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JP2022058167A - Reticle pod with antistatic performance - Google Patents

Reticle pod with antistatic performance Download PDF

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JP2022058167A
JP2022058167A JP2021119004A JP2021119004A JP2022058167A JP 2022058167 A JP2022058167 A JP 2022058167A JP 2021119004 A JP2021119004 A JP 2021119004A JP 2021119004 A JP2021119004 A JP 2021119004A JP 2022058167 A JP2022058167 A JP 2022058167A
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reticle
base
recess
pod
depth
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JP7256845B2 (en
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銘乾 邱
Ming-Chien Chiu
家和 荘
Chia-Ho CHUANG
怡萱 李
Yi-Hsuan Lee
星閔 ▲温▼
Hsing-Min Wen
新民 薛
Hsin-Min Hsueh
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Gudeng Precision Industrial Co Ltd
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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    • H10P72/1906
    • GPHYSICS
    • G08SIGNALLING
    • G08CTRANSMISSION SYSTEMS FOR MEASURED VALUES, CONTROL OR SIMILAR SIGNALS
    • G08C17/00Arrangements for transmitting signals characterised by the use of a wireless electrical link
    • G08C17/02Arrangements for transmitting signals characterised by the use of a wireless electrical link using a radio link
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/66Containers specially adapted for masks, mask blanks or pellicles; Preparation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70691Handling of masks or workpieces
    • G03F7/70733Handling masks and workpieces, e.g. exchange of workpiece or mask, transport of workpiece or mask
    • G03F7/70741Handling masks outside exposure position, e.g. reticle libraries
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70691Handling of masks or workpieces
    • G03F7/70733Handling masks and workpieces, e.g. exchange of workpiece or mask, transport of workpiece or mask
    • G03F7/7075Handling workpieces outside exposure position, e.g. SMIF box
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/708Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/7085Detection arrangement, e.g. detectors of apparatus alignment possibly mounted on wafers, exposure dose, photo-cleaning flux, stray light, thermal load
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/708Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/70858Environment aspects, e.g. pressure of beam-path gas, temperature
    • G03F7/70866Environment aspects, e.g. pressure of beam-path gas, temperature of mask or workpiece
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00Casings, cabinets or drawers for electric apparatus
    • H05K5/0026Casings, cabinets or drawers for electric apparatus provided with connectors and printed circuit boards [PCB], e.g. automotive electronic control units
    • H05K5/0034Casings, cabinets or drawers for electric apparatus provided with connectors and printed circuit boards [PCB], e.g. automotive electronic control units having an overmolded housing covering the PCB
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00Casings, cabinets or drawers for electric apparatus
    • H05K5/02Details
    • H05K5/0208Interlock mechanisms; Means for avoiding unauthorised use or function, e.g. tamperproof
    • H10P72/06
    • H10P72/19
    • H10P72/1908
    • H10P72/1912
    • H10P72/1921
    • H10P72/1924
    • H10P72/1926
    • H10P72/1928

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  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)
  • Arrangements For Transmission Of Measured Signals (AREA)
  • Packaging Frangible Articles (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Casings For Electric Apparatus (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Debugging And Monitoring (AREA)

Abstract

Figure 2022058167000001

【課題】EUVプロセスにおいて、静電荷により生じるレチクル欠陥を考慮して、静電荷を帯びたレチクルを受け入れるよう帯電防止性能を備えたレチクルポッドを提供する。
【解決手段】帯電防止性能を備えたレチクルポッドが基部(212)および支持部材(2121)を有する。基部は、凹部(2124)が形成されるとともに底面によって構成された担持面(2122)を有する。支持部材は、基部の担持面を包囲した状態でレチクルを支持するようになっている。凹部は、担持面と底面との間に延びる深さによって規定されている。深さは、300μmから3400μmまでの範囲にあり、それにより担持面上の粒子に及ぼされる静電気力が弱められる。
【選択図】図5

Figure 2022058167000001

PROBLEM TO BE SOLVED: To provide a reticle pod having antistatic performance so as to accept a reticle carrying an electrostatic charge in consideration of a reticle defect caused by an electrostatic charge in an EUV process.
A reticle pod with antistatic performance has a base (212) and a support member (2121). The base has a support surface (2122) formed by a recess (2124) and a bottom surface. The support member is adapted to support the reticle while surrounding the supporting surface of the base. The recess is defined by the depth extending between the supporting surface and the bottom surface. Depths range from 300 μm to 3400 μm, thereby reducing the electrostatic force exerted on the particles on the supporting surface.
[Selection diagram] FIG. 5

Description

本開示内容(本発明)は、レチクルポッド、特に帯電防止性能を備えたレチクルポッドに関する。 The present disclosure (the present invention) relates to a reticle pod, particularly a reticle pod having antistatic performance.

従来型EUVプロセスに用いられるレチクルは、専用EUVレチクルポッドで保護されなければならない。図1は、EUVレチクルを受け入れるレチクルポッドを示しており、このレチクルポッドは、外側ポッド(100)および内側ポッド(110)を有するとともに外側ポッド(100)および内側ポッド(110)によって画定された内側層および外側層受け入れ空間を備えている。外側ポッド(100)は、蓋(101)および基部(102)を有し、蓋(101)と基部(102)は、内側ポッド(110)を受け入れる受け入れ空間を画定するよう互いに結合される。内側ポッド(110)は、蓋(111)および基部(112)を有し、蓋(111)と基部(112)は、レチクル(120)を受け入れるとともにレチクルに対して気密封止作用を提供する受け入れ空間を画定するために専用の手段によって互いに結合される。 The reticle used in the conventional EUV process must be protected by a dedicated EUV reticle pod. FIG. 1 shows a reticle pod that receives an EUV reticle, which has an outer pod (100) and an inner pod (110) and is defined by an outer pod (100) and an inner pod (110). It has a layer and an outer layer receiving space. The outer pod (100) has a lid (101) and a base (102), and the lid (101) and the base (102) are coupled to each other to define a receiving space for receiving the inner pod (110). The inner pod (110) has a lid (111) and a base (112), the lid (111) and the base (112) receiving the reticle (120) and providing an airtight seal to the reticle. They are joined together by dedicated means to demarcate the space.

