JP2020080649A - Composition for improving fried food and method for producing fried food using the same - Google Patents
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Abstract
【課題】 食品本来の風味を損なうことなく、揚げ物における油の吸収量を低減する技術、揚げ物のサクサクとした食感を増強する技術、および、揚げ物の体積を増大させる技術を提供する。【解決手段】 五糖以上を50質量%以上含む糖組成である還元水飴を有効成分とする、揚げ物における油の吸収量を低減させるための組成物。本発明によれば、食品本来の風味を損なうことなく、揚げ物における油の吸収量を低減することができ、健康的であっさりとした、口当たりがよい揚げ物の製造に寄与することができる。【選択図】 図1[Problem] To provide a technique for reducing the amount of oil absorbed in fried food, a technique for enhancing the crispy texture of fried food, and a technique for increasing the volume of fried food without impairing the original flavor of the food. SOLUTION: A composition for reducing the amount of oil absorbed in fried food, comprising reduced starch syrup, which has a sugar composition containing 50% by mass or more of pentasaccharide or higher, as an active ingredient. INDUSTRIAL APPLICABILITY According to the present invention, it is possible to reduce the amount of oil absorbed in fried food without impairing the original flavor of the food, and to contribute to the production of healthy, light and palatable fried food. [Selection diagram] Fig. 1
Description
本発明は、揚げ物を改良する技術に関する。特に、所定の還元水飴を有効成分とする、揚げ物における油の吸収量を低減させるための組成物、揚げ物の体積を増大させるための組成物および揚げ物のサクサクした食感を増大させるための組成物ならびにこれを用いる揚げ物の製造方法に関する。 The present invention relates to a technique for improving fried food. In particular, a composition containing a predetermined reduced starch syrup as an active ingredient for reducing the amount of oil absorbed in fried food, a composition for increasing the volume of fried food, and a composition for increasing the crispy texture of fried food And a method for producing a fried food using the same.
揚げ物は、高温の多量の油の中で食材を加熱調理してなる食品をいう。揚げ物は、(1)油調過程で油を吸収することにより、コクや風味を得るため、嗜好性が高くなる、(2)高温の油による加熱調理が食材表面の水分を除去すると同時に殺菌効果も奏するため、食中毒を起こしにくい、(3)短時間で調理が完了する、(4)油調過程で油を吸収することにより食品のカロリーが増大するため、満足感が高くなる、などの特徴を有し、外食産業や弁当・総菜、パン・菓子などの食品製造業において重要な地位を占めており、多くの製品が存在する。 The fried food refers to a food prepared by heating foods in a large amount of hot oil. Fried foods (1) have a high palatability because they gain a richness and flavor by absorbing oil in the oil conditioning process. (2) Cooking with high-temperature oil removes water from food surface and sterilizing effect at the same time. Since it also plays a role, it is less likely to cause food poisoning, (3) cooking is completed in a short time, (4) the calorie of the food is increased by absorbing oil in the oil conditioning process, so that satisfaction is increased. And has an important position in the food manufacturing industry, such as the restaurant industry, bento and side dishes, and bread and confectionery, and there are many products.
一方、揚げ物は、油分の含有量が多すぎる場合、油っぽくなり食味が低下する。また、過剰の油分摂取が健康に悪影響を与える虞があり、健康志向の高い消費者から敬遠される懸念もある。さらに、冷蔵ないし冷凍保存後に揚げ物から油染みが生じ、製品の外観および食味に悪影響を与える。また、ドーナツや唐揚げ、天ぷら等の代表的な揚げ物は、サクサクとした食感を有することが嗜好性ないし商品価値を高める上で重要であるが、揚げ物に当該食感を十分に付与できるか否かは、製造者の技量に左右される場合が少なくない。 On the other hand, when the fried food contains too much oil, it becomes oily and has a poor taste. In addition, excessive oil intake may adversely affect health, and there is also a concern that consumers who are health-conscious are discouraged. Furthermore, after chilled or frozen storage, oil stains are produced from the fried food, which adversely affects the appearance and taste of the product. In addition, it is important for typical fried foods such as donuts, fried chicken, and tempura to have a crispy texture in order to enhance palatability or commercial value. Is it possible to sufficiently impart the texture to the fried food? Whether or not there are many cases depends on the skill of the manufacturer.
そこで、揚げ物における油の吸収量を低減させる技術や、揚げ物のサクサクとした食感を増強する技術が研究開発されており、例えば、特許文献1には、グルコシルセラミドを含有させたフライ用バッターにより、口溶けがよく、サクサク感があり油っぽくなく歯切れがよいフライ食品を製造できることが開示されている。また、特許文献2には、小麦粉からなる衣材、ガルバンゾー、チャナダル、レンズ豆、ムングダル、エンドウから選ばれる粉砕物および水から主になる揚げ物用衣組成物により、サクサク感やカリカリ感が高く、かつ、油の吸収が少ない揚げ物を製造できることが開示されている。 Therefore, a technique for reducing the amount of oil absorbed in the fried food and a technique for enhancing the crispy texture of the fried food have been researched and developed. For example, Patent Document 1 discloses a frying batter containing glucosylceramide. It is disclosed that a fried food that melts well in the mouth, has a crunchy feeling, is not oily, and has a crisp texture can be produced. Further, Patent Document 2 has a high crispness and crispness due to a garment composition made of wheat flour, garbanzo, chanadal, lentils, mungdal, pea selected from pea, and a fried food composition mainly composed of water, Moreover, it is disclosed that a fried food with less oil absorption can be produced.
