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JP7580107B2 - Hydrogen water production device and hydrogen water production method - Google Patents

Hydrogen water production device and hydrogen water production method Download PDF

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JP7580107B2
JP7580107B2 JP2020161244A JP2020161244A JP7580107B2 JP 7580107 B2 JP7580107 B2 JP 7580107B2 JP 2020161244 A JP2020161244 A JP 2020161244A JP 2020161244 A JP2020161244 A JP 2020161244A JP 7580107 B2 JP7580107 B2 JP 7580107B2
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景珍 羅
成權 金
文士 張
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Hikarimirai Co Ltd
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本発明は、水に水素を溶存させた水素水を製造するための水素水製造装置及び水素水製造方法に関し、特に、供給される水から連続して水素水を取り出し可能な水素水製造装置及び水素水製造方法に関する。 The present invention relates to a hydrogen water production device and method for producing hydrogen water by dissolving hydrogen in water, and in particular to a hydrogen water production device and method that can continuously extract hydrogen water from supplied water.

水に水素を溶存させた水素水についての効能が報告されている。ここで、気温25℃、1気圧のもとでは、水1lに水素ガス(以下、単に「水素」とする。)は、1.57mg、つまり、1.6ppm程度までしか溶解させることはできず、例えば、二酸化炭素ガスや酸素ガスなど、他のガスを水に溶解させる場合に比べ、非常に微量しか水中には存在しないことになる。そこで、水と水素とを圧力を高めた閉空間に共存させた溶存槽で気液二相状態にて維持して、ヘンリーの法則に従って溶解度(飽和濃度)を高めることが考慮された。一方、溶存槽から水素水を大気中に取り出してしまうと、圧力が元に戻り、溶解度も低下するため、一気に水素水から水素が大気中に抜けてしまい、飽和濃度以下にまで濃度が低下してしまう。 The efficacy of hydrogen water, which is water in which hydrogen is dissolved, has been reported. Here, at a temperature of 25°C and 1 atmosphere, hydrogen gas (hereinafter simply referred to as "hydrogen") can only be dissolved in 1 liter of water to a concentration of 1.57 mg, or about 1.6 ppm. This is a very small amount compared to dissolving other gases, such as carbon dioxide gas or oxygen gas, in water. Therefore, it was considered to maintain a two-phase gas-liquid state in a dissolution tank in which water and hydrogen coexist in a closed space with increased pressure, and to increase the solubility (saturation concentration) according to Henry's law. On the other hand, if the hydrogen water is taken out of the dissolution tank into the atmosphere, the pressure returns to normal and the solubility also decreases, so hydrogen is released from the hydrogen water into the atmosphere all at once, and the concentration decreases to below the saturation concentration.

例えば、特許文献1では、溶存槽から細い径且つ長尺の細管を介して水に粘性抵抗を与えつつ、徐々に細管内で減圧させて水素を水から抜けないようにして水素水を大気中に取り出すことのできる気体溶解装置が開示されている。ここでは、水槽の水と水素とをポンプで溶存槽へと導き、大気圧よりも高い圧力の気液二相状態に維持して水素を水に溶解させる一方、該溶存槽から細管を通して水素水を再び水槽へと導き、水槽の水を溶解度(飽和濃度)以上に高い濃度で水素を溶存させた水素水とできることを述べている。 For example, Patent Document 1 discloses a gas dissolution device that applies viscous resistance to water from a dissolution tank through a thin, long capillary tube, gradually reducing the pressure inside the capillary tube to prevent hydrogen from escaping from the water, and extracts hydrogen water into the atmosphere. This device describes how water and hydrogen from a tank are pumped into a dissolution tank, where the hydrogen is dissolved in the water while being maintained in a two-phase gas-liquid state at a pressure higher than atmospheric pressure, while hydrogen water is again guided from the dissolution tank through the capillary tube back into the tank, turning the water in the tank into hydrogen water with hydrogen dissolved in it at a concentration higher than the solubility (saturation concentration).

一方、一般家庭に配給されている水道水や、タンクのミネラルウォータを連続的に水素水として取り出すことの出来る装置も提案されている。 On the other hand, devices have been proposed that can continuously extract hydrogen water from tap water provided to ordinary households or from mineral water in tanks.

特許文献2では、水道配管で液体を圧送する加圧部を形成し、該水道配管に接続される流路に水素のような気体を注入する気体注入部を設け、大気圧よりも高い圧力の気液二相状態とするとともに、圧力調整弁を設けた減圧部を介して気体を溶存させた水を取り出すことのできる気体溶解装置を開示している。ここで、減圧部は、圧力損失を与えるような長さの管路でも良いとしており、水を連続的に水素水として取り出すことができる。また、ポンプを用いていないため、装置構造を簡略化できるとともに、駆動部としてのバルブ機構を減らすことができて、故障の機会を減じ得るのである。 Patent Document 2 discloses a gas dissolving device that forms a pressurizing section that pressurizes liquid through a water pipe, provides a gas injection section that injects a gas such as hydrogen into a flow path connected to the water pipe, creates a two-phase gas-liquid state at a pressure higher than atmospheric pressure, and can extract water with dissolved gas through a pressure reducing section equipped with a pressure adjustment valve. Here, the pressure reducing section can be a pipe of a length that causes pressure loss, and water can be continuously extracted as hydrogen water. In addition, because a pump is not used, the device structure can be simplified and the number of valve mechanisms as a drive section can be reduced, reducing the chance of breakdowns.

特開2016-101585号公報JP 2016-101585 A 特開2008-188574号公報JP 2008-188574 A

上記したように、溶存槽を用いて大気圧よりも高い圧力で水と水素とを気液二相状態にすると、ヘンリーの法則に従って大気中よりも水素の水への溶解度を高めることができる。一方、溶存槽に水を供給しながら水素を溶存させた水を取り出そうとすると、水を供給せずに水素を溶解させた水を取り出す場合に比べ、取り出される水に溶解している水素の濃度が低下する傾向となる。そこで、時間当たりに供給する水の量を減らし、溶存槽にて気液二相状態で水を滞留させる時間を長くし、十分に水素を水に溶解させてから取り出すことが考慮されるが、生産性が低下してしまう。また、溶存槽の圧力、水量、そして単位時間の水の供給量及び取り出し量などのパラメータが相互に関連し合って、取り出される水素水の水素濃度を安定させることが難しい。 As described above, when water and hydrogen are put into a gas-liquid two-phase state at a pressure higher than atmospheric pressure using a dissolution tank, the solubility of hydrogen in water can be increased compared to that in the atmosphere according to Henry's law. On the other hand, when attempting to extract water with dissolved hydrogen while supplying water to the dissolution tank, the concentration of hydrogen dissolved in the extracted water tends to be lower than when water with dissolved hydrogen is extracted without supplying water. Therefore, it has been considered to reduce the amount of water supplied per hour and extend the time that water is retained in the dissolution tank in a gas-liquid two-phase state, so that hydrogen is sufficiently dissolved in the water before it is extracted, but this reduces productivity. In addition, parameters such as the pressure of the dissolution tank, the amount of water, and the amount of water supplied and extracted per unit time are interrelated, making it difficult to stabilize the hydrogen concentration of the extracted hydrogen water.

