JPH06171003A - Reinforcing material for urethane from molding having unpleasant sound preventing capacity, production thereof and product - Google Patents
Reinforcing material for urethane from molding having unpleasant sound preventing capacity, production thereof and productInfo
- Publication number
- JPH06171003A JPH06171003A JP4352487A JP35248792A JPH06171003A JP H06171003 A JPH06171003 A JP H06171003A JP 4352487 A JP4352487 A JP 4352487A JP 35248792 A JP35248792 A JP 35248792A JP H06171003 A JPH06171003 A JP H06171003A
- Authority
- JP
- Japan
- Prior art keywords
- urethane
- layer
- nonwoven fabric
- reinforcing
- porosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、車両等シートなどに用
いられるウレタン発泡成形用補強材と製造方法に関する
ものであり、特に、車両等のシート材のポリウレタンフ
ォームとバネ材間の摩擦により発生する擦過音発生を防
止し静寂性に優れ、補強効果にも優れたウレタン発泡成
形用補強材とその製造方法及びそれを用いて得る車両用
シートに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a urethane foam molding reinforcing material used for a vehicle seat and the like, and a method for manufacturing the same. In particular, it is generated by friction between a polyurethane foam of a seat material of a vehicle and a spring material. TECHNICAL FIELD The present invention relates to a urethane foam molding reinforcing material which prevents generation of rubbing noise, is excellent in quietness, and is also excellent in reinforcing effect, a method for producing the same, and a vehicle seat obtained by using the same.
【0002】[0002]
【従来の技術】車両用等のシート材は、軟質ポリウレタ
ンフォーム型内発泡成形品が主流として用いられてい
る。2. Description of the Related Art As a sheet material for vehicles and the like, a soft polyurethane foam in-mold foam molded article is mainly used.
【0003】このようなシート材が良好なクッション性
を実現するためには、一般に多く用いられる図3に示す
ようなシート材構造において、人体に接する最上層(A
層)は柔らかいものでなければならないが、次に存在す
る層(B)は適度の曲げ剛性又は張力(高引張り弾性
率)をもった材料であるべきで、B層を受け衝撃的な力
を吸収しバネ感覚を生ずるスプリング(C層)のクッシ
ョン作用を、均等に分散し、B層を平らに保ち支えて上
下動するような構造と作用が必要である。In order for such a sheet material to realize a good cushioning property, in the sheet material structure shown in FIG. 3, which is generally used in many cases, the uppermost layer (A) in contact with the human body is used.
The layer) must be soft, but the next layer (B) should be a material with appropriate flexural rigidity or tension (high tensile modulus) so that it will receive the impact force when receiving layer B. The cushioning action of the spring (C layer) that absorbs and produces a spring sensation is required to have a structure and action that evenly disperse and keep the B layer flat and support it to move up and down.
【0004】また、このような軟質ポリウレタンフォー
ム型内発泡成形品の耐久性を確保する面からも、スプリ
ング(コイル状バネ)が接しポリウレタンフォームが摩
擦され、局部的応力を受け損傷することを避けるため、
従来次のようなポリウレタンフォームのバネ材接触面側
に補強布を入れ、良好なクッション性の確保をはかると
ともに耐久性をも確保して来た。Also, from the viewpoint of ensuring the durability of such a foamed product in a flexible polyurethane foam mold, it is avoided that the polyurethane foam is rubbed by the contact of the spring (coil spring) and locally damaged. For,
Conventionally, a reinforcing cloth has been put on the surface of the polyurethane foam contacting the spring material as described below to ensure good cushioning properties and durability.
【0005】即ち、その代表的事例を掲げると、 補強材としてスラブウレタンと寒冷紗を用い、発泡成
形金型面に接するようにスラブウレタンを設置し、その
内側に寒冷紗を設置し、ウレタン液を注入し、加熱加圧
し発泡させて補強層が挿入された軟質ポリウレタンフオ
ーム型内発泡成形品を製造する方法が多く用いられ主役
の座を占めていた。That is, to give a typical example thereof, slab urethane and frosted gauze are used as a reinforcing material, slab urethane is installed so as to be in contact with the surface of the foam molding die, and frosted gauze is installed on the inside of the slab urethane and the urethane liquid is injected. However, a method of producing a soft polyurethane foam in-mold foam molded article in which a reinforcing layer is inserted by heating and pressurizing and foaming is often used, and it occupies the leading role.
【0006】この方法におけるスラブウレタンの役割
は、得られるクッション材への剛性の付与とともに、ウ
レタン流入による発泡金型空気抜き孔の閉塞防止にあ
り、寒冷沙の役割は、発泡し膨張してくるポリウレタン
を容易に透過し、寒冷紗が容易にポリウレタンフォーム
内に包埋一体化され、引張り弾性率を改善し優れた補強
層を形成することにある。The role of the slab urethane in this method is to impart rigidity to the obtained cushioning material and to prevent the foam die air vent hole from being blocked by the inflow of urethane, and the role of chills is to expand and expand the polyurethane. It is to form a superior reinforcing layer by improving the tensile elastic modulus by embedding and integrating the gauze into the polyurethane foam.
【0007】しかしながら、スラブウレタンによる剛性
改善効果が不充分であるとともに、何よりも工数が多く
作業が煩雑であること、及び補強布である寒冷紗が成形
品のなす3次曲面形状に沿い難いという難点があった。However, the rigidity improving effect of the slab urethane is insufficient, and above all, the number of man-hours is large and the work is complicated, and it is difficult for the kansai as a reinforcing cloth to conform to the cubic curved surface shape formed by the molded product. was there.
【0008】次いで、前記寒冷紗の成形形状に沿い難
いという難点解消とコストダウンを目的とし開発され主
役の座に就いたのは不織布(反毛フェルト)である。[0008] Next, a non-woven fabric (removed felt) has been developed and played a leading role for the purpose of solving the problem that it is difficult to conform to the shape of the above-mentioned cheesecloth and reducing the cost.
【0009】この不織布が補強布としての要求特性を満
たすためには、発泡し膨張してくるウレタン液の適度の
透過性を有することが必要で、このためには適度のポア
ーサイズの空隙孔と空隙率(見掛け嵩密度)を有するこ
とが必要であり、又充分な補強効果と剛性を付与するた
めにも、発泡し膨張してくるポリウレタン内に不織布が
包埋されポリウレタンで不織布交点が再結合され、不織
布組織内にポリウレタンフォームが充填され適度な剛性
と高い引張り弾性率を発揮する適度の見掛け嵩密度(空
隙率)が必要であり、更に、成形品曲面形状への順応性
確保のため不織布構成繊維交点間の接着を比較的緩やか
に行ない組織変形の自由度を持たしめることが必要であ
った。In order for this non-woven fabric to satisfy the required properties as a reinforcing fabric, it is necessary that it has a suitable permeability for the urethane liquid that expands and expands. For this purpose, it has pores and pores of a suitable pore size. It is necessary to have a ratio (apparent bulk density), and in order to provide sufficient reinforcing effect and rigidity, the non-woven fabric is embedded in the polyurethane that expands and expands, and the non-woven fabric intersection points are re-bonded with the polyurethane. , Non-woven fabric must be filled with polyurethane foam to have appropriate rigidity and appropriate apparent bulk density (porosity) to exert a high tensile elastic modulus. Furthermore, non-woven fabric structure is required to ensure conformability to the curved surface shape of molded products. It was necessary to make the adhesion between the fiber intersections relatively gentle so as to have the degree of freedom of tissue deformation.
