JPH0616840B2 - Aldehyde gas adsorbent - Google Patents
Aldehyde gas adsorbentInfo
- Publication number
- JPH0616840B2 JPH0616840B2 JP61026802A JP2680286A JPH0616840B2 JP H0616840 B2 JPH0616840 B2 JP H0616840B2 JP 61026802 A JP61026802 A JP 61026802A JP 2680286 A JP2680286 A JP 2680286A JP H0616840 B2 JPH0616840 B2 JP H0616840B2
- Authority
- JP
- Japan
- Prior art keywords
- gas adsorbent
- present
- aldehyde gas
- aldehyde
- adsorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003463 adsorbent Substances 0.000 title claims description 16
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims description 9
- 150000002337 glycosamines Chemical class 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 16
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 12
- 108010039918 Polylysine Proteins 0.000 description 4
- 229920000656 polylysine Polymers 0.000 description 4
- 229920001661 Chitosan Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920001308 poly(aminoacid) Polymers 0.000 description 3
- -1 aliphatic aldehyde Chemical class 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 108010020346 Polyglutamic Acid Proteins 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- GTCAXTIRRLKXRU-UHFFFAOYSA-N carbamic acid methyl ester Natural products COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000724 poly(L-arginine) polymer Polymers 0.000 description 1
- 108010054442 polyalanine Proteins 0.000 description 1
- 108010011110 polyarginine Proteins 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 108010094020 polyglycine Proteins 0.000 description 1
- 229920000232 polyglycine polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
Landscapes
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明はガス吸着剤に関する。TECHNICAL FIELD The present invention relates to a gas adsorbent.
ポリリジンなどのポリアミノ酸やキトサンなどのアミノ
糖を有するポリマーは例えば医療用の基剤などへの利用
が試みられている。しかし、アルデヒドガス吸着剤とし
ての用途は知られていない。Polymers having polyamino acids such as polylysine and amino sugars such as chitosan have been attempted to be used as medical bases, for example. However, its use as an aldehyde gas adsorbent is not known.
ポリアミノ酸やアミノ糖を有するポリマーを有効に活用
するため、これらの化合物の用途開発が望まれている。In order to effectively utilize polymers having polyamino acids and amino sugars, application development of these compounds is desired.
〔問題点を解決するための手段〕 そこで本発明者らは種々検討した結果、ポリアミノ酸や
アミノ糖を有するポリマーがアルデヒドガスを吸着する
ことを見い出した。[Means for Solving Problems] As a result of various studies, the present inventors have found that polymers having polyamino acids and amino sugars adsorb aldehyde gas.
本発明は上記知見に基づいて完成されたものである。The present invention has been completed based on the above findings.
即ち、本発明はポリアミノ酸又はアミノ糖を有するポリ
マーを含有するアルデヒドガス吸着剤に関する。That is, the present invention relates to an aldehyde gas adsorbent containing a polymer having a polyamino acid or amino sugar.
本発明で使用されるポリアミノ酸としては特に制限はな
く、例えばポリリジン、ポリアラニン、ポリグルタミン
酸、ポリグリシン、ポリアルギニンなどのホモポリマ
ー、ポリ（アラニン−グリシン）、グルタミン酸−γ−
メチル−ウレタン共重合体などのコポリマーがあげられ
るが、構成成分としてリジンやアルギニンなどの塩基性
アミノ酸を有するものが好ましい。その平均分子量は特
に制限はないが、例えば３０００〜１０００００程度が
実用的である。又、その粒度は１０メツシユ以下、好ま
しくは５０メツシユ以下、さらに好ましくは１００〜２
５０メツシユ程度がよい。The polyamino acid used in the present invention is not particularly limited, and examples thereof include homopolymers such as polylysine, polyalanine, polyglutamic acid, polyglycine, and polyarginine, poly (alanine-glycine), glutamic acid-γ-.
Examples thereof include copolymers such as methyl-urethane copolymers, and those having a basic amino acid such as lysine or arginine as a constituent are preferable. The average molecular weight is not particularly limited, but for example, about 3,000 to 100,000 is practical. The particle size is 10 mesh or less, preferably 50 mesh or less, more preferably 100 to 2
About 50 mesh is good.
アミノ糖を有するポリマーとしては、例えば、キチンが
キトサンなどのアミノ糖からなる多糖類などがあげられ
る。このものの形態は特に制限なく、フイルム状繊維
状、布状、粉状のものが使用できるが、布状、粉状のも
のが好ましく、粉状の場合、その粒度は１０メツシユ以
下、好ましくは１００〜２５０メツシユ程度がよい。Examples of polymers having amino sugars include polysaccharides in which chitin is an amino sugar such as chitosan. The form of this product is not particularly limited, and a film-like fibrous, cloth-like, or powder-like product can be used, but a cloth-like or powder-like product is preferred. ~ 250 mesh is good.
