JP7035295B2 - A woodchip mortar composition containing a metal having a weed-proofing effect and / or an antibacterial effect. - Google Patents
A woodchip mortar composition containing a metal having a weed-proofing effect and / or an antibacterial effect. Download PDFInfo
- Publication number
- JP7035295B2 JP7035295B2 JP2016234465A JP2016234465A JP7035295B2 JP 7035295 B2 JP7035295 B2 JP 7035295B2 JP 2016234465 A JP2016234465 A JP 2016234465A JP 2016234465 A JP2016234465 A JP 2016234465A JP 7035295 B2 JP7035295 B2 JP 7035295B2
- Authority
- JP
- Japan
- Prior art keywords
- wood
- mortar
- wood chip
- metal
- weed control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Catching Or Destruction (AREA)
- Road Paving Structures (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は防草効果及び／又は抗菌効果を有する金属を含有するウッドチップモルタル組成物に関し、特に、土木用途、建築用途、園芸用途等に最適な前記ウッドチップモルタル組成物に関する。 The present invention relates to a wood chip mortar composition containing a metal having a weed-proof effect and / or an antibacterial effect, and more particularly to the wood chip mortar composition which is most suitable for civil engineering use, building use, horticultural use and the like.
一般道の歩道や公園の遊歩道等における雑草の繁殖は、景観を損ねるばかりでなく、交通の障害や火災等の問題も生じるため、定期的な除草作業は必須となり、多くの自治体ではその費用が問題になっている。また、一般家庭のインターロッキング等においても、雑草の繁殖は問題となっている。従って、公共の歩道を有する自治体やインターロッキング等を有する一般家庭において、「雑草の生えないブロック平板」の需要は高い。また、「雑菌が繁殖しないブロック平板」については、食品を管理する倉庫や酪農・畜産施設など殺菌作業を定期的に行う施設での需要が高い。 Propagation of weeds on sidewalks of general roads and promenades of parks not only spoils the landscape, but also causes problems such as traffic obstacles and fires, so regular weeding work is essential, and many local governments have to pay for it. It's a problem. In addition, weed breeding has become a problem in interlocking of ordinary households. Therefore, there is a high demand for "block flat plates without weeds" in local governments with public sidewalks and ordinary households with interlocking. In addition, there is a high demand for "block flat plates that do not propagate germs" in facilities that regularly perform sterilization work, such as warehouses that manage food and dairy and livestock facilities.
防草ブロック工法のようなブロック形状によって雑草の進入を防ぐ方法やシートで被覆して雑草の生育を妨げる方法はこれまで数多く開発されているが、ブロック平板そのものに防草効果や殺菌効果のような機能を持たせる製品の開発は行われていない。
一方、ウッドチップを含有させたモルタル組成物は知られているが（例えば、特許文献１～５）、防草効果及び／又は抗菌効果を発揮させる目的でウッドチップモルタル組成物に金属を含有させた例はない。
Many methods have been developed so far, such as the weed-proof block method, which prevents the invasion of weeds by using a block shape, and the method of covering with a sheet to prevent the growth of weeds. No products have been developed to provide such functions.
On the other hand, although mortar compositions containing wood chips are known (for example, Patent Documents 1 to 5), the wood chip mortar composition contains a metal for the purpose of exerting a weed-proof effect and / or an antibacterial effect. There is no example.
上記の通り、本発明は、防草効果及び／又は抗菌効果を有する土木、建築又は園芸用資材を提供することを課題とする。 As described above, it is an object of the present invention to provide civil engineering, building or horticultural materials having a weed control effect and / or an antibacterial effect.
本発明者らは上記課題を解決するために鋭意検討を行った結果、銅や銀などを含むウッドチップモルタル組成物の開発に成功し、この組成物が防草効果及び／又は抗菌効果を有し、土木、建築又は園芸用資材として優れることを見出し、本発明を完成させるに至った。 As a result of diligent studies to solve the above problems, the present inventors have succeeded in developing a wood chip mortar composition containing copper, silver, etc., and this composition has a weed-proof effect and / or an antibacterial effect. However, they have found that they are excellent as materials for civil engineering, construction or horticulture, and have completed the present invention.
