JPH07329096A - Large-scale purification cistern - Google Patents
Large-scale purification cisternInfo
- Publication number
- JPH07329096A JPH07329096A JP13226394A JP13226394A JPH07329096A JP H07329096 A JPH07329096 A JP H07329096A JP 13226394 A JP13226394 A JP 13226394A JP 13226394 A JP13226394 A JP 13226394A JP H07329096 A JPH07329096 A JP H07329096A
- Authority
- JP
- Japan
- Prior art keywords
- tank
- rib
- solution
- metathesis
- tank part
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000746 purification Methods 0.000 title 1
- 239000000243 solution Substances 0.000 claims abstract description 53
- 239000000178 monomer Substances 0.000 claims abstract description 30
- -1 cyclic olefin Chemical class 0.000 claims abstract description 23
- 239000003054 catalyst Substances 0.000 claims abstract description 18
- 238000005649 metathesis reaction Methods 0.000 claims abstract description 18
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000004132 cross linking Methods 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 21
- 229920006037 cross link polymer Polymers 0.000 claims description 14
- 239000002685 polymerization catalyst Substances 0.000 claims description 13
- 239000012190 activator Substances 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 8
- 229920000642 polymer Polymers 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 230000004913 activation Effects 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000003365 glass fiber Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 7
- 150000003658 tungsten compounds Chemical class 0.000 description 7
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 6
- 239000011151 fibre-reinforced plastic Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 4
- 239000002879 Lewis base Substances 0.000 description 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 150000007527 lewis bases Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000012779 reinforcing material Substances 0.000 description 3
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 description 3
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010800 human waste Substances 0.000 description 2
- AGQPHHBPENBBIO-UHFFFAOYSA-M iodo(dioctyl)alumane Chemical compound [I-].CCCCCCCC[Al+]CCCCCCCC AGQPHHBPENBBIO-UHFFFAOYSA-M 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- PNRZRBBBDPNPQM-UHFFFAOYSA-N 2-ethylhexyl 5-methylbicyclo[2.2.1]hept-2-ene-5-carboxylate Chemical compound C1C2C(C(=O)OCC(CC)CCCC)(C)CC1C=C2 PNRZRBBBDPNPQM-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- JGLIHSMBVDZMSA-UHFFFAOYSA-N 5-(cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene Chemical compound C1=CC2CC1CC2C1=CCCCC1 JGLIHSMBVDZMSA-UHFFFAOYSA-N 0.000 description 1
- OWETXGRKCLKMMD-UHFFFAOYSA-N 5-(phenoxymethyl)bicyclo[2.2.1]hept-2-ene Chemical compound C1C(C=C2)CC2C1COC1=CC=CC=C1 OWETXGRKCLKMMD-UHFFFAOYSA-N 0.000 description 1
- PSCJIEZOAFAQRM-UHFFFAOYSA-N 5-chlorobicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(Cl)CC1C=C2 PSCJIEZOAFAQRM-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Natural products CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- ROQVLEJBZBDIMF-UHFFFAOYSA-N C.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O Chemical compound C.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O.C=CC(C)(C)C=1C(=C(C=C(C=CC(=O)O)C1)C(C)(C)C)O ROQVLEJBZBDIMF-UHFFFAOYSA-N 0.000 description 1
- KNOVZEUMNAFMCY-UHFFFAOYSA-N C12CCC(C=C1)C2.C21CCC(C=C2)C1.C=C Chemical compound C12CCC(C=C1)C2.C21CCC(C=C2)C1.C=C KNOVZEUMNAFMCY-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- BMAXQTDMWYDIJX-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-ene-5-carbonitrile Chemical compound C1C2C(C#N)CC1C=C2 BMAXQTDMWYDIJX-UHFFFAOYSA-N 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- BWKCCRPHMILRGD-UHFFFAOYSA-N chloro hypochlorite;tungsten Chemical compound [W].ClOCl BWKCCRPHMILRGD-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 150000001925 cycloalkenes Chemical group 0.000 description 1
- NOSWQDCFTDHNCM-UHFFFAOYSA-N cyclopenta-1,3-diene;1-methylcyclopenta-1,3-diene Chemical compound C1C=CC=C1.CC1=CC=CC1 NOSWQDCFTDHNCM-UHFFFAOYSA-N 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000010840 domestic wastewater Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005323 electroforming Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 125000005462 imide group Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- RMAZRAQKPTXZNL-UHFFFAOYSA-N methyl bicyclo[2.2.1]hept-2-ene-5-carboxylate Chemical compound C1C2C(C(=O)OC)CC1C=C2 RMAZRAQKPTXZNL-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- JFKBLKGQCUHUHJ-UHFFFAOYSA-N tricyclo[6.2.1.02,7]undec-9-ene Chemical compound C12CCCCC2C2CC1C=C2 JFKBLKGQCUHUHJ-UHFFFAOYSA-N 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Injection Moulding Of Plastics Or The Like (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は軽量で衝突に対して強
く、且つ耐久性に優れた大型浄化槽に関するものであ
る。また本発明は繊維強化の必要もなく、リサイクルが
可能であり、さらに廃棄焼却処分時有害ガスを発生しな
い無公害な、一体成形された大型浄化槽に関するもので
ある。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a large-sized septic tank which is lightweight, resistant to collision and excellent in durability. The present invention also relates to a pollution-free, integrally-molded large-sized septic tank that does not require fiber reinforcement, can be recycled, and does not generate harmful gas during waste incineration.
【0002】[0002]
【従来の技術】従来、浄化槽の多くは繊維強化プラスチ
ック(FRP)を使用して成形されている。特にガラス
繊維で強化した不飽和ポリエステル樹脂を使用して成形
されている。このガラス繊維で強化した不飽和ポリエス
テル樹脂を用いて浄化槽を成形する場合、ガラス繊維を
含んだ大量の粉塵が発生し、作業環境が劣悪となる問題
があった。その上かかるFRPを使用した浄化槽は重量
も大きく、また運搬時落とした場合や施工時小石があた
った場合、その衝撃によって容易に割れ目が発生すると
いう欠点があった。さらにFRPの成形品は、ガラス繊
維入りのため廃棄時に破砕、粉砕が困難であり、また焼
却してもガラス繊維が大量に残りその処理に手間を要し
ていた。2. Description of the Related Art Conventionally, most septic tanks are molded using fiber reinforced plastic (FRP). In particular, it is molded using an unsaturated polyester resin reinforced with glass fiber. When a septic tank is formed by using this unsaturated polyester resin reinforced with glass fibers, there is a problem that a large amount of dust containing glass fibers is generated and the working environment becomes poor. In addition, such a septic tank using FRP has a heavy weight, and has a drawback that cracks easily occur due to the impact when dropped during transportation or hit by pebbles during construction. Further, since the FRP molded product contains glass fiber, it is difficult to crush and crush it at the time of disposal, and even if it is incinerated, a large amount of glass fiber remains and it takes a lot of time to process it.
【0003】本発明者らの一部は、これらの解決策とし
て、少なくとも上槽部および下槽部は、メタセシス重合
触媒系の触媒成分を含有するメタセシス重合性環状オレ
フィンからなるモノマー液A(溶液A)とメタセシス重
合触媒系の活性化剤成分を含有するメタセシス重合性環
状オレフィンからなるモノマー液B(溶液B)とを混合
し、その原料混合液を金型内に注入しその金型内におい
て重合および架橋反応せしめることによって得られた架
橋重合体成形品が大型浄化槽として有用であることを見
い出し、先に、特許出願を行った(特願平5−2850
97号明細書;平成5年1月15日出願)。As a solution to these problems, some of the inventors of the present invention at least in the upper tank portion and the lower tank portion include a monomer liquid A (solution) composed of a metathesis-polymerizable cyclic olefin containing a catalyst component of a metathesis polymerization catalyst system. A) and a monomer liquid B (solution B) composed of a metathesis-polymerizable cyclic olefin containing an activator component of a metathesis polymerization catalyst system are mixed, and the raw material mixed liquid is injected into the mold, It was found that the crosslinked polymer molded product obtained by the polymerization and the crosslinking reaction is useful as a large-scale septic tank, and the patent application was previously filed (Japanese Patent Application No. 5-2850).
