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JP4301110B2 - Continuous molding method and apparatus for fiber reinforced resin molded product - Google Patents

Continuous molding method and apparatus for fiber reinforced resin molded product Download PDF

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JP4301110B2
JP4301110B2 JP2004239080A JP2004239080A JP4301110B2 JP 4301110 B2 JP4301110 B2 JP 4301110B2 JP 2004239080 A JP2004239080 A JP 2004239080A JP 2004239080 A JP2004239080 A JP 2004239080A JP 4301110 B2 JP4301110 B2 JP 4301110B2
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resin
carrier film
layer
pattern material
fiber
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JP2006056089A (en
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昭二 簗田
康雄 角井
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Nitto Boseki Co Ltd
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Description

本発明は、表面層が柄材を含有した意匠性に優れた繊維補強樹脂成形品の成形方法及び装置に関する。   The present invention relates to a molding method and apparatus for a fiber-reinforced resin molded article having a surface layer containing a pattern material and excellent in design.

従来より、表面層が柄材を含み、基材層が繊維材で強化されている樹脂成形品が、浴室床材、壁材などの種々な用途に用いられている。この種の樹脂成形品の製造には、柄材を有する成形用シートと繊維強化樹脂成形材料とを重ね合わせて金型にセットし、金型内で一体に熱圧成形する方法が用いられている。例えば、特開2001−62949号公報(特許文献1)には、柄材を含有する加飾用バルクモールディングコンパウンド(BMC)からなる表面材と、柄材を含有しないシートモールディングコンパウンド(SMC)やBMCなどの繊維強化樹脂成形材料からなる裏側材とを重ね、金型内で一体に熱圧成形することで加飾FRP成形品を製造する方法が記載されている。また、特開平9−174792号公報(特許文献2)には、印刷または模様付けされた基材シートに、柄材を含有した熱硬化性樹脂組成物を含浸させた構成の加飾成形用シートを作成し、その加飾成形用シートを、SMCやBMCなどの熱硬化性成形材料と共に金型内にセットし、熱プレス成形して加飾成形品を製造する方法が記載されている。   Conventionally, resin molded products in which a surface layer includes a pattern material and a base material layer is reinforced with a fiber material have been used for various applications such as bathroom floor materials and wall materials. For the production of this type of resin molded product, a method is used in which a molding sheet having a pattern material and a fiber reinforced resin molding material are overlapped and set in a mold, and are integrally heat-pressure molded in the mold. Yes. For example, Japanese Patent Laid-Open No. 2001-62949 (Patent Document 1) discloses a surface material made of a decorative bulk molding compound (BMC) containing a pattern material, and a sheet molding compound (SMC) or BMC containing no pattern material. A method of manufacturing a decorated FRP molded product by stacking a back side material made of a fiber reinforced resin molding material such as the above and integrally hot pressing in a mold is described. JP-A-9-174792 (Patent Document 2) discloses a decorative molding sheet having a structure in which a printed or patterned base sheet is impregnated with a thermosetting resin composition containing a pattern material. Is prepared, and the decorative molding sheet is set in a mold together with a thermosetting molding material such as SMC or BMC, followed by hot press molding to produce a decorative molded product.

しかしながら、従来の製造方法は金型を用いた熱プレス成形であるので長尺ものが生産できないという問題があった。また、SMCやBMCを用いているので出来上がった製品は剛性の大きいものとなり、柔軟性を持った製品を製造できないという問題もあった。   However, since the conventional manufacturing method is hot press molding using a mold, there is a problem that a long product cannot be produced. Further, since SMC and BMC are used, the finished product has a large rigidity, and there is a problem that a flexible product cannot be manufactured.

ところで、従来よりFRPシートの連続成形方法が知られている。この連続成形方法は、第一のキャリアフィルムを所定の走行経路に沿って走行させ、そのキャリアフィルムの上に液状の熱硬化性樹脂を所定厚さに供給し、その上に補強用繊維材を供給し、含浸ローラ等で樹脂を補強用繊維材に含浸させて樹脂含浸繊維層を形成し、更にその上に第二のキャリアフィルムをかぶせ、必要に応じ、第一のキャリアフィルムと第二のキャリアフィルムの外側から脱泡ローラ等で樹脂含浸繊維層を挟み付けて脱泡及び厚さ規制を行い、次いで、硬化炉を通過させて樹脂を加熱、硬化させ、その後、第一及び第二のキャリアフィルムを剥がすという方法であり、これにより、長尺のFRPシートを生産性良く製造することができる。ここで用いるキャリアフィルムは、通常は平面フィルムであるが、平面フィルムに代えてエンボス加工したフィルムを用いることで、表面をエンボス面としたFRPシートを製造することも知られている[例えば、特開昭57−144724号公報(特許文献3)参照]。   By the way, the continuous forming method of FRP sheet is known conventionally. In this continuous molding method, a first carrier film is caused to travel along a predetermined traveling path, a liquid thermosetting resin is supplied to the carrier film in a predetermined thickness, and a reinforcing fiber material is provided thereon. Then, the fiber material for reinforcement is impregnated with an impregnation roller or the like to form a resin-impregnated fiber layer, and a second carrier film is placed thereon, and if necessary, the first carrier film and the second carrier film are covered. The resin-impregnated fiber layer is sandwiched by a defoaming roller or the like from the outside of the carrier film to perform defoaming and thickness regulation, then the resin is heated and cured by passing through a curing furnace, and then the first and second In this method, the carrier film is peeled off, whereby a long FRP sheet can be produced with high productivity. The carrier film used here is usually a flat film, but it is also known to produce an FRP sheet having an embossed surface by using an embossed film instead of the flat film [for example, a special film. No. 57-144724 (Patent Document 3)].

そこで、本発明者らは、柄材を含有する長尺の繊維補強樹脂成形品を製造するため、従来より知られていたFRPシートの連続成形方法を適用することに着目し、第一のキャリアフィルム上に供給する液状の熱硬化性樹脂として、柄材を均一に混合した熱硬化性樹脂を用いて連続成形を行なった。ところが、液状の熱硬化性樹脂に柄材を良好に混合、分散させてキャリアフィルム上に供給しても、その樹脂に補強用繊維材を含浸させた際に柄材の分散が不均一となってしまい、柄材の分散むらが大きくなり、得られたFRPシートの外観が悪くなるという問題が生じた。
特開2001−62949号公報 特開平9−174792号公報 特開昭57−144724号公報
Accordingly, the present inventors have focused on applying a conventionally known FRP sheet continuous molding method to produce a long fiber-reinforced resin molded product containing a pattern material, and the first carrier Continuous molding was performed using a thermosetting resin in which a pattern material was uniformly mixed as a liquid thermosetting resin to be supplied onto the film. However, even if the pattern material is well mixed and dispersed in the liquid thermosetting resin and supplied onto the carrier film, the dispersion of the pattern material becomes uneven when the resin is impregnated with the reinforcing fiber material. As a result, the dispersion of the pattern material is increased, resulting in a problem that the appearance of the obtained FRP sheet is deteriorated.
JP 2001-62949 A JP-A-9-174792 JP-A-57-144724

本発明はかかる状況に鑑みてなされたもので、表面層が柄材を良好に分散させた形態で含有し、基材層が繊維材で強化されている長尺の樹脂成形品を生産性良く製造することを可能とし、且つ柔軟性を有する樹脂成形品を製造することも可能とする繊維補強樹脂成形品の連続成形方法及び装置を提供することを課題とする。   The present invention has been made in view of such a situation, and a long resin molded product in which the surface layer is contained in a form in which the pattern material is well dispersed and the base material layer is reinforced with a fiber material has high productivity. It is an object of the present invention to provide a continuous molding method and apparatus for a fiber-reinforced resin molded product that can be produced and that can also produce a flexible resin molded product.

