JPH07165527A - Ultraviolet-absorbing skin cosmetic - Google Patents
Ultraviolet-absorbing skin cosmeticInfo
- Publication number
- JPH07165527A JPH07165527A JP5343025A JP34302593A JPH07165527A JP H07165527 A JPH07165527 A JP H07165527A JP 5343025 A JP5343025 A JP 5343025A JP 34302593 A JP34302593 A JP 34302593A JP H07165527 A JPH07165527 A JP H07165527A
- Authority
- JP
- Japan
- Prior art keywords
- cassia
- extract
- linn
- senna
- skin cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 239000004909 Moisturizer Substances 0.000 description 1
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- 239000005642 Oleic acid Substances 0.000 description 1
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- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
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- 239000002270 dispersing agent Substances 0.000 description 1
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- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
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- 229940074774 glycyrrhizinate Drugs 0.000 description 1
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- 239000006210 lotion Substances 0.000 description 1
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- 229910052623 talc Inorganic materials 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
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- HTJNEBVCZXHBNJ-XCTPRCOBSA-H trimagnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one;diphosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.OC[C@H](O)[C@H]1OC(=O)C(O)=C1O HTJNEBVCZXHBNJ-XCTPRCOBSA-H 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は皮膚化粧料、特に紫外線
吸収効果を有する植物抽出物を含有する安全性の高い紫
外線吸収性皮膚化粧料に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a skin cosmetic, and more particularly to a highly safe UV absorbent skin cosmetic containing a plant extract having a UV absorbing effect.
【0002】[0002]
【従来の技術】太陽光線に含まれる紫外線は、皮膚科学
的には400nm〜320nmの長波長紫外線(UV−
A)、320nm〜290nm中波長紫外線(UV−
B)、290nm以下の短波長紫外線(UV−C)に分
類される。このうち、290nm以下の波長の紫外線
は、オゾン層によって吸収され、地表に到達しない。2. Description of the Related Art Ultraviolet rays contained in sunlight are dermatologically long wavelength ultraviolet rays (UV-) of 400 nm to 320 nm.
A), 320 nm to 290 nm medium wavelength ultraviolet light (UV-
B) Classified as short wavelength ultraviolet rays (UV-C) of 290 nm or less. Of these, ultraviolet rays having a wavelength of 290 nm or less are absorbed by the ozone layer and do not reach the surface of the earth.
【0003】地表に届く紫外線は、人間の皮膚に様々な
影響を及ぼす。地上にまで達する紫外線の内で、UV−
Bは皮膚の紅班や水泡を形成し、メラニン形成も促進す
る。一方、UV−Aは皮膚の褐色化を惹起し、皮膚の弾
力性の低下及びシワの発生を促進し急激な老化をもたら
す。また、紅班反応の開始を促進し、或いはある種の患
者に対してはこの反応を増強し、更に光毒性或いは光ア
レルギー反応の原因とさえなり得る。このような紫外線
の有害性から皮膚を保護するために、各種紫外線吸収剤
が開発されてきた。Ultraviolet rays reaching the surface of the earth have various effects on human skin. Of the ultraviolet rays that reach the ground, UV-
B forms erythema and blisters on the skin and promotes melanin formation. On the other hand, UV-A causes browning of the skin, lowers the elasticity of the skin and promotes the generation of wrinkles, resulting in rapid aging. It can also accelerate the onset of the erythema reaction, or enhance this reaction for some patients, and even cause phototoxicity or even a photoallergic reaction. Various ultraviolet absorbers have been developed to protect the skin from such harmful effects of ultraviolet rays.
【0004】化学合成による多種多様な紫外線吸収剤と
しては、例えば、ジベンゾイルメタン誘導体、ベンゾフ
ェノン誘導体、ウロカニン酸、p−アミノ安息香酸、2
−エチルヘキシルp−ジメチルアミノベンゾエートなど
が挙げられ、これらは実際に化粧料に配合され、紫外線
による障害の予防に用いられている。As a wide variety of UV absorbers obtained by chemical synthesis, for example, dibenzoylmethane derivatives, benzophenone derivatives, urocanic acid, p-aminobenzoic acid, 2
-Ethylhexyl p-dimethylaminobenzoate and the like are mentioned, and these are actually blended in cosmetics and used for prevention of damage due to ultraviolet rays.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、従来の
化学合成による紫外線吸収剤を配合した日焼け防止化粧
料は光感作性等の点で安全性に問題があり、配合量が制
限されるなど化粧品原料の中では最も問題のある薬剤で
ある。一方、天然物由来のものは一般に作用が温和で安
全性が高く、多量に配合することも可能であるが、紫外
線吸収剤としては吸収波長が270nm以下の短波長の
紫外線を吸収するものが多く、問題となるUV−A及び
/又はUV−B領域の波長の紫外線を吸収するものは余
りなく、いまだ満足すべき効果を発揮するものは得られ
ていなかった。However, conventional sunscreen cosmetics containing an ultraviolet absorber produced by chemical synthesis have a safety problem in terms of photosensitization and the cosmetics are limited in their amount. It is the most problematic drug among raw materials. On the other hand, those derived from natural products generally have a mild action and are highly safe, and it is possible to mix them in a large amount, but many ultraviolet absorbers absorb short-wavelength ultraviolet rays having an absorption wavelength of 270 nm or less. However, there are few substances that absorb the problematic ultraviolet rays having wavelengths in the UV-A and / or UV-B regions, and those that exhibit a satisfactory effect have not yet been obtained.
【0006】本発明はこのような従来技術の課題に鑑み
なされたものであり、その目的は天然物より得られる安
全性が高い物質で、しかもUV−A及び/又はUV−B
領域に吸収を有する紫外線吸収剤およびこれを含有する
皮膚化粧料を提供することにある。The present invention has been made in view of the above problems of the prior art, and its object is a highly safe substance obtained from a natural product, and UV-A and / or UV-B.
An object is to provide an ultraviolet absorber having absorption in a region and a skin cosmetic containing the same.
【0007】[0007]
【課題を解決するための手段】本発明者らは、前記目的
を達成するために鋭意検討した結果、マメ科植物(Legum
inosae Juss.)の抽出物に優れた紫外線吸収能が存在
し、この抽出物を配合することによって安全なサンケア
製品が得られることができることを見出し、本発明を完
成するに至った。本発明の皮膚化粧料は、一つにはマメ
科植物(Leguminosae Juss.)の抽出物を含有することを
特徴とする。本発明の皮膚化粧料は、一つにはマメ科植
物(Leguminosae Juss.)の抽出物がカワラケツメイ属植
物(Cassia Linn.)の抽出物であることを特徴とする。The present inventors have SUMMARY OF THE INVENTION As a result of intensive studies for achieving the above object, legumes (Legum
inosae Juss.) has an excellent ability to absorb ultraviolet rays, and it has been found that a safe sun care product can be obtained by incorporating this extract, and the present invention has been completed. One feature of the skin cosmetic of the present invention is that it contains an extract of a leguminous plant ( Leguminosae Juss.). One feature of the skin cosmetic of the present invention is that an extract of a leguminous plant ( Leguminosae Juss.) Is an extract of a plant belonging to the genus Kawasetsu ( Cassia Linn.).
