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JPH0581528B2 - - Google Patents

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Publication number
JPH0581528B2
JPH0581528B2 JP1085784A JP8578489A JPH0581528B2 JP H0581528 B2 JPH0581528 B2 JP H0581528B2 JP 1085784 A JP1085784 A JP 1085784A JP 8578489 A JP8578489 A JP 8578489A JP H0581528 B2 JPH0581528 B2 JP H0581528B2
Authority
JP
Japan
Prior art keywords
salt
potassium chloride
mixed salt
seasoning
cooling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP1085784A
Other languages
Japanese (ja)
Other versions
JPH02267117A (en
Inventor
Satoru Kondo
Haya Yonekura
Shusuke Yano
Shigeru Nomi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tateho Chemical Industries Co Ltd
Original Assignee
Tateho Chemical Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tateho Chemical Industries Co Ltd filed Critical Tateho Chemical Industries Co Ltd
Priority to JP1085784A priority Critical patent/JPH02267117A/en
Publication of JPH02267117A publication Critical patent/JPH02267117A/en
Publication of JPH0581528B2 publication Critical patent/JPH0581528B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は塩化カリウムを主成分とする天然調味
料に関し、詳しくは、食塩含量が低く、塩化カリ
ウムを主成分とし、その他の海水中の塩類を含
み、若干の苦味はあるが、塩の辛味と旨味を有
し、貯蔵および保存において固結するこがなく、
使い易い粉末状の天然調味料に関する。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a natural seasoning containing potassium chloride as a main component, and more specifically, to a natural seasoning containing potassium chloride as a main component, containing potassium chloride as a main component, and other salts in seawater. Although it has a slight bitterness, it has the spiciness and flavor of salt, and does not solidify during storage and storage.
This invention relates to an easy-to-use powdered natural seasoning.

本発明による天然調味料は、食塩の代わりに使
用することができ、調理および食卓用の調味料と
して利用することができるだけでなく、また漬物
および食塩の塩蔵に利用することができる。
The natural seasoning according to the present invention can be used in place of common salt, and can be used not only as a seasoning for cooking and table use, but also for salting pickles and salt.

〔技術の背景および従来技術の説明〕[Technical background and explanation of conventional technology]

食塩(NaCl)は、調理または食卓用の調味料、
漬物の製造および塩蔵品の製造に古くから利用さ
れているが、科学的に純粋な塩化ナトリウムより
も、古くから伝わる天日製造法により海水からつ
くられた食塩であつて、科学的には粗製食塩とい
うべき食塩が調味料または漬物の生産に好まれる
ことが多い。
Salt (NaCl) is a seasoning for cooking or table use,
Although it has been used for a long time in the production of pickles and salted products, it is a salt made from seawater using an ancient solar manufacturing method, and is scientifically considered crude salt rather than scientifically pure sodium chloride. Common salt, or common salt, is often preferred for the production of seasonings or pickles.

またマグネシウムは、植物の生育に必要な元素
であつて、水酸化マグネシウムまたは炭酸マグネ
シウムを肥料として利用するが、海水から生産し
た水酸化マグネシウムまたは炭酸マグネシウム
は、実用的な肥料として好まれる場合が多い。さ
らに海水から食塩を取り出した母液から塩化マグ
ネシウムを主成分とするニガリは、豆腐の生産に
おいて使用されている。
Magnesium is also an element necessary for plant growth, and magnesium hydroxide or magnesium carbonate is used as fertilizer, but magnesium hydroxide or magnesium carbonate produced from seawater is often preferred as a practical fertilizer. . Furthermore, bittern, which contains magnesium chloride as a main component from the mother liquor obtained by extracting salt from seawater, is used in the production of tofu.