すなわち、本発明は、抗菌効果及び／又は防草効果を有する金属を０．０００１～５重量％含有するウッドチップモルタル組成物を提供する。ウッドチップモルタル組成物におけるウッドチップとモルタルの重量比は２：８～８：２であることが好ましい。
ここで、前記金属としては、銅、銀、亜鉛、ニッケル又は白金であることが好ましい。
また、本発明は、前記モルタル組成物を含む土木、建築又は園芸用資材を提供する。
また、本発明は、ウッドチップモルタルを抗菌効果及び／又は防草効果を有する金属の
溶液に含浸させる工程を含む、土木、建築又は園芸用資材の製造方法を提供する。
That is, the present invention provides a wood chip mortar composition containing 0.0001 to 5% by weight of a metal having an antibacterial effect and / or a weed control effect. The weight ratio of wood chips to mortar in the wood chip mortar composition is preferably 2: 8 to 8: 2.
Here, the metal is preferably copper, silver, zinc, nickel or platinum.
The present invention also provides civil engineering, building or horticultural materials containing the mortar composition.
The present invention also provides a method for producing a material for civil engineering, construction or horticulture, which comprises a step of impregnating a wood chip mortar with a solution of a metal having an antibacterial effect and / or a weed control effect.
本発明のウッドチップモルタル組成物によれば、施工箇所に雑草や雑菌が繁殖せず、手入れが不要で、景観や衛生が維持できる。例えば、銅を担持したウッドチップモルタル組成物を用いて歩道等を舗装することにより、雑草が生えず、安全で景観を損なわない歩道等とすることができる。また、銀を担持したウッドチップモルタル組成物を用いて厨房、豚舎、倉庫等を施工することにより、雑菌が繁殖せず、衛生的な厨房、豚舎、倉庫等とすることができる。 According to the wood chip mortar composition of the present invention, weeds and germs do not propagate in the construction site, maintenance is not required, and the landscape and hygiene can be maintained. For example, by paving a sidewalk or the like using a wood chip mortar composition supporting copper, it is possible to make a sidewalk or the like that is safe and does not spoil the landscape without weeds growing. Further, by constructing a kitchen, a piggery, a warehouse, etc. using a wood chip mortar composition carrying silver, it is possible to make a hygienic kitchen, a piggery, a warehouse, etc. without breeding germs.
本発明の資材は抗菌効果及び／又は防草効果を有する金属を０．０００１～５重量％含有するウッドチップモルタル組成物を含む。金属は金属イオンとして含有されることが好ましい。
抗菌効果を有する金属としては、銀、銅、白金などが挙げられる。
防草効果を有する金属としては、亜鉛、ニッケル、銅などが挙げられる。
前記金属の含有量は０．０００１～５重量％であるが、好ましくは０．００１～５重量％であり、より好ましくは０．０１～０．５重量％である。
The material of the present invention contains a wood chip mortar composition containing 0.0001 to 5% by weight of a metal having an antibacterial effect and / or a weed control effect. The metal is preferably contained as a metal ion.
Examples of the metal having an antibacterial effect include silver, copper and platinum.
Examples of the metal having a weed-proof effect include zinc, nickel and copper.
The content of the metal is 0.0001 to 5% by weight, preferably 0.001 to 5% by weight, and more preferably 0.01 to 0.5% by weight.
ウッドチップモルタルは、ウッドチップと、セメントと、骨材とを主成分としており、各成分を以下に説明する。 Woodchip mortar is mainly composed of woodchip, cement, and aggregate, and each component will be described below.
［ウッドチップ］
本発明の組成物はウッドチップを含むことにより、ウッドチップに含まれるリグニン等の作用により金属を効率よく吸着することができ、金属含有組成物を効率よく作製することができる。
ウッドチップとしては、リグニンやセルロースを含む木材を細かく切断又は粉砕したものが使用でき、木粉、木片、木毛、木繊維、パルプ、木質繊維束、木質ファイバー等が挙げられる。ここで、木粉としては、平均粒径が０．１～１ｍｍであるものが好ましく、木片としては、平均の長さが５～３０ｍｍの木片が好ましい。ウッドチップの原料となる木材の種類は特に限定されないが、例えば、杉、檜、松、栂、さわら、樫、なら、かば、ブナ、オーク、ラワン、ひば、栗、けやき、椎、柳、竹などの材料が挙げられる。廃材や間伐材を使用してもよい。
[Woodchip]
By containing the wood chips in the composition of the present invention, the metal can be efficiently adsorbed by the action of lignin and the like contained in the wood chips, and the metal-containing composition can be efficiently produced.
