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JP2023127033A - Manufacturing method of resistive element and resistive element obtained by the same - Google Patents

Manufacturing method of resistive element and resistive element obtained by the same Download PDF

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JP2023127033A
JP2023127033A JP2022030564A JP2022030564A JP2023127033A JP 2023127033 A JP2023127033 A JP 2023127033A JP 2022030564 A JP2022030564 A JP 2022030564A JP 2022030564 A JP2022030564 A JP 2022030564A JP 2023127033 A JP2023127033 A JP 2023127033A
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metal member
resistance element
rotary tool
manufacturing
metal
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JP7708386B2 (en
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亨 長岡
Toru Nagaoka
猛 京田
Takeshi Kyoda
昌宏 安東
Masahiro Ando
哲司 三輪
Tetsuji Miwa
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Fuji Tanshi Kogyo Kk
Osaka Research Institute of Industrial Science and Technology
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Fuji Tanshi Kogyo Kk
Osaka Research Institute of Industrial Science and Technology
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Abstract

To provide a manufacturing method of a resistive element capable of bonding a resistor and a terminal in a satisfactory state.SOLUTION: A first metal member 10 consisting of a copper-manganese-nickel alloy for general electric resistance and a second metal member 20 consisting of aluminum are prepared. The first metal member 10 and the second metal member 20 are adjacently disposed without a gap. In a state where a rotary tool 30 is inserted to the second metal member 20 in such a manner that an outer peripheral edge of the rotary tool 30 is substantially matched with a boundary 3 of the first metal member 10 and the second metal member 20, the rotary tool 30 is moved along the boundary 3, thereby providing a resistive element 1 in which the first metal member 10 and the second metal member 20 are bonded by frictional stir bonding, the first metal member 10 is defined as a resistive element main body 11, the second metal member 20 is defined as an electrode part 21 and the resistive element main body 11 and the electrode part 21 are bonded via an AL2Cu compound layer.SELECTED DRAWING: Figure 1

Description

本発明は、たとえばシャント抵抗器等に利用可能な抵抗素子の製造方法およびそれによって得られた抵抗素子に関するものである。
The present invention relates to a method for manufacturing a resistance element that can be used, for example, in a shunt resistor, and the resistance element obtained thereby.

近年、普及し始めている電気自動車やスマートメーターでは、数十A~数百Aという大電流が流れることがある。このような大電流は、電流を電圧に変換して測定するシャント抵抗によって高速で精度よくしかも安価に測定できる。したがって、電気自動車やスマートメーターなどの普及にともない、シャント抵抗器の需要が増えている。 Electric vehicles and smart meters, which have become popular in recent years, can draw large currents ranging from several tens of amperes to several hundred amperes. Such large currents can be measured quickly, accurately, and inexpensively by using a shunt resistor that converts the current into voltage. Therefore, with the spread of electric vehicles and smart meters, demand for shunt resistors is increasing.

このようなシャント抵抗器には、抵抗値の温度依存性が低いマンガニン(登録商標)が抵抗素子として用いられる。上記抵抗素子に銅等の金属からなる端子が溶接されて抵抗器が構成される。 Manganin (registered trademark), whose resistance value has low temperature dependence, is used as a resistance element in such a shunt resistor. A terminal made of metal such as copper is welded to the resistive element to form a resistor.

このような抵抗素子およびその製造方法に関する先行技術文献として、出願人は下記の特許文献1および2を把握している。
The applicant is aware of the following Patent Documents 1 and 2 as prior art documents regarding such a resistive element and its manufacturing method.

特開2007-220714号公報Japanese Patent Application Publication No. 2007-220714 特許第6671129号公報Patent No. 6671129

上記特許文献1は、抵抗器に関する技術を開示するものであり、以下の記載がある。
〔0017〕
上記構成において、前記抵抗体11は銅ニッケル、ニクロム、マンガニン等の金属板により構成されている。また前記金属端子12は、前記抵抗体11より電気伝導度が大きな金属、例えば金、銀、銅、アルミニウム等の金属により板状に構成され、そしてこの板状の金属端子12は抵抗体11の両端部を挟みこむようにU字状に折り曲げられて形成されている。そしてまた、この金属端子12は前記抵抗体11の少なくとも上面および下面に電気的に接続されるように構成している。
The above-mentioned Patent Document 1 discloses a technology related to a resistor, and includes the following description.
[0017]
In the above configuration, the resistor 11 is made of a metal plate made of copper nickel, nichrome, manganin, or the like. The metal terminal 12 is made of a metal having higher electrical conductivity than the resistor 11, such as gold, silver, copper, aluminum, etc., and has a plate shape. It is formed by being bent into a U-shape so as to sandwich both ends. Furthermore, the metal terminal 12 is configured to be electrically connected to at least the upper and lower surfaces of the resistor 11.

上記特許文献2は、シャント抵抗器の製造方法に関する技術を開示するものであり、以下の記載がある。
〔0002〕
長板状の抵抗体に電極となる長板状金属板を接合し、この接合した板材(溶接済み板材)から所定形状に切り抜いて抵抗器とするものが公知である。この場合に抵抗体は通常、Cu(銅)、Mn(マンガン)、Ni(ニッケル)等のマンガニン金属合金であり、端子板は通常銅板である。このような異種金属を溶接する手段として、電子ビームを用いる方法が公知である。この電子ビームを用いる方法は、真空中で電子ビームを接合部(抵抗体と端子板との突き合わせ部)に照射する必要があるため真空チャンバや真空装置が必要になり、溶接装置が大型化し高価になり、また溶接処理能率が悪いという問題が有った。
〔0003〕
そこで電子ビームに代えてレーザービームを用いて溶接することが提案されている。特許文献1には、長板状の抵抗体と端子板との突き合わせ端面に外側からレーザビームを照射して、抵抗体と端子板の接触部を溶融接合する方法が開示されている。この種の抵抗器において、いわゆるシャント抵抗器が近年広く使用されている。このシャント抵抗器は自動車などの電子機器などにおいて、電流を検出するために広く用いられるものであるが、この場合は抵抗値が小さく大電流に耐えられる(大定格電力)ものであることが望まれている。
The above-mentioned Patent Document 2 discloses a technique related to a method for manufacturing a shunt resistor, and includes the following description.
[0002]
2. Description of the Related Art A resistor is known in which a long plate-shaped metal plate serving as an electrode is bonded to a long plate-shaped resistor, and a predetermined shape is cut out from the bonded plate material (welded plate material). In this case, the resistor is usually a manganin metal alloy such as Cu (copper), Mn (manganese), Ni (nickel), etc., and the terminal plate is usually a copper plate. A method using an electron beam is known as a means for welding such dissimilar metals. This method of using an electron beam requires a vacuum chamber and vacuum equipment because it is necessary to irradiate the joint (the butt part between the resistor and the terminal plate) with the electron beam in a vacuum, making the welding equipment large and expensive. There was also the problem of poor welding efficiency.
[0003]
Therefore, it has been proposed to perform welding using a laser beam instead of an electron beam. Patent Document 1 discloses a method of irradiating a laser beam from the outside onto the abutting end surfaces of a long plate-shaped resistor and a terminal plate to melt and join the contact portion between the resistor and the terminal plate. Among this type of resistors, so-called shunt resistors have been widely used in recent years. This shunt resistor is widely used to detect current in electronic equipment such as automobiles, but in this case, it is desirable that it has a small resistance value and can withstand large currents (large power rating). It is rare.

上記特許文献1は、抵抗体11の両端部に金属端子12を挟みこむようにU字状に折り曲げられて形成した抵抗器が開示されている。上記抵抗体11としてマンガニン(登録商標)を用いることが記載され、上記金属端子12を構成する金属として銅やアルミニウムを用いることが記載されている。 The above Patent Document 1 discloses a resistor formed by bending a resistor 11 into a U-shape so as to sandwich a metal terminal 12 between both ends thereof. It is described that Manganin (registered trademark) is used as the resistor 11, and copper or aluminum is used as the metal that constitutes the metal terminal 12.

上記特許文献2は、マンガニン金属合金からなる抵抗体に銅板を溶接してシャント抵抗器を製造する方法が開示されている。上記の溶接を行う手段として、電子ビームを用いる方法やレーザービームを用いる方法について記載されている。 The above Patent Document 2 discloses a method of manufacturing a shunt resistor by welding a copper plate to a resistor made of a manganin metal alloy. As means for performing the above-mentioned welding, a method using an electron beam and a method using a laser beam are described.

抵抗器の構成としては、マンガニン(登録商標)の抵抗体に銅の金属端子を組み合わせるのが一般的である。マンガニン(登録商標)と銅を組み合わせた抵抗体には、常温で抵抗の温度計数が非常に小さい、抵抗値や抵抗温度計数の経年変化が少ない、対銅熱電力が小さい、圧延加工や細線加工が容易である、ろう付けやはんだ付けも容易である等のメリットがあるからである。一方、耐蝕性が悪い、僅かの加工が特性に影響する、常温付近の抵抗温度係数がリニアでない、加熱により表面に劣化層を生じやすい、等のデメリットが知られている。 The typical configuration of a resistor is to combine a Manganin (registered trademark) resistor with a copper metal terminal. A resistor that combines Manganin (registered trademark) and copper has a very small resistance temperature coefficient at room temperature, little change in resistance value or resistance temperature coefficient over time, low thermal power to copper, and can be processed by rolling or fine wire processing. This is because it has advantages such as easy brazing and soldering. On the other hand, it is known to have disadvantages such as poor corrosion resistance, slight processing affects its properties, temperature coefficient of resistance near room temperature is not linear, and a deteriorated layer is easily formed on the surface by heating.

また、上記のような抵抗器において、マンガニン(登録商標)と銅の接合は電子ビーム溶接が主であったが、電子ビーム溶接は真空環境が必須となり、レーザービーム溶接も実用化しているが、依然として設備が大型で高くなるという問題がある。 In addition, in the above resistors, Manganin (registered trademark) and copper were mainly joined by electron beam welding, but electron beam welding requires a vacuum environment, and laser beam welding has also been put into practical use. There is still a problem that the equipment is large and expensive.

上記特許文献1には、上記金属端子12としてアルミニウムを用いることが記載されているが、U字状に折り曲げた金属端子12で抵抗体11を挟みこんで機械的に接続するものである。このため金属端子12と抵抗体11の接合界面には、構造的な欠陥が避けられず、上述したような各種の抵抗体の特性が得られないおそれがある。 Patent Document 1 describes that aluminum is used as the metal terminal 12, and the resistor 11 is sandwiched between the metal terminals 12 bent into a U-shape for mechanical connection. Therefore, structural defects are inevitable at the bonding interface between the metal terminal 12 and the resistor 11, and there is a possibility that the characteristics of the various resistors described above cannot be obtained.

本発明は、上記課題を解決するため、つぎの目的をもってなされたものである。
抵抗体と金属端子が欠陥の少ない極めて良好な状態で接合できる抵抗素子の製造方法およびそれによって得られた抵抗素子を提供するものである。
The present invention has been made with the following objectives in order to solve the above problems.
The present invention provides a method for manufacturing a resistance element in which a resistor and a metal terminal can be bonded in an extremely good condition with few defects, and a resistance element obtained thereby.

請求項1記載の抵抗素子の製造方法は、上記目的を達成するため、下記の構成を採用した。
一般電気抵抗用の銅-マンガン-ニッケル合金からなる第1金属部材と、アルミニウムからなる第2金属部材とを準備し、
上記第1金属部材と上記第2金属部材を実質的に隙間ができないように隣接して配置し、
上記第1金属部材と上記第2金属部材の境界に対して回転工具の外周縁が略一致するよう、上記回転工具を上記第2金属部材に挿入した状態で、上記回転工具を上記境界に沿って移動させることにより、上記第1金属部材と上記第2金属部材を摩擦攪拌接合により接合し、
上記第1金属部材を抵抗素子本体とし、上記第2金属部材を電極部とし、上記抵抗素子本体と上記電極部が、ALCu化合物層を介して接合された抵抗素子を得る。
In order to achieve the above object, the method for manufacturing a resistance element according to claim 1 employs the following configuration.
Prepare a first metal member made of a copper-manganese-nickel alloy for general electrical resistance and a second metal member made of aluminum,
the first metal member and the second metal member are arranged adjacent to each other so that there is substantially no gap;
With the rotary tool inserted into the second metal member, the rotary tool is moved along the boundary so that the outer peripheral edge of the rotary tool substantially coincides with the boundary between the first metal member and the second metal member. joining the first metal member and the second metal member by friction stir welding,
A resistance element is obtained in which the first metal member is used as a resistance element body, the second metal member is used as an electrode part, and the resistance element main body and the electrode part are joined via an AL 2 Cu compound layer.

請求項2記載の抵抗素子の製造方法は、請求項1記載の構成に加え、下記の構成を採用した。
上記第1金属部材と上記第2金属部材の境界に沿う領域を少なくとも覆う補助金属材を配置し、
上記補助金属材の存在する領域で上記回転工具を上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う。
The method for manufacturing a resistance element according to the second aspect employs the following configuration in addition to the configuration according to the first aspect.
disposing an auxiliary metal material that covers at least a region along the boundary between the first metal member and the second metal member;
The friction stir welding is performed by inserting the rotary tool into the second metal member in a region where the auxiliary metal material is present.

請求項3記載の抵抗素子の製造方法は、請求項2記載の構成に加え、下記の構成を採用した。
隣接して配置された上記第1金属部材と上記第2金属部材の上側に上記補助金属材を配置し、
上記回転工具を上記補助金属材の上側から上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う。
The method for manufacturing a resistance element according to claim 3 employs the following configuration in addition to the configuration described in claim 2.
The auxiliary metal material is arranged above the first metal member and the second metal member that are arranged adjacent to each other,
The friction stir welding is performed by inserting the rotary tool into the second metal member from above the auxiliary metal member.

請求項4記載の抵抗素子の製造方法は、請求項2または3記載の構成に加え、下記の構成を採用した。
隣接して配置された上記第1金属部材と上記第2金属部材の下側に上記補助金属材を配置し、
上記回転工具を上記第2金属部材の上側から上記補助金属材に至るまで上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う。
The method for manufacturing a resistance element according to claim 4 employs the following configuration in addition to the configuration described in claim 2 or 3.
The auxiliary metal material is arranged below the first metal member and the second metal member that are arranged adjacent to each other,
The friction stir welding is performed by inserting the rotary tool into the second metal member from above the second metal member to the auxiliary metal member.

請求項5記載の抵抗素子の製造方法は、請求項2~4のいずれか一項に記載の構成に加え、下記の構成を採用した。
上記補助金属材を、第2金属部材と実質的に同じアルミニウムとする。
The method for manufacturing a resistance element according to claim 5 employs the following configuration in addition to the configuration described in any one of claims 2 to 4.
The auxiliary metal material is made of substantially the same aluminum as the second metal member.

請求項6記載の抵抗素子の製造方法は、請求項1~5のいずれか一項に記載の構成に加え、下記の構成を採用した。
上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である。
The method for manufacturing a resistance element according to claim 6 employs the following configuration in addition to the configuration described in any one of claims 1 to 5.
The copper-manganese-nickel alloy has Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more.

請求項7記載の抵抗素子は、上記目的を達成するため、下記の構成を採用した。
一般電気抵抗用の銅-マンガン-ニッケル合金からなる抵抗素子本体と、
上記抵抗素子本体に対して接合されたアルミニウムからなる電極部とを備え、
上記抵抗素子本体と上記電極部は、ALCu化合物層を介して接合されている。
In order to achieve the above object, the resistance element according to claim 7 employs the following configuration.
A resistance element body made of a copper-manganese-nickel alloy for general electrical resistance,
an electrode portion made of aluminum bonded to the resistive element body;
The resistive element body and the electrode portion are bonded to each other via an AL 2 Cu compound layer.

請求項8記載の抵抗素子は、請求項8記載の構成に加え、下記の構成を採用した。
上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である。
The resistance element according to claim 8 employs the following configuration in addition to the configuration described in claim 8.
The copper-manganese-nickel alloy has Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more.

請求項1記載の抵抗素子の製造方法は、まず、一般電気抵抗用の銅-マンガン-ニッケル合金からなる第1金属部材と、アルミニウムからなる第2金属部材とを準備する。ついで、上記第1金属部材と上記第2金属部材を実質的に隙間ができないように隣接して配置する。つぎに、上記第1金属部材と上記第2金属部材の境界に対して回転工具の外周縁が略一致するよう、上記回転工具を上記第2金属部材に挿入した状態で、上記回転工具を上記境界に沿って移動させることにより、上記第1金属部材と上記第2金属部材を摩擦攪拌接合により接合する。これにより、上記第1金属部材を抵抗素子本体とし、上記第2金属部材を電極部とする抵抗素子を得る。
上記摩擦攪拌接合により、上記第2金属部材に塑性流動が生じて第1金属部材との上記境界に密着し、上記第1金属部材と第2金属部材が接合される。このとき、上記第2金属部材だけに塑性流動が生じ、第1金属部材では塑性流動がほとんど起こらない。また、上記抵抗素子本体と上記電極部が、ALCu化合物層を介して接合されるため、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。つまり、ALCu化合物層が生成することで、アルミニウムと銅は金属的に結合がなされる。しかも、2種類の金属が混合することなく、ALCu化合物層が接合界面にフィルム状に形成され、接合部の電気抵抗値が安定する。さらに、ALCu化合物層の厚さを1ミクロン程度と薄いものにすれば、接合部が脆性的に破壊し難くなる。
In the method for manufacturing a resistance element according to the first aspect, first, a first metal member made of a copper-manganese-nickel alloy for general electrical resistance and a second metal member made of aluminum are prepared. Then, the first metal member and the second metal member are placed adjacent to each other so that there is substantially no gap between them. Next, the rotary tool is inserted into the second metal member so that the outer peripheral edge of the rotary tool substantially coincides with the boundary between the first metal member and the second metal member, and the rotary tool is inserted into the second metal member. By moving the metal member along the boundary, the first metal member and the second metal member are joined by friction stir welding. Thereby, a resistance element is obtained in which the first metal member serves as the resistance element body and the second metal member serves as the electrode portion.
Due to the friction stir welding, plastic flow occurs in the second metal member and the second metal member comes into close contact with the boundary with the first metal member, thereby joining the first metal member and the second metal member. At this time, plastic flow occurs only in the second metal member, and almost no plastic flow occurs in the first metal member. Further, since the resistive element main body and the electrode portion are bonded via the AL 2 Cu compound layer, an extremely good bonding state with few defects such as mixing of two types of metals and voids can be obtained. In other words, the formation of the AL 2 Cu compound layer causes aluminum and copper to be metallically bonded. Moreover, the AL 2 Cu compound layer is formed in the form of a film at the bonding interface without mixing the two types of metals, and the electrical resistance value of the bonded portion is stabilized. Furthermore, if the thickness of the AL 2 Cu compound layer is made as thin as about 1 micron, the bonded portion becomes difficult to break brittlely.

請求項2記載の抵抗素子の製造方法は、上記第1金属部材と上記第2金属部材の境界に沿う領域を少なくとも覆う補助金属材を配置する。そして、上記補助金属材の存在する領域で上記回転工具を上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う。
このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材が上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。また、上記第1金属部材と上記第2金属部材が薄板(たとえば2mm以下程度)であっても、上記第1金属部材と上記第2金属部材を上記補助金属材が保持することにより、良好な接合状態が得られる。
In the method for manufacturing a resistance element according to a second aspect of the present invention, an auxiliary metal material is arranged to cover at least a region along a boundary between the first metal member and the second metal member. Then, the friction stir welding is performed by inserting the rotary tool into the second metal member in the area where the auxiliary metal material is present.
By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material joins the plastic flow to compensate for the material, and as a result, the occurrence of voids can be significantly reduced. . Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids. Further, even if the first metal member and the second metal member are thin plates (for example, about 2 mm or less), the first metal member and the second metal member are held by the auxiliary metal member, thereby providing a good performance. A bonded state is obtained.

請求項3記載の抵抗素子の製造方法は、隣接して配置された上記第1金属部材と上記第2金属部材の上側に上記補助金属材を配置する。そして、上記回転工具を上記補助金属材の上側から上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う。
このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材が上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。また、上記第1金属部材と上記第2金属部材が薄板(たとえば2mm以下程度)であっても、上記第1金属部材と上記第2金属部材を上記補助金属材が保持することにより、良好な接合状態が得られる。
In the method for manufacturing a resistance element according to a third aspect of the present invention, the auxiliary metal material is arranged above the first metal member and the second metal member that are arranged adjacent to each other. Then, the friction stir welding is performed by inserting the rotary tool into the second metal member from above the auxiliary metal member.
By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material joins the plastic flow to compensate for the material, and as a result, the occurrence of voids can be significantly reduced. . Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids. Further, even if the first metal member and the second metal member are thin plates (for example, about 2 mm or less), the first metal member and the second metal member are held by the auxiliary metal member, thereby providing a good performance. A bonded state is obtained.

請求項4記載の抵抗素子の製造方法は、隣接して配置された上記第1金属部材と上記第2金属部材の下側に上記補助金属材を配置する。そして、上記回転工具を上記第2金属部材の上側から上記補助金属材に至るまで上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う。
このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材が上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。また、上記第1金属部材と上記第2金属部材が薄板(たとえば2mm以下程度)であっても、上記第1金属部材と上記第2金属部材を上記補助金属材が保持することにより、良好な接合状態が得られる。
In the method for manufacturing a resistance element according to a fourth aspect of the present invention, the auxiliary metal material is arranged below the first metal member and the second metal member that are arranged adjacent to each other. Then, the friction stir welding is performed by inserting the rotary tool into the second metal member from above the second metal member to the auxiliary metal material.
By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material joins the plastic flow to compensate for the material, and as a result, the occurrence of voids can be significantly reduced. . Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids. Further, even if the first metal member and the second metal member are thin plates (for example, about 2 mm or less), the first metal member and the second metal member are held by the auxiliary metal member, thereby providing a good performance. A bonded state is obtained.

請求項5記載の抵抗素子の製造方法は、上記補助金属材を、第2金属部材と実質的に同じアルミニウムとする。
このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材が上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。
In the method for manufacturing a resistance element according to a fifth aspect of the present invention, the auxiliary metal material is made of substantially the same aluminum as the second metal member.
By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material joins the plastic flow to compensate for the material, and as a result, the occurrence of voids can be significantly reduced. . Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids.

請求項6記載の抵抗素子の製造方法は、上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である
このため、市場に流通する銅-マンガン-ニッケル合金で上記抵抗素子を構成することができ、一定品質のものを安価に得ることができる。
The method for manufacturing a resistance element according to claim 6, wherein the copper-manganese-nickel alloy contains Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more. Therefore, the resistance element can be constructed from a copper-manganese-nickel alloy that is available on the market, and one of constant quality can be obtained at low cost.

請求項7記載の抵抗素子は、一般電気抵抗用の銅-マンガン-ニッケル合金からなる抵抗素子本体と、上記抵抗素子本体に対して接合されたアルミニウムからなる電極部とを備えている。そして、上記抵抗素子本体と上記電極部は、ALCu化合物層を介して接合されている。このため、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。つまり、ALCu化合物層が生成することで、アルミニウムと銅は金属的に結合がなされる。しかも、2種類の金属が混合することなく、ALCu化合物層が接合界面にフィルム状に形成され、接合部の電気抵抗値が安定する。さらに、ALCu化合物層の厚さを1ミクロン程度と薄いものにすれば、接合部が脆性的に破壊し難くなる。 A resistive element according to a seventh aspect of the present invention includes a resistive element body made of a copper-manganese-nickel alloy for general electrical resistance, and an electrode part made of aluminum joined to the resistive element body. The resistive element body and the electrode portion are bonded to each other via an AL 2 Cu compound layer. Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids. In other words, the formation of the AL 2 Cu compound layer causes aluminum and copper to be metallically bonded. Moreover, the AL 2 Cu compound layer is formed in the form of a film at the bonding interface without mixing the two types of metals, and the electrical resistance value of the bonded portion is stabilized. Furthermore, if the thickness of the AL 2 Cu compound layer is made as thin as about 1 micron, the bonded portion becomes difficult to break brittlely.

請求項8記載の抵抗素子は、上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である。
このため、市場に流通する銅-マンガン-ニッケル合金で上記抵抗素子を構成することができ、一定品質のものを安価に得ることができる。
In the resistor element according to claim 8, the copper-manganese-nickel alloy contains Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more.
Therefore, the resistor element can be constructed from a copper-manganese-nickel alloy that is available on the market, and a resistor element of constant quality can be obtained at a low cost.

本発明の抵抗素子の製造方法の第1実施形態を説明する図である。1 is a diagram illustrating a first embodiment of a method for manufacturing a resistance element of the present invention. FIG. 上記方法によって得られた抵抗素子を説明する図である。It is a figure explaining the resistance element obtained by the said method. 本発明の抵抗素子の製造方法の第2実施形態を説明する図である。It is a figure explaining 2nd Embodiment of the manufacturing method of the resistance element of this invention. 実施例の抵抗素子の断面顕微鏡写真を示す。A cross-sectional micrograph of a resistance element of an example is shown.

つぎに、本発明を実施するための形態を説明する。 Next, a mode for carrying out the present invention will be explained.

〔工程〕
図1は、本発明の抵抗素子の製造方法の第1実施形態を説明する図である。(A)は正面から見た状態、(B)は上から見た状態である。
[Process]
FIG. 1 is a diagram illustrating a first embodiment of the method for manufacturing a resistance element of the present invention. (A) shows the state seen from the front, and (B) shows the state seen from above.

この製造方法は、まず、一般電気抵抗用の銅-マンガン-ニッケル合金からなる第1金属部材10と、アルミニウムからなる第2金属部材20とを準備する。 In this manufacturing method, first, a first metal member 10 made of a copper-manganese-nickel alloy for general electrical resistance and a second metal member 20 made of aluminum are prepared.

上記第1金属部材10を構成する上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上のものを好ましく用いることができる。たとえば、JIS C 2532において一般電気抵抗用の銅マンガンGCM44として規定されるものや、マンガニン(登録商標)として流通するものを用いることができる。 The copper-manganese-nickel alloy constituting the first metal member 10 has Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and preferably Cu+Ni+Mn is 98% by weight or more. Can be used. For example, it is possible to use what is defined as copper manganese GCM44 for general electrical resistance in JIS C 2532, or what is distributed as Manganin (registered trademark).

上記第1金属部材10を構成する上記アルミニウムとしては、電気接続用の端子材料として用いられる各種のアルミニウム系の材料(合金を含む)を用いることができる。 As the aluminum constituting the first metal member 10, various aluminum-based materials (including alloys) used as terminal materials for electrical connections can be used.

図示した例では、上記第1金属部材10と上記第2金属部材20は、ともに四角形(正方形または長方形)を呈している。 In the illustrated example, the first metal member 10 and the second metal member 20 both have a quadrilateral shape (square or rectangle).

ついで、上記第1金属部材10と上記第2金属部材20を実質的に隙間ができないように隣接して配置する。図示した例では、それぞれ四角形の板材である第1金属部材10と第2金属部材20を、金床40上に載せ、互いの辺を突き合せて配置する。上記第1金属部材10と第2金属部材20と突き合せたところに境界3が形成される。 Next, the first metal member 10 and the second metal member 20 are placed adjacent to each other so that there is substantially no gap between them. In the illustrated example, the first metal member 10 and the second metal member 20, each of which is a rectangular plate, are placed on an anvil 40 and arranged with their sides butted against each other. A boundary 3 is formed where the first metal member 10 and the second metal member 20 abut against each other.

上記金床40は、第1金属部材10と第2金属部材20を突き合せた状態より、すこし大きな四角形である。この例では、上記金床40には、突き合せた第1金属部材10と第2金属部材20の境界3に沿うように隙間41が形成されている。 The anvil 40 has a rectangular shape that is slightly larger than the state in which the first metal member 10 and the second metal member 20 are butted together. In this example, a gap 41 is formed in the anvil 40 along the boundary 3 between the first metal member 10 and the second metal member 20 that are butted against each other.

つぎに、上記第1金属部材10と上記第2金属部材20の上記境界3に対して回転工具30の外周縁が略一致するよう、上記回転工具30を上記第2金属部材20に挿入した状態で、上記回転工具30を上記境界3に沿って移動させることにより、上記第1金属部材10と上記第2金属部材20を摩擦攪拌接合により接合する。 Next, the rotary tool 30 is inserted into the second metal member 20 such that the outer peripheral edge of the rotary tool 30 substantially coincides with the boundary 3 between the first metal member 10 and the second metal member 20. By moving the rotary tool 30 along the boundary 3, the first metal member 10 and the second metal member 20 are joined by friction stir welding.

図2は、上記第1金属部材10の両側に、一対の上記第2金属部材20を上述した摩擦攪拌接合により接合した状態である。(A)は平面図、(B)は正面から見た状態である。 FIG. 2 shows a state in which a pair of second metal members 20 are joined to both sides of the first metal member 10 by the above-described friction stir welding. (A) is a plan view, and (B) is a front view.

このようにして、上記第1金属部材10を抵抗素子本体11とし、上記第2金属部材20を電極部21とした抵抗素子1を得ることができる。 In this way, it is possible to obtain the resistance element 1 in which the first metal member 10 is the resistance element main body 11 and the second metal member 20 is the electrode part 21.

上述したように、上記抵抗素子本体11を構成する上記第1金属部材10は、一般電気抵抗用の銅-マンガン-ニッケル合金からなるものである。好ましくは、上記銅-マンガン-ニッケル合金として、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上であるものを用いることができる。上記電極部21を構成する第2金属部材20はアルミニウムである。そして、摩擦攪拌の作用により、上記第1金属部材10(銅-マンガン-ニッケル合金)中の銅と、上記第2金属部材20(アルミニウム)が反応して両者の界面に化合物層が形成される。これにより、上記抵抗素子本体11と上記電極部21は、ALCu化合物層を介して接合される。 As described above, the first metal member 10 constituting the resistance element main body 11 is made of a copper-manganese-nickel alloy for general electrical resistance. Preferably, the above-mentioned copper-manganese-nickel alloy may be one in which Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more. The second metal member 20 constituting the electrode section 21 is made of aluminum. Then, due to the action of friction stirring, the copper in the first metal member 10 (copper-manganese-nickel alloy) and the second metal member 20 (aluminum) react to form a compound layer at the interface between the two. . Thereby, the resistive element main body 11 and the electrode section 21 are joined via the AL 2 Cu compound layer.

〔第1実施形態の効果〕
上記第1実施形態の抵抗素子の製造方法は、まず、一般電気抵抗用の銅-マンガン-ニッケル合金からなる第1金属部材10と、アルミニウムからなる第2金属部材20とを準備する。ついで、上記第1金属部材10と上記第2金属部材20を実質的に隙間ができないように隣接して配置する。つぎに、上記第1金属部材10と上記第2金属部材20の境界3に対して回転工具30の外周縁が略一致するよう、上記回転工具30を上記第2金属部材20に挿入した状態で、上記回転工具30を上記境界3に沿って移動させることにより、上記第1金属部材10と上記第2金属部材20を摩擦攪拌接合により接合する。これにより、上記第1金属部材10を抵抗素子本体11とし、上記第2金属部材20を電極部21とする抵抗素子を得る。
上記摩擦攪拌接合により、上記第2金属部材20に塑性流動が生じて第1金属部材10との上記境界3に密着し、上記第1金属部材10と第2金属部材20が接合される。このとき、上記第2金属部材20だけに塑性流動が生じ、第1金属部材10では塑性流動がほとんど起こらない。また、上記抵抗素子本体11と上記電極部21が、ALCu化合物層を介して接合されるため、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。つまり、ALCu化合物層が生成することで、アルミニウムと銅は金属的に結合がなされる。しかも、2種類の金属が混合することなく、ALCu化合物層が接合界面にフィルム状に形成され、接合部の電気抵抗値が安定する。さらに、ALCu化合物層の厚さを1ミクロン程度と薄いものにすれば、接合部が脆性的に破壊し難くなる。
[Effects of the first embodiment]
In the method for manufacturing a resistance element according to the first embodiment, first, a first metal member 10 made of a copper-manganese-nickel alloy for general electrical resistance and a second metal member 20 made of aluminum are prepared. Next, the first metal member 10 and the second metal member 20 are placed adjacent to each other so that there is substantially no gap between them. Next, the rotary tool 30 is inserted into the second metal member 20 so that the outer peripheral edge of the rotary tool 30 substantially coincides with the boundary 3 between the first metal member 10 and the second metal member 20. By moving the rotary tool 30 along the boundary 3, the first metal member 10 and the second metal member 20 are joined by friction stir welding. Thereby, a resistance element is obtained in which the first metal member 10 is used as the resistance element body 11 and the second metal member 20 is used as the electrode part 21.
Through the friction stir welding, plastic flow occurs in the second metal member 20 and it comes into close contact with the boundary 3 with the first metal member 10, thereby joining the first metal member 10 and the second metal member 20. At this time, plastic flow occurs only in the second metal member 20, and almost no plastic flow occurs in the first metal member 10. Furthermore, since the resistive element main body 11 and the electrode portion 21 are bonded via the AL 2 Cu compound layer, an extremely good bonding state can be obtained with few defects such as mixing of two types of metals and voids. . In other words, the formation of the AL 2 Cu compound layer causes aluminum and copper to be metallically bonded. Moreover, the AL 2 Cu compound layer is formed in the form of a film at the bonding interface without mixing the two types of metals, and the electrical resistance value of the bonded portion is stabilized. Furthermore, if the thickness of the AL 2 Cu compound layer is made as thin as about 1 micron, the bonded portion becomes difficult to break brittlely.

上記第1実施形態の抵抗素子の製造方法は、上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である
このため、市場に流通する銅-マンガン-ニッケル合金で上記抵抗素子を構成することができ、一定品質のものを安価に得ることができる。
In the method for manufacturing the resistance element of the first embodiment, the copper-manganese-nickel alloy contains Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more. Therefore, the resistance element can be constructed from a copper-manganese-nickel alloy that is available on the market, and one of constant quality can be obtained at low cost.

上記第1実施形態の抵抗素子は、一般電気抵抗用の銅-マンガン-ニッケル合金からなる抵抗素子本体11と、上記抵抗素子本体11に対して接合されたアルミニウムからなる電極部21とを備えている。そして、上記抵抗素子本体11と上記電極部21は、ALCu化合物層を介して接合されている。このため、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。つまり、ALCu化合物層が生成することで、アルミニウムと銅は金属的に結合がなされる。しかも、2種類の金属が混合することなく、ALCu化合物層が接合界面にフィルム状に形成され、接合部の電気抵抗値が安定する。さらに、ALCu化合物層の厚さを1ミクロン程度と薄いものにすれば、接合部が脆性的に破壊し難くなる。 The resistance element of the first embodiment includes a resistance element body 11 made of a copper-manganese-nickel alloy for general electrical resistance, and an electrode part 21 made of aluminum bonded to the resistance element body 11. There is. The resistive element main body 11 and the electrode section 21 are bonded to each other via an AL 2 Cu compound layer. Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids. In other words, the formation of the AL 2 Cu compound layer causes aluminum and copper to be metallically bonded. Moreover, the AL 2 Cu compound layer is formed in the form of a film at the bonding interface without mixing the two types of metals, and the electrical resistance value of the bonded portion is stabilized. Furthermore, if the thickness of the AL 2 Cu compound layer is made as thin as about 1 micron, the bonded portion becomes difficult to break brittlely.

上記第1実施形態の抵抗素子は、上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である。
このため、市場に流通する銅-マンガン-ニッケル合金で上記抵抗素子を構成することができ、一定品質のものを安価に得ることができる。
In the resistance element of the first embodiment, the copper-manganese-nickel alloy has Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more.
Therefore, the resistor element can be constructed from a copper-manganese-nickel alloy that is available on the market, and a resistor element of constant quality can be obtained at a low cost.

図3は、本発明の抵抗素子の製造方法の第2実施形態を説明する図である。(A)は第1例、(B)は第2例、(C)は第3例である。 FIG. 3 is a diagram illustrating a second embodiment of the method for manufacturing a resistance element of the present invention. (A) is the first example, (B) is the second example, and (C) is the third example.

第2実施形態では、上記第1金属部材10と上記第2金属部材20の境界3に沿う領域を少なくとも覆う補助金属材50A/50Bを配置する。そして、上記補助金属材50A/50Bの存在する領域で上記回転工具30を上記第2金属部材20に挿入することにより上記摩擦攪拌接合を行う。 In the second embodiment, auxiliary metal members 50A/50B are arranged to cover at least a region along the boundary 3 between the first metal member 10 and the second metal member 20. Then, the friction stir welding is performed by inserting the rotary tool 30 into the second metal member 20 in the region where the auxiliary metal materials 50A/50B are present.

このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材が上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。 By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material joins the plastic flow to compensate for the material, and as a result, the occurrence of voids can be significantly reduced. . Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids.

第2実施形態では、上記補助金属材50A/50Bを、第2金属部材20と実質的に同じアルミニウムとすることができる。 In the second embodiment, the auxiliary metal material 50A/50B can be made of substantially the same aluminum as the second metal member 20.

このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材が上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。 By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material joins the plastic flow to compensate for the material, and as a result, the occurrence of voids can be significantly reduced. . Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids.

図3(A)は第2実施形態の第1例である。 FIG. 3(A) is a first example of the second embodiment.

この例では、隣接して配置された上記第1金属部材10と上記第2金属部材20の上側に補助金属材50Aを配置する。また、上記第1金属部材10と上記第2金属部材20の下側にも補助金属材50Bを配置する。上記下側の補助金属材50Bは、金床40Aに形成された溝42にはめ込まれている。そして、上記回転工具30を上記補助金属材50Aの上側から上記補助金属材50Bに至るまで上記第2金属部材20に挿入し、上記摩擦攪拌接合を行う。 In this example, the auxiliary metal member 50A is placed above the first metal member 10 and the second metal member 20 that are arranged adjacent to each other. Further, an auxiliary metal material 50B is also arranged below the first metal member 10 and the second metal member 20. The lower auxiliary metal material 50B is fitted into a groove 42 formed in the anvil 40A. Then, the rotary tool 30 is inserted into the second metal member 20 from above the auxiliary metal material 50A to the auxiliary metal material 50B, and the friction stir welding is performed.

図3(B)は第2実施形態の第2例である。 FIG. 3(B) is a second example of the second embodiment.

この例では、隣接して配置された上記第1金属部材10と上記第2金属部材20の上側に上記補助金属材50Aを配置し、上記回転工具30を上記補助金属材50Aの上側から上記第2金属部材20に挿入することにより上記摩擦攪拌接合を行う。 In this example, the auxiliary metal member 50A is placed above the first metal member 10 and the second metal member 20, which are arranged adjacent to each other, and the rotary tool 30 is moved from above the auxiliary metal member 50A to the second metal member 20. The above-mentioned friction stir welding is performed by inserting it into the two metal members 20.

図3(C)は第2実施形態の第3例である。 FIG. 3(C) is a third example of the second embodiment.

この例では、隣接して配置された上記第1金属部材10と上記第2金属部材20の下側に上記補助金属材50Bを配置し、上記回転工具30を上記第2金属部材20の上側から上記補助金属材50Bに至るまで上記第2金属部材20に挿入することにより上記摩擦攪拌接合を行う。 In this example, the auxiliary metal member 50B is arranged below the first metal member 10 and the second metal member 20 which are arranged adjacent to each other, and the rotary tool 30 is inserted from above the second metal member 20. The friction stir welding is performed by inserting the auxiliary metal member 50B into the second metal member 20.

〔第2実施形態の効果〕
第2実施形態の抵抗素子の製造方法は、上記第1金属部材10と上記第2金属部材20の境界3に沿う領域を少なくとも覆う補助金属材50A/50Bを配置する。そして、上記補助金属材50A/50Bの存在する領域で上記回転工具30を上記第2金属部材20に挿入することにより上記摩擦攪拌接合を行う。
このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材50A/50Bが上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。また、上記第1金属部材10と上記第2金属部材20が薄板(たとえば2mm以下程度)であっても、上記第1金属部材10と上記第2金属部材20を上記補助金属材50A/50Bが保持することにより、良好な接合状態が得られる。
[Effects of the second embodiment]
In the method for manufacturing a resistance element of the second embodiment, auxiliary metal materials 50A/50B are arranged to cover at least a region along the boundary 3 between the first metal member 10 and the second metal member 20. Then, the friction stir welding is performed by inserting the rotary tool 30 into the second metal member 20 in the region where the auxiliary metal materials 50A/50B are present.
By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material 50A/50B joins the plastic flow to compensate for the material, and as a result, the occurrence of voids is significantly reduced. be able to. Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids. Further, even if the first metal member 10 and the second metal member 20 are thin plates (for example, about 2 mm or less), the first metal member 10 and the second metal member 20 can be By holding it, a good bonding state can be obtained.

第2実施形態の抵抗素子の製造方法は、上記補助金属材50A/50Bを、第2金属部材20と実質的に同じアルミニウムとする。
このようにすることにより、激しい塑性流動で材料が飛散等したとしても、上記補助金属材50A/50Bが上記塑性流動に加わることにより材料が補われ、結果的にボイドの発生を大幅に減少させることができる。したがって、2種類の金属の混在やボイド等の欠陥が少ない極めて良好な接合状態を得ることができる。
In the method for manufacturing a resistance element of the second embodiment, the auxiliary metal material 50A/50B is made of substantially the same aluminum as the second metal member 20.
By doing this, even if the material is scattered due to intense plastic flow, the auxiliary metal material 50A/50B joins the plastic flow to compensate for the material, and as a result, the occurrence of voids is significantly reduced. be able to. Therefore, it is possible to obtain an extremely good bonding state with few defects such as coexistence of two types of metals and voids.

図4は、実施例の抵抗素子1の断面顕微鏡写真を示す。 FIG. 4 shows a cross-sectional micrograph of the resistance element 1 of the example.

上記実施例の抵抗素子1は、以下の条件により得た。
▽第1金属部材10:
一般電気抵抗用の銅-マンガン-ニッケル合金(Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上)(板厚3mm)
▽第2金属部材20:
アルミニウム(板厚3mm)
▽摩擦攪拌接合:
回転工具直径:6mm
回転数:2000rpm
移動速度:200mm/min
補助金属材:アルミニウム
Resistance element 1 of the above example was obtained under the following conditions.
▽First metal member 10:
Copper-manganese-nickel alloy for general electrical resistance (Mn: 10-13% by weight, Ni: 1-4% by weight, balance: Cu, Cu+Ni+Mn is 98% by weight or more) (plate thickness 3mm)
▽Second metal member 20:
Aluminum (plate thickness 3mm)
▽Friction stir welding:
Rotary tool diameter: 6mm
Rotation speed: 2000rpm
Traveling speed: 200mm/min
Auxiliary metal material: aluminum

2枚の写真は、拡大倍率が異なるものである。いずれの写真においても、画面の左側に見える相が銅-マンガン-ニッケル合金であり、画面の右側に見える相がアルミニウムである。 The two photographs have different magnifications. In both photographs, the phase visible on the left side of the screen is a copper-manganese-nickel alloy, and the phase visible on the right side of the screen is aluminum.

