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JPH04187603A - Scattering composition - Google Patents

Scattering composition

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Publication number
JPH04187603A
JPH04187603A JP31970990A JP31970990A JPH04187603A JP H04187603 A JPH04187603 A JP H04187603A JP 31970990 A JP31970990 A JP 31970990A JP 31970990 A JP31970990 A JP 31970990A JP H04187603 A JPH04187603 A JP H04187603A
Authority
JP
Japan
Prior art keywords
specific gravity
particles
composition
carrier
scattering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP31970990A
Other languages
Japanese (ja)
Other versions
JP3039984B2 (en
Inventor
Mototada Matsushima
松島 資忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SAN GREEN SHOJI KK
Original Assignee
SAN GREEN SHOJI KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAN GREEN SHOJI KK filed Critical SAN GREEN SHOJI KK
Priority to JP2319709A priority Critical patent/JP3039984B2/en
Publication of JPH04187603A publication Critical patent/JPH04187603A/en
Application granted granted Critical
Publication of JP3039984B2 publication Critical patent/JP3039984B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To obtain a composition not being scattered with ordinary wind by supporting an applicable material such as deoxidant, deodorant, fungicide, agricultural chemicals or fertilizer on a granular carrier comprising particles having low specific gravity such as burnt diatomaceous granules and granules having high specific gravity such as hard zeolite. CONSTITUTION:An applying composition obtained by supporting deoxidant, deodorant, agricultural chemicals or fertilizer on a granular carrier comprising a mixture of particles having low specific gravity and granules having high specific gravity in a ratio of 70:30-50:50. The size of the carrier is such a macroscopic size (0.5-2mm) as not to be scattered with ordinary wind, the particles having low specific gravity has <0.8 bulk density and further addition of <=20% extremely light granular carrier (e.g. pulp powder) having <0.2 bulk density can more average density in scattering. The composition is suitable for scattering on small scale by hand application, scattering people have no fear of inhalation and scattering density can be relatively uniformed.

Description

【発明の詳細な説明】[Detailed description of the invention] 【発明の目的】[Purpose of the invention]

[産業上の利用分野] 本発明は、散布用の脱酸素剤、脱臭剤、防腐剤、殺菌剤
、農薬又は肥料などの組成物に関する。 [従来の技術] 従来の散布用の粉末農薬は、タルク、炭酸カルシウム、
石膏等の多孔質担体に吸着させた状態で散粉機でく大規
模にはヘリコプタ−から)散布するのが普通である。こ
の方法は省力的に有効ではあるが、散布者が中毒したり
、風で予定地外へ飛散して環境公害を起こしたりする懸
念を払拭できない。 これに反し、手撒きは比較的安全な方法である −が、
作業に労力がかかり、その上、散布を均一に行い難いと
いう欠点を持っている。 [発明が解決しようとする課題] そこで本発明が解決しようとする課題は、主として脱酸
素剤、脱臭剤、防腐剤、殺菌剤、農薬又は肥料などの手
撒きによる小規模な散布に適し、散布時に散布者が吸い
込む恐れかなく、しがも散布密度を比較的均一化するこ
とができる散布用の組成物を提供することである。
[Industrial Application Field] The present invention relates to compositions for spraying such as oxygen scavengers, deodorizers, preservatives, fungicides, agricultural chemicals, or fertilizers. [Conventional technology] Conventional powdered pesticides for spraying include talc, calcium carbonate,
It is usually adsorbed onto a porous carrier such as gypsum and then dispersed using a powder duster (or, on a large scale, from a helicopter). Although this method is labor-saving and effective, it does not eliminate concerns that the sprayer may be poisoned or the spray may be blown away by the wind and cause environmental pollution. On the other hand, hand-spreading is a relatively safe method.
It is labor intensive and has the disadvantage that it is difficult to spray uniformly. [Problems to be Solved by the Invention] Therefore, the problems to be solved by the present invention are mainly suitable for small-scale manual spraying of oxygen absorbers, deodorizers, preservatives, fungicides, agricultural chemicals, fertilizers, etc. It is an object of the present invention to provide a composition for spraying that can make the spraying density relatively uniform without the risk of being inhaled by a sprayer.