本願請求項1に係る発明の連続成形方法は、表面層に柄材を良好に分散させた形態で含有する繊維補強樹脂成形品を連続成形することを可能とするため、所定の経路を走行中の第一のキャリアフィルムの上に液状の熱硬化性樹脂と補強用繊維材とを供給し且つ補強用繊維材に熱硬化性樹脂を含浸させて樹脂含浸繊維層を形成する工程と、所定の経路を走行中の第二のキャリアフィルムの上に、あらかじめ柄材を混合、分散させた液状の熱硬化性樹脂を供給して柄材含有樹脂層を形成する工程と、前記第二のキャリアフィルムに保持されて走行中の前記柄材含有樹脂層を半硬化させる工程と、前記第一のキャリアフィルム上に形成されている樹脂含浸繊維層の上に、半硬化した柄材含有樹脂層を第二のキャリアフィルムと共に、前記柄材含有樹脂層を前記樹脂含浸繊維層に対面させて重ね合わせる工程と、重ね合わされ、前記第一及び第二のキャリアフィルムで挟まれて走行中の前記樹脂含浸繊維層と柄材含有樹脂層を硬化させる工程を有する構成としたものである。 In the continuous molding method of the invention according to claim 1 of the present invention, it is possible to continuously mold a fiber-reinforced resin molded product containing a pattern material in a form in which a pattern material is well dispersed in a surface layer. Supplying a liquid thermosetting resin and a reinforcing fiber material onto the first carrier film, and impregnating the reinforcing fiber material with the thermosetting resin to form a resin-impregnated fiber layer; Forming a pattern material-containing resin layer by supplying a liquid thermosetting resin in which a pattern material is mixed and dispersed in advance on a second carrier film traveling on a path; and the second carrier film A semi-cured pattern material-containing resin layer formed on the first carrier film and a resin-impregnated fiber layer formed on the first carrier film. Along with the second carrier film, the pattern material-containing tree A step of facing and overlapping the resin-impregnated fiber layer, and a step of curing the resin-impregnated fiber layer and the handle material-containing resin layer that are being overlapped and being sandwiched between the first and second carrier films It is set as the structure which has.

請求項2に係る発明は、上記した請求項1に係る発明において、前記第二のキャリアフィルムをエンボス加工されたシートとしたことを特徴とするものである。   The invention according to claim 2 is the invention according to claim 1, wherein the second carrier film is an embossed sheet.

請求項3に係る発明は、上記した請求項1に係る発明において、前記柄材を樹脂の粒状物若しくは樹脂フィルムの裁断物としたものである。   The invention according to claim 3 is the invention according to claim 1 described above, wherein the pattern material is a resin granule or a cut product of a resin film.

請求項4に係る発明は、上記した請求項1に係る発明の連続成形方法を実施するために用いる装置を提供するものであり、所定の経路に沿って走行するように設けられた第一のキャリアフィルムと、走行中の前記第一のキャリアフィルムの上に液状の熱硬化性樹脂と補強用繊維材とを供給し且つ補強用繊維材に熱硬化性樹脂を含浸させて樹脂含浸繊維層を形成する樹脂含浸繊維層形成手段と、水平な経路を走行した後、反転して前記第一のキャリアフィルムに重なる位置を走行するように設けられた第二のキャリアフィルムと、前記水平な経路を走行中の第二のキャリアフィルムの上に、あらかじめ柄材を混合、分散させた液状の熱硬化性樹脂を供給して柄材含有樹脂層を形成する柄材含有樹脂層形成手段と、前記第二のキャリアフィルムに保持されて走行中の前記柄材含有樹脂層を半硬化させるよう加熱する半硬化用加熱装置と、半硬化した柄材含有樹脂層を第二のキャリアフィルムと共に、前記第一のキャリアフィルム上に形成されている樹脂含浸繊維層に、前記柄材含有樹脂層を前記樹脂含浸繊維層に対面させて重ね合わせる重ね合わせ手段と、重ね合わされ、前記第一及び第二のキャリアフィルムで挟まれて走行中の前記樹脂含浸繊維層と柄材含有樹脂層を硬化させるよう加熱する硬化用加熱装置を有することを特徴とする繊維補強樹脂成形品の連続成形装置である。 The invention according to claim 4 provides an apparatus used for carrying out the continuous molding method of the invention according to claim 1 described above, and is a first device provided to travel along a predetermined route. A liquid thermosetting resin and a reinforcing fiber material are supplied onto the carrier film and the running first carrier film, and the reinforcing fiber material is impregnated with the thermosetting resin to form a resin-impregnated fiber layer. A resin-impregnated fiber layer forming means to be formed, a second carrier film provided so as to travel in a position that overlaps the first carrier film after traveling along a horizontal path, and the horizontal path A pattern material-containing resin layer forming means for supplying a liquid thermosetting resin in which a pattern material is mixed and dispersed in advance to form a pattern material-containing resin layer on the traveling second carrier film; Second carrier film A semi-curing heating device that heats the handle material-containing resin layer being held and semi-cured and a semi-cured handle material-containing resin layer together with a second carrier film on the first carrier film. Overlaid on the formed resin-impregnated fiber layer with an overlapping means for overlapping the pattern material-containing resin layer so as to face the resin-impregnated fiber layer, it is overlapped and traveled by being sandwiched between the first and second carrier films A continuous molding device for a fiber-reinforced resin molded product, comprising a curing heating device for heating the resin-impregnated fiber layer and the pattern material-containing resin layer therein.

請求項5に係る発明は、上記した請求項4に係る発明において、前記第二のキャリアフィルムをエンボス加工されたシートとしたことを特徴とするものである。   The invention according to claim 5 is the invention according to claim 4, wherein the second carrier film is an embossed sheet.