本発明の吸着剤に吸着されるガスとしては例えばアルデ
ヒド類のガスがあげられるが、ホルムアルデヒドやアセ
トアルデヒドなどの脂肪族アルデヒド類のガスが好まし
い。Examples of the gas adsorbed on the adsorbent of the present invention include aldehyde gases, and aliphatic aldehyde gases such as formaldehyde and acetaldehyde are preferable.
本発明の吸着剤を使用するにはポリアミノ酸又はアミノ
糖を有するポリマーをそのまま袋などの容器に入れるか
又は増量剤や他のガス吸着剤とともに容器に入れ、冷蔵
庫や食品包装体中に静置すればよい。又、本発明の吸着
剤は空気清浄器などのフィルターとしても使用しうる。To use the adsorbent of the present invention, the polymer having a polyamino acid or amino sugar is placed in a container such as a bag as it is, or placed in a container together with a bulking agent or another gas adsorbent, and then left in a refrigerator or a food package. do it. The adsorbent of the present invention can also be used as a filter for air purifiers and the like.
次に本発明の効果を実験例により説明する。 Next, the effects of the present invention will be described with reference to experimental examples.
実験例 〔試 料〕 実施例１及び２の方法で得られたガス吸着剤を本発明の
試料１及び２とし、小包（５cm×５cm）の中に何も封入
しないものを対照試料とした。Experimental Examples [Reagents] The gas adsorbents obtained by the methods of Examples 1 and 2 were used as Samples 1 and 2 of the present invention, and a sample in which nothing was enclosed in a parcel (5 cm x 5 cm) was used as a control sample.
試料をガス不透過性のナイロンラミネート袋に封入し、
粘着ゴム板（東レエンジニアリング(株)製、１cm×１c
m）を袋に貼り付けた。Enclose the sample in a gas impermeable nylon laminate bag,
Adhesive rubber plate (Toray Engineering Co., Ltd., 1 cm x 1 c
m) was attached to the bag.
このゴム板を通して注射器で約１０００ccの空気及び
０．０２４ｇのアセトアルデヒドを注入した。About 1000 cc of air and 0.024 g of acetaldehyde were injected with a syringe through the rubber plate.
次いで所定時間、室温放置後、袋中のアセトアルデヒド
量をガスクロマトグラフイー法により測定した。Then, after leaving at room temperature for a predetermined time, the amount of acetaldehyde in the bag was measured by a gas chromatography method.
結果を表−１に示す。なお、アセトアルデヒド量は定量
値として示すことが困難なので対照試料を封入した袋中
のアセトアルデヒド量を１００としたものの相対値で示
した。The results are shown in Table-1. Since it is difficult to show the amount of acetaldehyde as a quantitative value, it was shown as a relative value when the amount of acetaldehyde in the bag containing the control sample was 100.
これられの表から明らかの様に本発明のガス吸着剤を使
用すると容器中のアセトアルデヒド量は使用しない場合
に比し、大幅に減少する。 As is clear from these tables, when the gas adsorbent of the present invention is used, the amount of acetaldehyde in the container is greatly reduced as compared with the case where it is not used.
従って本発明のアルデヒドガス吸着剤は冷蔵庫及び食品
包装容器中のアルデヒドガス吸着剤として有効に使用で
きるものである。Therefore, the aldehyde gas adsorbent of the present invention can be effectively used as an aldehyde gas adsorbent in refrigerators and food packaging containers.
以下実施例により本発明のアルデヒドガス吸着剤の製法
を説明する。The method for producing the aldehyde gas adsorbent of the present invention will be described below with reference to examples.
〔実施例１〕 ポリリジン（平均分子量２３，０００、粒径150メツシ
ユ）０．４ｇを片面がポリエチレン、もう一方の片面が
滅菌紙で構成されている小包（５cm×５cm）に封入して
本発明のガス吸着剤を得た。[Example 1] 0.4 g of polylysine (average molecular weight 23,000, particle size 150 mesh) was enclosed in a parcel (5 cm x 5 cm) having polyethylene on one side and sterilized paper on the other side. A gas adsorbent of
〔実施例２〕 実施例１においてポリリジンのかわりにキトサン（粒径
１００メツシユ）粉末０．４ｇを用い、同様にして本発
明のガス吸着剤を得た。[Example 2] A gas adsorbent of the present invention was obtained in the same manner as in Example 1, except that 0.4 g of chitosan (particle size 100 mesh) powder was used instead of polylysine.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭59−33220（ＪＰ，Ａ) 特公 昭53−3788（ＪＰ，Ｂ２) ─────────────────────────────────────────────────── ─── Continuation of front page (56) References JP-A-59-33220 (JP, A) JP-B-53-3788 (JP, B2)
Claims (1)
マーを含有するアルデヒドガス吸着剤1. An aldehyde gas adsorbent containing a polyamino acid or a polymer having an amino sugar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61026802A JPH0616840B2 (en) | 1986-02-12 | 1986-02-12 | Aldehyde gas adsorbent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61026802A JPH0616840B2 (en) | 1986-02-12 | 1986-02-12 | Aldehyde gas adsorbent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62186939A JPS62186939A (en) | 1987-08-15 |
| JPH0616840B2 true JPH0616840B2 (en) | 1994-03-09 |
Family
ID=12203437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61026802A Expired - Lifetime JPH0616840B2 (en) | 1986-02-12 | 1986-02-12 | Aldehyde gas adsorbent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0616840B2 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990001537A2 (en) * | 1988-08-04 | 1990-02-22 | Harris William J | Alcohol reduction of beverages |