レチクル(120)が内側ポッド(110)内に受け入れられると、レチクル(120)の縁部または底部は、基部(112)に設けられた支持部材(1121)によって支持され、その結果、レチクル(120)の下方に向いた表面は、レチクル(120)の上方に向いた担持面(1122)よりも僅かに高くなっている。以下、単に「担持面(1122)」と称する上方に向いた担持面(1122)は、支持部材(1121)によって包囲されていて、この担持面(1122)は、レチクル(120)のパターンゾーン(図示せず)の面積よりも広い面積のものである。担持面(1122)は、基部(112)の周囲のところに設けられかつ蓋(111)と接触関係をなすようになっている上方に向いた接触面(1123)とは異なっている。上方に向いた接触面(1123)は、リングの形状をしている。 When the reticle (120) is received in the inner pod (110), the edge or bottom of the reticle (120) is supported by a support member (1121) provided on the base (112), resulting in the reticle (120). ) Downward facing surface is slightly higher than the upward supporting surface (1122) of the reticle (120). The upwardly facing support surface (1122), which is simply referred to as the "support surface (1122)", is surrounded by the support member (1121), and the support surface (1122) is a pattern zone (120) of the reticle (120). The area is wider than the area (not shown). The carrier surface (1122) is different from the upward facing contact surface (1123) that is provided around the base (112) and is in contact with the lid (111). The upwardly facing contact surface (1123) is in the shape of a ring.

露光機器から取り出されたレチクル(120)は、残留電圧を呈しており、この残留電圧は、50Vを超える。残留電圧のあるレチクル(120)が内側ポッド(110)内に戻された場合、基部(112)に付着している粒子がレチクル(120)の底部に吸着される場合がある。粒子がレチクル(120)のパターンゾーンに吸着された場合、レチクル(120)は、露光プロセスの次の段階においてパターン欠陥を生じることになる。 The reticle (120) taken out from the exposure apparatus exhibits a residual voltage, which is more than 50V. When the reticle (120) with residual voltage is returned to the inner pod (110), particles adhering to the base (112) may be adsorbed to the bottom of the reticle (120). If the particles are adsorbed on the pattern zone of the reticle (120), the reticle (120) will cause pattern defects in the next stage of the exposure process.

図2は、基部(112)への帯電レチクル(120)の接近のステップを示している。基部(112)をアースし、かくしてこれを帯電させることはないが、粒子(P)は、上面(例えば、基部(112)の上述の担持面(1122))上に存在する。帯電または荷電レチクル(120)がある程度まで基部(112)に近づくと、レチクル(120)の負電荷によって生じた電場により、基部(112)の上面および粒子(P)は、正電荷を発生させる。レチクル(120)が基部(112)にかなり接近すると、静電界の強度は、粒子(P)を引き付けるのに十分であり、その結果、粒子(P)は、基部(112)の上面から逃げ、かくして、レチクル(120)の底部に吸着状態になる。明らかなこととして、基部(112)をアースすることによっては静電荷によって生じる全ての欠陥を解決することはできない。 FIG. 2 shows the steps of approaching the charged reticle (120) to the base (112). Although the base (112) is grounded and thus does not charge it, the particles (P) are present on the top surface (eg, the above-mentioned carrier surface (1122) of the base (112)). When the charged or charged reticle (120) approaches the base (112) to some extent, the electric field generated by the negative charge of the reticle (120) causes the top surface of the base (112) and the particles (P) to generate a positive charge. When the reticle (120) is fairly close to the base (112), the strength of the electrostatic field is sufficient to attract the particles (P) so that the particles (P) escape from the top surface of the base (112). Thus, it becomes adsorbed to the bottom of the reticle (120). Obviously, grounding the base (112) cannot solve all the defects caused by static charges.

静電荷により生じるレチクル欠陥を考慮して、静電荷を帯びたレチクルを受け入れるよう帯電防止性能を備えたレチクルポッドを提供することが必要である。 Considering the reticle defects caused by static charges, it is necessary to provide a reticle pod with antistatic performance to accept statically charged reticle.

図3は、粒子(P)が重力(Fw)および静電力(Fe)を受け入れている状態を示し、Fは、合力を示し、qは、電荷の量を示し、Eは、静電界を示し、mは、粒子の質量を示し、gは、万有引力定数を示し、Vは、電圧を示し、dは、レチクルの底部と基部の上面との間の隙間を示している。かくして、基部上の粒子(P)をレチクル底部に吸着させる際の要因としては、粒径(重量)、レチクル電荷量、およびレチクルの底部と基部の上面との間の距離が挙げられる。 FIG. 3 shows a state in which the particle (P) accepts gravity (Fw) and electrostatic force (Fe), where F indicates a resultant force, q indicates an amount of electric charge, and E indicates an electrostatic field. , M indicate the mass of the particle, g indicates the gravitational constant, V indicates the voltage, and d indicates the gap between the bottom of the reticle and the top of the base. Thus, factors for adsorbing the particles (P) on the base to the bottom of the reticle include particle size (weight), the amount of charge on the reticle, and the distance between the bottom of the reticle and the top surface of the base.