上記した本発明の繊維補強樹脂成形品の成形方法及び装置では、あらかじめ柄材を混合、分散させた液状の熱硬化性樹脂を第二のキャリアフィルムの上に供給して柄材含有樹脂層を形成し、その柄材含有樹脂層を半硬化させた後、第一のキャリアフィルム上に形成されている樹脂含浸繊維層の上に積層して一体化し、加熱、硬化させる構成としたことにより、第二のキャリアフィルム上に柄材を良好に分散させた柄材含有樹脂層を形成しておけば、その柄材の分散状態を乱すことなく樹脂含浸繊維層に積層、一体化することができ、また、第二のキャリアフィルム上に形成した柄材含有樹脂層は繊維材に含浸させないので、柄材を良好に分散させた液状の熱硬化性樹脂を第二のキャリアフィルム上に供給することで、柄材を良好に分散させた状態の柄材含有樹脂層を容易に形成できる。かくして、表面層が柄材を良好に分散させた形態で含み、基材層が繊維材で強化されている構造の繊維補強樹脂成形品を連続的に成形することができ、従って、表面の意匠性の良い繊維補強樹脂成形品を生産性良く且つ所望の長さに製造することができ、長尺の繊維補強樹脂成形品も製造できる。また、連続成形に当たって、第一のキャリアフィルム上に供給する熱硬化性樹脂と補強用繊維材の材質、形態、供給量、混合割合等は所望のように選定できるので、これらの適切な選定により適度な柔軟性を備えた繊維補強樹脂成形品を製造することも可能であり、ロール状に巻き取った形態の長尺の繊維補強樹脂成形品の製造も可能となる。 In the above-described method and apparatus for molding a fiber-reinforced resin molded article of the present invention, a liquid thermosetting resin in which a pattern material is mixed and dispersed in advance is supplied onto the second carrier film to form a pattern material-containing resin layer. After forming and semi-curing the pattern material-containing resin layer, it is laminated and integrated on the resin-impregnated fiber layer formed on the first carrier film, and is heated and cured. If a pattern material-containing resin layer in which the pattern material is well dispersed is formed on the second carrier film, it can be laminated and integrated with the resin-impregnated fiber layer without disturbing the dispersion state of the pattern material. Also, since the pattern material-containing resin layer formed on the second carrier film is not impregnated into the fiber material, a liquid thermosetting resin in which the pattern material is well dispersed is supplied onto the second carrier film. With the pattern material dispersed well The pattern material containing resin layer state can be easily formed. Thus, it is possible to continuously form a fiber reinforced resin molded article having a structure in which the surface layer contains the pattern material in a well-dispersed form and the base material layer is reinforced with the fiber material. A good fiber-reinforced resin molded product can be manufactured to a desired length with high productivity, and a long fiber-reinforced resin molded product can also be manufactured. In addition, the material, shape, supply amount, mixing ratio, etc. of the thermosetting resin and the reinforcing fiber material supplied onto the first carrier film can be selected as desired during continuous molding. It is also possible to manufacture a fiber reinforced resin molded product having appropriate flexibility, and it is also possible to manufacture a long fiber reinforced resin molded product wound up in a roll shape.

ここで、第二のキャリアフィルムをエンボス加工されたフィルムとしておくと、その第二のキャリアフィルム上に形成される柄材含有樹脂層にキャリアフィルムのエンボス面を転写することができ、表面層が柄材を良好に分散させた形態で含有し且つその表面がエンボス面となった繊維補強樹脂成形品を連続的に成形し、生産性良く製造することができるという効果が得られる。   Here, if the second carrier film is an embossed film, the embossed surface of the carrier film can be transferred to the pattern material-containing resin layer formed on the second carrier film, and the surface layer An effect is obtained that a fiber-reinforced resin molded product containing the pattern material in a well-dispersed form and having an embossed surface on the surface can be continuously molded and manufactured with high productivity.

また、前記柄材を樹脂の粒状物若しくは樹脂フィルムの裁断物としておくと、この柄材を液状の熱硬化性樹脂に入れて混合する際、熱硬化性樹脂と柄材との比重差が小さいので均一な混合状態を得ることが容易であり、第二のキャリアフィルム上に柄材含有樹脂層を形成した際に、その柄材含有樹脂層内での柄材の分散状態をきわめて均一とすることができ、表面層が柄材を一層均一に分散させた形態で含んだ繊維補強樹脂成形品を連続的に成形し、生産性良く製造することができるという効果が得られる。   In addition, when the pattern material is a resin granule or a resin film cut, when the pattern material is mixed in a liquid thermosetting resin, the specific gravity difference between the thermosetting resin and the pattern material is small. Therefore, it is easy to obtain a uniform mixed state, and when the pattern material-containing resin layer is formed on the second carrier film, the dispersion state of the pattern material in the pattern material-containing resin layer is made extremely uniform. The fiber reinforced resin molded product in which the surface layer contains the pattern material in a more uniformly dispersed form can be continuously molded and can be manufactured with good productivity.

図1(a)、(b)はそれぞれ、本発明方法及び装置によって製造する繊維補強樹脂成形品(以下樹脂成形品と略称する)の代表例を示す概略断面図である。図1(a)に示す樹脂成形品1は、表面層2と基材層3を備えた積層体である。表面層2はマトリックス樹脂4内に柄材5を良好に分散させた構造であり、基材層3はマトリックス樹脂7を補強用繊維材8で強化した構造である。表面層2の表面及び基材層3の表面は共に平坦面となっている。図1(b)に示す樹脂成形品1Aも、図1(a)に示す樹脂成形品1と同様に表面層2と基材層3を備えた積層体であるが、表面層2の表面をエンボス面としている。その他の構成は樹脂成形品1と同様である。これらの樹脂成形品1、1Aは共に、柄材を良好に分散させた表面層2を備えたことで優れた意匠性を備えており、また、繊維強化された基材層3を備えたことで優れた強度特性、耐久性、耐水性等を備えている。なお、表面層2には意匠的な効果を発揮させるのみならず、必要に応じ、マトリックス樹脂4の材質や充填物の選定により防水性、親水性、耐候性等の特性を持たせることもできる。樹脂成形品1、1Aの厚さは、その樹脂成形品1、1Aの使用目的に応じて適宜定められるものであり、多くの場合、全体の厚さは0.5〜3.0mm程度に選定され、表面層2の厚さは0.2〜1.0mm程度に選定される。表面層2、基材層3等の各組成については、後述する。   FIGS. 1A and 1B are schematic cross-sectional views showing typical examples of fiber-reinforced resin molded products (hereinafter abbreviated as resin molded products) manufactured by the method and apparatus of the present invention, respectively. A resin molded product 1 shown in FIG. 1A is a laminate including a surface layer 2 and a base material layer 3. The surface layer 2 has a structure in which the pattern material 5 is well dispersed in the matrix resin 4, and the base material layer 3 has a structure in which the matrix resin 7 is reinforced with the reinforcing fiber material 8. Both the surface of the surface layer 2 and the surface of the base material layer 3 are flat surfaces. The resin molded product 1A shown in FIG. 1 (b) is also a laminate including the surface layer 2 and the base material layer 3 like the resin molded product 1 shown in FIG. 1 (a). Embossed surface. Other configurations are the same as those of the resin molded product 1. Both of these resin molded products 1 and 1A have an excellent design by having a surface layer 2 in which a pattern material is well dispersed, and also have a base layer 3 reinforced with fibers. It has excellent strength characteristics, durability, water resistance, etc. In addition, the surface layer 2 can not only exhibit a design effect, but can also have characteristics such as waterproofness, hydrophilicity, and weather resistance by selecting the material and filler of the matrix resin 4 as necessary. . The thickness of the resin molded product 1 or 1A is appropriately determined according to the purpose of use of the resin molded product 1 or 1A. In many cases, the overall thickness is selected to be about 0.5 to 3.0 mm. The thickness of the surface layer 2 is selected to be about 0.2 to 1.0 mm. Each composition of the surface layer 2, the base material layer 3, etc. is mentioned later.