No. 97 specification; filed on January 15, 1993).
【0004】しかし、該大型浄化槽は浄化槽としての良
好な結果をもたらすが、成形材質そのものが持つ低弾性
率のため、フランジ部の厚みが薄く、且つフランジ部を
ボルト等で固定すると、ボルト間の中央部の変形量が大
きくなり、耐水漏れ性において必ずしも十分でない場合
があることが判明した。However, although the large septic tank gives good results as a septic tank, since the molding material itself has a low elastic modulus, when the flange portion is thin and the flange portion is fixed with bolts, etc. It was found that the amount of deformation in the central part became large and the water leakage resistance was not always sufficient.
【0005】[0005]
【発明が解決しようとする課題】本発明の目的は繊維強
化プラスチック(FRP)の欠点である作業環境問題、
重量的に重く、且つ衝撃強度が低い等の解決策として提
案した少なくとも上槽部および下槽部は、メタセシス重
合触媒系の触媒成分を含有するメタセシス重合性環状オ
レフィンからなるモノマー液A(溶液A)とメタセシス
重合触媒系の活性化剤成分を含有するメタセシス重合性
環状オレフィンからなるモノマー液B(溶液B)とを混
合し、その原料混合液を金型内に注入しその金型内にお
いて重合および架橋反応せしめることによって得られた
架橋重合体成形品であって、上槽部フランジ/下槽部フ
ランジ間、上槽部フランジ/中槽部フランジ間または中
槽部フランジ/下槽部フランジ間の接合部からの液漏れ
が起こらず、長期間使用することができる大型浄化槽を
提供することにある。The object of the present invention is to solve the problem of working environment which is a drawback of fiber reinforced plastics (FRP).
At least the upper tank portion and the lower tank portion, which have been proposed as a solution to the problem of being heavy in weight and having low impact strength, at least the upper tank portion and the lower tank portion are composed of a monomer liquid A (solution A containing a metathesis polymerizable cyclic olefin containing a catalyst component of a metathesis polymerization catalyst system). ) And a monomer liquid B (solution B) composed of a metathesis-polymerizable cyclic olefin containing an activator component of a metathesis polymerization catalyst system, and the raw material mixed liquid is injected into the mold to polymerize in the mold. And a cross-linked polymer molded product obtained by causing a cross-linking reaction, between the upper tank part flange / lower tank part flange, the upper tank part flange / middle tank part flange, or the middle tank part flange / lower tank part flange. It is intended to provide a large-scale septic tank which can be used for a long period of time without liquid leakage from the joint part of.
【0006】[0006]
【課題を解決するための手段】本発明者らは前記本発明
の目的を解決するために鋭意研究を進めた結果、大型浄
化槽の各槽部を連結するフランジ部に剛性を向上するた
めの格子状リブを付与することによって、接合部からの
液漏れが起こらなくなることを見い出し、本発明に到達
した。DISCLOSURE OF THE INVENTION As a result of intensive studies conducted by the present inventors in order to solve the above-mentioned object of the present invention, a grid for improving rigidity in a flange portion connecting each tank portion of a large-scale septic tank. The present invention has been completed by finding that the liquid leakage from the joint portion does not occur by providing the ribs.
【0007】すなわち、本発明は、上槽部および下槽部
より構成されるか或いは上槽部、下槽部およびそれらを
連結する板状帯の中間槽部より構成される大型浄化槽で
あって、該大型浄化槽は、(1)少なくとも上槽部およ
び下槽部は、メタセシス重合触媒系の触媒成分を含有す
るメタセシス重合性環状オレフィンからなるモノマー液
A(溶液A)とメタセシス重合触媒系の活性化剤成分を
含有するメタセシス重合性環状オレフィンからなるモノ
マー液B(溶液B)とを混合し、その原料混合液を金型
内に注入しその金型内において重合および架橋反応せし
めることによって得られた架橋重合体成形品であり、
(2)上槽部および下槽部、或いは上槽部、中間槽部お
よび下槽部は、互いに接合する部分に設けられたフラン
ジを介して接合するような構造を有し、そして(3)そ
れぞれのフランジ部において、その接合面と反対側の面
に格子状リブを有する、ことを特徴とする大型浄化槽で
ある。That is, the present invention is a large-scale septic tank composed of an upper tank part and a lower tank part, or an upper tank part, a lower tank part and an intermediate tank part of a plate-shaped belt connecting them. The large-scale septic tank has (1) at least an upper tank portion and a lower tank portion, a monomer liquid A (solution A) made of a metathesis polymerizable cyclic olefin containing a catalyst component of a metathesis polymerization catalyst system and an activity of the metathesis polymerization catalyst system. It is obtained by mixing a monomer liquid B (solution B) composed of a metathesis-polymerizable cyclic olefin containing an agent component, injecting the raw material mixed liquid into a mold, and causing polymerization and crosslinking reaction in the mold. Is a cross-linked polymer molded article,
(2) The upper tank part and the lower tank part, or the upper tank part, the intermediate tank part, and the lower tank part have a structure in which they are joined via a flange provided in a portion to be joined to each other, and (3) The large septic tank is characterized in that each of the flange portions has a grid-like rib on the surface opposite to the joining surface.
【0008】かかる本発明によれば槽容量が2m3以
上、好ましくは3〜15m3、特に好ましくは3〜12
m3の大型の浄化槽が提供される。According to the present invention, the tank volume is 2 m 3 or more, preferably 3 to 15 m 3 , and particularly preferably 3 to 12
A large m 3 septic tank is provided.
【0009】以下本発明についてさらに具体的に説明す
る。本発明の浄化槽を構成する架橋重合体を形成するた
めのメタセシス重合性環状オレフィンとしては、メタセ
シス重合性シクロアルケン基を分子中に1〜2個含有す
るものが使用される。好ましくはノルボルネン骨格を分
子中に少なくとも1つ有する化合物である。これらの具
体例としては、ジシクロペンタジエン、トリシクロペン
タジエン、シクロペンタジエン−メチルシクロペンタジ
エン共二量体、5−エチリデンノルボルネン、ノルボル
ネン、ノルボルナジエン、5−シクロヘキセニルノルボ
ルネン、1,4,5,8−ジメタノ−1,4,4a,5,6,
7,8,8a−オクタヒドロナフタレン、1,4−メタノ
−1,4,4a,5,6,7,8,8a−オクタヒドロナフタ
レン、6−エチリデン−1,4,5,8−ジメタノ−1,
4,4a,5,6,7,8,8a−オクタヒドロナフタレン、
6−エチリデン−1,4,5,8−ジメタノ−1,4,4a,
5,6,7,8,8a−ヘプタヒドロナフタレン、1,4,
5,8−ジメタノ−1,4,4a,5,6,7,8,8a−ヘキ
サヒドロナフタレン、エチレンビス(5−ノルボルネ
ン)などを挙げることができこれらの混合物も使用する
ことができる。特にジシクロペンタジエンまたはそれを
50モル%以上、好ましくは70モル%以上含む混合物
が好適に用いられる。The present invention will be described in more detail below. As the metathesis-polymerizable cyclic olefin for forming the crosslinked polymer that constitutes the septic tank of the present invention, those containing 1-2 metathesis-polymerizable cycloalkene groups in the molecule are used. A compound having at least one norbornene skeleton in the molecule is preferable. Specific examples thereof include dicyclopentadiene, tricyclopentadiene, cyclopentadiene-methylcyclopentadiene co-dimer, 5-ethylidene norbornene, norbornene, norbornadiene, 5-cyclohexenyl norbornene, 1,4,5,8-dimethano -1,4,4a, 5,6,
7,8,8a-octahydronaphthalene, 1,4-methano-1,4,4a, 5,6,7,8,8a-octahydronaphthalene, 6-ethylidene-1,4,5,8-dimethano- 1,
4,4a, 5,6,7,8,8a-octahydronaphthalene,
6-ethylidene-1,4,5,8-dimethano-1,4,4a,
5,6,7,8,8a-heptahydronaphthalene, 1,4,
5,8-Dimethano-1,4,4a, 5,6,7,8,8a-hexahydronaphthalene, ethylene bis (5-norbornene) and the like can be mentioned, and a mixture thereof can also be used. Particularly, dicyclopentadiene or a mixture thereof containing 50 mol% or more, preferably 70 mol% or more is suitably used.
