JPH0656612A - Termite controller - Google Patents
Termite controllerInfo
- Publication number
- JPH0656612A JPH0656612A JP15817793A JP15817793A JPH0656612A JP H0656612 A JPH0656612 A JP H0656612A JP 15817793 A JP15817793 A JP 15817793A JP 15817793 A JP15817793 A JP 15817793A JP H0656612 A JPH0656612 A JP H0656612A
- Authority
- JP
- Japan
- Prior art keywords
- salt
- group
- substitutable
- optionally substituted
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000256602 Isoptera Species 0.000 title claims abstract description 20
- 150000003839 salts Chemical class 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000004480 active ingredient Substances 0.000 claims abstract description 10
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims abstract description 3
- 125000003373 pyrazinyl group Chemical group 0.000 claims abstract description 3
- 125000004076 pyridyl group Chemical group 0.000 claims abstract description 3
- 125000000335 thiazolyl group Chemical group 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 abstract description 6
- 239000002917 insecticide Substances 0.000 abstract description 6
- 230000000895 acaricidal effect Effects 0.000 abstract description 4
- 239000000642 acaricide Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 abstract description 2
- 229960005235 piperonyl butoxide Drugs 0.000 abstract description 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 239000004599 antimicrobial Substances 0.000 abstract 1
- -1 urea Organic Chemical class 0.000 description 14
- 239000000843 powder Substances 0.000 description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003899 bactericide agent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000005942 Triflumuron Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- MKNJWAXSYGAMGJ-UHFFFAOYSA-N (2,3,4,5,6-pentachlorophenyl) dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl MKNJWAXSYGAMGJ-UHFFFAOYSA-N 0.000 description 1
- FHNKBSDJERHDHZ-UHFFFAOYSA-N (2,4-dimethylphenyl)methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(C)C=C1C FHNKBSDJERHDHZ-UHFFFAOYSA-N 0.000 description 1
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 1
- CXNPLSGKWMLZPZ-GIFSMMMISA-N (2r,3r,6s)-3-[[(3s)-3-amino-5-[carbamimidoyl(methyl)amino]pentanoyl]amino]-6-(4-amino-2-oxopyrimidin-1-yl)-3,6-dihydro-2h-pyran-2-carboxylic acid Chemical compound O1[C@@H](C(O)=O)[C@H](NC(=O)C[C@@H](N)CCN(C)C(N)=N)C=C[C@H]1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-GIFSMMMISA-N 0.000 description 1
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 description 1
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 description 1
- FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 description 1
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- KGURSDWHGSLAPP-UHFFFAOYSA-N 4-bromo-2,6-dichlorophenol Chemical compound OC1=C(Cl)C=C(Br)C=C1Cl KGURSDWHGSLAPP-UHFFFAOYSA-N 0.000 description 1
- YHBIGBYIUMCLJS-UHFFFAOYSA-N 5-fluoro-1,3-benzothiazol-2-amine Chemical compound FC1=CC=C2SC(N)=NC2=C1 YHBIGBYIUMCLJS-UHFFFAOYSA-N 0.000 description 1
- FFISWZPYNKWIRR-UHFFFAOYSA-N 5-oxidophenazin-5-ium Chemical compound C1=CC=C2[N+]([O-])=C(C=CC=C3)C3=NC2=C1 FFISWZPYNKWIRR-UHFFFAOYSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- 239000005745 Captan Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- STUSTWKEFDQFFZ-UHFFFAOYSA-N Chlordimeform Chemical compound CN(C)C=NC1=CC=C(Cl)C=C1C STUSTWKEFDQFFZ-UHFFFAOYSA-N 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RAPBNVDSDCTNRC-UHFFFAOYSA-N Chlorobenzilate Chemical compound C=1C=C(Cl)C=CC=1C(O)(C(=O)OCC)C1=CC=C(Cl)C=C1 RAPBNVDSDCTNRC-UHFFFAOYSA-N 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- 239000005947 Dimethoate Substances 0.000 description 1