図からわかるように、上述した摩擦攪拌接合により上記第1金属部材10(抵抗素子本体11)と上記第2金属部材20(電極部21)を接合することで、上記抵抗素子1は、上記抵抗素子本体11と上記電極部21が、ALCu化合物層を介して接合されている。上記ALCu化合物層の厚みは1ミクロン程度の薄いものであった。 As can be seen from the figure, by joining the first metal member 10 (resistance element body 11) and the second metal member 20 (electrode part 21) by the above-described friction stir welding, the resistance element 1 The element body 11 and the electrode section 21 are bonded to each other via an AL 2 Cu compound layer. The thickness of the AL 2 Cu compound layer was as thin as about 1 micron.

〔変形例〕
以上は本発明の特に好ましい実施形態について説明したが、本発明は図示した実施形態に限定する趣旨ではなく、各種の態様に変形して実施することができ、本発明は各種の変形例を包含する趣旨である。
[Modified example]
Although particularly preferred embodiments of the present invention have been described above, the present invention is not intended to be limited to the illustrated embodiments, but can be modified and implemented in various ways, and the present invention includes various modified examples. The purpose is to

1:抵抗素子
3:境界
10:第1金属部材
11:抵抗素子本体
20:第2金属部材
21:電極部
30:回転工具
40:金床
41:隙間
42:溝
50A:補助金属材
50B:補助金属材
1: Resistance element 3: Boundary 10: First metal member 11: Resistance element body 20: Second metal member 21: Electrode section 30: Rotary tool 40: Anvil 41: Gap 42: Groove 50A: Auxiliary metal material 50B: Auxiliary metal material

Claims (8)

一般電気抵抗用の銅-マンガン-ニッケル合金からなる第1金属部材と、アルミニウムからなる第2金属部材とを準備し、
上記第1金属部材と上記第2金属部材を実質的に隙間ができないように隣接して配置し、
上記第1金属部材と上記第2金属部材の境界に対して回転工具の外周縁が略一致するよう、上記回転工具を上記第2金属部材に挿入した状態で、上記回転工具を上記境界に沿って移動させることにより、上記第1金属部材と上記第2金属部材を摩擦攪拌接合により接合し、
上記第1金属部材を抵抗素子本体とし、上記第2金属部材を電極部とし、上記抵抗素子本体と上記電極部が、ALCu化合物層を介して接合された抵抗素子を得る
ことを特徴とする抵抗素子の製造方法。
Prepare a first metal member made of a copper-manganese-nickel alloy for general electrical resistance and a second metal member made of aluminum,
the first metal member and the second metal member are arranged adjacent to each other so that there is substantially no gap;
With the rotary tool inserted into the second metal member, the rotary tool is moved along the boundary so that the outer peripheral edge of the rotary tool substantially coincides with the boundary between the first metal member and the second metal member. joining the first metal member and the second metal member by friction stir welding,
The first metal member serves as a resistor element body, the second metal member serves as an electrode portion, and the resistor element body and the electrode portion are bonded via an AL 2 Cu compound layer. A method for manufacturing a resistive element.
上記第1金属部材と上記第2金属部材の境界に沿う領域を少なくとも覆う補助金属材を配置し、
上記補助金属材の存在する領域で上記回転工具を上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う
請求項1記載の抵抗素子の製造方法。
disposing an auxiliary metal material that covers at least a region along the boundary between the first metal member and the second metal member;
The method for manufacturing a resistance element according to claim 1, wherein the friction stir welding is performed by inserting the rotary tool into the second metal member in a region where the auxiliary metal material is present.
隣接して配置された上記第1金属部材と上記第2金属部材の上側に上記補助金属材を配置し、
上記回転工具を上記補助金属材の上側から上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う
請求項2記載の抵抗素子の製造方法。
The auxiliary metal material is arranged above the first metal member and the second metal member that are arranged adjacent to each other,
The method for manufacturing a resistance element according to claim 2, wherein the friction stir welding is performed by inserting the rotary tool into the second metal member from above the auxiliary metal member.
隣接して配置された上記第1金属部材と上記第2金属部材の下側に上記補助金属材を配置し、
上記回転工具を上記第2金属部材の上側から上記補助金属材に至るまで上記第2金属部材に挿入することにより上記摩擦攪拌接合を行う
請求項2または3記載の抵抗素子の製造方法。
The auxiliary metal material is arranged below the first metal member and the second metal member that are arranged adjacent to each other,
4. The method of manufacturing a resistance element according to claim 2, wherein the friction stir welding is performed by inserting the rotary tool into the second metal member from above the second metal member to the auxiliary metal member.
上記補助金属材を、第2金属部材と実質的に同じアルミニウムとする
請求項2~4のいずれか一項に記載の抵抗素子の製造方法。
The method for manufacturing a resistance element according to claim 2, wherein the auxiliary metal material is substantially the same aluminum as the second metal member.
上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である
請求項1~5のいずれか一項に記載の抵抗素子の製造方法。
The copper-manganese-nickel alloy has Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more. A method of manufacturing the resistance element described above.
一般電気抵抗用の銅-マンガン-ニッケル合金からなる抵抗素子本体と、
上記抵抗素子本体に対して接合されたアルミニウムからなる電極部とを備え、
上記抵抗素子本体と上記電極部は、ALCu化合物層を介して接合されている
ことを特徴とする抵抗素子。
A resistance element body made of a copper-manganese-nickel alloy for general electrical resistance,
an electrode portion made of aluminum bonded to the resistive element body;
The resistance element, wherein the resistance element main body and the electrode portion are joined via an AL 2 Cu compound layer.
上記銅-マンガン-ニッケル合金は、Mn:10~13重量%、Ni:1~4重量%、残部:Cuであり、Cu+Ni+Mnが98重量%以上である
請求項7記載の抵抗素子。
The resistance element according to claim 7, wherein the copper-manganese-nickel alloy has Mn: 10 to 13% by weight, Ni: 1 to 4% by weight, and the balance is Cu, and Cu+Ni+Mn is 98% by weight or more.
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JP2002224860A (en) * 2001-02-06 2002-08-13 Hitachi Ltd Butt joining method of metal by friction stir welding
JP2013052425A (en) * 2011-09-05 2013-03-21 Tokushu Kinzoku Excel Co Ltd Method for production of low-resistance metal-fixed resistor
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