【0010】また、必要に応じて、酸素、窒素などの異
種元素を含有する極性基を有するメタセシス重合性環状
オレフィンを共重合モノマーとして用いることができ
る。かかる共重合モノマーも、ノルボルネン構造単位を
有するものが好ましく且つ極性基としてはエステル基、
エーテル基、シアノ基、N−置換イミド基、ハロゲン基
などが好ましい。かかる共重合モノマーの具体例として
は、5−メトキシカルボニルノルボルネン、5−(2−
エチルヘキシロキシ)カルボニル−5−メチルノルボル
ネン、5−フェニロキシメチルノルボルネン、5−シア
ノノルボルネン、6−シアノ−1,4,5,8−ジメタノ
−1,4,4a,5,6,7,8,8a−オクタヒドロナフタ
レン、N−ブチルナデック酸イミド、5−クロルノルボ
ルネンなどを挙げることができる。If necessary, a metathesis-polymerizable cyclic olefin having a polar group containing a different element such as oxygen and nitrogen can be used as a copolymerization monomer. Such a copolymerizable monomer also preferably has a norbornene structural unit, and the polar group is an ester group,
Ether groups, cyano groups, N-substituted imide groups, halogen groups and the like are preferable. Specific examples of the copolymerization monomer include 5-methoxycarbonylnorbornene and 5- (2-
Ethylhexyloxy) carbonyl-5-methylnorbornene, 5-phenyloxymethylnorbornene, 5-cyanonorbornene, 6-cyano-1,4,5,8-dimethano-1,4,4a, 5,6,7,8 Examples include 8,8a-octahydronaphthalene, N-butyl nadecimide, 5-chloronorbornene, and the like.
【0011】本発明におけるモノマー液A(溶液A)中
には、メタセシス重合触媒系の触媒成分が含有されてい
る。かかる触媒成分としては、タングステン、レニウ
ム、タンタル、モリブデンなどの金属のハライドなどの
塩類が用いられるが、特にタングステン化合物が好まし
い。かかるタングステン化合物としては、タングステン
ヘキサハライド、タングステンオキシハライドなどが好
ましく、より具体的にはタングステンヘキサクロライ
ド、タングステンオキシクロライドなどが好ましい。ま
た、有機アンモニウムタングステン酸塩なども用いるこ
とができる。かかるタングステン化合物は、直接モノマ
ーに添加すると、直ちにカチオン重合を開始することが
分かっており好ましくない。従って、かかるタングステ
ン化合物は不活性溶媒、例えばベンゼン、トルエン、ク
ロロベンゼンなどに予め懸濁し、少量のアルコール系化
合物および/またはフェノール系化合物を添加すること
によって可溶化させて使用するのが好ましい。さらに上
述した如き、好ましくない重合を予防するためにタング
ステン化合物1モルに対し、約1〜5モルのルイス塩基
またはキレート化剤を添加することが好ましい。かかる
添加剤としてはアセチルアセトン、アセト酢酸アルキル
エステル類、テトラヒドロフラン、ベンゾニトリルなど
を挙げることができる。極性モノマーを用いる場合に
は、前述の如く、そのものがルイス塩基である場合があ
り、上記の如き化合物を特に加えなくてもその作用を有
している場合もある。前述の如くして、触媒成分を含む
モノマー液A(溶液A)は、実質上充分な安定性を有す
ることになる。The monomer solution A (solution A) in the present invention contains a catalyst component of a metathesis polymerization catalyst system. As the catalyst component, salts such as halides of metals such as tungsten, rhenium, tantalum and molybdenum are used, and tungsten compounds are particularly preferable. As such a tungsten compound, tungsten hexahalide, tungsten oxyhalide, etc. are preferable, and more specifically, tungsten hexachloride, tungsten oxychloride, etc. are preferable. Further, organic ammonium tungstate or the like can also be used. It has been found that when such a tungsten compound is directly added to the monomer, it immediately starts cationic polymerization, which is not preferable. Therefore, such a tungsten compound is preferably suspended in an inert solvent such as benzene, toluene, chlorobenzene and the like in advance and solubilized by adding a small amount of an alcohol compound and / or a phenol compound to be used. Further, as described above, it is preferable to add about 1 to 5 mol of Lewis base or chelating agent to 1 mol of the tungsten compound in order to prevent undesired polymerization. Examples of such additives include acetylacetone, acetoacetic acid alkyl esters, tetrahydrofuran, and benzonitrile. When a polar monomer is used, it may be a Lewis base itself as described above, and it may have its action even if the above compound is not added. As described above, the monomer liquid A (solution A) containing the catalyst component has substantially sufficient stability.
【0012】一方、本発明におけるモノマー液B(溶液
B)中には、メタセシス重合触媒系の活性化剤成分が含
有されている。この活性剤化成分は、周期律表第I〜第
III族の金属のアルキル化物を中心とする有機金属化
合物、特にテトラアルキル錫、アルキルアルミニウム化
合物、アルキルアルミニウムハライド化合物が好まし
く、具体的には塩化ジエチルアルミニウム、ジ塩化エチ
ルアルミニウム、トリオクチルアルミニウム、ジオクチ
ルアルミニウムアイオダイド、テトラブチル錫などを挙
げることができる。これら活性化剤成分としての有機金
属化合物をモノマーに溶解することにより、モノマー液
B(溶液B)が形成される。On the other hand, the monomer liquid B (solution B) in the present invention contains an activator component of the metathesis polymerization catalyst system. This activator component is preferably an organometallic compound centered on an alkylated compound of a metal of Group I to Group III of the Periodic Table, particularly a tetraalkyltin, an alkylaluminum compound, an alkylaluminum halide compound, and specifically a chloride. Examples thereof include diethyl aluminum, diethyl aluminum chloride, trioctyl aluminum, dioctyl aluminum iodide, and tetrabutyl tin. A monomer liquid B (solution B) is formed by dissolving the organometallic compound as the activator component in the monomer.
【0013】基本的には前記溶液Aおよび溶液Bを混合
し、金型内に注入することによって、目的とする架橋重
合体の成形品を得ることができるが、上記組成のままで
は、重合反応が非常に速く開始されるので、成形金型に
十分流れ込まない間に硬化が起こることもあり、度々問
題となる場合が多い。従って、活性調節剤を用いること
が好ましい。かかる調節剤としては、ルイス塩基類が一
般に用いられ、なかんずく、エーテル類、エステル類、
ニトリル類などが用いられる。具体例としては安息香酸
エチル、ブチルエーテル、ジグライムなどを挙げること
ができる。かかる調節剤は一般的に、有機金属化合物の
活性化剤の成分の溶液(溶液B)の側に添加して用いら
れる。前述と同様にルイス塩基を有するモノマーを使用
する場合には、それを調節剤の役目を兼ねさせることが
できる。Basically, the solution A and the solution B are mixed and poured into a mold to obtain a molded article of the desired crosslinked polymer. Is initiated very quickly, so that curing can occur before it has flowed sufficiently into the mold, which is often a problem. Therefore, it is preferable to use an activity regulator. As such a regulator, Lewis bases are generally used, among others, ethers, esters,
Nitriles and the like are used. Specific examples include ethyl benzoate, butyl ether, diglyme and the like. Such a regulator is generally used by adding it to the solution (solution B) side of the component of the activator of the organometallic compound. When a monomer having a Lewis base is used as described above, it can also serve as a regulator.