- 239000005764 Dithianon Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005958 Fenamiphos (aka phenamiphos) Substances 0.000 description 1
- 239000005657 Fenpyroximate Substances 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 239000005786 Flutolanil Substances 0.000 description 1
- 239000005790 Fosetyl Substances 0.000 description 1
- FSYXMFXBRJFYBS-UHFFFAOYSA-N Furamethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(CC#C)O1 FSYXMFXBRJFYBS-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 239000005867 Iprodione Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 239000005807 Metalaxyl Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- XJLXINKUBYWONI-NNYOXOHSSA-N NADP zwitterion Chemical compound NC(=O)C1=CC=C[N+]([C@H]2[C@@H]([C@H](O)[C@@H](COP([O-])(=O)OP(O)(=O)OC[C@@H]3[C@H]([C@@H](OP(O)(O)=O)[C@@H](O3)N3C4=NC=NC(N)=C4N=C3)O)O2)O)=C1 XJLXINKUBYWONI-NNYOXOHSSA-N 0.000 description 1
- JAYZFNIOOYPIAH-UHFFFAOYSA-N Oxydeprofos Chemical compound CCS(=O)CC(C)SP(=O)(OC)OC JAYZFNIOOYPIAH-UHFFFAOYSA-N 0.000 description 1
- 239000005921 Phosmet Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000005923 Pirimicarb Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- 239000005823 Propineb Substances 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 239000005663 Pyridaben Substances 0.000 description 1
- 239000005927 Pyriproxyfen Substances 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- PNAAEIYEUKNTMO-UHFFFAOYSA-N S-Seven Chemical compound C=1C=CC=CC=1P(=S)(OCC)OC1=CC=C(Cl)C=C1Cl PNAAEIYEUKNTMO-UHFFFAOYSA-N 0.000 description 1
- OUNSASXJZHBGAI-UHFFFAOYSA-N Salithion Chemical compound C1=CC=C2OP(OC)(=S)OCC2=C1 OUNSASXJZHBGAI-UHFFFAOYSA-N 0.000 description 1
- 101000984731 Salvia officinalis (+)-bornyl diphosphate synthase, chloroplastic Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005938 Teflubenzuron Substances 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000005858 Triflumizole Substances 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 229930195482 Validamycin Natural products 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- BZMIHNKNQJJVRO-LVZFUZTISA-N [(e)-c-(3-chloro-2,6-dimethoxyphenyl)-n-ethoxycarbonimidoyl] benzoate Chemical compound COC=1C=CC(Cl)=C(OC)C=1C(=N/OCC)\OC(=O)C1=CC=CC=C1 BZMIHNKNQJJVRO-LVZFUZTISA-N 0.000 description 1
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 description 1
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- QGLZXHRNAYXIBU-WEVVVXLNSA-N aldicarb Chemical compound CNC(=O)O\N=C\C(C)(C)SC QGLZXHRNAYXIBU-WEVVVXLNSA-N 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229960002587 amitraz Drugs 0.000 description 1
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- FYZBOYWSHKHDMT-UHFFFAOYSA-N benfuracarb Chemical compound CCOC(=O)CCN(C(C)C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 FYZBOYWSHKHDMT-UHFFFAOYSA-N 0.000 description 1
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- CXNPLSGKWMLZPZ-UHFFFAOYSA-N blasticidin-S Natural products O1C(C(O)=O)C(NC(=O)CC(N)CCN(C)C(N)=N)C=CC1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-UHFFFAOYSA-N 0.000 description 1
- FOANIXZHAMJWOI-UHFFFAOYSA-N bromopropylate Chemical compound C=1C=C(Br)C=CC=1C(O)(C(=O)OC(C)C)C1=CC=C(Br)C=C1 FOANIXZHAMJWOI-UHFFFAOYSA-N 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