本発明は、以上のような状況を鑑みてなされたものであって、その目的とするところは、供給される水から連続して水素水を取り出し可能であって、生産性に優れるとともに、安定した水素濃度の水素水を得られるような水素水製造装置及び水素水製造方法を提供することにある。 The present invention was made in consideration of the above circumstances, and its purpose is to provide a hydrogen water production device and method that can continuously extract hydrogen water from supplied water, has excellent productivity, and can obtain hydrogen water with a stable hydrogen concentration.

本発明による水素水製造装置は、中空筒状の密閉容器からなる溶存槽の上部及び下部にそれぞれ上部管路及び下部管路を設けて、前記上部管路から水をその内部に供給し気圧よりも高い圧力で水素と二相共存状態にして、前記下部管路から水を水素水として取り出す水素水製造装置であって、上流から下流に向けて前記下部管路を前記上部管路へと順次接続して直列接続された複数の前記溶存槽を含み、最上流にある前記溶存槽の前記上部管路である流入配管に送水管を接続し、全ての前記溶存槽を前記流入配管の送水圧力Tで二相共存状態を維持させたまま、最下流にある前記溶存槽の前記下部管路である取出配管の内部で圧力損失を与えて外部に水を取り出すことを特徴とする。 The hydrogen water production device according to the present invention is a hydrogen water production device that has an upper pipeline and a lower pipeline at the top and bottom of a dissolution tank made of a hollow cylindrical sealed container, supplies water from the upper pipeline into the inside of the tank, creates a two-phase coexistence state with hydrogen at a pressure higher than atmospheric pressure, and extracts the water as hydrogen water from the lower pipeline. The device includes a plurality of dissolution tanks connected in series by sequentially connecting the lower pipeline to the upper pipeline from upstream to downstream, connects a water supply pipe to the inlet pipeline, which is the upper pipeline of the most upstream dissolution tank, and creates a pressure loss inside the outlet pipeline, which is the lower pipeline of the most downstream dissolution tank, to extract water to the outside while maintaining the two-phase coexistence state in all of the dissolution tanks at the water supply pressure T of the inlet pipeline.

かかる特徴によれば、外部から水を供給される溶存槽と、水素水を外部に取り出す溶存槽とを独立させ、安定した水素濃度の水素水を生産性よく得られるのである。 With these features, the dissolution tank to which water is supplied from the outside and the dissolution tank from which hydrogen water is extracted to the outside are separated, making it possible to produce hydrogen water with a stable hydrogen concentration with good productivity.

上記した発明において、前記流入配管に水素供給機構からの水素供給配管を接続され、水素又は/及び水を最上流にある前記溶存槽に供給されることを特徴としてもよい。かかる特徴によれば、簡便な機構で複数の溶存槽内部の気相部分を水素で満たすことができて、安定した水素濃度の水素水を生産性よく得られるのである。 In the above-mentioned invention, a hydrogen supply pipe from a hydrogen supply mechanism may be connected to the inlet pipe, and hydrogen and/or water may be supplied to the dissolution tank located at the most upstream. With this feature, the gas phase inside the multiple dissolution tanks can be filled with hydrogen using a simple mechanism, and hydrogen water with a stable hydrogen concentration can be obtained with good productivity.

上記した発明において、前記流入配管及び前記取出配管はそれぞれ流量弁を設けられ、単位時間当たりの前記流入配管及び前記取出配管を流れる水の流量を等しくするように制御されることを特徴としてもよい。かかる特徴によれば、安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above invention, the inlet pipe and the outlet pipe may each be provided with a flow valve, and the flow rate of water flowing through the inlet pipe and the outlet pipe per unit time may be controlled to be equal. With this feature, hydrogen water with a stable hydrogen concentration can be continuously and productively obtained.

上記した発明において、前記取出配管は、最上流にある前記溶存槽内の圧力と大気圧との圧力差分の圧力損失を与えるように粘性抵抗を生じさせる径及び長さを有する管状路であることを特徴としてもよい。かかる特徴によれば、圧力調整のためのバルブのような駆動機構を用いることなく、安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above-mentioned invention, the extraction pipe may be a tubular passage having a diameter and length that generates viscous resistance so as to provide a pressure loss equal to the pressure difference between the pressure in the dissolution tank at the most upstream and atmospheric pressure. With this feature, hydrogen water with a stable hydrogen concentration can be continuously and productively obtained without using a driving mechanism such as a valve for pressure adjustment.

上記した発明において、前記流入配管には送水圧力調整弁が設けられ、前記送水管からの送水圧力よりも低い前記送水圧力Tに調整されることを特徴としてもよい。かかる特徴によれば、供給される水道水の供給圧力に依存せず、安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above invention, the inlet pipe may be provided with a water supply pressure regulating valve, and the water supply pressure T may be adjusted to be lower than the water supply pressure from the water supply pipe. With this feature, hydrogen water with a stable hydrogen concentration can be continuously and productively obtained, regardless of the supply pressure of the tap water supplied.

上記した発明において、前記溶存槽は、最上流にある水素溶解溶存槽と、最下流にある水素濃度保持溶存槽と、その間にあって圧力を調整する圧力調整溶存槽と、の3つからなることを特徴としてもよい。かかる特徴によれば、簡便な装置で、安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above-mentioned invention, the dissolution tank may be characterized by comprising three tanks: a hydrogen dissolution tank at the most upstream, a hydrogen concentration holding tank at the most downstream, and a pressure adjustment tank between them for adjusting the pressure. With this characteristic, hydrogen water with a stable hydrogen concentration can be continuously and productively obtained using a simple device.

上記した発明において、前記圧力調整溶存槽には多孔質フィルタを収容することを特徴としてもよい。かかる特徴によれば、安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above-mentioned invention, the pressure-adjusting dissolution tank may be characterized by containing a porous filter. With this characteristic, hydrogen water with a stable hydrogen concentration can be continuously and productively obtained.

上記した発明において、前記水素溶解溶存槽にはカーボンフィルタを収容することを特徴としてもよい。かかる特徴によれば、飲用に適した安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above invention, the hydrogen dissolving tank may be characterized by housing a carbon filter. With this characteristic, hydrogen water with a stable hydrogen concentration suitable for drinking can be continuously and productively obtained.