【0014】メタセシス重合触媒系の使用量は、例えば
触媒成分としてタングステン化合物を用いる場合は、上
記原料モノマーに対するタングステン化合物の比率は、
モル基準で約1,000対1〜15,000対1、好まし
くは2,000対1の付近であり、また、活性化剤成分
はアルキルアルミニウム類を用いる場合には、上記原料
モノマーに対するアルミニウム化合物の比率は、モル基
準で約100対1〜10,000対1、好ましくは20
0対1〜500対1の付近が用いられる。さらに上述し
た如き、マスク剤や調節剤については、実験によって上
記触媒系の使用量に応じて、適宜調節して用いることが
できる。The amount of the metathesis polymerization catalyst system used is, for example, when a tungsten compound is used as the catalyst component, the ratio of the tungsten compound to the raw material monomer is
It is about 1,000 to 15,000 to 1, preferably about 2,000 to 1 on a molar basis, and when an alkylaluminum is used as the activator component, an aluminum compound for the above raw material monomer is used. The ratio of about 100 to 1 to 10,000 to 1, preferably 20.
The vicinity of 0: 1 to 500: 1 is used. Further, as described above, the masking agent and the adjusting agent can be appropriately adjusted and used depending on the amount of the catalyst system used by experiments.
【0015】本発明の成形品は、基本的には、前記した
溶液Aおよび溶液Bを混合して金型内へ注入することに
より得ることができる。その際溶液Aおよび溶液Bを混
合することによって形成されるメタセシス触媒系の触媒
活性は、両溶液を混合した時から混合液が流動性を失う
までの時間で表わすことができる。すなわち、この流動
性を失うまでの時間を、両溶液を攪拌機を備えたガラス
容器中に入れてからその攪拌機の攪拌軸に溶液がゲル化
して絡み出すまでの時間と定義すれば、本発明の溶液A
および溶液Bは、30℃で前記流動性を失う時間が1〜
120秒、好ましくは2〜100秒の間であることが望
ましい。The molded article of the present invention can basically be obtained by mixing the above-mentioned solution A and solution B and injecting them into a mold. At that time, the catalytic activity of the metathesis catalyst system formed by mixing the solution A and the solution B can be expressed by the time from when the two solutions are mixed to when the mixed solution loses fluidity. That is, if the time until the fluidity is lost is defined as the time from when both solutions are put in a glass container equipped with a stirrer until the solution gels and entangles with the stirring shaft of the stirrer, Solution A
And the solution B has a time of 1 to 1 at which the fluidity is lost at 30 ° C.
It is desired to be 120 seconds, preferably between 2 and 100 seconds.
【0016】本発明によって得られる架橋重合体の成形
品には、実用に当ってその特性を改良または維持するた
めに更にその目的に応じた各種添加剤を配合することが
できる。かかる添加剤としては、充填剤、顔料、酸化防
止剤、光安定剤、難燃剤、高分子改良剤などがある。こ
のような添加剤は、本発明の架橋重合体が成形されて後
は添加することが不可能であるから添加する場合には予
め前述した原料溶液に添加しておく必要がある。The molded article of the crosslinked polymer obtained according to the present invention may further contain various additives depending on the purpose in order to improve or maintain the characteristics in practical use. Such additives include fillers, pigments, antioxidants, light stabilizers, flame retardants, polymer modifiers and the like. Such additives cannot be added after the crosslinked polymer of the present invention has been molded, and therefore, when added, it is necessary to add them to the above-mentioned raw material solution in advance.
【0017】その最も容易な方法としては、前記溶液A
および溶液Bのいずれかまたは両方に前もって添加して
おく方法を挙げることができるが、その場合、その液中
の反応性の強い触媒成分、活性化剤成分と実用上差支え
ある程度には反応せず、且つ重合を阻害しないものでな
くてはならない。どうしても、その反応が避け得ないも
のが共存しても、重合は実質的に阻害しないものの場合
は、モノマーと混合して、第三液を調製し、重合直前に
混合使用することもできる。また、重合触媒または活性
化剤を第三液とし、これを含まない溶液Aまたは溶液B
に上記添加物を添加する方法も考えられる。さらに、固
体の充填剤の場合であって、両成分が混合されて、重合
反応を開始する直前あるいは重合しながら、その空隙を
充分に埋め得る形状の物については、成形型内に、充填
しておくことも可能である。添加剤としての補強材また
は充填剤は、曲げモジュラスを向上するのに効果があ
る。かかるものとしては、ガラス繊維、雲母、カーボン
ブラック、ウオラストナイトなどを挙げることができ
る。これらを、いわゆるシランカップラーなどによって
表面処理したものを好適に使用できる。The easiest method is the solution A described above.
And a solution B may be added in advance to either or both of them, but in that case, they do not react to a certain extent with the catalyst component and activator component having strong reactivity in the liquid and do not react to some extent. , And it should not interfere with the polymerization. If the reaction does not substantially hinder the polymerization even when the reaction is unavoidable, it is possible to prepare a third liquid by mixing with the monomer and mix and use it immediately before the polymerization. Further, the polymerization catalyst or activator is used as the third liquid, and solution A or solution B containing no third catalyst is used.
A method of adding the above-mentioned additive to the above is also considered. Further, in the case of a solid filler, when the two components are mixed and the shape is such that the voids can be sufficiently filled immediately before starting the polymerization reaction or during the polymerization, it is filled in the molding die. It is also possible to keep it. Reinforcing agents or fillers as additives are effective in improving the bending modulus. Examples of such a material include glass fiber, mica, carbon black, wollastonite and the like. Those obtained by surface-treating these with a so-called silane coupler can be preferably used.
【0018】また、本発明による成形物は、酸化防止剤
を添加しておくことが好ましく、そのため、フェノール
系またはアミン系の酸化防止剤を予め溶液中に加えてお
くことが望ましい。これら酸化防止剤の具体例として
は、2,6−ジ−t−ブチル−p−クレゾール、N,N'
−ジフェニル−p−フェニレンジアミン、テトラキス
[メチレン(3,5−ジ−t−ブチル−4−ヒドロキシ
シンナメート)]メタンなどが挙げられる。Further, it is preferable to add an antioxidant to the molded article according to the present invention. Therefore, it is desirable to add a phenol type or amine type antioxidant to the solution in advance. Specific examples of these antioxidants include 2,6-di-t-butyl-p-cresol and N, N '.
-Diphenyl-p-phenylenediamine, tetrakis [methylene (3,5-di-t-butyl-4-hydroxycinnamate)] methane and the like.
【0019】また、本発明の成形物は、他の重合体を成
形時にモノマー溶液状態の時に添加しておいて得ること
ができる。かかる重合体添加剤としてはエラストマーの
添加が、成形物の耐衝撃性を高めることおよび溶液の粘
度を調節する上で効果がある。かかる目的に用いられる
エラストマーとしては、スチレン−ブタジエン−スチレ
ントリブロックゴム、スチレン−イソプレン−スチレン
トリブロックゴム、ポリブタジエン、ポリイソプレン、
ブチルゴム、エチレンプロピレン−ジエンターポリマ
ー、ニトリルゴムなど広範なエラストマーを挙げること
ができる。Further, the molded product of the present invention can be obtained by adding another polymer in a monomer solution state at the time of molding. As such a polymer additive, the addition of an elastomer is effective in enhancing the impact resistance of the molded product and controlling the viscosity of the solution. Elastomers used for such purpose include styrene-butadiene-styrene triblock rubber, styrene-isoprene-styrene triblock rubber, polybutadiene, polyisoprene,
There may be mentioned a wide range of elastomers such as butyl rubber, ethylene propylene-diene terpolymer, nitrile rubber.