【0010】このような観点から適切な嵩密度、空隙率
を有する不織布が試行錯誤的に検討され開発され使用さ
れてきた。From such a viewpoint, nonwoven fabrics having appropriate bulk density and porosity have been studied and developed by trial and error and used.
【0011】これらの補強用不織布における嵩密度、空
隙率設定の基準は、発泡し膨張してくるポリウレタンが
不織布前面にわたり透過し、不織布表面をポリウレタン
皮膜が覆えるような比較的高い透過性を有するように選
定し、透過性が高すぎ成形金型の空気抜き孔にまでポリ
ウレタンが流入することのないレベルに抑制することに
留意して選定されている。The criteria for setting the bulk density and porosity of these reinforcing non-woven fabrics are that the polyurethane that expands and expands permeates over the front face of the non-woven fabric, and that the non-woven fabric surface can be covered with a polyurethane film. It was selected in consideration of the fact that the permeability is too high and the polyurethane is suppressed to a level where it does not flow into the air vent hole of the molding die.
【0012】以上が軟質ポリウレタンフォーム型内発泡
成形用補強布の主流である。The above is the mainstream of the reinforcing fabric for in-mold expansion molding of flexible polyurethane foam.
【0013】しかしながら、より緩やかな管理下にお
いて安定してポリウレタンの必要且つ充分な透過性を確
保し、成形金型空気抜き孔へのポリウレタン流入を完全
に防止し、高収率、高生産性で生産を行なえ、ウレタン
樹脂の含浸、透過性が良く、剛性アップと補強に寄与
し、ウレタンフォームと補強布間の一体化能の高い補強
布を得るため、嵩密度の低い補強用不織布層と、膨張し
てくるポリウレタンの金型空気抜き孔への流入を遮断す
るに、充分な比較的高い嵩密度を有する不織布層を遮断
層として設けて、積層一体化した補強用不織布が開発さ
れた(実公昭62−26193号公報)。However, under more gradual control, the necessary and sufficient permeability of polyurethane is stably secured, and the polyurethane is completely prevented from flowing into the air vent hole of the molding die, thereby producing with high yield and high productivity. In order to obtain a reinforcing cloth that is highly impregnated with urethane resin, has good permeability, contributes to increased rigidity and reinforcement, and has a high ability to integrate urethane foam and reinforcing cloth, a non-woven fabric layer for reinforcement with low bulk density and expansion A non-woven fabric for reinforcement was developed in which a non-woven fabric layer having a relatively high bulk density was provided as a shut-off layer to block the incoming polyurethane from flowing into the mold air vent hole. No. 26193).
【0014】更に、補強効果とポリウレタン流入によ
る空気抜き孔閉鎖防止効果を強化するため、高目付不織
布を補強用基布として用い、高い補強効果と、高目付け
化によるポリウレタンの空気抜き孔への流入を遮断、防
止する方法、更には、その高目付け不織布の片面をエン
ボス加工等により高密度化し、実公昭62−26193
号公報に開示されているような遮断層を積層せずに設
け、ポリウレタンの空気抜き孔への流入防止をより確実
にして用いる方法(特開平2−258332号公報)等
も発明され開発されている。Further, in order to reinforce the reinforcing effect and the effect of preventing the air vent holes from closing due to the inflow of polyurethane, a high basis weight non-woven fabric is used as a reinforcing base fabric to block the high reinforcing effect and the flow of polyurethane into the air vent holes due to the higher basis weight. In order to prevent this, one side of the high-density fabric is densified by embossing, etc.
The method disclosed in Japanese Patent Laid-Open No. 2-258332 is also invented and developed, in which the barrier layer is provided without being laminated and the polyurethane is more reliably prevented from flowing into the air vent hole. .
【0015】[0015]
【発明が解決しようとする課題】最近の高級品指向の高
揚に伴い、車両用シートクッション材に要求される機能
も、優れたクッション機能を満足するのみでは不充分と
なり、従来技術で達成される機能に加え静粛性等の環境
機能充足の要求をも満足することが必要となり、軟質ポ
リウレタンフォーム発泡成型品とバネ材間の摩擦による
擦過音や屈曲、屈折音などの異音発生抑制が強く望まれ
るに至った。With the recent trend toward high-end products, the functions required for a vehicle seat cushion material are not sufficient if only satisfying the excellent cushion function, which is achieved by the prior art. In addition to the functions, it is necessary to satisfy the requirements for satisfying environmental functions such as quietness, and it is strongly desired to suppress the generation of abnormal noise such as rubbing noise, bending, and refraction noise due to the friction between the flexible polyurethane foam foam molding and the spring material. It came to be.
【0016】しかしながら、先行技術により得られる、
前記,項に示した方法により現在主流を占め多量に
生産される軟質ポリウレタンフォーム型内発泡成型品
は、バネ材と接する面は、補強布を透過したポリウレタ
ンの皮膜で覆われており、このポリウレタンスキン層が
補強布と相俟って補強効果を発揮し、それなりに商品機
能を満足しているのではあるが、このポリウレタンスキ
ン層とバネ材との間の摩擦による擦過音発生は避けるべ
くもないのである。However, obtained by the prior art,
The flexible polyurethane foam in-mold foam moldings, which currently occupy the mainstream and are produced in large quantities by the method described in the above item, have a surface in contact with the spring material covered with a polyurethane film that penetrates a reinforcing cloth. Although the skin layer exerts a reinforcing effect in combination with the reinforcing cloth and satisfies the product function as it is, it is necessary to avoid generation of scratching noise due to friction between the polyurethane skin layer and the spring material. There is no.
