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JPH07166200A - Toilet cleaning composition - Google Patents

Toilet cleaning composition

Info

Publication number
JPH07166200A
JPH07166200A JP34209293A JP34209293A JPH07166200A JP H07166200 A JPH07166200 A JP H07166200A JP 34209293 A JP34209293 A JP 34209293A JP 34209293 A JP34209293 A JP 34209293A JP H07166200 A JPH07166200 A JP H07166200A
Authority
JP
Japan
Prior art keywords
weight
toilet
coconut oil
composition
polylysine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP34209293A
Other languages
Japanese (ja)
Inventor
Junichiro Hirata
準一郎 平田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP34209293A priority Critical patent/JPH07166200A/en
Publication of JPH07166200A publication Critical patent/JPH07166200A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719Polyamides or polyimides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

(57)【要約】 【目的】 アンモニア等の悪臭を抑え、清浄な状態を長
期にわたって維持し、しかも安全で抗菌性を有する。 【構成】 本発明のトイレ洗浄剤組成物は、ヤシ油アル
キルジメチルアミンオキシド、水及びポリリジンを含む
ことを特徴とするもので、該ヤシ油アルキルジメチルア
ミンオキシドのアルキル基の炭素鎖がC8 〜C18のう
ち、少なくともいづれか1つを含み、これらは混合物を
形成している。このトイレ洗浄剤組成物には、香料を加
えてもよい。ヤシ油アルキルジメチルアミンオキシドの
含有量は5重量%〜40重量%が良い。ポリリジンの添
加量は3重量%〜35重量%が好ましい。
(57) [Summary] [Purpose] It suppresses offensive odors such as ammonia, maintains a clean state for a long time, and is safe and has antibacterial properties. [Configuration] toilet detergent composition of the present invention, which is characterized in that it comprises a coconut oil alkyl dimethyl amine oxide, water and polylysine, the carbon chain of the alkyl group of the coconut oil alkyl dimethyl amine oxide C 8 ~ It contains at least one of C 18 , which forms a mixture. A perfume may be added to this toilet cleaner composition. The content of coconut oil alkyldimethylamine oxide is preferably 5% by weight to 40% by weight. The addition amount of polylysine is preferably 3% by weight to 35% by weight.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、トイレ洗浄剤組成物に
関し、更に詳しくはトイレ便器、便器配管あるいはそれ
らの周辺等から発生するアンモニア等の悪臭を抑え、清
浄な状態を長期にわたり維持し、しかも安全で抗菌性洗
浄性を有するトイレ洗浄剤組成物に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a toilet cleaner composition, and more specifically, it suppresses the bad odor of ammonia and the like generated from toilet bowls, toilet pipes or their surroundings, and maintains a clean state for a long period of time. Moreover, the present invention relates to a toilet cleaning composition that is safe and has antibacterial detergency.

【0002】[0002]