次に、本発明の好適な実施の形態に係る樹脂成形品の連続成形装置及びそれを用いた連続成形方法を説明する。図2は、図1に示す樹脂成形品1又は1Aを連続的に成形する連続成形装置10を概略的に示すものである。図2において、11は第一のキャリアフィルム(以下下部キャリアフィルムという)であり、キャリアフィルムロール11Aから引き出され、水平に設定された所定の経路に沿って走行し、キャリアフィルムロール11Bに巻き取られるようになっている。この下部キャリアフィルム11には平面フィルムが用いられている。   Next, a continuous molding apparatus for a resin molded product and a continuous molding method using the same according to a preferred embodiment of the present invention will be described. FIG. 2 schematically shows a continuous molding apparatus 10 for continuously molding the resin molded product 1 or 1A shown in FIG. In FIG. 2, 11 is a first carrier film (hereinafter referred to as a lower carrier film), which is pulled out from the carrier film roll 11A, travels along a predetermined horizontal path, and is wound around the carrier film roll 11B. It is supposed to be. A flat film is used for the lower carrier film 11.

15は、走行中の下部キャリアフィルム11の上に液状の熱硬化性樹脂と補強用繊維材とを供給し且つ補強用繊維材に熱硬化性樹脂を含浸させて樹脂含浸繊維層16を形成する樹脂含浸繊維層形成手段であり、液状の熱硬化性樹脂17を収容した樹脂タンク18と、その樹脂タンク18から下部キャリアフィルム11上に供給された樹脂を所定厚さに規制するドクターナイフ19と、下部キャリアフィルム11上に塗布された熱硬化性樹脂17の上に補強用繊維材21を連続的に供給する繊維材供給装置22と、下部キャリアフィルム11上に供給された補強用繊維材21に熱硬化性樹脂17を含浸させる含浸ローラ23等を備えている。   15, a liquid thermosetting resin and a reinforcing fiber material are supplied onto the traveling lower carrier film 11, and the reinforcing fiber material is impregnated with the thermosetting resin to form the resin-impregnated fiber layer 16. Resin impregnated fiber layer forming means, a resin tank 18 containing a liquid thermosetting resin 17, and a doctor knife 19 for regulating the resin supplied from the resin tank 18 onto the lower carrier film 11 to a predetermined thickness; The fiber material supply device 22 that continuously supplies the reinforcing fiber material 21 onto the thermosetting resin 17 applied on the lower carrier film 11, and the reinforcing fiber material 21 supplied onto the lower carrier film 11. Are provided with an impregnation roller 23 for impregnating with a thermosetting resin 17.

下部キャリアフィルム11上に形成される樹脂含浸繊維層16は、樹脂成形品1又は1Aの基材層3を形成するものであり、熱硬化性樹脂17には、例えば、オルソ系ポリエステル、イソ系ポリエステル、ビニルエステル樹脂単量体もしくはそれらの混合品が用いられる。また、補強用繊維材21には、種々な形態及び材質のものが使用可能であり、例えば、形態としては、不織布(短繊維不織布、スパンボンド等)、織物、編物、チョップドストランドマットなどを、材質としては、無機質繊維(ガラス繊維、ロックウール、セラミック繊維など)、有機質繊維(ポリエステル、ナイロン、アクリル、ポリプロピレンなど)を例示できる。熱硬化性樹脂17及び補強用繊維材21の供給量(坪量)や配合割合は、製造しようとする樹脂成形品1又は1Aに要求される仕様に応じて適宜定めればよい。熱硬化性樹脂17及び補強用繊維材21の材質、形態、供給量、配合割合等の選定により、種々な特性の樹脂成形品1又は1Aを製造することができ、例えば、適度な柔軟性を有する製品を製造することも可能である。   The resin-impregnated fiber layer 16 formed on the lower carrier film 11 forms the base material layer 3 of the resin molded product 1 or 1A. Examples of the thermosetting resin 17 include ortho-based polyester and iso-based polyester. Polyester, vinyl ester resin monomer, or a mixture thereof is used. Further, the reinforcing fiber material 21 can be used in various forms and materials. For example, as the form, a nonwoven fabric (short fiber nonwoven fabric, spun bond, etc.), a woven fabric, a knitted fabric, a chopped strand mat, etc. Examples of the material include inorganic fibers (glass fiber, rock wool, ceramic fiber, etc.) and organic fibers (polyester, nylon, acrylic, polypropylene, etc.). The supply amount (basis weight) and blending ratio of the thermosetting resin 17 and the reinforcing fiber material 21 may be appropriately determined according to the specifications required for the resin molded product 1 or 1A to be manufactured. By selecting the material, form, supply amount, blending ratio, etc. of the thermosetting resin 17 and the reinforcing fiber material 21, the resin molded product 1 or 1A having various characteristics can be manufactured. It is also possible to produce products with

25は第二のキャリアフィルム(以下上部キャリアフィルムという)であり、キャリアフィルムロール25Aから引き出され、水平に設定された所定の経路を走行した後、反転して下部キャリアフィルム11に重なる位置を走行し、その後キャリアフィルムロール25Bに巻き取られるようになっている。この上部キャリアフィルム25には、図1(a)に示すような表面層2の表面を平坦面とした樹脂成形品1を製造する場合には平面フィルムが用いられ、図1(b)に示すような表面層2の表面を凹凸のあるエンボス面とした樹脂成形品1Aを製造する場合には、エンボス加工したフィルムが用いられる。   Reference numeral 25 denotes a second carrier film (hereinafter referred to as an upper carrier film), which is pulled out from the carrier film roll 25A, travels along a predetermined route set horizontally, and then reverses and travels at a position overlapping the lower carrier film 11. Then, the film is wound around the carrier film roll 25B. As the upper carrier film 25, a flat film is used when the resin molded product 1 having the surface of the surface layer 2 as shown in FIG. 1 (a) as a flat surface is manufactured, as shown in FIG. 1 (b). In the case of manufacturing a resin molded product 1A in which the surface of the surface layer 2 has an uneven embossed surface, an embossed film is used.

27は、水平な経路を走行中の上部キャリアフィルム25の上に柄材を混合した液状の熱硬化性樹脂を供給して柄材含有樹脂層28を形成する柄材含有樹脂層形成手段である。この柄材含有樹脂層形成手段27は、柄材を混合した液状の熱硬化性樹脂29を収容した樹脂タンク30と、その樹脂タンク30から上部キャリアフィルム25上に供給された樹脂を所定厚さに規制するドクターナイフ31等を備えている。樹脂タンク30には柄材を熱硬化性樹脂29内に良好に混合、分散させるように攪拌装置(図示せず)が設けられており、この樹脂タンク30内の、柄材を良好に分散させた熱硬化性樹脂29を上部キャリアフィルム25上に流下させ、ドクターナイフ31で膜厚を規制することで、柄材が良好に分散した柄材含有樹脂層28を形成することができる。 Reference numeral 27 denotes a pattern material-containing resin layer forming means for supplying a liquid thermosetting resin obtained by mixing a pattern material onto the upper carrier film 25 traveling along a horizontal path to form the pattern material-containing resin layer 28. . The pattern material-containing resin layer forming means 27 has a resin tank 30 containing a liquid thermosetting resin 29 mixed with a pattern material, and a resin supplied from the resin tank 30 onto the upper carrier film 25 with a predetermined thickness. A doctor knife 31 or the like is provided. The resin tank 30 is provided with a stirrer (not shown) so that the pattern material is well mixed and dispersed in the thermosetting resin 29. The pattern material in the resin tank 30 is well dispersed. The pattern material-containing resin layer 28 in which the pattern material is well dispersed can be formed by allowing the thermosetting resin 29 to flow down on the upper carrier film 25 and regulating the film thickness with the doctor knife 31.