塩分の過剰摂取は高血圧の原因の一つといわれ
ており、塩分含量を低減した減塩味噌および減塩
醤油が健康食品として市販され、また食塩におけ
る塩化ナトリウム(NaCl)の一部を塩化カリウ
ム(KCl)に置換した塩代用品も市販され、さら
に塩化ナトリウムおよび塩化カリウムの混合塩に
粉末固形苦汁を加えて、塩化カリウムの有する苦
味を軽減した低ナトリウム塩調味料が提案され
(特公昭64−18号公報)、さらにまた、うどん、中
華麺、そば、その他の小麦粉製品の製造に塩化カ
リウムまたは塩化カリウムと塩化ナトリウムの混
合物を使用して、小麦製品の歯ごたえ、コシ、舌
触りおよび艶などの品質を向上することが提案さ
れている(特公昭63−57023号公報)。
Excessive salt intake is said to be one of the causes of high blood pressure. Low-salt miso and low-salt soy sauce with reduced salt content are commercially available as health foods, and some of the sodium chloride (NaCl) in table salt is replaced with potassium chloride (KCl). ) was also commercially available, and a low-sodium salt seasoning was proposed in which the bitterness of potassium chloride was reduced by adding powdered solid bittern to a mixed salt of sodium chloride and potassium chloride. Furthermore, potassium chloride or a mixture of potassium chloride and sodium chloride is used in the production of udon, Chinese noodles, soba, and other flour products to improve the chewiness, body, texture, and luster of wheat products. It has been proposed to improve this (Special Publication No. 63-57023).

また海水から食塩(NaCl)および硫酸カルシ
ウム(CaSO4・2H2O)を除去したカン水に石灰
乳または苛性アルカリ液を加えて、生成した水酸
化マグネシウムをガン予防の体質強化剤として利
用することが提案されている(特開昭52−136924
号公報)。
Additionally, lime milk or caustic alkaline solution is added to water from which salt (NaCl) and calcium sulfate (CaSO 4 2H 2 O) have been removed from seawater, and the magnesium hydroxide produced can be used as a body-strengthening agent to prevent cancer. has been proposed (Japanese Patent Application Laid-Open No. 52-136924
Publication No.).

さらに地球上の動物および植物のすべての生物
は、海にその起源があるといわれていて、海水中
に微量に含まれる元素に、生物の生育に必要な元
素(マグネシウム、ホウ素など)があることもよ
く知られていることである。
Furthermore, all animal and plant life on Earth is said to have originated from the sea, and the elements (magnesium, boron, etc.) necessary for the growth of living things are found in trace amounts in seawater. is also well known.

本発明者らは、製塩事業に永年従事している
が、その業務において、脱塩カン水(海水の濃縮
液から食塩を取り出した残りの母液)から石膏を
主体とする結晶を除去した後の上澄液から析出し
た塩化カリウムを主体とする結晶塩は、若干の苦
味はあつても、薄い塩辛さと旨味のあることを知
見し、またその塩化カリウムを主体とする結晶塩
を風乾したものは、粉末の流動性を保持してお
り、その貯蔵および輸送において固結することが
なく、使い易い粉末状を維持しうることを知見
し、これらの知見に基づいて本発明に到達した。
The present inventors have been engaged in the salt manufacturing business for many years. It was discovered that the crystalline salt mainly composed of potassium chloride precipitated from the supernatant liquid has a slightly bitter taste, but has a slightly salty and umami taste, and the air-dried crystalline salt mainly composed of potassium chloride is It was discovered that the powder maintains its fluidity, does not clump during storage and transportation, and can maintain an easy-to-use powder form.Based on these findings, the present invention was achieved.

〔発明の目的および発明の要約〕[Object of the invention and summary of the invention]

本発明の目的は、塩化カリウムを主成分とし、
若干の苦味はあるが、塩の辛味と旨味のある調味
料を提供することにあり、詳しくは、塩化カリウ
ムを主成分とし、若干の苦味はあるが塩の辛味と
旨味があり、また固結することがなく、使い易い
調味料の製造法を提供することにある。
The purpose of the present invention is to use potassium chloride as a main component,
Our objective is to provide a seasoning that has the spiciness and umami of salt, although it has a slight bitterness.More specifically, we provide a seasoning that has potassium chloride as its main ingredient, has a slight bitterness, but has the spiciness and umami of salt, and is solidified. To provide a method for producing seasonings that is easy to use and requires no additional steps.