【従来の技術】トイレ便器やその関連機器またはそれら
の周辺は、そのまま放置しておくとアンモニア等の悪臭
が漂い、不快感を覚えるばかりでなく環境として好まし
いものではない。このようなトイレ便器やその関連機器
等の悪臭を防止するために、トイレ便器等の洗浄が行わ
れるが、通常この洗浄にはトイレ用洗浄剤が使用され
る。このトイレ用洗浄剤としては、従来、塩酸系、次亜
塩素酸ナトリウム系、アルデヒド系等の洗浄剤及び陰イ
オン界面活性剤等が主流である。また洗浄水タンクに直
接投入するタイプでは、非イオン界面活性剤をベースと
したものや有機酸を利用したものがある。
2. Description of the Related Art Toilet bowls and their related equipment or their surroundings are not preferable as an environment as well as giving offensive odors such as ammonia if they are left as they are. In order to prevent such a bad smell from the toilet bowl and related equipment, the toilet bowl is washed, and a toilet cleaner is usually used for this washing. As the toilet cleaner, conventionally, a hydrochloric acid-based cleaner, a sodium hypochlorite-based cleaner, an aldehyde-based cleaner, an anionic surfactant and the like have been mainly used. Further, in the type that is directly added to the wash water tank, there are a type based on a nonionic surfactant and a type using an organic acid.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、前述の
塩酸系洗浄剤を使用する場合は、アルカリ性物質との反
応により塩素を発生するので、人体に好ましくなく、ま
た次亜塩素酸ナトリウム系洗浄剤の場合には、悪臭物等
の悪臭源に反応する際、塩素を発生するので、塩酸系洗
浄剤と同様に好ましくない。またアルデヒド系等の洗浄
剤や有機酸系のものでは、素材に影響することが考えら
れるので、好ましくない。更に前述のごとき界面活性剤
を使用する場合は、界面活性剤だけでは抗菌性が弱く、
複数の洗浄剤との組合せを必要とするという問題があ
り、この組合せに酸性物質やアルカリ性物質を使用して
も上記問題点の解決にはならない。
However, when the above-mentioned hydrochloric acid-based cleaning agent is used, chlorine is generated by the reaction with an alkaline substance, which is not preferable for the human body, and the sodium hypochlorite-based cleaning agent In this case, chlorine is generated when it reacts with a malodorous source such as a malodorous substance, which is not preferable like the hydrochloric acid-based detergent. Further, an aldehyde-based cleaning agent or an organic acid-based cleaning agent is not preferable because it may affect the material. Further, when using a surfactant as described above, the antibacterial property is weak only with the surfactant,
There is a problem that a combination with a plurality of cleaning agents is required, and even if an acidic substance or an alkaline substance is used for this combination, the above problems cannot be solved.

【0004】そこで、本発明者等は、前述の問題点を解
決して、トイレ便器、その配管あるいはそれらの周辺等
から発生するアンモニア等の悪臭を抑え、清浄な状態を
長期にわたって維持し、しかも安全で抗菌性を有するト
イレ洗浄剤組成物を得るべく鋭意研究を重ねた結果、偶
然にも天然物の素材のみから構成されたトイレ洗浄剤組
成物を見出し、ここに本発明を完成するに至った。した
がって本発明の目的は、アンモニア等の悪臭を抑え、清
浄な状態を長期にわたって維持し、しかも安全で抗菌性
を有するトイレ洗浄剤組成物を提供することにある。
Therefore, the inventors of the present invention have solved the above-mentioned problems to suppress the bad odor of ammonia and the like generated from the toilet bowl, its pipes or their surroundings, and maintain a clean state for a long period of time. As a result of earnest studies to obtain a safe and antibacterial toilet cleaner composition, a toilet cleaner composition which was accidentally composed only of natural materials was found, and the present invention was completed here. It was Therefore, an object of the present invention is to provide a toilet cleaning composition that suppresses a bad odor of ammonia and the like, maintains a clean state for a long time, and is safe and has antibacterial properties.

【0005】[0005]

【課題を解決するための手段】本発明の上記目的は、下
記のそれぞれの発明によって達成される。 (1)ヤシ油アルキルジメチルアミンオキシド、水及び
ポリリジンを含むことを特徴とするトイレ洗浄剤組成
物。
The above objects of the present invention can be achieved by the following respective inventions. (1) A toilet cleaner composition comprising coconut oil alkyldimethylamine oxide, water and polylysine.

【0006】(2)ヤシ油アルキルジメチルアミンオキ
シドのアルキル基の炭素鎖がC8 〜C18のうち、少なく
ともいづれか1つを含むことを特徴とする前記第1項に
記載のトイレ洗浄剤組成物。
(2) A toilet cleaner composition according to the above item 1, wherein the carbon chain of the alkyl group of coconut oil alkyldimethylamine oxide contains at least one of C 8 to C 18 . .

【0007】(3)香料を含むことを特徴とする前記第
1項又は第2項のいづれかに記載のトイレ洗浄剤組成
物。
(3) The toilet cleaning composition according to any one of the above items 1 and 2, which contains a fragrance.