【0008】本発明の皮膚化粧料は、一つにはマメ科植
物(Leguminosae Juss.)の抽出物が、カワラケツメイ属
植物(Cassia Linn.)に属するキャシア・チモレンシス
(Cassia timorensis DC.)、ハナセンナ(Cassia alata
Linn.)、センナ(Cassia angustifolia Vahl)、コバノ
センナ(Cassia coluteoides Collad)、ハナセンナ(Cass
ia corymbosa Lam.)、コヤシセンナ(Cassia didymobotr
ya Fresen.)、ナンバンサイカチ(Cassia fistura Lin
n.)、ジャワセンナ(Cassia javjanica Linn.)、エビス
グサ(Cassia obutusifolia Linn.)、ハブソウ(Cassia o
ccidentalis Linn.)、タガヤサンノキ(Cassia siamea L
am.)、オオバノセンナ(Cassia sophera Linn.)、モクセ
ンナ(Cassia surattensis Burm.f.)の抽出物の中から選
ばれた少なくとも1種以上の抽出物であることを特徴と
する。One of the skin cosmetics of the present invention is Cassia timorensis DC., Which is an extract of leguminous plants ( Leguminosae Juss.), Which belongs to the genus Plant of Cassia Linn. Cassia alata
Linn.), Senna ( Cassia angustifolia Vahl), Cobano Senna ( Cassia coluteoides Collad), Hana Senna ( Cass )
ia corymbosa Lam.), Cassia didymobotr
ya Fresen.), Nanbang Saikachi ( Cassia fistura Lin
n.), Java Senna ( Cassia javjanica Linn.), Ebisugusa ( Cassia obutusifolia Linn.), Habuso ( Cassia o )
ccidentalis Linn.), Tagaya Sanuki ( Cassia siamea L
am.), Obana nosenna ( Cassia sophera Linn.), and Moxenna ( Cassia surattensis Burm. f .) extracts.
【0009】本発明の皮膚化粧料は、一つにはマメ科植
物(Leguminosae Juss.)の抽出物がカワラケツメイ属(Ca
ssia Linn.)の樹皮から抽出された抽出物であることを
特徴とする。[0009] skin cosmetic of the present invention, legumes in part (Leguminosae Juss.) Of the extract Kawaraketsumei genus (Ca
ssia Linn.) bark extract.
【0010】以下、本発明の構成について詳述する。本
発明で用いるマメ科の植物としては、カワラケツメイ属
植物(Cassia Linn.)に属するキャシア・チモレンシス
(Cassia timorensis DC.)、ハナセンナ(Cassia alata
Linn.)、センナ(Cassia angustifolia Vahl)、コバノ
センナ(Cassia coluteoides Collad)、ハナセンナ(Cass
ia corymbosa Lam.)、コヤシセンナ(Cassia didymobotr
ya Fresen.)、ナンバンサイカチ(Cassia fistura Lin
n.)、ジャワセンナ(Cassia javanica Linn.)、エビスグ
サ(Cassia obutusifolia Linn.)、ハブソウ(Cassia occ
identalis Linn.)、タガヤサンノキ(Cassia siamea La
m.)、オオバノセンナ(Cassia sophera Linn.)、モクセ
ンナ(Cassia surattensis Burm.f.)等が挙げられるが、
特に、キャシア・チモレンシス(Cassia timorensis D
C.)が好ましい。The structure of the present invention will be described in detail below. Examples of legumes used in the present invention include Cassia timorensis DC. And Cassena alata ( Cassia alata ), which belong to the genus Kawasaki Tsutsumei ( Cassia Linn.).
Linn.), Senna ( Cassia angustifolia Vahl), Cobano Senna ( Cassia coluteoides Collad), Hana Senna ( Cass )
ia corymbosa Lam.), Cassia didymobotr
ya Fresen.), Nanbang Saikachi ( Cassia fistura Lin
n.), Jawasen'na (Cassia javanica Linn.), sicklepod (Cassia obutusifolia Linn.), Senna occidentalis (Cassia occ
identalis Linn.), Tagaya Sanki ( Cassia siamea La
m.), Obano senna ( Cassia sophera Linn.), Mox senna ( Cassia surattensis Burm.f.), etc.,
In particular, Cassia timorensis D
C.) is preferred.
【0011】本発明に係る抽出物は前記植物の花、樹
皮、果実、葉、根、種子、茎等の部位あるいは全草を用
いて抽出され、特に、キャシア・チモレンシス(Cassia
timorensis DC.)では樹皮を中心にして用いられる。
本発明で用いる植物抽出物の抽出方法としては、前記植
物を溶媒、例えば、メタノール、エタノール、プロピル
アルコール、イソプロピルアルコール、ブタノール、イ
ソブタノール等の低級アルコール或いは含水低級アルコ
ール、プロピレングリコール、1,3−ブチレングリコ
ール等の多価アルコール或いは含水多価アルコール、ア
セトン、酢酸エチルエステル等の各種有機溶媒により抽
出し、溶媒を留去することにより得ることができる。特
に、メタノール又はエタノールは本発明で用いる植物に
対する浸潤性が良好で、抽出効率や収量の点で好まし
い。The extract according to the present invention is extracted using the above-mentioned plant flowers, bark, fruits, leaves, roots, seeds, stems or the like or whole plants, and in particular, Cassia timolensis.
timorensis DC.) is used mainly in the bark.
As the method for extracting the plant extract used in the present invention, the plant is used as a solvent, for example, lower alcohols such as methanol, ethanol, propyl alcohol, isopropyl alcohol, butanol, isobutanol or lower water alcohols, propylene glycol, 1,3-. It can be obtained by extracting with a polyhydric alcohol such as butylene glycol or a water-containing polyhydric alcohol, various organic solvents such as acetone and ethyl acetate, and distilling off the solvent. In particular, methanol or ethanol is preferable in terms of the extraction efficiency and the yield because it has good infiltration property with respect to plants used in the present invention.
【0012】また、本発明に係る抽出物はその色や匂い
を除いてより使用しやすくするために、活性炭やカラム
クロマトグラフィー等を用いて、本発明の効果を損わな
い程度に精製を行っても良い。このような精製物もま
た、本発明の皮膚外用剤に用いることができる。本発明
の紫外線吸収性皮膚化粧料全量におけるマメ科植物抽出
物の配合量は、乾燥物として0.005〜30重量%が
好ましい。配合量が0.005重量%未満であると紫外
線吸収効果が十分に発揮されず、また30重量%以上配
合してもコストが高くなり現実的でない。Further, the extract according to the present invention is purified by using activated carbon, column chromatography or the like in order to remove the color and odor and to make it easier to use, to the extent that the effect of the present invention is not impaired. May be. Such a purified product can also be used in the external preparation for skin of the present invention. The compounding amount of the leguminous plant extract in the total amount of the ultraviolet absorbent skin cosmetic of the present invention is preferably 0.005 to 30% by weight as a dried product. If the blending amount is less than 0.005% by weight, the ultraviolet ray absorbing effect is not sufficiently exerted, and if it is blended in an amount of 30% by weight or more, the cost becomes high, which is not realistic.