本発明は、脱塩カン水を55〜42℃に冷却し、析
出する硫酸カルシウムを主体とする結晶縁煙を分
離除去すること、その上澄み液を20℃以下に冷却
して、塩化カリウム混在塩を分離すること、およ
びその塩化カリウム混在塩をその温度を上げるこ
となく、常温において、風乾して、粉末の流動性
を保持する塩化カリウム混在塩を得ることを特徴
とするアルカリ性塩化カリウム混在塩調味料の製
造法である。
The present invention involves cooling desalinated water to 55 to 42°C, separating and removing precipitated crystal fringe smoke mainly composed of calcium sulfate, and cooling the supernatant liquid to 20°C or lower to remove salts mixed with potassium chloride. An alkaline potassium chloride mixed salt seasoning characterized by separating the potassium chloride mixed salt and air-drying the potassium chloride mixed salt at room temperature without raising the temperature to obtain a potassium chloride mixed salt that maintains the fluidity of the powder. This is a method of manufacturing food.

〔発明の具体的な説明〕[Specific description of the invention]

本発明の塩化カリウム混在調味料の製造におけ
る脱塩カン水は、海水を濃縮し、析出する食塩を
分離除去した後に残つた母液であるが、海水をイ
オン交換樹脂膜処理により海水の食塩(NaCl)
濃度を上昇し、その食塩濃度の上昇した処理液を
加熱、蒸発、濃縮して、析出する食塩を分離除去
した後に残つた母液を使用するのが好ましい。
Desalinated Kansui in the production of the potassium chloride mixed seasoning of the present invention is the mother liquor that remains after concentrating seawater and separating and removing precipitated common salt. )
It is preferable to increase the concentration, heat, evaporate, and concentrate the treated solution with the increased salt concentration, and use the mother liquor remaining after separating and removing the precipitated salt.

本発明の塩化カリウム混在塩調味料の製造にお
いて、脱塩カン水を55〜42℃に冷却して、析出す
る硫酸カルシウムを主体とする結晶塩を分離除去
した後、その上澄濾液をさらに20℃以下に冷却し
て、析出する塩化カリウム混在塩を分離除去する
が、硫酸カルシウムを主体とする結晶塩の分離お
よび塩化カリウム混在塩の分離は、遠心分離によ
つて行うのが好ましい。脱塩カン水の冷却は55〜
42℃にすることによつて行われるが、その冷却温
度が55℃以上であると、硫酸カルシウムの除去が
充分でなく、またその冷却温度が42℃以下である
と、塩化カリウムが硫酸カルシウムといつしよに
析出して、塩化カリウムの取得量が低下する。ま
た硫酸カルシウムを主体とする結晶塩の分離除去
後の上澄濾液の冷却は20℃以下において行われる
が、その冷却は20〜15℃において行うことが好ま
しく、その冷却温度が20℃以上であると、塩化カ
リウムの取得量が低下する。
In the production of the potassium chloride mixed salt seasoning of the present invention, after cooling the desalted canned water to 55 to 42°C and separating and removing precipitated crystalline salts mainly composed of calcium sulfate, the supernatant filtrate is further added to The precipitated potassium chloride mixed salt is separated and removed by cooling to a temperature below .degree. C., but it is preferable to separate the crystalline salt mainly composed of calcium sulfate and the potassium chloride mixed salt by centrifugation. Cooling of desalinated water is 55~
However, if the cooling temperature is 55°C or higher, the removal of calcium sulfate will not be sufficient, and if the cooling temperature is 42°C or lower, potassium chloride will be converted to calcium sulfate. Precipitation occurs over time, reducing the amount of potassium chloride obtained. In addition, the supernatant filtrate after separation and removal of crystalline salts mainly composed of calcium sulfate is cooled at a temperature of 20°C or lower, but it is preferable that the cooling is performed at a temperature of 20 to 15°C, and the cooling temperature is 20°C or higher. , the amount of potassium chloride obtained decreases.

遠心分離により分離取得した塩化カリウム混在
塩の風乾は、塩化カリウム混在塩の温度を上昇す
ることなく、常温において行うことを必要とす
る。塩化カリウム混在塩の乾燥を熱風により行
い、塩化カリウム混在塩の温度を上昇すると、塩
化カリウム混在塩の乾燥物が固結し、塊状の塩化
カリウム混在塩となる。これは、温度の上昇によ
つて塩化カリウム混在塩に含まれる塩化カリウム
以外の塩の含水塩が無水塩に変化し、その変化の
時に固結すると考えられる。
Air drying of the salt mixed with potassium chloride separated and obtained by centrifugation needs to be carried out at room temperature without increasing the temperature of the salt mixed with potassium chloride. When the potassium chloride mixed salt is dried with hot air and the temperature of the potassium chloride mixed salt is increased, the dried potassium chloride mixed salt solidifies and becomes a lumpy potassium chloride mixed salt. This is because the hydrated salts other than potassium chloride contained in the potassium chloride-mixed salt change to anhydrous salts due to the rise in temperature, and it is thought that they solidify at the time of this change.