【0020】本発明の浄化槽を成形するための型の材質
としては、スチール、鋳造あるいは鍛造のアルミニウ
ム、亜鉛合金などの鋳造や溶射、ニッケルや銅などの電
鋳および樹脂などが挙げられる。また型の構造は成形時
に型内に発生する圧力が数kg/cm2と他の成形方法
に比べて極めて低いので簡単なもので十分であり、従っ
て他の成形方法の型に比べて安価に作ることができる。Examples of the material of the mold for molding the septic tank of the present invention include steel, cast or forged aluminum, casting of zinc alloy and the like, thermal spraying, electroforming of nickel and copper, and resin. Also, the structure of the mold is sufficient because the pressure generated in the mold at the time of molding is several kg / cm 2 , which is extremely low compared to other molding methods, and is therefore simpler and cheaper than molds of other molding methods. Can be made.
【0021】本発明の環状オレフィン架橋重合体成形品
の特長の一つは耐衝撃性の優れていることであり落下さ
せてもまた小石などの固形物が衝突しても容易に壊れる
ことはない。さらに本発明の成形品は基本的にはガラス
繊維などの補強材を特に用いる必要はない。そのため曲
げ弾性率はこれらの補強材を用いたものと比べて一般に
低くなる。本発明者らは、これを解決する手段として特
定構造の凹凸状のリブを有した形状が大型浄化槽に有効
であることを既に提案した(特願平5−285097号
明細書;平成5年11月15日出願)。この先に提案し
た大型浄化槽は、上槽部および下槽部より構成されるか
或いは上槽部、下槽部およびそれらを連結する板状帯の
中間槽部より構成される大型浄化槽であって、該大型浄
化槽は、(1)前記環状オレフィンの架橋重合体成形品
であり、(2)少なくとも上槽部および下槽部は、縦方
向に角形凹凸リブを有し、その凹凸リブは浄化槽の横方
向の巾の長さに対し平均して1m当たり1.5〜5個有
し、且つ(3)それぞれの凹凸リブは下記形状特性
(i)〜(iv) (i) 10≦H≦50 (ii) 30≦W≦200 (iii)2≦R<H、2≦R'<H (iv) 3≦t [但し、tは凹凸リブの長さ方向に対する直角断面の成
形品の平均厚さを示し、Hは成形品表面からの凸部の高
さを示し、Wは凹凸部の巾を示し、RおよびR'は、そ
れぞれ凹凸部の屈曲部の半径を示す。t、H、W、Rお
よびR'の単位はミリ(mm)で表わされる。]を満足
する点に特徴を有している。本発明の大型浄化槽は、こ
のようなリブを有することができ、むしろその方が好ま
しい。また中間槽部が設けられる場合、中間槽部にも同
様のリブを有することができる。One of the features of the cyclic olefin cross-linked polymer molded article of the present invention is that it has excellent impact resistance and is not easily broken even when dropped or when solid matter such as pebbles collides. . Further, the molded article of the present invention basically does not need to use a reinforcing material such as glass fiber. Therefore, the flexural modulus is generally lower than those using these reinforcing materials. As a means for solving this, the present inventors have already proposed that a shape having an uneven rib having a specific structure is effective for a large-scale septic tank (Japanese Patent Application No. 5-285097; November 1993). 15th application a month). The large septic tank proposed earlier is a large septic tank composed of an upper tank part and a lower tank part, or an upper tank part, a lower tank part and an intermediate tank part of a plate-shaped belt connecting them, The large-sized septic tank is (1) a cross-linked polymer molded product of the cyclic olefin, and (2) at least the upper tank portion and the lower tank portion have rectangular concave and convex ribs in the longitudinal direction, and the concave and convex ribs are lateral to the septic tank. The average length of the width in the direction is 1.5 to 5 per 1 m, and (3) each of the uneven ribs has the following shape characteristics (i) to (iv) (i) 10 ≦ H ≦ 50 ( ii) 30 ≦ W ≦ 200 (iii) 2 ≦ R <H, 2 ≦ R ′ <H (iv) 3 ≦ t [where t is the average thickness of the molded product in a cross section perpendicular to the length direction of the uneven ribs] , H indicates the height of the convex portion from the surface of the molded product, W indicates the width of the concave and convex portion, and R and R ′ are Each shows the radius of the bent portion of the uneven portion. The units of t, H, W, R and R'are expressed in millimeters (mm). ] Is characterized in that it satisfies. The large septic tank of the present invention may have such ribs, and is rather preferable. When the intermediate tank portion is provided, the intermediate tank portion can also have the same rib.
【0022】次に本発明の大型浄化槽の構造について図
面により説明する。本発明の大型浄化槽は、基本的には
2個または3個の部材より構成される。すなわち、上槽
部および下槽部の2個の部材より構成されるか、あるい
は上槽部、下槽部およびそれらを連結する板状帯の中間
槽部の3個より構成される。Next, the structure of the large-scale septic tank of the present invention will be described with reference to the drawings. The large-scale septic tank of the present invention is basically composed of two or three members. That is, it is composed of two members, an upper tank part and a lower tank part, or is composed of three members, an upper tank part, a lower tank part, and a plate-shaped intermediate tank part connecting them.
【0023】図1には本発明の大型浄化槽の1例が示さ
れておりAはその正面図であり、Bはその側面図であ
る。図1において1は上槽部であり2は下槽部である。
図1において上槽部1と下槽部2とはフランジ3および
3'によって固定される。また上槽部1と下槽部2と
は、それらを連結する板状帯の中間槽部より固定されて
いてもよい。この中間槽部は図1には示されていない。
中間槽部は、上槽部と下槽部とを通常フランジを介して
その両者の間に固く固定される。この中間槽部を設ける
ことにより、内容積が増大した浄化槽とすることができ
る。また図1の大型浄化槽では上槽部および下槽部にそ
れぞれリブ4、4'が縦方向に設けられている(凹凸リ
ブの数は図1の場合、正面図で4本、側面図で2本であ
る)。FIG. 1 shows an example of a large-scale septic tank of the present invention, A is a front view thereof, and B is a side view thereof. In FIG. 1, 1 is an upper tank part and 2 is a lower tank part.
In FIG. 1, the upper tank portion 1 and the lower tank portion 2 are fixed by flanges 3 and 3 '. Further, the upper tank portion 1 and the lower tank portion 2 may be fixed to each other by a plate-shaped intermediate tank portion connecting them. This intermediate tank part is not shown in FIG.
The intermediate tank portion is fixed between the upper tank portion and the lower tank portion, usually via a flange, between them. By providing this intermediate tank portion, a septic tank having an increased internal volume can be obtained. Further, in the large-sized septic tank of FIG. 1, ribs 4 and 4 ′ are provided in the vertical direction in the upper tank portion and the lower tank portion, respectively (the number of concave and convex ribs is four in the front view and two in the side view in FIG. 1). Is a book).
【0024】本発明の大型浄化槽は、少なくとも上槽部
および下槽部は、前述したメタセシス重合性環状オレフ
ィンの架橋重合体の成形品であり、好ましくは上槽部、
下槽部および中間槽部の全てがこの架橋重合体の成形品
である。これら上槽部、下槽部および中間槽部のそれぞ
れは、一体成形品である点にも特徴を有している。In the large-scale septic tank of the present invention, at least the upper tank portion and the lower tank portion are molded products of the crosslinked polymer of the metathesis-polymerizable cyclic olefin described above, preferably the upper tank portion,
All of the lower tank portion and the intermediate tank portion are molded products of this crosslinked polymer. Each of the upper tank portion, the lower tank portion, and the intermediate tank portion is also characterized in that they are integrally molded products.
【0025】浄化槽は一旦設置すると10〜20年以上
の長期にわたって使用されるものであり、またその内部
に水が入るので内部に水圧がかかり、さらに地下に埋設
した場合、土砂や地下水によって外側からも圧力が常に
かかるなど、耐久性および耐熱性も厳しさが要求され
る。Once the septic tank is installed, it will be used for a long period of 10 to 20 years or more, and water will enter the inside of the septic tank, so that water pressure will be applied to the inside of the septic tank. The durability and heat resistance are also required to be severe, such as the constant pressure.