As the wood chip, one obtained by finely cutting or crushing wood containing lignin or cellulose can be used, and examples thereof include wood flour, wood chips, wood wool, wood fiber, pulp, wood fiber bundle, and wood fiber. Here, the wood powder preferably has an average particle size of 0.1 to 1 mm, and the wood piece preferably has an average length of 5 to 30 mm. The type of wood used as the raw material for wood chips is not particularly limited, but for example, cedar, cypress, pine, 栂, sawara, oak, nara, kaba, beech, oak, lauan, hiba, chestnut, keyaki, shii, willow, etc. Materials such as bamboo can be mentioned. Waste wood and thinned wood may be used.
［セメント］
本発明の組成物はセメントを含むことにより、アルカリ性にすることができ、その結果、ウッドチップに含まれるリグニン等への金属の吸着がより促進され、金属含有組成物を効率よく作製することができる。本発明者の検討により、ウッドチップモルタルを銅水溶液に浸漬した場合のウッドチップモルタルへの銅の吸着量は、ウッドチップのみを銅水溶液に浸漬した場合のウッドチップへの銅の吸着量の約７倍であることが分かった。
ウッドチップモルタルの成分であるセメントとしては、例えば、ポルトランドセメント、シリカセメント、フライアッシュセメント等のセメントがあるが、通常、ポルトランドセメントを使用することが好ましい。
[cement]
The composition of the present invention can be made alkaline by containing cement, and as a result, the adsorption of metals to lignin and the like contained in wood chips is further promoted, and the metal-containing composition can be efficiently produced. can. According to the study of the present inventor, the amount of copper adsorbed on the woodchip mortar when the woodchip mortar is immersed in the copper aqueous solution is about the amount of copper adsorbed on the woodchip when only the woodchip is immersed in the copper aqueous solution. It turned out to be 7 times.
Examples of cement that is a component of wood chip mortar include cement such as Portland cement, silica cement, and fly ash cement, but it is usually preferable to use Portland cement.
［骨材］
骨材としてはケイ酸（ＳｉＯ2）含有材料が挙げられ、具体的には、ケイ砂、珪石粉、
珪藻土、シリカフューム、フライアッシュ、ボトムアッシュ、高炉スラグ、鋼鉄スラグ等が挙げられる。
また、ケイ酸含有材料などの骨材は微細粉末であることが好ましく、例えば、平均粒径が０．１～１００μｍの微細粉末であることが好ましい。
例えば、ケイ砂粉末などの微細ケイ酸含有材料の原料砂は砕砂、山砂、海砂、川砂などが使用でき、これらの原料砂を円筒状の回転式粉砕機で粉砕し、分級機や篩で分級された微細ケイ酸含有材料を骨材として使用できる。
[aggregate]
Examples of the aggregate include silicic acid (SiO 2 ) -containing materials, specifically, silica sand, silica stone powder, and the like.
Examples thereof include diatomaceous earth, silica fume, fly ash, bottom ash, blast furnace slag, and steel slag.
Further, the aggregate such as a silicic acid-containing material is preferably a fine powder, and for example, a fine powder having an average particle size of 0.1 to 100 μm is preferable.
For example, crushed sand, mountain sand, sea sand, river sand, etc. can be used as the raw material sand for fine silicic acid-containing materials such as silica sand powder. The fine silicic acid-containing material classified in 1 can be used as an aggregate.
［その他の成分］
ウッドチップモルタルには上記主成分のほか、ベントナイトやマイカ等の鉱物由来物質、パーライト、シラスバルーン、バーミキュライト等の無機焼成発泡体、無機質成形体の粉砕物やリジェクト等のリターン原料、ミョウバンや水ガラス等の少量の硬化促進剤や、ロウ、ワックス、パラフィン、界面活性剤、シリコン等の防水剤や撥水剤、ポリスチレンやポリビニルアルコール等の樹脂成分、ポリプロピレン繊維などの有機繊維や、ワラストナイト等の無機繊維等が適宜混合されてもよい。
[Other ingredients]
In addition to the above-mentioned main components, wood chip mortar contains mineral-derived substances such as bentonite and mica, inorganic fired foam such as pearlite, silas balloon, and vermiculite, return raw materials such as crushed and rejected inorganic molded products, and myoban and water glass. A small amount of curing accelerator such as wax, wax, paraffin, surfactant, waterproofing agent such as silicon, water repellent, resin component such as polystyrene and polyvinyl alcohol, organic fiber such as polypropylene fiber, wallastnite, etc. Inorganic fibers and the like may be appropriately mixed.