したがって、本発明の目的は、帯電防止性能を備えたレチクルポッドであって、レチクルポッドが担持面を備えた基部を有し、担持面が底面によって構成された凹部を有し、レチクルポッドが基部の担持面を包囲した状態でレチクルを支持するよう構成された複数の支持部材をさらに有し、凹部が担持面と底面との間に延びる深さによって規定され、深さが担持面に付着している粒子に及ぼされる静電気力を弱めるよう300μmから3400μmまでの範囲にあることを特徴とするレチクルポッドを提供することにある。 Therefore, an object of the present invention is a reticle pod having antistatic performance, in which the reticle pod has a base having a supporting surface, the supporting surface has a recess formed by a bottom surface, and the reticle pod is a base. It further has a plurality of support members configured to support the reticle while surrounding the support surface of the reticle, the recess is defined by the depth extending between the support surface and the bottom surface, and the depth adheres to the support surface. It is an object of the present invention to provide a reticle pod characterized by being in the range of 300 μm to 3400 μm so as to weaken the electrostatic force exerted on the particles.

特定の実施形態では、基部は、担持面を包囲した状態で気密封止された受け入れ空間を形成するよう蓋と接触関係をなすようになっている上方に向いた接触面をさらに有する。 In certain embodiments, the base further has an upward facing contact surface that is in contact with the lid to form an airtightly sealed receiving space surrounding the carrier surface.

特定の実施形態では、凹部は、レチクルのパターンゾーンの面積に等しいまたはこれよりも広い面積のゾーンを包囲したリング状の縁部を有する。 In certain embodiments, the recess has a ring-shaped edge that surrounds a zone with an area equal to or greater than the area of the pattern zone of the reticle.

特定の実施形態では、凹部は、レチクルのパターンゾーンを覆うのに十分なゾーンを包囲するリング状の縁部を有する。 In certain embodiments, the recess has a ring-shaped edge that surrounds the zone sufficient to cover the pattern zone of the reticle.

特定の実施形態では、凹部は、長さ138mm、幅が110mmの長方形の縁部を有する。 In certain embodiments, the recess has a rectangular edge that is 138 mm long and 110 mm wide.

特定の実施形態では、レチクルの残留電圧は、50Vを超え、深さは、少なくとも、400μmを超える。 In certain embodiments, the residual voltage of the reticle is greater than 50 V and the depth is greater than at least 400 μm.

本発明の別の目的は、帯電防止性能を備えたレチクルポッドであって、レチクルポッドが上面を備えた基部を有し、上面が機械的加工によって形成された偏向面であり、レチクルポッドが上面を包囲した状態でレチクルを支持するよう構成された複数の支持部材をさらに有し、レチクルの下方に向いた表面と基部の上面との間には、基部の上面に付着した粒子に及ぼされる静電気力を弱めるよう少なくとも300μmを超える隙間が形成されていることを特徴とするレチクルポッドを提供することにある。 Another object of the present invention is a reticle pod with antistatic performance, where the reticle pod has a base with an upper surface, the upper surface is a deflection surface formed by mechanical processing, and the reticle pod is the upper surface. It further has a plurality of support members configured to support the reticle while surrounding the reticle, and static electricity exerted on the particles adhering to the upper surface of the base between the downwardly facing surface of the reticle and the upper surface of the base. It is an object of the present invention to provide a reticle pod characterized in that a gap of at least 300 μm is formed so as to weaken the force.

特定の実施形態では、基部は、上面を包囲するとともに気密封止された受け入れ空間を形成するよう蓋と接触関係をなすようになっている上方に向いた接触面をさらに有する。 In certain embodiments, the base further has an upward facing contact surface that surrounds the top surface and is in contact with the lid to form an airtightly sealed receiving space.

特定の実施形態では、上面の面積は、レチクルのパターンゾーンの面積に等しくまたはこれよりも広い。 In certain embodiments, the area of the top surface is equal to or greater than the area of the pattern zone of the reticle.

特定の実施形態では、上面のゾーンは、レチクルのパターンゾーンを覆うのに十分である。 In certain embodiments, the top surface zone is sufficient to cover the pattern zone of the reticle.

特定の実施形態では、上面は、長さ138mm、幅が110mmの長方形の縁部を有する。 In certain embodiments, the top surface has a rectangular edge that is 138 mm long and 110 mm wide.

特定の実施形態では、レチクルの残留電圧は、50Vを超え、隙間は、少なくとも、400μmを超える。 In certain embodiments, the residual voltage of the reticle exceeds 50 V and the clearance exceeds at least 400 μm.

本発明のさらに別の目的は、レチクルポッドの基部に利用されるレチクルポッドの加工方法であって、基部が担持面および複数の支持部材を有し、複数の支持部材が基部の担持面を包囲した状態でレチクルを支持するよう構成されていることを構成要件とする方法を提供することにある。本方法は、担持面を機械的に加工して担持面上に凹部を形成するステップを含み、凹部が底面によって構成され、本方法は、凹部を加工して凹部をレチクルの残留電圧に応じた深さによって規定するステップをさらに含み、深さが少なくとも300μmを超える。 Yet another object of the present invention is a method for processing a reticle pod used for a base of a reticle pod, in which the base has a support surface and a plurality of support members, and the plurality of support members surround the support surface of the base. The purpose is to provide a method of making it a constituent requirement that the reticle is configured to support the reticle in a state of being. The method comprises the step of mechanically processing the carrier surface to form a recess on the carrier surface, the recess being composed of a bottom surface, the method of processing the recess and making the recess according to the residual voltage of the reticle. Further including steps defined by depth, the depth exceeds at least 300 μm.