本発明による水素水の製造方法は、中空筒状の密閉容器からなる溶存槽の上部及び下部にそれぞれ上部管路及び下部管路を設けて、前記上部管路から水をその内部に供給し気圧よりも高い圧力で水素と二相共存状態にして、前記下部管路から水を水素水として取り出す水素水製造方法であって、上流から下流に向けて前記下部管路を前記上部管路へと順次接続して直列接続された複数の前記溶存槽について、最上流にある前記溶存槽の前記上部管路である流入配管から送水し、全ての前記溶存槽を前記流入配管の送水圧力Tで二相共存状態を維持させたまま、最下流にある前記溶存槽の前記下部管路である取出配管の内部で圧力損失を与えて外部に水を取り出すことを特徴とする。 The method for producing hydrogen water according to the present invention is a method for producing hydrogen water by providing an upper pipeline and a lower pipeline at the top and bottom of a dissolution tank consisting of a hollow cylindrical sealed container, supplying water from the upper pipeline into the inside of the tank and creating a two-phase coexistence state with hydrogen at a pressure higher than atmospheric pressure, and extracting the water as hydrogen water from the lower pipeline. The method is characterized in that for a plurality of dissolution tanks connected in series by sequentially connecting the lower pipelines to the upper pipeline from upstream to downstream, water is supplied from the inlet pipe, which is the upper pipeline of the most upstream dissolution tank, and water is extracted to the outside by applying a pressure loss inside the outlet pipe, which is the lower pipeline of the most downstream dissolution tank, while maintaining the two-phase coexistence state in all of the dissolution tanks at the water supply pressure T of the inlet pipe.

かかる特徴によれば、外部から水を供給される溶存槽と、水素水を外部に取り出す溶存槽とを独立させ、安定した水素濃度の水素水を生産性よく得られるのである。 With these features, the dissolution tank to which water is supplied from the outside and the dissolution tank from which hydrogen water is extracted to the outside are separated, making it possible to produce hydrogen water with a stable hydrogen concentration with good productivity.

上記した発明において、前記取出配管を開放し全ての前記溶存槽を空とした状態から、水素を前記流入配管から供給し前記溶存槽を水素で満たした後に、前記水素の供給を停止するとともに前記取出配管を閉じて、前記流入配管から供給される水で前記溶存槽を昇圧させ、全ての前記溶存槽を前記流入配管の送水圧力Tで二相共存状態とさせることを特徴としてもよい。かかる特徴によれば、複数の溶存槽の内部を水素でパージし、安定した水素濃度の水素水を生産性よく得られるのである。 In the above-mentioned invention, the outlet pipe is opened and all of the dissolution tanks are empty, then hydrogen is supplied from the inlet pipe to fill the dissolution tanks with hydrogen, the supply of hydrogen is stopped and the outlet pipe is closed, the dissolution tanks are pressurized with water supplied from the inlet pipe, and all of the dissolution tanks are brought into a two-phase coexistence state at the water supply pressure T of the inlet pipe. According to this feature, the insides of multiple dissolution tanks are purged with hydrogen, and hydrogen water with a stable hydrogen concentration can be obtained with good productivity.

上記した発明において、単位時間当たりの前記流入配管及び前記取出配管を流れる水の流量を等しくすることを特徴としてもよい。かかる特徴によれば、安定した水素濃度の水素水を連続して生産性よく得られるのである。 In the above-mentioned invention, the flow rate of water flowing through the inlet pipe and the outlet pipe per unit time may be made equal. With this feature, hydrogen water with a stable hydrogen concentration can be continuously and productively obtained.

本発明の代表的な一例による水素水製造装置のブロック図である。1 is a block diagram of a hydrogen water production device according to a representative example of the present invention. 水素水製造装置の要部の側面図である。FIG. 2 is a side view of the main part of the hydrogen water production device. 水素水製造装置の要部の側面図である。FIG. 2 is a side view of the main part of the hydrogen water production device. 水素水製造装置の要部の側面図である。FIG. 2 is a side view of the main part of the hydrogen water production device.

以下、図1乃至図3を用いて、本発明による水素水製造装置及びこれを用いた水素水製造方法について具体的に説明する。 The hydrogen water production device and the hydrogen water production method using the same according to the present invention will be specifically described below with reference to Figures 1 to 3.

図1に示すように、水素水製造装置10は、複数の溶存槽を備え、例えば水道に接続させるなどして気圧よりも高い圧力で水を供給しつつ連続的に水素水を製造することのできるものである。 As shown in FIG. 1, the hydrogen water production device 10 has multiple dissolution tanks and can continuously produce hydrogen water by supplying water at a pressure higher than atmospheric pressure, for example by connecting it to a water supply.

水の経路に沿って順に説明する。まず、水を供給する送水管1は気圧よりも高い水圧を有する水源に接続させて、水圧を確保する。例えば水道に接続すると好適である。ここで、水素水製造装置10では送水管1から送水される水の圧力により送水圧力Tを得ている。そこで、送水管1には圧力制御バルブ21が設けられ、送水管1に供給される水源の圧力よりも低い送水圧力Tに調整できるようにされている。これによって、送水管1に供給される水道水などの圧力に依存せずに、送水圧力Tで安定して水素水製造装置10に水を送水できる。送水管1は、さらに逆流防止のためのチェックバルブ22を備え、チェックバルブ22を介して流入配管2へ接続される。流入配管2は分岐配管2aを備えて水の流れを一部分岐させ得るとともに、さらに後述する水素供給機構30からの水素供給配管2bも備えて水素を合流させることもできるがこれらについては後述する。 The water path will be described in order. First, the water supply pipe 1 that supplies water is connected to a water source with a water pressure higher than the atmospheric pressure to ensure water pressure. For example, it is preferable to connect to a water supply. Here, the hydrogen water production device 10 obtains water supply pressure T from the pressure of water supplied from the water supply pipe 1. Therefore, the water supply pipe 1 is provided with a pressure control valve 21 so that the water supply pressure T can be adjusted to a value lower than the pressure of the water source supplied to the water supply pipe 1. This allows water to be stably supplied to the hydrogen water production device 10 at the water supply pressure T without depending on the pressure of tap water or the like supplied to the water supply pipe 1. The water supply pipe 1 further includes a check valve 22 for preventing backflow, and is connected to the inlet pipe 2 via the check valve 22. The inlet pipe 2 includes a branch pipe 2a to partially branch the water flow, and also includes a hydrogen supply pipe 2b from the hydrogen supply mechanism 30 described later to merge hydrogen, which will be described later.