［原料組成配合］
ウッドチップモルタル組成物における原料の配合割合は用途や施工箇所などによっても異なり、適宜調整可能であるが、例えば、ウッドチップ（乾燥重量として）２０～８０重量％に対し、モルタルを８０～２０重量％とすることが好ましい。この範囲にすることで、金属吸着力の高いウッドチップモルタルが得られる。モルタルにおけるセメントと骨材の割合は例えば、重量比で１：３～１：２である。
[Ingredient composition combination]
The mixing ratio of the raw materials in the wood chip mortar composition varies depending on the application and the place of construction, and can be adjusted as appropriate. It is preferably%. Within this range, a wood chip mortar having a high metal adsorption force can be obtained. The ratio of cement to aggregate in the mortar is, for example, 1: 3 to 1: 2 by weight.
［製造方法］
次に本発明に係るウッドチップモルタル資材の製造方法の一例について説明する。
まず、前記原料（ウッドチップ、セメント、骨材、その他の成分）を適量の水と混合して原料混合物とする。これを、例えば、オムニミキサー、ヘンシェルミキサーなどを使用して混合・混錬し、成型・養生を行う。例えば、前記原料混合物を型枠上に散布落下し、ホットプレス等により所定時間、加圧、加熱して硬化させた後、脱型することにより得ることができる。
[Production method]
Next, an example of a method for manufacturing a wood chip mortar material according to the present invention will be described.
First, the raw materials (wood chips, cement, aggregates, and other components) are mixed with an appropriate amount of water to prepare a raw material mixture. This is mixed and kneaded using, for example, an omni mixer, a Henschel mixer, etc., and molding and curing are performed. For example, it can be obtained by spraying and dropping the raw material mixture onto a mold, pressurizing and heating it with a hot press or the like for a predetermined time to cure it, and then removing the mold.
そして、得られたウッドチップモルタル成型体に金属イオンを含有させる。例えば、ウッドチップモルタル成型体を、上記抗菌効果及び／又は防草効果を有する金属イオンを０．００１～０．１％の濃度で含有する溶液中に一定時間含浸させることで金属イオンを含有するウッドチップモルタル成型体を得ることができる。含浸は例えば、常温で１～２４時間行うことができる。このようにして製造された金属イオンを含有するウッドチップモルタル成型体は３００日以上の長期間金属イオンを保持しており、長期の使用にも耐えうる。 Then, the obtained wood chip mortar molded body contains metal ions. For example, a wood chip mortar molded product is impregnated with a solution containing the metal ions having the antibacterial effect and / or the weed control effect at a concentration of 0.001 to 0.1% for a certain period of time to contain the metal ions. A wood chip mortar molded body can be obtained. Impregnation can be performed, for example, at room temperature for 1 to 24 hours. The wood chip mortar molded body containing the metal ions produced in this manner retains the metal ions for a long period of 300 days or more, and can withstand long-term use.
ただし、金属イオンを含むウッドチップモルタル組成物は、予め、ウッドチップモルタルの原料を混合するときに、金属イオンを含む水溶液を用いることによっても得ることができる。 However, the wood chip mortar composition containing metal ions can also be obtained by using an aqueous solution containing metal ions when mixing the raw materials of the wood chip mortar in advance.
本発明に係るウッドチップモルタル組成物は抗菌効果及び／又は防草効果を有する土木、建築、園芸資材等として有用であり、例えば、歩道、駐車場、公園の遊具周辺、車道のガードレール下、車道の中央分離帯、一般家庭の庭、家屋の壁面、食品を管理する倉庫や酪農・畜産施設などに使用することができる。 The wood chip mortar composition according to the present invention is useful as civil engineering, construction, horticultural materials and the like having an antibacterial effect and / or a weed control effect, and is used, for example, on a sidewalk, a parking lot, around play equipment in a park, under a guardrail on a roadway, or on a roadway. It can be used for median strips, gardens of ordinary households, sidewalks of houses, warehouses for managing food, and dairy and livestock facilities.