上部キャリアフィルム25上に形成される柄材含有樹脂層28は、樹脂成形品1又は1Aの柄材を含有する表面層2を形成するものである。ここで用いる熱硬化性樹脂29には、例えば、オルソ系ポリエステル、イソ系ポリエステル、ビニルエステル樹脂単量体もしくはそれらの混合品が用いられ、必要に応じて紫外線吸収剤、親水剤、防カビ剤などが加えられる。また、柄材は液状の熱硬化性樹脂29内に均一に混合、分散させることができるものであり、具体的には、樹脂系粒状物、鉱物系粉砕物、金属系粉砕物、着色した樹脂フィルムの裁断物、金属箔の裁断物等を例示でき、なかでも、樹脂系粒状物や着色した樹脂フィルムの裁断物が、熱硬化性樹脂29に近い比重を持っているため熱硬化性樹脂29内に均一に分散させやすいので好ましい。柄材の大きさは、あまり大きくなると熱硬化性樹脂29への均一な分散が困難になり、一方あまり小さくなると意匠上の効果が小さくなる。そこで柄材の大きさとしては、0.1〜1.0mm程度に選定するのが好ましい。なお、柄材の大きさとは、粒状物の場合には平均粒径を示し、フィルムや箔の裁断物のように平坦な柄材の場合には柄材の平面における縦横サイズの平均値を示すものとする。熱硬化性樹脂に対する柄材の配合量としては、1〜5wt%程度とすることが好ましい。上記キャリアフィルム25上に形成する柄材含有樹脂層28の厚さは、所望厚さの表面層2を形成しうるように定めている。 The handle material-containing resin layer 28 formed on the upper carrier film 25 forms the surface layer 2 containing the handle material of the resin molded product 1 or 1A. As the thermosetting resin 29 used here, for example, ortho polyester, iso polyester, vinyl ester resin monomer, or a mixture thereof is used, and an ultraviolet absorber, a hydrophilic agent, and an antifungal agent are used as necessary. Etc. are added. In addition, the pattern material can be uniformly mixed and dispersed in the liquid thermosetting resin 29. Specifically, the resin material granular material, mineral-based pulverized material, metal-based pulverized material, colored resin Examples of the cut material of the film and the cut material of the metal foil include the resin-based granular material and the colored resin film material having a specific gravity close to that of the thermosetting resin 29. It is preferable because it can be easily dispersed uniformly. If the size of the pattern material is too large, uniform dispersion in the thermosetting resin 29 becomes difficult. On the other hand, if the size of the pattern material is too small, the design effect is reduced. Therefore, the size of the pattern material is preferably selected to be about 0.1 to 1.0 mm. The size of the pattern material indicates an average particle diameter in the case of a granular material, and indicates an average value of vertical and horizontal sizes in the plane of the pattern material in the case of a flat pattern material such as a cut product of film or foil. Shall. The blending amount of the pattern material with respect to the thermosetting resin is preferably about 1 to 5 wt%. The thickness of the pattern material-containing resin layer 28 formed on the carrier film 25 is determined so that the surface layer 2 having a desired thickness can be formed.

33は、上部キャリアフィルム25上に形成された柄材含有樹脂層28を半硬化させるよう加熱する半硬化用加熱装置である。この加熱装置33は上部キャリアフィルム25に保持されて連続的に走行している柄材含有樹脂層28を半硬化させるよう加熱できる構造のものであれば、その構造は任意である。   Reference numeral 33 denotes a semi-curing heating device that heats the pattern material-containing resin layer 28 formed on the upper carrier film 25 so as to be semi-cured. The heating device 33 may be of any structure as long as the heating device 33 can be heated so as to semi-cure the handle material-containing resin layer 28 held by the upper carrier film 25 and continuously running.

35は、半硬化した柄材含有樹脂層28を上部キャリアフィルム25と共に、下部キャリアフィルム11上に形成されている樹脂含浸繊維層16に、柄材含有樹脂層28を樹脂含浸繊維層16に対面させて重ね合わせる重ね合わせ手段であり、ここでは一対のニップローラ35a、35aが用いられている。この一対のニップローラ35a、35aは樹脂含浸繊維層16と柄材含有樹脂層28を密着させて積層体36を形成すると共に樹脂含浸繊維層16の含浸、脱泡を更に進める作用も果たしている。なお、必要に応じ、一対のニップローラ35a、35aの下流に脱泡ローラを配置して更に脱泡を行なう構成としてもよい。37は重ね合わせた樹脂含浸繊維層16と柄材含有樹脂層28からなる積層体36を硬化させるよう加熱する硬化用加熱装置である。この加熱装置37は、下部キャリアフィルム11と上部キャリアフィルム25ではさみ付けられて連続的に走行している積層体36を硬化させるよう加熱できる構造のものであれば、その構造は任意である。38は成形された積層体36を所望長さに切断する切断装置、40はキャリアフィルム11、25を案内するローラである。なお、成形製品として、ロール状に巻き取ることを可能とする柔軟性を備えたものを成形する場合には、切断装置38の下流に、成形された積層体36をロール状に巻き取るための巻取装置を設けておく。   35, the semi-cured pattern material-containing resin layer 28 faces the resin-impregnated fiber layer 16 formed on the lower carrier film 11 together with the upper carrier film 25, and the pattern material-containing resin layer 28 faces the resin-impregnated fiber layer 16. In this case, a pair of nip rollers 35a and 35a are used. The pair of nip rollers 35a, 35a form a laminate 36 by bringing the resin-impregnated fiber layer 16 and the handle material-containing resin layer 28 into close contact with each other, and also perform the action of further impregnating and defoaming the resin-impregnated fiber layer 16. In addition, it is good also as a structure which arrange | positions a defoaming roller downstream from a pair of nip rollers 35a and 35a as needed, and defoams further. Reference numeral 37 denotes a curing heating device that heats the laminated body 36 composed of the superimposed resin-impregnated fiber layer 16 and the pattern material-containing resin layer 28. The heating device 37 may have any structure as long as the heating device 37 can be heated to cure the laminated body 36 that is sandwiched between the lower carrier film 11 and the upper carrier film 25 and is continuously running. Reference numeral 38 denotes a cutting device for cutting the formed laminate 36 to a desired length, and reference numeral 40 denotes a roller for guiding the carrier films 11 and 25. In addition, in the case of forming a molded product having flexibility that enables winding into a roll shape, the molded product 36 is wound downstream in the cutting device 38 into a roll shape. A winding device is provided.

次に、上記構成の連続成形装置10による成形動作を説明する。図2において、下部キャリアフィルム11がキャリアフィルムロール11Aから引き出され、所定の水平な経路を走行している。この下部キャリアフィルム11上に、樹脂タンク18から液状の熱硬化性樹脂17が供給され、ドクターナイフ19で所定の厚さに規制され、次いで、その上に補強用繊維材21が供給され、含浸ローラ23によって樹脂が含浸され、樹脂含浸繊維層16が形成される。ここで樹脂含浸繊維層16の厚さや補強用繊維材の含有率等は、製造しようとする樹脂成形品1又は1A(図1参照)の基材層3を形成することができるように設定している。   Next, the molding operation by the continuous molding apparatus 10 having the above configuration will be described. In FIG. 2, the lower carrier film 11 is pulled out of the carrier film roll 11A and travels along a predetermined horizontal path. On this lower carrier film 11, a liquid thermosetting resin 17 is supplied from a resin tank 18, regulated to a predetermined thickness by a doctor knife 19, and then a reinforcing fiber material 21 is supplied thereon and impregnated. The resin is impregnated by the roller 23 to form the resin-impregnated fiber layer 16. Here, the thickness of the resin-impregnated fiber layer 16 and the content of the reinforcing fiber material are set so that the base material layer 3 of the resin molded product 1 or 1A (see FIG. 1) to be manufactured can be formed. ing.