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- SCKHCCSZFPSHGR-UHFFFAOYSA-N cyanophos Chemical compound COP(=S)(OC)OC1=CC=C(C#N)C=C1 SCKHCCSZFPSHGR-UHFFFAOYSA-N 0.000 description 1
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- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- WCMMILVIRZAPLE-UHFFFAOYSA-M cyhexatin Chemical compound C1CCCCC1[Sn](C1CCCCC1)(O)C1CCCCC1 WCMMILVIRZAPLE-UHFFFAOYSA-M 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
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- 238000007865 diluting Methods 0.000 description 1
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- 235000013312 flour Nutrition 0.000 description 1
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- 229910052602 gypsum Inorganic materials 0.000 description 1
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- 239000007924 injection Substances 0.000 description 1
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
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- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
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- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000008297 liquid dosage form Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- BCTQJXQXJVLSIG-UHFFFAOYSA-N mepronil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C)=C1 BCTQJXQXJVLSIG-UHFFFAOYSA-N 0.000 description 1
- MEBQXILRKZHVCX-UHFFFAOYSA-N methidathion Chemical compound COC1=NN(CSP(=S)(OC)OC)C(=O)S1 MEBQXILRKZHVCX-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- XYFMGGWVGACNEC-UHFFFAOYSA-N n-carbamoyl-n-phenylbenzamide Chemical compound C=1C=CC=CC=1N(C(=O)N)C(=O)C1=CC=CC=C1 XYFMGGWVGACNEC-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 description 1
- RLBIQVVOMOPOHC-UHFFFAOYSA-N parathion-methyl Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1 RLBIQVVOMOPOHC-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- IOUNQDKNJZEDEP-UHFFFAOYSA-N phosalone Chemical compound C1=C(Cl)C=C2OC(=O)N(CSP(=S)(OCC)OCC)C2=C1 IOUNQDKNJZEDEP-UHFFFAOYSA-N 0.000 description 1
- LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- QHGVXILFMXYDRS-UHFFFAOYSA-N pyraclofos Chemical compound C1=C(OP(=O)(OCC)SCCC)C=NN1C1=CC=C(Cl)C=C1 QHGVXILFMXYDRS-UHFFFAOYSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
- CXJSOEPQXUCJSA-UHFFFAOYSA-N pyridaphenthion Chemical compound N1=C(OP(=S)(OCC)OCC)C=CC(=O)N1C1=CC=CC=C1 CXJSOEPQXUCJSA-UHFFFAOYSA-N 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- XRJLAOUDSILTFT-UHFFFAOYSA-N pyroquilon Chemical compound O=C1CCC2=CC=CC3=C2N1CC3 XRJLAOUDSILTFT-UHFFFAOYSA-N 0.000 description 1
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- VMSRVIHUFHQIAL-UHFFFAOYSA-M sodium;n,n-dimethylcarbamodithioate Chemical compound [Na+].CN(C)C([S-])=S VMSRVIHUFHQIAL-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は後記式〔Ｉ〕のアミン誘
導体又はその塩を有効成分として含有する白蟻防除剤に
関する。FIELD OF THE INVENTION The present invention relates to a termite control agent containing an amine derivative of the formula [I] or a salt thereof as an active ingredient.
【０００２】[0002]
【従来の技術】白蟻の防除に、従来より、有機塩素系薬
剤、有機リン剤、カーバメート系薬剤等多数の白蟻防除
剤が使用されているが、その効力が不十分であったり、
毒性が強かったりすることから、必ずしも満足すべき防
除剤とは言い難いものが少なくない。従って、かかる欠
点の少ない安全に使用できる薬剤の開発が要望されてい
る。2. Description of the Related Art Conventionally, many termite control agents such as organic chlorine agents, organic phosphorus agents, carbamate agents have been used for controlling termites, but their efficacy is insufficient,
Since it is highly toxic, it is difficult to say that it is a satisfactory control agent. Therefore, there is a demand for the development of a drug that can be used safely with few such drawbacks.