しかしながら、特許文献1に記載のフライ用バッターを用いたフライ食品は、官能評価にて「油っぽくない」ことや、「サクサク感がある」ことを確認しているに過ぎず、実際に油の吸収量が低減されているか、あるいは、食感の改良効果が十分か否かは不明である。また、特許文献2に記載の揚げ物用衣組成物を用いた揚げ物は、特定の豆類の風味が付与され、当該揚げ物本来の風味が損なわれることが懸念される。すなわち、これら先行技術を鑑みても、食品本来の風味を損なうことなく、揚げ物における油の吸収量を効果的に低減する技術、また、揚げ物のサクサクとした食感を効果的に増強する技術は十分に提供されている状況ではない。 However, the fried food using the frying batter described in Patent Document 1 only confirms that it is "not oily" and "has a crispy feeling" in the sensory evaluation, and it is actually oiled. It is unclear whether the absorption amount of is reduced or whether the texture improving effect is sufficient. In addition, there is a concern that the fried food using the fried food coating composition described in Patent Document 2 is imparted with a particular bean flavor and the original flavor of the fried food is impaired. That is, even in view of these prior art, without impairing the original flavor of food, technology for effectively reducing the amount of oil absorbed in the fried food, and technology for effectively enhancing the crispy texture of the fried food are The situation is not fully provided.
本発明は、これらの課題を解決するためになされたものであって、食品本来の風味を損なうことなく、揚げ物における油の吸収量を低減する技術、および、揚げ物のサクサクとした食感を増強する技術を提供することを目的とする。また、本発明は、揚げ物の体積を増大させる技術を提供することを目的とする。 The present invention has been made in order to solve these problems, a technique for reducing the amount of oil absorption in fried foods without impairing the original flavor of food, and enhancing the crispy texture of fried foods. The purpose is to provide the technology to do so. Another object of the present invention is to provide a technique for increasing the volume of fried food.
本発明者らは、鋭意研究の結果、低糖化還元水飴が、揚げ物における油の吸収量を低減すること、揚げ物の体積を増大させること、および、揚げ物のサクサクした食感を増強することを見出した。そこで、これらの知見に基づいて、下記の各発明を完成した。 As a result of diligent research, the present inventors have found that low saccharified reduced starch syrup reduces oil absorption in fried foods, increases fried food volume, and enhances the crispy texture of fried foods. It was Therefore, the following inventions have been completed based on these findings.
(1)本発明に係る組成物は、揚げ物における油の吸収量を低減させるための組成物であって、五糖以上を50質量%以上含む糖組成である還元水飴を有効成分とする。 (1) The composition according to the present invention is a composition for reducing the amount of oil absorbed in a fried food, and contains reduced starch syrup as an active ingredient, which is a sugar composition containing 50% by mass or more of pentasaccharide.
(2)本発明に係る組成物は、揚げ物における油の吸収量を低減させるための組成物であって、デキストロース当量が40未満の水飴を還元してなる還元水飴を有効成分とする。 (2) The composition according to the present invention is a composition for reducing the amount of oil absorbed in fried foods, and contains reduced starch syrup obtained by reducing starch syrup having a dextrose equivalent of less than 40 as an active ingredient.
(3)本発明に係る組成物は、揚げ物の体積を増大させるための組成物であって、五糖以上を50質量%以上含む糖組成である還元水飴を有効成分とする。 (3) The composition according to the present invention is a composition for increasing the volume of fried food, and contains reduced starch syrup as an active ingredient, which is a sugar composition containing 50% by mass or more of pentasaccharide.
(4)本発明に係る組成物は、揚げ物の体積を増大させるための組成物であって、デキストロース当量が40未満の水飴を還元してなる還元水飴を有効成分とする。 (4) The composition according to the present invention is a composition for increasing the volume of fried foods, and contains reduced starch syrup obtained by reducing starch syrup having a dextrose equivalent of less than 40 as an active ingredient.
(5)本発明に係る組成物は、揚げ物のサクサクした食感を増強させるために用いることができる。 (5) The composition according to the present invention can be used to enhance the crispy texture of fried foods.
(6)本発明に係る組成物において、還元水飴の糖組成は、単糖が1〜10質量%、二糖が6〜21質量%、三糖が7〜23質量%および四糖以上が55〜92質量%であってよい。 (6) In the composition according to the present invention, the sugar composition of the reduced starch syrup has a monosaccharide content of 1 to 10% by mass, a disaccharide content of 6 to 21% by mass, a trisaccharide content of 7 to 23% by mass, and a tetrasaccharide content of 55 or more. ˜92% by weight.
(7)本発明に係る揚げ物の製造方法は、本発明に係る組成物を含む材料を油調する工程を有する。 (7) The method for producing a fried food according to the present invention has a step of adjusting the oil content of the material containing the composition according to the present invention.
五糖以上を50質量%以上含む糖組成である還元水飴、あるいは、デキストロース当量が40未満の水飴を還元してなる還元水飴の味は、砂糖の1/3程度の低い甘味である。よって、本発明によれば、食品本来の風味を損なうことなく、揚げ物における油の吸収量を低減することができ、健康的であっさりとした、口当たりがよい揚げ物の製造に寄与することができる。 The taste of reduced starch syrup having a sugar composition containing 50% by mass or more of pentasaccharide or reduced starch syrup obtained by reducing starch syrup having a dextrose equivalent of less than 40 has a sweetness as low as about 1/3 that of sugar. Therefore, according to the present invention, it is possible to reduce the amount of oil absorbed in the fried food without impairing the original flavor of the food, and it is possible to contribute to the production of a healthy, light, and fried food with a pleasant mouthfeel.
また、本発明によれば、食品本来の風味を損なうことなく、揚げ物の体積を増大させることができる。よって、本発明によれば、外観が良く見栄えが向上した揚げ物や中身がふんわりとして食感が向上した揚げ物の製造に寄与することができる。 Further, according to the present invention, the fried food volume can be increased without impairing the original flavor of the food. Therefore, according to the present invention, it is possible to contribute to the production of a fried food having a good appearance and an improved appearance, or a fried food having a soft texture and an improved texture.