【0026】かかる厳しい要求特性に対し、本発明の大
型浄化槽は以下に説明する上槽部と下槽部或いは上槽
部、下槽部およびそれらを連結する板状帯の中間槽部の
接合部に設けられた特定のフランジにて固定することに
よって、前記要求特性を克服したものである。In order to meet such strict requirements, the large-scale septic tank of the present invention has an upper tank portion and a lower tank portion described below or a joint portion of an upper tank portion, a lower tank portion and an intermediate tank portion of a plate-like belt connecting them. The above-mentioned required characteristics are overcome by fixing with a specific flange provided on the.
【0027】すなわち、本発明の成形品は、ガラス繊維
等の補強材を含有しないため素材自体は剛性が少ないに
も拘らず、フランジ部の接着面とは反対の面に格子状の
リブを付与して剛性を向上させたものであり、内圧およ
び外圧による水漏れに耐える構造物となっている。That is, since the molded article of the present invention does not contain a reinforcing material such as glass fiber, the material itself has a low rigidity, but a rib in a grid pattern is provided on the surface opposite to the adhesive surface of the flange portion. It has improved rigidity and is a structure that can withstand water leakage due to internal pressure and external pressure.
【0028】また、素材自体の剛性を補うものとして凹
凸のリブの形状を浄化槽の縦方向に設けられていてもよ
く、底部の剛性を増すために、底部にも凹凸リブ付けて
もよい。これらの補強構造は浄化槽本体との一体成形品
として得られる点にも特徴を有している。Further, in order to supplement the rigidity of the material itself, an uneven rib shape may be provided in the longitudinal direction of the septic tank, and in order to increase the rigidity of the bottom part, the uneven part may be provided on the bottom part. These reinforcing structures are also characterized in that they can be obtained as an integrally molded product with the septic tank body.
【0029】図2のCにはフランジ部における接合面と
反対の面に設けられる格子状リブの横断面図が模式的に
示されている。図2のCにおいて、5はフランジ部分で
あり、6はフランジ部分における接合面を示す。その接
合面6の反対側の面には格子状リブ7、7’が設けられ
ている。格子状リブ7、7’の高さはhであり、格子状
リブの巾はwで示されている。図2のCにおいて、格子
状リブの高さhは、好ましくは2〜15mmの範囲であ
り、特に好ましくは5〜12mmの範囲である。高さh
が2mmよりも小さい場合、構造体の剛性の向上が少な
くなり、一方15mmを越えると格子リブ深さが大きす
ぎ、成形時の取扱いが面倒となる。格子状のリブはそれ
ぞれのリブ高さが同じである必要性はない。リブ巾w
は、好ましくは2.5〜5mmの範囲であり、特に好ま
しくは3〜4mmの範囲である。巾wは2.5mmより
も小さい場合、素材のもつ長期物性特性上好ましくな
く、5mmより厚い場合には、軽量化に寄与しなくな
る。[0029] The C in FIG. 2 cross-sectional view of the grid-shaped ribs provided on the opposite surface and the bonding surface of the flange portion is shown schematically. In FIG. 2C , 5 is a flange portion, and 6 is a joint surface in the flange portion. Lattice-shaped ribs 7 and 7 ′ are provided on the surface opposite to the joint surface 6. The height of the grid ribs 7 and 7'is h, and the width of the grid ribs is w. In FIG. 2C , the height h of the grid-like ribs is preferably in the range of 2 to 15 mm, particularly preferably 5 to 12 mm. Height h
Is less than 2 mm, the rigidity of the structure is less improved. On the other hand, when it is more than 15 mm, the lattice rib depth is too large, and the handling during molding becomes troublesome. The grid-shaped ribs do not need to have the same rib height. Rib width w
Is preferably in the range of 2.5 to 5 mm, particularly preferably in the range of 3 to 4 mm. If the width w is smaller than 2.5 mm, it is not preferable in terms of the long-term physical properties of the material, and if it is thicker than 5 mm, it will not contribute to weight reduction.
【0030】図2のDは、フランジ部分の接合面と反対
側の面に存在する2組の隔接する格子状リブ7、7’が
交叉する部分を模式的に示したものである。格子状リブ
の繰返し間隔d(隔接して平行する2つの格子状リブの
中心線の距離)は10〜150mm、もう一方の間隔
d'は10〜1000mmの範囲で好ましくはそれぞれ
10〜100mm、10〜100mmの範囲である。繰
返し間隔は10mmよりも小さいと、成形時の取扱いが
面倒になるばかりでなく、ガラスのない構造体の特徴で
ある軽量性が損なわれる。間隔が長すぎると剛性の向上
が思わしくない。間隔dを持つリブ群のリブ方向はフラ
ンジの長手方向(浄化槽本体部)に平行、ないしは浄化
槽本体部と30゜以下の角度で交わる範囲内が望まし
い。フランジの剛性にはリブ方向が浄化槽本体部と平行
に近い程、効果があるためである。一例を図3(フラン
ジ平面図の部分拡大)を示す。格子状リブの交叉する角
度rおよびr'は20〜160゜の範囲であり、望まし
くは30〜150゜である。角度が20゜よりも小さい
場合、もしくは160゜より大きい場合には、1組の交
叉が必ず極端な鋭角になり、成形上取扱いが面倒とな
る。すべての交叉角度が同じ値である必要がなく成形時
の液流れによって変えてもよい。[0030] D of FIG. 2 is a portion of grid-like ribs 7, 7 to two pairs of隔接present on the surface opposite to the bonding surface of the flange portion 'is crossover that shown schematically. The repeating distance d of the grid-like ribs (distance between the center lines of two grid-like ribs that are spaced apart and parallel to each other) is 10 to 150 mm, and the other distance d'is in the range of 10 to 1000 mm, preferably 10 to 100 mm, respectively. The range is -100 mm. When the repeating interval is smaller than 10 mm, not only the handling at the time of molding becomes troublesome, but also the lightness which is a characteristic of the glass-free structure is impaired. If the interval is too long, the rigidity will not be improved. The rib direction of the rib group having the interval d is preferably parallel to the longitudinal direction of the flange (the septic tank main body) or within a range intersecting with the septic tank main body at an angle of 30 ° or less. This is because the rigidity of the flange is more effective when the rib direction is closer to the parallel to the septic tank main body. An example is shown in FIG. 3 (partially enlarged plan view of the flange). The intersecting angles r and r ′ of the lattice ribs are in the range of 20 to 160 °, preferably 30 to 150 °. When the angle is smaller than 20 ° or larger than 160 °, one set of intersections always has an extremely acute angle, which is troublesome in molding. It is not necessary that all the crossing angles have the same value, and they may be changed depending on the liquid flow during molding.
【0031】図3は、大型浄化槽を組み立てた場合、そ
の上部(或いは下部)から見たフランジ部分(接合面と
反対側の面)に存在する格子状リブの部分拡大図が示さ
れている。図3はフランジ端部9の長手方向にほぼ平行
して1組の格子状リブが設けられている例である。FIG. 3 is a partially enlarged view of the grid-like ribs existing in the flange portion (the surface opposite to the joint surface) viewed from the upper part (or the lower part) when the large-scale septic tank is assembled. FIG. 3 shows an example in which a set of grid-shaped ribs is provided substantially parallel to the longitudinal direction of the flange end portion 9.
【0032】本発明の浄化槽は、一般には上槽部と下槽
部の2つに分けて必要により中間槽部がある場合にはそ
れぞれ別個に成形する。その成形方法はすでに公知の、
例えば特公平3−28451号公報により開示された方
法で成形される。上槽部および下槽部の開口部には合わ
せ目となるフランジ部が設けられており、該フランジ部
で合わせることにより上槽部と下槽部が合体した浄化槽
になる。本発明においては、上槽部と下槽部のフランジ
部の間に、上下のフランジを有する帯状の中間槽部を介
してさしはさむことにより浄化槽の容積を増すことがで
きる。フランジ接合部は接着剤を用いるほか、合成ゴム
の帯状パッキング材を挟むことも可能である。The septic tank of the present invention is generally divided into two parts, an upper tank part and a lower tank part, and if necessary an intermediate tank part is formed separately. The molding method is already known,
For example, it is molded by the method disclosed in Japanese Examined Patent Publication No. 3-28451. Flange portions that serve as joints are provided at the openings of the upper tank portion and the lower tank portion, and by combining the flange portions, the upper tank portion and the lower tank portion are combined to form a septic tank. In the present invention, the volume of the septic tank can be increased by sandwiching the strip-shaped intermediate tank portion having upper and lower flanges between the flange portions of the upper tank portion and the lower tank portion. An adhesive may be used for the flange joint portion, and a band-shaped packing material made of synthetic rubber may be sandwiched.