特定の実施形態では、残留電圧は、50Vを超え、深さは、少なくとも、400μmを超える。 In certain embodiments, the residual voltage is greater than 50 V and the depth is greater than at least 400 μm.

特定の実施形態では、残留電圧は、100Vを超え、深さは、少なくとも、400μmを超える。 In certain embodiments, the residual voltage is greater than 100 V and the depth is greater than at least 400 μm.

特定の実施形態では、残留電圧は、200Vを超え、深さは、少なくとも、800μmを超える。 In certain embodiments, the residual voltage is greater than 200 V and the depth is greater than at least 800 μm.

特定の実施形態では、残留電圧は、400Vを超え、深さは、少なくとも、1600μmを超える。 In certain embodiments, the residual voltage is greater than 400 V and the depth is greater than at least 1600 μm.

本開示内容は、添付の図面に示されており、このかかる開示内容について以下に説明する。非限定的かつ非網羅的な実施形態が添付の図面に関して以下に提供されている。添付の図面は、技術的特徴および原理を説明するようになっているが、必ずしも縮尺通りには描かれていない。 The contents of this disclosure are shown in the accompanying drawings, which will be described below. Non-limiting and non-exhaustive embodiments are provided below with respect to the accompanying drawings. The accompanying drawings are intended to explain the technical features and principles, but are not necessarily drawn to scale.

従来型レチクルポッドの分解組立図(先行技術)である。It is an exploded view (prior art) of the conventional reticle pod. レチクルポッドの基部への荷電粒子の接近のステップを示す図(先行技術)である。It is a figure (prior art) which shows the step of approaching a charged particle to the base of a reticle pod. 静電力および重力を受けている粒子を示す図(先行技術)である。It is a figure (prior art) which shows the particle under electrostatic force and gravity. 本発明のレチクルポッドの分解組立図である。It is an exploded view of the reticle pod of this invention. レチクルポッドの基部の斜視図である。It is a perspective view of the base of a reticle pod. 図5に基づく断面図である。It is sectional drawing based on FIG. 図5のレチクルポッドの基部の平面図である。FIG. 5 is a plan view of the base of the reticle pod of FIG. 図5のレチクルポッドの基部の底面図である。It is a bottom view of the base of the reticle pod of FIG. レチクルパターンゾーンと凹部カバーゾーンとの関係を示す図である。It is a figure which shows the relationship between the reticle pattern zone and the concave cover zone. レチクルと凹部底面との間の隙間を示す図である。It is a figure which shows the gap between a reticle and the bottom surface of a recess. 本発明の別の実施形態に係るレチクルポッドの基部の斜視図である。It is a perspective view of the base of the reticle pod which concerns on another embodiment of this invention. 粒子に及ぼされる正味の力に対するレチクルの残留電圧、粒径および隙間の影響を示す図である。It is a figure which shows the influence of the residual voltage, the particle size and the gap of a reticle on the net force exerted on a particle. 粒子に及ぼされる正味の力に対するレチクルの異なる残留電圧、異なる粒径および異なる隙間の影響を示す図である。It is a figure which shows the influence of a different residual voltage, a different particle size and a different gap of a reticle on a net force exerted on a particle. 粒子に及ぼされる正味の力に対するレチクルの異なる残留電圧、異なる粒径および異なる隙間の影響を示す図である。It is a figure which shows the influence of a different residual voltage, a different particle size and a different gap of a reticle on a net force exerted on a particle. 粒子に及ぼされる正味の力に対するレチクルの異なる残留電圧、異なる粒径および異なる隙間の影響を示す図である。It is a figure which shows the influence of a different residual voltage, a different particle size and a different gap of a reticle on a net force exerted on a particle.

本開示内容は、添付の図面を参照して以下に説明されるとともに特定の実施形態によって例示される。しかしながら、本開示内容によってクレーム請求されている内容を互いに異なる形態で具体化でき、かくして、その範囲は、以下に開示する例示の実施例および実施形態には限定されない。例示の実施例および実施形態は、説明目的に役立つに過ぎない。本開示内容は、クレーム請求されている内容に合理的に広い範囲をもたらす。 The present disclosure is described below with reference to the accompanying drawings and is exemplified by specific embodiments. However, the content claimed by the present disclosure can embody the content claimed in different forms from each other, and thus the scope is not limited to the exemplary examples and embodiments disclosed below. Illustrated examples and embodiments serve only explanatory purposes. The content of this disclosure provides a reasonably wide range of content claimed.

本明細書で用いられる「一実施例では」という表現は、必ずしも、同一の実施形態を指していない。本明細書で用いられている「別の実施形態では」という表現は、必ずしも互いに異なる特定の実施形態を指してはいない。クレーム請求されている内容は、全体または一部が例示の実施例および実施形態の組み合わせの範囲に属するものと見なされるべきである。 The expression "in one embodiment" as used herein does not necessarily refer to the same embodiment. The phrase "in another embodiment" as used herein does not necessarily refer to specific embodiments that differ from each other. The claimed content, in whole or in part, should be considered to belong to the scope of the combination of exemplary embodiments and embodiments.