また、本発明によれば、食品本来の風味を損なうことなく、揚げ物のサクサクとした食感を増強することができる。よって、本発明によれば、クリスピーで良好な食感を有する揚げ物の製造に寄与することができる。 Further, according to the present invention, the crispy texture of fried food can be enhanced without impairing the original flavor of the food. Therefore, according to the present invention, it is possible to contribute to the production of fried foods having a crispy and good texture.
以下、本発明について詳細に説明する。本発明は、下記(a)〜(d)の組成物を提供する。以下、(a)〜(d)の組成物をまとめて「本発明の組成物」または「本発明に係る組成物」という場合がある。
(a)五糖以上を50質量%以上含む糖組成である還元水飴を有効成分とする、揚げ物における油の吸収量を低減させるための組成物(油の吸収量低減用組成物)。
(b)デキストロース当量が40未満の水飴を還元してなる還元水飴を有効成分とする、揚げ物における油の吸収量を低減させるための組成物(油の吸収量低減用組成物)。
(c)五糖以上を50質量%以上含む糖組成である還元水飴を有効成分とする、揚げ物の体積を増大させるための組成物(体積増大用組成物)。
(d)デキストロース当量が40未満の水飴を還元してなる還元水飴を有効成分とする、揚げ物の体積を増大させるための組成物(体積増大用組成物)。
Hereinafter, the present invention will be described in detail. The present invention provides the following compositions (a) to (d). Hereinafter, the compositions (a) to (d) may be collectively referred to as the “composition of the present invention” or the “composition of the present invention”.
(A) A composition for reducing the absorption amount of oil in fried foods (composition for reducing the absorption amount of oil), which comprises reduced starch syrup having a sugar composition containing 50% by mass or more of pentasaccharide as an active ingredient.
(B) A composition for reducing the amount of absorbed oil in frying (a composition for reducing the amount of absorbed oil), which contains reduced starch syrup obtained by reducing starch syrup having a dextrose equivalent of less than 40 as an active ingredient.
(C) A composition for increasing the volume of fried foods (composition for increasing volume), which contains reduced starch syrup having a sugar composition containing 50% by mass or more of pentasaccharide as an active ingredient.
(D) A composition for increasing the volume of fried foods (composition for increasing volume), which contains reduced starch syrup obtained by reducing starch syrup having a dextrose equivalent of less than 40 as an active ingredient.
本発明の組成物は、揚げ物のサクサクとした食感を増強する効果も有する。よって、本発明の組成物は、揚げ物における油の吸収量を低減させるとともに、揚げ物のサクサクとした食感を増強するための組成物(サクサク食感増強用組成物)として用いることができる。また、本発明の組成物は、揚げ物の体積を増大させるとともに、揚げ物のサクサクとした食感を増強するための組成物(サクサク食感増強用組成物)として用いることができる。 The composition of the present invention also has the effect of enhancing the crispy texture of fried foods. Therefore, the composition of the present invention can be used as a composition for reducing the amount of oil absorbed in a fried food and enhancing the crispy texture of the fried food (a composition for enhancing a crispy texture). Further, the composition of the present invention can be used as a composition for increasing the volume of fried foods and enhancing the crispy texture of the fried foods (composition for enhancing crispy texture).
本発明の組成物はいずれも、所定の還元水飴を有効成分としている。還元水飴は、水飴を還元して得られる糖アルコールの一種(水飴の還元物)である。ここで、水飴はデンプンを酸や酵素などで糖化して得られるものであり、単糖(ブドウ糖)および多糖(オリゴ糖やデキストリンなど)の混合物である。よって、還元水飴も、単糖の糖アルコールおよび多糖(二糖、三糖、四糖または五糖以上)の糖アルコールのうち、2種以上の糖アルコールを含む混合物である。 Each of the compositions of the present invention has a predetermined reduced starch syrup as an active ingredient. Reduced starch syrup is a kind of sugar alcohol obtained by reducing starch syrup (reduced starch syrup). Here, starch syrup is obtained by saccharifying starch with an acid or an enzyme, and is a mixture of monosaccharides (glucose) and polysaccharides (oligosaccharides, dextrin, etc.). Therefore, reduced starch syrup is also a mixture containing two or more sugar alcohols among monosaccharide sugar alcohols and polysaccharide (disaccharide, trisaccharide, tetrasaccharide or pentasaccharide or more) sugar alcohols.
還元水飴は、原料とする水飴の糖化の程度により、高糖化還元水飴(糖組成:単糖が30〜50質量%、二糖が20〜50質量%、三糖以上が25質量%以下)、中糖化還元水飴(糖組成:単糖が30質量%未満かつ五糖以上が50質量%未満)および低糖化還元水飴(糖組成:五糖以上が50質量%以上)に分けられる場合があるが、本発明の組成物が有効成分としているのは、これらのうち、低糖化還元水飴である。低糖化還元水飴のより詳細な糖組成としては、単糖が1〜10質量%、二糖が6〜21質量%、三糖が7〜23質量%および四糖以上が55〜92質量%を例示することができる。 Reduced starch syrup is highly saccharified reduced starch syrup (sugar composition: 30 to 50% by mass of monosaccharide, 20 to 50% by mass of disaccharide, 25% by mass or less of trisaccharide or more) depending on the degree of saccharification of starch syrup as a raw material. It may be divided into medium saccharified reduced starch syrup (sugar composition: less than 30% by mass of monosaccharide and less than 50% by mass of pentasaccharide) and low saccharified reduced starch syrup (sugar composition: 50% by mass or more of pentasaccharide). Of these, low saccharified reduced starch syrup is the active ingredient of the composition of the present invention. As a more detailed sugar composition of the low saccharified and reduced starch syrup, monosaccharide is 1 to 10% by mass, disaccharide is 6 to 21% by mass, trisaccharide is 7 to 23% by mass, and tetrasaccharide or more is 55 to 92% by mass. It can be illustrated.
なお、糖組成とは、糖の総質量に占める各糖の質量割合を百分率で示すものをいう。すなわち、糖の総質量を100とした場合の、各糖の質量百分率である。 The sugar composition is a composition showing the mass ratio of each sugar to the total mass of sugar as a percentage. That is, it is a mass percentage of each sugar when the total mass of sugar is 100.
糖組成は、高速液体クロマトグラフィー(HPLC)を用いて確認することができる。すなわち、還元水飴や水飴を試料としてHPLCに供してクロマトグラムを得る。当該クロマトグラムにおいて、全ピークの面積の総和が「糖の総質量」に、各ピークの面積が「各糖の質量」に相当する。よって、試料における各糖の質量百分率は、検出された全ピークの面積の総和に対する各ピークの面積の割合として算出することができる。HPLCの条件は、定法に従って適宜設定することができるが、下記条件を例示することができる。
《HPLCの条件》
カラム;Shodex SUGAR KS-802 HQ(8.0mm ID x 300mm) 2本
溶離液;高純水
流速;1.0mL/分
注入量;200μL
カラム温度;50℃
検出;示差屈折率検出器Shodex RI
The sugar composition can be confirmed using high performance liquid chromatography (HPLC). That is, a reduced starch syrup or starch syrup is used as a sample for HPLC to obtain a chromatogram. In the chromatogram, the sum of the areas of all peaks corresponds to the “total mass of sugar”, and the area of each peak corresponds to the “mass of each sugar”. Therefore, the mass percentage of each sugar in the sample can be calculated as the ratio of the area of each peak to the total area of all the detected peaks. The HPLC conditions can be appropriately set according to a conventional method, and the following conditions can be exemplified.
<<HPLC conditions>>
Column; Shodex SUGAR KS-802 HQ (8.0mm ID x 300mm) 2 eluents; High pure water flow rate; 1.0mL/min injection rate; 200μL
Column temperature: 50°C
Detection: Differential refractive index detector Shodex RI
また、還元水飴が原料とする水飴の糖化の程度の指標は、一般に、デキストロース当量(Dextrose Equivalent値;DE)が用いられる。DEは、試料中の還元糖をブドウ糖として測定したときの、当該還元糖の全固形分に対する割合(百分率)である。DEの最大値は100で、固形分の全てがブドウ糖であることを意味し、DEが小さくなるほど少糖類や多糖類が多いことを意味する。すなわち、DEが大きい水飴の還元物は高糖化還元水飴であり、DEが小さい水飴の還元物は低糖化還元水飴であるといえる。 In addition, the dextrose equivalent (DE) is generally used as an index of the degree of saccharification of starch syrup, which is a raw material of reduced starch syrup. DE is the ratio (percentage) of the reducing sugar to the total solid content when the reducing sugar in the sample is measured as glucose. The maximum value of DE is 100, which means that all solids are glucose, and the smaller the DE, the greater the amount of oligosaccharides and polysaccharides. That is, it can be said that a reduced product of starch syrup having a large DE is a highly saccharified reduced starch syrup, and a reduced product of starch syrup having a small DE is a reduced saccharified reduced starch syrup.
本発明では、後述する実施例で示すように、DEが40未満の水飴を還元してなる還元水飴(低糖化還元水飴)を用いることにより、揚げ物における油の吸収量を低減することができ、揚げ物の体積を増大することができ、あるいは、揚げ物のサクサクした食感を増強することができる。本発明に係る低糖化還元水飴において、原料とする水飴のDE値は、より好ましくは、1以上40未満、5以上40未満、5以上35以下、10以上40未満、10以上35以下、15以上40未満、15以上35以下などを例示することができる。 In the present invention, as shown in Examples to be described later, by using a reduced starch syrup obtained by reducing starch syrup having a DE of less than 40 (low saccharified reduced starch syrup), the amount of oil absorbed in the fried food can be reduced, The volume of the fried food can be increased, or the crispy texture of the fried food can be enhanced. In the low saccharified reduced starch syrup according to the present invention, the DE value of starch syrup as a raw material is more preferably 1 or more and less than 40, 5 or more and less than 40, 5 or more and 35 or less, 10 or more and less than 40, 10 or more and 35 or less, 15 or more. Examples include less than 40, 15 or more and 35 or less.
なお、水飴のDEは、下記の方法により測定することができる。
《DEの測定方法》
試料2.5gを正確に量り、水で溶かして200mLとする。この液10mLを量り、1/25mol/L ヨウ素溶液(注1)10mLと1/25mol/L 水酸化ナトリウム溶液(注2)15mLを加えて20分間暗所に放置する。次に、2mol/L塩酸(注3)を5mL加えて混和した後、1/25mol/L チオ硫酸ナトリウム溶液(注4)で滴定する。滴定の終点近くで液が微黄色になったら、デンプン指示薬(注5)2滴を加えて滴定を継続し、液の色が消失した時点を滴定の終点とする。水を用いてブランク値を求め、次式1によりDE値を求める。
式1:DE = (b−a)×f×3.602/(1/1000)/(200/10)/{A×(100−B)/100}×100
a:滴定値(mL)、b:ブランク値(mL)、f:チオ硫酸ナトリウム溶液のファクター値、A:試料の秤取量(g)、B:試料の水分値(%)
(注1)1/25mol/L ヨウ素溶液:ヨウ化カリウム20.4gとヨウ素10.2gを2Lのメスフラスコに入れ、少量の水で溶解後、標線まで水を加える。
(注2)1/25mol/L 水酸化ナトリウム溶液:水酸化ナトリウム3.2gを2Lのメスフラスコに入れ、少量の水で溶解後、標線まで水を加える。
(注3)2mol/L 塩酸:水750mLに塩酸150mLをかき混ぜながら徐々に加える。
(注4)1/25mol/L チオ硫酸ナトリウム溶液:チオ硫酸ナトリウム20gを2Lのメスフラスコに入れ、少量の水で溶解後、標線まで水を加える。
(注5)デンプン指示薬:可溶性デンプン5gを水500mLに溶解し、これに塩化ナトリウム100gを溶解する。
The DE of starch syrup can be measured by the following method.
<< DE measurement method >>
Precisely weigh 2.5 g of sample and dissolve in water to make 200 mL. 10 mL of this solution is weighed, 10 mL of 1/25 mol/L iodine solution (Note 1) and 15 mL of 1/25 mol/L sodium hydroxide solution (Note 2) are added, and the mixture is left for 20 minutes in the dark. Next, 5 mL of 2 mol/L hydrochloric acid (Note 3) is added and mixed, and then titrated with a 1/25 mol/L sodium thiosulfate solution (Note 4). When the liquid turns slightly yellow near the end point of the titration, 2 drops of starch indicator (Note 5) are added to continue the titration, and the end point of the titration is the time when the color of the liquid disappears. A blank value is obtained using water, and a DE value is obtained by the following equation 1.
Formula 1: DE=(b−a)×f×3.602/(1/1000)/(200/10)/{A×(100−B)/100}×100
a: titration value (mL), b: blank value (mL), f: factor value of sodium thiosulfate solution, A: sample weight (g), B: water content (%) of sample
(Note 1) 1/25 mol/L iodine solution: 20.4 g of potassium iodide and 10.2 g of iodine are put into a 2 L measuring flask, dissolved with a small amount of water, and water is added up to the marked line.
(Note 2) 1/25 mol/L sodium hydroxide solution: 3.2 g of sodium hydroxide is placed in a 2 L measuring flask, dissolved with a small amount of water, and water is added up to the marked line.
(Note 3) 2 mol/L hydrochloric acid: Gradually add 150 mL of hydrochloric acid to 750 mL of water while stirring.
(Note 4) 1/25 mol/L sodium thiosulfate solution: 20 g of sodium thiosulfate is placed in a 2 L measuring flask, dissolved with a small amount of water, and water is added up to the marked line.
(Note 5) Starch indicator: 5 g of soluble starch is dissolved in 500 mL of water, and 100 g of sodium chloride is dissolved therein.
本発明において、低糖化還元水飴は、市販されているものをそのまま用いてもよく、当業者に公知の方法に従って製造して用いてもよい。低糖化還元水飴の公知の製造方法としては、原料となる、五糖以上が50質量%以上の糖組成の水飴あるいはDEが40未満の水飴(原料糖)に水素を添加する還元反応を挙げることができる。 In the present invention, the low saccharified reduced starch syrup may be a commercially available one as it is or may be produced and used according to a method known to those skilled in the art. As a known method for producing reduced saccharified reduced starch syrup, a reduction reaction of adding hydrogen to starch syrup having a sugar composition of 50% by mass or more of pentasaccharide or starch syrup (raw sugar) having a DE of less than 40 is used as a raw material. You can
水素添加による還元反応は、例えば、40〜75質量%の原料糖水溶液を、還元触媒と併せて高圧反応器中に仕込み、反応器中の水素圧を4.9〜19.6MPa、反応液温を70〜180℃として、混合攪拌しながら、水素の吸収が認められなくなるまで反応を行なえばよい。その後、還元触媒を分離し、イオン交換樹脂処理、必要であれば活性炭処理等で脱色脱塩した後、所定の濃度まで濃縮すれば、高濃度の低糖化還元水飴を作ることができる。 In the reduction reaction by hydrogenation, for example, a 40 to 75% by mass raw material sugar aqueous solution is charged into a high pressure reactor together with a reduction catalyst, the hydrogen pressure in the reactor is set to 4.9 to 19.6 MPa, and the reaction liquid temperature is set. The temperature may be 70 to 180° C., and the reaction may be performed with mixing and stirring until hydrogen absorption is no longer observed. After that, the reducing catalyst is separated, decolorized and desalted by treatment with an ion exchange resin, if necessary with activated carbon, and then concentrated to a predetermined concentration, whereby a high-concentration low-saccharified reduced starch syrup can be produced.
本発明において、揚げ物とは、高温の多量の油の中で食材を加熱調理してなる食品をいう。揚げ物は、食材を、衣が無い状態で油で揚げたもの(素揚げ;油揚げ、厚揚げ、揚げかまぼこ、揚げ玉、チキン・ナゲット、揚げパン、ドーナツ、クルトン、フライドポテト、ポテトチップス、かりんとう、揚げ煎餅や揚げあられなどの米菓、揚げ麺、スナック菓子など)であってもよく、衣がある状態で揚げたもの(衣揚げ;天ぷら、唐揚げ、竜田揚げ、磯辺揚げ、フリッター、トンカツやコロッケなどのフライ類)であってもよく、皮を衣として具材を包み揚げたもの(春巻き、サモサ、揚げ餃子、揚げシュウマイ、カレーパン、揚げおやきなど)であってもよい。 In the present invention, the fried food refers to a food product obtained by cooking foods in a large amount of high temperature oil. Fried foods are fried foods in a state without clothes (fried; fried, thick fried, fried kamaboko, fried balls, chicken nuggets, fried bread, donuts, croutons, fried potatoes, potato chips, karinto, fried) Rice crackers such as rice crackers and fried arare, fried noodles, snacks, etc. may also be fried in the presence of batter (fried batter; tempura, fried chicken, fried Tatsuda, fried isobe, fritters, pork cutlet, croquettes, etc. Fried foods), or fried foods wrapped in leather and wrapped (spring rolls, samosa, fried dumplings, fried shumai, curry bread, fried oysters, etc.).
次に、本発明の組成物の使用方法について述べる。揚げ物が「衣が無い状態で食材を油で揚げるもの」である場合は、油調前に、当該食材に低糖化還元水飴を混合すればよい。食材に低糖化還元水飴を混合する際の濃度は、1〜50質量%(油調前の食材の全体重量に対して)を例示することができる。また、低糖化還元水飴を水や調味液に溶解して低糖化還元水飴溶液とし、これを油調前に当該食材の表面に塗布してもよい。塗布する方法は、低糖化還元水飴溶液に当該食材を浸漬する、刷毛塗りやローラーブラシ塗り、エアスプレー、ロールコーティングなど、当該食材や調味液の種類・形態に応じて種々の方法を用いることができる。低糖化還元水飴溶液における低糖化還元水飴の濃度は、1〜50質量%を例示することができる。 Next, a method of using the composition of the present invention will be described. In the case where the fried food is “fried food material without oil batter”, the low-saccharified reduced starch syrup may be mixed with the food material before the oil preparation. The concentration when the low saccharified reduced starch syrup is mixed with the food material can be, for example, 1 to 50 mass% (based on the total weight of the food material before oil conditioning). Further, the low saccharified reduced starch syrup may be dissolved in water or a seasoning solution to obtain a low saccharified reduced starch syrup solution, which may be applied to the surface of the food material before oil conditioning. As the method for applying, various methods may be used depending on the type and form of the food or seasoning liquid, such as dipping the food in a low saccharified reduced starch syrup solution, brush coating, roller brush coating, air spray, or roll coating. it can. The concentration of the low saccharified reduced starch syrup in the low saccharified reduced starch syrup solution can be exemplified by 1 to 50 mass %.
また、揚げ物が、「衣がある状態で食材を油で揚げるもの」や「皮を衣として具材を包み揚げるもの」である場合は、その衣または皮に低糖化還元水飴を混合すればよい。衣または皮における低糖化還元水飴の濃度は、1〜50質量%(油調前の衣または皮の全体重量に対して)を例示することができる。また、上述の低糖化還元水飴溶液を、油調前に衣または皮の表面に塗布してもよい。塗布する方法および低糖化還元水飴溶液における低糖化還元水飴の濃度は、上述と同様のものを例示することができる。 Also, when the fried food is "a food item is fried with a batter in oil" or "a skin is a batter and the ingredients are wrapped in a fried food", a low saccharified reduced starch syrup may be mixed with the batter or the skin. .. The concentration of the reduced saccharified and reduced starch syrup in the clothes or the skin can be exemplified by 1 to 50% by mass (based on the total weight of the clothes or the skin before oil preparation). In addition, the above-described reduced saccharified starch syrup solution may be applied to the surface of clothing or leather before oil preparation. The method of applying and the concentration of the reduced saccharified reduced starch syrup in the reduced saccharified reduced starch syrup solution may be similar to those described above.
本発明において、揚げ物における油の吸収量を低減させるとは、油調により食品に吸収される油の量を減少させることをいう。揚げ物における油の吸収量が低減されたか否かは、例えば、後述する実施例に示す方法により確認することができる。すなわち、当該食品の「油調後重量から油調前重量を減じた値」の「油調後重量」に対する百分率を吸油率とし、本発明の組成物を用いた場合と用いない場合とで、吸油率を比較する。前者の方が吸油率が小さければ、本発明により揚げ物における油の吸収量が低減されたと判断することができる。あるいは、油調による揚げ油の減少量を測定し、これを比較してもよい。本発明の組成物を用いた場合の方が、これを用いない場合と比較して、揚げ油の減少量が小さければ、本発明により揚げ物における油の吸収量が低減されたと判断することができる。 In the present invention, reducing the amount of oil absorbed in the fried food means reducing the amount of oil absorbed in the food due to the oil condition. Whether or not the amount of oil absorbed in the fried food has been reduced can be confirmed, for example, by the method described in Examples below. That is, the percentage of the value of “the value obtained by subtracting the weight before oil adjustment from the weight after oil adjustment” of the food relative to the “weight after oil adjustment” is the oil absorption rate, with and without using the composition of the present invention, Compare the oil absorption. If the former has a smaller oil absorption, it can be determined that the amount of oil absorbed in the fried food was reduced by the present invention. Alternatively, the reduction amount of frying oil due to the oil condition may be measured and compared. If the amount of frying oil reduced when the composition of the present invention is used is smaller than that when the composition of the present invention is not used, it can be determined that the present invention reduced the amount of oil absorbed in the frying product.
本発明において、揚げ物の体積を増大させるとは、揚げ物において、油調により増加する体積の割合を大きくすることをいう。揚げ物の体積を増大したか否かは、例えば、後述する実施例に示す方法により確認することができる。すなわち、当該食品の油調前の重量を揃えた上で、油調後の体積を測定し、本発明の組成物を用いた場合と用いない場合とで比較する。前者の方が体積が大きければ、本発明により揚げ物の体積を増大したと判断することができる。体積の測定は定法に従って行うことができ、例えば、レーザー体積計や菜種法により測定することができる。 In the present invention, increasing the volume of fried food means increasing the proportion of the volume of fried food that increases due to the oil condition. Whether or not the volume of the fried food has been increased can be confirmed, for example, by the method described in Examples below. That is, after adjusting the weight of the food before oil conditioning, the volume after oil conditioning is measured, and the case of using the composition of the present invention and the case of not using the composition are compared. If the former has a larger volume, it can be judged that the volume of the fried food has been increased by the present invention. The volume can be measured according to a standard method, for example, a laser volume meter or a rapeseed method.