【発明の構成】[Structure of the invention]

二課題を解決するための手段] (1)概念 本発明者は、脱臭剤、防腐剤、農藁、肥料なとの手撒散
布に係る上記課題の解決、即ち、散布時に風により吹き
飛ばされず、しかも手撒きにより簡単に平均的な散布を
可能とする散布剤の組成につき検討を加えた結果、本発
明に到達した。 (2)概要 即ち、本発明は、通常の風では飛散しない程度の巨視的
な大きさの、被散布物を担持している粒状担体からなる
組成物であって、該粒状担体は、少なくとも二種の小比
重粒子と大比重粒子とからなることを特徴とする散布用
組成物を要旨とするものである。 以下、発明を構成する諸要素等につき項分けして説明す
る。 (31粒状担体の種類 本発明において粒状担体というのは、下記被散布物等の
担持に適した、がなりの比表面積を持つ巨視的な粒状の
物質を意味する7典型的な粒状担体の例としては、例え
は焼結アルミナ、シリカケル、パーライト、赤玉土、焼
成セオライ1〜又は計成ゼオライト、粒状膨張スラグ、
銅がらみ、粗砕コークス、パルプ粉、活性炭、木炭粒等
の人工粒状物の他、バーミキュライト、即粒化クレイ、
ケイソウ藻土若しくはヘントナイト、軽石粗砕物、麦飯
石粗粒、粗砕溶岩、粗砕バルク若しくはピートモス、籾
殻くん炭、鋸屑なとの天然物由来の多孔質粒体が例示さ
れる。 (4)粒状担体の大きさ及び嵩比重 発明の目的上、上記粒状担体は、少なくとも二種以上混
合して使用される。第一の担体は、比重が比較的小さい
種類のものである。次に第二の担体は、逆に比重の大き
いものである。−船釣には、小比重粒子は、大比重粒子
よりも粒径が大であることが好ましい。 これら粒体の大きさは、散布時に存在しうる通常の風で
は吹き飛はされない程度の巨視的な大きさであるべきで
、−船釣には、径0.5〜2mm程度の大きさのものか
ら選択される。 更に、粒体の比重を絶対的に規定するのは困難であるか
、第一の粒体は嵩密度1未満、好ましくは0.8未満の
ものが好ましい。しかし嵩密度02未満のような超軽質
粒子は、微風でさえも飛散する恐れがあるので、多量成
分用には不向きである。 上記各種粒状担体を嵩密度1.0及び0.2を目安に分
類すると下記の通りである。 嵩密度1.0以上(重質粒状担体);焼結アルミナ、焼
成ゼオライト、合成ゼオライト、銅からみ。 嵩密度1.0未満(軽質粒状担体)ニジリカゲル、パー
ライト、赤玉土、焼成ゼオライト又は合成ゼオライト、
粒状膨張スラグ、粗砕コークス、活性炭、バーミキュラ
イト、顆粒(ヒフレイ、ケイソウ藻土若しくはヘシトナ
イ1〜、軽石粗砕物、麦飯石粗粒、粗砕溶岩、木炭粒。 嵩密度0.2未満(超軽質粒状担体) パルプ粉、粗砕
バルク若しくはピートモス、籾殻くん炭、鋸屑。 (5)  配合 上記重質粒状担体と軽質担体く及び要すれは超軽質担体
)は、後記被散布物を担持した状態で適宜の割合に配合
される。この際の配合比率は、担体の嵩密度及び粒度に
応して適宜決定されるか、−船釣には30ニア0〜50
:50の範囲で配合される。 なお超軽質の担体を少量(20%以内)配合すると、散
布時の密度をより平均化することができる。 所望により担体を着色してその色彩を変化させることに
より(勿論担体自体の色彩か異なるときはそのまま)、
散布密度の均等性を肉眼で確かめることができる。 (6)被散布物 本発明の粒状担体に担持さるj\き被散布物としては、
例えは脱酸素剤、農薬(殺菌剤、殺虫剤、植物成長制御
剤等)、肥料等を例示できるか、固よりこれらに限るも
のてはない。なお、ナタネ、コマ、タバコ、シバ、ラン
のような小型の種子を平均的に散布したい場合も本発明
を利用できる。 以上の被散布物は、被散布物の性質、特性等に応して、
溶液、懸濁液、微粉状又はそのままの形態で上記担体と
混合され、必要に応じ乾燥せしめられる。被散布物か種
子のような比較的大型の物であるときは、必要に応し担
体に対し確実に付着させる目的で少量の糊料が添加され
てもよい。 [作用] 本発明に係る散布剤では、重質の粒状担体と軽質の粒状
担体とか混在しているので、これを散布すると、重質の
担体は狭い範囲内に落下し、軽質の担体はより広い範囲
内に落下する。特に散布口が点状である場合、重質の担
体は、主として法面が水平面(被散布面)に対して急傾
斜した円錐状に落下するが、軽質の担体は、主として法
面か緩く傾斜した円錐状に落下するから、前者の散布面
(円錐の底面)は後者の散布面より直径か大きくなる。 従って、二種の担体の粒径及び密度か適当てあれば、散
布域に関し平均的な密度分布が得られる。組成物を構成
する担体の密度かより多様てあれば、より平均的な散布
密度か得られる。なお、以上の散布効果は、例えは振り
掛けのように、剤を狭い散布口から振り出した場合に最
も良く発揮されるが、手で握って撒いた場合ても略々間
等の効果を期待できる。 [実施例] 以下、実施例により発明実施の態様を説明するか、例示
は単に説明用のもので、発明思想の制限又は限定を意味
するものではない。 製造例 焼成硬質ゼオライト(平均粒径Q、 5〜L 5 ”/
ゎ。 平均嵩密度的1.4>100重量部(以下同じ)と焼成
ケイソウ土(平均粒径1.0”/、、平均嵩密度的0.
8)100部とを小型コンクリートミキサーで緊密に混
合した。この際、アスコルビン酸1100pp及び微粒
鉄214ppmを含む水溶液4 t)Q部を徐々に散布
し、完全に混合酸、攪拌しつつ熱風で乾燥させなること
により、散布用粒状脱臭剤組成物約201〕部を得た。 使用例1 製造例の組成物を、内径2 ml、、の小孔を有する紙
カートンに入れ、生後約4月の仔猫(在来種。 ♂2体重約2.2kg)がトイレとして常用している園
芸用土(°゛花の土′°として市販されている混合培養
土)を入れたプランタ−に毎朝上全体をスコップで5回
つつ切り返し、最後に切り返しを終わった土の表面に上
記組成物を土の表面に薄く散在する程度に平均的に散布
する操作を反復した。なお、糞便は予めスコップて除去
した。 新鮮な土を入れた実験開始日(10月1日)から7日後
より、最初の切り返しの際アンモニア臭を感しるように
なったが、切り返しと上記組成物の散布により消失し、
実験開始から1月を経過しても、土の表面から約5cm
の深さでも殆どアンモニア臭を検知できなかった。 因に本実験期間中の平均最高温度は約22℃で、上記組
成物か存在しないとすれば土壌微生物か尿中の尿素や尿
酸をアンモニアに還元するのに充分な温度であった。な
お、実験後の土壌は充分な量の硝酸塩類を含み、花弁、
野菜用の培養土として好適である。 使用例2 上記製造例の組成物を、8月始めから毎日ポリ袋に生ゴ
ミを投入する都度Logづつ投入、散布する操作を7日
間続けた。対照として、全く上記組成物を投入しない対
照区を設けた。 上記組成物を投入した試験区の生ゴミ袋は、7日後も殆
ど異臭を生じなかったが、対照区では2日後より異臭を
生じるようになり、3日後に異臭が著しくなったので実
験を中止した。
Means for Solving the Two Problems] (1) Concept The present inventor has solved the above problems related to the manual spreading of deodorizers, preservatives, agricultural straw, fertilizers, etc. Moreover, as a result of studying the composition of a spraying agent that can be easily and evenly distributed by hand, the present invention has been arrived at. (2) Overview That is, the present invention is a composition comprising a granular carrier supporting a material to be dispersed and having a macroscopic size that is not blown away by ordinary wind, the granular carrier comprising at least two particles. The gist of the present invention is a composition for dispersion characterized by comprising small specific gravity particles and large specific gravity particles of seeds. Hereinafter, various elements constituting the invention will be explained in terms of sections. (31 Types of granular carriers In the present invention, granular carriers refer to macroscopic granular substances with a specific surface area that are suitable for supporting the following substances to be sprayed, etc.) 7 Typical examples of granular carriers For example, sintered alumina, silica gel, pearlite, Akadama clay, calcined zeolite 1 or calcined zeolite, granular expanded slag,