流入配管2は、上部管路として第1溶存槽11の上部に接続する。第1溶存槽11は中空筒状の縦型の密閉容器であり、上部管路である流入配管2から水を落下させつつ水素とともに内部に供給させることができる。第1溶存槽11の内部では水素と水とが二相共存状態にされ、供給される水によって圧力を付与されることで水素の水への溶解を促進させることができる。また、上部から水を落下させることで水相中に気相の泡を形成させ、これによっても水素の溶解を促進させ得る。 The inlet pipe 2 is connected to the top of the first dissolution tank 11 as the upper pipeline. The first dissolution tank 11 is a hollow, vertical, sealed container, and water can be dropped from the inlet pipe 2, which is the upper pipeline, and supplied to the inside together with hydrogen. Inside the first dissolution tank 11, hydrogen and water coexist in two phases, and pressure is applied by the supplied water, which can promote the dissolution of hydrogen into the water. In addition, by dropping water from the top, gas phase bubbles are formed in the aqueous phase, which can also promote the dissolution of hydrogen.

第1溶存槽11の下部管路は上流側の接続配管3であり、第2溶存槽12の上部管路として第2溶存槽12の上部に接続されている。第2溶存槽12も同様に、中空筒状の縦型の密閉容器であり、内部では水素と水(水素水)とが二相共存状態にされている。さらに、第2溶存槽12の下部管路である下流側の接続配管4が、第3溶存槽13の上部管路として第3溶存槽13の上部に接続されている。第3溶存槽13も同様に、中空筒状の縦型の密閉容器であり、内部では水素と水(水素水)とが二相共存状態にされている。つまり、上流から下流に向けて下部管路を上部管路へと順次接続して第1溶存槽11、第2溶存槽12及び第3溶存槽13を直列接続している。これにより、全ての溶存槽を流入配管2の送水圧力Tで二相共存状態とし、これを維持させたまま水素水を製造できる。 The lower pipe of the first dissolved tank 11 is the upstream connecting pipe 3, which is connected to the upper part of the second dissolved tank 12 as the upper pipe of the second dissolved tank 12. The second dissolved tank 12 is also a hollow cylindrical vertical sealed container, and hydrogen and water (hydrogen water) are in a two-phase coexistence state inside. Furthermore, the downstream connecting pipe 4, which is the lower pipe of the second dissolved tank 12, is connected to the upper part of the third dissolved tank 13 as the upper pipe of the third dissolved tank 13. The third dissolved tank 13 is also a hollow cylindrical vertical sealed container, and hydrogen and water (hydrogen water) are in a two-phase coexistence state inside. In other words, the lower pipes are connected to the upper pipes in sequence from upstream to downstream, connecting the first dissolved tank 11, the second dissolved tank 12, and the third dissolved tank 13 in series. As a result, all dissolved tanks are in a two-phase coexistence state at the water supply pressure T of the inlet pipe 2, and hydrogen water can be produced while maintaining this state.

なお各溶存槽には適宜フィルタを設けてもよい。水素水製造装置10においては、第1溶存槽11にカーボンフィルタを収容し、第2溶存槽12にはナノフィルタなどの多孔質フィルタを収容している。カーボンフィルタでは飲用に適した水素水を製造することができ、多孔質フィルタでは生じた水素の気泡を細かくして水素水中に長時間留まるようにさせ得る。つまり、飲用に適するとともに安定した水素濃度の水素水を得ようとするものである。一方、第3溶存槽はフィルタのないブランクタンクとされている。 Each dissolution tank may be provided with a filter as appropriate. In the hydrogen water production device 10, the first dissolution tank 11 contains a carbon filter, and the second dissolution tank 12 contains a porous filter such as a nanofilter. The carbon filter can produce hydrogen water suitable for drinking, and the porous filter can break down the hydrogen bubbles that are produced so that they remain in the hydrogen water for a long time. In other words, the aim is to obtain hydrogen water that is suitable for drinking and has a stable hydrogen concentration. On the other hand, the third dissolution tank is a blank tank without a filter.

第3溶存槽13の下部管路としての取出配管5は、取り出す水素水の圧力を大気圧付近まで低下させる圧力降下機構23を備えている。圧力降下機構23は、急激な減圧による水素水からの水素の離脱を抑制するためのものである。例えば、圧力降下機構23は、第1溶存槽11内の圧力と大気圧との圧力差分の圧力損失を流れる水素水に与えるように粘性抵抗を生じさせる径及び長さを有する管状路とし得る。これには比較的長い経路を有する細管を好適に用いることができる。これによって、安定した流れを形成して急激な圧力低下を防止することができ、圧力調整のためのバルブのような駆動機構を用いることなく減圧できる。取出配管5のさらに下流には、流量計測センサ24が備えられ、取出配管5からの水素水の流量を測定している。取出配管5はさらに下流に電磁弁25を備え、取出し口6に接続している。電磁弁25は蛇口としてもよい。 The extraction pipe 5 as the lower pipe of the third dissolved tank 13 is equipped with a pressure drop mechanism 23 that reduces the pressure of the hydrogen water to near atmospheric pressure. The pressure drop mechanism 23 is intended to suppress the release of hydrogen from the hydrogen water due to a sudden reduction in pressure. For example, the pressure drop mechanism 23 may be a tubular passage having a diameter and length that generates viscous resistance so as to impart the pressure loss of the pressure difference between the pressure in the first dissolved tank 11 and the atmospheric pressure to the flowing hydrogen water. A thin tube having a relatively long path can be preferably used for this purpose. This makes it possible to form a stable flow and prevent a sudden drop in pressure, and the pressure can be reduced without using a driving mechanism such as a valve for pressure adjustment. A flow rate measurement sensor 24 is provided further downstream of the extraction pipe 5 to measure the flow rate of the hydrogen water from the extraction pipe 5. The extraction pipe 5 is equipped with an electromagnetic valve 25 further downstream and is connected to the extraction port 6. The electromagnetic valve 25 may be a faucet.