【0013】本発明の皮膚化粧料においては、マメ科植
物由来の抽出物を少なくとも1種以上含有するものであ
る。本発明の紫外線吸収皮膚化粧料は前記の必須成分に
加え、必要に応じて本発明の効果を損わない範囲内で、
化粧料、医薬部外品、医薬品等に一般に用いられる各種
成分、水性成分、保湿剤、増粘剤、防腐剤、酸化防止
剤、香料、色剤、薬剤等を配合することができる。例え
ば固体状或いは液状パラフィン、クリスタルオイル、セ
レシン、オゾケライト、モンタンロウ等の炭化水素類、
シリコン油類、オリーブ油、地ロウ、カルナバロウ、ラ
ノリンのような植物性もしくは動物性油脂やロウ、更に
ステアリン酸、パルミチン酸、オレイン酸、グリセリン
モノステアリン酸エステル、グリセリンモノオレイン酸
エステル、イソプロピルミリスチン酸プロピル、イソプ
ロピルステアリン酸エステルのような脂肪酸又はそのエ
ステル類、分岐脂肪酸の一価アルコール又は多価アルコ
ールのエステル類、エチルアルコール、イソプロピルア
ルコール、セチルアルコール、パルミチルアルコール等
のアルコール類、グリコール、グリセリン、ソルビトー
ル等の多価アルコール類又はそのエステル類、非イオン
性界面活性剤、アニオン性界面活性剤、カチオン性界面
活性剤のような界面活性剤を挙げることができる。The skin cosmetic of the present invention contains at least one extract derived from legumes. The ultraviolet-absorbing skin cosmetic of the present invention is, in addition to the above-mentioned essential components, within a range that does not impair the effects of the present invention, if necessary,
Various components generally used in cosmetics, quasi drugs, pharmaceuticals, etc., an aqueous component, a moisturizer, a thickener, an antiseptic, an antioxidant, a fragrance, a coloring agent, a drug and the like can be added. Hydrocarbons such as solid or liquid paraffin, crystal oil, ceresin, ozokerite, montan wax, etc.,
Vegetable or animal oils and waxes such as silicone oils, olive oil, ground wax, carnauba wax and lanolin, and stearic acid, palmitic acid, oleic acid, glycerin monostearate ester, glycerin monooleate ester, propyl isopropyl myristate propyl ester , Fatty acids or esters thereof such as isopropyl stearate, esters of monohydric alcohols or polyhydric alcohols of branched fatty acids, alcohols such as ethyl alcohol, isopropyl alcohol, cetyl alcohol, palmityl alcohol, glycols, glycerin, sorbitol Examples thereof include surfactants such as polyhydric alcohols or esters thereof, nonionic surfactants, anionic surfactants, and cationic surfactants.
【0014】また本発明には下記植物抽出物や薬剤も適
宜配合することができる。例えば、トウガラシ、ヨウテ
イ、アロエ、クコ、ヨモギ、カラシ、イネ、マンケイ
シ、マンネンロウ、コッサイホ、エニシダ、リンドウ、
タンジン、ヘチマ、キキョウ、マツ、クジン、ベニバ
ナ、メギ、ビンロウジ、ユーカリ、カゴソウ、モクロ
ウ、ゴシツ、サイコ、チャ、シンイ、ワサビ、ジョテイ
シ(ジョテイジツ)、オランダセンニチ、クチナシ、ウ
スバサイシン、ニンニク、ハッカ、ヨクイニン、キリン
ケツ、ヤシ、ゴボウ、カンゾウ、ホップ、キク、ラッキ
ョ、ニラ、ネギ、タマネギ、セネガ、アマチャヅル、マ
ンネンタケ、ジオウ、グリチルリチン酸モノアンモニウ
ム、グリチルレチン酸、グリチルリチン、ゴマ、センキ
ュウ、カシュウ等が挙げられる。In addition, the following plant extracts and medicines can be appropriately incorporated in the present invention. For example, capsicum, youtei, aloe, wolfberry, mugwort, mustard, rice, mankeishi, mannen wax, kossai ho, nishida, gentian,
Tanjin, loofah, kyoto, pine, kujin, safflower, barberry, areca, eucalyptus, Kagosou, mokuro, goshitsu, psycho, cha, shinui, wasabi, joteishi, netherlands senchi, gardenia, usabasaicin, garlic, mint, Yokuinin, giraffe, palm, burdock, licorice, hop, chrysanthemum, rakkyo, leek, leek, onion, senega, armchadul, mannoke mushroom, dio, monoammonium glycyrrhetinic acid, glycyrrhetinic acid, glycyrrhizinate, sesame, senkyu, kashi and the like.
【0015】また本発明の紫外線吸収皮膚化粧料の剤型
は任意であり、例えば液状、乳液状、クリーム状、ステ
ィック状等の剤型をとることができる。The dosage form of the ultraviolet absorbent skin cosmetic of the present invention is arbitrary, and for example, liquid, emulsion, cream, stick, and other dosage forms can be used.
【0016】[0016]
【実施例】以下、本発明の好適な実施例を説明する。
尚、本発明はこれらに限定されるものではない。また、
配合量は他に指定がない限り重量%で示す。抽出例1 まず、キャシア・チモレンシス(Cassia timorensis D
C.)の樹皮からの有効抽出画分の抽出法について説明す
る。 原料 キャシア・チモレンシス(Cassia timorensis DC.)の
樹皮粉砕品100g 抽出 前記キャシア・チモレンシスの樹皮粉砕品100gにメ
タノール500mlを加え、温度30℃、時間3時間、
回転攪拌数100rpmで抽出操作を行った。 加圧濾過 前記で得られた抽出液を、窒素0.1kg/cm2以
下の加圧力を付加した状態で、濾紙No.2により濾過
を行った。 濃縮 前記で得られた濾液について、温度25〜30℃、減
圧度60〜65torrで減圧濃縮を行った。この結果、メ
タノール抽出物1.13gが得られた。The preferred embodiments of the present invention will be described below.
The present invention is not limited to these. Also,
Unless otherwise specified, the compounding amount is shown in% by weight. Extraction Example 1 First, Cassia timorensis D
The method for extracting the effective extraction fraction from the bark of C.) will be described. Raw material Cassia timorensis DC. 100g crushed bark extract 100ml of crushed Cassia timorensis bark added with 500 ml of methanol, temperature 30 ° C, time 3 hours,
The extraction operation was performed at a rotational stirring number of 100 rpm. Pressure filtration The extract obtained as described above was filtered under a pressure of nitrogen of 0.1 kg / cm 2 or less, with filter paper No. Filtered by 2. Concentration The filtrate obtained above was concentrated under reduced pressure at a temperature of 25 to 30 ° C. and a degree of reduced pressure of 60 to 65 torr. As a result, 1.13 g of a methanol extract was obtained.
【0017】試験例1 紫外線吸収スペクトルの測定 前記抽出例1の抽出物を濃度10ppmとなるようにエ
タノールに溶解し、紫外線吸収スペクトルを測定した。
また、同じ天然物由来の紫外線吸収剤として、甘草(Gl
ycyrrhizae Radix)の全草から前記抽出例1と同様に抽
出した抽出物を比較例1として用い、同様に紫外線吸収
スペクトルを測定した。 Test Example 1 Measurement of Ultraviolet Absorption Spectrum The extract of Extraction Example 1 was dissolved in ethanol to a concentration of 10 ppm and the ultraviolet absorption spectrum was measured.
In addition, as an ultraviolet absorber derived from the same natural product, licorice (Gl
An extract extracted from the whole plant of ycyrrhizae Radix) in the same manner as in the above-mentioned Extraction Example 1 was used as Comparative Example 1, and the ultraviolet absorption spectrum was similarly measured.
【0018】その結果を図1及び図2に示す。抽出例1
は約325nmのUV−A領域に最大吸収を有し、約2
70〜350nmというUV−A〜UV−B領域で優れ
た紫外線吸収能を示したが、比較例1では約280nm
のUV−C領域に最大吸収を有し、UV−A〜UV−B
領域における紫外線吸収能は低かった。以上のことから
明らかなように、本発明の抽出物はUV−A及びUV−
B領域に優れた紫外線吸収能を有していた。The results are shown in FIGS. 1 and 2. Extraction example 1
Has a maximum absorption in the UV-A region of about 325 nm and is about 2
Although it showed an excellent ultraviolet absorbing ability in the UV-A to UV-B region of 70 to 350 nm, it was about 280 nm in Comparative Example 1.
Has maximum absorption in the UV-C region of UV-A to UV-B
The ultraviolet absorption capacity in the region was low. As is clear from the above, the extract of the present invention is UV-A and UV-A.