この工程に並行して、上部キャリアフィルム25がキャリアフィルムロール25Aから引き出され、所定の水平な経路を走行し、その上部キャリアフィルム25上に、樹脂タンク30から、柄材を良好に混合、分散させている液状の熱硬化性樹脂29が供給され、ドクターナイフ31で所定の厚さに規制され、柄材含有樹脂層28が形成される。ここで、上部キャリアフィルム25に供給された熱硬化性樹脂29には柄材が良好に分散しているので、これをドクターナイフ31で所望の膜厚に規制して形成した柄材含有樹脂層28においても、柄材が良好に分散した状態となっており、例え柄材含有樹脂層28内において比重差によって柄材の沈降や浮き上がりが生じても、平面的には柄材は良好に分散した状態に保たれている。ここで柄材含有樹脂層28の厚さは、製造しようとする樹脂成形品1又は1A(図1参照)の表面層2を形成することができるように設定している。次に、柄材含有樹脂層28が半硬化用加熱装置33を通過し、加熱、半硬化される。ここで、半硬化の程度としては、柄材含有樹脂層28内に含まれる柄材が移動しない程度以上に硬化しているが、柄材含有樹脂層28を反転させて樹脂含浸繊維層16に重ね合わせる操作は支障なく実施できる程度の柔軟性は備えているように選定する。 In parallel with this process, the upper carrier film 25 is pulled out from the carrier film roll 25A, travels along a predetermined horizontal path, and the pattern material is well mixed and dispersed on the upper carrier film 25 from the resin tank 30. The liquid thermosetting resin 29 is supplied and regulated to a predetermined thickness by the doctor knife 31 to form the pattern material-containing resin layer 28. Here, since the pattern material is well dispersed in the thermosetting resin 29 supplied to the upper carrier film 25, the pattern material-containing resin layer formed by restricting the pattern material to a desired film thickness by the doctor knife 31. 28, the pattern material is well dispersed. Even if the pattern material settles or rises due to the difference in specific gravity in the pattern material-containing resin layer 28, the pattern material is well dispersed in a plane. It is kept in the state. Here, the thickness of the pattern material-containing resin layer 28 is set so that the surface layer 2 of the resin molded product 1 or 1A (see FIG. 1) to be manufactured can be formed. Next, the pattern material-containing resin layer 28 passes through the semi-curing heating device 33 and is heated and semi-cured. Here, as the degree of semi-curing, the pattern material contained in the pattern material-containing resin layer 28 is cured to an extent that does not move, but the pattern material-containing resin layer 28 is inverted to form the resin-impregnated fiber layer 16. The overlapping operation should be selected so that it is flexible enough to be performed without hindrance.

次に上部キャリアフィルム25が反転して下部キャリアフィルム11上に重なる位置に走行し、半硬化した柄材含有樹脂層28が下部キャリアフィルム11上の樹脂含浸繊維層16に対面した状態で、重ね合わされ、ニップローラ35a、35aによって密着させられ、積層体36が形成される。次いで、重ね合わされた樹脂含浸繊維層16と柄材含有樹脂層28からなる積層体36が、下部キャリアフィルム11及び上部キャリアフィルム25で挟まれた状態で硬化用加熱装置37を通過し、加熱、硬化させられ、樹脂含浸繊維層16と柄材含有樹脂層28が一体化する。これらの重ね合わせ及び硬化工程において、柄材含有樹脂層28は半硬化した状態となっているので、柄材含有樹脂層28内に良好に分散している柄材が動いて分散むらを大きくするということはなく、このため硬化した後における積層体においても、柄材は良好に分散した状態に保たれている。その後、硬化した積層体36から下部キャリアフィルム11及び上部キャリアフィルム25が剥がされ、積層体36は所望サイズに切断され、樹脂成形品1又は1Aが形成される。ここで、上部キャリアフィルム25として平面フィルムを用いた場合には、図1(a)に示すように表面層2の表面を平坦面とした樹脂成形品1が形成され、上部キャリアフィルム25としてエンボス付フィルムを用いた場合には、図1(b)に示すように表面層2の表面をエンボス面とした樹脂成形品1Aが形成される。   Next, the upper carrier film 25 is reversed and travels to a position where it overlaps the lower carrier film 11, and the semi-cured pattern material-containing resin layer 28 faces the resin-impregnated fiber layer 16 on the lower carrier film 11. Then, they are brought into close contact with the nip rollers 35a, 35a to form a laminate 36. Next, the laminated body 36 composed of the superimposed resin-impregnated fiber layer 16 and the handle material-containing resin layer 28 is passed through the heating device 37 for curing while being sandwiched between the lower carrier film 11 and the upper carrier film 25, and heated. The resin-impregnated fiber layer 16 and the pattern material-containing resin layer 28 are integrated by being cured. In these overlaying and curing steps, the pattern material-containing resin layer 28 is in a semi-cured state, so that the pattern material that is well dispersed in the pattern material-containing resin layer 28 moves to increase dispersion unevenness. In other words, the pattern material is kept in a well-dispersed state even in the laminated body after curing. Thereafter, the lower carrier film 11 and the upper carrier film 25 are peeled off from the cured laminate 36, and the laminate 36 is cut into a desired size to form the resin molded product 1 or 1A. Here, when a flat film is used as the upper carrier film 25, the resin molded product 1 having the surface layer 2 as a flat surface is formed as shown in FIG. When the attached film is used, as shown in FIG. 1B, a resin molded product 1A having the surface of the surface layer 2 as an embossed surface is formed.

上記した連続成形装置において、柔軟性を有する樹脂成形品1又は1Aを製造する場合には、切断装置38の下流に設けた巻取装置(図示せず)により、積層体36がロール状に巻き取られ、ロール形態の樹脂成形品1又は1Aが製造される。一方、剛性の大きい樹脂成形品1又は1Aを製造する場合には、切断装置38で切断された積層体36が板状のままで所定の集積位置に積み重ねられ、板状の樹脂成形品1又は1Aが製造される。   When the flexible molded resin 1 or 1A is manufactured in the continuous molding apparatus described above, the laminate 36 is wound into a roll shape by a winding device (not shown) provided downstream of the cutting device 38. Then, the resin molded product 1 or 1A in roll form is manufactured. On the other hand, when manufacturing the resin molded product 1 or 1A having high rigidity, the laminated body 36 cut by the cutting device 38 is stacked in a predetermined accumulation position while remaining in a plate shape, and the plate-shaped resin molded product 1 or 1A is manufactured. 1A is manufactured.