【０００３】[0003]
【発明が解決しようとする課題】本発明の目的は、効果
が確実で安全に使用できる白蟻防除剤を提供することで
ある。SUMMARY OF THE INVENTION An object of the present invention is to provide a termite control agent which has a reliable effect and can be used safely.
【０００４】[0004]
【課題を解決するための手段】本発明は、一般式〔Ｉ〕The present invention has the general formula [I]
【化２】 ｛式中、Ｒ1 は、置換されてもよいピリジル基、置換さ
れてもよいピラジニル基又は置換されてもよいチアゾリ
ル基を、Ｒ2 は水素原子、置換されてもよいアルキル
基、シクロアルキル基、又はアルコキシ基を、Ｒ3 は水
素原子、置換されてもよいアルキル基を、Ｒ4 はシアノ
基又はニトロ基を示す。｝で表わされる化合物又はその
塩の少なくとも１種を有効成分として含有することを特
徴とする白蟻防除剤である。[Chemical 2] {In the formula, R 1 is an optionally substituted pyridyl group, an optionally substituted pyrazinyl group or an optionally substituted thiazolyl group, and R 2 is a hydrogen atom, an optionally substituted alkyl group or a cycloalkyl group. , Or an alkoxy group, R 3 represents a hydrogen atom or an optionally substituted alkyl group, and R 4 represents a cyano group or a nitro group. } It is a termite control agent containing at least 1 sort (s) of the compound represented by these or its salt as an active ingredient.
【０００５】本発明に係わる一般式〔Ｉ〕で表されるア
ミン誘導体の例として第１表に示す化合物が挙げられ
る。一般式〔Ｉ〕で表されるアミン誘導体又はその塩の
製造方法及びそれらの殺虫剤としての使用は、ＷＯ９１
／０４９６５に記載されている。Examples of the amine derivative represented by the general formula [I] according to the present invention include the compounds shown in Table 1. A method for producing an amine derivative represented by the general formula [I] or a salt thereof and use thereof as an insecticide is disclosed in WO 91
/ 04965.
【０００６】[0006]
【表１０１】 [Table 101]
【０００７】[0007]
【表１０２】 [Table 102]
【０００８】一般式〔Ｉ〕で表されるアミン誘導体又は
その塩を施用することにより、等翅目虫のシロアリ、例
えばイエシロアリ、ヤマトシロアリ、ダイコクシロア
リ、アメリカカンザイシロアリ、タイワンシロアリ等を
防除することができる。By controlling the amine derivative represented by the general formula [I] or a salt thereof, it is possible to control termites of the order Lepidoptera, such as house termites, mountain termites, white termites, dwarf termites, and American termites. You can
【０００９】本発明の白蟻防除剤は、一般式〔Ｉ〕で表
わされる化合物又はその塩を有効成分として含有するも
のであり、有効成分化合物の純品のままでも使用できる
が、通常、一般の薬剤のとり得る形態、即ち、水和剤、
水溶剤、粉剤、乳剤、液剤、粒剤、フロアブル油剤、ペ
ースト、エアゾール剤、燻蒸剤、燻煙剤等の形態で使用
される。添加剤及び担体としては、固型剤を目的とする
場合は、大豆粉、小麦粉等の植物性粉末、珪藻土、燐灰
石、石膏、タルク、ベントナイト、クレイ等の鉱物性微
粉末、安息香酸ソーダ、尿素、芒硝等の有機および無機
化合物が使用される。液体の剤型を目的とする場合は、
植物油、鉱物油、ケロシン、キシレンおよびソルベント
ナフサ等の石油留分、シクロヘキサン、シクロヘキサノ
ン、ジメチルホルムアミド、ジメチルスルホキシド、ト
リクロルエチレン、メチルイソブチルケトン、水等を溶
剤として使用する。これらの製剤において、均一なかつ
安定な形態をとるために必要ならば界面活性剤を添加す
ることもできる。このようにして得られた水和剤、乳
剤、水溶液、フロアブル剤は水で所定の濃度に希釈して
懸濁液、溶液あるいは乳濁液として、粉剤、粒剤はその
まま、散布する方法で使用される。The termite control agent of the present invention contains a compound represented by the general formula [I] or a salt thereof as an active ingredient, and a pure product of the active ingredient compound can be used, but it is usually used in general. A possible form of the drug, namely a wettable powder,