本発明に係るウッドチップモルタル組成物を含む資材の形状は特に限定されず、施工場所や用途によって適宜選択されるが、例えば、平板状とすることができる。
図１に、平板状の資材の施工例の一態様を示す。ここでは、３０ｃｍ×３０ｃｍの平板（厚さ６ｃｍ）を用意し、施工場所である道路の両端の間に平板を敷き詰めて道路の舗装に使用される。平板の形状や色、サイズ、敷き詰め方を工夫することでインターロッキングなども含め、様々な模様の外観を実現できる。
The shape of the material containing the wood chip mortar composition according to the present invention is not particularly limited and may be appropriately selected depending on the construction site and application, but may be, for example, a flat plate.
FIG. 1 shows an example of construction of a flat plate-shaped material. Here, a flat plate (thickness 6 cm) of 30 cm × 30 cm is prepared, and flat plates are spread between both ends of the road, which is the construction site, and used for road pavement. By devising the shape, color, size, and laying method of the flat plate, it is possible to realize the appearance of various patterns including interlocking.
そして、図２に示すように、従来の資材では平板上や平板を敷き詰めた境界に雑菌や雑草が繁殖していたのに対し、本発明に係るウッドチップモルタル組成物を含む資材を使用することにより、内部に含まれる金属の効果により雑菌や雑草が繁殖せず、安全で景観を損なわず衛生的な環境を実現できる。家屋の壁面等への適用も同様にして行うことができる。 Then, as shown in FIG. 2, while germs and weeds propagated on the flat plate or at the boundary where the flat plates were spread in the conventional material, the material containing the wood chip mortar composition according to the present invention should be used. As a result, germs and weeds do not propagate due to the effect of the metal contained inside, and a safe and hygienic environment can be realized without damaging the landscape. It can be applied to the wall surface of a house in the same manner.
以下、実施例を挙げて本発明をより具体的に説明するが、本発明の態様は以下の実施例には限定されない。 Hereinafter, the present invention will be described in more detail with reference to examples, but the embodiments of the present invention are not limited to the following examples.
［製造例１］
重量比で、セメント１に対して２．５倍のケイ砂を混合し、さらに、これにセメントと砂のトータル容積に対して５０容積％のウッドチップを混合する。ウッドチップは杉の木を素材とし、平均長さ約２０ｍｍ、平均厚さ約３ｍｍのものを使用した。セメント重量１ｋｇに対して、０．４５リットルの水を添加し、混練りしてウッドチップ含有セメントモルタルを調製した。このウッドチップ含有セメントモルタルを、３０ｃｍ×３０ｃｍの型枠に流し込み、圧力９４ｋｇｆ/ｃｍ2、温度４５℃で５時間、加圧・加熱成型した。その後、成型されたウッドチップモルタルを型枠から外し、銅イオンを０．００６％の濃度で含む水溶液に常温で２４時間含浸させたのち溶液から引き上げ、水で洗浄後24時間常温で乾燥させた。得られたウッドチップモルタル成型体は銅イオンを０．０６重量％濃度含有していた。
[Manufacturing Example 1]
2.5 times the weight of silica sand is mixed with 1 cement, and 50% by volume of wood chips are mixed with the total volume of cement and sand. The wood chips used were made of cedar wood, with an average length of about 20 mm and an average thickness of about 3 mm. 0.45 liters of water was added to 1 kg of cement weight and kneaded to prepare a wood chip-containing cement mortar. This wood chip-containing cement mortar was poured into a mold of 30 cm × 30 cm, and pressured and heat-molded at a pressure of 94 kgf / cm 2 and a temperature of 45 ° C. for 5 hours. Then, the molded wood chip mortar was removed from the mold, impregnated with an aqueous solution containing copper ions at a concentration of 0.006% at room temperature for 24 hours, pulled out of the solution, washed with water, and dried at room temperature for 24 hours. .. The obtained wood chip mortar molded product contained copper ions at a concentration of 0.06% by mass.
