JPH0586327A - Coating composition for thermoplastic elastomer - Google Patents
Coating composition for thermoplastic elastomerInfo
- Publication number
- JPH0586327A JPH0586327A JP3274821A JP27482191A JPH0586327A JP H0586327 A JPH0586327 A JP H0586327A JP 3274821 A JP3274821 A JP 3274821A JP 27482191 A JP27482191 A JP 27482191A JP H0586327 A JPH0586327 A JP H0586327A
- Authority
- JP
- Japan
- Prior art keywords
- diisocyanate
- thermoplastic elastomer
- coating
- paint
- resin component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 13
- 239000008199 coating composition Substances 0.000 title claims description 3
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims abstract description 9
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920005862 polyol Polymers 0.000 claims abstract description 7
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 6
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 5
- 239000004417 polycarbonate Substances 0.000 claims abstract description 5
- 150000003077 polyols Chemical class 0.000 claims abstract description 5
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002576 ketones Chemical class 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 10
- 238000012644 addition polymerization Methods 0.000 claims description 5
- XJRAOMZCVTUHFI-UHFFFAOYSA-N isocyanic acid;methane Chemical compound C.N=C=O.N=C=O XJRAOMZCVTUHFI-UHFFFAOYSA-N 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 2
- 239000002075 main ingredient Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 33
- 239000011248 coating agent Substances 0.000 abstract description 32
- 238000000465 moulding Methods 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 3
- 125000005442 diisocyanate group Chemical group 0.000 abstract description 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000010408 film Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- -1 urethane polyol Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- NCEXYHBECQHGNR-UHFFFAOYSA-N chembl421 Chemical compound C1=C(O)C(C(=O)O)=CC(N=NC=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、サーモプラスチックエ
ラストマー樹脂成形物の表面塗装に用いる１コート系塗
料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a one-coat paint used for surface coating of thermoplastic elastomer resin molded products.
【０００２】[0002]
【従来の技術】従来、サーモプラスチックエラストマー
樹脂成形物の塗装としては、大別して１液タイプ及び２
液タイプがあり、特に自動車内装部品用としては、１液
タイプ及び２液タイプの各々について、次の組成配合塗
料が知られている。以下、１液タイプのものを二つ例示
しこれを表５に、２液タイプのものを四つ例示してこれ
を表６に夫々示す。2. Description of the Related Art Conventionally, the coating of thermoplastic elastomer resin moldings is roughly classified into one-pack type and two-pack type.
There are liquid types, and particularly for automobile interior parts, the following composition-blended coating compositions are known for each of the one-component type and the two-component type. Hereinafter, two examples of one-component type are shown in Table 5, four examples of two-component type are shown in Table 6, respectively.
【０００３】[0003]
【表５】 [Table 5]
【０００４】[0004]
【表６】 [Table 6]
【０００５】[0005]
【発明が解決しようとする課題】しかしながら、このよ
うな従来の塗料にあっては、１液タイプ及び２液タイプ
の何れの場合にも、サーモプラスチックエラストマー樹
脂成形物の表面塗装に要求される、前処理及びプライマ
ーレスでの付着性に問題があり、又、薄膜（１０μ）で
の塗装性能及び意匠効果（シボ再現性，ソフトタッチ
性）に欠けるものであった。However, in the case of such a conventional paint as described above, it is required to coat the surface of the thermoplastic elastomer resin molded product in both the one-pack type and the two-pack type. There was a problem with the pretreatment and adhesion without primer, and the coating performance and design effect (texture reproducibility, soft touch) on a thin film (10 μ) were lacking.
【０００６】本願発明は、このような従来の課題に着目
してなされたもので、サーモプラスチックエラストマー
成形物、特に自動車内装用サーモプラスチックエラスト
マー成形物の塗料として付着性、塗膜性能、意匠性、塗
装作業性と塗装外観を兼ね備えたサーモプラスチックエ
ラストマー成形物用塗料を提供せんとする。The present invention has been made by paying attention to such a conventional problem, and has the following properties: as a coating material for thermoplastic elastomer moldings, especially for automobile interiors, adhesion, coating film performance, designability, We do not provide a coating material for thermoplastic elastomer moldings that has both coating workability and coating appearance.