常温において風乾した塩化カリウム混在塩は、
粉末の流動性を保持していて、そのままの状態で
は固結することがない。この塩化カリウム混在塩
は、塩化カリウムを主成分とし、その元素の分析
値から、食塩、塩化マグネシウム、リン酸塩、鉄
塩およびそれ以外の海水の塩類の少量を含むと考
えられ、調味料および食塩と同様の用途に使用す
ることができるが、若干の苦味を感じるが、塩の
辛味と旨味のある調味料として使用することがで
きる。
Potassium chloride mixed salt air-dried at room temperature is
It maintains the fluidity of powder and does not solidify in its original state. This potassium chloride mixed salt has potassium chloride as its main component, and is thought to contain small amounts of common salt, magnesium chloride, phosphates, iron salts, and other seawater salts based on the elemental analysis values, and is used as a seasoning and It can be used in the same way as table salt, but although it has a slightly bitter taste, it can be used as a seasoning with the spiciness and flavor of salt.

この塩化カリウム混在塩の調味料は、その温度
を上昇することがなければ、その輸送および保存
において固結することがなく、粉末の流動性を保
持していて、使い易いものであるが、これはその
塩化カリウム混在塩に含まれる塩化カリウム以外
の塩類が結晶水を保持した安定な結晶を維持して
いると考えられる。
This potassium chloride mixed salt seasoning does not solidify during transportation and storage without increasing its temperature, retains the fluidity of a powder, and is easy to use. It is thought that salts other than potassium chloride contained in the potassium chloride mixed salt maintain stable crystals that retain crystal water.

以下において、実施例により本発明をさらに詳
しく説明する。
In the following, the invention will be explained in more detail by means of examples.

実施例 海水を濾過して、浮遊物を除去した後、その清
澄海水3394Kl/時を製塩用イオン交換樹脂膜処理
装置(設備容量:54445−対/m2)に送り、2.97
アンペア/dm2の電流密度においてその清澄海水
を濃縮し、カン水(NaCl濃度:188.3g/)
136.6Kl/時を得た。そのカン水を真空式四重効
用蒸発装置に送り、濃縮して、NaClを析出させ、
そのスラリーを遠心分離して、NaCl124.92ト
ン/時に分離した。
Example After filtering seawater and removing suspended matter, 3394 Kl/hour of the clear seawater is sent to an ion exchange resin membrane treatment device for salt production (equipment capacity: 54445 pairs/m 2 ), and 2.97
Concentrate the clear seawater at a current density of Ampere/dm 2 to obtain Kansui (NaCl concentration: 188.3g/).
136.6Kl/hour was obtained. The water is sent to a vacuum quadruple effect evaporator to concentrate and precipitate NaCl.
The slurry was centrifuged to separate 124.92 tons/hour of NaCl.

真空式四重効用蒸発装置の第2段目の苦汁缶か
ら90℃の苦汁〔比重(ボーメ):31.5(49℃)、マ
グネシウム濃度:126.5g/Kg(MgCl2)〕7.9Kl/
時を排出し、その苦汁を苦汁放冷槽に送り、自然
放冷と同時に析出した石膏を主体とする結晶の自
然沈降を行つた。50℃において上澄液を苦汁放冷
槽から取り出し、塩化カリウム析出槽に送り、さ
らに自然放冷して、KCl混合塩を析出させた。20
℃において、そのスラリーを遠心分離して、KCl
混合塩3500Kg/日を得た。
Bittern at 90℃ from the second stage of the vacuum quadruple effect evaporator [specific gravity (Baume): 31.5 (49℃), magnesium concentration: 126.5g/Kg (MgCl 2 )] 7.9Kl/
After draining the bittern, the bittern was sent to a bittern cooling tank, and at the same time as it was allowed to cool naturally, the precipitated crystals, mainly composed of gypsum, were allowed to settle naturally. The supernatant liquid was taken out from the bittern cooling tank at 50°C, sent to a potassium chloride precipitation tank, and further allowed to cool naturally to precipitate a KCl mixed salt. 20
At °C, centrifuge the slurry and add KCl.
3500 kg/day of mixed salt was obtained.