上記したように、流入配管2は分岐配管2aを備えて水の流れを一部分岐させ得る。分岐配管2aは、水素供給機構30に接続され分岐した水を供給することができる。水素供給機構30では、分岐配管2aからの水を逆浸透膜からなるROフィルタ31及びイオン交換樹脂からなるイオンフィルタ32を介して電解槽33に供給する。電解槽33では水を電気分解することで水素を製造できる。水素と同時に生成される酸素は電解槽33の上部から排出される。製造された水素は電解槽33から上記した水素供給配管2bを通って流入配管2に供給され、流入配管2内部の水と合流される。水素供給配管2bには圧力センサ39が接続され、電磁バルブ34によって水素供給配管2bに供給される水素の圧力や量を調整できる。 As described above, the inlet pipe 2 is provided with a branch pipe 2a to partially branch the water flow. The branch pipe 2a is connected to the hydrogen supply mechanism 30 and can supply the branched water. In the hydrogen supply mechanism 30, the water from the branch pipe 2a is supplied to the electrolytic cell 33 via an RO filter 31 made of a reverse osmosis membrane and an ion filter 32 made of an ion exchange resin. In the electrolytic cell 33, hydrogen can be produced by electrolyzing the water. Oxygen produced at the same time as hydrogen is discharged from the top of the electrolytic cell 33. The produced hydrogen is supplied to the inlet pipe 2 through the hydrogen supply pipe 2b from the electrolytic cell 33 and merges with the water inside the inlet pipe 2. A pressure sensor 39 is connected to the hydrogen supply pipe 2b, and the pressure and amount of hydrogen supplied to the hydrogen supply pipe 2b can be adjusted by an electromagnetic valve 34.

圧力センサ39及び上記した取出配管5の流量計測センサ24からは、計測された値に対応する信号が制御基板40に入力される。制御基板40では、これらの入力信号に対応しつつ、予め定められたプログラムに従って電解槽33、圧力制御バルブ21、電磁バルブ34の動作を制御できる。 Signals corresponding to the measured values are input from the pressure sensor 39 and the flow rate measurement sensor 24 of the extraction pipe 5 to the control board 40. The control board 40 responds to these input signals and controls the operation of the electrolytic cell 33, pressure control valve 21, and solenoid valve 34 according to a predetermined program.

次に、水素水製造装置10を用いた水素水の製造方法について説明する。 Next, we will explain the method for producing hydrogen water using the hydrogen water production device 10.

水素水製造装置10の使用開始にあたり、電磁弁25を開放して取出配管5を開放し、第1溶存槽11、第2溶存槽12及び第3溶存槽13のいずれも内部が空の状態、つまり内部に空気が満たされた状態から使用を開始する。なお、説明をわかりやすくするために、溶存槽の内部のフィルタについては無いものとする。 When starting to use the hydrogen water production device 10, the solenoid valve 25 is opened to open the extraction pipe 5, and the first dissolution tank 11, the second dissolution tank 12, and the third dissolution tank 13 are all empty, that is, filled with air. For ease of explanation, it is assumed that there are no filters inside the dissolution tanks.

図1を再び参照すると、まず、圧力制御バルブ21を開け、送水管1から流入配管2に水を導く。さらに、流入配管2からの水の一部を分岐配管2aから水素供給機構30に導き、ROフィルタ31及びイオンフィルタ32を介して電解槽33に供給し、水の電気分解によって水素を生成させる。生成された水素は水素供給配管2bから流入配管2に合流し水と混合され、又は直接第1溶存槽11の上部に供給される。 Referring again to FIG. 1, first, the pressure control valve 21 is opened and water is guided from the water supply pipe 1 to the inlet pipe 2. Furthermore, a portion of the water from the inlet pipe 2 is guided from the branch pipe 2a to the hydrogen supply mechanism 30 and supplied to the electrolytic cell 33 via the RO filter 31 and ion filter 32, where hydrogen is generated by electrolysis of water. The generated hydrogen flows from the hydrogen supply pipe 2b into the inlet pipe 2 and is mixed with the water, or is supplied directly to the top of the first dissolved tank 11.

すると、図2に示すように、第1溶存槽11では、気液二相共存状態で下側に液体、上側に気体を貯留させる。水に併せ気体(水素)を供給することで、第1溶存槽11の内部圧力を第2溶存槽12の内部圧力に釣り合わせるように、水が接続配管3へ追い出され、第2溶存槽12へ流入する。さらに、気体の一部、特に、水素に比べ比重の大きい空気が水とともに接続配管3へ流入し、第2溶存槽12へ移動する。同様に、第2溶存槽12では、接続配管3を介して第1溶存槽11から水に併せ気体(空気)が供給されるが、接続配管4を介して、空気が水とともに第3溶存槽13へと移動する。また、第3溶存槽13では、接続配管4を介して第2溶存槽12から水に併せ気体(空気)が供給されるが、接続配管5を介して、空気が水とともに外部に排出されるのである。つまり、第1溶存槽11、第2溶存槽12、第3溶存槽13の水面Sは底部近傍にあってほとんど上昇しない。 2, in the first dissolved tank 11, liquid is stored in the lower part and gas is stored in the upper part in a gas-liquid two-phase coexistence state. By supplying gas (hydrogen) together with water, water is expelled to the connecting pipe 3 and flows into the second dissolved tank 12 so that the internal pressure of the first dissolved tank 11 is balanced with the internal pressure of the second dissolved tank 12. Furthermore, a part of the gas, especially air, which has a higher specific gravity than hydrogen, flows into the connecting pipe 3 together with the water and moves to the second dissolved tank 12. Similarly, in the second dissolved tank 12, gas (air) is supplied together with water from the first dissolved tank 11 through the connecting pipe 3, but the air moves together with water to the third dissolved tank 13 through the connecting pipe 4. In addition, in the third dissolved tank 13, gas (air) is supplied together with water from the second dissolved tank 12 through the connecting pipe 4, but the air is discharged to the outside together with water through the connecting pipe 5. In other words, the water levels S in the first dissolution tank 11, the second dissolution tank 12, and the third dissolution tank 13 are near the bottom and barely rise.

この状態で時間が経過すると、第1溶存槽11の内部の空気が全て第2溶存槽12に移動し、第1溶存槽11の内部は水素に置換される。同様に、第2溶存槽12、第3溶存槽13においても、若干の時差を生じつつ、順次、内部が水素に置換される。 As time passes in this state, all of the air inside the first dissolution tank 11 moves to the second dissolution tank 12, and the inside of the first dissolution tank 11 is replaced with hydrogen. Similarly, the insides of the second dissolution tank 12 and the third dissolution tank 13 are successively replaced with hydrogen, with a slight time lag occurring.

図3に示すように、第1溶存槽11、第2溶存槽12、第3溶存槽13の内部を水素で満たしたら、電磁弁25を閉じ取出配管5を閉塞するとともに、水素の供給を停止して流入配管2から水のみを第1溶存槽11に供給する。すると、水面Sが上昇し、第1溶存槽11内の気相部分の体積が圧縮されて内部圧力を上昇させる。一方、第1溶存槽11の内部圧力が第2溶存槽12よりも高くなろうとするため、下部管路である接続配管3から第2溶存槽12へ向けて水を流出させ、第1溶存槽11及び第2溶存槽12の内部圧力を釣り合わせようとする。 As shown in FIG. 3, once the first dissolved tank 11, the second dissolved tank 12, and the third dissolved tank 13 are filled with hydrogen, the solenoid valve 25 is closed to block the outlet pipe 5, the supply of hydrogen is stopped, and only water is supplied to the first dissolved tank 11 from the inlet pipe 2. This causes the water level S to rise, compressing the volume of the gas phase in the first dissolved tank 11 and increasing the internal pressure. Meanwhile, since the internal pressure of the first dissolved tank 11 is attempting to become higher than that of the second dissolved tank 12, water is caused to flow out from the lower pipe, the connecting pipe 3, toward the second dissolved tank 12 in an attempt to balance the internal pressures of the first dissolved tank 11 and the second dissolved tank 12.