【０００７】[0007]
【課題を解決するための手段】本願発明は、鋭意研究の
結果、以下の特徴を有するサーモプラスチックエラスト
マー成形物用塗料を提供することにより上記課題を解決
した。本願発明のサーモプラスチックエラストマー成形
物用塗料の主剤の樹脂成分は、イソホロンジイソシアネ
ート、ヘキサメチレンジイソシアネート及び水添メタン
ジイソシアネートよりなる１群中より選択された任意の
一員もしくは数員と、ポリカーボネートポリオールとの
付加重合物（以下本件ウレタンポリオールという）を主
成分とする。又、この塗料の硬化剤の樹脂成分は、脂肪
族系ジイソシアネートの付加重合物を主成分とするもの
である。As a result of earnest research, the present invention has solved the above problems by providing a coating material for a thermoplastic elastomer molding having the following characteristics. The resin component of the main component of the coating material for thermoplastic elastomer moldings of the present invention is the addition of polycarbonate polyol and any one or several members selected from the group consisting of isophorone diisocyanate, hexamethylene diisocyanate and hydrogenated methane diisocyanate. The main component is a polymer (hereinafter referred to as the urethane polyol). Further, the resin component of the curing agent of this paint contains an addition polymer of an aliphatic diisocyanate as a main component.
【０００８】例えば、主剤としてのイソホロンジイソシ
アネートとポリカーボネートポリオールとの付加重合物
は、以下の性状及び特徴を有する。 性状 分子量 １５０００〜２００００ ＯＨ％ ３％以下 酸 価 １以上 一般式 基本骨格For example, an addition polymerization product of isophorone diisocyanate as a main agent and a polycarbonate polyol has the following properties and characteristics. Properties Molecular weight 15000 to 20000 OH% 3% or less Acid value 1 or more General formula Basic skeleton
【０００９】[0009]
【化１】 [Chemical 1]
【００１０】伸び／抗張力 ４００〜５００％／３００
〜４００ｋｇ／ｃｍ2 特徴 結合エネルギーが大きく、伸び／抗張力のバランスがと
れており、塗膜の強度が強い。しかも、付着性に優れて
いる。Elongation / tensile strength 400-500% / 300
~ 400 kg / cm 2 Features High binding energy, well balanced elongation / tensile strength, and strong coating film strength. Moreover, it has excellent adhesion.
【００１１】尚、イソホロンジイソシアネートとヘキサ
メチレンジイソシアネートと水添メタンジイソシアネー
ト中の二種又は、三種の混合系又は、ヘキサメチレンジ
イソシアネート，水添メタンジイソシアネート単独にお
いても、分子量が大きく、結合エネルギーが大きい点で
イソホロンジイソシアネートと同等である。It should be noted that even in the case of a mixed system of two or three kinds of isophorone diisocyanate, hexamethylene diisocyanate and hydrogenated methane diisocyanate, or hexamethylene diisocyanate and hydrogenated methane diisocyanate alone, the molecular weight is large and the binding energy is large. Equivalent to isophorone diisocyanate.
【００１２】主剤成分の配合としては以下の範囲とする
ことが好ましい。 主剤成分の配合 （単位：重量部） 本件ウレタンポリオール １０〜２０ ポリエステルポリオール ５〜２０ カーボンブラック １〜４ 光沢調整剤 ２〜５ 顔料分散剤 ０．１〜１．５ メチルエチルケトン １７〜３０ シクロヘキサノン １７〜３０ キシレン ５〜１１ セルソルブアセテート １〜３ 耐光剤 ０．３〜３The content of the main ingredient is preferably in the following range. Blending of main agent components (unit: parts by weight) Urethane polyol 10-20 Polyester polyol 5-20 Carbon black 1-4 Gloss modifier 2-5 Pigment dispersant 0.1-1.5 Methyl ethyl ketone 17-30 Cyclohexanone 17-30 Xylene 5-11 Cellosolve acetate 1-3 Light resistance agent 0.3-3
【００１３】又、アルコール変性シリコーン（メチルハ
イドロジエンポリシロキサン）での変性を行うことで付
着性をより強くすることができる。この変性シリコーン
の配合割合の範囲としては１〜３重量部（以下配合の単
位を重量部で表す。）とすることが好ましい。Further, the adhesion can be further strengthened by modifying with an alcohol-modified silicone (methylhydrogenpolysiloxane). The range of the compounding ratio of the modified silicone is preferably 1 to 3 parts by weight (hereinafter, the unit of the compounding is represented by parts by weight).