It is used in the form of water solvent, powder, emulsion, liquid, granule, flowable oil, paste, aerosol, fumigant, smoke agent and the like. As the additives and carriers, when the purpose is a solidifying agent, soybean powder, vegetable powder such as wheat flour, diatomaceous earth, apatite, gypsum, talc, bentonite, mineral fine powder such as clay, sodium benzoate, urea Organic and inorganic compounds such as Glauber's salt are used. For the purpose of liquid dosage form,
As a solvent, vegetable oil, mineral oil, petroleum fraction such as kerosene, xylene and solvent naphtha, cyclohexane, cyclohexanone, dimethylformamide, dimethylsulfoxide, trichloroethylene, methyl isobutyl ketone, water and the like are used. Surfactants can also be added to these formulations if necessary to achieve a uniform and stable form. The wettable powder, emulsion, aqueous solution, and flowable agent thus obtained are diluted with water to a predetermined concentration and used as a suspension, solution, or emulsion, and powders and granules are used as they are for spraying. To be done.
【００１０】製剤中の有効成分の濃度および製剤の施用
量は、剤型、処理方法、白蟻の種類などにより選定すれ
ばよい。製剤中の有効成分である一般式〔Ｉ〕で表され
る化合物又はその塩の含有率は、通常、０．１〜４０重
量％であり、好ましくは１〜３０重量％である。本発明
の白蟻防除剤は、有効成分そのもの、または、その製剤
を、例えば白蟻発生部位や巣、土台、柱、などの建築部
材、建築物、その周辺土壌、コンクリートブロック、床
スラブ、電線または各種ケーブルの被覆物などに対して
塗布、吹き付け、散布、浸漬、加圧注入、練合、混合等
を行なうことにより施用する。The concentration of the active ingredient in the preparation and the application rate of the preparation may be selected depending on the dosage form, treatment method, kind of termite and the like. The content of the compound represented by the general formula [I] or a salt thereof, which is the active ingredient in the preparation, is usually 0.1 to 40% by weight, preferably 1 to 30% by weight. The termite control agent of the present invention is the active ingredient itself, or a formulation thereof, for example, a building member such as termite generation site or nest, base, pillar, building, surrounding soil, concrete block, floor slab, electric wire or various types. It is applied by coating, spraying, spraying, dipping, pressure injection, kneading, mixing, etc. on the coating of the cable.
【００１１】なお、一般式〔Ｉ〕で表される化合物又は
その塩は単独でも十分有効であることはいうまでもない
が、Ｓ−４２１、ピペロニルブトキサイド等の共力剤、
各種の殺虫剤、殺ダニ剤（殺菌剤）及び防腐剤と混合し
て使用することもできる。本発明化合物と混合して使用
できる殺虫剤、殺ダニ剤（殺菌剤）及び防腐剤の代表例
を以下に示す。Needless to say, the compound represented by the general formula [I] or a salt thereof is sufficiently effective alone, but a synergist such as S-421, piperonyl butoxide,
It can also be used as a mixture with various insecticides, acaricides (bactericides) and preservatives. Representative examples of insecticides, acaricides (bactericides) and preservatives that can be used by mixing with the compound of the present invention are shown below.