得られた樹脂成形品1又は1Aは、樹脂内に柄材を良好に分散させた表面層2と、繊維材で強化された基材層3を一体化した構造となっており、柄材による優れた意匠性を呈すと共に繊維補強樹脂成形品であることによる優れた強度、耐久性、耐水性等の諸特性を備えている。樹脂成形品1又は1Aの用途は特に限定されるものではないが、床材、壁材、内装材などに好適である。また、樹脂成形品1又は1Aの厚さを2mm程度以下とし、適度な柔軟性を付与しておくことで、浴室床や壁等の補修用のシートとしても使用できる。   The obtained resin molded product 1 or 1A has a structure in which the surface layer 2 in which the pattern material is well dispersed in the resin and the base material layer 3 reinforced with the fiber material are integrated. It exhibits excellent design properties and has various properties such as excellent strength, durability, and water resistance due to being a fiber-reinforced resin molded product. The use of the resin molded product 1 or 1A is not particularly limited, but is suitable for a flooring material, a wall material, an interior material, and the like. Moreover, it can be used also as a sheet | seat for repairs, such as a bathroom floor and a wall, by setting the thickness of the resin molded product 1 or 1A to about 2 mm or less, and giving moderate softness | flexibility.

[実施例1]
図2に示す連続成形装置10を用い、次の材料、条件で、図1(a)に示す樹脂成形品1を成形した。
(1)使用材料
下部キャリアフィルム11:平面フィルム(材質;ポリエステル製 、厚さ25μm)
上部キャリアフィルム25:平面フィルム(材質;ポリエステル製 、厚さ75μm)
基材層形成用の熱硬化性樹脂17:ビニルエステル樹脂(日本ユピカ株式会社製、「8932」)
基材層形成用の繊維材21:ガラスペーパー(オリベスト株式会社製、「FBP−025」)とスパンボンド(東洋紡績株式会社製、「3501A」)を重ねて使用。
表面層形成用の熱硬化性樹脂29:ビニルエステル樹脂(日本ユピカ株式会社製、「8932」)
柄材:PETフィルムの裁断物、サイズ0.5mm×0.5mm、厚さ20μm 熱硬化性樹脂100重量部に対して3重量部を混合
[Example 1]
Using the continuous molding apparatus 10 shown in FIG. 2, the resin molded product 1 shown in FIG. 1A was molded under the following materials and conditions.
(1) Material used Lower carrier film 11: Flat film (material: polyester, thickness 25 μm)
Upper carrier film 25: flat film (material: polyester, thickness 75 μm)
Thermosetting resin 17 for forming base material layer: Vinyl ester resin (manufactured by Nippon Iupika Co., Ltd., “8932”)
Fiber material 21 for forming the base layer: Glass paper (Olivest Co., Ltd., “FBP-025”) and spunbond (Toyobo Co., Ltd., “3501A”) are used in layers.
Thermosetting resin 29 for surface layer formation: Vinyl ester resin (manufactured by Nippon Iupika Co., Ltd., “8932”)
Pattern material: Cut PET film, size 0.5 mm x 0.5 mm, thickness 20 μm 3 parts by weight per 100 parts by weight of thermosetting resin

(2)成形条件
下部キャリアフィルム11を1m/分の速度で連続的に走行させ、その上に熱硬化性樹脂17と繊維材21を供給し、含浸ローラ23にて含浸させ、厚さ約1.0mmの樹脂含浸繊維層16を形成。
上部キャリアフィルム25を1m/分の速度で連続的に走行させ、その上に柄材を含有する熱硬化性樹脂29を供給し、ドクターナイフ31で一定厚さに規制して厚さ約0.3mmの柄材含有樹脂層28を形成し、それを半硬化用加熱装置33に通して半硬化。加熱装置33内の温度100℃、柄材含有樹脂層28の通過時間3分。
半硬化した柄材含有樹脂層28を樹脂含浸繊維層16に重ねた後、硬化用加熱装置37に通して硬化。加熱装置37の入口温度80℃、出口温度140℃、柄材含有樹脂層28及び樹脂含浸繊維層16の積層体の通過時間45分。
その後、上下のキャリアフィルムを剥がし、硬化した積層体をロール状に巻き取り且つ一定長さに切断して樹脂成形品1を得た。
(2) Molding conditions The lower carrier film 11 is continuously run at a speed of 1 m / min, the thermosetting resin 17 and the fiber material 21 are supplied thereon, impregnated by the impregnation roller 23, and the thickness is about 1 A resin impregnated fiber layer 16 having a thickness of 0 mm is formed.
The upper carrier film 25 is continuously run at a speed of 1 m / min, a thermosetting resin 29 containing a pattern material is supplied on the upper carrier film 25, and the thickness is regulated to about a constant thickness by a doctor knife 31. A 3 mm pattern material-containing resin layer 28 is formed and passed through a semi-curing heating device 33 to be semi-cured. The temperature in the heating device 33 is 100 ° C., and the passing time of the pattern material-containing resin layer 28 is 3 minutes.
The semi-cured pattern material-containing resin layer 28 is superposed on the resin-impregnated fiber layer 16 and then cured by passing through a curing heating device 37. The inlet temperature of the heating device 37 is 80 ° C., the outlet temperature is 140 ° C., and the transit time of the laminate of the pattern material-containing resin layer 28 and the resin-impregnated fiber layer 16 is 45 minutes.
Thereafter, the upper and lower carrier films were peeled off, and the cured laminate was wound into a roll and cut into a predetermined length to obtain a resin molded product 1.

(3)結果
得られた樹脂成形品1はロール状に巻かれた形態で、幅1000mm、長さ15m、全厚さ約1.7mm、表面層2の厚さ約0.5mmであった。その樹脂成形品1の表面を目視検査した結果、表面層に柄材が均一に分散しており、優れた意匠性を備えていた。
(3) Result The obtained resin molded product 1 was rolled up, and had a width of 1000 mm, a length of 15 m, a total thickness of about 1.7 mm, and a thickness of the surface layer 2 of about 0.5 mm. As a result of visual inspection of the surface of the resin molded product 1, the pattern material was uniformly dispersed in the surface layer and had excellent design properties.

[実施例2]
上部キャリアフィルム25として、エンボス付フィルム(材質;つや消しポリエステル製、厚さ75μm、エンボスの深さ0.9mm)を用いた以外は、実施例1と同一条件にて成形を行い、図1(b)に示す樹脂成形品1Aを得た。
得られた樹脂成形品1Aはロール状に巻かれた形態で、幅1000mm、長さ15m、全厚さ約1.7mm、表面層2の厚さ約1.0mm、表面層の表面に形成されているエンボスの深さ約0.7mmであった。その樹脂成形品1Aの表面を目視検査した結果、表面層に柄材が均一に分散し、且つその表面にエンボスが形成されており、優れた意匠性を備えていた。
[Example 2]
The upper carrier film 25 was molded under the same conditions as in Example 1 except that an embossed film (material; made of matte polyester, thickness 75 μm, embossed depth 0.9 mm) was used. The resin molded product 1A shown in FIG.
The obtained resin molded product 1A is in the form of a roll, and is formed on the surface of the surface layer with a width of 1000 mm, a length of 15 m, a total thickness of about 1.7 mm, a thickness of the surface layer 2 of about 1.0 mm. The embossing depth is about 0.7 mm. As a result of visual inspection of the surface of the resin molded product 1A, the pattern material was uniformly dispersed in the surface layer, and an emboss was formed on the surface, which provided excellent design properties.