【００１４】更に、上記配合物に表面調整剤としてのポ
リエチワックスを２〜５の割合で混合することにより意
匠性をもたせることができる。Further, by mixing polyethylene wax as a surface conditioner in a ratio of 2 to 5 to the above-mentioned composition, it is possible to impart a design property.
【００１５】一方、硬化剤としての脂肪族系ジイソシア
ネートの付加重合物、例えばヘキサメチレンジイソシア
ネートは以下の性状及び特徴を有する。 性状 ＮＣＯ％ １６〜１７ 特徴 無黄変である。又、良好な乾燥性と付着性を有する。On the other hand, an addition polymerization product of an aliphatic diisocyanate as a curing agent, such as hexamethylene diisocyanate, has the following properties and characteristics. Properties NCO% 16-17 Characteristics It is non-yellowing. Also, it has good dryness and adhesion.
【００１６】尚、硬化剤としてしては、ヘキサメチレン
ジイソシアネートに限らず、例えばキシレンジイソシア
ネート等の無黄変ジイソシアネート等の他の脂肪族系ジ
イソシアネートの付加重合物を用いることも可能であ
る。The curing agent is not limited to hexamethylene diisocyanate, and it is also possible to use addition polymerization products of other aliphatic diisocyanates such as non-yellowing diisocyanates such as xylene diisocyanate.
【００１７】又、希釈用シンナーとして、ケトン、エス
テル、芳香族炭化水素及びグリコールの混合物を主成分
とするものを用いることにより、付着性、塗膜性能、意
匠性、塗装作業性及び塗装外観上記の効果をより向上さ
せることができる。Further, by using, as a diluent thinner, one containing a mixture of a ketone, an ester, an aromatic hydrocarbon and a glycol as a main component, adhesion, coating performance, designability, coating workability and coating appearance are The effect of can be further improved.
【００１８】[0018]
【発明の効果】本願発明においては、主剤の樹脂成分
が、シソホロンジイソシアネート、ヘキサメチレンジイ
ソシアネート及び水添メタンジイソシアネートよりなる
１群中より選択された任意の一員もしくは数員と、ポリ
カーボネートポリオールとの付加重合物を主成分とする
ものであるため、第１にポリマー主結合の結合エネルギ
ーが大であり、第２にその分子量も大（１０．０００以
上）であり、第３に塗膜の強度、即ち、伸び（１００％
以上）と抗張力（２００kg／cm2 以上）とのバランス、
が大きいという特徴がある。従って、サ成形品の変形に
対する追随と薄膜での優れた塗膜性能と成形物の形シボ
再現性を得ることができた。又、この主剤の樹脂成分
は、メチルハイドロジエンポリシロキサンで変性するこ
とにより、サーモプラスチックエラストマー成形物への
より良好な付着性を得ることができた。しかもこれと同
時に、上記の主剤の樹脂成分と共に硬化剤の樹脂成分と
して脂肪族系ジイソシアネートの付加重合物を用いるこ
とにより、目的とする塗膜の性能、作業性、乾燥性、外
観、意匠性等に対する安定性（信頼性）を著しく向上さ
せることが可能となった。INDUSTRIAL APPLICABILITY In the present invention, the resin component of the main component is the addition of polycarbonate polyol and any one or several members selected from the group consisting of shisophorone diisocyanate, hexamethylene diisocyanate and hydrogenated methane diisocyanate. Since the polymer is the main component, firstly the binding energy of the polymer main bond is large, secondly its molecular weight is also large (10.000 or more), and thirdly the strength of the coating film, That is, elongation (100%
Above) and tensile strength (over 200 kg / cm 2 ),
Has the characteristic of being large. Therefore, it was possible to obtain conformity to the deformation of the molded product, excellent coating performance in the thin film, and shape reproducibility of the molded product. Further, by modifying the resin component of this main component with methylhydrogenpolysiloxane, it was possible to obtain better adhesion to the thermoplastic elastomer molded product. Moreover, at the same time, by using the addition polymer of the aliphatic diisocyanate as the resin component of the curing agent together with the resin component of the main component, the performance, workability, drying property, appearance, designability, etc. of the target coating film can be obtained. It has become possible to significantly improve the stability (reliability) with respect to.