【００１２】有機燐及びカーバメイト系殺虫剤：フェン
チオン、フェニトロチオン、ダイアジノン、クロルピリ
ホス、ＥＳＰ、バミドチオン、フェントエート、ジメト
エート、ホルモチオン、マラソン、トリクロルホン、チ
オメトン、ホスメット、ジクロルボス、アセフェート、
ＥＰＢＰ、メチルパラチオン、オキシジメトンメチル、
エチオン、サリチオン、シアノホス、イソキサチオン、
ピリダフェンチオン、ホサロン、メチダチオン、スルプ
ロホス、ピラクロホス、モノクロトホス、フェナミホ
ス、アルディカーブ、プロポキスル、メソミル、ＢＰＭ
Ｃ、ＭＴＭＣ、カルバリル、カルタップ、チオシクラ
ム、ベンスルタップ、カルボスルファン、ベンフラカル
ブ、ピリミカーブ、エチオフェンカルブ、フェノキシカ
ルブ、チオジカルブ、Organophosphorus and carbamate insecticides: phenthion, fenitrothion, diazinon, chlorpyrifos, ESP, bamidthione, fentoate, dimethoate, formothione, marathon, trichlorfon, thiomethone, phosmet, dichlorvos, acephate,
EPBP, methyl parathion, oxydimethone methyl,
Ethion, salithion, cyanophos, isoxathion,
Pyridafenthion, phosalone, methidathion, sulprophos, pyraclofos, monocrotophos, fenamiphos, aldicarb, propoxur, mesomil, BPM
C, MTMC, carbaryl, cartap, thiocyclam, bensultap, carbosulfan, benfuracarb, pirimicarb, etiophencarb, phenoxycarb, thiodicarb,
【００１３】ピレスロイド系殺虫剤：ペルメトリン、ジ
ペルメトリン、デカメスリン、フェンバレレート、フェ
ンプロパトリン、ピレトリン、アレスリン、テトラメス
リン、レスメトリン、ジメスリン、プロパスリン、ビフ
ェンスリン、プロスリン、フルバリネート、シフルトリ
ン、シハロトリン、フルシトリネート、エトフェンプロ
ックス、シクロプロトリン、トラロメトリン、シラネオ
ファン、 ベンゾイルフェニルウレア系その他の殺虫剤：ジフルベ
ンズロン、クロルフルアズロン、トリフルムロン、テフ
ルベンズロン、ヘキサフルムロン、トリフルムロン、フ
ルフェノクスロン、ブプロフェジン、ピリプロキシフェ
ン、ダイアフェンチウロン、機械油、硫酸ニコチン、Ｂ
Ｔ、Pyrethroid insecticides: permethrin, dipermethrin, decamethrin, fenvalerate, fenpropatrine, pyrethrin, allethrin, tetramethrin, resmethrin, dimethrin, propasulin, bifenthrin, prothrin, fluvalinate, cyfluthrin, cyhalothrin, flucitrinate, eth Fenprox, cycloprothrin, tralomethrin, silaneophane, benzoylphenylurea and other insecticides: diflubenzuron, chlorfluazuron, triflumuron, teflubenzuron, hexaflumuron, triflumuron, flufenoxuron, buprofezin, pyriproxyfen, diafenthiu. Ron, machine oil, nicotine sulfate, B
T,
【００１４】殺ダニ剤（殺菌剤）：クロルベンジレー
ト、フェニソブロモレート、ジコホル、クロルジメホル
ム、アミトラズ、ＢＰＰＳ、ベンゾメート、ヘキシチア
ゾクス、酸化フェンブタスズ、ポリナクチン、キノメチ
オネート、ＣＰＣＢＳ、テトラジホン、アベルメクチ
ン、多硫化石灰、クロフェンテジン、フルベンツミン、
フルフェノクスロン、シヘキサチン、ピリダベン、フェ
ンピロキシメート、フェンピラド、チオファネートメチ
ル、ベノミル、チウラム、ＩＢＰ、ＥＤＤＰ、フサライ
ド、プロベナゾール、イソプロチオラン、ＴＰＮ、キャ
プタン、ポリオキシン、ブラストサイジンＳ、カスガマ
イシン、バリダマイシン、トリシクラゾール、ピロキロ
ン、フェナジンオキシド、メプロニル、フルトラニル、
ペンシクロン、イプロジオン、ヒメキサゾール、メタラ
キシル、トリフルミゾール、ジクロメジン、テクロフタ
ラム、プロピネブ、ジラム、ジチアノン、ホセチル、ト
リホリン、ビンクロゾリン、プロシミドン、オキサジキ
シル、トリアジメホン、ビテルタノール、フェナリモ
ル、グアザチン、プロパモカルブ塩酸塩、フルアジナ