| JP3013860B2 (en) * | 1991-03-22 | 2000-02-28 | 三菱瓦斯化学株式会社 | Food preservative and method for preserving food using the same |
| EP0526977A2 (en) * | 1991-07-03 | 1993-02-10 | E.I. Du Pont De Nemours And Company | Novel packaging compositions that extend shelf life of oil-containing foods |
| JPH0539622U (en) * | 1991-11-11 | 1993-05-28 | 日本ケンブリツジ・フイルター株式会社 | Filter |
| JP2884228B2 (en) * | 1996-01-22 | 1999-04-19 | 鳥取県 | Aldehyde emission control method for wood-based materials |
| CN1325155C (en) * | 2004-08-27 | 2007-07-11 | 中国科学院海洋研究所 | Macromolecular chromoprotein adsorbing medium and its application |
| JP4867220B2 (en) * | 2005-07-15 | 2012-02-01 | トヨタ自動車株式会社 | Fuel reformer |
| CN103751944B (en) * | 2014-01-26 | 2016-04-20 | 河北工程大学 | A kind of formaldehyde catching agent and preparation method thereof |
| CN106422743A (en) * | 2016-11-02 | 2017-02-22 | 金福兴 | High-efficiency air purification material and preparation method thereof |
| CN107661690A (en) * | 2017-10-27 | 2018-02-06 | 佛山市高科合创科技有限公司 | A kind of alumina base purifying formaldehyde composite and preparation method thereof |
| CN108816036A (en) * | 2018-06-29 | 2018-11-16 | 浙江四逸环保科技有限公司 | A kind of polyamino acid coenzyme, preparation method and slow-release aldehyde remover |
| CN114904384B (en) * | 2021-06-04 | 2023-08-22 | 浙江施维康生物医学材料有限公司 | Biological enzyme-containing air purifying agent and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS533788A (en) * | 1976-07-01 | 1978-01-13 | Seiko Instr & Electronics Ltd | Frequency adjustment method of crystal vibrator |
| JPS5933220A (en) * | 1982-08-19 | 1984-02-23 | Hidetoshi Tsuchida | Oxygen adsorption/desorption agent |
-
1986
- 1986-02-12 JP JP61026802A patent/JPH0616840B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62186939A (en) | 1987-08-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0616840B2 (en) | Aldehyde gas adsorbent | |
| US5030610A (en) | Acidic gas absorbent and process for production thereof | |
| KR20100057647A (en) | Flavor emitting compositions, devices and packaged food products therewith | |
| EP0159696A2 (en) | Self-supporting structures containing immobilized carbon particles and method for forming same | |
| CN1270240A (en) | Staltic fibre and its manufacture method | |
| AU2004259960A1 (en) | Water-absorbent resin composition and method for producing thereof, and absorbent material and absorbent product using thereof | |
| US4812404A (en) | Apatite immobilized glucanase | |
| CN113426423B (en) | Adsorbent for removing LDL in extracorporeal circulation of blood and its preparation method and perfusion device | |
| WO2023089633A1 (en) | Activated carbon beads with reduced dust spillage | |
| JPH066050B2 (en) | Sustained release ethanol preparation | |
| JPH11152330A (en) | Polylysine, production of polylysine, polylysine composition, and production of medicine which removes endotoxin | |
| CN118490662A (en) | A protein-polysaccharide based Physalis pubescens flavonoids nano-delivery system | |
| CN113908285B (en) | A composite solid biological preparation based on self-assembled crystalline materials, and its preparation and application | |
| CN102512414B (en) | Sultamicittin composition and preparation method thereof | |
| JPH0516902B2 (en) | ||
| Yavuz et al. | Immunoaffinity beads for selective removal of cholesterol from human plasma | |
| CN115887628A (en) | Lysozyme preparation and production method and application thereof | |
| JP3433493B2 (en) | Acid gas absorbent | |
| JPH04244228A (en) | Oxygen absorbent molded article and its manufacturing method | |
| JPH0852303A (en) | Method for improving storage stability of adsorption column for extracorporeal circulation treatment | |
| US20240260617A1 (en) | Oxygen absorber tablet | |
| CN121446458A (en) | A resin filler for reducing blood ammonia concentration and its preparation method | |
| JPS62220178A (en) | Preservative for food or the like | |
| CN108743546A (en) | A kind of 2-Propen-1-amine polymer with(chloromethyl)oxirane carbonate dry suspensoid agent and preparation method thereof | |
| JPS5934261A (en) | Production of granular aromatic material |