そのKCl混合塩を風乾して、KCl混合塩粉末
3395Kg/日を得た。
Air-dry the KCl mixed salt to form KCl mixed salt powder.
Obtained 3395Kg/day.

このKCl混合塩を、水分:2.2%、カルシウ
ム:0.54%、ナトリウム:8.45%、カリウム:
39.4%、マグネシウム:0.42%、塩素:48.3%、
鉄:40.5ppm、リン酸:226ppm、ケイ素:
21ppmの分析値を有していたが、ヒ素、カドミウ
ム、水銀、スズ、コバルトおよびセレンは検出せ
ず、固結せずに、粉末の流動性を保持していた。
This KCl mixed salt is water: 2.2%, calcium: 0.54%, sodium: 8.45%, potassium:
39.4%, Magnesium: 0.42%, Chlorine: 48.3%,
Iron: 40.5ppm, Phosphoric acid: 226ppm, Silicon:
Although it had an analysis value of 21 ppm, arsenic, cadmium, mercury, tin, cobalt, and selenium were not detected, and the powder maintained its fluidity without caking.

〔発明の効果〕〔Effect of the invention〕

若干の苦味はあるが、適度の塩の辛味と旨味が
あり、食塩の代替として使用することができる。
Although it has a slightly bitter taste, it has the spiciness and flavor of salt, and can be used as a substitute for table salt.

その輸送および保存において、固結することが
なく、粉末の流動性を保持していて、使い易い粉
末状を維持することができる。
During transportation and storage, the powder does not clump and maintains its fluidity, making it possible to maintain an easy-to-use powder form.

Claims (1)

【特許請求の範囲】[Claims] 1 脱塩カン水を55〜42℃に冷却し、析出する硫
酸カルシウムを分離除去すること、その上澄み液
を20℃以下に冷却し、析出する塩化カリウム混在
塩を分離すること、およびその塩化カリウム混在
塩を風乾することを特徴とするアルカリ性塩化カ
リウム混在塩調味料の製造法。
1. Cooling the desalinated water to 55-42°C and separating and removing the precipitated calcium sulfate, cooling the supernatant liquid to 20°C or lower and separating the precipitated potassium chloride mixed salt, and the potassium chloride. A method for producing an alkaline potassium chloride mixed salt seasoning characterized by air-drying the mixed salt.
JP1085784A 1989-04-06 1989-04-06 Production of salty seasoning blended with alkaline potassium chloride Granted JPH02267117A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1085784A JPH02267117A (en) 1989-04-06 1989-04-06 Production of salty seasoning blended with alkaline potassium chloride

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1085784A JPH02267117A (en) 1989-04-06 1989-04-06 Production of salty seasoning blended with alkaline potassium chloride

Publications (2)

Publication Number Publication Date
JPH02267117A JPH02267117A (en) 1990-10-31
JPH0581528B2 true JPH0581528B2 (en) 1993-11-15

Family

ID=13868513

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1085784A Granted JPH02267117A (en) 1989-04-06 1989-04-06 Production of salty seasoning blended with alkaline potassium chloride

Country Status (1)

Country Link
JP (1) JPH02267117A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7208189B2 (en) * 2004-04-06 2007-04-24 Council Of Scientific And Industrial Research Low sodium salt of botanic origin
JP2007290927A (en) * 2006-04-26 2007-11-08 Aoi Umi:Kk Method for producing bittern, salt obtained in the production method, and salt having low sodium content obtained by using the salt
KR100732066B1 (en) * 2006-07-25 2007-06-25 (주)블루오션월드 Efficient Extraction of High Purity Minerals from Deep Sea Water by Low Temperature Vacuum Crystallization
CN103449478A (en) * 2013-08-26 2013-12-18 中盐制盐工程技术研究院 Comprehensive utilization and production method of underground potassium chloride-rich brine
CN104172091B (en) * 2014-07-03 2016-10-05 叶卫斌 A kind of production technology of the edible salt containing water-soluble silicon

Also Published As

Publication number Publication date
JPH02267117A (en) 1990-10-31

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