It had an excellent ultraviolet absorbing ability in the B region.
【0019】試験例2 光安定性 次に本発明者らは、本発明にかかる植物抽出物の光安定
性について検討した。すなわち、前記抽出例1及び比較
例1の抽出物を濃度30ppmとなるようにエタノール
に溶解してガラス製サンプルビンに充填し、キセノンラ
ンプ光照射を30時間(夏場の約10日に相当)行っ
た。キセノンランプ照射前後に紫外線吸収スペクトルを
測定し、その紫外線吸収能を比較した。その結果、抽出
例1のキセノンランプ照射後の紫外線吸収スペクトルの
チャートは照射前と殆ど変化が認められなかったが、比
較例1では270nm以上の波長領域で吸光度が大きく
低下していた。以上の結果から、本発明にかかる抽出物
は優れた光安定性を有していることが理解される。 Test Example 2 Light Stability Next, the present inventors examined the light stability of the plant extract according to the present invention. That is, the extracts of Extraction Example 1 and Comparative Example 1 were dissolved in ethanol so as to have a concentration of 30 ppm and filled in a glass sample bottle, and a xenon lamp light irradiation was performed for 30 hours (corresponding to about 10 days in summer). It was The ultraviolet absorption spectra were measured before and after irradiation with a xenon lamp, and the ultraviolet absorption capacities were compared. As a result, the chart of the ultraviolet absorption spectrum after the irradiation with the xenon lamp in Extraction Example 1 showed almost no change from that before the irradiation, but in Comparative Example 1, the absorbance was greatly reduced in the wavelength region of 270 nm or more. From the above results, it is understood that the extract according to the present invention has excellent photostability.
【0020】以下に本発明にかかるマメ科植物抽出物を
配合した皮膚化粧料の配合例を示す。配合例1 クリーム A.油相 ステアリン酸 10.0% ステアリルアルコール 4.0 グリセリンモノステアリン酸エステル 8.0 ビタミンEアセテート 0.5 香料 0.4 エチルパラベン 0.1 ブチルパラベン 0.1 プロピルパラベン 0.1 B.水相 キャシア・チモレンシス樹皮抽出物(抽出例1) 0.03 1,3−ブチレングリコール 10.0 プロピレングリコール 8.0 グリセリン 2.0 水酸化カリウム 0.4 精製水 残 余The following is a formulation example of a skin cosmetic containing the legume extract according to the present invention. Formulation Example 1 Cream A. Oil phase Stearic acid 10.0% Stearyl alcohol 4.0 Glycerin monostearate 8.0 Vitamin E acetate 0.5 Perfume 0.4 Ethylparaben 0.1 Butylparaben 0.1 Propylparaben 0.1 B. Aqueous phase Cassia Timorensis bark extract (Extraction example 1) 0.03 1,3-butylene glycol 10.0 Propylene glycol 8.0 Glycerin 2.0 Potassium hydroxide 0.4 Purified water Residue
【0021】〈製法〉キャシア・チモレンシス樹皮抽出
物を1,3−ブチレングリコールに予め溶解したものを
用いて、更に各成分を溶解し、水相Bを製造する。そし
て、油相Aと水相Bをそれぞれ70℃に加熱し、完全溶
解する。A相をB相に加えて、乳化機で乳化する。乳化
物を熱交換機を用いて冷却してクリームを得た。また、
本配合例にかかるクリームを75%エタノールにキャシ
ア・チモレンシス抽出物濃度が0.003%濃度溶液と
なるように希釈し、石英セルに入れ、分光光度計により
200〜700nmの波長の吸光度を測定した結果、抽
出例1の紫外線吸収スペクトル(図1)と同様に270
〜350nm付近の波長領域において高い吸収能を有
し、日焼け防止等に効果があることが示唆された。<Manufacturing Method> A water phase B is manufactured by further dissolving each component using a solution of Cassia thymolensis bark extract previously dissolved in 1,3-butylene glycol. Then, the oil phase A and the water phase B are heated to 70 ° C. to completely dissolve them. Phase A is added to phase B and emulsified with an emulsifier. The emulsion was cooled using a heat exchanger to obtain a cream. Also,
The cream according to this formulation example was diluted with 75% ethanol so that the Cassia thymolensis extract concentration became a 0.003% concentration solution, placed in a quartz cell, and the absorbance at a wavelength of 200 to 700 nm was measured by a spectrophotometer. As a result, the UV absorption spectrum of Extraction Example 1 was 270
It has been suggested that it has a high absorption ability in the wavelength region around 350 nm and is effective in preventing sunburn.
【0022】以下の皮膚化粧料は何れも配合例1と同
様、安全性が高く、紫外線吸収効果を有する皮膚化粧料
であった。配合例2 クリーム A.セタノール 4.0% ワセリン 7.0 イソプロピルミリステート 8.0 スクワラン 12.0 ジメチルポリシロキサン 3.0 グリセリンモノステアリル酸エステル 2.2 POE(20)ソルビタンモノステアレート 2.8 グリチルレチン酸ステアレート 0.02 エチルパラベン 0.1 ブチルパラベン 0.1 B.水相 ハナセンナ樹皮抽出物 0.1 1,3−ブチレングリコール 7.0 フェノキシエタノール 0.2 L−アスコルビン酸リン酸エステルマグネシウム塩 3.0 アスコルビン酸リン酸エステルマグネシウム塩 1.0 精製水 残 余All of the following skin cosmetics were highly safe and had an ultraviolet absorbing effect as in Formulation Example 1. Formulation 2 Cream A. Cetanol 4.0% Vaseline 7.0 Isopropyl myristate 8.0 Squalane 12.0 Dimethylpolysiloxane 3.0 Glycerin monostearyl ester 2.2 POE (20) sorbitan monostearate 2.8 Glycyrrhetinic acid stearate 0.0. 02 Ethylparaben 0.1 Butylparaben 0.1 B.I. Water phase Hana Senna bark extract 0.1 1,3-butylene glycol 7.0 Phenoxyethanol 0.2 L-Ascorbic acid phosphate magnesium salt 3.0 Ascorbic acid phosphate magnesium salt 1.0 Purified water Residue
【0023】〈製法〉ハナセンナ樹皮抽出物を1,3−
ブチレングリコールに予め溶解した後、配合例1に準じ
てクリームを得た。<Production method> 1,3-
After preliminarily dissolving in butylene glycol, a cream was obtained according to Formulation Example 1.
【0024】配合例3 乳液 A.油相 スクワラン 5.0% オレイルオレート 3.0 ワセリン 2.0 ソルビタンセスキオレイン酸エステル 0.8 ポリオキシエチレン(20)オレイルエーテル 1.2 2−エチルヘキシル−p−メトキシシンナメート 3.0 香料 0.12 B.水相 センナ樹皮抽出物 0.2 ジプロピレングリコール 5.0 エタノール 3.0 カルボキシルビニルポリマー 0.17 ヒアルロン酸ナトリウム 0.1 水酸化カリウム 0.08 メチルパラベン 0.15 ヘキサメタンリン酸ナトリウム 0.05 精製水 残 余 Formulation Example 3 Emulsion A. Oil phase Squalane 5.0% Oleyl oleate 3.0 Vaseline 2.0 Sorbitan sesquioleate 0.8 Polyoxyethylene (20) oleyl ether 1.2 2-Ethylhexyl-p-methoxycinnamate 3.0 Perfume 0.1. 12 B. Water phase Senna bark extract 0.2 Dipropylene glycol 5.0 Ethanol 3.0 Carboxyl vinyl polymer 0.17 Sodium hyaluronate 0.1 Potassium hydroxide 0.08 Methylparaben 0.15 Sodium hexamethanephosphate 0.05 Purification Water residue
【0025】〈製法〉センナ樹皮抽出物を予めジプロピ
レングリコールに溶解した後、配合例1に準じて乳液を
得た。<Manufacturing Method> The senna bark extract was previously dissolved in dipropylene glycol, and then an emulsion was obtained according to the formulation example 1.