【0017】更に、実公昭62−26193号公報によ
り得られる改良商品も、二層の不織布を一体化しただけ
ではウレタン遮断性を充分に満足できず、成形後コイル
バネ等との接触により異音を発生するという問題があ
る。また、特開平2−258332号公報によるもの
も、(1)目付110ないし800g/m2 、繊維径1
ないし16dの高目付不織布からなる発泡成形用補強材
基布、(2)(1)の一方の面側に圧着層を有する発泡
成形用補強材基布が提案されているが、(1)の構造で
は適度のウレタン含浸性と高いウレタン遮断性を満足さ
せるには基布の目付を高くする必要があり、結果として
成形品の重量増加となるという問題がある。(2)の構
造では圧着層を有することにより、ウレタン遮断性にお
いては(1)と比較した場合、同目付のもとでは優位に
あるが、片面圧着層のみで高いウレタン遮断性を満足す
るには(1)と同様に基布の目付を高くする必要があ
り、結果として成形品の重量増加になるという問題があ
る。更に、流出しようとするポリウレタンを遮断する高
密度の不織布層が、最外層に存在しバネ材と接するた
め、紙状物を屈曲する際に発生する如きパリパリという
(屈曲・屈折音)異音発生が避け難いのである。Furthermore, the improved product obtained from Japanese Utility Model Publication No. 62-26193 cannot sufficiently satisfy the urethane barrier property only by integrating two layers of non-woven fabric, and abnormal noise is caused by contact with a coil spring after molding. There is a problem that it occurs. Further, the one disclosed in JP-A-2-258332 (1) has a basis weight of 110 to 800 g / m 2 , a fiber diameter of 1
Nos. 16 to 16d, a foam-forming reinforcing material base cloth composed of a high-density nonwoven fabric, (2) a foam-forming reinforcing material base cloth having a pressure-bonding layer on one surface side of (1) have been proposed. In terms of the structure, it is necessary to increase the basis weight of the base fabric in order to satisfy the appropriate urethane impregnation property and high urethane barrier property, and as a result, there is a problem that the weight of the molded product increases. Since the structure of (2) has a pressure-bonding layer, the urethane-blocking property is superior to that of (1) under the same basis weight, but only one-sided pressure-bonding layer can satisfy the high urethane-blocking property. As in (1), it is necessary to increase the basis weight of the base fabric, resulting in a problem that the weight of the molded product increases. In addition, the high-density non-woven fabric layer that blocks the polyurethane that is about to flow out is in the outermost layer and is in contact with the spring material, which causes a crispy (bending / refraction) abnormal noise that occurs when the paper-like object is bent. Is unavoidable.
【0018】本発明は、前記のような問題点、即ち、ウ
レタン遮断性不足、異音発生及びウレタン遮断性を上げ
ると基布の目付も増加するという問題点を解決するため
に、ウレタン発泡成形、特に、異音発生のためウレタン
遮断性を強く要求される車両用シート等のウレタン発泡
成形に際し、ウレタン遮断性と異音防止及び成形性を満
足し、且つ成形後の強固なウレタンと基布との一体性を
付与し、ウレタンの補強効果の大きい車両用シート等の
ウレタン発泡成形用補強及び異音防止基布とその製造方
法、それを用いた高性能の成形性ポリウレタンシート材
を提供せんとするものである。In order to solve the above-mentioned problems, that is, the problems that the urethane barrier property is insufficient, the abnormal noise is generated, and the urethane barrier property is increased, the basis weight of the base fabric is also increased. In particular, in urethane foam molding of vehicle seats, etc., where urethane blocking is strongly required due to the generation of abnormal noise, urethane blocking performance and noise prevention and moldability are satisfied, and a strong urethane and base fabric after molding We do not provide reinforcement for urethane foam molding such as vehicle seats that have a great effect of reinforcing urethane and noise-preventing base fabric, its manufacturing method, and high-performance moldable polyurethane sheet material using the same. It is what
【0019】[0019]
【課題を解決するための手段】異音発生を抑制し優秀な
補強効果と優れた加工性を付与するために、軟質ポリウ
レタンフォーム型内発泡成型品補強材(不織布)は、図
1に示す空隙率の異なる不織布の三層積層構造体である
ことが必要である。[Means for Solving the Problems] In order to suppress the generation of abnormal noise, and to impart an excellent reinforcing effect and excellent workability, a flexible polyurethane foam in-mold foam molded article reinforcing material (nonwoven fabric) has voids shown in FIG. It is necessary to have a three-layer laminated structure of nonwoven fabrics having different rates.
【0020】図1において、1は、目付30ないし20
0g/m2 、空隙率90ないし94%の嵩高な不織布層
で、強固な基材とウレタンとの一体性を得るために充分
な目付と層内に適当な空隙、そしてウレタンと接する面
に適度な毛羽立ちを有する不織布である。2は、目付2
0ないし100g/m2 、空隙率87ないし91%の緻
密な不織布層で、良好なウレタン遮断性を有する不織布
である。3の層は、1の層と同様な不織布で2の層とと
もにウレタン遮断性に寄与すると同時にウレタン層とコ
イルバネ等との接触による異音発生を防止する働きがあ
る。そしてポリウレタンフォームとの接合強化層で、4
は、この三層が積層一体化された本発明の発泡成形品補
強材である。In FIG. 1, 1 is a basis weight 30 to 20.
A bulky non-woven fabric layer with 0 g / m 2 and a porosity of 90 to 94%, sufficient basis weight to obtain the integrity of the strong base material and urethane, suitable voids in the layer, and moderate on the surface in contact with urethane. It is a non-woven fabric with a smooth fluff. 2 is basis weight 2
The nonwoven fabric is a dense nonwoven fabric layer having 0 to 100 g / m 2 and a porosity of 87 to 91% and having a good urethane barrier property. The third layer is a non-woven fabric similar to the first layer and contributes to the urethane barrier property together with the second layer, and at the same time, has a function of preventing the generation of abnormal noise due to the contact between the urethane layer and the coil spring or the like. And with a layer to strengthen the bond with polyurethane foam, 4
Is the foam-molded product reinforcing material of the present invention in which these three layers are laminated and integrated.
【0021】図2は、この補強基布を用いて製造された
軟質ポリウレタンフォーム型内発泡成形品の断面の一部
を示す。FIG. 2 shows a part of a cross section of a flexible polyurethane foam in-mold foam molded article manufactured by using this reinforcing base cloth.
【0022】図2において、1は異音発生防止用の嵩高
な不織布層、2は発泡成型金型内で発泡し浸透してきた
ポリウレタンにより充填されたポリウレタンを含有する
緻密な補強用不織布層であり、5はポリウレタンフォー
ム層である。In FIG. 2, 1 is a bulky non-woven fabric layer for preventing abnormal noise, and 2 is a dense reinforcing non-woven fabric layer containing polyurethane filled with polyurethane that has been foamed and permeated in the foaming mold. 5 is a polyurethane foam layer.
【0023】このような、異音発生が抑制された優秀な
補強効果と加工性に優れた軟質ポリウレタンフォーム型
内発泡成形用補強材(不織布)に対し要求される機能
は、The functions required for such a reinforcing material (nonwoven fabric) for in-mold expansion molding of a flexible polyurethane foam which has an excellent reinforcing effect in which generation of abnormal noise is suppressed and is excellent in workability are as follows.