［製造例２］
重量比で、セメント１に対して２．５倍のケイ砂を混合し、さらに、これにセメントと砂のトータル容積に対して５０容積％のウッドチップを混合する。ウッドチップは杉の木を素材とし、平均長さ約２０ｍｍ、平均厚さ約３ｍｍのものを使用した。セメント重量１ｋｇに対して、０．４５リットルの水を添加し、混練りしてウッドチップ含有セメントモルタルを調製した。このウッドチップ含有セメントモルタルを、３０ｃｍ×３０ｃｍの型枠に流し込み、圧力９４ｋｇｆ/ｃｍ2、温度４５℃で５時間、加圧・加熱成型した。その後、成型されたウッドチップモルタルを型枠から外し、銀イオンを０．０１％の濃度で含む水溶液に常温で２４時間含浸させた。得られたウッドチップモルタル成型体は銀イオンを０．１重量％濃度含有していた。
[Manufacturing Example 2]
2.5 times the weight of silica sand is mixed with 1 cement, and 50% by volume of wood chips are mixed with the total volume of cement and sand. The wood chips used were made of cedar wood, with an average length of about 20 mm and an average thickness of about 3 mm. 0.45 liters of water was added to 1 kg of cement weight and kneaded to prepare a wood chip-containing cement mortar. This wood chip-containing cement mortar was poured into a mold of 30 cm × 30 cm, and pressured and heat-molded at a pressure of 94 kgf / cm 2 and a temperature of 45 ° C. for 5 hours. Then, the molded wood chip mortar was removed from the mold and impregnated with an aqueous solution containing silver ions at a concentration of 0.01% at room temperature for 24 hours. The obtained wood chip mortar molded product contained silver ions at a concentration of 0.1% by mass.
[実施例１]
製造例１で得られた銅イオンを含有するウッドチップモルタル平板を園芸用土の上に敷き、西洋芝とホウレンソウのタネを蒔き２２℃で一定期間（１４日）散水して育成を試みたが、発芽が確認されなかった。
[Example 1]
A wood chip mortar flat plate containing copper ions obtained in Production Example 1 was laid on horticultural soil, and seeds of western turf and spinach were sown and sprinkled at 22 ° C for a certain period (14 days) to grow. No germination was confirmed.
[実施例２]
製造例２で得られた銀イオンを吸着させたウッドチップモルタル平板をカビが生えた培地に設置して２２℃で２１日間放置したところ、カビの繁殖が抑制されることが確認できた。
[Example 2]
When the wood chip mortar plate on which the silver ion obtained in Production Example 2 was adsorbed was placed on a medium on which mold grew and left at 22 ° C. for 21 days, it was confirmed that the growth of mold was suppressed.
[比較例１]
製造例１の銅イオンを含浸させる前のウッドチップモルタル平板を園芸用土の上に敷き、西洋芝とホウレンソウのタネを蒔き２２℃で一定期間（１４日）散水して育成を試みたところ、発芽が確認された。
[Comparative Example 1]
A wood chip mortar flat plate before impregnation with copper ions of Production Example 1 was laid on horticultural soil, and seeds of western turf and spinach were sown and sprinkled at 22 ° C for a certain period (14 days) to try to germinate. Was confirmed.
[比較例２]
製造例２の銀イオンを含浸させる前のウッドチップモルタル平板をカビが生えた培地に設置して２２℃で２１日間放置したところ、ウッドチップモルタル平板にカビの繁殖が確認された。
[Comparative Example 2]
When the wood chip mortar plate before impregnation with the silver ion of Production Example 2 was placed in a medium on which mold grew and left at 22 ° C. for 21 days, the growth of mold was confirmed on the wood chip mortar plate.
以上より、本発明のウッドチップモルタル組成物を含む資材は防草効果及び／又は抗菌効果を有し、土木、建築又は園芸用資材として優れることがわかった。 From the above, it was found that the material containing the wood chip mortar composition of the present invention has a weed-proofing effect and / or an antibacterial effect, and is excellent as a material for civil engineering, construction or horticulture.