本発明において、揚げ物のサクサクした食感を増強させるとは、揚げ物の表面が硬くもろいことによって呈される、咀嚼時のサクサクあるいはカリカリといったクリスピーで歯切れのよい食感(サク味)を強くすることをいう。サクサクした食感が増強されたか否かは、例えば、後述する実施例に示す方法により確認することができる。すなわち、クリープメーターを用いて荷重波形を取得し、もろさ荷重を算出して、本発明の組成物を用いた場合と用いない場合とで比較する。前者の方がもろさ荷重が大きければ、本発明により揚げ物のサクサクとした食感が増強されたと判断することができる。あるいは、官能試験によって確認することもできる。 In the present invention, enhancing the crispy texture of fried foods means strengthening the crispy and crispy texture (crispy taste) such as crispy or crunchy when chewing, which is exhibited by the surface of the fried foods being hard and brittle. Say. Whether or not the crispy texture has been enhanced can be confirmed, for example, by the method described in Examples below. That is, the load waveform is acquired using a creep meter, the brittleness load is calculated, and the case of using the composition of the present invention and the case of not using the composition are compared. If the former has a larger brittleness load, it can be judged that the crispy texture of the fried food is enhanced by the present invention. Alternatively, it can be confirmed by a sensory test.
本発明は、揚げ物の製造方法を提供する。本製造方法は、本発明に係る組成物を含む材料を油調する工程を有する。ここで、本発明に係る組成物を含む材料とは、上述の「本発明の組成物の使用方法」で述べたように、本発明の組成物の有効成分である低糖化還元水飴を、混合や塗布等した食品材料をいう。油調は、通常の揚げ物を製造する場合と同様に行えばよく、揚げ油の種類や揚げ温度、揚げ時間等は、揚げ物の種類に応じて適宜設定することができる。 The present invention provides a method of making a fried food. This manufacturing method has a step of adjusting the oil content of a material containing the composition according to the present invention. Here, the material containing the composition according to the present invention, as described in the above-mentioned “method of using the composition of the present invention”, is mixed with a reduced saccharified reduced starch syrup which is an active ingredient of the composition of the present invention. It refers to food materials that have been applied or coated. The oil adjustment may be performed in the same manner as in the case of producing a normal fried food, and the type of frying oil, the frying temperature, the frying time and the like can be appropriately set according to the type of the fried food.
以下、本発明について、各実施例に基づいて説明する。なお、本発明の技術的範囲は、これらの実施例によって示される特徴に限定されない。 Hereinafter, the present invention will be described based on each example. The technical scope of the present invention is not limited to the features shown by these examples.
本実施例において、甘味料は下記の表1に示すものを用いた。
<実施例1>油の吸収量低減効果
下記の表2に示す配合で各材料をミキサー(愛工舎製作所)に入れ、低速で2分、続いて中速で1分攪拌し、ドーナツ生地を得た。これを20g/個に分割して丸め、20gを油調前重量とした。丸めたドーナツ生地を180℃の油に入れて5分間揚げることによりドーナツを作製した。常温に20分置いて冷ました後、重量を測定し、これを油調後重量とした。下記の式1により吸油率(%)を算出し、各試料につき、15個のドーナツの平均値を求めた。その結果を表2の最下段に示す。
式1:吸油率(%)={(油調後重量−油調前重量)/油調後重量}×100
Formula 1: Oil absorption rate (%)={(weight after oil adjustment−weight before oil adjustment)/weight after oil adjustment}×100
表2の最下段に示すように、吸油率は、試料1では5.12%、試料2では5.25%であったのに対して、試料3では0.38%であり、試料3で顕著に小さかった。すなわち、低糖化還元水飴(スイートNT)を配合したドーナツにおける油の吸収量は、砂糖や高糖化還元水飴を配合したものと比較して顕著に小さかった。この結果から、低糖化還元水飴は、揚げ物における油の吸収量を顕著に低減する効果を有することが明らかになった。 As shown in the bottom row of Table 2, the oil absorption was 5.12% in Sample 1 and 5.25% in Sample 2, whereas it was 0.38% in Sample 3 and It was remarkably small. That is, the amount of oil absorbed by the donut containing the low saccharified reduced starch syrup (Sweet NT) was remarkably small as compared with the one containing sugar or the highly saccharified reduced starch syrup. From this result, it was clarified that the reduced saccharified and reduced starch syrup has an effect of remarkably reducing the amount of oil absorbed in the fried food.
<実施例2>体積増大効果
表3に示す配合および実施例1に記載の方法によりドーナツを作製した。常温に20分置いて冷ました後、レーザー体積計「AR−01」(ケイ・アクシス社)を用いて体積を測定し、各試料につき、8個のドーナツの平均値を求めた。その結果を図1に示す。
図1に示すように、体積は、試料1では30.23cm3、試料2では28.33cm3であったのに対して、試料3では33.28cm3、試料4では32.92cm3であり、試料3および試料4で顕著に大きかった。すなわち、低糖化還元水飴(スイートNTおよびエスイー100)を配合したドーナツの大きさは、砂糖や高糖化還元水飴を配合したものと比較して顕著に大きかった。この結果から、低糖化還元水飴は、揚げ物の体積を増大させる効果を有することが明らかになった。 As shown in FIG. 1, volume, sample 1 in 30.23Cm 3, whereas was Sample 2 28.33Cm 3, Sample 3, 33.28Cm 3, be sample 4 in 32.92Cm 3 , Sample 3 and Sample 4 were significantly larger. That is, the size of the donut containing the reduced saccharified reduced starch syrup (Sweet NT and S100) was significantly larger than that of the mixture containing sugar or the highly saccharified reduced starch syrup. From this result, it was clarified that the reduced saccharified reduced starch syrup has an effect of increasing the volume of fried food.