ム、Acaricide (bactericidal agent): chlorbenzilate, phenisobromolate, dicofol, chlordimeform, amitraz, BPPS, benzomate, hexthiazox, fenbutatin oxide, polynactin, quinomethionate, CPCBS, tetradiphone, avermectin, lime polysulfide, chlor. Fentedine, flubenzutin,
Flufenoxuron, cyhexatin, pyridaben, fenpyroximate, fenpyrad, thiophanate methyl, benomyl, thiuram, IBP, EDDP, fusaride, probenazole, isoprothiolane, TPN, captan, polyoxin, blasticidin S, kasugamycin, validamycin, tricyclazole, pyroquilon, phenazine oxide, Mepronil, flutolanil,
Penciclone, iprodione, hymexazole, metalaxyl, triflumizole, diclomedine, teclophthalam, propineb, diram, dithianon, fosetyl, triphorine, vinclozolin, procymidone, oxadixyl, triadimefone, bitertanol, fenarimol, guazatine, propamozinam, hydrochloride, fluazacin, fluazacarb.
【００１５】防腐剤：ペンタクロルフェニルラウレー
ト、ｐ−ブロモ−２，６−ジクロルフェノール、３−ヨ
ード−２−プロピニルブチルカーバメート、３−エトキ
シカルボニルオキシ−１−ブロモ−１，２−ジヨードプ
ロペン、ベンザルコニウムクロリド、ジアルキルジメチ
ルアンモニウムクロリド、ビス（ｎ−トリブチルスズ）
オキシド、トリブチルスズテレフタレート、アフテン酸
亜鉛、キシリゲンアルミニウム塩。Preservatives: pentachlorophenyl laurate, p-bromo-2,6-dichlorophenol, 3-iodo-2-propynylbutyl carbamate, 3-ethoxycarbonyloxy-1-bromo-1,2-diiodo. Propene, benzalkonium chloride, dialkyldimethylammonium chloride, bis (n-tributyltin)
Oxide, tributyltin terephthalate, zinc aphthenate, xylogen aluminum salt.
【００１６】[0016]
【実施例】次に製剤の実施例を示すが、添加する担体、
界面活性剤等はこれらの実施例に限定されるものではな
い。 実施例１ 乳剤 一般式〔Ｉ〕で表される化合物又はその塩 １０部 アルキルフェニルポリオキシエチレン ５部 ジメチルホルムアミド ５０部 キシレン ３５部 以上を混合溶解し、使用に際し水で希釈して乳濁液とし
て散布する。[Examples] Examples of formulations are shown below.
The surfactant and the like are not limited to these examples. Example 1 Emulsion Compound represented by general formula [I] or salt thereof 10 parts Alkylphenyl polyoxyethylene 5 parts Dimethylformamide 50 parts Xylene 35 parts Mix and dissolve the above components, and dilute with water to use as an emulsion. Disperse.
【００１７】実施例２ 水和剤 一般式〔Ｉ〕で表される化合物又はその塩 ２０部 高級アルコール硫酸エステル ５部 珪藻土 ７０部 シリカ ５部 以上を混合して微粉に粉砕し、使用に際し水で希釈して
懸濁液として散布する。Example 2 Wettable powder A compound represented by the general formula [I] or a salt thereof 20 parts Higher alcohol sulfate 5 parts Diatomaceous earth 70 parts Silica 5 parts The above components are mixed and ground to a fine powder, and water is used before use. Dilute and apply as a suspension.