＜ウッドチップモルタルとポーラスモルタルとの比較＞
砂、ウッドチップ、セメントを重量比2：2：1の割合で混合し、成型したものをウッド
チップモルタル（WPM）とした。
比較対象として、砂とセメントを重量比4：1で混合し、成型したものをポーラスモルタル（以下PMと称する）とした。
これらを食塩水に一定期間浸漬することにより、0から75％程度、内部に含まれるカル
シウムを溶脱させ、それぞれ、次の重金属吸着試験に用いた。
結果を図３に示す。図３は横軸にPMまたはWPMのカルシウム溶脱率、縦軸に重金属の吸
着率とｐＨの変化を示している。その結果、PMにおいては、カルシウム溶脱前では、銅を定量的に吸着していたが、カルシウムの溶脱率が大きくなるにしたがって、銅の吸着率が急激に減少することがわかった。また、これに伴い、ｐＨも１３から３まで低下することがわかった。
一方、WPMの場合は、カルシウムの溶脱率に関わらず、銅に対し80％以上の吸着率を維
持し、ｐＨもほとんど低下しなかった。これらの結果から、本発明のウッドチップモルタル組成物を含む資材は長期間環境中に置かれて資材自体が劣化しても、銅の吸着能を維持しており、耐久性に優れた防草効果及び／又は抗菌効果を有する土木、建築又は園芸用資材として有用であることがわかった。
<Comparison between wood chip mortar and porous mortar>
Sand, wood chips, and cement were mixed at a weight ratio of 2: 2: 1 and molded into wood chip mortar (WPM).
For comparison, sand and cement were mixed at a weight ratio of 4: 1 and molded into a porous mortar (hereinafter referred to as PM).
By immersing these in a saline solution for a certain period of time, calcium contained in the inside was leached by about 0 to 75%, and each of them was used for the next heavy metal adsorption test.
The results are shown in FIG. In FIG. 3, the horizontal axis shows the calcium leaching rate of PM or WPM, and the vertical axis shows the adsorption rate of heavy metals and changes in pH. As a result, it was found that in PM, copper was quantitatively adsorbed before calcium leaching, but as the calcium leaching rate increased, the copper adsorption rate decreased sharply. Along with this, it was found that the pH also decreased from 13 to 3.
On the other hand, in the case of WPM, the adsorption rate of 80% or more with respect to copper was maintained regardless of the leaching rate of calcium, and the pH hardly decreased. From these results, the material containing the wood chip mortar composition of the present invention maintains the adsorptive ability of copper even when the material itself deteriorates after being left in the environment for a long period of time, and has excellent durability. It has been found to be useful as a civil engineering, building or horticultural material with an effect and / or an antibacterial effect.
Claims (5)
前記ウッドチップはリグニンを含み、
前記ウッドチップは平均の長さが５～３０ｍｍの木片であり、
前記防草効果を有する金属が亜鉛、ニッケル、又は銅である、
防草用のウッドチップモルタル組成物。 A wood chip mortar composition containing wood chips and a mortar for weed control , which contains 0.001 to 5% by weight of a metal having a weed control effect.
The wood chips contain lignin and
The wood chips are pieces of wood with an average length of 5 to 30 mm.
The metal having the weed control effect is zinc, nickel, or copper.
Woodchip mortar composition for weed control.
前記ウッドチップは平均の長さが５～３０ｍｍの木片である、製造方法。 The civil engineering, horticultural or horticultural work for weed control according to claim 4 , wherein the wood chip mortar containing the wood chips and the mortar is impregnated with a solution of a metal having a weed control effect selected from zinc, nickel, and copper. It is a manufacturing method of gardening materials.
A method of manufacturing the wood chip, which is a piece of wood having an average length of 5 to 30 mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016234465A JP7035295B2 (en) | 2016-12-01 | 2016-12-01 | A woodchip mortar composition containing a metal having a weed-proofing effect and / or an antibacterial effect. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016234465A JP7035295B2 (en) | 2016-12-01 | 2016-12-01 | A woodchip mortar composition containing a metal having a weed-proofing effect and / or an antibacterial effect. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2018090437A JP2018090437A (en) | 2018-06-14 |
| JP7035295B2 true JP7035295B2 (en) | 2022-03-15 |
Family
ID=62565145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016234465A Active JP7035295B2 (en) | 2016-12-01 | 2016-12-01 | A woodchip mortar composition containing a metal having a weed-proofing effect and / or an antibacterial effect. |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP7035295B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7361677B2 (en) * | 2020-08-27 | 2023-10-16 | 東興ジオテック株式会社 | Weed control method for sloped land |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000128608A (en) | 1998-10-26 | 2000-05-09 | Showa Denko Kk | Flame resistant cement formed product reinforced by modified pulp |
| JP2004511421A (en) | 2000-10-17 | 2004-04-15 | ジェイムズ ハーディー リサーチ ピーティーワイ．リミテッド | Fiber cement composite using durable cellulose fibers treated with biocide |
| JP2006248837A (en) | 2005-03-10 | 2006-09-21 | Kyushu Electric Power Co Inc | Chip mix |