In addition to artificial granules such as copper, coarsely crushed coke, pulp powder, activated carbon, and charcoal particles, vermiculite, ready-to-grain clay,
Examples include porous particles derived from natural products such as diatomaceous earth or hentonite, crushed pumice, coarse grains of maifanite, crushed lava, coarsely crushed bulk or peat moss, rice husk charcoal, and sawdust. (4) Size and bulk specific gravity of granular carrier For the purpose of the invention, at least two or more of the above granular carriers are used as a mixture. The first carrier is of a type having a relatively low specific gravity. The second carrier, on the contrary, has a high specific gravity. - For boat fishing, it is preferable that the small specific gravity particles have a larger particle size than the large specific gravity particles. The size of these particles should be macroscopic enough that they will not be blown away by normal winds that may be present during dispersion; selected from things. Furthermore, it is difficult to absolutely define the specific gravity of the granules, or the first granules preferably have a bulk density of less than 1, preferably less than 0.8. However, ultra-light particles with a bulk density of less than 02 may be blown away even by a slight breeze, so they are not suitable for use with large amounts of components. The various granular carriers mentioned above are classified as follows based on the bulk density of 1.0 and 0.2. Bulk density 1.0 or more (heavy granular carrier); sintered alumina, calcined zeolite, synthetic zeolite, copper entangled. Bulk density less than 1.0 (light granular carrier) Nijirica gel, perlite, Akadama soil, calcined zeolite or synthetic zeolite,
Granular expanded slag, coarsely crushed coke, activated carbon, vermiculite, granules (Hifurei, diatomaceous earth or hesitone 1~, crushed pumice, coarse grains of maifanite, coarsely crushed lava, charcoal grains. Bulk density less than 0.2 (ultra light granules) Carrier) Pulp powder, coarsely crushed bulk or peat moss, rice husk charcoal, sawdust. (5) Combination The above-mentioned heavy granular carrier and light carrier (and optionally ultra-light carrier) may be mixed as appropriate while supporting the material to be sprayed as described below. It is blended in the proportion of The blending ratio at this time may be appropriately determined depending on the bulk density and particle size of the carrier;
: It is blended in the range of 50. By adding a small amount (within 20%) of an ultra-light carrier, the density at the time of dispersion can be more evened out. By coloring the carrier to change its color as desired (of course, if the color of the carrier itself is different, leave it as is),
The uniformity of the distribution density can be confirmed with the naked eye. (6) Spreading material The material to be spread carried on the granular carrier of the present invention includes:
Examples include, but are not limited to, oxygen scavengers, agricultural chemicals (bactericides, insecticides, plant growth regulators, etc.), fertilizers, etc. Note that the present invention can also be used when it is desired to uniformly disperse small seeds such as rapeseed, top, tobacco, grass, and orchid. The above-mentioned materials to be spread are determined according to the nature and characteristics of the materials to be