【0024】型内発泡成形時に、発泡し膨張してくる
ウレタン樹脂が均等に含浸、充填できて、ウレタンフォ
ームと補強材間が強固に一体化できるだけのウレタン樹
脂透過性を有し、それ以上の過度の透過性を有しないこ
と。During the in-mold foam molding, the urethane resin that expands and expands can be evenly impregnated and filled, and the urethane foam and the reinforcing material have a urethane resin permeability sufficient to firmly integrate them. Do not have excessive permeability.
【0025】補強材が、型内発泡成形品形状に追従し
優れた成形能を保持するため、不織布構成繊維交点間接
着は、強固でなく組織変形に融通性を持った組織構造と
緩やかに接着された構造物であることSince the reinforcing material follows the shape of the in-mold foamed molded article and retains excellent molding ability, the bonding between the inter-fiber intersection points of the non-woven fabric is not strong but gently bonds with the structural structure which is flexible to the structural deformation. Must be a structure
【0026】充分な補強効果を発揮せしめるため、不
織布の嵩密度は型内発泡成形時のウレタン樹脂含浸、充
填が可能なレベルで出来得る限り高いこと。In order to exert a sufficient reinforcing effect, the bulk density of the non-woven fabric should be as high as possible to the extent that urethane resin can be impregnated and filled during in-mold foam molding.
【0027】バネ部との接触面における擦過音発生を
防止し、屈曲音発生などの異音発生を防止せしめるため
に、スプリングが直接ウレタンフォームと接触せず比較
的低嵩密度(比較的高空隙率)の不織布と接触するよう
な構造が必要で、更に、補強されたウレタンフォームと
一体構造体ならしめる必要があるため、補強布は,,
の機能を有する比較的空隙率の低い(比較的嵩密度の
高い)補強兼ウレタン樹脂透過、流入バリア用織布層と
比較的低嵩密度(比較的高空隙率)の異音発生防止用不
織布が積層された一体構造体をなすことが要求される。In order to prevent generation of scratching noise on the contact surface with the spring portion and generation of abnormal noise such as bending noise, the spring does not directly contact the urethane foam and has a relatively low bulk density (relatively high void volume). Since it is necessary to have a structure that comes in contact with a non-woven fabric, and it is also necessary to make it a unified structure with a reinforced urethane foam,
With a relatively low porosity (relatively high bulk density) that functions as a reinforcing and urethane resin permeation, inflow barrier woven fabric layer and a relatively low bulk density (relatively high porosity) non-woven noise prevention nonwoven fabric It is required to form an integrated structure in which the layers are laminated.
【0028】項に規定した型内発泡成形時のウレタン
樹脂の透過性は、補強用不織布の空隙のポアーサイズ及
び空隙率(見掛けの嵩密度)により決定される値であ
り、空隙率を適正に選定することにより、発泡成形金型
内で発泡し膨張してくるポリウレタン樹脂を補強材内に
包含させ充填させるが、補強用不織布層外(上面)に多
量に流出させることなく若干のニジミダシ程度に抑制し
制御することが可能であることが判明した。The permeability of the urethane resin at the time of in-mold foam molding specified in the item is a value determined by the pore size and the porosity (apparent bulk density) of the reinforcing nonwoven fabric, and the porosity is properly selected. By doing so, the polyurethane resin that expands and expands in the foam molding die is included and filled in the reinforcing material, but it is suppressed to a slight amount without flowing out to the outside (upper surface) of the reinforcing nonwoven fabric layer in large quantities. It turned out that it is possible to control.
【0029】そこで、実験的にこの適正値を選定した結
果、空隙率87ないし91%が適正であることを見出し
た。Then, as a result of experimentally selecting this appropriate value, it was found that a porosity of 87 to 91% is appropriate.
【0030】また、この空隙率(見掛けの嵩密度)は、
項に規定した補強性能に関連性の高い性状であり、嵩
密度が高く不織布構成繊維交点間距離が短いほど、型内
発泡成形時に、不織布構成組織内へのポリウレタン樹脂
の充填が緻密な状態で行なわれ、剛性アップに寄与し、
また、浸透、含浸されるウレタン樹脂による交点間再接
着による引張り弾性率も高い値を得ることができるた
め、型内発泡成形時のウレタン樹脂含浸、充填が可能な
レベルで、出来る限り高い見掛け嵩密度を選定すること
が望ましく、透過性を満足させるための補強基布嵩密度
(空隙率)選定基準と合致し相反する要素を含まず、空
隙率87ないし91%となるように補強用不織布の空隙
率選定を行なうことが全てにおいて好結果を与える。The porosity (apparent bulk density) is
It is a property that is highly relevant to the reinforcing performance specified in paragraph, and the higher the bulk density and the shorter the distance between the fibers constituting the nonwoven fabric, the more dense the filling of the polyurethane resin into the nonwoven fabric structure during in-mold foam molding. Is performed and contributes to the increase in rigidity,
In addition, since a high tensile modulus can be obtained by re-adhesion between the intersections due to the urethane resin that is impregnated and impregnated, the urethane resin can be impregnated and filled during in-mold foam molding, and the apparent bulk is as high as possible. It is desirable to select the density of the reinforcing non-woven fabric so that the reinforcing base cloth bulk density (porosity) for satisfying the permeability meets the selection criteria and does not include contradictory elements and the porosity is 87 to 91%. Performing porosity selection gives good results in all.
【0031】因みに空隙率選定を91%より大きくした
場合を考えると、この際は、膨張してくるポリウレタン
樹脂が補強用不織布層を透過し、その上面に溢れ空気抜
き孔に流入するトラブルを発生するか、補強布に不織布
層が積層されている際には、その不織布層に流入して、
異音発生防止用不織布層に流入し、その効果を殺してし
まうことになる。Considering the case where the porosity is selected to be larger than 91%, in this case, the expanding polyurethane resin permeates the reinforcing non-woven fabric layer, overflows to the upper surface thereof, and causes a trouble of flowing into the air vent hole. Or, when a nonwoven fabric layer is laminated on the reinforcing cloth, it flows into the nonwoven fabric layer,
It will flow into the non-woven fabric layer for preventing abnormal noise and kill its effect.
【0032】逆に空隙率選定が87%より小さい場合
は、補強用不織布層にポリウレタン樹脂が含浸し難くな
り、補強用不織布層とポリウレタンフォーム層間の接合
不充分を招くようになる。On the contrary, when the porosity is selected to be less than 87%, it becomes difficult to impregnate the reinforcing non-woven fabric layer with the polyurethane resin, resulting in insufficient bonding between the reinforcing non-woven fabric layer and the polyurethane foam layer.
【0033】項に規定した成形性能確保のため、補強
用不織布の交点間接着を緩やかに行なっておくことは、
何ら補強効果に影響を及ぼさず補強材構成繊維の交点間
接着は、型内発泡成形時に浸透、含浸してくるウレタン
樹脂により最終的接着が行なわれ完結するため、成形性
能を阻害する強固な接着を予め行なっておくことは必要
ないのである。In order to secure the molding performance specified in the above item, it is necessary to gently bond the reinforcing non-woven fabric between the intersections.