(a)、(b)はそれぞれ、本発明方法及び装置によって成形する樹脂成形体の例を示す概略断面図(A), (b) is a schematic sectional drawing which shows the example of the resin molded object shape | molded by this invention method and apparatus, respectively. 本発明の好適な実施の形態に係る連続成形装置の概略構成図Schematic configuration diagram of a continuous molding apparatus according to a preferred embodiment of the present invention

符号の説明Explanation of symbols

1、1A 樹脂成形品
2 表面層
3 基材層
4、7 マトリックス樹脂
5 柄材
8 補強用繊維材
10 連続成形装置
11 第一のキャリアフィルム(下部キャリアフィルム)
15 樹脂含浸繊維層形成手段
16 樹脂含浸繊維層
17 熱硬化性樹脂
18 樹脂タンク
19 ドクターナイフ
21 補強用繊維材
22 繊維材供給装置
23 脱泡ローラ
25 第二のキャリアフィルム(上部キャリアフィルム)
27 柄材含有樹脂層形成手段
28 柄材含有樹脂層
29 熱硬化性樹脂
30 樹脂タンク
31 ドクターナイフ
33 半硬化用加熱装置
35 重ね合わせ手段
35a ニップローラ
36 積層体
37 硬化用加熱装置
38 切断装置
40 ローラ
DESCRIPTION OF SYMBOLS 1, 1A resin molded product 2 Surface layer 3 Base material layer 4, 7 Matrix resin 5 Pattern material 8 Reinforcing fiber material 10 Continuous molding apparatus 11 First carrier film (lower carrier film)
DESCRIPTION OF SYMBOLS 15 Resin impregnated fiber layer formation means 16 Resin impregnated fiber layer 17 Thermosetting resin 18 Resin tank 19 Doctor knife 21 Reinforcing fiber material 22 Fiber material supply device 23 Defoaming roller 25 Second carrier film (upper carrier film)
27 Pattern material-containing resin layer forming means 28 Pattern material-containing resin layer 29 Thermosetting resin 30 Resin tank 31 Doctor knife 33 Semi-curing heating device 35 Superposition means 35a Nip roller 36 Laminate 37 Curing heating device 38 Cutting device 40 Roller

Claims (5)

所定の経路を走行中の第一のキャリアフィルムの上に液状の熱硬化性樹脂と補強用繊維材とを供給し且つ補強用繊維材に熱硬化性樹脂を含浸させて樹脂含浸繊維層を形成する工程と、所定の経路を走行中の第二のキャリアフィルムの上に、あらかじめ柄材を混合、分散させた液状の熱硬化性樹脂を供給して柄材含有樹脂層を形成する工程と、前記第二のキャリアフィルムに保持されて走行中の前記柄材含有樹脂層を半硬化させる工程と、前記第一のキャリアフィルム上に形成されている樹脂含浸繊維層の上に、半硬化した柄材含有樹脂層を第二のキャリアフィルムと共に、前記柄材含有樹脂層を前記樹脂含浸繊維層に対面させて重ね合わせる工程と、重ね合わされ、前記第一及び第二のキャリアフィルムで挟まれて走行中の前記樹脂含浸繊維層と柄材含有樹脂層を硬化させる工程を有する繊維補強樹脂成形品の連続成形方法。 A liquid thermosetting resin and a reinforcing fiber material are supplied onto the first carrier film traveling along a predetermined route, and the reinforcing fiber material is impregnated with the thermosetting resin to form a resin-impregnated fiber layer. And a step of forming a pattern material-containing resin layer by supplying a liquid thermosetting resin in which a pattern material is mixed and dispersed in advance on the second carrier film traveling on a predetermined route, Semi-cured pattern on the resin-impregnated fiber layer formed on the first carrier film, and a step of semi-curing the pattern material-containing resin layer being held by the second carrier film and running The material-containing resin layer and the second carrier film are overlapped with the pattern material-containing resin layer facing the resin-impregnated fiber layer, and the material-containing resin layer is overlapped and traveled between the first and second carrier films. Inside the resin impregnated fiber Continuous molding method of a fiber reinforced resin molded product comprising a step of curing the pattern material containing resin layer and. 前記第二のキャリアフィルムがエンボス加工されたフィルムであることを特徴とする請求項1記載の繊維補強樹脂成形品の連続成形方法。   The continuous molding method for a fiber-reinforced resin molded product according to claim 1, wherein the second carrier film is an embossed film. 前記柄材が樹脂の粒状物若しくは樹脂フィルムの裁断物であることを特徴とする請求項1又は2記載の繊維補強樹脂成形品の連続成形方法。   The method for continuously forming a fiber-reinforced resin molded product according to claim 1 or 2, wherein the pattern material is a resin granular material or a resin film cut product. 所定の経路に沿って走行するように設けられた第一のキャリアフィルムと、走行中の前記第一のキャリアフィルムの上に液状の熱硬化性樹脂と補強用繊維材とを供給し且つ補強用繊維材に熱硬化性樹脂を含浸させて樹脂含浸繊維層を形成する樹脂含浸繊維層形成手段と、水平な経路を走行した後、反転して前記第一のキャリアフィルムに重なる位置を走行するように設けられた第二のキャリアフィルムと、前記水平な経路を走行中の第二のキャリアフィルムの上に、あらかじめ柄材を混合、分散させた液状の熱硬化性樹脂を供給して柄材含有樹脂層を形成する柄材含有樹脂層形成手段と、前記第二のキャリアフィルムに保持されて走行中の前記柄材含有樹脂層を半硬化させるよう加熱する半硬化用加熱装置と、半硬化した柄材含有樹脂層を第二のキャリアフィルムと共に、前記第一のキャリアフィルム上に形成されている樹脂含浸繊維層に、前記柄材含有樹脂層を前記樹脂含浸繊維層に対面させて重ね合わせる重ね合わせ手段と、重ね合わされ、前記第一及び第二のキャリアフィルムで挟まれて走行中の前記樹脂含浸繊維層と柄材含有樹脂層を硬化させるよう加熱する硬化用加熱装置を有することを特徴とする繊維補強樹脂成形品の連続成形装置。 A first carrier film provided so as to travel along a predetermined path, and a liquid thermosetting resin and a reinforcing fiber material are supplied onto the first carrier film while traveling and are used for reinforcement. A fiber-impregnated fiber layer forming means for impregnating a fiber material with a thermosetting resin to form a resin-impregnated fiber layer and a horizontal path, and then reversing and traveling on a position overlapping the first carrier film A pattern material is supplied by supplying a liquid thermosetting resin in which a pattern material is mixed and dispersed in advance on the second carrier film provided on the second carrier film traveling on the horizontal path. A pattern material-containing resin layer forming means for forming a resin layer, a semi-curing heating device that heats the pattern material-containing resin layer that is being held by the second carrier film to be semi-cured, and semi-cured The resin layer containing the pattern material Along with the carrier film, the resin impregnated fiber layer formed on the first carrier film is superposed on the resin material-impregnated fiber layer with the pattern material-containing resin layer facing the resin impregnated fiber layer, A continuous fiber-reinforced resin molded product comprising a curing heating device that heats the resin-impregnated fiber layer and the handle material-containing resin layer that are sandwiched between the first and second carrier films and that is cured. Molding equipment. 前記第二のキャリアフィルムがエンボス加工されたフィルムであることを特徴とする請求項4記載の繊維補強樹脂成形品の連続成形装置。   The continuous molding apparatus for a fiber-reinforced resin molded product according to claim 4, wherein the second carrier film is an embossed film.
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