【００１９】本願の第２の発明においては、希釈用シン
ナーとして、ケトン、エステル、芳香族炭化水素及びグ
リコールの混合物を主成分とするものを用いることによ
り、上記の効果をより確実に発揮し得るものである。In the second invention of the present application, the above-mentioned effect can be more surely exhibited by using, as the dilution thinner, one having a mixture of ketone, ester, aromatic hydrocarbon and glycol as a main component. It is a thing.
【００２０】以上、本願の両発明に係る塗料は、サ成形
物用塗料に必要な塗膜性能と意匠性を薄膜（１０μ）で
可能にして、さらに前処理及びプライマーを省くことが
可能となった為、自動車内装用を始めとして各種塗装に
使用が可能となったものである。加えて、カラー化も容
易に行えるので、他の成形物との一体感を得ることがで
きる等の優れた意匠効果を出すことができるものであ
る。As described above, the coating materials according to both inventions of the present application enable the coating film performance and the design property required for the coating material for sa molding to be a thin film (10 μm), and further pretreatment and primer can be omitted. Therefore, it has become possible to use it for various coatings including automobile interiors. In addition, since colorization can be easily performed, an excellent design effect such as a sense of unity with other molded products can be obtained.
【００２１】[0021]
【実施例】以下、本願発明の具体的な実施例を説明す
る。先ず、主剤に対し効果剤を加えて良く攪拌混合後、
希釈シンナーを加え更に攪拌し塗料を調節する（粘度１
１〜１３秒、不揮発分１３〜１５％）。これにより得ら
れた実施例１〜４の塗料について主剤、硬化剤、希釈シ
ンナー各々の配合例を下記の表１に示す。EXAMPLES Specific examples of the present invention will be described below. First, the effect agent is added to the main agent, and after thoroughly stirring and mixing,
Add diluted thinner and stir to adjust paint (viscosity 1
1-13 seconds, nonvolatile content 13-15%). With respect to the coating materials of Examples 1 to 4 obtained in this way, Table 1 below shows an example of blending each of the main component, the curing agent, and the diluted thinner.
【００２２】[0022]
【表１】 [Table 1]
【００２３】そして、これら各々の実施例１〜４を下記
の表３に示す条件で配合するとともに、下記の表２に示
す配合例の比較例１〜４各々を下記の表４に示す条件で
配合し、塗装を行う。Each of Examples 1 to 4 was blended under the conditions shown in Table 3 below, and Comparative Examples 1 to 4 of the blending examples shown in Table 2 below were blended under the conditions shown in Table 4 below. Blend and paint.
【００２４】[0024]
【表２】 [Table 2]
【００２５】[0025]
【表３】 [Table 3]
【００２６】[0026]
【表４】 [Table 4]
【００２７】この塗装は、調節した塗料をエアースプレ
ーガン（イワタワイダー７１，口径０．８〜１．３ｍ／
ｍ）を用いて空気圧３〜５ｋｇ／ｃｍ2 、吐出量６０〜
１００ｃｃ／分の条件で成形品表面に所定の膜厚になる
ように塗装を行う。塗装後、室温で２〜５分放置してか
ら、６０〜８０°Ｃで２０〜４０分乾燥を行う。これに
より、成形品表面に皮膜を形成させることができる。For this coating, the adjusted coating is applied with an air spray gun (Iwata winder 71, caliber 0.8 to 1.3 m /
m), air pressure 3 to 5 kg / cm 2 , discharge rate 60 to
Coating is performed on the surface of the molded product under a condition of 100 cc / min so that a predetermined film thickness is obtained. After coating, it is left at room temperature for 2 to 5 minutes and then dried at 60 to 80 ° C for 20 to 40 minutes. As a result, a film can be formed on the surface of the molded product.