【0008】以下本発明を更に詳しく説明すると、本発
明に用いられるヤシ油アルキルジメチルアミンオキシド
は、洗浄性を付与するために用いられ、その含有量は5
重量%〜40重量%が良く、この添加量が5重量%未満
では洗浄作用が十分でなく、また添加量が40重量%を
越えると起泡性が高くなり過ぎるため好ましくない。本
発明に用いられるヤシ油アルキルジメチルアミンオキシ
ドは、アルキル基の炭素鎖がC8 〜C18のうち、少なく
ともいづれか1つを含む。即ちこのヤシ油アルキルジメ
チルアミンオキシドは、天然物である場合は、C8 〜C
18が混合物となっている。またアルキル基は直鎖又は分
岐のアルキル基のいづれでもよいが、好ましくは直鎖ア
ルキル基である。具体的にはアルキル基は、ノニル基、
デシル基、ドデシル基、ペンタデシル基、ヘプタデシル
基、オクタデシル基等が挙げられる。
The present invention is described in more detail below. The coconut oil alkyldimethylamine oxide used in the present invention is used for imparting detergency, and its content is 5
The content is preferably 40% by weight to 40% by weight. If the added amount is less than 5% by weight, the cleaning action is insufficient, and if the added amount exceeds 40% by weight, the foaming property becomes too high, which is not preferable. Coconut oil alkyl dimethyl amine oxides used in the present invention, among the carbon chain of the alkyl group is a C 8 -C 18, including one either at least. That is, this coconut oil alkyldimethylamine oxide is C 8 -C when it is a natural product.
18 is a mixture. The alkyl group may be a linear or branched alkyl group, but is preferably a linear alkyl group. Specifically, the alkyl group is a nonyl group,
Examples thereof include a decyl group, a dodecyl group, a pentadecyl group, a heptadecyl group and an octadecyl group.

【0009】また本発明に用いられるポリリジンは、抗
菌作用を有しているので、洗浄剤に抗菌性を付与するた
めに加える。ポリリジンの添加量は3重量%〜35重量
%が好ましい。この添加量が3重量%未満では抗菌性が
弱いので、効果がない。またポリリジンの添加量は35
重量%を越えると茶褐色となり洗浄剤としての外観上好
ましくない。更に水はヤシ油アルキルジメチルアミンオ
キシド及びポリリジンを溶解するために必要で、溶解に
必要な量としては、45重量%〜65重量%が好まし
い。水の量が45重量%未満では洗浄剤組成物の濃度が
高くなり該組成物がべたつくので、好ましくなく、また
水の量が65重量%を越えると逆に洗浄剤組成物の濃度
が低くなり過ぎ、該組成物の性能が低下するので、好ま
しくない。
Since polylysine used in the present invention has an antibacterial action, it is added to impart an antibacterial property to the detergent. The addition amount of polylysine is preferably 3% by weight to 35% by weight. If the addition amount is less than 3% by weight, the antibacterial property is weak, so that there is no effect. The addition amount of polylysine is 35
If it exceeds 5% by weight, it becomes dark brown and it is not preferable in appearance as a detergent. Further, water is necessary to dissolve coconut oil alkyldimethylamine oxide and polylysine, and the amount required for dissolution is preferably 45% by weight to 65% by weight. If the amount of water is less than 45% by weight, the concentration of the detergent composition becomes high and the composition becomes sticky, which is not preferable, and if the amount of water exceeds 65% by weight, the concentration of the detergent composition decreases. It is not preferable because the performance of the composition is deteriorated.

【0010】本発明のトイレ洗浄剤組成物には、更に香
料を入れて使用してもよく、使用できる香料としては、
各種のものが用いられ、天然や合成の香料、例えば柑橘
類の匂いのある香料、芳香性の匂いのある香料、森林臭
香料、ばら様香気香料等が挙げられる(香料の実際知
識、1991年9月25日第2版東洋経済新報社発行、
印籐元一著参照)。香料の具体例としては、ジャスミ
ン、ラベンダー、リラ、カトレア、レモン、クールミン
ト、スズラン、ローズ、バイオレット、フリージア等が
挙げられる。これらの香料の添加量は、適宜の量が用い
られ、好ましくは0.5重量%〜5重量%がよい。
The toilet cleaning composition of the present invention may be used by further containing a fragrance.
Various substances are used, including natural and synthetic fragrances such as citrus scents, aromatic scents, forest scents, and rose-like scents (actual knowledge of fragrances, September 1991). Published by Toyo Keizai Inc. on the 25th of May,
See Motoichi Ino. Specific examples of the fragrance include jasmine, lavender, lira, cattleya, lemon, cool mint, lily of the valley, rose, violet, and freesia. An appropriate amount of these fragrances is added, and preferably 0.5% by weight to 5% by weight.