【００１８】実施例３ 粉剤 一般式〔Ｉ〕で表される化合物又はその塩 ５部 タルク ９４．７部 シリカ ０．３部 以上を混合粉砕し、使用に際してはそのまま散布する。Example 3 Dust Powder Compound represented by the general formula [I] or salt thereof 5 parts Talc 94.7 parts Silica 0.3 parts The above components are mixed and pulverized, and sprayed as they are before use.
【００１９】実施例４ 粒剤 一般式〔Ｉ〕で表される化合物又はその塩 ５部 クレー ７３部 ベントナイト ２０部 ジオクチルスルホサクシネートナトリウム塩 １部 リン酸ナトリウム １部 以上を造粒し、使用に際してはそのまま施用する。Example 4 Granules Compound represented by the general formula [I] or salt thereof 5 parts Clay 73 parts Bentonite 20 parts Dioctyl sulfosuccinate sodium salt 1 part Sodium phosphate 1 part The above are granulated and used. Is applied as is.
【００２０】[0020]
試験例 実施例１に示した乳剤を所定薬量になるようにアセトン
で希釈した薬液１ｍｌを直径９ｃｍのガラスシャーレ内
の口紙に滴下した。風乾後、イエシロアリ職蟻１０頭を
接種し、蓋をして、温度２５℃の恒温室内に置いた。２
日後に殺虫率を調べ、その結果を第２表に示した。Test Example 1 ml of a chemical solution obtained by diluting the emulsion shown in Example 1 with acetone to a predetermined dose was dropped on a mouthpiece in a glass petri dish having a diameter of 9 cm. After air-drying, 10 termite worker ants were inoculated, covered, and placed in a temperature-controlled room at a temperature of 25 ° C. Two
The insecticidal rate was examined after a day, and the results are shown in Table 2.
【表２】 [Table 2]
Claims (1)
れてもよいピラジニル基又は置換されてもよいチアゾリ
ル基を、Ｒ2 は水素原子、置換されてもよいアルキル
基、シクロアルキル基、又はアルコキシ基を、Ｒ3 は水
素原子、置換されてもよいアルキル基を、Ｒ4 はシアノ
基又はニトロ基を示す。｝で表わされる化合物又はその
塩の少なくとも１種を有効成分として含有することを特
徴とする白蟻防除剤。1. A compound represented by the general formula [I]: {In the formula, R 1 is an optionally substituted pyridyl group, an optionally substituted pyrazinyl group or an optionally substituted thiazolyl group, and R 2 is a hydrogen atom, an optionally substituted alkyl group or a cycloalkyl group. , Or an alkoxy group, R 3 represents a hydrogen atom or an optionally substituted alkyl group, and R 4 represents a cyano group or a nitro group. } The termite control agent containing at least 1 sort (s) of the compound represented by these or its salt as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15817793A JPH0656612A (en) | 1992-06-11 | 1993-06-04 | Termite controller |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17739592 | 1992-06-11 | ||
| JP4-177395 | 1992-06-11 | ||
| JP15817793A JPH0656612A (en) | 1992-06-11 | 1993-06-04 | Termite controller |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0656612A true JPH0656612A (en) | 1994-03-01 |
Family
ID=26485385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15817793A Pending JPH0656612A (en) | 1992-06-11 | 1993-06-04 | Termite controller |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0656612A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008520571A (en) * | 2004-11-16 | 2008-06-19 | エフ エム シー コーポレーション | Termite group control method |
| JP2009543819A (en) * | 2006-07-20 | 2009-12-10 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | N'-cyano-N-halogenated alkylimidoamide derivatives |
-
1993
- 1993-06-04 JP JP15817793A patent/JPH0656612A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008520571A (en) * | 2004-11-16 | 2008-06-19 | エフ エム シー コーポレーション | Termite group control method |
| JP2009543819A (en) * | 2006-07-20 | 2009-12-10 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | N'-cyano-N-halogenated alkylimidoamide derivatives |
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