JP2020059043A - Method for producing amorphous alloy pieces - Google Patents
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Abstract
【課題】非晶質合金リボンから非晶質合金片を打抜き加工する、非晶質合金片の製造方法において、工具コーティングだけに依存しない別の方法で、工具寿命を改善することが可能な、製造方法を提供する。
【解決手段】非晶質金属リボン表面に、所定形状の打抜き輪郭線となる塑性加工溝を形成し、打抜き用パンチ及びダイにより、前記所定形状の非晶質合金片に打抜き加工する、ことを特徴とする非晶質合金片の製造方法。
【選択図】図1PROBLEM TO BE SOLVED: To improve the tool life by a method of punching an amorphous alloy piece from an amorphous alloy ribbon, which is another method which does not depend only on the tool coating. A manufacturing method is provided.
SOLUTION: A plastic working groove which becomes a punching contour line of a predetermined shape is formed on a surface of an amorphous metal ribbon, and the amorphous alloy piece of the predetermined shape is punched by a punch and a die for punching. A method for producing a featured amorphous alloy piece.
[Selection diagram] Figure 1
Description
非晶質合金リボンから所定形状の非晶質合金片に打抜き加工する、非晶質合金片の製造方法に関するものである。 The present invention relates to a method for manufacturing an amorphous alloy piece, which comprises punching an amorphous alloy ribbon into an amorphous alloy piece having a predetermined shape.
非晶質合金は、通常の結晶質合金と同じ組成でも、機械的特性、磁気特性、耐食性等に優れた特性を示すことが知られている。特に、Fe基やCo基の非晶質合金は、結晶粒界が形成されないことから、保磁力の小さい軟磁性材料になることが知られている。
また、非晶質合金は、合金溶湯を急冷凝固して作製することができ、例えば、合金溶湯を回転する冷却ロール表面に供給し、合金溶湯をロール表面で連続凝固させて作製することができる。これは、単ロール法と呼ばれる製法であり、非晶質合金をリボン状に作製できる製法である。
そして、リボン状に作製した非晶質合金は、例えば、巻き回しにより磁気コアに成形することができる。
Amorphous alloys are known to exhibit excellent mechanical properties, magnetic properties, corrosion resistance, etc. even if they have the same composition as a normal crystalline alloy. In particular, it is known that an Fe-based or Co-based amorphous alloy is a soft magnetic material having a small coercive force because no grain boundary is formed.
The amorphous alloy can be prepared by rapidly solidifying the molten alloy, for example, by supplying the molten alloy to the surface of a rotating cooling roll and continuously solidifying the molten alloy on the roll surface. . This is a manufacturing method called a single roll method, and is a manufacturing method capable of manufacturing an amorphous alloy into a ribbon shape.
The ribbon-shaped amorphous alloy can be wound into a magnetic core, for example.
また、非晶質合金リボンから、モータのステータコアやローターコアを成形しようとする場合、これら磁気コアは、形状が複雑なので巻き回しにより成形することができない。そこで、非晶質合金リボンを所定形状に打抜いて非晶質合金片とし、この非晶質合金片を積層して磁気コアにすることが知られている(例えば、特許文献1)。 Further, when an attempt is made to form a motor stator core or rotor core from an amorphous alloy ribbon, these magnetic cores cannot be formed by winding because of their complicated shape. Therefore, it is known that an amorphous alloy ribbon is punched into a predetermined shape to form an amorphous alloy piece, and the amorphous alloy piece is laminated to form a magnetic core (for example, Patent Document 1).
また、非晶質合金リボンを打抜き加工する場合、非晶質合金リボンは硬く加工性が悪いため、連続して加工を行うと、工具、すなわち、パンチとダイが急速に摩耗し、結果として、工具寿命が短くなることが知られている。これを改善する方法としては、これら工具表面にコーティングを施し、工具表面の摩耗を予防する方法が知られている(例えば、特許文献2) Further, when punching the amorphous alloy ribbon, since the amorphous alloy ribbon is hard and has poor workability, continuous working causes rapid wear of the tool, that is, the punch and the die, and as a result, It is known that tool life is shortened. As a method of improving this, a method of coating these tool surfaces to prevent wear of the tool surfaces is known (for example, Patent Document 2).
特許文献2に示されているような工具コーティングは、工具寿命の改善には有効ではあるものの、非晶質合金リボンを連続して打抜き加工するには、改善が不十分であった。したがって、工具コーティングだけに依存しない別の方法で、工具寿命を改善する方法が望まれていた。 Although the tool coating as disclosed in Patent Document 2 is effective for improving the tool life, the improvement is insufficient for continuously punching the amorphous alloy ribbon. Therefore, there is a need for another way to improve tool life that does not rely solely on tool coating.