【0033】また、フランジ部を接合するボルトまたは
リベット位置部には格子リブの高さまで嵩上げして厚み
を増すこともできる。このことにより、取り付け作業性
を上げるとともに、強度的にもしっかりした構造体にな
る。Further, at the bolt or rivet position where the flange is joined, the thickness can be increased by raising the height of the grid rib. As a result, the workability of mounting is improved and the structure has a strong strength.
【0034】本発明の浄化槽の厚みは、強度上3mm以
上、好ましくは4mm以上、さらに好ましくは4.5m
m以上である。また、フランジ全体の厚みは浄化槽の平
均厚みの0.8〜5倍の厚さが好適に用いられる。The thickness of the septic tank of the present invention is 3 mm or more, preferably 4 mm or more, more preferably 4.5 m because of its strength.
It is m or more. The thickness of the entire flange is preferably 0.8 to 5 times the average thickness of the septic tank.
【0035】本発明の浄化槽内部は図示されていない
が、通常の浄化槽内部と基本的に同様の構造であり、嫌
気槽、好気槽、消毒槽などの各機能別に区画されてお
り、各区画は排水を効率よく浄化するための各種部材を
充填し、且つ流水路を設けてある。本発明の大型浄化槽
はし尿処理だけの単独槽としても、或いはし尿と家庭排
水の両方を浄化処理する合併浄化槽としても使用でき
る。Although the inside of the septic tank of the present invention is not shown, it has basically the same structure as the inside of a normal septic tank, and is divided according to each function such as an anaerobic tank, an aerobic tank, and a disinfection tank. Is filled with various members for efficiently purifying drainage and is provided with a running water channel. The large-scale septic tank of the present invention can be used as a single tank for treating human waste only or as a combined septic tank for purifying both human waste and domestic wastewater.
【0036】[0036]
【実施例】以下実施例を挙げて本発明を説明する。な
お、実施例は説明のためのものであって、本発明はこれ
らに限定されるわけではない。EXAMPLES The present invention will be described below with reference to examples. It should be noted that the embodiments are for explanation, and the present invention is not limited to these.
【0037】[型]図1に示す製品形状を盛り込んだア
ルミニウム型を使用した。実施例で作った浄化槽の寸法
は次のとおりであった。 C=2326mm D=950mm E=800mm F=1140mm 図2に示す製品形状を盛り込んだフランジを使用した。 (i)h=10mm (ii)d=15mm d’=15mm (iii)r=45゜(135゜)[Mold] An aluminum mold containing the product shape shown in FIG. 1 was used. The dimensions of the septic tank made in the examples were as follows. C = 2326 mm D = 950 mm E = 800 mm F = 1140 mm A flange incorporating the product shape shown in FIG. 2 was used. (I) h = 10 mm (ii) d = 15 mm d '= 15 mm (iii) r = 45 ° (135 °)
【0038】[モノマー液] [溶液Aの調製]六塩化タングステン20重量部を窒素
気流中下で乾燥トルエン70重量部に添加し、次いでノ
ニルフェノール2重量部およびトルエン16重量部より
なる溶液を添加して0.5Mのタングステン含有触媒を
調製し、この溶液に対し窒素ガスを一晩パージして、六
塩化タングステンとノニルフェノールとの反応によって
生成される塩化水素ガスを除去して、さらにかかる溶液
10容量部に対し、1容量部のアセチルアセトンを加え
て重合用触媒とした。[Monomer solution] [Preparation of solution A] 20 parts by weight of tungsten hexachloride were added to 70 parts by weight of dry toluene under a nitrogen stream, and then a solution of 2 parts by weight of nonylphenol and 16 parts by weight of toluene was added. A 0.5M tungsten-containing catalyst was prepared by purging the solution with nitrogen gas overnight to remove hydrogen chloride gas produced by the reaction of tungsten hexachloride and nonylphenol, and further 10 volume of the solution. To 1 part by weight, 1 volume part of acetylacetone was added to obtain a polymerization catalyst.
【0039】次いで、精製ジシクロペンタジエン(純度
99.7重量%、以下同様)95重量部、精製エチリデ
ンノルボルネン(純度99.5重量%、以下同様)5重
量部よりなるモノマー混合物に対し、エチレン含有70
モル%のエチレン−プロピレン−エチリデンノルボルネ
ン重合ゴム3重量部、酸化安定剤としてエタノックス7
02 2重量部を加えた溶液に上記重合用触媒溶液をタ
ングステン含量が0.01/リットルになるように加え
て触媒成分を含有するモノマー液A(溶液A)を調製し
た。Next, ethylene was added to a monomer mixture consisting of 95 parts by weight of purified dicyclopentadiene (purity 99.7% by weight, hereinafter the same) and 5 parts by weight of purified ethylidene norbornene (purity 99.5% by weight, hereinafter the same). 70
3% by weight of ethylene-propylene-ethylidene norbornene polymer rubber in mol%, and Ethanox 7 as an oxidation stabilizer
The above catalyst solution for polymerization was added to a solution containing 22 parts by weight so that the tungsten content was 0.01 / liter to prepare a monomer solution A (solution A) containing a catalyst component.
【0040】[溶液Bの調製]トリオクチルアルミニウ
ム85、ジオクチルアルミニウムアイオダイド15、ジ
グライム100のモル割合で混合調製した重合用活性化
剤混合溶液を精製ジシクロペンタジエン95重量部、精
製エチリデンノルボルネン5重量部、エチレン含有70
モル%のエチレン−プロピレン−エチリデンノルボルネ
ン重合ゴム3重量部よりなるモノマー混合物にアルミニ
ウム含量が0.03モル/リットルになる割合で混合
し、活性化剤成分を含有するモノマー液B(溶液B)を
調製した。溶液Bの粘度は30℃で300cpsであっ
た。[Preparation of Solution B] Trioctylaluminum 85, dioctylaluminum iodide 15, and diglyme 100 were mixed and prepared at a molar ratio of 95 parts by weight of purified dicyclopentadiene and 5 parts by weight of purified ethylidene norbornene. Parts, ethylene content 70
A monomer mixture consisting of 3 parts by weight of ethylene-propylene-ethylidene norbornene polymer rubber (mol%) was mixed at a ratio of aluminum content of 0.03 mol / liter to prepare a monomer solution B (solution B) containing an activator component. Prepared. The viscosity of solution B was 300 cps at 30 ° C.
【0041】[成形]成形用アルミニウム金型をキャビ
ティー型90℃、コア型60℃に加熱し型を閉じた後、
この中へRIM成形機を利用してミキシングヘッド中で
等量の溶液Aと溶液Bを衝突混合し注入した。液注入充
填後2分で型を開き3.5分後に架橋重合品を取り出し
た。[Molding] The aluminum mold for molding was heated to 90 ° C. for the cavity mold and 60 ° C. for the core mold and the mold was closed.
Using a RIM molding machine, equal amounts of solution A and solution B were collision-mixed and injected into the mixture in a mixing head. Two minutes after the liquid injection and filling, the mold was opened and after 3.5 minutes, the crosslinked polymer product was taken out.
【0042】[浄化槽としての評価]得られた架橋重合
体成形品の上下槽をフランジ部を介してボルトと接着剤
で固定して評価用製品とした。なお、該製品は予めFR
P製仕切板3枚を用い同じボルトおよび接着剤で固定さ
れてある。該製品はJISA4101に基づく剛性試
験、耐久試験をいずれも満足した。[Evaluation as a septic tank] The upper and lower tanks of the obtained cross-linked polymer molded product were fixed with bolts and adhesives through the flanges to obtain a product for evaluation. The product is FR
Three P partition plates are used and fixed with the same bolt and adhesive. The product satisfied both the rigidity test and the durability test based on JISA4101.