更に、第2溶存槽12でも、接続配管3から水が流入し、水面Sを上昇させることで、気相部分の体積が圧縮されて内部圧力を上昇させる。すると、接続配管4から第3溶存槽13へ向けて水を流出させ、第2溶存槽12及び第3溶存槽13の内部圧力を釣り合わせようとする。 Furthermore, in the second dissolution tank 12, water flows in from the connecting pipe 3, raising the water level S, compressing the volume of the gas phase and increasing the internal pressure. Then, water flows out from the connecting pipe 4 toward the third dissolution tank 13, attempting to balance the internal pressures of the second dissolution tank 12 and the third dissolution tank 13.

一方、第3溶存槽13でも、接続配管4から水が流入し、水面Sを上昇させることで、気相部分の体積が圧縮されて内部圧力を上昇させるが、取出配管5が閉塞されているため、そのまま内部圧力が上昇しようとする。これにより、第3溶存槽13の内部圧力と釣り合うように、第2溶存槽12の内部圧力が高くなる、つまり、水面Sが上昇し、同様に、第1溶存槽11の水面も上昇する。ここで、第1溶存槽11、第2溶存槽12、第3溶存槽13の内径(断面積)が同じであれば、水面Sの高さもほぼ同等となる。 Meanwhile, in the third dissolution tank 13, water flows in from the connecting pipe 4, causing the water level S to rise, compressing the volume of the gas phase and increasing the internal pressure, but because the extraction pipe 5 is blocked, the internal pressure tends to continue to rise. As a result, the internal pressure of the second dissolution tank 12 increases to balance with the internal pressure of the third dissolution tank 13, that is, the water level S rises, and similarly, the water level of the first dissolution tank 11 also rises. Here, if the inner diameters (cross-sectional areas) of the first dissolution tank 11, second dissolution tank 12, and third dissolution tank 13 are the same, the heights of the water levels S will also be approximately the same.

そして、図4に示すように、第1溶存槽11、第2溶存槽12、第3溶存槽13の内部圧力が送水圧力Tとつり合うまで水が供給されて、圧力制御バルブ21が閉じられる。各溶存槽11~13では、送水圧力Tによって加圧された水素による気相部分を形成するとともに、貯留された水に水素を溶解させて水素水を製造することができる。 As shown in FIG. 4, water is supplied to the first dissolution tank 11, the second dissolution tank 12, and the third dissolution tank 13 until their internal pressures balance with the water supply pressure T, and the pressure control valve 21 is closed. In each of the dissolution tanks 11 to 13, a gas phase portion is formed by hydrogen pressurized by the water supply pressure T, and hydrogen water can be produced by dissolving hydrogen in the stored water.

このように、使用開始時に溶存槽内に空気が満たされていても溶存槽内の気相部分を水素で満たすことができて、安定して送水圧力Tに対応した濃度の水素水を製造し得る。 In this way, even if the dissolution tank is filled with air at the start of use, the gas phase in the dissolution tank can be filled with hydrogen, making it possible to stably produce hydrogen water with a concentration corresponding to the water supply pressure T.

続いて、電磁弁25を開いて水素水を取り出すとともに、圧力制御バルブ21が開放されて水が第1溶存槽11へ供給される。ここで、第3溶存槽13内部の水が減少することで気相部分が膨張し圧力が低下しようとする。これに対して、第2溶存槽12から水が供給され、圧力をつり合わせようとする。同様に第2溶存槽12の圧力が低下しようとすると第1溶存槽11から水が供給される。ここで、第1溶存槽11の圧力が低下しようとした分を流入配管2から水を供給し第1溶存槽11の圧力を維持するように圧力制御バルブ21によって供給する水量及び圧力を制御する。このとき、取出配管5の圧力降下機構23によって、その上流側である第3溶存槽13の圧力を所定の値に維持させて、全体の圧力をバランスさせるように、圧力制御バルブ21は制御される。例えば、取出配管5の流量と等しい流量を流入配管2に与えるようにするとよい。これによって、系全体の圧力低下を抑制し、安定した濃度の水素水を連続的に製造することができる。 Next, the solenoid valve 25 is opened to extract hydrogen water, and the pressure control valve 21 is opened to supply water to the first dissolved tank 11. Here, as the water inside the third dissolved tank 13 decreases, the gas phase expands and the pressure tends to decrease. In response to this, water is supplied from the second dissolved tank 12 to balance the pressure. Similarly, when the pressure of the second dissolved tank 12 tends to decrease, water is supplied from the first dissolved tank 11. Here, the amount and pressure of water supplied by the pressure control valve 21 are controlled so that water is supplied from the inflow pipe 2 to compensate for the decrease in pressure in the first dissolved tank 11 and the pressure of the first dissolved tank 11 is maintained. At this time, the pressure control valve 21 is controlled so that the pressure of the third dissolved tank 13, which is upstream of the extraction pipe 5, is maintained at a predetermined value by the pressure drop mechanism 23 of the extraction pipe 5, and the overall pressure is balanced. For example, it is preferable to provide a flow rate equal to the flow rate of the extraction pipe 5 to the inflow pipe 2. This prevents pressure drops throughout the system and allows hydrogen water to be produced continuously at a stable concentration.

特に、溶存槽を複数設けたため、最上流の溶存槽である第1溶存槽11に水素の溶解していない水を供給して一時的に第1溶存槽11内の水素水を希釈させて水素濃度を低下させたとしても、下流側の溶存槽12及び13には第1溶存槽11からの水素水が供給されるため、希釈の度合いは小さくなる。その結果、下流側の特に溶存槽13では、常に送水圧力Tに対応した濃度に近い水素水を貯留し続けることができ、安定した水素濃度の水素水を連続的に製造することができる。つまり、外部から水を供給される溶存槽と、水素水を外部に取り出す溶存槽とを独立させたことで、安定した水素濃度の水素水を生産性よく得られる。 In particular, since multiple dissolution tanks are provided, even if water not containing dissolved hydrogen is supplied to the first dissolution tank 11, which is the most upstream dissolution tank, to temporarily dilute the hydrogen water in the first dissolution tank 11 and reduce the hydrogen concentration, the degree of dilution is reduced because hydrogen water from the first dissolution tank 11 is supplied to the downstream dissolution tanks 12 and 13. As a result, hydrogen water close to the concentration corresponding to the water supply pressure T can be stored at all times in the downstream dissolution tank, particularly in the dissolution tank 13, and hydrogen water with a stable hydrogen concentration can be continuously produced. In other words, by separating the dissolution tank to which water is supplied from the outside and the dissolution tank from which hydrogen water is taken out to the outside, hydrogen water with a stable hydrogen concentration can be obtained with good productivity.