Adhesion between the intersections of the reinforcing material fibers without affecting the reinforcing effect is completed by the urethane resin that penetrates and is impregnated during in-mold foam molding to complete the final bond, which is a strong bond that impairs molding performance. It is not necessary to carry out in advance.
【0034】異音防止層に用いられる不織布層は、実験
の結果、嵩高でクッション性がある方が望ましく、屈曲
時に異音を発生しないことが必要であるため、補強用不
織布層より空隙率が大きく、また目付けの大きく厚手の
ものが必要であり、目付30ないし200g/m2 、空
隙率90ないし94%のものを選定すれば良いことが明
らかとなった。As a result of experiments, it is desirable that the non-woven fabric layer used for the abnormal noise prevention layer be bulky and have cushioning properties, and it is necessary that no abnormal noise is generated during bending. It has been clarified that a large one having a large weight and a large weight is required, and it is clear that the one having a weight of 30 to 200 g / m 2 and a porosity of 90 to 94% should be selected.
【0035】このような機能分析結果に基づき、本発明
は、異音発生防止層として、目付30ないし200g/
m2 で空隙率90ないし94%の嵩高な不織布を、補強
層兼ウレタン樹脂透過、流入バリアー層として、目付2
0ないし100g/m2 で空隙率87ないし91%の緻
密な不織布層を、補強層兼ポリウレタンフォームと補強
層間接合強化層として、目付30ないし200g/m2
で空隙率90ないし94%の嵩高な不織布を当て、この
三層を積層し一体化して目的とする機能を達成する積層
構造ウレタン発泡成形用補強材を構成せしめた。Based on the results of such functional analysis, the present invention provides the abnormal noise preventing layer with a basis weight of 30 to 200 g /
A bulky non-woven fabric with a porosity of 90 to 94% at m 2 is used as a reinforcement layer and urethane resin permeation, and an inflow barrier layer.
A dense non-woven fabric layer having a porosity of 87 to 91% at 0 to 100 g / m 2 is used as a reinforcing layer / polyurethane foam and a reinforcing interlayer joint reinforcing layer, and a basis weight of 30 to 200 g / m 2
Then, a bulky non-woven fabric having a porosity of 90 to 94% was applied, and these three layers were laminated and integrated to form a reinforcing material for urethane foam molding having a laminated structure that achieves a desired function.
【0036】本発明の不織布は、上記の条件を満足する
ものなればスパンボンド法不織布であろうと、短繊維不
織布であろうと何れにても良く、又構成繊維素材も何ら
限定する必要がないが、型内発泡成形時に熱収縮しない
だけの耐熱性(熱収縮率が低いこと)が要求される。The non-woven fabric of the present invention may be either spun-bonded non-woven fabric or short-fiber non-woven fabric as long as the above conditions are satisfied, and the constituent fiber material is not limited at all. In addition, heat resistance (low heat shrinkage) that does not cause heat shrinkage during in-mold foam molding is required.
【0037】但し、補強用不織布層には長繊維からなる
スパンボンド法不織布の適用が補強効果が高くより好適
である。However, it is more preferable to use a spunbonded nonwoven fabric composed of long fibers for the reinforcing nonwoven fabric layer because the reinforcing effect is high.
【0038】これらの所定の空隙率(見掛けの嵩密度)
を有し、異なる見掛け嵩密度(空隙率)の不織布を積層
し一体化した不織布積層体は、下記の方法を適宜選定し
組合せて製造することが可能である。These predetermined porosities (apparent bulk density)
It is possible to manufacture a non-woven fabric laminate having the above-mentioned, and laminating and integrating non-woven fabrics having different apparent bulk densities (porosity) by appropriately selecting and combining the following methods.
【0039】不織布の見掛け嵩密度(空隙率)は、不織
布構成繊維のデニール、クリンプの有無、クリンプの形
状、接着の状態(条件)、交絡の状態(条件)、カレン
ダー加工等のプレス条件等により決定されるので、目的
に合致する条件を選定することにより所定の見掛け嵩密
度を有する不織布が製造できる。The apparent bulk density (porosity) of the non-woven fabric depends on the denier of the non-woven fabric constituent fibers, the presence or absence of crimp, the shape of the crimp, the adhesion state (condition), the entangled state (condition), press conditions such as calendering, etc. Since it is determined, a non-woven fabric having a predetermined apparent bulk density can be manufactured by selecting the conditions that match the purpose.
【0040】一般的に、高い見掛け嵩密度の不織布を得
るには、低デニール繊維を使用すること、ニードルパン
チによる交絡時にニードル密度を高く、ニードル深さを
深くすること、カレンダー加工における温度と圧力を上
げることなどが有効である。Generally, in order to obtain a non-woven fabric having a high apparent bulk density, use of low denier fiber, high needle density and deep needle depth during entanglement with a needle punch, and temperature and pressure during calendering. It is effective to raise it.
【0041】また、積層され一体構造をなす不織布を製
造するには、 a.2種(異種)のウエッブを重ねニードルパンチング
することにより、機械的交絡により積層一体化された不
織性ウェッブを得ることが出来る。In order to produce a laminated non-woven fabric having a unitary structure, a. By stacking two types (different types) of webs and performing needle punching, it is possible to obtain a non-woven web that is laminated and integrated by mechanical entanglement.
【0042】このウェッブは、そのままで又は接着剤を
含浸、乾燥して製品化するか、又はウェッブ構成繊維を
複合繊維あるいは熱融着性繊維で構成させれば熱接着し
て製品化される。This web is manufactured as it is or by impregnating it with an adhesive and drying it into a product, or if the web-constituting fibers are composed of composite fibers or heat-fusible fibers, they are heat-bonded into a product.
【0043】b.2種のウエッブの接合面に接着剤を塗
布し積層し接合することにより製造できる。B. It can be manufactured by applying an adhesive to the joining surfaces of two kinds of webs, laminating them and joining them.
【0044】この際、接着剤は、接着剤溶液(エマルジ
ョン)のコーティング、ホットメルト接着剤シート(不
織布シート、フィルム)の層間挿入等に付与し、それぞ
れ乾燥或いは熱処理することにより接合が行なわれる。At this time, the adhesive is applied to the coating of the adhesive solution (emulsion), the intercalation of the hot melt adhesive sheet (nonwoven fabric sheet, film) or the like, and dried or heat-treated to perform the joining.
【0045】なお、不織布構成繊維自体が、複合繊維よ
りなるか、或いは熱融着性繊維を包含する場合には、直
接両者の積層体を熱処理することにより接合一体化が可
能である。When the non-woven fabric-constituting fiber itself is composed of a composite fiber or includes a heat-fusible fiber, it is possible to join and integrate them by directly heat-treating the laminated body of both.