| JP2015059107A (en) | 2013-09-19 | 2015-03-30 | ユニチカ株式会社 | Weed prevention sheet |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3358714B2 (en) * | 1997-12-16 | 2002-12-24 | 三菱マテリアル株式会社 | Antibacterial concrete, antibacterial mortar and method for producing them |
-
2016
- 2016-12-01 JP JP2016234465A patent/JP7035295B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000128608A (en) | 1998-10-26 | 2000-05-09 | Showa Denko Kk | Flame resistant cement formed product reinforced by modified pulp |
| JP2004511421A (en) | 2000-10-17 | 2004-04-15 | ジェイムズ ハーディー リサーチ ピーティーワイ．リミテッド | Fiber cement composite using durable cellulose fibers treated with biocide |
| JP2006248837A (en) | 2005-03-10 | 2006-09-21 | Kyushu Electric Power Co Inc | Chip mix |
| JP2015059107A (en) | 2013-09-19 | 2015-03-30 | ユニチカ株式会社 | Weed prevention sheet |
Non-Patent Citations (2)
| Title |
|---|
| MORI Masanobuら，Adsorptivity of heavy metals CuII, CdII, and PbII on woodchip-mixed porous mortar，Chemical Engineering Journal，2013年01月15日，Vol.215-216，P.202-208 |
| 鈴木裕二, 半井健一郎, 森勝伸 , 小林祐介，ウッドチップ混入ポーラスモルタルのカルシウム溶脱による強度変化，土木学会全国大会年次学術講演会講演概要集，2010年09月，Vol.65，P.923-924 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2018090437A (en) | 2018-06-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11365152B2 (en) | Cement-free porous substrate for plant germination and growth made of alkali-activated pozzolans | |
| JP2003052241A (en) | A vegetation medium base material, a vegetation medium molded body, a method for producing the same, and a greening method using a vegetation medium molded body block. | |
| US9523175B2 (en) | Binder composition and path material comprising a binder composition | |
| JP2003052241A5 (en) | ||
| CN107572952A (en) | A kind of plant-growing type eco-concrete and its preparation and application | |
| JP7035295B2 (en) | A woodchip mortar composition containing a metal having a weed-proofing effect and / or an antibacterial effect. | |
| KR101815017B1 (en) | Manufacturing method of eco-friendly colonnade protective plate using oyster shell and eco-friendly colonnade protective plate and staging process | |
| CN110240451B (en) | Greening concrete and construction method thereof | |
| JP5800259B2 (en) | Soil material | |
| JP3865700B2 (en) | Greening medium | |
| JP2008002225A (en) | Water absorbing/retaining carbide-coated aggregate and water absorbing/retaining paving material using the same | |
| JP2000170318A (en) | Manufacture of wooden block/concrete structural body, structural body obtained thereby and using method thereof | |
| JP6405594B2 (en) | Interlocking block | |
| JP2010104271A (en) | Greening concrete, and method for producing the same | |
| JP2015158119A (en) | Mixing of material and construction method for water-permeable, water-retaining and weed-proof pavement containing shirasu balloon | |
| JP2002220273A (en) | Gypsum-based structural material, method for manufacturing gypsum-based structural material, and construction method for structure using gypsum-based structural material | |
| EP2570028B1 (en) | Free-flowing composite particle for inhibiting plant growth and use of same | |
| JP3858079B2 (en) | Lightweight shirasu base, greening shirasu base and manufacturing method thereof | |
| JP3780266B2 (en) | Weed control structure and weed control permeability construction method | |
| WO2005032253A1 (en) | Curable termite control composition | |
| JP6545637B2 (en) | Zeolite-containing hardened body and method for producing zeolite-containing hardened body | |
| KR100804204B1 (en) | Ocher aggregate and its manufacturing method | |
| JP2003239210A (en) | Raw material for pavement finishing material, method for producing pavement finishing material, and pavement finishing method | |
| KR101110219B1 (en) | Manufacturing method of vegetation block | |
| KR20110002297A (en) | Manufacturing method of environmentally friendly Masato brick with phytoncide and Masato brick |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20191114 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20201030 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20201110 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210108 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210420 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20210617 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210812 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20211109 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20211227 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20220118 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20220208 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7035295 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |