JP3171211B2 - Method for producing heat-sensitive stencil printing base paper - Google Patents
Method for producing heat-sensitive stencil printing base paperInfo
- Publication number
- JP3171211B2 JP3171211B2 JP03149392A JP3149392A JP3171211B2 JP 3171211 B2 JP3171211 B2 JP 3171211B2 JP 03149392 A JP03149392 A JP 03149392A JP 3149392 A JP3149392 A JP 3149392A JP 3171211 B2 JP3171211 B2 JP 3171211B2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- thermoplastic film
- ink
- support
- permeable support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Printing Plates And Materials Therefor (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、感熱孔版用印刷原紙に
関し、更に詳しくは高性能且つ高感度な感熱孔版用印刷
原紙に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat-sensitive stencil printing stencil, and more particularly to a high-performance and high-sensitivity heat-sensitive stencil printing stencil.
【０００２】[0002]
【従来の技術】従来、簡便な印刷方法として孔版印刷方
式が広く行なわれており、この方式では適当なインキ透
過性支持体表面に熱可塑性フィルムを積層したものを感
熱孔版用印刷原紙として使用し、サーマルヘッド等によ
り印字して、熱可塑性フィルムを加熱溶融して画像状の
穿孔を形成し、インキ透過性支持体側から印刷インキを
通して紙等の被印刷物に印刷を行うものである。2. Description of the Related Art Conventionally, a stencil printing method has been widely used as a simple printing method. In this method, a thermoplastic film laminated on an appropriate ink-permeable support is used as a heat-sensitive stencil printing base paper. The printing is performed by a thermal head or the like, the thermoplastic film is heated and melted to form image-like perforations, and printing is performed on a printing material such as paper through printing ink from the ink-permeable support.
【０００３】上記従来の孔版印刷方式で使用する感熱孔
版用印刷原紙は一般にインキ透過性支持体の表面に数μ
ｍ程度の薄い熱可塑性フィルムを接着剤等により積層し
て形成されるものであるが、最近では印刷物の画質向上
のため、サーマルヘッドによる製版方式が主流となり、
且つその１つのドット当りの大きさも微細化される傾向
にある。又、１ドット当りの熱量も小さくなる傾向にあ
り、感熱孔版用印刷原紙に対してさらに高性能化を要求
される。熱可塑性フィルムとしては従来は２軸延伸ポリ
エチレンテレフタレート（ＰＥＴ）フィルム等が広く用
いられているが、ポリエチレンテレフタレート（ＰＥ
Ｔ）フィルム等を熱穿孔し充分な印字濃度を得るために
はサーマルヘッドに供給するエネルギーを大とする必要
がある。また熱可塑性フィルムとインキ透過性支持体と
の接着には従来一般に接着剤を用い接着を行なっていた
が、接着剤樹脂等が熱可塑性フィルムとインキ透過性支
持体との間に存在するため熱可塑性フィルムの熱穿孔性
を阻害する欠点、またインキ透過性支持体の繊維目の間
に入り込み、インキの透過を阻害する欠点があった。The heat-sensitive stencil printing base paper used in the above-mentioned conventional stencil printing method generally has several μm on the surface of an ink-permeable support.
It is formed by laminating a thin thermoplastic film of about m with an adhesive or the like, but recently, in order to improve the image quality of printed matter, a plate making method using a thermal head has become mainstream,
In addition, the size per one dot tends to be miniaturized. Also, the amount of heat per dot tends to be small, and higher performance is required for the heat-sensitive stencil printing base paper. Conventionally, a biaxially stretched polyethylene terephthalate (PET) film or the like is widely used as a thermoplastic film.
T) In order to obtain a sufficient print density by thermally perforating a film or the like, it is necessary to increase the energy supplied to the thermal head. Conventionally, the adhesive between the thermoplastic film and the ink-permeable support has been generally bonded using an adhesive. However, since an adhesive resin or the like exists between the thermoplastic film and the ink-permeable support, the heat is not applied. There is a disadvantage that the thermal perforation of the plastic film is impaired, and that it penetrates between the fibers of the ink-permeable support and impedes the permeation of the ink.
【０００４】[0004]
【発明が解決しようとする課題】本発明の目的は上述の
如き欠点を解決し、感度及び接着性に優れると共に良好
な性能を示す感熱孔版用印刷原紙を提供することであ
る。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned drawbacks and to provide a heat-sensitive stencil sheet having excellent sensitivity and adhesiveness and good performance.
【０００５】[0005]
【課題を解決するための手段】本発明によれば、感熱孔
版用印刷原紙に使用される熱可塑性フィルムと合成繊維
を主体としたインキ透過性支持体とを、接着剤等の層を
介せず２層間を接着する感熱孔版用印刷原紙の製造方法
において、該熱可塑性フィルムの支持体側表面を、該熱
可塑性フィルムの溶融温度より０〜５℃高い温度に加熱
して熱溶融し、前記インキ透過性支持体と熱融着させる
ことを特徴とする、該熱可塑性フィルムと該支持体との
２層からなる感熱孔版用印刷原紙の製造方法が提供さ
れ、また感熱孔版用印刷原紙に使用される熱可塑性フィ
ルムと合成繊維を主体としたインキ透過性支持体とを、
接着剤等の層を介せず２層間を接着する感熱孔版用印刷
原紙の製造方法において、該熱可塑性フィルムの支持体
側表面を、該熱可塑性フィルムの溶融温度より０〜５℃
高い温度に加熱したインキ透過性支持体を接触させるこ
とにより熱溶融し、前記インキ透過性支持体と熱融着さ
せることを特徴とする、該熱可塑性フィルムと該支持体
との２層からなる感熱孔版用印刷原紙の製造方法が提供
され、特に前記製造方法において、熱融着させるインキ
透過性支持体として合成繊維を主体とした薄葉紙を用い
ること特徴とする前記感熱孔版用印刷原紙の製造方法が
提供される。According to the present invention, a thermoplastic film used for a printing stencil for heat-sensitive stencil and an ink-permeable support mainly composed of synthetic fibers are interposed through a layer such as an adhesive. In a method for producing a heat-sensitive stencil printing base paper in which at least two layers are adhered to each other, the support-side surface of the thermoplastic film is heated to a temperature higher than the melting temperature of the thermoplastic film by 0 to 5 ° C. and melted by heating. A method for producing a heat-sensitive stencil printing base paper comprising two layers of the thermoplastic film and the support, which is characterized by being thermally fused with a permeable support. A thermoplastic film and an ink-permeable support mainly composed of synthetic fibers,
In the method for producing a heat-sensitive stencil printing base paper in which two layers are adhered to each other without a layer of an adhesive or the like, the support-side surface of the thermoplastic film is set at 0 to 5 ° C.
The ink-permeable support is heated to a high temperature, and is heated and melted by contact with the ink-permeable support, and is heat-fused with the ink-permeable support. A method for producing a heat-sensitive stencil printing base paper is provided. In particular, in the method, a thin paper mainly composed of synthetic fibers is used as an ink-permeable support to be heat-sealed. Is provided.
【０００６】更に、本発明について詳細に説明する。 １）本発明は、前記２層間の接着方法として、熱可塑性
フィルムの支持体側表面を熱溶融するに当り、該フィル
ムの溶融温度より少なくとも０〜５℃高温の棒状体を該
フィルムの表面に接して軟化させた後、インキ透過性支
持体と圧着し熱融着する方法として使用する熱棒（棒状
体）の径が０．１ｍｍφ〜１０ｍｍφであることを特徴
とするものであり、また熱可塑性フィルムとインキ透過
性支持体が接触する位置から０ｍｍ〜５０ｍｍの距離に
熱棒が位置することを特徴とするものである。 ２）本発明は、前記２層間の接着方法として、熱可塑性
フィルムの支持体側表面を、加熱したインキ透過性支持
体を接触させることにより熱溶融するに当たり、インキ
透過性支持体を加熱する為に熱ローラを使用し、その熱
ローラの径が５０ｍｍφ〜１０００ｍｍφであることを
特徴とするものであり、また加熱するインキ透過性支持
体の温度を、熱融着させる熱可塑性フィルムの溶融点よ
り０〜５℃高温にすることを特徴とするものである。Further, the present invention will be described in detail. 1) In the present invention, as a method of bonding between the two layers, a rod-shaped body having a temperature at least 0 to 5 ° C. higher than the melting temperature of the film is brought into contact with the surface of the thermoplastic film when the support side surface of the thermoplastic film is hot-melted. The method is characterized in that the diameter of a hot rod (rod-shaped body) used as a method for pressure-bonding and heat-sealing after being softened with an ink-permeable support is 0.1 mmφ to 10 mmφ. The heating rod is located at a distance of 0 mm to 50 mm from a position where the film and the ink-permeable support come into contact with each other. 2) The present invention relates to a method for bonding the two layers by heating the ink-permeable support when the support-side surface of the thermoplastic film is heated and melted by contacting the heated ink-permeable support. A heat roller is used, and the diameter of the heat roller is 50 mmφ to 1000 mmφ, and the temperature of the ink-permeable support to be heated is set at 0 ° from the melting point of the thermoplastic film to be heat-sealed. It is characterized by raising the temperature to -5 ° C.
【０００７】本発明で使用するインキ透過性支持体と
は、印刷時に使用する印刷インキが通過できるように多
孔質であることが必要であり、例えば、レーヨン、ビニ
ロン、ポリエステル、ポリアクリロニトリル、ナイロン
等の各種の材料からなる合成繊維を主とした薄葉紙、及
びレーヨン、ビニロン、ポリエステル、ポリアクリロニ
トリル、ナイロン等の各種の合成繊維を主体とした材料
にマニラ麻等を用いた天然繊維を混抄した薄葉紙等が使
用でき、好ましくは坪量７〜１５ｇ／ｍ2程度の合成繊
維、混抄紙等が有利に使用される。The ink-permeable support used in the present invention must be porous so that the printing ink used during printing can pass therethrough. For example, rayon, vinylon, polyester, polyacrylonitrile, nylon, etc. Tissue paper mainly composed of synthetic fibers made of various materials, and thin paper mixed with natural fibers using manila hemp etc. in a material mainly composed of various synthetic fibers such as rayon, vinylon, polyester, polyacrylonitrile, and nylon. It can be used, and preferably, synthetic fibers having a basis weight of about 7 to 15 g / m 2, mixed paper, and the like are advantageously used.
【０００８】本発明で使用する熱可塑性フィルムとして
は、押出法、流延法等により形成されたフィルムであ
り、ポリエステル（好ましくは共重合体ポリエステル）
系、ナイロン（好ましくは共重合ナイロン）系、ポリオ
レフィン系、ポリスチレン系、ポリ塩化ビニル系、ポリ
アクリル酸誘導体系、ポリエチレン・ビニルアルコール
系、ポリカーボネート系共重合体等が挙げられる。好ま
しくは該フィルムの穿孔感度が高いものが有効であり、
そのためにはフィルムを構成している状態における熱可
塑性樹脂が実質的に非晶質なレベルから結晶化度１５％
までの範囲のものがよい。より好ましくは該フィルムが
実質的に非晶質なレべルのものである。ここで、実質的
に非晶質なレベルのフィルムとは、その原料がＤＳＣ法
で融点がほとんどみられないものである場合と、加工法
（急冷法等）等により結晶化を抑制したものである場合
等がある。上記結晶化度はＸ線法により決定されるがＤ
ＳＣ法で融解エネルギーの面積比でもとめてもよい。[0008] The thermoplastic film used in the present invention is a film formed by an extrusion method, a casting method or the like, and is a polyester (preferably a copolymer polyester).
, A nylon (preferably copolymerized nylon), a polyolefin, a polystyrene, a polyvinyl chloride, a polyacrylic acid derivative, a polyethylene / vinyl alcohol, and a polycarbonate copolymer. Preferably, a film having high perforation sensitivity is effective,
For this purpose, the thermoplastic resin in the state of constituting the film is changed from a substantially amorphous level to a crystallinity of 15%.
A range of up to is preferred. More preferably, the film is of a substantially amorphous level. Here, the film having a substantially amorphous level means a film whose raw material has almost no melting point by the DSC method and a film whose crystallization is suppressed by a processing method (a quenching method or the like). There are some cases. The above crystallinity is determined by the X-ray method.
The area ratio of the melting energy may be determined by the SC method.
【０００９】フィルムは更に好ましくは共重合ポリエス
テルを主体としたものであり、且つ該フィルムが実質的
に非晶質なレベルのものである。又最も好ましくは、原
料としての該共重合ポリエステルの実質的に非晶質であ
ることである。ここで実質的に非晶質のポリエステルと
は、通常市販されているその結晶融点（ＤＳＣ法によ
る）が２４５〜２６０℃にある所謂高結晶性ポリエチレ
ンテレフタレートを主体とした樹脂とは異なり、まず原
料としてのその重合体単体及び混合成分よりなる重合体
又は重合体同士をブレンドした組成物状にて、充分アニ
ール処理して平衡状態としたものをＸ線法によって結晶
化度を固定し、このサンプルを標準にして測定した結晶
化度が１０％以下のものであり、好ましくは５％以下、
より好ましくはＤＳＣ法でも融点がほとんど見られない
ものである。The film is more preferably based on a copolyester and the film is of a substantially amorphous level. Most preferably, the copolymer polyester as a raw material is substantially amorphous. Here, the substantially amorphous polyester is different from a commercially available resin mainly composed of so-called highly crystalline polyethylene terephthalate whose crystalline melting point (by the DSC method) is 245 to 260 ° C. In the form of a polymer consisting of the polymer alone and a mixed component or a composition in which the polymers are blended with each other, a state of equilibrium by sufficiently annealing is fixed to the crystallinity by an X-ray method. The degree of crystallinity measured by using as a standard is 10% or less, preferably 5% or less,
More preferably, a melting point is hardly observed even by the DSC method.
【００１０】本発明に用いるフィルムの厚みは好ましく
は０．５μｍ〜７μｍ、より好ましくは０．７μｍ〜５
μｍである。また、溶融開始温度としては、５０℃〜３
００℃、好ましくは７０℃〜２９０℃である。The thickness of the film used in the present invention is preferably 0.5 μm to 7 μm, more preferably 0.7 μm to 5 μm.
μm. The melting start temperature is 50 ° C. to 3 ° C.
00 ° C, preferably 70 ° C to 290 ° C.
【００１１】感熱孔版用印刷原紙に使用される熱可塑性
フィルムとインキ透過性支持体が接着剤等の層を介せず
２層である感熱孔版用印刷原紙は以下に具体的に述べる
方法により作成することができる。熱可塑性フィルムの
支持体側表面を熱溶融し、インキ透過性支持体と熱融着
する第１の方法としては、加熱した熱棒をインキ透過性
支持体と熱可塑性フィルムの間に位置するようにし、加
熱した熱棒が熱可塑性フィルムの支持体側表面を熱溶融
し、その後、該支持体と圧着し熱融着する方法である
（図１参照）。A heat-sensitive stencil printing base paper in which the thermoplastic film used for the heat-sensitive stencil printing base paper and the ink-permeable support are two layers without a layer of an adhesive or the like is prepared by a method specifically described below. can do. The first method of heat-melting the support-side surface of the thermoplastic film and heat-sealing the ink-permeable support with the ink-permeable support is to place a heated hot rod between the ink-permeable support and the thermoplastic film. In this method, a heated hot rod heat-melts the surface of the thermoplastic film on the side of the support, and is then pressed against the support and thermally fused (see FIG. 1).
【００１２】熱棒の加熱方法としては、棒の外周部が幅
方向に一定の温度になる様に加熱できる方法であればよ
く、例えば棒の内側に加熱源としてニクロム線を用いる
方法、棒の内側に加熱源として加熱蒸気または加熱オイ
ルを用いる方法などがある。加熱した熱棒の形状として
は円形または楕円形等の熱可塑性フィルムの支持体側表
面を損傷、裂傷させず且つ熱可塑性フィルムのインキ透
過性支持体側表面への熱伝導が良好な形状が望ましく、
加熱した熱棒が熱可塑性フィルムのインキ透過性支持体
側表面を熱溶融しインキ透過性支持体との熱融着する時
間を可能な限り短くする為（具体的には、０．１秒の短
時間内）熱棒の径は可能な限り小さくし（具体的には
０．１ｍｍφ〜１０ｍｍφ）、熱可塑性フィルムとイン
キ透過性支持体が接触する直前に位置させることが望ま
しい（例えば、０ｍｍ〜５０ｍｍの距離）。熱棒は、熱
可塑性フィルムとインキ透過性の支持体の２層と同速度
の周速で回転するようにした。また熱可塑性フィルムへ
の接触圧力は、０．１〜０．５ｇ／ｍｍ2とした。As a heating method of the heating rod, any method can be used as long as the outer peripheral portion of the rod can be heated to a constant temperature in the width direction. For example, a method using a nichrome wire as a heating source inside the rod, There is a method using heating steam or heating oil as a heating source inside. As the shape of the heated hot rod, a shape which does not damage the support side surface of the thermoplastic film such as a circle or an ellipse, does not rupture, and has good heat conduction to the ink permeable support side surface of the thermoplastic film is desirable.
In order to minimize the time required for the heated hot rod to heat-melt the surface of the thermoplastic film on the ink-permeable support side and to heat-bond the thermoplastic film to the ink-permeable support as much as possible (specifically, as short as 0.1 second). It is desirable that the diameter of the hot rod be as small as possible (specifically, 0.1 mmφ to 10 mmφ) and positioned immediately before the thermoplastic film comes into contact with the ink-permeable support (for example, 0 mm to 50 mm). Distance). The hot rod was rotated at the same peripheral speed as the two layers of the thermoplastic film and the ink-permeable support. The contact pressure with the thermoplastic film was 0.1 to 0.5 g / mm 2 .
【００１３】熱可塑性フィルムの支持体側表面を熱溶融
し、インキ透過性支持体と熱溶融する第２の方法として
は、インキ透過性支持体を熱可塑性フィルムの支持体側
表面と接触させる直前に、内部に加熱機構をもった熱ロ
ーラにより、熱可塑性フィルムの支持体側表面を熱溶融
させ得る温度までインキ透過性支持体を接触加熱させ、
該熱可塑性フィルムと圧着し、熱融着する方法である
（図２参照）。A second method for heat-melting the surface of the thermoplastic film on the support side and heat-melting the ink-permeable support with the ink-permeable support is as follows: immediately before bringing the ink-permeable support into contact with the surface of the thermoplastic film on the support side; By a heat roller having a heating mechanism inside, the ink-permeable support is contact-heated to a temperature at which the support-side surface of the thermoplastic film can be thermally melted,
This is a method in which the film is pressure-bonded to the thermoplastic film and heat-fused (see FIG. 2).
【００１４】内部に加熱機構をもった熱ローラの加熱源
としては、加熱蒸気、加熱オイルなどを用いることがで
きる。この場合においても熱可塑性フィルムを熱溶融し
てからインキ透過性支持体と熱融着するまでの時間は可
能な限り短くすることが好ましい。また、インキ透過性
の支持体への熱伝導を必要十分に行なう為に熱ローラの
径はある程度大きい方が良い（例えば５０ｍｍφ〜１０
００ｍｍφ）。上記の方法による加熱するインキ透過性
の支持体の温度は、熱融着させる熱可塑性フィルムの溶
融点より０〜５℃高温であると上記の方法による熱融着
は良好におこなえ、加熱するインキ透過性の支持体の性
能（インキ透過性支持体の強度及びインキの透過性）を
損なわない。As a heating source of the heat roller having a heating mechanism inside, heating steam, heating oil and the like can be used. Also in this case, it is preferable to shorten the time from the time when the thermoplastic film is thermally fused to the time when the thermoplastic film is thermally fused to the ink-permeable support as much as possible. In order to conduct heat to the ink-permeable support as necessary and sufficiently, the diameter of the heat roller is preferably somewhat large (for example, 50 mmφ to 10 mm).
00 mmφ). When the temperature of the ink-permeable support to be heated by the above method is 0 to 5 ° C. higher than the melting point of the thermoplastic film to be heat-sealed, the heat-sealing by the above method can be carried out well, The performance of the permeable support (strength of the ink permeable support and ink permeability) is not impaired.
【００１５】熱融着させるインキ透過性支持体として合
成繊維を主体とした薄葉紙を用いると、熱可塑性フィル
ムに用いられているポリエステル（好ましくは共重合体
ポリエステル）系、ナイロン（好ましくは共重合ナイロ
ン）系、ポリオレフィン系、ポリスチレン系、ポリ塩化
ビニル系、ポリアクリル酸誘導体系、ポリエチレン・ビ
ニルアルコール系、ポリカーボネート系共重合体等との
熱融着性が良好となり、熱可塑性フィルム部分の熱穿孔
性を損なわない。上記の様にして作成した熱融着した熱
可塑性フィルムとインキ透過性支持体との２層からなる
積層体の熱可塑性フィルム上にサーマルヘツド製版時の
熱融着防止層を０．１ｇ／ｍ2塗布し、本発明の優れた
性能と感度及び接着性に優れた性能を有する感熱孔版用
印刷原紙を作成することができる。When thin paper mainly composed of synthetic fibers is used as the ink-permeable support to be heat-fused, polyester (preferably copolymer polyester) based nylon or nylon (preferably copolymer nylon) used for the thermoplastic film is used. ), Polyolefin, polystyrene, polyvinyl chloride, polyacrylic acid derivative, polyethylene / vinyl alcohol, polycarbonate copolymers, etc. Does not impair. On the thermoplastic film of the laminate composed of the two layers of the heat-fused thermoplastic film and the ink-permeable support formed as described above, a heat-fusion preventing layer at the time of thermal head plate-making is 0.1 g / m 2. Two coatings can be used to prepare a heat-sensitive stencil printing base paper having the excellent performance of the present invention and the performance excellent in sensitivity and adhesiveness.
【００１６】本発明による感熱孔版用印刷原紙を使用す
ることによって、サーマルヘッドにより供給されるエネ
ルギーが少量時においても、優れた性能と感度を有する
感熱孔版用印刷原紙を提供することができる。また、イ
ンキ透過性支持体と熱可塑性フィルムの接着方法とし
て、熱可塑性フィルムの支持体側表面を熱溶融後、イン
キ透過性支持体と熱融着することにより、感熱孔版用印
刷原紙は熱可塑性フィルム部分の熱穿孔性を損なわず優
れた性能と感度を有する感熱孔版用印刷原紙を提供する
ことができる。特に優れた熱融着方法は、熱可塑性フィ
ルムの支持体側表面に加熱したインキ透過性支持体を接
触させ熱溶融する方法で、この方法で製造することによ
り、熱可塑性フィルムの支持体側表面のインキ透過性支
持体非接触部の熱溶融を防止することが可能となり、熱
可塑性フィルム部分の熱穿孔性を損なわず優れた性能と
感度を有する感熱孔版用印刷原紙を提供することができ
る。加熱するインキ透過性支持体の温度が、熱融着させ
る熱可塑性フィルムの溶融温度より５℃を越える高温で
ある場合、加熱されたインキ透過性支持体の接触により
熱可塑性フィルムの熱穿孔性を著しく悪化させる。特に
著しく悪化させた場合、熱可塑性フィルムはインキ透過
性支持体により熱穿孔された状態となり、感熱孔版用印
刷原紙として使用不能となる。また、加熱するインキ透
過性支持体の温度が、熱融着させる熱可塑性フィルムの
溶融点より低温である場合、加熱されたインキ透過性支
持体の接触により熱可塑性フィルムは熱溶融せず、熱可
塑性フィルムとインキ透過性の支持体の熱融着は可能と
ならない。したがって加熱するインキ透過性支持体の温
度が、熱融着させる熱可塑性フィルムの溶融点より０〜
５℃高温であることを特徴とすることにより、熱可塑性
フィルム部分の熱穿孔性を損なわず優れた性能と感度を
有する感熱孔版用印刷原紙を提供することができる。熱
融着させるインキ透過性支持体として天然繊維を主体と
した薄葉紙を用いた場合、熱可塑性フィルムとの融着性
が悪く、熱可塑性フィルムとインキ透過性支持体の熱融
着は可能とならない。熱融着させるインキ透過性支持体
として合成繊維を主体とした薄葉紙を用いた場合、熱可
塑性フィルムとの融着性は良好であり、熱可塑性フィル
ムとインキ透過性支持体の熱融着は可能となり、熱可塑
性フィルム部分の熱穿孔性を損なわず優れた性能と感度
及び接着性に優れた性能を有する感熱孔版用印刷原紙を
提供することができる。By using the heat-sensitive stencil printing base paper according to the present invention, a heat-sensitive stencil printing base paper having excellent performance and sensitivity can be provided even when the energy supplied by the thermal head is small. In addition, as a method of bonding the ink-permeable support and the thermoplastic film, the support-side surface of the thermoplastic film is heat-fused and then heat-fused with the ink-permeable support, so that the heat-sensitive stencil printing base paper is a thermoplastic film. It is possible to provide a heat-sensitive stencil printing base paper having excellent performance and sensitivity without impairing the heat-perforability of a portion. A particularly excellent heat-sealing method is a method in which a heated ink-permeable support is brought into contact with the surface of the thermoplastic film on the support side and is melted by heating. By this method, the ink on the support-side surface of the thermoplastic film is produced. It is possible to prevent thermal melting of the non-contact portion of the permeable support, and to provide a heat-sensitive stencil printing base paper having excellent performance and sensitivity without impairing the thermal porosity of the thermoplastic film portion. When the temperature of the ink-permeable support to be heated is higher than the melting temperature of the thermoplastic film to be heat-fused by more than 5 ° C. , the thermal perforation of the thermoplastic film is reduced by the contact of the heated ink-permeable support. Significantly worsens. In particular, when it is significantly deteriorated, the thermoplastic film is in a state of being perforated by the ink-permeable support, and cannot be used as a heat-sensitive stencil printing base paper. When the temperature of the ink-permeable support to be heated is lower than the melting point of the thermoplastic film to be heat-fused, the thermoplastic film does not melt due to the contact of the heated ink-permeable support, Thermal fusion of the plastic film and the ink-permeable support is not possible. Therefore, the temperature of the ink-permeable support to be heated is 0 to the melting point of the thermoplastic film to be heat-sealed.
By being characterized by a high temperature of 5 ° C., it is possible to provide a heat-sensitive stencil printing base paper having excellent performance and sensitivity without impairing the thermal porosity of the thermoplastic film portion. When thin paper mainly composed of natural fibers is used as the ink-permeable support to be heat-sealed, the heat-sealing property between the thermoplastic film and the ink-permeable support is not possible due to poor fusion property with the thermoplastic film. . When thin paper made mainly of synthetic fiber is used as the ink-permeable support to be heat-sealed, the fusion property with the thermoplastic film is good, and the heat-fusion of the thermoplastic film and the ink-permeable support is possible. Thus, it is possible to provide a heat-sensitive stencil printing base paper having excellent performance and excellent performance in sensitivity and adhesiveness without impairing the heat piercing property of the thermoplastic film portion.
【００１７】[0017]
【実施例】次に実施例により本発明を更に詳細に説明す
るが本発明はこれらの例によってなんら限定されるもの
ではない。なお、各例中の物性の測定は以下の方法で行
なった。 （１）結晶化度 Ｘ線回折法により、所定の試料について、２θ：０゜〜
４０゜の範囲において、Ｘ線回折強度を測定し、あらか
じめ結晶化度が知られている標準試料との間の面積比か
ら結晶化度を求める。また、ＤＳＣ法により、所定の試
料について、昇温速度１０℃／ｍｉｎで融点測定を行な
い、あらかじめ融解熱が知られている酸化アルミニウム
の標準試料との間の面積比から融解熱（△Ｈ）を求め、
次式に従って計算してもよい。 結晶化度＝１００×△Ｈ／△Ｈｍ ただし、△Ｈｍは試料自体の結晶成分の融解熱。 （２）溶融温度 ＤＳＣ法により、所定の試料について、昇温速度１０℃
／ｍｉｎで融点測定を行ない、あらかじめ融解熱が知ら
れている酸化アルミニウムの標準試料との示差熱カーブ
の融解熱（△Ｈ）を求めた面積範囲の最も低温側（吸熱
が始まる温度）を溶融温度とした。 （３）穿孔感度 所定の感熱孔版用印刷原紙について、（株）リコー社製
プリポートＶＴ−３５００の製版部のライン型サーマル
ヘッドを用いて、調整された印加エネルギーのもとで穿
孔し、黒べタ部（標準条件、文字モードで製版印刷した
安定部分）の光学濃度をマクベス社製濃度計ＲＤ９１４
により測定し、標準黒サンプルをブランクとしたときの
値をもって穿孔感度とする。 （４）耐刷性 所定の感熱孔版用印刷原紙について、（株）リコー社製
プリポートＶＴ−３５００の製版部にライン型サーマル
ヘッドを用いて、調整された印加エネルギーのもとで穿
孔し、ある一定の印刷枚数を印刷し耐刷性を評価した。Next, the present invention will be described in more detail by way of examples, but the present invention is not limited to these examples. In addition, the measurement of the physical property in each example was performed by the following methods. (1) Crystallinity By a X-ray diffraction method, for a predetermined sample, 2θ: 0 ゜
The X-ray diffraction intensity is measured in the range of 40 °, and the crystallinity is determined from the area ratio with respect to a standard sample whose crystallinity is known in advance. Further, the melting point of a predetermined sample is measured at a heating rate of 10 ° C./min by the DSC method, and the heat of fusion (ΔH) is determined from the area ratio between the predetermined sample and the standard sample of aluminum oxide whose heat of fusion is known in advance. ,
It may be calculated according to the following equation. Crystallinity = 100 × ΔH / ΔHm where ΔHm is the heat of fusion of the crystal component of the sample itself. (2) Melting temperature According to the DSC method, a predetermined sample was heated at a rate of 10 ° C.
The melting point is measured at / min, and the lowest temperature side (the temperature at which endotherm starts) of the area range where the heat of fusion (ΔH) of the differential heat curve with the standard sample of aluminum oxide whose heat of fusion is known is determined in advance is melted. Temperature. (3) Perforation sensitivity A predetermined printing base paper for heat-sensitive stencil was perforated under the applied energy adjusted by using a line-type thermal head of a plate making section of Preport VT-3500 manufactured by Ricoh Co., Ltd. Density (standard conditions, stable part printed and made in character mode) was measured using a densitometer RD914 manufactured by Macbeth.
And the value obtained when a standard black sample is used as a blank is defined as the perforation sensitivity. (4) Printing Durability A predetermined heat-sensitive stencil printing base paper was perforated in a plate making section of Preport VT-3500 manufactured by Ricoh Co., Ltd. using a line thermal head under an adjusted applied energy. A fixed number of prints were printed and the printing durability was evaluated.
【００１８】実施例１ 熱可塑性フィルムとして共重合ポリエステルを主体とし
たフィルムが実質的に非晶質な（結晶化度１．０％）厚
み１．８μｍ、溶融温度１８０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％からなる合成繊維紙を用い、１８５℃に加熱した
熱棒１０ｍｍφをインキ透過性支持体と熱可塑性フィル
ムの間に位置する様にし、加熱した熱棒１０ｍｍφが熱
可塑性フィルムの支持体側表面を熱溶融するように接触
させてインキ透過性支持体と熱融着する様にした。加熱
した熱棒は円形の熱可塑性フィルムの支持体側表面を損
傷、裂傷させず、且つ熱可塑性フィルムの支持体側の表
面への熱伝導が良好な鉄を用いた。熱棒が熱可塑性フィ
ルムの支持体側表面を熱溶融しインキ透過性支持体と熱
融着する時間を可能な限り短くする為、熱棒の径は１０
ｍｍφとし、熱可塑性フィルムとインキ透過性支持体が
接触する５０ｍｍ前に位置し、熱可塑性フィルムと支持
体が０．５ｍ／ｓｅｃの速度で貼合わさるようにした。
その後該熱可塑性フィルム上に熱融着防止層を０．１ｇ
／ｍ2塗布し、本発明の感熱孔版用印刷原紙を作成し
た。Example 1 As a thermoplastic film, a film mainly composed of a copolymerized polyester having a substantially amorphous (crystallinity: 1.0%) thickness of 1.8 μm and a melting temperature of 180 ° C. was used. Polyethylene terephthalate fiber 1 as a permeable support
Using a synthetic fiber paper consisting of 00%, a hot rod 10 mmφ heated to 185 ° C. is positioned between the ink-permeable support and the thermoplastic film, and the heated hot rod 10 mmφ is applied to the surface of the thermoplastic film on the support side. The contact was made so as to be melted by heat so as to be heat-fused with the ink-permeable support. The heated hot rod used iron that did not damage or tear the surface of the circular thermoplastic film on the support side and had good heat conduction to the surface of the thermoplastic film on the support side. The diameter of the hot rod should be 10 in order to minimize the time required for the hot rod to heat-melt the surface of the thermoplastic film on the support side and to heat-bond it to the ink-permeable support as much as possible.
mmφ, the thermoplastic film and the support were positioned 50 mm before contact with the ink-permeable support, and the thermoplastic film and the support were bonded at a speed of 0.5 m / sec.
Thereafter, 0.1 g of the heat-sealing prevention layer was formed on the thermoplastic film.
/ M 2 to prepare a heat-sensitive stencil printing base paper of the present invention.
【００１９】実施例２ 熱可塑性フィルムとして一般に市販されているポリエチ
レンテレフタレートフィルムの結晶融点（ＤＳＣ法によ
る）が２５０℃にある高結晶性（結晶化度４５％）ポリ
エチレンテレフタレート２．０μｍ、溶融温度２４０℃
のものを用い、インキ透過性の支持体としてポリエチレ
ンテレフタレート繊維３０％、マニラ麻７０％からなる
合成繊維・天然繊維を用いた混抄紙を用い、２４５℃に
加熱した熱棒１０ｍｍφをインキ透過性支持体と熱可塑
性フィルムの間に位置する様にし、加熱した熱棒１０ｍ
ｍφが熱可塑性フィルムの支持体側表面を熱溶融するよ
うに接触させインキ透過性支持体と熱融着する様にし
た。加熱した熱棒は円形の熱可塑性フィルムの支持体側
表面を損傷、裂傷させず且つ熱可塑性フィルムの支持体
側表面への熱伝導が良好な鉄を用いた。熱棒が熱可塑性
フィルムの支持体側表面を熱溶融しインキ透過性支持体
と熱融着する時間を可能な限り短くする為、熱棒の径は
１０ｍｍφとし、熱可塑性フィルムとインキ透過性支持
体が接触する５０ｍｍ前に位置し、熱可塑性フィルムと
支持体が０．５ｍ／ｓｅｃの速度で貼合わさるようにし
た。その後該熱可塑性フィルムの上に熱融着防止層を
０．１ｇ／ｍ2塗布し、本発明の感熱孔版用印刷原紙を
作成した。Example 2 A polyethylene terephthalate film generally commercially available as a thermoplastic film has a crystalline melting point (according to DSC method) of 250 ° C. Highly crystalline (45% crystallinity) polyethylene terephthalate 2.0 μm, melting temperature 240 ° C
Using a mixed paper made of synthetic fiber and natural fiber composed of 30% polyethylene terephthalate fiber and 70% manila hemp as an ink-permeable support, and using a hot rod 10 mmφ heated to 245 ° C. as an ink-permeable support 10m heated hot rod so that it is located between the
The mφ contact was made so that the surface of the thermoplastic film on the support side was melted by heat so that the thermoplastic film was thermally fused with the ink-permeable support. The heated hot rod used iron which did not damage or tear the surface of the circular thermoplastic film on the support side and had good heat conduction to the surface of the thermoplastic film on the support side. In order to minimize the time required for the hot rod to heat-melt the surface of the thermoplastic film on the support side and heat-bond it to the ink-permeable support, the diameter of the hot rod is 10 mmφ, and the thermoplastic film and the ink-permeable support Is located 50 mm before contact with the thermoplastic film, and the thermoplastic film is bonded to the support at a speed of 0.5 m / sec. Thereafter, a heat-fusing-preventing layer was applied at 0.1 g / m 2 on the thermoplastic film to prepare a heat-sensitive stencil printing base paper of the present invention.
【００２０】実施例３ 熱可塑性フィルムとして共重合ポリエステルを主体とし
たフィルムが実質的に非晶質な（結晶化度１．０％）厚
み１．８μｍ、溶融温度１８０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％からなる合成繊維紙を用い、インキ透過性支持体
を熱可塑性フィルムの支持体側表面と接触させる直前に
内部に加熱機構をもった１８５℃に加熱した熱ローラに
より加熱し、熱可塑性フィルムの支持体側表面を加熱し
たインキ透過性支持体により熱溶融させ熱融着させた。
この場合においても加熱したインキ透過性支持体が熱可
塑性フィルムの支持体側表面を熱溶融しインキ透過性支
持体と熱融着する時間を可能な限り短くする為に熱ロー
ラから加熱したインキ透過性支持体が熱可塑性フィルム
の支持体側表面を熱溶融しインキ透過性支持体と熱融着
する距離は０．０ｍｍとし、また、インキ透過性支持体
への熱伝導を必要十分に行なう為に熱ローラの径は５０
０ｍｍφとした。熱可塑性フィルムとインキ透過性支持
体が０．５ｍ／ｓｅｃの速度で貼合わさるようにした。
その後該熱可塑性フィルム上に熱融着防止層を０．１ｇ
／ｍ2塗布し、本発明の感熱孔版用印刷原紙を作成し
た。EXAMPLE 3 As a thermoplastic film, a film mainly composed of a copolymerized polyester having a substantially amorphous (crystallinity 1.0%) thickness of 1.8 μm and a melting temperature of 180 ° C. was used. Polyethylene terephthalate fiber 1 as a permeable support
Immediately before the ink-permeable support was brought into contact with the surface of the thermoplastic film on the support side using a synthetic fiber paper consisting of 00%, the thermoplastic film was heated by a heat roller heated to 185 ° C. with a heating mechanism inside. The support side surface was heated and fused by a heated ink-permeable support.
In this case, too, the heated ink permeable support heats the support-side surface of the thermoplastic film and heat-fuses with the ink permeable support in order to minimize the time required for the heat fusibility. The distance at which the support thermally melts the surface of the thermoplastic film on the support side and heat-fuses the surface with the ink-permeable support is 0.0 mm, and heat is applied to conduct heat to the ink-permeable support as necessary and sufficiently. Roller diameter is 50
0 mmφ. The thermoplastic film and the ink-permeable support were bonded at a speed of 0.5 m / sec.
Thereafter, 0.1 g of the heat-sealing prevention layer was formed on the thermoplastic film.
/ M 2 to prepare a heat-sensitive stencil printing base paper of the present invention.
【００２１】実施例４ 熱可塑性フィルムとして一般に市販されているポリエチ
レンテレフタレートフィルムの結晶融点（ＤＳＣ法によ
る）が２５０℃にある高結晶性（結晶化度４０％）ポリ
エチレンテレフタレート２．０μｍ、溶融温度２４０℃
のものを用い、インキ透過性支持体としてポリエチレン
テレフタレート繊維１００％、合成繊維紙を用い、イン
キ透過性支持体を熱可塑性フィルムの支持体側表面と接
触させる直前に内部に加熱機構をもった２４５℃に加熱
した熱ローラにより加熱し、熱可塑性フィルムの支持体
側表面を加熱したインキ透過性支持体により熱溶融させ
熱融着させた。この場合においても加熱したインキ透過
性支持体が熱可塑性フィルムの支持体側表面を熱溶融し
インキ透過性支持体と熱融着する時間を可能な限り短く
する為に熱ローラから加熱したインキ透過性支持体が熱
可塑性フィルムの支持体側表面を熱溶融しインキ透過性
支持体と熱融着する距離は０．０ｍｍとし、また、イン
キ透過性支持体への熱伝導を必要十分に行なう為に熱ロ
ーラの径は５００ｍｍφとした。熱可塑性フィルムとイ
ンキ透過性の支持体が０．５ｍ／ｓｅｃの速度で貼合わ
さるようにした。その後該熱可塑性フィルム上に熱融着
防止層を０．１ｇ／ｍ2塗布し、本発明の感熱孔版用印
刷原紙を作成した。Example 4 A polyethylene terephthalate film generally commercially available as a thermoplastic film has a crystalline melting point (according to DSC method) of 250 ° C., high crystalline (40% crystallinity) polyethylene terephthalate 2.0 μm, melting temperature 240 ° C
245 ° C. having a heating mechanism inside immediately before the ink-permeable support is brought into contact with the surface of the thermoplastic film on the support side, using 100% polyethylene terephthalate fiber and synthetic fiber paper as the ink-permeable support. Then, the surface of the thermoplastic film on the side of the support was heat-melted by the heated ink-permeable support and heat-sealed. In this case, too, the heated ink permeable support heats the support-side surface of the thermoplastic film and heat-fuses with the ink permeable support in order to minimize the time required for the heat fusibility. The distance at which the support thermally melts the surface of the thermoplastic film on the support side and heat-fuses the surface with the ink-permeable support is 0.0 mm, and heat is applied to conduct heat to the ink-permeable support as necessary and sufficiently. The diameter of the roller was 500 mmφ. The thermoplastic film and the ink-permeable support were laminated at a speed of 0.5 m / sec. Thereafter, a heat-fusing-preventing layer was applied at 0.1 g / m 2 on the thermoplastic film to prepare a heat-sensitive stencil printing base paper of the present invention.
【００２２】実施例５ 熱可塑性フィルムとしてポリエチレンテレフタレートフ
ィルムの結晶融点（ＤＳＣ法による）が２１０℃にある
高結晶性（結晶化度２５％）ポリエチレンテレフタレー
ト２．０μｍ、溶融温度１９０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％の合成繊維紙を用い、インキ透過性支持体を熱可
塑性フィルムの支持体側表面と接触させる直前に内部に
加熱機構をもった１９５℃に加熱した熱ローラにより加
熱し、これにより熱可塑性フィルムの支持体側表面を熱
溶融させ熱融着させた。この場合においても加熱したイ
ンキ透過性支持体が熱可塑性フィルムの支持体側表面を
熱溶融しインキ透過性支持体と熱融着する時間を可能な
限り短くする為に熱ローラから加熱したインキ透過性支
持体が熱可塑性フィルムの支持体側表面を熱溶融しイン
キ透過性支持体と熱融着する距離は０．０ｍｍとし、ま
た、インキ透過性支持体への熱伝導を必要十分に行なう
為に熱ローラの径は５００ｍｍφとした。熱可塑性フィ
ルムとインキ透過性支持体が０．５ｍ／ｓｅｃの速度で
貼合わさるようにした。その後該熱可塑性フィルム上に
熱融着防止層を０．１ｇ／ｍ2塗布し、本発明の感熱孔
版用印刷原紙を作成した。Example 5 As a thermoplastic film, a polyethylene terephthalate film having a crystal melting point (according to DSC method) of 210 ° C., high crystallinity (crystallinity 25%) polyethylene terephthalate 2.0 μm, and a melting temperature of 190 ° C. is used. Polyethylene terephthalate fiber 1 as an ink-permeable support
Immediately before the ink-permeable support was brought into contact with the support-side surface of the thermoplastic film using a 00% synthetic fiber paper, it was heated by a heat roller heated to 195 ° C. having a heating mechanism inside, thereby forming the thermoplastic film. The surface of the support side was heat-fused and heat-sealed. In this case, too, the heated ink permeable support heats the support-side surface of the thermoplastic film and heat-fuses with the ink permeable support in order to minimize the time required for the heat fusibility. The distance at which the support thermally melts the surface of the thermoplastic film on the support side and heat-fuses the surface with the ink-permeable support is 0.0 mm, and heat is applied to conduct heat to the ink-permeable support as necessary and sufficiently. The diameter of the roller was 500 mmφ. The thermoplastic film and the ink-permeable support were bonded at a speed of 0.5 m / sec. Thereafter, a heat-fusing-preventing layer was applied at 0.1 g / m 2 on the thermoplastic film to prepare a heat-sensitive stencil printing base paper of the present invention.
【００２３】実施例６ 熱可塑性フィルムとして共重合ポリエステルを主体とし
たフィルムが実質的に非晶質な（結晶化度１．０％）厚
み１．８μｍ、溶融温度１８０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％からなる合成繊維を用い、１８５℃に加熱した熱
棒１００ｍｍφをインキ透過性支持体と熱可塑性フィル
ムの間に位置する様にし、加熱した熱棒１００ｍｍφが
熱可塑性フィルムの支持体側表面を熱溶融するように接
触させてインキ透過性支持体と熱融着する様にした。加
熱した熱棒は円形の熱可塑性フィルムの支持体側表面を
損傷、裂傷させず且つ熱可塑性フィルムの支持体側表面
への熱伝導が良好な鉄を用いた。熱棒が熱可塑性フィル
ムの支持体側表面を熱溶融しインキ透過性支持体と熱融
着する時間を可能な限り短くする為、熱棒の径は１０ｍ
ｍφとし、熱可塑性フィルムとインキ透過性支持体が接
触する５０ｍｍ前に位置し、熱可塑性フィルムとインキ
透過性支持体が０．５ｍ／ｓｅｃの速度で貼合わさるよ
うにした。その後該熱可塑性フィルム上に熱融着防止層
を０．１ｇ／ｍ2塗布し感熱孔版用印刷原紙を作成し
た。熱可塑性フィルムの熱溶融が若干不完全であり熱可
塑性フィルムに裂傷が僅かに発生し熱可塑性フィルムと
インキ透過性支持体との熱融着が多少不充分であるた
め、感熱孔版用印刷原紙として実施例１〜５のものに比
べて少し劣っていた。Example 6 As a thermoplastic film, a film mainly composed of a copolymerized polyester having a thickness of 1.8 μm, which is substantially amorphous (crystallinity 1.0%), and a melting temperature of 180 ° C. was used. Polyethylene terephthalate fiber 1 as a permeable support
Using 100% synthetic fiber, a hot rod 100 mmφ heated to 185 ° C. is positioned between the ink-permeable support and the thermoplastic film, and the heated hot rod 100 mmφ heats the support-side surface of the thermoplastic film. The contact was made so as to be melted, so that the ink was thermally fused to the ink-permeable support. The heated hot rod used iron which did not damage or tear the surface of the circular thermoplastic film on the support side and had good heat conduction to the surface of the thermoplastic film on the support side. The diameter of the hot rod is 10 m in order to minimize the time required for the hot rod to heat-melt the support-side surface of the thermoplastic film and the ink-permeable support as much as possible.
mφ, 50 mm before the thermoplastic film and the ink-permeable support were in contact with each other, and the thermoplastic film and the ink-permeable support were bonded at a speed of 0.5 m / sec. Thereafter, a heat-fusing-preventing layer was applied at 0.1 g / m 2 on the thermoplastic film to prepare a printing base paper for heat-sensitive stencil. As the thermal fusion of the thermoplastic film is slightly incomplete and the thermoplastic film slightly cracks, and the thermal fusion between the thermoplastic film and the ink-permeable support is somewhat insufficient, so it is used as a heat-sensitive stencil printing base paper. It was slightly inferior to those of Examples 1 to 5.
【００２４】実施例７ 熱可塑性フィルムとして共重合ポリエステルを主体とし
たフィルムが実質的に非晶質な（結晶化度１．０％）厚
み１．８μｍ、溶融温度１８０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％からなる合成繊維を用い、１８５℃に加熱した熱
棒１０ｍｍφをインキ透過性支持体と熱可塑性フィルム
の間に位置する様にし、加熱した熱棒１０ｍｍφが熱可
塑性フィルムの支持体側表面を熱溶融するように接触さ
せてインキ透過性支持体と熱融着する様にした。加熱し
た熱棒は円形の熱可塑性フィルムの支持体側表面を損
傷、裂傷させず且つ熱可塑性フィルムの支持体側表面へ
の熱伝導が良好な鉄を用いた。熱棒が熱可塑性フィルム
の支持体側表面を熱溶融しインキ透過性支持体と熱融着
する時間を可能な限り短くする為、熱棒の径は１０ｍｍ
φとし、熱可塑性フィルムとインキ透過性支持体が接触
する位置から１００ｍｍの距離に位置し、熱可塑性フィ
ルムとインキ透過性支持体が０．５ｍ／ｓｅｃの速度で
貼合わさるようにした。その後該熱可塑性フィルム上に
熱融着防止層を０．１ｇ／ｍ2塗布し感熱孔版用印刷原
紙を作成した。熱可塑性フィルムの熱溶融が若干不完全
であり熱可塑性フィルムとインキ透過性支持体との熱融
着が多少不充分であり、感熱孔版用印刷原紙として実施
例１〜５のものに比較して少し劣っていた。Example 7 As a thermoplastic film, a film mainly composed of a copolymerized polyester having a substantially amorphous (crystallinity: 1.0%) thickness of 1.8 μm and a melting temperature of 180 ° C. was used. Polyethylene terephthalate fiber 1 as a permeable support
Using a synthetic fiber of 100%, a hot rod 10 mmφ heated to 185 ° C. is positioned between the ink-permeable support and the thermoplastic film, and the heated hot rod 10 mmφ heats the surface of the thermoplastic film on the support side. The contact was made so as to be melted, so that the ink was thermally fused to the ink-permeable support. The heated hot rod used iron which did not damage or tear the surface of the circular thermoplastic film on the support side and had good heat conduction to the surface of the thermoplastic film on the support side. The diameter of the hot rod is 10 mm in order to minimize the time required for the hot rod to heat-melt the surface of the thermoplastic film on the support side and to heat-bond it to the ink-permeable support as much as possible.
φ was set at a distance of 100 mm from a position where the thermoplastic film and the ink-permeable support were in contact with each other, and the thermoplastic film and the ink-permeable support were bonded at a speed of 0.5 m / sec. Thereafter, a heat-fusing-preventing layer was applied at 0.1 g / m 2 on the thermoplastic film to prepare a printing base paper for heat-sensitive stencil. The thermal fusion of the thermoplastic film was slightly incomplete, the thermal fusion between the thermoplastic film and the ink-permeable support was somewhat insufficient, and as compared with those of Examples 1 to 5 as heat-sensitive stencil printing base paper. It was a bit inferior.
【００２５】実施例８ 熱可塑性フィルムとしてポリエチレンテレフタレートフ
ィルムの結晶融点（ＤＳＣ法による）が２１０℃にある
高結晶性（結晶化度２５％）ポリエチレンテレフタレー
ト２．０μｍ、溶融温度１９０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％の合成繊維紙を用い、インキ透過性支持体を熱可
塑性フィルムの支持体側表面と接触させる直前に内部に
加熱機構をもった１９５℃に加熱した熱ローラにより加
熱し、感熱孔版用フィルムの支持体側の表面を加熱した
インキ透過性支持体により熱溶融させ熱融着させた。こ
の場合においても加熱したインキ透過性支持体が熱可塑
性フィルムの支持体側表面層を熱溶融しインキ透過性支
持体と熱融着する時間を可能な限り短くする為に熱ロー
ラから加熱したインキ透過性支持体が熱可塑性フィルム
の支持体側表面を熱溶融しインキ透過性支持体と熱融着
する距離は０．０ｍｍとし、また、インキ透過性支持体
への熱伝導を必要十分に行なう為に熱ローラの径は５ｍ
ｍφとした。熱可塑性フィルムとインキ透過性支持体は
０．４ｍ／ｓｅｃの速度で貼合わさるようにした。その
後該熱可塑性フィルム上に熱融着防止層を０．１ｇ／ｍ
2塗布し、本発明の感熱孔版用印刷原紙を作成した。熱
可塑性フィルムの熱溶融が若干不完全であり熱可塑性フ
ィルムとインキ透過性支持体との熱融着が充分行なえ
ず、感熱孔版用印刷原紙として実施例１〜５のものに比
較して少し劣っていた。Example 8 As a thermoplastic film, a polyethylene terephthalate film having a crystalline melting point (by the DSC method) of 210 ° C., high crystalline (25% crystallinity) polyethylene terephthalate 2.0 μm, and a melting temperature of 190 ° C. is used. Polyethylene terephthalate fiber 1 as an ink-permeable support
Immediately before the ink-permeable support was brought into contact with the support-side surface of the thermoplastic film using a 00% synthetic fiber paper, it was heated by a heat roller heated to 195 ° C. having a heating mechanism inside, and the heat-sensitive stencil film was heated. The surface on the side of the support was heat-fused by a heated ink-permeable support and was heat-sealed. In this case, too, the heated ink-permeable support heat-fuses the support-side surface layer of the thermoplastic film and heat-fuses with the ink-permeable support in order to minimize the time required for heat-sealing. The distance at which the porous support thermally fuses the surface of the thermoplastic film on the support side and heat-fuses it with the ink-permeable support is 0.0 mm. In order to conduct heat to the ink-permeable support as necessary and sufficiently, Heat roller diameter is 5m
mφ. The thermoplastic film and the ink-permeable support were bonded at a speed of 0.4 m / sec. Thereafter, a heat-fusion preventing layer is formed on the thermoplastic film by 0.1 g / m 2.
2 was applied to prepare a printing stencil sheet for heat-sensitive stencil of the present invention. The thermal fusion of the thermoplastic film was slightly incomplete, and the thermal fusion between the thermoplastic film and the ink-permeable support could not be performed sufficiently. As a heat-sensitive stencil printing base paper, it was slightly inferior to those of Examples 1 to 5. I was
【００２６】比較例１ 熱可塑性フィルムとして一般に市販されているポリエチ
レンテレフタレートフィルムの結晶融点（ＤＳＣ法によ
る）が２５０℃にある高結晶性（結晶化度４５％）ポリ
エチレンテレフタレート２．０μｍ、溶融温度２４０℃
のものを用い、インキ透過性支持体としてポリエチレン
テレフタレート繊維３０％、マニラ麻７０％からなる合
成繊維・天然繊維を用いた混抄紙を用い、塩ビ／酢ビ系
接着剤を１．０ｇ／ｍ2の付着量となるようにして接着
積層し熱融着防止層を０．１ｇ／ｍ2塗布し、感熱孔版
用印刷原紙を作成したが熱可塑性フィルムとインキ透過
性支持体の間に接着層があり熱可塑性フィルムとインキ
透過性支持体との間の接着層により熱可塑性フィルムの
熱穿孔性を阻害し溶融し穿孔感度の良好な感熱孔版用印
刷原紙が作成できなかった。Comparative Example 1 A polyethylene terephthalate film, which is generally commercially available as a thermoplastic film, has a crystalline melting point (by DSC method) of 250 ° C., high crystalline (45% crystallinity) polyethylene terephthalate 2.0 μm, melting temperature 240 ° C
Using a mixed paper made of a synthetic fiber / natural fiber composed of 30% polyethylene terephthalate fiber and 70% manila hemp as an ink-permeable support, and a polyvinyl chloride / vinyl acetate adhesive of 1.0 g / m 2 . Adhesion and lamination were performed so that the adhesion amount was reached, and a heat-fusion preventing layer was applied at 0.1 g / m 2 to prepare a printing base paper for heat-sensitive stencil. However, there was an adhesion layer between the thermoplastic film and the ink-permeable support. The adhesive layer between the thermoplastic film and the ink-permeable support interfered with the thermal porosity of the thermoplastic film and melted, making it impossible to prepare a heat-sensitive stencil printing base paper having good piercing sensitivity.
【００２７】比較例２ 熱可塑性フィルムとして共重合ポリエステルを主体とし
たフィルムが実質的に非晶質な（結晶化度１．０％）厚
み１．８μｍ、溶融温度１８０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％からなる合成繊維紙を用い、１８５℃に加熱した
熱棒１０ｍｍφをインキ透過性支持体と熱可塑性フィル
ムの間に位置する様にし、加熱した熱棒１０ｍｍφが熱
可塑性フィルムの支持体側と逆側の表面を熱溶融するよ
うに接触させ、インキ透過性支持体と熱融着する様にし
た。加熱した熱棒は円形の熱可塑性フィルムの支持体側
表面を損傷、裂傷させず且つ熱可塑性フィルムの支持体
側表面への熱伝導が良好な鉄を用いた。熱棒が熱可塑性
フィルムのインキ透過性支持体側表面を熱溶融し、イン
キ透過性支持体と熱融着する時間を可能な限り短くする
為、熱棒の径は１０ｍｍφとし、熱可塑性フィルムとイ
ンキ透過性支持体が接触する５０ｍｍ前に位置し、熱可
塑性フィルムとインキ透過性支持体が０．５ｍ／ｓｅｃ
の速度で貼合わさるようにした。その後該熱可塑性フィ
ルムの上に熱融着防止層を０．１ｇ／ｍ2塗布し感熱孔
版用印刷原紙を作成したが、熱可塑性フィルムの熱溶融
が不十分であり熱可塑性フィルムとインキ透過性支持体
との熱融着が行なえず良好な感熱孔版用印刷原紙が作成
できなかった。COMPARATIVE EXAMPLE 2 As a thermoplastic film, a film mainly composed of a copolymerized polyester having a thickness of 1.8 μm, which is substantially amorphous (crystallinity 1.0%), and a melting temperature of 180 ° C. was used. Polyethylene terephthalate fiber 1 as a permeable support
Using a synthetic fiber paper consisting of 00%, a hot rod 10 mmφ heated to 185 ° C. is positioned between the ink-permeable support and the thermoplastic film, and the heated hot rod 10 mmφ is opposite to the support side of the thermoplastic film. The surface on the side was contacted so as to be melted by heat so as to be heat-fused with the ink-permeable support. The heated hot rod used iron which did not damage or tear the surface of the circular thermoplastic film on the support side and had good heat conduction to the surface of the thermoplastic film on the support side. In order to minimize the time required for the hot rod to heat-melt the surface of the thermoplastic film on the ink-permeable support side and to heat-bond it to the ink-permeable support as much as possible, the diameter of the hot rod is 10 mmφ, It is located 50 mm before the permeable support comes into contact with the thermoplastic film and the ink permeable support at 0.5 m / sec.
It was made to stick at the speed of. Thereafter, a heat-fusion preventing layer was coated on the thermoplastic film at a rate of 0.1 g / m 2 to prepare a printing stencil for heat-sensitive stencil printing. A good heat-sensitive stencil printing base paper could not be prepared because heat-sealing with the support could not be performed.
【００２８】比較例３ 熱可塑性フィルムとして一般に市販されているポリエチ
レンテレフタレートフィルムの結晶融点（ＤＳＣ法によ
る）が２５０℃にある高結晶性（結晶化度４５％）ポリ
エチレンテレフタレート２．０μｍ、溶融温度２４０℃
のものを用い、インキ透過性支持体として、マニラ麻１
００％からなる天然繊維紙を用いたインキ透過性支持体
を用い、２４５℃に加熱した熱棒１０ｍｍφをインキ透
過性支持体と熱可塑性フィルムの間に位置する様にし、
加熱した熱棒１０ｍｍφが熱可塑性フィルムの支持体側
表面を熱溶融するように接触させてインキ透過性支持体
と熱融着する様にした。加熱した熱棒は円形の熱可塑性
フィルムの支持体側表面を損傷、裂傷させず且つ熱可塑
性フィルムの支持体側表面への熱伝導が良好な鉄を用い
た。熱棒が熱可塑性フィルムの支持体側表面を熱溶融し
インキ透過性支持体と熱融着する時間を可能な限り短く
する為、熱棒の径は１０ｍｍφとし、熱可塑性フィルム
とインキ透過性支持体が接触する５０ｍｍ前に位置し、
熱可塑性フィルムとインキ透過性支持体が０．５ｍ／ｓ
ｅｃの速度で貼合わさるようにした。その後該熱可塑性
フィルムの上に熱融着防止層を０．１ｇ／ｍ2塗布し、
感熱孔版用印刷原紙を作成したが、熱可塑性フィルムの
熱溶融接着が不十分であり熱可塑性フィルムとインキ透
過性支持体との熱融着が行なえず良好な耐刷性をもった
感熱孔版用印刷原紙が作成できなかった。Comparative Example 3 Highly crystalline (45% crystallinity) polyethylene terephthalate having a crystal melting point (by DSC method) of 250 ° C. and a melting point of 240 ° C. ° C
Manila hemp 1 as ink-permeable support
Using an ink-permeable support made of 100% natural fiber paper, a hot rod 10 mmφ heated to 245 ° C. was positioned between the ink-permeable support and the thermoplastic film,
A heated hot rod of 10 mmφ was brought into contact with the support side surface of the thermoplastic film so as to be melted by heat so that the surface was thermally fused with the ink-permeable support. The heated hot rod used iron which did not damage or tear the surface of the circular thermoplastic film on the support side and had good heat conduction to the surface of the thermoplastic film on the support side. In order to minimize the time required for the hot rod to heat-melt the surface of the thermoplastic film on the support side and heat-bond it to the ink-permeable support, the diameter of the hot rod is 10 mmφ, and the thermoplastic film and the ink-permeable support Is located 50mm before contact,
0.5 m / s of thermoplastic film and ink-permeable support
It was made to stick at the speed of ec. Thereafter, 0.1 g / m 2 of a thermal fusion preventing layer is applied on the thermoplastic film,
A printing base paper for heat-sensitive stencils was prepared, but the heat-melt adhesion of the thermoplastic film was insufficient, and the heat-sealing of the thermoplastic film and the ink-permeable support could not be performed. Printing base paper could not be created.
【００２９】比較例４ 熱可塑性フィルムとして共重合ポリエステルを主体とし
たフィルムが実質的に非晶質な（結晶化度１．０％）厚
み１．８μｍ、溶融温度１８０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％からなる合成繊維を用い、インキ透過性支持体を
熱可塑性フィルムの支持体側表面と接触させる直前に内
部に加熱機構をもった２４５℃に加熱した熱ローラによ
り加熱し、熱可塑性フィルムの支持体側表面を加熱した
インキ透過性支持体により熱溶融させ熱融着させた。こ
の場合においても加熱したインキ透過性支持体が熱可塑
性フィルムの支持体側表面を熱溶融しインキ透過性支持
体と熱融着する時間を可能な限り短くする為に熱ローラ
から加熱したインキ透過性支持体が熱可塑性フィルムの
支持体側表面を熱溶融しインキ透過性支持体と熱融着す
る距離は０．０ｍｍとし、また、インキ透過性支持体へ
の熱伝導を必要十分に行なう為に熱ローラの径は５００
ｍｍφとした。熱可塑性フィルムとインキ透過性支持体
は０．５ｍ／ｓｅｃの速度で貼合わさるようにした。そ
の後該熱可塑性フィルムの上に熱融着防止層を０．１ｇ
／ｍ2塗布し、感熱孔版用印刷原紙を作成したが、熱可
塑性フィルムがインキ透過性支持体側の表面だけでなく
全体にわたり熱溶融し、熱可塑性フィルムとインキ透過
性支持体との熱融着が行なえず良好な感熱孔版用印刷原
紙が作成できなかった。COMPARATIVE EXAMPLE 4 As a thermoplastic film, a film mainly composed of a copolymerized polyester having a substantially amorphous (crystallinity: 1.0%) thickness of 1.8 μm and a melting temperature of 180 ° C. was used. Polyethylene terephthalate fiber 1 as a permeable support
Immediately before the ink-permeable support is brought into contact with the surface of the thermoplastic film on the support side using a synthetic fiber consisting of 00%, it is heated by a heat roller heated to 245 ° C. having a heating mechanism inside to support the thermoplastic film. The body side surface was heated and fused by a heated ink-permeable support. In this case, too, the heated ink permeable support heats the support-side surface of the thermoplastic film and heat-fuses with the ink permeable support in order to minimize the time required for the heat fusibility. The distance at which the support thermally melts the surface of the thermoplastic film on the support side and heat-fuses the surface with the ink-permeable support is 0.0 mm, and heat is applied to conduct heat to the ink-permeable support as necessary and sufficiently. Roller diameter is 500
mmφ. The thermoplastic film and the ink-permeable support were laminated at a speed of 0.5 m / sec. Thereafter, 0.1 g of a heat-sealing prevention layer was placed on the thermoplastic film.
/ M 2 was applied to prepare a printing stencil for thermosensitive stencil, but the thermoplastic film melted not only on the surface on the ink-permeable support side but also on the entire surface, and the thermal fusion of the thermoplastic film and the ink-permeable support was performed. And a good printing base paper for heat-sensitive stencils could not be produced.
【００３０】比較例５ 熱可塑性フィルムとして一般に市販されているポリエチ
レンテレフタレートフィルムの結晶融点（ＤＳＣ法によ
る）が２５０℃にある高結晶性（結晶化度４０％）ポリ
エチレンテレフタレート２．０μｍ、溶融温度２４０℃
のものを用い、インキ透過性支持体としてマニラ麻繊維
１００％の天然繊維紙を用い、インキ透過性支持体を熱
可塑性フィルムの支持体側表面と接触させる直前に内部
に加熱機構をもった２４５℃に加熱した熱ローラにより
加熱し、熱可塑性フィルムの支持体側の表面を加熱した
インキ透過性支持体により熱溶融させ熱融着させた。こ
の場合においても加熱したインキ透過性支持体が熱可塑
性フィルムの支持体側表面を熱溶融しインキ透過性支持
体と熱融着する時間を可能な限り短くする為に熱ローラ
から加熱したインキ透過性支持体が熱可塑性フィルムの
支持体側表面を熱溶融しインキ透過性支持体と熱融着す
る距離は０．０ｍｍとし、また、インキ透過性支持体へ
の熱伝導を必要十分に行なう為に熱ローラの径は５００
ｍｍφとした。熱可塑性フィルムとインキ透過性支持体
は０．５ｍ／ｓｅｃの速度で貼合わさるようにした。そ
の後該熱可塑性フィルム上に熱融着防止層を０．１ｇ／
ｍ2塗布し、感熱孔版用印刷原紙を作成したが、熱可塑
性フィルムの熱溶融が不十分であり熱可塑性フィルムと
インキ透過性支持体との熱融着が行なえず良好な感熱孔
版用印刷原紙が作成できなかった。Comparative Example 5 A polyethylene terephthalate film which is generally commercially available as a thermoplastic film has a crystalline melting point (by the DSC method) of 250 ° C., high crystalline (40% crystallinity) polyethylene terephthalate 2.0 μm, melting temperature 240 ° C
Using natural fiber paper of 100% Manila hemp fiber as an ink-permeable support, and having a heating mechanism inside at 245 ° C. immediately before the ink-permeable support is brought into contact with the surface of the thermoplastic film on the support side. Heating was performed by a heated heat roller, and the surface of the thermoplastic film on the support side was heated and fused by the heated ink-permeable support. In this case, too, the heated ink permeable support heats the support-side surface of the thermoplastic film and heat-fuses with the ink permeable support in order to minimize the time required for the heat fusibility. The distance at which the support thermally melts the surface of the thermoplastic film on the support side and heat-fuses the surface with the ink-permeable support is 0.0 mm, and heat is applied to conduct heat to the ink-permeable support as necessary and sufficiently. Roller diameter is 500
mmφ. The thermoplastic film and the ink-permeable support were laminated at a speed of 0.5 m / sec. Thereafter, a heat-fusion preventing layer was added on the thermoplastic film at 0.1 g /
m 2 was applied, was a heat-sensitive stencil printing base paper is insufficient hot melt thermoplastic film thermoplastic film and the ink permeable support with good thermal stencil printing sheet can not be performed thermal fusion of Could not be created.