It is mixed with the above carrier in the form of a solution, suspension, fine powder, or as it is, and dried if necessary. When the object to be dispersed is a relatively large object such as a seed, a small amount of glue may be added, if necessary, for the purpose of ensuring reliable adhesion to the carrier. [Function] In the spraying agent according to the present invention, heavy granular carriers and light granular carriers are mixed, so when this is sprayed, the heavy carriers fall within a narrow range, and the lighter carriers fall into a smaller area. Fall within a wide range. In particular, when the spray opening is point-shaped, heavy carriers mainly fall in a conical shape with a steeply sloped slope relative to the horizontal plane (spreading surface), whereas light carriers fall mainly on a slope or gently sloped. Since the particles fall in a conical shape, the dispersion surface of the former (bottom of the cone) is larger in diameter than the dispersion surface of the latter. Therefore, if the particle sizes and densities of the two types of carriers are properly determined, an average density distribution can be obtained over the spray area. The more varied the densities of the carriers that make up the composition, the more average the distribution density will be. The above-mentioned spraying effect is best achieved when the agent is shaken out from a narrow spray opening, as in the case of furikake, but the same effect can be expected even when the agent is squeezed by hand. . [Examples] Hereinafter, embodiments of the invention will be explained using Examples, and the examples are merely for explanation and do not mean any restriction or limitation on the idea of the invention. Production example: Calcined hard zeolite (average particle size Q, 5~L5''/
Wow. Average bulk density: 1.4>100 parts by weight (the same applies hereinafter) and calcined diatomaceous earth (average particle size: 1.0"/, average bulk density: 0.
8) and 100 parts were intimately mixed in a small concrete mixer. At this time, gradually sprinkle 4 t) Part Q of an aqueous solution containing 1100 ppm of ascorbic acid and 214 ppm of fine particulate iron, completely mix the acid, and dry with hot air while stirring to form a granular deodorizing composition for spraying of about 201 g. I got the department. Usage Example 1 The composition of the production example was placed in a paper carton with a small hole of 2 ml in inner diameter, and a 4-month-old kitten (native species, male 2, weighing approximately 2.2 kg) regularly used it as a toilet. In a planter filled with horticultural soil (commercially available mixed culture soil as ``Hana no Soil''), the entire top is cut back five times with a shovel every morning, and the above composition is added to the surface of the soil that has been cut back. The operation of evenly distributing the powder to a thin layer on the soil surface was repeated. Note that feces were removed by scooping in advance. Seven days after the start of the experiment (October 1st) when fresh soil was added, an ammonia odor was felt during the first cutting, but it disappeared after cutting and spraying the above composition.
Approximately 5 cm from the soil surface even after January has passed since the start of the experiment.
Almost no ammonia odor could be detected even at such depths. Incidentally, the average maximum temperature during the experiment period was about 22°C, which was sufficient for soil microorganisms to reduce urea and uric acid in urine to ammonia if the above composition were not present. In addition, the soil after the experiment contained a sufficient amount of nitrates, and flower petals,
Suitable as culture soil for vegetables. Use Example 2 Starting from the beginning of August, the composition of the above-mentioned production example was poured into a plastic bag every day for 7 days, each time a Log amount of garbage was poured into the plastic bag, followed by spraying. As a control, a control group was set up in which the above composition was not added at all. The food waste bags in the test area in which the above composition was added had almost no off-odor even after 7 days, but in the control area, the off-odor began to develop after 2 days, and after 3 days, the off-odor became noticeable, so the experiment was discontinued. did.