【0011】[0011]

【作用】本発明において、ヤシ油アルキルジメチルアミ
ンオキシドは、洗浄作用を有していると共に香料を溶解
する能力を有する。またポリリジンは、抗菌作用を有す
るので、悪臭の発生源での洗浄と洗浄後の菌類の繁殖を
抑えるために、ヤシ油アルキルジメチルアミンオキシド
とポリリジンを併用する。またこれらの化合物は、水溶
性であるので、水を用いて液状組成物をつくると共に水
で該組成物の濃度を調整して最良の性能を発揮させるた
めである。
In the present invention, coconut oil alkyldimethylamine oxide has a cleaning action and the ability to dissolve perfume. Further, since polylysine has an antibacterial action, coconut oil alkyldimethylamine oxide is used in combination with polylysine in order to prevent the growth of fungi after washing with a source of bad odor. Further, since these compounds are water-soluble, a liquid composition is prepared by using water and the concentration of the composition is adjusted by water so that the best performance is exhibited.

【0012】[0012]

【実施例】以下に実施例を示して本発明を更に詳しく説
明するが、本発明は、これらの例によって限定されるも
のではない。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.

【0013】実施例1 ポリリジン30gを水100gに溶解し、これにヤシ油
アルキルジメチルアミンオキシド(東邦化学工業(株)
製、商品名、カチナールAOC)70gを加えて調整
し、200gのトイレ洗浄剤組成物を得た。ついで、こ
の洗浄剤組成物を10gづつ取り、男子トイレ便器及び
その周辺を1回/日の割合で洗浄した。これに対して比
較として、水のみで1回/日の割合で洗浄した。両者の
アンモニア検出量を北川式検知管(光明理化学工業
(株)製、ガス検知管アンモニアSD)を用いて測定し
た。得られた洗浄結果を表1に示す。(表1:単位はp
pm)
Example 1 Polylysine (30 g) was dissolved in water (100 g), and coconut oil alkyldimethylamine oxide (Toho Chemical Industry Co., Ltd.) was added thereto.
(Manufactured, trade name, Katinal AOC) 70 g was added to adjust the amount to obtain 200 g of a toilet cleaner composition. Then, 10 g of each of the cleaning composition was taken, and the toilet bowl for men's toilet and its surroundings were washed once per day. On the other hand, as a comparison, it was washed with water only once / day. The ammonia detection amount of both was measured using a Kitagawa type detector tube (manufactured by Komei Rikagaku Co., Ltd., gas detector tube ammonia SD). The obtained cleaning results are shown in Table 1. (Table 1: Unit is p
pm)

【0014】以下に示される表1から明らかなように、
本発明のトイレ洗浄剤組成物を用いた場合には、その使
用の初期は、勿論のこと1〜2週間たっても良好な洗浄
効果を有し、長期にわたって清浄な状態を保持すること
ができるのに対して、比較のものでは長期になるほどア
ンモニアの量が多く検出され、その効果がないことがわ
かる。
As is clear from Table 1 shown below,
When the toilet cleaning composition of the present invention is used, it has a good cleaning effect at the beginning of its use, of course, even after 1 to 2 weeks, and can maintain a clean state for a long period of time. On the other hand, in the comparative example, the amount of ammonia was detected to be larger as the period was longer, and it was found that the effect was not obtained.