【0046】次に本発明の実施態様を具体的に示すため
に実施例により詳細に説明する。Next, the present invention will be described in detail with reference to Examples in order to specifically show the embodiments.
【0047】[0047]
【実施例】スパンボンド法により製造された3デニール
のポリエチレンテレフタレート繊維よりなるランダムル
ープ組織の目付80g/m2 のウェッブを170℃の熱
ロールによるカレンダー加工で仮熱圧着した不織布1と
同じくスパンボンド法により製造された1.5デニール
のポリエチレンテレフタレート繊維よりなるランダムル
ープ組織の目付40g/m2 のウェッブを200℃の熱
ロールによるカレンダー加工で熱圧着した不織布2とを
積層し、オルガン社製FPD1−40Sのニードルを用
いニードル密度40ケ/cm2 、針深度14mmでニー
ドルパンチングし、得られる二層積層構造不織布の不織
布2面側に、不織布1と同じ製造条件で製造した不織布
3を重ね、更に、オルガン社製FPD1−40Sのニー
ドルを用いニードル密度40ケ/cm2 、針深度14m
mでニードルパンチングし、交絡し三層が一体化され
た、図1に示す成形品補強用不織布4を得る。Example A spun bond similar to the non-woven fabric 1 in which a web having a basis weight of 80 g / m 2 of a random loop structure made of polyethylene terephthalate fiber of 3 denier produced by the spun bond method was provisionally thermocompression bonded by calendering with a heat roll at 170 ° C. FPD1 manufactured by Organ Co. was laminated with a non-woven fabric 2 which was thermocompression-bonded by calendering a web having a random loop structure of 40 g / m 2 composed of 1.5 denier polyethylene terephthalate fiber produced by Using a -40S needle, needle punching at a needle density of 40 / cm 2 and a needle depth of 14 mm is performed, and the nonwoven fabric 3 produced under the same production conditions as the nonwoven fabric 1 is overlaid on the nonwoven fabric 2 side of the obtained two-layer laminated structure nonwoven fabric, Furthermore, using the needle of Organ FPD1-40S Density 40 / cm 2 , needle depth 14m
Needle punching with m, entanglement and three layers are integrated to obtain a nonwoven fabric 4 for reinforcing a molded product shown in FIG.
【0048】不織布2の測定の結果、図1における不織
布1,3よりなる異なる音防止用不織布層の空隙率は9
2%、不織布2よりなる補強用不織布層の空隙率は88
%であった。As a result of the measurement of the nonwoven fabric 2, the different soundproofing nonwoven fabric layers composed of the nonwoven fabrics 1 and 3 in FIG.
2%, the void ratio of the nonwoven fabric layer consisting of nonwoven fabric 2 is 88
%Met.
【0049】得られた、ポリウレタンフォーム型内発泡
成形品補強用不織布3を、発泡成形用金型内に不織布1
面を金型の上面、即ち空気抜き孔方向に向け、他の不織
布1面を発泡性ウレタン樹脂添加側に向け金型にセット
し、常法通り発泡性ウレタン樹脂を添加し、加熱、加圧
下でポリウレタンの発泡成形を行ない、軟質ポリウレタ
ンフォーム型内発泡成形品を作成した。The obtained non-woven fabric 3 for reinforcing the foamed product inside the polyurethane foam is placed in the metal mold for foaming molding.
Face the upper surface of the mold, that is, the direction of the air vent hole, and set the other non-woven fabric 1 surface to the mold with the foamable urethane resin addition side, add the foamable urethane resin as usual, and heat and pressurize it under pressure. Polyurethane foam molding was performed to prepare a soft polyurethane foam in-mold foam molded article.
【0050】得られた成形品における積層構造不織布3
へのポリウレタン樹脂の浸透、透過状態と、ポリウレタ
ンフォーム層と積層構造不織布3間の接合状態を確認す
るため、得られた成形品を切断し、断面の状態観察及び
ポリウレタンフォーム層と積層構造不織布3間接合強さ
を検討した。Laminated nonwoven fabric 3 in the obtained molded product
In order to check the permeation and permeation state of the polyurethane resin into the polyurethane foam layer and the bonding state between the polyurethane foam layer and the laminated structure nonwoven fabric 3, the obtained molded product was cut, the cross-sectional state was observed, and the polyurethane foam layer and the laminated structure nonwoven fabric 3 were observed. The interbonding strength was examined.
【0051】観察の結果は、発泡し膨張したポリウレタ
ン樹脂は不織布1,2層内に均等に浸透し充満し、若干
不織布2層内の不織布1側に向かってほぼ90%まで均
等に浸透し充填され、不織布1層には全く浸透しておら
ず、目標とした理想的状態が実現されていることを示し
た。As a result of the observation, the expanded and expanded polyurethane resin evenly permeates and fills the first and second layers of the non-woven fabric, and slightly permeates the non-woven fabric 1 side in the second non-woven fabric layer to approximately 90% and fills. As a result, it has not penetrated into one layer of the non-woven fabric, indicating that the desired ideal state was achieved.
【0052】更に、ポリウレタンフォーム層と積層構造
不織布3間の接合強さは、境界面剥離以前にポリウレタ
ンフォーム層の破壊が起こり、充分な接合が行なわれて
いることが示された。Further, regarding the bonding strength between the polyurethane foam layer and the nonwoven fabric 3 having a laminated structure, it was shown that the polyurethane foam layer was broken before the boundary surface was peeled off, and sufficient bonding was performed.
【0053】また、異音発生防止層である不織布1面を
コイル状バネに接して加圧、除圧を繰り返す異音発生モ
デル試験において異音の発生は全く検知出来なかった。 比較例 実施例における補強用不織布1層を省略し、不織布層
2、3層のみで構成させ、不織布層2の空隙率のみを8
3%に変更した試料と、全体を空隙率95%の不織布層
で形成させ、実施例と同様に軟質ポリウレタンフォーム
型内発泡成形品を作成し、成形品における積層構造不織
布3へのポリウレタン樹脂の浸透、透過状態と、ポリウ
レタンフォーム層と積層構造不織布3間の接合状態を観
察した。Further, in the abnormal noise generation model test in which one surface of the nonwoven fabric which is the abnormal noise generation preventing layer is brought into contact with the coiled spring and pressure and depressurization are repeated, generation of abnormal noise was not detected at all. Comparative Example The reinforcing non-woven fabric 1 layer in the example was omitted, and the non-woven fabric layer 2 was constituted by only 3 layers, and the void ratio of the non-woven fabric layer 2 was 8
A sample changed to 3% and a non-woven fabric layer having an overall porosity of 95% were used to form a flexible polyurethane foam in-mold foam molded product in the same manner as in the example, and the polyurethane resin for the laminated structure non-woven fabric 3 in the molded product was prepared. The state of permeation and permeation and the state of bonding between the polyurethane foam layer and the laminated structure nonwoven fabric 3 were observed.