<実施例3>食感向上効果:ドーナツ
表4に示す配合および実施例1に記載の方法によりドーナツを作製した。常温に20分置いて冷ました後、クリープメータ(山電)の直径3mm棒型のプランジャーを用いて、ドーナツを圧縮速度1mm/秒で100体積%圧縮変形するまで圧縮した。この圧縮中の荷重を測定し、各試料について図2に示すような荷重波形を得た。図2において、F1は、試料が破断するまでの荷重(破断荷重)を示し、「かたさ」の指標となる。F2は、試料が破断してからの荷重(応力)の減少量を示し、「口の中での砕けやすさ」の指標となる(参考資料1:丹羽昭夫,“食品の食感の評価について”,[online],平成29年3月16日,あいち産業科学技術総合センター食品工業技術センター, [平成30年10月15日検索],インターネット,<URL: http://www.aichi-inst.jp/shokuhin/other/up_docs/news1703-2.pdf>)。このことから、F2を「もろさ荷重」と定義し、その値を算出した。すなわち、もろさ荷重の値が大きいほど、試料は、咀嚼時のサクサクあるいはカリカリといったクリスピーで歯切れのよい食感(サク味)が強いことを表す。もろさ荷重は、各試料につき、15個のドーナツの平均値を求めた。その結果を図3に示す。
図3に示すように、もろさ荷重は、試料1では約5.14Nであったのに対して、試料2では約0.47Nであり、顕著に小さかった。一方、試料3では約3.82Nであり、試料1と同等であった。そして、試料4では7.64Nであり、顕著に大きかった。すなわち、中糖化還元水飴を配合したドーナツは、砂糖を配合したものと同等のもろさ荷重を達成していた。また、低糖化還元水飴(エスイー30)を配合したドーナツは、砂糖や高糖化還元水飴を配合したものと比較して、顕著に、もろさ荷重が大きかった。この結果から、低糖化還元水飴は、揚げ物のサクサクした食感を増強する効果を有することが明らかになった。 As shown in FIG. 3, the brittleness load was about 5.14 N in the sample 1 and about 0.47 N in the sample 2, which was remarkably small. On the other hand, in Sample 3, it was about 3.82 N, which was equivalent to that of Sample 1. The value of Sample 4 was 7.64 N, which was remarkably large. That is, the donut containing the medium saccharified and reduced starch syrup achieved the same brittleness load as that containing the sugar. In addition, the donut containing the low saccharified reduced starch syrup (S30) had a significantly high brittleness load as compared with the one containing sugar or the highly saccharified reduced starch syrup. From this result, it was revealed that the reduced saccharified reduced starch syrup has an effect of enhancing the crispy texture of fried foods.
<実施例4>食感向上効果:揚げ玉
下記の表5に示す配合で各材料をボウルに入れ、泡立て器で1分攪拌し、バッターを得た。これを油面上40cmの高さから180℃の油に流し入れ、2分間揚げることにより揚げ玉を作製した。常温に20分置いて冷ました後、実施例3に記載の方法によりもろさ荷重を測定した。もろさ荷重は、各試料につき、10個の揚げ玉の平均値を求めた。その結果を図4に示す。
図4に示すように、もろさ荷重は、試料1では約0.51Nであったのに対して、試料2では約0.88Nであり、試料2で顕著に大きかった。すなわち、低糖化還元水飴(スイートNT)を配合した揚げ玉は、配合していないものと比較して、顕著に、もろさ荷重が大きかった。この結果から、低糖化還元水飴は、揚げ物のサクサクした食感を増強する効果を有することが明らかになった。 As shown in FIG. 4, the brittleness load was approximately 0.51 N in sample 1, whereas it was approximately 0.88 N in sample 2, and was significantly large in sample 2. That is, the fried balls containing the reduced saccharified reduced starch syrup (Sweet NT) had a significantly large brittleness load as compared to the fried balls containing no saccharified reduced starch syrup. From this result, it was revealed that the reduced saccharified reduced starch syrup has an effect of enhancing the crispy texture of fried foods.
<実施例5>食感向上効果:冷凍ドーナツ
表2に示す配合および実施例1に記載の方法によりドーナツを作製した。常温に30分置いて冷ました後、−20℃の冷凍庫に入れて急速冷凍し、1週間冷凍保存した。続いて、電子レンジにより1600ワットで10秒/1個あたり加熱した後、実施例3に記載の方法によりもろさ荷重を測定した。もろさ荷重は、各試料につき、8個のドーナツの平均値を求めた。その結果を図5に示す。
<Example 5> Texture improving effect: Frozen donuts Donuts were prepared according to the formulations shown in Table 2 and the method described in Example 1. After leaving it at room temperature for 30 minutes to cool, it was put in a freezer at -20°C for quick freezing, and then frozen and stored for 1 week. Then, after heating with a microwave oven at 1600 watts for 10 seconds per piece, the brittleness load was measured by the method described in Example 3. The brittleness load was obtained by averaging eight donuts for each sample. The result is shown in FIG.
図5に示すように、もろさ荷重は、試料1では約1.75Nであったのに対して、試料2では約0.05Nであり、顕著に小さかった。一方、試料3では約3.05Nであり、顕著に大きかった。すなわち、低糖化還元水飴(スイートNT)を配合したドーナツは、冷凍後再加熱したものであっても、砂糖や高糖化還元水飴を配合したものと比較して、顕著に、もろさ荷重が大きかった。この結果から、低糖化還元水飴は、揚げ物のサクサクした食感を増強する効果を有することが明らかになった。 As shown in FIG. 5, the brittleness load was about 1.75 N in the sample 1 and about 0.05 N in the sample 2, which was remarkably small. On the other hand, in Sample 3, the value was about 3.05 N, which was remarkably large. That is, the donut containing the low saccharified reduced starch syrup (Sweet NT) had a significantly large brittleness load even when it was frozen and then reheated, as compared with the one containing sugar or a highly saccharified reduced starch syrup. .. From this result, it was revealed that the reduced saccharified reduced starch syrup has an effect of enhancing the crispy texture of fried foods.
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| WO2024151403A1 (en) * | 2023-01-09 | 2024-07-18 | Frito-Lay North America, Inc. | Coating to reduce oil uptake in fried snacks |
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