【発明の効果】【Effect of the invention】

本発明の散布用組成物は、手などによる簡易散布に際し
て担持薬剤を吸入する恐れがなしに該組成物を対象面に
対し均一に散布する手段を提供するので、脱臭剤、鮮度
保持剤、農薬、肥料などの散布、適用に多大の効果を奏
する。
The spraying composition of the present invention provides a means for uniformly spraying the composition onto a target surface without the risk of inhaling the carrier agent during simple spraying by hand, etc. It is highly effective for spreading and applying fertilizers, etc.

Claims (1)

【特許請求の範囲】 1 通常の風では飛散しない程度の巨視的な大きさの、
被散布物を担持している粒状担体からなる組成物であっ
て、該粒状担体は、小比重粒子と大比重粒子とからなる
少なくとも二種又は多種の粒子からなることを特徴とす
る散布用組成物。 2 被散布物が、脱酸素剤、脱臭剤、防腐剤、殺菌剤、
農薬又は肥料である請求項1記載の組成物。 3 小比重粒子が焼成ケイソウ土粒子であり、大比重粒
子が硬質ゼオライトである請求項1記載の組成物。 4 小比重粒子と大比重粒子の配合時配合比が70:3
0〜50:50である請求項1又は3記載の組成物。
[Claims] 1. A material of a macroscopic size that is not blown away by normal wind.
A composition for dispersion comprising a granular carrier supporting a material to be sprayed, the granular carrier comprising at least two or more types of particles consisting of particles of small specific gravity and particles of large specific gravity. thing. 2 The material to be sprayed contains oxygen absorbers, deodorizers, preservatives, disinfectants,
The composition according to claim 1, which is a pesticide or a fertilizer. 3. The composition according to claim 1, wherein the small specific gravity particles are calcined diatomaceous earth particles and the large specific gravity particles are hard zeolite. 4 The blending ratio of small specific gravity particles and large specific gravity particles is 70:3
The composition according to claim 1 or 3, wherein the ratio is 0 to 50:50.
JP2319709A 1990-11-22 1990-11-22 Spraying composition Expired - Fee Related JP3039984B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2319709A JP3039984B2 (en) 1990-11-22 1990-11-22 Spraying composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2319709A JP3039984B2 (en) 1990-11-22 1990-11-22 Spraying composition

Publications (2)

Publication Number Publication Date
JPH04187603A true JPH04187603A (en) 1992-07-06
JP3039984B2 JP3039984B2 (en) 2000-05-08

Family

ID=18113306

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2319709A Expired - Fee Related JP3039984B2 (en) 1990-11-22 1990-11-22 Spraying composition

Country Status (1)

Country Link
JP (1) JP3039984B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007039273A (en) * 2005-08-03 2007-02-15 Sumitomo Chemical Co Ltd Fertilizer particle composition for aerial application

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007039273A (en) * 2005-08-03 2007-02-15 Sumitomo Chemical Co Ltd Fertilizer particle composition for aerial application

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