水素水製造装置10では、溶存槽を3つとしたので、最下流の溶存槽である第3溶存槽13では、特に安定した水素濃度の水素水を貯留し続けることができ、かかる水素濃度の水素水を常に取出配管5から取り出すことができる。特に、第1溶存槽11は水素を溶解させることを主とした水素溶解溶存槽であり、第3溶存槽13は、取り出す水素水の水素濃度を保持するための水素濃度保持溶存槽である。また、第2溶存槽12は、水素濃度の維持に寄与するだけでなく、第1溶存槽11での圧力変動を吸収し、第3溶存槽13の圧力変動を抑制する圧力調整溶存槽としても機能する。 Since the hydrogen water production device 10 has three dissolution tanks, hydrogen water with a particularly stable hydrogen concentration can be continuously stored in the third dissolution tank 13, which is the most downstream dissolution tank, and hydrogen water with such a hydrogen concentration can be constantly extracted from the extraction pipe 5. In particular, the first dissolution tank 11 is a hydrogen dissolution tank whose main function is to dissolve hydrogen, and the third dissolution tank 13 is a hydrogen concentration retention dissolution tank for retaining the hydrogen concentration of the hydrogen water to be extracted. In addition, the second dissolution tank 12 not only contributes to maintaining the hydrogen concentration, but also functions as a pressure adjustment dissolution tank that absorbs pressure fluctuations in the first dissolution tank 11 and suppresses pressure fluctuations in the third dissolution tank 13.

なお、上記した実施例において、第1溶存槽11、第2溶存槽12、第3溶存槽13のそれぞれの高さを11インチ(約280mm)とし、送水圧力Tを、3Bar(0.3MPa)とし、圧力降下機構23として5/32インチ(約4mm)の内径と80mm以上の長さを有する細管を用いたところ、安定して2.5ppm以上の水素濃度の水素水を連続的に製造できることを確認した。 In the above example, the height of each of the first dissolution tank 11, the second dissolution tank 12, and the third dissolution tank 13 was set to 11 inches (approximately 280 mm), the water supply pressure T was set to 3 Bar (0.3 MPa), and a thin tube with an inner diameter of 5/32 inches (approximately 4 mm) and a length of 80 mm or more was used as the pressure reduction mechanism 23. It was confirmed that hydrogen water with a hydrogen concentration of 2.5 ppm or more could be stably and continuously produced.

なお、取出配管5の流量計測センサ24及び電磁弁25は流量弁として動作し得るが、流入配管2の下流側にさらに流量弁を設け、流入配管2と取出配管5のそれぞれを流れる水の流量を等しくするよう制御できるようにすることも好ましい。これによって、安定した水素濃度の水素水を連続してさらに生産性よく得ることができる。 The flow rate measurement sensor 24 and solenoid valve 25 of the outlet pipe 5 can function as a flow rate valve, but it is also preferable to provide an additional flow rate valve downstream of the inlet pipe 2 so that the flow rates of the water flowing through the inlet pipe 2 and the outlet pipe 5 can be controlled to be equal. This makes it possible to continuously produce hydrogen water with a stable hydrogen concentration with even greater productivity.

使用開始時において、水と水素を同時に供給する方法を説明したが、最初に第1溶存槽11~第3溶存槽13に水素をパージするようにしてもよい。この場合、流入配管2のうちの、分岐配管2aと水素供給配管2bとの間に水の供給を絶つバルブを追加しておく。そして、このバルブを閉じて、水素供給機構30にのみ水を供給し、水素を生成し、流入配管2から第1溶存槽11へは水素のみを供給する。これにより、全ての溶存槽に水素をパージし、その後水素の供給を止めて、水のみを供給するようにしても、水素水を製造できる。特に、各溶存槽11~13は上部から水素を供給できるので、比重の大きな空気を先んじて下部から排出でき、速やかに水素のパージを完了できて、生産性の向上に寄与する。 Although the method of simultaneously supplying water and hydrogen at the start of use has been described, hydrogen may be purged from the first dissolved tank 11 to the third dissolved tank 13 first. In this case, a valve that cuts off the water supply is added to the inlet pipe 2 between the branch pipe 2a and the hydrogen supply pipe 2b. This valve is then closed to supply water only to the hydrogen supply mechanism 30, generate hydrogen, and supply only hydrogen from the inlet pipe 2 to the first dissolved tank 11. This allows hydrogen water to be produced even if hydrogen is purged from all dissolved tanks, the hydrogen supply is then stopped, and only water is supplied. In particular, since hydrogen can be supplied from the top of each dissolved tank 11 to 13, air with a high specific gravity can be discharged first from the bottom, and hydrogen purging can be completed quickly, which contributes to improved productivity.

以上、本発明による実施例及びこれに基づく変形例を説明したが、本発明は必ずしもこれに限定されるものではなく、当業者であれば、本発明の主旨又は添付した特許請求の範囲を逸脱することなく、様々な代替実施例及び改変例を見出すことができるであろう。 Although the above describes an embodiment of the present invention and variations based thereon, the present invention is not necessarily limited thereto, and a person skilled in the art will be able to find various alternative embodiments and modifications without departing from the spirit of the present invention or the scope of the appended claims.