図4は、本発明のレチクルポッドの分解組立図である。図1と同様、図4は、外側ポッド(200)および内側ポッド(210)を示している。外側ポッド(200)は、蓋(201)および基部(202)を有する。蓋(201)と基部(202)は、一緒になって、内側ポッド(210)を受け入れる受け入れ空間を画定する。内側ポッド(210)は、蓋(211)および基部(212)をさらに有し、蓋(211)と基部(212)は一緒になって、レチクル(220)を受け入れる受け入れ空間を画定する。本開示内容における本発明の技術的特徴は、基部(212)にある。外側ポッド(200)および内側ポッド(210)の蓋(211)の他の細部は、以下の説明では省かれている。 FIG. 4 is an exploded view of the reticle pod of the present invention. Similar to FIG. 1, FIG. 4 shows an outer pod (200) and an inner pod (210). The outer pod (200) has a lid (201) and a base (202). The lid (201) and base (202) together define a receiving space for receiving the inner pod (210). The inner pod (210) further has a lid (211) and a base (212), the lid (211) and the base (212) together defining a receiving space for receiving the reticle (220). The technical feature of the present invention in the present disclosure is in the base (212). Other details of the outer pod (200) and the inner pod (210) lid (211) are omitted in the following description.

基部(212)は、複数の支持部材(2121)、上方に向いた担持面(以下、担持面(2122)と呼ばれる)および上方に向いた接触面(2123)を有する。支持部材(2121)は、担持面(2122)と上方に向いた(2123)との間に設けられていて担持面(2122)を包囲している。支持部材(2121)は、レチクル(220)の底部または側縁部を支持するために互いに異なる形状を取るよう構成されている。例えば、この実施形態では、各支持部材(2121)は、レチクル(220)の横方向変位を制限するための2つの制限ポストおよびレチクルの下方に向いた表面に接触し、かくしてレチクル(220)を担持面(2122)の上方に持ち上げる支持ピンを有する。レチクル(220)の下方に向いた表面と担持面(2122)との間の隙間は、支持ピンの高さで決まる。基本的には、担持面(2122)は平坦であるが、実際には、担持面(2122)の少なくとも一部は、機械加工によって形成されるが裸眼でめったに識別できない偏向状態の表面である。担持面(2122)は、これに凹部(2124)を形成するよう機械的に加工されている。凹部(2124)は、実質的に中心が担持面(2122)のところに配置されるだけでなく、担持面(2122)によって包囲されている。レチクル(220)が支持部材(2121)上に位置したとき、レチクル(220)のパターンゾーンは、位置が凹部(2124)に一致する。 The base (212) has a plurality of support members (2121), an upwardly facing support surface (hereinafter referred to as a support surface (2122)) and an upwardly facing contact surface (2123). The support member (2121) is provided between the support surface (2122) and the upward facing (2123) and surrounds the support surface (2122). The support members (2121) are configured to take different shapes to support the bottom or side edges of the reticle (220). For example, in this embodiment, each support member (2121) is in contact with two limiting posts for limiting lateral displacement of the reticle (220) and a downward facing surface of the reticle, thus the reticle (220). It has a support pin that lifts above the carrier surface (2122). The gap between the downward facing surface of the reticle (220) and the supporting surface (2122) is determined by the height of the support pin. Basically, the carrier surface (2122) is flat, but in practice at least a portion of the carrier surface (2122) is a surface that is machined but rarely discernible to the naked eye. The carrier surface (2122) is mechanically machined to form a recess (2124) in it. The recess (2124) is not only substantially centered at the carrier surface (2122), but is surrounded by the carrier surface (2122). When the reticle (220) is located on the support member (2121), the pattern zone of the reticle (220) coincides with the recess (2124).

図5は、基部(212)の微細な構造的特徴を示している。図6は、図5の破線に沿って取った断面図である。図示のように、溝(参照符号によっては示されていない)が基部(212)の周囲のところで担持面(2122)と上方に向いた接触面(2123)との間に形成されており、この溝は、蓋(211)と基部(212)の接合部中に入り込んだ粒子を捕捉するようになっている。図6は、担持面(2122)が上方に向いた接触面(2123)よりも高く、それにより構造的バリヤを形成し、かくして粒子が担持面(2122)上に落下する恐れを軽減し、それにより内側ポッド(210)の清浄さを保証していることを明示している。変形実施形態では、担持面(2122)および上方に向いた接触面(2123)は、同一高さのものであり、あるいは、担持面(2122)は、これよりも低く、溝はまた、完全に満たされるのが良い。凹部(2124)は、底面(600)および壁面(601)によって画定され、かくして、深さ(D)によって規定されている。深さ(D)は、加工深さであり、すなわち、図6に示されているように、担持面(2122)と凹部底面(600)との間の垂直距離である。凹部(2124)もまた機械的加工によって形成されるので、底面(600)もまた偏向される場合がある。 FIG. 5 shows the fine structural features of the base (212). FIG. 6 is a cross-sectional view taken along the broken line of FIG. As shown, a groove (not shown by reference numeral) is formed around the base (212) between the carrier surface (2122) and the upwardly facing contact surface (2123). The grooves are adapted to capture particles that have entered the junction between the lid (211) and the base (212). FIG. 6 shows that the carrier surface (2122) is higher than the upward contact surface (2123), thereby forming a structural barrier, thus reducing the risk of particles falling onto the carrier surface (2122). Clearly guarantees the cleanliness of the inner pod (210). In the modified embodiment, the carrier surface (2122) and the upward contact surface (2123) are flush with each other, or the carrier surface (2122) is lower and the groove is also completely. Good to be satisfied. The recess (2124) is defined by a bottom surface (600) and a wall surface (601) and thus is defined by a depth (D). The depth (D) is the machining depth, that is, the vertical distance between the carrier surface (2122) and the bottom surface of the recess (600), as shown in FIG. Since the recesses (2124) are also formed by mechanical machining, the bottom surface (600) may also be deflected.

図7は、図5の基部(212)の平面図である。図示のように、凹部(2124)の開口部(担持面の内側縁部によって画定されている)および底面(600)は、長方形であり、この開口部と底面(600)の両方は、実質的に同一の面積を有する。一実施形態では、長方形は、各々、長さ138mm、幅110mmのものである。凹部(2124)は、実質的に中心が担持面(2122)のところに配置され、この凹部は、担持面のどの側部にも接触していない。図8は、図5の基部(212)の底面図であり、位置決め構造体(800)が基部(212)の底部に設けられた状態で基部(212)を加工機内に位置決めするようになっていることを示している。 FIG. 7 is a plan view of the base (212) of FIG. As shown, the opening (defined by the inner edge of the supporting surface) and bottom surface (600) of the recess (2124) are rectangular, and both the opening and the bottom surface (600) are substantially. Have the same area. In one embodiment, the rectangles are 138 mm long and 110 mm wide, respectively. The recess (2124) is substantially centered at the carrier surface (2122), and the recess is not in contact with any side of the carrier surface. FIG. 8 is a bottom view of the base portion (212) of FIG. 5, in which the base portion (212) is positioned in the processing machine with the positioning structure (800) provided at the bottom portion of the base portion (212). It shows that there is.

図9Aは、レチクル(900)のレチクルパターン領域(901、包囲実線によって境界づけられる)と基部凹部領域(902)との関係を示す平面図である。図中の破線が凹部開口部のリング状縁部を示しており、この破線は、凹部カバー領域(902)が少なくともレチクルパターン領域(901)よりも広いことを明示している。この構成により、レチクルパターンゾーンのあらゆる部分が凹部の底面に向くようになっている。図9Bは、レチクルパターン領域(901)の下方に向いた表面と凹部の底面(903)との間に設けられた隙間(G)を示す側面図である。支持されるべきレチクルの高さに応じて、レチクルの底面(904)の高さは、基部の担持面の高さにほぼ等しいのが良く、レチクルの底面(904)と凹部の底面(600)との間の隙間が凹部の深さ(図6に示された深さD)に等しくなっている。一実施形態では、凹部の深さ(D)は、300μmから3400μmまでの範囲にあり、あるいは3400μmから3750μmまでの範囲にある。かくして、隙間(G)は、少なくとも300μmよりも大きい。したがって、静電荷を帯びたレチクルが基部上に置かれると、凹部深さ(D)または隙間(G)を調節することによって、基部の担持面上の粒子に及ぼされる静電気力を効果的に弱めることができ、かくして粒子がレチクルの下方に向いた表面に引き付けられる恐れを軽減することができる。 FIG. 9A is a plan view showing the relationship between the reticle pattern region (901, bounded by the surrounding solid line) and the base recessed region (902) of the reticle (900). The dashed line in the figure indicates the ring-shaped edge of the recess opening, which indicates that the recess cover area (902) is at least wider than the reticle pattern area (901). With this configuration, every part of the reticle pattern zone faces the bottom of the recess. FIG. 9B is a side view showing a gap (G) provided between the downwardly facing surface of the reticle pattern region (901) and the bottom surface (903) of the recess. Depending on the height of the reticle to be supported, the height of the bottom surface of the reticle (904) should be approximately equal to the height of the supporting surface of the base, the bottom surface of the reticle (904) and the bottom surface of the recess (600). The gap between the and the recess is equal to the depth of the recess (depth D shown in FIG. 6). In one embodiment, the recess depth (D) ranges from 300 μm to 3400 μm, or from 3400 μm to 3750 μm. Thus, the gap (G) is at least greater than 300 μm. Therefore, when a statically charged reticle is placed on the base, it effectively weakens the electrostatic force exerted on the particles on the supporting surface of the base by adjusting the recess depth (D) or gap (G). It can thus reduce the risk of particles being attracted to the downward facing surface of the reticle.

図10は、本発明の別の実施形態に係るレチクルポッドの基部の斜視図である。図5と比較して、図10は、基部内の担持面のゾーンの大幅な減少および連続壁(1001)によって包囲された上面(1002)を形成する凹部カバーゾーンの増加を示すとともに壁(1001)が上方に向いた接触面(1003)よりも僅かに高く、それにより上面(1002)中への汚染粒子の侵入の恐れが軽減していることを示している。変形実施形態では、壁(1001)が必要とされず、図示の溝が上方に向いた接触面を上面から隔てている。同様に、基部の上面上の粒子に及ぼされる静電気力は、基部上のレチクルの下方に向いた上面(1002)との間の隙間の形成および上面(1002)の深さの適切な調節時に効果的に弱められ、それにより、例えば、壁(1001)の垂直高さが300μmから3400μmまでの範囲にあるようにすることができまたはレチクルの下面と上面(1002)との間の隙間が少なくとも、300μmよりも大きくすることができる。 FIG. 10 is a perspective view of the base of the reticle pod according to another embodiment of the present invention. Compared to FIG. 5, FIG. 10 shows a significant reduction in the zones of the carrier surface within the base and an increase in the recessed cover zones forming the top surface (1002) surrounded by the continuous wall (1001) as well as the wall (1001). ) Is slightly higher than the upwardly facing contact surface (1003), thereby reducing the risk of contaminated particles entering the top surface (1002). In the modified embodiment, the wall (1001) is not required and the illustrated groove separates the upwardly facing contact surface from the top surface. Similarly, the electrostatic force exerted on the particles on the top surface of the base is effective in forming a gap between the reticle on the base and the downward facing top surface (1002) and in properly adjusting the depth of the top surface (1002). The vertical height of the wall (1001) can be, for example, in the range of 300 μm to 3400 μm, or the gap between the bottom and top surfaces of the reticle (1002) is at least. It can be larger than 300 μm.