【００２８】この結果、本実施例で得られた塗膜の性能
値及び性能評価を表３に、比較例で得られた塗膜の性能
値及び性能評価を表４に夫々示す。以上、表３，表４に
示すように各実施例の塗膜は、比較例に比して付着性，
塗膜性能，外観（意匠性）に優れていることが確認され
た。As a result, the performance value and performance evaluation of the coating film obtained in this example are shown in Table 3, and the performance value and performance evaluation of the coating film obtained in the comparative example are shown in Table 4. As described above, as shown in Tables 3 and 4, the coating films of the respective examples have adhesiveness,
It was confirmed that the coating film performance and appearance (design) were excellent.
Claims (2)
成形品に、前処理及びプライマーを省く１コート系塗料
として用いることのできる塗料において、 この塗料の主剤の樹脂成分が、イソホロンジイソシアネ
ート、ヘキサメチレンジイソシアネート及び水添メタン
ジイソシアネートよりなる１群中より選択された任意の
一員もしくは数員と、ポリカーボネートポリオールとの
付加重合物を主成分とし、 この塗料の硬化剤の樹脂成分が、脂肪族系ジイソシアネ
ートの付加重合物を主成分とするものであることを特徴
とする、 サーモプラスチックエラストマー成形部品用の１コート
系塗料。1. A paint which can be used as a one-coat paint which does not require a pretreatment and a primer on a molded article using a thermoplastic elastomer, wherein the resin component of the main ingredient of this paint is isophorone diisocyanate, hexamethylene diisocyanate and water. The main component is an addition polymerization product of a polycarbonate polyol and any one or several members selected from the group consisting of added methane diisocyanate, and the resin component of the curing agent of this paint is an addition polymerization product of an aliphatic diisocyanate. A one-coat type paint for thermoplastic elastomer molded parts, which is mainly composed of
ナーが、ケトン、エステル、芳香族炭化水素及びグリコ
ールの混合物を主成分とするサーモプラスチックエラス
トマー成形部品用の１コート系塗料。2. The coating composition according to claim 1, wherein the diluent thinner is mainly composed of a mixture of a ketone, an ester, an aromatic hydrocarbon and a glycol, for a thermoplastic elastomer molded part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3274821A JP2893301B2 (en) | 1991-09-25 | 1991-09-25 | Thermoplastic elastomer paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3274821A JP2893301B2 (en) | 1991-09-25 | 1991-09-25 | Thermoplastic elastomer paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0586327A true JPH0586327A (en) | 1993-04-06 |
| JP2893301B2 JP2893301B2 (en) | 1999-05-17 |
Family
ID=17547041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3274821A Expired - Fee Related JP2893301B2 (en) | 1991-09-25 | 1991-09-25 | Thermoplastic elastomer paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2893301B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937399A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Harmful substance adsorbing coating and preparation method thereof |
| CN107892837A (en) * | 2017-11-15 | 2018-04-10 | 惠州市维尔康王漆化工有限公司 | A kind of paint diluent and application suitable for glass fiber reinforced PC composite material base material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01240577A (en) * | 1988-03-22 | 1989-09-26 | Tanabe Kagaku Kogyo Kk | Mold-coating for polyurethane molded article |
-
1991
- 1991-09-25 JP JP3274821A patent/JP2893301B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01240577A (en) * | 1988-03-22 | 1989-09-26 | Tanabe Kagaku Kogyo Kk | Mold-coating for polyurethane molded article |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937399A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Harmful substance adsorbing coating and preparation method thereof |
| CN107892837A (en) * | 2017-11-15 | 2018-04-10 | 惠州市维尔康王漆化工有限公司 | A kind of paint diluent and application suitable for glass fiber reinforced PC composite material base material |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2893301B2 (en) | 1999-05-17 |
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