【0054】観察結果は、全体を空隙率95%とした試
料においては、発泡し膨張したポリウレタン樹脂が一部
不織布層を透過し外部に溢れだし、成形金型の空気抜き
孔を閉塞させる恐れのある状態を示し、ポリウレタン樹
脂が不織布表層に達するため異音防止効果もないことを
示し、補強層用不織布2層の空隙率を83%に変更した
試料では、補強層用不織布2層へのポリウレタン樹脂の
浸透、含浸が不充分の個所があり、ポリウレタンフォー
ム層と積層構造不織布3間接合が部分的に不充分である
個所があった。The observation result shows that in the sample having a porosity of 95% as a whole, the expanded and expanded polyurethane resin may partially permeate the non-woven fabric layer and overflow to the outside to block the air vent hole of the molding die. Shows that the polyurethane resin reaches the surface layer of the non-woven fabric and has no noise suppressing effect. In the sample in which the void ratio of the two layers of the non-woven fabric for the reinforcing layer is changed to 83%, the polyurethane resin for the two non-woven fabrics of the reinforcing layer is shown. There was a part where the permeation and impregnation were insufficient, and there was a part where the bonding between the polyurethane foam layer and the laminated structure nonwoven fabric 3 was partially insufficient.
【0055】なお、本発明における空隙率とは、20g
/cm2 の荷重を付したときの不織布厚みを用い算出し
た見掛け嵩密度と、不織布構成繊維の密度より算出した
不織布の有効空隙体積の百分率表示である。The porosity in the present invention is 20 g.
It is a percentage display of the apparent void density calculated using the thickness of the nonwoven fabric when a load of / cm 2 is applied and the effective void volume of the nonwoven fabric calculated from the density of the fibers constituting the nonwoven fabric.
【0056】[0056]
【発明の効果】目付30ないし200g/m2 で空隙率
90ないし94%の嵩高な不織布層により、中間層とし
て目付20ないし100g/m2 で空隙率87ないし9
1%の緻密な不織布層をサンドイッチ状に挾み積層し一
体化された三層構造不織布を、軟質ポリウレタンフォー
ム型内発泡成形品用補強材として使用することにより、
異音発生防止能が付与され、ウレタン発泡成形品に適度
の剛性と優れた引張り弾性率が付与される。The bulky non-woven fabric layer having a basis weight of 30 to 200 g / m 2 and a porosity of 90 to 94% provides an intermediate layer having a basis weight of 20 to 100 g / m 2 and a porosity of 87 to 9
By using a three-layer structure nonwoven fabric in which 1% dense non-woven fabric layers are sandwiched and laminated and integrated as a reinforcing material for a flexible polyurethane foam in-mold foam molded article,
The ability to prevent abnormal noise is imparted, and the urethane foam molded article is imparted with appropriate rigidity and excellent tensile elastic modulus.
【0057】そして、その製造法において、ウレタン発
泡成形において、発泡ウレタンが強固な補強剤とウレタ
ンとの一体性を得るために充分な目付と層内に適度な空
隙、そしてウレタンと接する面に適度な毛羽立ちを有し
た層を通過した後、早期に高いウレタン遮断性を有した
緻密な層に達し、更にその層で遮断できなかったウレタ
ンを次ぎの第三層で完全にウレタンを遮断することによ
り、比較的低い基布目付で成形性を損なうことなく、高
いウレタン遮断性が得られ、異音防止を満足するととも
に基布とウレタンが強固に一体化した、即ち、ウレタン
の補強効果の大きいウレタン発泡成形を可能とする。そ
して、その製品として、優れた引張り弾性率が付与され
ることに基づいた優れたクッション性能と良好な座り心
地を有する、優れた補強効果による耐久性優秀な車両用
シート等を得ることが出来る。Further, in the production method thereof, in urethane foam molding, the urethane foam has a basis weight sufficient to obtain the integrity of the strong reinforcing agent and the urethane, an appropriate void in the layer, and an appropriate amount on the surface in contact with the urethane. After passing through a layer with a fluff, it reaches a dense layer with a high urethane blocking property at an early stage, and the urethane that could not be blocked by that layer is completely blocked by the next third layer. With a relatively low basis weight, a high urethane barrier property is obtained without impairing moldability, satisfying the prevention of abnormal noise, and the base cloth and urethane are firmly integrated, that is, urethane with a large urethane reinforcing effect. Enables foam molding. Then, as the product, it is possible to obtain a vehicle seat or the like having excellent cushioning performance based on imparting an excellent tensile elastic modulus and good sitting comfort and excellent durability due to an excellent reinforcing effect.
【図1】本発明の補強基布の断面図である。FIG. 1 is a cross-sectional view of a reinforcing base fabric of the present invention.
【図2】本発明の補強基布を用いて製造されたポリウレ
タンフォーム型内発泡成形品の断面図である。FIG. 2 is a cross-sectional view of a polyurethane foam in-mold foam molded product manufactured using the reinforcing base fabric of the present invention.
【図3】軟質ポリウレタンフォーム型内発泡成形品の断
面図である。FIG. 3 is a cross-sectional view of a flexible polyurethane foam in-mold foam molded product.
1 嵩高不織布層 2 緻密不織布層 3 嵩高不織布層 4 発泡成形品用補強基布 5 ポリウレタンフォーム層 A ポリウレタンフォーム層 B 補強層 C スプリング 1 Bulky Nonwoven Layer 2 Dense Nonwoven Layer 3 Bulky Nonwoven Layer 4 Reinforcement Base Fabric for Foam Molded Products 5 Polyurethane Foam Layer A Polyurethane Foam Layer B Reinforcement Layer C Spring
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 B29L 31:58 4F (72)発明者 井上 武士 福井県敦賀市東洋町10番24号 東洋紡績株 式会社敦賀工場内 (72)発明者 塩谷 禎邦 神奈川県厚木市金田982番地 トーヨーソ フラン株式会社本社内 (72)発明者 稲毛 茂 神奈川県厚木市金田982番地 トーヨーソ フラン株式会社本社内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification number Reference number within the agency FI Technical indication location B29L 31:58 4F (72) Inventor Takeshi Inoue 10-24 Toyocho, Tsuruga City, Fukui Prefecture Toyobo Co., Ltd. Ceremony company Tsuruga factory (72) Inventor Sadakuni Shioya 982 Kaneda, Atsugi-shi, Kanagawa Toyo Soflan Co., Ltd. Main office (72) Inventor Shigeru Inage 982 Kaneda, Atsugi-shi, Kanagawa Toyoso Franc Co., Ltd.