【図1】 本発明における大型浄化槽の1例を示すもの
であり、Aは正面図、Bは側面図を示す。1 shows an example of a large-sized septic tank according to the present invention, where A is a front view and B is a side view.
【図2】 本発明における大型浄化槽のフランジ部にお
ける接合面と反対側に設けられた格子状リブの1例を示
すもので、Cは横断面図、Dは2組の隔接する格子状リ
ブの交叉部分を模式的に示した図を示す。FIG. 2 shows an example of a grid-like rib provided on the side opposite to the joint surface in the flange portion of the large-sized septic tank according to the present invention, where C is a cross-sectional view, and D is a pair of grid-like ribs that are separated from each other. The figure which showed the crossing part typically is shown.
【図3】 本発明の大型浄化槽におけるフランジ部の格
子状リブが存在する一部分の拡大図を示す。FIG. 3 shows an enlarged view of a portion of the large-sized septic tank of the present invention in which the lattice ribs of the flange portion are present.
1 浄化槽上槽部 2 浄化槽下槽部 3、3’ フランジ 4、4’ リブ 5 フランジ部 6 フランジ部における接合面 7、7’ 格子状リブ 8 浄化槽本体部 9 フランジ端部 10 ボルト 1 septic tank upper tank part 2 septic tank lower tank part 3, 3'flange 4, 4'rib 5 flange part 6 joint surface in flange part 7, 7'lattice-like rib 8 septic tank main body part 9 flange end part 10 bolt
フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 // B29K 23:00 B29L 22:00 Continuation of front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location // B29K 23:00 B29L 22:00
Claims (2)
いは上槽部、下槽部およびそれらを連結する板状帯の中
間槽部より構成される大型浄化槽であって、該大型浄化
槽は、(1)少なくとも上槽部および下槽部は、メタセ
シス重合触媒系の触媒成分を含有するメタセシス重合性
環状オレフィンからなるモノマー液A(溶液A)とメタ
セシス重合触媒系の活性化剤成分を含有するメタセシス
重合性環状オレフィンからなるモノマー液B(溶液B)
とを混合し、その原料混合液を金型内に注入しその金型
内において重合および架橋反応せしめることによって得
られた架橋重合体成形品であって、(2)上槽部および
下槽部、或いは上槽部、中間槽部および下槽部は、互い
に接合する部分に設けられたフランジを介して接合する
ような構造を有し、そして(3)それぞれのフランジ部
において、その接合面と反対側の面に格子状リブを有す
る、ことを特徴とする大型浄化槽。1. A large-sized septic tank comprising an upper tank part and a lower tank part, or an upper tank part, a lower tank part and an intermediate tank part of a plate-shaped belt connecting them. (1) At least the upper tank part and the lower tank part contain a monomer liquid A (solution A) composed of a metathesis-polymerizable cyclic olefin containing a catalyst component of a metathesis polymerization catalyst system and an activator component of the metathesis polymerization catalyst system. Monomer liquid B containing the metathesis-polymerizable cyclic olefin contained therein (solution B)
And (2) a cross-linked polymer molded article obtained by mixing and mixing the raw material mixed solution into a mold to cause a polymerization and a cross-linking reaction in the mold. Alternatively, the upper tank portion, the intermediate tank portion, and the lower tank portion have a structure such that they are joined via a flange provided in a portion to be joined to each other, and (3) at each flange portion A large-scale septic tank having a grid-like rib on the opposite surface.
(iv)を満足する請求項1記載の大型浄化槽。 (i)2≦h≦15 (ii)2.5≦w≦5 (iii)10≦d≦150、10≦d’≦1000 (iv)20°≦r≦160° [但し、hは格子状リブのリブ高さをミリ単位で示し、
wは平均リブ厚みをミリ単位で示し、dは格子状リブの
内の一組のリブ間隔距離をミリ単位で示し、d’はもう
一組のリブ間隔距離をミリ単位で示し、rは格子状を構
成する交叉リブの角度を示す。]2. The grid-shaped rib has the following shape characteristics (i) to
The large-sized septic tank according to claim 1, which satisfies (iv). (I) 2 ≦ h ≦ 15 (ii) 2.5 ≦ w ≦ 5 (iii) 10 ≦ d ≦ 150, 10 ≦ d ′ ≦ 1000 (iv) 20 ° ≦ r ≦ 160 ° [where h is a lattice shape Indicates the rib height of the rib in millimeters,
w is the average rib thickness in millimeters, d is the rib spacing of one set of grid ribs in millimeters, d'is the other rib spacing in millimeters, and r is the grid. The angle of the cross rib which comprises a shape is shown. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13226394A JP3148793B2 (en) | 1994-06-14 | 1994-06-14 | Large septic tank |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13226394A JP3148793B2 (en) | 1994-06-14 | 1994-06-14 | Large septic tank |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07329096A true JPH07329096A (en) | 1995-12-19 |
| JP3148793B2 JP3148793B2 (en) | 2001-03-26 |
Family
ID=15077195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13226394A Expired - Fee Related JP3148793B2 (en) | 1994-06-14 | 1994-06-14 | Large septic tank |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3148793B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002531648A (en) * | 1998-12-09 | 2002-09-24 | ザ ビー.エフ.グッドリッチ カンパニー | Addition polymerization of norbornene-type monomer in mold using complex of Group 10 metal |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3484464B2 (en) | 1995-02-17 | 2004-01-06 | 帝人化成株式会社 | Large septic tank |
-
1994
- 1994-06-14 JP JP13226394A patent/JP3148793B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002531648A (en) * | 1998-12-09 | 2002-09-24 | ザ ビー.エフ.グッドリッチ カンパニー | Addition polymerization of norbornene-type monomer in mold using complex of Group 10 metal |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3148793B2 (en) | 2001-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3177078B2 (en) | Large septic tank | |
| JP3439862B2 (en) | Large septic tank | |
| JPH07329096A (en) | Large-scale purification cistern | |
| JP3174458B2 (en) | Large septic tank | |
| JP3241960B2 (en) | Large septic tank | |
| JP3271846B2 (en) | Large septic tank | |
| JP3122291B2 (en) | Crosslinked polymer concrete formwork | |
| JP3484464B2 (en) | Large septic tank | |
| JPH0967852A (en) | Large-sized septic tank | |
| JP3380644B2 (en) | Large septic tank | |
| KR100329405B1 (en) | Large Septic Tank | |
| EP0534482B1 (en) | Metathesis catalyst system | |
| JPH07132533A (en) | Crosslinked polymer concrete shuttering | |
| JPH07290484A (en) | Large-scaled purifying tank | |
| JP3217970B2 (en) | cooling tower | |
| KR100226312B1 (en) | Metathesis polymerization catalyst solution and system for preparing cross-linked polymers | |
| JPH09131739A (en) | Concrete form of cross-linked polymer | |
| JPH08276515A (en) | Large-sized septic tank | |
| JPH09195504A (en) | Crosslinked polymer concrete form for ceiling | |
| JPH0852755A (en) | Concrete form of crosslinked polymer | |
| EP0358158A2 (en) | Hollow polycycloolefin molded product | |
| JPH11169826A (en) | Garbage disposal tank | |
| JPH09203207A (en) | Crosslinkable polymer concrete form and connection method thereof | |
| JPH07693B2 (en) | Method for producing crosslinked polymer molding | |
| JPH0811150A (en) | Crosslinked polymer planking |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20001211 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080112 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090112 Year of fee payment: 8 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090112 Year of fee payment: 8 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100112 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100112 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110112 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120112 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120112 Year of fee payment: 11 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120112 Year of fee payment: 11 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120112 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130112 Year of fee payment: 12 |
|
| LAPS | Cancellation because of no payment of annual fees |