【0026】配合例4 クリーム A.油相 ベヘニルアルコール 0.5% 12-ヒト゛ロキシステアリン酸 コレスタノールエステル 2.0 スクワラン 7.0 ホホバオイル 5.0 自己乳化型モノステアリン酸グリセリル 2.5 ポリオキシエチレン(20) ソルビタンモノステアリン酸エステル 1.5 2−ヒドロキシ−4−メトキシベンゾフェノン 3.0 エチルパラベン 0.2 ブチルパラベン 0.1 香料 0.1 B.水相 1,3−ブチレングリコール 6.0 コバノセンナ樹皮抽出物 0.05 グリセリン 3.5 亜鉛崋 1.5 カオリン 0.5 ベントナイト 0.3 ヘキサメタリン酸ナトリウム 0.03 精製水 残 余 Formulation Example 4 Cream A. Oil phase Behenyl alcohol 0.5% 12-human oxystearic acid cholestanol ester 2.0 Squalane 7.0 Jojoba oil 5.0 Self-emulsifying glyceryl monostearate 2.5 Polyoxyethylene (20) sorbitan monostearate 1. 5 2-Hydroxy-4-methoxybenzophenone 3.0 Ethylparaben 0.2 Butylparaben 0.1 Perfume 0.1 B.I. Aqueous phase 1,3-butylene glycol 6.0 Covanocenna bark extract 0.05 Glycerin 3.5 Zinc oxide 1.5 Kaolin 0.5 Bentonite 0.3 Sodium hexametaphosphate 0.03 Purified water Residue
【0027】〈製法〉コバノセンナ樹皮抽出物を1,3
−ブチレングリコールに溶解した後、配合例1に準じた
製法で粉末入りクリームを得た。<Manufacturing Method> 1,3 of Kovanocenna bark extract
-After being dissolved in butylene glycol, a powdered cream was obtained by a production method according to Formulation Example 1.
【0028】配合例5 エッセンス A.油相 ステアリン酸 3.0% セタノール 1.0 ラノリン誘導体 3.0 流動パラフィン 5.0 2−エチルヘキシルステアレート 3.0 POEセチルアルコールエーテル 2.0 モノステアリン酸グリセリン 2.0 防腐剤 適 量 香料 適 量 B.水相 1,3−ブチレングリコール 6.0 トリエタノールアミン 10.0 コヤシセンナ茎抽出物 10.0 精製水 残 余 Formulation Example 5 Essence A. Oil phase Stearic acid 3.0% Cetanol 1.0 Lanolin derivative 3.0 Liquid paraffin 5.0 2-Ethylhexyl stearate 3.0 POE Cetyl alcohol ether 2.0 Glycerin monostearate 2.0 Preservative Suitable amount Perfume Suitable Amount B. Water phase 1,3-butylene glycol 6.0 Triethanolamine 10.0 Coconut senna stem extract 10.0 Purified water Residue
【0029】〈製法〉1,3−ブチレングリコールにコ
ヤシセンナ茎抽出物を溶解し、これをトリエタノールア
ミンとともに精製水に溶解し、水相Bを製造する。ステ
アリン酸、セタノール、ラノリン誘導体、流動パラフィ
ン、2−エチルヘキシルステアレート、モノステアリン
酸グリセリンを70〜80℃にて加熱溶解後、POEセ
チルアルコールエーテル、防腐剤、香料を順次溶解し、
温度を70℃にし、油相Aを製造する。前述の水相Bに
攪拌しながら油相Aを添加し、乳化を行う。ホモミキサ
ーで乳化粒子を均一に調製後、脱気、冷却を行い、エッ
センスを得た。<Manufacturing Method> A coconut senna stem extract is dissolved in 1,3-butylene glycol, and this is dissolved in purified water together with triethanolamine to prepare an aqueous phase B. Stearic acid, cetanol, lanolin derivative, liquid paraffin, 2-ethylhexyl stearate, and glycerol monostearate are heated and dissolved at 70 to 80 ° C., and then POE cetyl alcohol ether, preservative, and perfume are sequentially dissolved,
The temperature is brought to 70 ° C. and oil phase A is produced. The oil phase A is added to the above-mentioned water phase B with stirring to emulsify. After uniformly preparing the emulsified particles with a homomixer, deaeration and cooling were performed to obtain an essence.
【0030】配合例6 エッセンス A.エタノール相 ソルビタンモノオレイン酸エステル 1.0% オレイルアルコール 0.5 ビタミンEアセテート 0.2 香料 適 量 エタノール 10.0 POEソルビタンジラウレート モノステアリン酸エステル 1.0 防腐剤 適 量 退色防止剤 適 量 B.水相 ナンバンサイカチ樹皮抽出物 0.05 ジプロピレングリコール 5.0 ポリエチレングリコール400 5.0 カルボキシビニルポリマー 0.3 アルギン酸ナトリウム 0.3 水酸化ナトリウム 0.15 POEソルビタンジラウレート モノステアリン酸エステル 1.0 プラセンタエキス 0.2 精製水 残 部 Formulation 6 Essence A. Ethanol phase Sorbitan monooleate 1.0% Oleyl alcohol 0.5 Vitamin E acetate 0.2 Perfume proper amount Ethanol 10.0 POE sorbitan dilaurate monostearate ester 1.0 Preservative proper amount anti-fading agent proper amount B. Water phase Nanbansai Kachi Bark Extract 0.05 Dipropylene glycol 5.0 Polyethylene glycol 400 5.0 Carboxyvinyl polymer 0.3 Sodium alginate 0.3 Sodium hydroxide 0.15 POE sorbitan dilaurate monostearate 1.0 Placenta Extract 0.2 Purified water balance
【0031】〈製法〉精製水にカルボキシビニルポリマ
ーを溶解した後、ジプロピレングリコール、ポリエチレ
ングリコール400、ナンバンサイカチを順次溶解し、
水相Bを得る。エタノールにPOEソルビタンジラウレ
ートモノステアリン酸エステル、ソルビタンモノオレイ
ン酸エステル、オレイルアルコール、ビタミンEアセテ
ート、香料、防腐剤、退色防止剤を順次溶解し、エタノ
ール相Aを得、該エタノール相Aを水相Bに添加し乳化
する。精製水の一部に水酸化ナトリウムを溶解し、これ
を添加して攪拌、脱気、濾過する。<Manufacturing Method> After dissolving the carboxyvinyl polymer in purified water, dipropylene glycol, polyethylene glycol 400 and Nanbansai Kachi are sequentially dissolved,
An aqueous phase B is obtained. POE sorbitan dilaurate monostearate ester, sorbitan monooleate ester, oleyl alcohol, vitamin E acetate, perfume, preservative and anti-fading agent are sequentially dissolved in ethanol to obtain ethanol phase A, and ethanol phase A is converted to aqueous phase B. And emulsify. Sodium hydroxide is dissolved in a part of purified water, which is added, stirred, degassed, and filtered.