【００３１】比較例６ 熱可塑性フィルムとしてポリエチレンテレフタレートフ
ィルムの結晶融点（ＤＳＣ法による）が２１０℃にある
高結晶性（結晶化度２５％）ポリエチレンテレフタレー
ト２．０μｍ、溶融温度１９０℃のものを用い、インキ
透過性支持体としてポリエチレンテレフタレート繊維１
００％の合成繊維紙を用い、インキ透過性支持体を熱可
塑性フィルムの支持体側表面と接触させる直前に内部に
加熱機構をもった２０５℃に加熱した熱ローラにより加
熱し、熱可塑性フィルムの支持体側表面を加熱したイン
キ透過性支持体により熱溶融させ熱融着させた。この場
合においても加熱したインキ透過性支持体が熱可塑性フ
ィルムの支持体側表面を熱溶融しインキ透過性支持体と
熱融着する時間を可能な限り短くする為に熱ローラから
加熱したインキ透過性支持体が熱可塑性フィルムの支持
体側表面を熱溶融しインキ透過性支持体と熱融着する距
離は０．０ｍｍとし、また、インキ透過性支持体への熱
伝導を必要十分に行なう為に熱ローラの径は４００ｍｍ
φとした。熱可塑性フィルムとインキ透過性支持体は
０．４ｍ／ｓｅｃの速度で貼合わさるようにした。その
後該熱可塑性フィルム上に熱融着防止層を０．１ｇ／ｍ
2塗布し、感熱孔版用印刷原紙を作成したが、熱可塑性
フィルムの熱溶融が過剰であり熱可塑性フィルムとイン
キ透過性支持体との熱融着が熱可塑性フィルムの支持体
側表面のみならず中間層内部まで熱溶融し穿孔感度の良
好な感熱孔版用印刷原紙が作成できなかった。Comparative Example 6 As a thermoplastic film, a polyethylene terephthalate film having a crystalline melting point (according to DSC method) of 210 ° C., a high crystalline (25% crystallinity) polyethylene terephthalate 2.0 μm, and a melting temperature of 190 ° C. was used. Polyethylene terephthalate fiber 1 as an ink-permeable support
Immediately before the ink-permeable support was brought into contact with the surface of the thermoplastic film on the support side using a 00% synthetic fiber paper, the support was heated by a heat roller heated to 205 ° C. having a heating mechanism inside, thereby supporting the thermoplastic film. The body side surface was heated and fused by a heated ink-permeable support. In this case, too, the heated ink permeable support heats the support-side surface of the thermoplastic film and heat-fuses with the ink permeable support in order to minimize the time required for the heat fusibility. The distance at which the support thermally melts the surface of the thermoplastic film on the support side and heat-fuses the surface with the ink-permeable support is 0.0 mm, and heat is applied to conduct heat to the ink-permeable support as necessary and sufficiently. Roller diameter is 400mm
φ. The thermoplastic film and the ink-permeable support were bonded at a speed of 0.4 m / sec. Thereafter, a heat-fusion preventing layer is formed on the thermoplastic film by 0.1 g / m 2.
(2) Coating was performed to prepare a heat-sensitive stencil printing base paper.However, the thermal fusion of the thermoplastic film was excessive, and the thermal fusion between the thermoplastic film and the ink-permeable support was not only at the support-side surface of the thermoplastic film but also at the middle. The inside of the layer was thermally melted, and a heat-sensitive stencil printing base paper having good perforation sensitivity could not be prepared.
【００３２】以上の様にして作成した感熱孔版用印刷原
紙を（株）リコー社製プリポートＶＴ−３５００にて製
版印刷を行なった。印刷特性を表１にまとめて示す。The stencil sheet for heat-sensitive stencil prepared as described above was subjected to stencil printing using Preport VT-3500 manufactured by Ricoh Co., Ltd. Table 1 summarizes the printing characteristics.
【００３３】[0033]
【表１】 [Table 1]
【００３４】[0034]
【発明の効果】本発明の感熱孔版用印刷原紙は、穿孔感
度及び耐刷性に優れた感熱孔版用印刷原紙として好適で
ある。The heat-sensitive stencil printing base paper of the present invention is suitable as a heat-sensitive stencil printing base paper excellent in perforation sensitivity and printing durability.
【図１】感熱孔版用印刷原紙に使用される熱可塑性フィ
ルムと、インキ透過性支持体とを、該フィルムの支持体
側表面を熱溶融し、該支持体と熱溶着させる感熱孔版用
印刷原紙の製造方法の模式図。FIG. 1 is a diagram of a heat-sensitive stencil printing base paper in which a thermoplastic film used for a heat-sensitive stencil printing base paper and an ink-permeable support are hot-melted on a support-side surface of the film and heat-welded to the support. FIG.
【図２】感熱孔版用印刷原紙に使用される熱可塑性フィ
ルムと、インキ透過性支持体とを、該フィルムの支持体
側表面に、加熱した該支持体を接触させて熱溶融し、該
支持体と熱融着させる感熱孔版用印刷原紙の製造方法の
模式図。FIG. 2 shows a thermoplastic film used for a heat-sensitive stencil printing base paper and an ink-permeable support, which are heated and melted by bringing the heated support into contact with the support-side surface of the film. FIG. 2 is a schematic view of a method for producing a heat-sensitive stencil printing base paper which is thermally fused with a printing plate.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平４−212891（ＪＰ，Ａ) 特開 昭62−288089（ＪＰ，Ａ) 特開 平１−182093（ＪＰ，Ａ) 特開 昭62−264998（ＪＰ，Ａ) 特開 昭59−16790（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) B41N 1/24 102 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-4-212891 (JP, A) JP-A-62-288089 (JP, A) JP-A-1-1822093 (JP, A) JP-A-62-28889 264998 (JP, A) JP-A-59-16790 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) B41N 1/24 102
Claims (3)
性フィルムと合成繊維を主体としたインキ透過性支持体
とを、接着剤等の層を介せず２層間を接着する感熱孔版
用印刷原紙の製造方法において、該熱可塑性フィルムの
支持体側表面を、該熱可塑性フィルムの溶融温度より０
〜５℃高い温度に加熱して熱溶融し、前記インキ透過性
支持体と熱融着させることを特徴とする、該熱可塑性フ
ィルムと該支持体との２層からなる感熱孔版用印刷原紙
の製造方法。1. A heat-sensitive stencil printing method in which a thermoplastic film used for heat-sensitive stencil printing base paper and an ink-permeable support mainly composed of synthetic fibers are bonded between two layers without a layer of an adhesive or the like. In the method for producing base paper, the surface of the thermoplastic film on the side of the support is set at a temperature lower than the melting temperature of the thermoplastic film by 0%.
A heat-melting by heating to a temperature higher by about 5 ° C., and heat-fusing the ink with the ink-permeable support; and a heat-sensitive stencil printing base paper comprising two layers of the thermoplastic film and the support. Production method.
性フィルムと合成繊維を主体としたインキ透過性支持体
とを、接着剤等の層を介せず２層間を接着する感熱孔版
用印刷原紙の製造方法において、該熱可塑性フィルムの
支持体側表面を、該熱可塑性フィルムの溶融温度より０
〜５℃高い温度に加熱したインキ透過性支持体を接触さ
せることにより熱溶融し、前記インキ透過性支持体と熱
融着させることを特徴とする、該熱可塑性フィルムと該
支持体との２層からなる感熱孔版用印刷原紙の製造方
法。2. A heat-sensitive stencil printing method in which a thermoplastic film used for a heat-sensitive stencil printing base paper and an ink-permeable support mainly composed of synthetic fibers are bonded between two layers without using an adhesive layer or the like. In the method for producing base paper, the surface of the thermoplastic film on the side of the support is set at a temperature lower than the melting temperature of the thermoplastic film by 0%.
(2) The thermoplastic film and the support are heat-melted by contacting the ink-permeable support heated to a temperature higher by ５5 ° C. and thermally fused to the ink-permeable support. A method for producing a heat-sensitive stencil printing base paper comprising a layer.
合成繊維を主体とした薄葉紙を用いることを特徴とする
請求項１又は２記載の感熱孔版用印刷原紙の製造方法。3. A process according to claim 1 or 2 method for producing a heat-sensitive stencil printing base paper, wherein the use of thin paper mainly containing synthetic fibers as ink permeable support thermally fusing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03149392A JP3171211B2 (en) | 1992-01-22 | 1992-01-22 | Method for producing heat-sensitive stencil printing base paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03149392A JP3171211B2 (en) | 1992-01-22 | 1992-01-22 | Method for producing heat-sensitive stencil printing base paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05193284A JPH05193284A (en) | 1993-08-03 |
| JP3171211B2 true JP3171211B2 (en) | 2001-05-28 |
Family
ID=12332781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP03149392A Expired - Fee Related JP3171211B2 (en) | 1992-01-22 | 1992-01-22 | Method for producing heat-sensitive stencil printing base paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3171211B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8065155B1 (en) | 1999-06-10 | 2011-11-22 | Gazdzinski Robert F | Adaptive advertising apparatus and methods |
-
1992
- 1992-01-22 JP JP03149392A patent/JP3171211B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05193284A (en) | 1993-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0740677A (en) | Stencil printing base paper and method for producing the same | |
| GB2240513A (en) | An apparatus for disposing of a used thermal stencil master sheet and a process for disposing of the same | |
| JP2527190B2 (en) | Method for manufacturing base paper for heat-sensitive stencil printing | |
| JP3171211B2 (en) | Method for producing heat-sensitive stencil printing base paper | |
| US5498464A (en) | Heat-sensitive stencil sheets and process | |
| US3587459A (en) | Thermographic stencil | |
| GB2176621A (en) | Heat-sensitive stencil paper | |
| JP3155061B2 (en) | Porous tissue paper for heat-sensitive stencil printing paper and method for producing the same | |
| JP2737001B2 (en) | Heat-sensitive perforated film and heat-sensitive stencil sheet using the same | |
| JPH0780364B2 (en) | Heat-sensitive stencil plate | |
| KR100579878B1 (en) | Thermal stencil printing base and manufacturing method | |
| JPS62156993A (en) | Ink ribbon for thermal fusion transfer | |
| JP3386936B2 (en) | Heat-sensitive stencil paper | |
| JP4186326B2 (en) | Heat-sensitive stencil paper and method for producing the same | |
| JP3418422B2 (en) | Thermal stencil printing method | |
| JPS62173296A (en) | Production of thermal stencil paper | |
| JPH0352354B2 (en) | ||
| JPH0493291A (en) | Thermal mimeograph paper and its plate-making method | |
| JPH03155990A (en) | Heat-sensitive stencil paper | |
| JPH0542782A (en) | Film for thermal stencil printing base paper | |
| JPS5941298A (en) | Combined heat-sensitive and pressure-sensitive stencil paper and production thereof | |
| JPH06101151A (en) | Sheet for printing | |
| JPH06340184A (en) | Melt transfer type ink image receiving sheet | |
| JPH0257035B2 (en) | ||
| JPH05177966A (en) | Base paper for heat-sensitive stencil printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |