive label |
| JPS63114050A (en) * | 1986-10-31 | 1988-05-18 | Nippon Carbide Ind Co Ltd | Exterior label for dry batteries |
| JPS63114048A (en) * | 1986-10-31 | 1988-05-18 | Nippon Carbide Ind Co Ltd | Outer label for dry cell and its production |
| US5292566A (en) * | 1990-05-22 | 1994-03-08 | National Label Company | Battery label with non-shrinkable top layer |
| FR2674979B1 (en) * | 1991-04-04 | 1995-10-13 | Rotanotice Sa | PROTECTION AND DECORATION LABEL, PARTICULARLY FOR ELECTRICAL BATTERIES. |
| US5747192A (en) * | 1995-06-07 | 1998-05-05 | Avery Dennison Corporation | Single ply PSA labels for battery applications |
| US5725966A (en) * | 1996-01-25 | 1998-03-10 | Matsushita Electric Industrial Co., Ltd. | Heat sensitive jacket label for battery and battery with the same |
| US6127024A (en) * | 1998-05-21 | 2000-10-03 | Morgan Adhesives Company | Single ply battery label including varnish with patterned edges |
| JP4435568B2 (en) | 2001-10-17 | 2010-03-17 | エーブリー デニソン コーポレイション | Multilayer shrink films and articles encapsulated with them |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5858783B2 (en) * | 1976-04-26 | 1983-12-27 | 日立マクセル株式会社 | dry battery |
| JPS5835349B2 (en) * | 1976-04-27 | 1983-08-02 | 日立マクセル株式会社 | dry battery |
-
1983
- 1983-04-01 JP JP58057489A patent/JPH0754697B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59123160A (en) | 1984-07-16 |
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