1 送水管
2 流入配管
2b 水素供給配管
5 取出配管
10 水素水製造装置
11 第1溶存槽
12 第2溶存槽
13 第3溶存槽
23 圧力降下機構
30 水素供給機構

Reference Signs List 1 Water pipe 2 Inlet pipe 2b Hydrogen supply pipe 5 Extraction pipe 10 Hydrogen water production device 11 First dissolution tank 12 Second dissolution tank 13 Third dissolution tank 23 Pressure drop mechanism 30 Hydrogen supply mechanism

Claims (9)

中空筒状の密閉容器からなる溶存槽の上部及び下部にそれぞれ上部管路及び下部管路を設けて、前記上部管路から水をその内部に供給し気圧よりも高い圧力で水素と二相共存状態にして、前記下部管路から水を水素水として取り出す水素水製造装置であって、
上流から下流に向けて前記下部管路を前記上部管路へと順次接続して直列接続された複数の前記溶存槽を含み、最上流にある前記溶存槽の前記上部管路である流入配管に送水管を接続し、
前記流入配管に設けられた送水圧力調整弁によって、前記送水管からの送水圧力よりも低い送水圧力Tに調整し、全ての前記溶存槽を二相共存状態を維持させたまま、最下流にある前記溶存槽の前記下部管路である取出配管の内部で圧力損失を与えて外部に水を取り出すことを特徴とする水素水製造装置。
An apparatus for producing hydrogen water, comprising: an upper pipe line and a lower pipe line provided at the upper and lower parts of a dissolution tank made of a hollow cylindrical sealed container; water is supplied into the dissolution tank from the upper pipe line, and the water and hydrogen are brought into a two-phase coexistence state at a pressure higher than atmospheric pressure; and the water is taken out as hydrogen water from the lower pipe line,
The dissolution tank includes a plurality of dissolution tanks connected in series by sequentially connecting the lower pipeline to the upper pipeline from upstream to downstream, and a water supply pipe is connected to an inlet pipe, which is the upper pipeline of the most upstream dissolution tank;
A hydrogen water production apparatus characterized in that a water supply pressure T lower than the water supply pressure from the water supply pipe is adjusted by a water supply pressure regulating valve provided in the inlet pipe, and water is taken out to the outside by applying a pressure loss inside the extraction pipe, which is the lower pipe of the most downstream dissolution tank, while maintaining a two -phase coexistence state in all of the dissolution tanks.
前記流入配管に水素供給機構からの水素供給配管を接続され、水素又は/及び水を最上流にある前記溶存槽に供給されることを特徴とする請求項1記載の水素水製造装置。 The hydrogen water production device according to claim 1, characterized in that the inlet pipe is connected to a hydrogen supply pipe from a hydrogen supply mechanism, and hydrogen and/or water is supplied to the dissolution tank located at the most upstream. 前記流入配管及び前記取出配管はそれぞれ流量弁を設けられ、単位時間当たりの前記流入配管及び前記取出配管を流れる水の流量を等しくするように制御されることを特徴とする請求項1又は2に記載の水素水製造装置。 The hydrogen water production device according to claim 1 or 2, characterized in that the inlet pipe and the outlet pipe are each provided with a flow valve, and the flow rate of water flowing through the inlet pipe and the outlet pipe per unit time is controlled to be equal. 前記取出配管は、最上流にある前記溶存槽内の圧力と大気圧との圧力差分の圧力損失を与えるように粘性抵抗を生じさせる径及び長さを有する管状路であることを特徴とする請求項1乃至3のうちの1つに記載の水素水製造装置。 The hydrogen water production device according to any one of claims 1 to 3, characterized in that the extraction pipe is a tubular passage having a diameter and length that generates viscous resistance so as to provide a pressure loss equal to the pressure difference between the pressure in the dissolution tank at the most upstream and atmospheric pressure. 前記溶存槽は、最上流にある水素溶解溶存槽と、最下流にある水素濃度保持溶存槽と、その間にあって圧力を調整する圧力調整溶存槽と、の3つからなることを特徴とする請求項1乃至のうちの1つに記載の水素水製造装置。 The hydrogen water production device according to any one of claims 1 to 4, characterized in that the dissolution tanks are composed of three tanks: a hydrogen dissolution tank at the most upstream side, a hydrogen concentration holding tank at the most downstream side, and a pressure adjustment tank between them for adjusting the pressure. 前記圧力調整溶存槽には多孔質フィルタを収容することを特徴とする請求項記載の水素水製造装置。 6. The hydrogen water generating apparatus according to claim 5 , wherein the pressure adjusting dissolution tank contains a porous filter. 前記水素溶解溶存槽にはカーボンフィルタを収容することを特徴とする請求項又はに記載の水素水製造装置。 7. The hydrogen water generating apparatus according to claim 5 , wherein the hydrogen dissolving tank contains a carbon filter. 中空筒状の密閉容器からなる溶存槽の上部及び下部にそれぞれ上部管路及び下部管路を設けて、前記上部管路から水をその内部に供給し気圧よりも高い圧力で水素と二相共存状態にして、前記下部管路から水を水素水として取り出す水素水製造方法であって、
上流から下流に向けて前記下部管路を前記上部管路へと順次接続して直列接続された複数の前記溶存槽について、最上流にある前記溶存槽の前記上部管路である流入配管から送水し、全ての前記溶存槽を前記流入配管の送水圧力Tで二相共存状態を維持させたまま、最下流にある前記溶存槽の前記下部管路である取出配管の内部で圧力損失を与えて外部に水を取り出すにあたって、
前記取出配管を開放し全ての前記溶存槽を空とした状態から、水素を前記流入配管から供給し前記溶存槽を水素で満たした後に、前記水素の供給を停止するとともに前記取出配管を閉じて、前記流入配管から供給される水で前記溶存槽を昇圧させ、全ての前記溶存槽を前記流入配管の送水圧力Tで二相共存状態とさせることを特徴とする水素水製造方法。
A method for producing hydrogen water, comprising the steps of: providing an upper pipe line and a lower pipe line at the upper and lower parts of a dissolution tank made of a hollow cylindrical sealed container; supplying water from the upper pipe line into the dissolution tank; making the water coexist with hydrogen at a pressure higher than atmospheric pressure; and extracting the water as hydrogen water from the lower pipe line,
With respect to a plurality of dissolution tanks connected in series by sequentially connecting the lower pipelines to the upper pipelines from upstream to downstream, water is supplied from an inlet pipe, which is the upper pipeline, of the most upstream dissolution tank, and while maintaining a two-phase coexistence state in all of the dissolution tanks at a water supply pressure T of the inlet pipe, a pressure loss is applied inside an outlet pipe, which is the lower pipeline, of the most downstream dissolution tank to take out water to the outside,
A method for producing hydrogen water, characterized in that the outlet pipe is opened and all of the dissolution tanks are empty, hydrogen is supplied from the inlet pipe to fill the dissolution tanks with hydrogen, the supply of hydrogen is stopped and the outlet pipe is closed, the dissolution tanks are pressurized with water supplied from the inlet pipe, and all of the dissolution tanks are brought into a two-phase coexistence state at the water supply pressure T of the inlet pipe .
単位時間当たりの前記流入配管及び前記取出配管を流れる水の流量を等しくすることを特徴とする請求項記載の水素水製造方法。 9. The method for producing hydrogen water according to claim 8 , wherein the flow rates of water flowing through the inlet pipe and the outlet pipe per unit time are set equal to each other.
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