【0015】[0015]

【表1】 [Table 1]

【0016】実施例2 実施例1と同じ組成の洗浄剤組成物を25.0ml調整
し、これを10リットルの洗浄水に投入し、便器洗浄水
として使用し、洗浄水で洗浄して流れた汚物を100リ
ットルタンク中に数日間保存した。この間、アンモニ
ア、メルカプタン、硫化水素を北川式検知管で調べた。
また比較としては、洗浄水のみを同様に使用した。得ら
れた防臭効果の結果を表2に示す。(表2:単位はpp
m)
Example 2 25.0 ml of a detergent composition having the same composition as in Example 1 was prepared, poured into 10 liters of wash water, used as toilet wash water, washed with wash water, and flowed. The waste was stored in a 100 liter tank for several days. During this period, ammonia, mercaptan, and hydrogen sulfide were examined with a Kitagawa detector tube.
For comparison, only washing water was used in the same manner. The results of the obtained deodorizing effect are shown in Table 2. (Table 2: Unit is pp
m)

【0017】[0017]

【表2】 [Table 2]

【0018】表2から明らかなように、本発明のトイレ
洗浄剤組成物を使用したものでは、メルカプタンや硫化
水素は検出されないのは勿論のこと、アンモニアの量も
比較例のものに比べて格段に低い。その結果本発明のト
イレ洗浄剤組成物を使用したものでは、使用済の洗浄水
を長期にわたって清浄な状態で保持することができる。
As is clear from Table 2, in the case of using the toilet cleaning composition of the present invention, not only mercaptan and hydrogen sulfide are not detected, but the amount of ammonia is much higher than that of the comparative example. Very low. As a result, with the toilet cleaning composition of the present invention, used cleaning water can be kept in a clean state for a long time.

【0019】[0019]

【発明の効果】本発明のトイレ洗浄剤組成物により、ト
イレ便器、便器配管あるいはそれらの周辺等から発生す
るアンモニア等の悪臭を抑え、清浄な状態を長期にわた
り維持し、しかもすべて天然物素材を使用しているの
で、安全で抗菌性洗浄性を有するという従来にない優れ
た効果を奏するものである。
EFFECTS OF THE INVENTION The toilet cleaning composition of the present invention suppresses the bad odor of ammonia and the like generated from toilet bowls, toilet pipes and their surroundings, maintains a clean state for a long period of time, and uses all natural product materials. Since it is used, it has an unprecedented excellent effect of being safe and having antibacterial detergency.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 ヤシ油アルキルジメチルアミンオキシ
ド、水及びポリリジンを含むことを特徴とするトイレ洗
浄剤組成物。
1. A toilet cleaner composition comprising coconut oil alkyldimethylamine oxide, water and polylysine.
【請求項2】 ヤシ油アルキルジメチルアミンオキシド
のアルキル基の炭素鎖がC8 〜C18のうち、少なくとも
いづれか1つを含むことを特徴とする請求項1に記載の
トイレ洗浄剤組成物。
2. The toilet cleaning composition according to claim 1, wherein the carbon chain of the alkyl group of the coconut oil alkyldimethylamine oxide contains at least one of C 8 to C 18 .
【請求項3】 香料を含むことを特徴とする請求項1又
は請求項2のいづれかに記載のトイレ洗浄剤組成物。
3. The toilet cleaning composition according to claim 1, which contains a fragrance.
JP34209293A 1993-12-14 1993-12-14 Toilet cleaning composition Withdrawn JPH07166200A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34209293A JPH07166200A (en) 1993-12-14 1993-12-14 Toilet cleaning composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34209293A JPH07166200A (en) 1993-12-14 1993-12-14 Toilet cleaning composition

Publications (1)

Publication Number Publication Date
JPH07166200A true JPH07166200A (en) 1995-06-27

Family

ID=18351101

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34209293A Withdrawn JPH07166200A (en) 1993-12-14 1993-12-14 Toilet cleaning composition

Country Status (1)

Country Link
JP (1) JPH07166200A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999007814A1 (en) * 1997-08-08 1999-02-18 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6214786B1 (en) * 1997-08-08 2001-04-10 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6407053B1 (en) 1997-08-08 2002-06-18 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6921745B2 (en) 2001-04-17 2005-07-26 Kao Corporation Bactericidal composition comprising polylysine and a plant essential oil

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999007814A1 (en) * 1997-08-08 1999-02-18 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
WO1999007813A1 (en) * 1997-08-08 1999-02-18 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6214786B1 (en) * 1997-08-08 2001-04-10 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6407053B1 (en) 1997-08-08 2002-06-18 The Procter & Gamble Company Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
US6921745B2 (en) 2001-04-17 2005-07-26 Kao Corporation Bactericidal composition comprising polylysine and a plant essential oil

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