Claims (3)
90ないし94%の嵩高な不織布層を上下層とし、目付
20ないし100g/m2 で空隙率87ないし91%の
緻密な不織布層を中間層として積層し一体化されたこと
を特徴とする積層構造ウレタン発泡成形用補強材。1. A bulky nonwoven fabric layer having a basis weight of 30 to 200 g / m 2 and a porosity of 90 to 94% is used as the upper and lower layers, and a dense nonwoven fabric layer having a basis weight of 20 to 100 g / m 2 and a porosity of 87 to 91% is intermediate. A reinforcing material for urethane foam molding having a laminated structure, which is laminated and integrated as a layer.
30ないし200g/m2 で空隙率90ないし94%の
嵩高な不織布層を上下層とし、目付20ないし100g
/m2 で空隙率87ないし91%の緻密な不織布層を中
間層として積層し一体化し、前記嵩高な不織布側に発泡
性ウレタン液を供給し、前記不織布層内にウレタンを浸
透させ発泡させて補強を行なうとともに、形成されるポ
リウレタンフォームと一体化せしめたことを特徴とする
ウレタン発泡成形用補強材の製造方法。2. In producing an in-mold foamed article, a bulky nonwoven fabric layer having a basis weight of 30 to 200 g / m 2 and a porosity of 90 to 94% is used as upper and lower layers, and a basis weight of 20 to 100 g.
/ It is no porosity 87 m 2 by laminating a dense non-woven layer of 91% as an intermediate layer integrally, the supply bulky nonwoven fabric side foamable urethane solution, and urethane impregnated foamed into the nonwoven layer A method for producing a urethane foam molding reinforcing material, which comprises reinforcing and integrally forming with a polyurethane foam to be formed.
90ないし94%の嵩高な不織布層を上下層とし、目付
20ないし100g/m2 で空隙率87ないし91%の
緻密な不織布層を中間層として積層し一体化されたウレ
タン発泡成形用補強材からなる車両用シート。3. A bulky nonwoven fabric layer having a basis weight of 30 to 200 g / m 2 and a porosity of 90 to 94% is used as the upper and lower layers, and a dense nonwoven fabric layer having a basis weight of 20 to 100 g / m 2 and a porosity of 87 to 91% is intermediate. A vehicle seat made of a urethane foam molding reinforcing material laminated and integrated as a layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4352487A JP2990208B2 (en) | 1992-12-11 | 1992-12-11 | Urethane foam molding reinforcing material having abnormal noise preventing ability, method for producing the same, and product thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4352487A JP2990208B2 (en) | 1992-12-11 | 1992-12-11 | Urethane foam molding reinforcing material having abnormal noise preventing ability, method for producing the same, and product thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06171003A true JPH06171003A (en) | 1994-06-21 |
| JP2990208B2 JP2990208B2 (en) | 1999-12-13 |
Family
ID=18424410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4352487A Expired - Fee Related JP2990208B2 (en) | 1992-12-11 | 1992-12-11 | Urethane foam molding reinforcing material having abnormal noise preventing ability, method for producing the same, and product thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2990208B2 (en) |
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| JP2002275749A (en) * | 2001-03-21 | 2002-09-25 | Unitika Ltd | Laminated nonwoven fabric and urethane foam reinforced with nonwoven fabric |
| KR100356412B1 (en) * | 1999-10-01 | 2002-10-19 | 한국바이린주식회사 | Internal Sheet of Moter and Method For Manufacturing The Same |
| WO2005010262A1 (en) * | 2003-07-28 | 2005-02-03 | Toyo Boseki Kabushiki Kaisha | Reinforcing material for polyurethane foam molded article, cushioning material for seat, and seat |
| JP2007146356A (en) * | 2005-10-27 | 2007-06-14 | Toyobo Co Ltd | Nonwoven fabric and method for producing the same |
| JP2007331259A (en) * | 2006-06-15 | 2007-12-27 | Toyobo Co Ltd | Urethane foam reinforcement |
| JP2008044160A (en) * | 2006-08-11 | 2008-02-28 | Nitto Boseki Co Ltd | Composite sheet and seat pad reinforcement |
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| JP2011168923A (en) * | 2010-02-19 | 2011-09-01 | Toyobo Co Ltd | Reinforcing material for urethane expansion molding |
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| JP2012131032A (en) * | 2010-12-17 | 2012-07-12 | Bridgestone Corp | Foam molded article and method of manufacturing the same |
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|---|---|---|---|---|
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| JP2002275749A (en) * | 2001-03-21 | 2002-09-25 | Unitika Ltd | Laminated nonwoven fabric and urethane foam reinforced with nonwoven fabric |
| WO2005010262A1 (en) * | 2003-07-28 | 2005-02-03 | Toyo Boseki Kabushiki Kaisha | Reinforcing material for polyurethane foam molded article, cushioning material for seat, and seat |
| JP2007146356A (en) * | 2005-10-27 | 2007-06-14 | Toyobo Co Ltd | Nonwoven fabric and method for producing the same |
| JP2009527382A (en) * | 2006-02-24 | 2009-07-30 | バイエル マテリアルサイエンス アクチェンゲゼルシャフト | Improved method for manufacturing a lightweight sound insulation cover for automobiles and its cover |
| US7790643B2 (en) | 2006-06-15 | 2010-09-07 | Toyo Boseki Kabushiki Kaisha | Urethane foam reinforcing material |
| JP2007331259A (en) * | 2006-06-15 | 2007-12-27 | Toyobo Co Ltd | Urethane foam reinforcement |
| JP2008044160A (en) * | 2006-08-11 | 2008-02-28 | Nitto Boseki Co Ltd | Composite sheet and seat pad reinforcement |
| JP2010174393A (en) * | 2009-01-28 | 2010-08-12 | Kureha Ltd | Urethan-reinforcing material |
| JP2011168923A (en) * | 2010-02-19 | 2011-09-01 | Toyobo Co Ltd | Reinforcing material for urethane expansion molding |
| WO2012014501A1 (en) * | 2010-07-29 | 2012-02-02 | 三井化学株式会社 | Non-woven fiber fabric, and production method and production device therefor |
| JPWO2012014501A1 (en) * | 2010-07-29 | 2013-09-12 | 三井化学株式会社 | Non-woven fabric, manufacturing method and manufacturing apparatus thereof |
| JP2016166442A (en) * | 2010-07-29 | 2016-09-15 | 三井化学株式会社 | Fiber non-woven fabric, and method and apparatus for manufacturing the same |
| US9649794B2 (en) | 2010-09-30 | 2017-05-16 | Dow Global Technologies | Container modifications to minimize defects during reactive polyurethane flow |
| JP2012131032A (en) * | 2010-12-17 | 2012-07-12 | Bridgestone Corp | Foam molded article and method of manufacturing the same |
| JP2015039846A (en) * | 2013-08-22 | 2015-03-02 | 株式会社オートネットワーク技術研究所 | Sound absorbing material and wire harness with sound absorbing material |
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