図11A~図11Dは、粒子に及ぼされる正味の力に対するレチクルの互いに異なる残留電圧、互いに異なる粒径および互いに異なる隙間の影響を示す図である。図11Aは、特に粒子が凹部の底面(903)上に位置するとともにレチクルの残留電圧が400Vであるときに図6および図9に示された形態に従って6つの互いに異なる粒径の粒子に及ぼされる正味の力と深さ(D)との関係を表わすグラフ図であり、グラフ図によって示されているように、深さが1600μmよりも大きい場合、粒子全ての正味の力が負になり、このことは、粒子が下向きの力を受け、それにより粒子に及ぼされる静電気力が効果的に弱められることを示唆している。同様に、図11Bは、レチクルの残留電圧が200Vであるときに上述の粒径の粒子に及ぼされる正味の力と深さ(D)との関係を表わすグラフ図であり、グラフ図によって示されているように、深さが800μmよりも大きい場合、粒子に及ぼされる静電気力が効果的に弱められる。図11Cは、レチクルの残留電圧が100Vであるときに上述の粒径の粒子に及ぼされる正味の力と深さ(D)との関係を表わすグラフ図であり、グラフ図によって示されているように、深さが400μmよりも大きい場合、粒子に及ぼされる静電気力が効果的に弱められる。図11Dは、レチクルの残留電圧を50Vであるときに上述の粒径の粒子に及ぼされる正味の力と深さ(D)との関係を表すグラフ図であり、これらグラフ図によって示されているように、深さが400μmを超える場合、粒子に及ぼされる静電気力が効果的に弱められる。上述の図では、グラフ図が粒径に従って互いに識別されるような仕方で色分けされていないが、当業者であれば、図に示されている開示内容に従ってグラフ図を互いに識別し、それにより上述の説明を理解することが依然として可能であろう。 11A-11D are diagrams showing the effects of different residual voltages of the reticle, different particle sizes and different gaps on the net force exerted on the particles. FIG. 11A shows six particles of different particle sizes according to the morphology shown in FIGS. 6 and 9, especially when the particles are located on the bottom surface (903) of the recess and the residual voltage of the reticle is 400V. It is a graph showing the relationship between the net force and the depth (D), and as shown by the graph, when the depth is larger than 1600 μm, the net force of all the particles becomes negative, and this This suggests that the particles receive a downward force, which effectively weakens the electrostatic force exerted on the particles. Similarly, FIG. 11B is a graph showing the relationship between the net force exerted on the particles having the above particle size and the depth (D) when the residual voltage of the reticle is 200 V, and is shown by the graph. As such, when the depth is larger than 800 μm, the electrostatic force exerted on the particles is effectively weakened. FIG. 11C is a graph showing the relationship between the net force exerted on the particles having the above-mentioned particle size and the depth (D) when the residual voltage of the reticle is 100 V, as shown by the graph. In addition, when the depth is larger than 400 μm, the electrostatic force exerted on the particles is effectively weakened. FIG. 11D is a graph showing the relationship between the net force exerted on the particles having the above-mentioned particle size and the depth (D) when the residual voltage of the reticle is 50 V, and is shown by these graphs. As such, when the depth exceeds 400 μm, the electrostatic force exerted on the particles is effectively weakened. In the above figure, the graphs are not color coded in such a way that they are distinguished from each other according to the particle size, but those skilled in the art will identify the graphs from each other according to the disclosure contents shown in the figure, thereby the above-mentioned figure. It will still be possible to understand the explanation of.

したがって、本開示内容は、レチクルポッドを提供する。レチクルポッドの基部に設けられた凹部の加工深さまたは凹部の底面(上面)とレチクルの下方に向いた表面との間の隙間を調節することによって、基部の表面上の粒子に対するレチクルの残留電圧の影響が効果的に弱められ、かくして粒子がレチクルの下方に向いた表面に引き寄せられる恐れが軽減し、それによりパターンゾーンが汚染から保護される。 Therefore, the present disclosure provides a reticle pod. The residual voltage of the reticle to the particles on the surface of the base by adjusting the machining depth of the recess provided at the base of the reticle pod or the gap between the bottom surface (top) of the recess and the downward facing surface of the reticle. The effect of the reticle is effectively diminished, thus reducing the risk of particles being attracted to the downward facing surface of the reticle, thereby protecting the pattern zone from contamination.

100 外側ポッド
101,111 蓋
102,112 基部
110 内側ポッド
120 レチクル
212 基部
600 底面
601 壁面
1121 支持部材
1122 担持面
1123 上方に向いた接触面
2121 支持部材
2122 担持面
2123 上方に向いた接触面
2124 凹部
D 深さ
G 隙間
100 Outer pods 101,111 Lid 102,112 Base 110 Inner pod 120 Reticle 212 Base 600 Bottom 601 Wall surface 1121 Support member 1122 Support surface 1123 Upward contact surface 2121 Support member 2122 Upward contact surface 2124 Recess D depth G gap

Claims (17)

帯電防止性能を備えたレチクルポッドであって、
担持面を備えた基部を有し、前記担持面は、底面によって構成された凹部を有し、
前記基部の前記担持面を包囲した状態でレチクルを支持するよう構成された複数の支持部材を有し、
前記凹部は、前記担持面と前記底面との間に延びる深さによって規定され、前記深さは、前記担持面に付着している粒子に及ぼされる静電気力を弱めるよう300μmから3400μmまでの範囲にある、レチクルポッド。
A reticle pod with antistatic performance
It has a base with a supporting surface, the supporting surface having a recess configured by a bottom surface.
It has a plurality of support members configured to support the reticle while surrounding the support surface of the base.
The recess is defined by a depth extending between the supported surface and the bottom surface, the depth in the range of 300 μm to 3400 μm to weaken the electrostatic force exerted on the particles adhering to the supported surface. There is a reticle pod.
前記基部は、前記担持面を包囲した状態で気密封止された受け入れ空間を形成するよう蓋と接触関係をなすようになっている上方に向いた接触面をさらに有する、請求項1記載のレチクルポッド。 The reticle according to claim 1, wherein the base further has an upwardly facing contact surface that is in contact with the lid so as to form an airtightly sealed receiving space surrounding the supporting surface. Pod. 前記凹部は、前記レチクルのパターンゾーンの面積に等しいまたはこれよりも広い面積のゾーンを包囲したリング状の縁部を有する、請求項1記載のレチクルポッド。 The reticle pod according to claim 1, wherein the recess has a ring-shaped edge surrounding a zone having an area equal to or larger than the area of the pattern zone of the reticle. 前記凹部は、前記レチクルのパターンゾーンを覆うのに十分なゾーンを包囲するリング状の縁部を有する、請求項1記載のレチクルポッド。 The reticle pod according to claim 1, wherein the recess has a ring-shaped edge surrounding a zone sufficient to cover the pattern zone of the reticle. 前記凹部は、長さ138mm、幅が110mmの長方形の縁部を有する、請求項1記載のレチクルポッド。 The reticle pod according to claim 1, wherein the recess has a rectangular edge having a length of 138 mm and a width of 110 mm. 前記レチクルの残留電圧は、50Vを超え、前記深さは、少なくとも、400μmを超える、請求項1記載のレチクルポッド。 The reticle pod according to claim 1, wherein the residual voltage of the reticle exceeds 50 V, and the depth exceeds at least 400 μm. 帯電防止性能を備えたレチクルポッドであって、
上面を備えた基部を有し、前記上面は、機械的加工によって形成された偏向面であり、
前記上面を包囲した状態でレチクルを支持するよう構成された複数の支持部材を有し、前記レチクルの下方に向いた表面と前記基部の前記上面との間には、前記基部の前記上面に付着した粒子に及ぼされる静電気力を弱めるよう少なくとも300μmを超える隙間が形成されている、レチクルポッド。
A reticle pod with antistatic performance
It has a base with an upper surface, the upper surface being a deflection surface formed by mechanical processing.
It has a plurality of support members configured to support the reticle while surrounding the upper surface, and adheres to the upper surface of the base between the downwardly facing surface of the reticle and the upper surface of the base. A reticle pod with a gap of at least 300 μm formed to weaken the electrostatic force exerted on the particles.
前記基部は、前記上面を包囲するとともに気密封止された受け入れ空間を形成するよう蓋と接触関係をなすようになっている上方に向いた接触面をさらに有する、請求項7記載のレチクルポッド。 17. The reticle pod of claim 7, wherein the base further comprises an upward facing contact surface that surrounds the top surface and is in contact with the lid to form an airtightly sealed receiving space. 前記上面の面積は、前記レチクルのパターンゾーンの面積に等しくまたはこれよりも広い、請求項7記載のレチクルポッド。 The reticle pod according to claim 7, wherein the area of the upper surface is equal to or larger than the area of the pattern zone of the reticle. 前記上面のゾーンは、前記レチクルのパターンゾーンを覆うのに十分である、請求項7記載のレチクルポッド。 The reticle pod according to claim 7, wherein the upper surface zone is sufficient to cover the pattern zone of the reticle. 前記上面は、長さ138mm、幅が110mmの長方形の縁部を有する、請求項7記載のレチクルポッド。 The reticle pod according to claim 7, wherein the upper surface has a rectangular edge having a length of 138 mm and a width of 110 mm. 前記レチクルの残留電圧は、50Vを超え、前記隙間は、少なくとも、400μmを超える、請求項7記載のレチクルポッド。 The reticle pod according to claim 7, wherein the residual voltage of the reticle exceeds 50 V, and the gap exceeds at least 400 μm. レチクルポッドの基部に利用されるレチクルポッドの加工方法であって、前記基部は、担持面および複数の支持部材を有し、前記複数の支持部材は、前記基部の前記担持面を包囲した状態でレチクルを支持するよう構成され、前記方法は、
前記担持面を機械的に加工して前記担持面上に凹部を形成するステップを含み、前記凹部は、底面によって構成され、
前記凹部を加工して前記凹部を前記レチクルの残留電圧に応じた深さによって規定するステップを含み、前記深さは、少なくとも300μmを超える、方法。
A method for processing a reticle pod used for a base of a reticle pod, wherein the base has a supporting surface and a plurality of supporting members, and the plurality of supporting members surround the supporting surface of the base. The method is configured to support the reticle.
A step of mechanically processing the supported surface to form a recess on the supported surface, wherein the recess is composed of a bottom surface.
A method comprising processing the recess and defining the recess by a depth corresponding to the residual voltage of the reticle, wherein the depth exceeds at least 300 μm.
前記残留電圧は、50Vを超え、前記深さは、少なくとも、400μmを超える、請求項13記載の方法。 13. The method of claim 13, wherein the residual voltage exceeds 50 V and the depth exceeds at least 400 μm. 前記残留電圧は、100Vを超え、前記深さは、少なくとも、400μmを超える、請求項13記載の方法。 13. The method of claim 13, wherein the residual voltage exceeds 100 V and the depth exceeds at least 400 μm. 前記残留電圧は、200Vを超え、前記深さは、少なくとも、800μmを超える、請求項13記載の方法。 13. The method of claim 13, wherein the residual voltage exceeds 200 V and the depth exceeds at least 800 μm. 前記残留電圧は、400Vを超え、前記深さは、少なくとも、1600μmを超える、請求項13記載の方法。 13. The method of claim 13, wherein the residual voltage exceeds 400 V and the depth exceeds at least 1600 μm.
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