【0032】配合例7 水中油型ファンデーション A.粉体 タルク 3.0% 二酸化チタン 5.0 ベンガラ 0.5 黄酸化鉄 1.4 黒酸化鉄 0.1 B.水相 ベントナイト 0.5 モノステアリン酸ポリオキシエチレンソルビタン 0.9 トリエタノールアミン 1.0 プロピレングリコール 10.0 ジャワセンナ樹皮抽出物 0.1 精製水 56.4 C.油相 ステアリン酸 2.2 イソヘキサデシルアルコール 7.0 モノステアリン酸グリセリン 2.0 液状ラノリン 2.0 流動パラフィン 8.0 防腐剤 適 量 香料 適 量 Formulation Example 7 Oil-in-water foundation A. Powder talc 3.0% Titanium dioxide 5.0 Red iron oxide 0.5 Yellow iron oxide 1.4 Black iron oxide 0.1 B. Water phase Bentonite 0.5 Polyoxyethylene sorbitan monostearate 0.9 Triethanolamine 1.0 Propylene glycol 10.0 Java senna bark extract 0.1 Purified water 56.4 C.I. Oil phase Stearic acid 2.2 Isohexadecyl alcohol 7.0 Glycerin monostearate 2.0 Liquid lanolin 2.0 Liquid paraffin 8.0 Preservative proper amount Perfume proper amount
【0033】〈製法〉予めジャワセンナ樹皮抽出物を一
部プロピレングリコールに溶解し、また水相の増粘剤で
あるベントナイト残部プロピレングリコールに分散す
る。これらを精製水に加え、70℃でホモミキサー処理
した後、残りの水相成分を添加し十分に攪拌する。これ
に十分混合粉砕された粉体部を攪拌しながら添加し、7
0℃でホモミキサー処理する。次に70℃〜80℃で加
熱溶解された油相を徐々に添加し70℃でホモミキサー
処理する。これを攪拌しながら冷却し、45℃で香料を
加え、室温まで冷却する。最後に脱気し容器に充填す
る。<Manufacturing Method> The Java senna bark extract is partially dissolved in propylene glycol in advance and dispersed in propylene glycol, which is the bentonite remaining as a thickener in the aqueous phase. These are added to purified water and subjected to a homomixer treatment at 70 ° C., then the remaining water phase components are added and sufficiently stirred. Add the powder portion that has been thoroughly mixed and pulverized to this while stirring,
Perform homomixer treatment at 0 ° C. Next, the oil phase heated and dissolved at 70 ° C. to 80 ° C. is gradually added and subjected to a homomixer treatment at 70 ° C. This is cooled with stirring, the fragrance is added at 45 ° C., and it is cooled to room temperature. Finally, degas and fill the container.
【0034】配合例8 W/O乳化型ファンデーション(クリームタイプ) A.粉体 セリサイト 5.36% カオリン 4.0 二酸化チタン 9.32 ベンガラ 0.36 黄酸化鉄 0.8 黒酸化鉄 0.16 B.油相 流動パラフィン 5.0 デカメチルシクロペンタシロキサン 12.0 ポリオキシエチレン変性ジメチルポリシロキサン 4.0 精製水 51.9 C.水相 分散剤 0.1 1,3−ブチレングリコール 5.0 エビスグサ全草抽出物 0.08 精製水 51.9 防腐剤 適 量 D.その他 安定化剤 2.0 香料 適 量 Formulation Example 8 W / O emulsion type foundation (cream type) A. Powder sericite 5.36% Kaolin 4.0 Titanium dioxide 9.32 Red iron oxide 0.36 Yellow iron oxide 0.8 Black iron oxide 0.16 B. Oil phase Liquid paraffin 5.0 Decamethylcyclopentasiloxane 12.0 Polyoxyethylene-modified dimethylpolysiloxane 4.0 Purified water 51.9 C.I. Aqueous phase dispersant 0.1 1,3-butylene glycol 5.0 Ebisugusha whole grass extract 0.08 Purified water 51.9 Preservative A suitable amount D.I. Other stabilizers 2.0 Fragrance suitable amount
【0035】〈製法〉エビスグサ全草樹皮抽出物を予め
1,3−ブチレングリコールに溶解し、更に水相を70
℃で加熱攪拌後、十分混合粉砕された粉体部を添加し7
0℃でホモミキサー処理する。これに一部の精製水に溶
解した安定化剤を加え攪拌する。更に70℃に加熱した
油相を加え、70℃でホモミキサー処理する。これを攪
拌しながら冷却し45℃で香料を加え、室温まで冷却す
る。最後に脱気し容器に充填する。<Production Method> The whole bark extract of Ebisugusha is dissolved in 1,3-butylene glycol in advance, and the aqueous phase is added to 70%.
After heating and stirring at ℃, add the powder part that was thoroughly mixed and pulverized.
Perform homomixer treatment at 0 ° C. A stabilizer dissolved in a part of purified water is added to this and stirred. Further, the oil phase heated to 70 ° C. is added, and the mixture is homomixed at 70 ° C. This is cooled with stirring, a fragrance is added at 45 ° C., and cooled to room temperature. Finally, degas and fill the container.
【0036】配合例9 W/Oクリームタイプサンスクリーン化粧料 A.水相 精製水 54.95% 1,3−ブチレングリコール 7.0 二酸化チタン 5.0 エデト酸二ナトリウム 0.05 エタノール 2.0 ハブソウ全草抽出物 0.5 B.油相 オキシベンゾン 2.0 パラメトキシケイ皮酸オクチル 5.0 スクワラン 10.0 ワセリン 5.0 ステアリルアルコール 3.0 ステアリン酸 3.0 グリセリルモノステアレート 3.0 ポリアクリル酸エチル 1.0 酸化防止剤 適 量 防腐剤 適 量 香料 適 量 Formulation Example 9 W / O cream type sunscreen cosmetic A. Aqueous phase Purified water 54.95% 1,3-butylene glycol 7.0 Titanium dioxide 5.0 Disodium edetate 0.05 Ethanol 2.0 Whole hazelnut extract 0.5 B. Oil phase Oxybenzone 2.0 Octyl paramethoxycinnamate 5.0 Squalane 10.0 Vaseline 5.0 Stearyl alcohol 3.0 Stearic acid 3.0 Glyceryl monostearate 3.0 Polyethyl acrylate 1.0 Antioxidant Appropriate amount Preservative Appropriate amount Perfume Appropriate amount
【0037】〈製法〉ハブソウ全草抽出物をエタノール
に予め溶解し、更に油相部と水相部をそれぞれ70℃に
加熱し溶解させる。水相部は二酸化チタンの分散を十分
に行い、油相部を加え、ホモジナイザーを用いて乳化す
る。乳化物を熱交換機を用い冷却する。<Manufacturing Method> The whole extract of Habusoum is dissolved in ethanol in advance, and the oil phase and the water phase are heated to 70 ° C. to dissolve them. In the water phase part, titanium dioxide is sufficiently dispersed, the oil phase part is added, and the mixture is emulsified using a homogenizer. The emulsion is cooled using a heat exchanger.
【0038】配合例10 O/W乳液タイプサンスクリーン化粧料 A.水相 精製水 68.3 ジプロピレングリコール 6.0 エタノール 3.0 ヒドロキシエチルセルロース 0.3 タガヤサンノキ樹皮抽出物 0.005 B.油相 パラメトキシケイ皮酸オクチル 6.0 ジパラメトキシケイ皮酸グリセリルオクチル 2.0 4-tert-ブチル4′-メトキシベンゾイルメタン 2.0 オキシベンゾン 3.0 オレイルオレート 5.0 ジメチルポリシロキサン 3.0 ワセリン 0.5 セチルアルコール 1.0 ソルビタンセスキオレイン酸エステル 0.8 POE(29)オレイルアルコールエーテル 1.2 酸化防止剤 適 量 防腐剤 適 量 香料 適 量 Formulation Example 10 O / W emulsion type sunscreen cosmetic A. Aqueous phase Purified water 68.3 Dipropylene glycol 6.0 Ethanol 3.0 Hydroxyethyl cellulose 0.3 Tagaya Sanuki bark extract 0.005 B.I. Oil phase Octyl paramethoxycinnamate 6.0 Glyceryloctyl diparamethoxycinnamate 2.0 4-tert-Butyl 4′-methoxybenzoylmethane 2.0 Oxybenzone 3.0 Oleyloleate 5.0 Dimethylpolysiloxane 3. 0 Vaseline 0.5 Cetyl alcohol 1.0 Sorbitan sesquioleate ester 0.8 POE (29) oleyl alcohol ether 1.2 Antioxidant proper amount Preservative proper amount Perfume proper amount
【0039】〈製法〉タガヤサンノキ樹皮抽出物を予め
エタノールに溶解し、更に他の水相成分と合わせて70
℃に加熱し、水相を調製する。そして、油相部を70℃
に加熱溶解させる。水相部に油相部を加え、ホモジナイ
ザーを用い乳化する。乳化物を熱交換機を用い冷却す
る。<Manufacturing Method> An extract of bark of Agave japonicus is dissolved in ethanol in advance, and the solution is combined with other aqueous phase components to 70%.
Heat to ° C to prepare the aqueous phase. And the oil phase part is 70 ° C
Heat to dissolve. Add the oil phase to the water phase and emulsify using a homogenizer. The emulsion is cooled using a heat exchanger.
【0040】配合例11 W/O型クリームタイプサンスクリーン化粧料 A.水相 精製水 36.5% 1,3−ブチレングリコール 6.0 オオバノセンナ全草抽出物 1.0 B.油相 パラメトキシケイ皮酸オクチル 5.0 オキシベンゾン 3.0 4-tert-ブチル4′-メトキジベンゾイルメタン 1.0 疎水化処理二酸化チタン 3.0 スクワラン 40.0 ジイソステアリン酸グリセリン 3.0 有機変性モンモリロナイト 1.5 防腐剤 適 量 香料 適 量 Formulation Example 11 W / O type cream type sunscreen cosmetic A. Aqueous phase Purified water 36.5% 1,3-butylene glycol 6.0 Obana senna whole plant extract 1.0 B.I. Oil phase Octyl paramethoxycinnamate 5.0 Oxybenzone 3.0 4-tert-butyl 4'-methokidibenzoylmethane 1.0 Hydrophobized titanium dioxide 3.0 Squalane 40.0 Glycerin diisostearate 3.0 Organically modified Montmorillonite 1.5 Preservative Suitable amount Perfume Suitable amount
【0041】〈製法〉予めエタノールにオオバノセンナ
全草抽出物を溶解し、更に油相部と水相部をそれぞれ7
0℃に加熱溶解させる。油相部は二酸化チタンの分散を
十分に行い、ホモジナイザー処理を行いながら水相部を
添加する。乳化物を熱交換機を用い冷却する。<Manufacturing Method> The whole plant extract of Obana senna was dissolved in ethanol in advance, and the oil phase part and the water phase part were each added to 7 parts.
Dissolve by heating at 0 ° C. In the oil phase part, titanium dioxide is sufficiently dispersed, and the water phase part is added while performing a homogenizer treatment. The emulsion is cooled using a heat exchanger.
【0042】配合例12 ローション 精製水 40.0% ジプロピレングリコール 5.0 1,3−ブチレングリコール 10.0 ポリエチレングリコール400 10.0 エチルアルコール 20.0 ポリオキシエチレン(60)硬化ヒマシ油 3.0 パラメトキシケイ皮酸オクチル 1.0 モクセンナ樹皮抽出物 5.0 トリエタノールアミン 5.0 香料 適 量 Formulation Example 12 Lotion Purified water 40.0% Dipropylene glycol 5.0 1,3-butylene glycol 10.0 Polyethylene glycol 400 10.0 Ethyl alcohol 20.0 Polyoxyethylene (60) hydrogenated castor oil 3. 0 Octyl paramethoxycinnamate 1.0 Moxenna bark extract 5.0 Triethanolamine 5.0 Perfume Suitable amount
【0043】〈製法〉エチルアルコールにポリオキシエ
チレン(60)硬化ヒマシ油、パラメトキシケイ皮酸オ
クチル及び香料を溶解する(アルコール相)。一方、エ
タノールにモクセンナ樹皮抽出物を予め溶解し、更に精
製水にその他の多価アルコールを添加し、十分に溶解さ
せる(水相)。水相にアルコール相を添加し、充分に攪
拌する。<Production Method> Polyoxyethylene (60) hydrogenated castor oil, octyl paramethoxycinnamate and a fragrance are dissolved in ethyl alcohol (alcohol phase). On the other hand, the moxenna bark extract is dissolved in ethanol in advance, and other polyhydric alcohol is added to purified water to sufficiently dissolve it (aqueous phase). Add the alcohol phase to the aqueous phase and stir well.
【0044】配合例13 O/W型乳液タイプサンスクリーン化粧料 A.油相 流動パラフィン 3.0% ミリスチン酸イソプロピル 2.0 オレイルオレエート 4.0 ワセリン 2.0 ステアリルアルコール 1.0 ステアリン酸 2.0 グリセリルモノステアレート 2.0 ビタミンEアセテート 適 量 防腐剤 適 量 香料 適 量 B.水相 精製水 77.8 1,3−ブチレングリコール 6.0 カルボキシビニルポリマー 0.2 トリエタノールアミン 3.0 キャシア・チモレンシス樹皮抽出物(抽出例1) 0.1 Formulation Example 13 O / W emulsion type sunscreen cosmetic A. Oil phase Liquid paraffin 3.0% Isopropyl myristate 2.0 Oleyl oleate 4.0 Vaseline 2.0 Stearyl alcohol 1.0 Stearic acid 2.0 Glyceryl monostearate 2.0 Vitamin E acetate Suitable amount Preservative Suitable amount Perfume proper amount B. Aqueous phase Purified water 77.8 1,3-Butylene glycol 6.0 Carboxyvinyl polymer 0.2 Triethanolamine 3.0 Cassia Timorensis bark extract (Extraction example 1) 0.1
【0045】〈製法〉キャシア・チモレンシス樹皮抽出
物を1,3−ブチレングリコールに予め溶解し、更に油
相部と水相部をそれぞれ70℃に加熱溶解させる。水相
に油相を加え、ホモジナイザーを用い乳化する。乳化物
を熱交換機を用い冷却する。<Manufacturing Method> The Cassia thymolensis bark extract is dissolved in 1,3-butylene glycol in advance, and the oil phase portion and the water phase portion are respectively dissolved by heating at 70 ° C. The oil phase is added to the aqueous phase, and the mixture is emulsified using a homogenizer. The emulsion is cooled using a heat exchanger.
【0046】[0046]
【発明の効果】以上説明したように本発明に係る皮膚化
粧料はマメ科植物(Leguminosae Juss.)の抽出物を配合
することにより、安全性、光安定性が高く、しかも優れ
た紫外線吸収効果を有する皮膚化粧料である。EFFECT OF THE INVENTION As described above, the skin cosmetic composition according to the present invention has high safety and photostability by incorporating an extract of leguminous plant ( Leguminosae Juss.), And has an excellent ultraviolet absorbing effect. It is a skin cosmetic having.
【図1】本発明の実施例にかかるキャシア・チモレンシ
ス(Cassia timorensis DC.)樹皮のメタノール抽出物
(抽出例1)の紫外線吸収スペクトル図である。FIG. 1 is an ultraviolet absorption spectrum diagram of a methanol extract of Cassia timorensis DC. Bark (Extraction Example 1) according to an example of the present invention.
【図2】本発明の比較例である甘草(Glycyrrhizae Rad
ix)全草のメタノール抽出物(比較例1)の紫外線吸収
スペクトル図である。FIG. 2 is a comparative example of the present invention, licorice (Glycyrrhizae Rad)
ix) It is an ultraviolet absorption spectrum diagram of the methanol extract of the whole plant (Comparative Example 1).
───────────────────────────────────────────────────── フロントページの続き (72)発明者 伊藤 建三 神奈川県横浜市港北区新羽町1050番地 株 式会社資生堂第一リサーチセンター内 (72)発明者 中村 哲治 神奈川県横浜市港北区新羽町1050番地 株 式会社資生堂第一リサーチセンター内 (72)発明者 西 豊行 京都府京都市南区吉祥院西ノ庄門口町14番 地 日本新薬株式会社内 (72)発明者 佐野 彰 京都府京都市南区吉祥院西ノ庄門口町14番 地 日本新薬株式会社内 (72)発明者 小島 信敏 京都府京都市南区吉祥院西ノ庄門口町14番 地 日本新薬株式会社内 ─────────────────────────────────────────────────── ─── Continued Front Page (72) Inventor Kenzo Ito 1050 Shinba-cho, Kohoku-ku, Yokohama City, Kanagawa Prefecture Shiseido Daiichi Research Center (72) Inventor Tetsuji Nakamura 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Address Incorporated Shiseido Daiichi Research Center (72) Inventor Toyoyuki Nishi 14 14 Nishinoshomonguchicho, Kichijoin, Minami-ku, Kyoto-shi, Kyoto Prefecture Nippon Shinyaku Co., Ltd. (72) Inventor Akira Sano Minami, Kyoto-shi, Kyoto Prefecture 14 Shinnoshomonguchi-cho, Kichijoin-ku, Nippon Shinyaku Co., Ltd. (72) Nobutoshi Kojima 14 Shinnoshomonguchi-cho, Kichijoin, Minami-ku, Kyoto Prefecture
Claims (4)
物を含有することを特徴とする皮膚化粧料。1. A skin cosmetic comprising an extract of a leguminous plant ( Leguminosae Juss.).
メ科植物(Leguminosae Juss.)の抽出物がカワラケツメ
イ属植物(Cassia Linn.)の抽出物であることを特徴とす
る皮膚化粧料。2. The skin cosmetic according to claim 1, wherein the extract of the leguminous plant ( Leguminosae Juss.) Is an extract of the plant of the genus Cassia Linn.
て、マメ科植物(Leguminosae Juss.)の抽出物が、カワ
ラケツメイ属植物(Cassia Linn.)に属するキャシア・チ
モレンシス(Cassia timorensis DC.)、ハナセンナ(Ca
ssia alata Linn.)、センナ(Cassia angustifolia Vah
l)、コバノセンナ(Cassia coluteoidesCollad)、ハナセ
ンナ(Cassia corymbosa Lam.)、コヤシセンナ(Cassia d
idymobotrya Fresen.)、ナンバンサイカチ(Cassia fist
ura Linn.)、ジャワセンナ(Cassia javanica Linn.)、
エビスグサ(Cassia obutusifolia Linn.)、ハブソウ(Ca
ssia occidentalis Linn.)、タガヤサンノキ(Cassia si
amea Lam.)、オオバノセンナ(Cassia sophera Linn.)、
モクセンナ(Cassia surattensis Burm.f.)の抽出物の中
から選ばれた少なくとも1種以上の抽出物であることを
特徴とする皮膚化粧料。3. The skin cosmetic according to claim 1 or 2, wherein the extract of leguminous plant ( Leguminosae Juss.) Is Cassia timorensis DC., Which belongs to the genus Plant of Cassia Linn. Hanasenna ( Ca
ssia alata Linn.), Senna ( Cassia angustifolia Vah
l), Cobano senna ( Cassia coluteoides Collad), Hana senna ( Cassia corymbosa Lam.), Cocos senna ( Cassia d
idymobotrya Fresen.), Nanbang Saikachi ( Cassia fist
ura Linn.), Java Senna ( Cassia javanica Linn.),
Ebisugusa ( Cassia obutusifolia Linn.), Habuso ( Ca
ssia occidentalis Linn.), Tagaya Sanki ( Cassia si
amea Lam.), Obano Senna ( Cassia sophera Linn.),
A skin cosmetic, which is an extract of at least one selected from the extracts of Moxenna ( Cassia surattensis Burm.f.).
て、マメ科植物(Leguminosae Juss.)の抽出物がカワラ
ケツメイ属(Cassia Linn.)の樹皮から抽出された抽出物
であることを特徴とする皮膚化粧料。4. The skin cosmetic according to any one of claims 1 to 3, wherein the extract of leguminous plant ( Leguminosae Juss.) Is an extract extracted from the bark of the genus Cassia Linn. Skin cosmetics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5343025A JPH07165527A (en) | 1993-12-15 | 1993-12-15 | Ultraviolet-absorbing skin cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5343025A JPH07165527A (en) | 1993-12-15 | 1993-12-15 | Ultraviolet-absorbing skin cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07165527A true JPH07165527A (en) | 1995-06-27 |
Family
ID=18358363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5343025A Withdrawn JPH07165527A (en) | 1993-12-15 | 1993-12-15 | Ultraviolet-absorbing skin cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07165527A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0952814A (en) * | 1995-08-09 | 1997-02-25 | Sunstar Inc | Skin cosmetic composition |
| FR2813195A1 (en) * | 2000-08-29 | 2002-03-01 | Serobiologiques Lab Sa | USE OF CASSIA ALATA PLANT EXTRACTS IN CARE PRODUCTS |
| JP2002265343A (en) * | 2001-03-07 | 2002-09-18 | Ichimaru Pharcos Co Ltd | Cosmetic composition |
| JP2009215269A (en) * | 2008-03-13 | 2009-09-24 | Okinawa Pref Gov | Tyrosinase activity inhibitor and skin-lightening cosmetic containing the same |
| KR20210006151A (en) * | 2019-07-08 | 2021-01-18 | 주식회사 팜스킨 | A composition for blue light interception comprising Senna alexandrina extract |
-
1993
- 1993-12-15 JP JP5343025A patent/JPH07165527A/en not_active Withdrawn
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0952814A (en) * | 1995-08-09 | 1997-02-25 | Sunstar Inc | Skin cosmetic composition |
| FR2813195A1 (en) * | 2000-08-29 | 2002-03-01 | Serobiologiques Lab Sa | USE OF CASSIA ALATA PLANT EXTRACTS IN CARE PRODUCTS |
| WO2002017938A1 (en) * | 2000-08-29 | 2002-03-07 | Cognis France S.A. | Use of extracts of the cassia alata plant |
| JP2004507505A (en) * | 2000-08-29 | 2004-03-11 | コグニス・フランス・ソシエテ・アノニム | Use of an extract of the plant Cassiaalata |
| JP2013121968A (en) * | 2000-08-29 | 2013-06-20 | Basf Beauty Care Solutions France Sas | Use of extract of cassia alata plant |
| US8535731B2 (en) | 2000-08-29 | 2013-09-17 | Basf Beauty Care Solutions France S.A.S. | Use of extracts of the Cassia alata plant |
| JP2002265343A (en) * | 2001-03-07 | 2002-09-18 | Ichimaru Pharcos Co Ltd | Cosmetic composition |
| JP2009215269A (en) * | 2008-03-13 | 2009-09-24 | Okinawa Pref Gov | Tyrosinase activity inhibitor and skin-lightening cosmetic containing the same |
| KR20210006151A (en) * | 2019-07-08 | 2021-01-18 | 주식회사 팜스킨 | A composition for blue light interception comprising Senna alexandrina extract |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20010306 |