そこで本発明では、非晶質合金リボンから非晶質合金片を打抜き加工によって得る、非晶質合金片の製造方法において、工具寿命を改善することが可能な製造方法を提供するものである。 Therefore, the present invention provides a method of manufacturing an amorphous alloy piece obtained by punching an amorphous alloy piece from an amorphous alloy ribbon, which is capable of improving the tool life.
本発明である非晶質合金片の製造方法は、非晶質金属リボン表面に、所定形状の打抜き輪郭線となる塑性加工溝を形成し、打抜き用パンチ及びダイにより、前記所定形状の非晶質合金片に打抜き加工する非晶質合金片の製造方法である。 The method for producing an amorphous alloy piece according to the present invention comprises forming a plastically machined groove on a surface of an amorphous metal ribbon, which serves as a punching contour line of a predetermined shape, and using a punch and a die for punching, the amorphous shape of the predetermined shape. This is a method for producing an amorphous alloy piece by punching into a fine alloy piece.
本発明によれば、非晶質合金リボンから非晶質合金片を打抜き加工によって得る、非晶質合金片の製造方法において、工具寿命を改善することが可能になる。 According to the present invention, it is possible to improve the tool life in a method for manufacturing an amorphous alloy piece, which is obtained by punching an amorphous alloy piece from an amorphous alloy ribbon.
一般的に、打抜き加工における、ダイとパンチとのクリアランスには、材料にあった適正範囲が存在し、板厚の3%〜20%程度とされる。そして、適正範囲を外れると工具寿命は短くなることが知られている。
従って、工具寿命を保ちつつ、打抜き加工するためには、予め、適正なクリアランス範囲を確認し、その後、加工が適正範囲内で行われるように、厳正に管理をしながら加工をしなければならなかった。上述した非晶質合金は、通常5〜50μm程度の厚さであるため、適正なクリアランス範囲は極めて狭く、クリアランスの調整はかなり難しい。
Generally, in the punching process, the clearance between the die and the punch has an appropriate range suitable for the material, and is about 3% to 20% of the plate thickness. And, it is known that the tool life is shortened when it deviates from the proper range.
Therefore, in order to perform punching while maintaining the tool life, it is necessary to confirm an appropriate clearance range in advance, and then perform processing with strict control so that the processing will be performed within the appropriate range. There wasn't. Since the above-mentioned amorphous alloy usually has a thickness of about 5 to 50 μm, the appropriate clearance range is extremely narrow and it is quite difficult to adjust the clearance.
そこで、本発明者らは、厳正なクリアランス管理をしなくても、工具寿命を維持することができる打抜き加工の方法を検討した。
その結果、予め、非晶質合金リボン表面に塑性加工溝を形成しておくことが有効であるであることを見出し、本発明に到達した。
Therefore, the present inventors have examined a punching method that can maintain the tool life without strict clearance management.
As a result, they have found that it is effective to form a plastically worked groove on the surface of the amorphous alloy ribbon in advance, and have reached the present invention.
本発明では、非晶質金属リボン表面に、所定形状の打抜き輪郭線となる塑性加工溝を形成し、打抜き用パンチ及びダイにて非晶質合金片に打抜き加工する。打抜き輪郭線となる塑性加工溝を形成することで、小さな打抜荷重で、非晶質合金片を打抜くことができ、工具寿命を改善することができる。以下、詳しく説明する。 In the present invention, a plastic working groove is formed on the surface of the amorphous metal ribbon as a punching contour line having a predetermined shape, and the amorphous alloy piece is punched by a punch and a die for punching. By forming the plastically machined groove as the punching contour line, the amorphous alloy piece can be punched with a small punching load, and the tool life can be improved. The details will be described below.
本発明者らは、初期検討において、非晶質合金リボン表面に、非晶質合金片の打抜き輪郭線となる溝を形成し、打抜き用パンチ及びダイにて、形成した溝に変形応力を集中させれば、良好な形状に打抜き加工できる、との仮説を立て取り組んだ。
具体的には、φ16mmの円板形状に加工された非晶質合金リボンサンプルの表面に、レーザーアブレーション加工により、φ9.3mmの円を描くように打抜き輪郭線となる溝を形成し、このサンプルについて、図1に示す治具1を用いて打抜き加工を行った。
In the initial examination, the present inventors formed a groove on the surface of the amorphous alloy ribbon to be the punching contour line of the amorphous alloy piece, and concentrated the deformation stress on the formed groove with the punch and die for punching. I worked on the hypothesis that if this is done, it would be possible to punch into a good shape.
Specifically, the amorphous alloy ribbon sample processed into a disk shape of φ16 mm was laser-ablated to form a groove of a punching contour line so as to draw a circle of φ9.3 mm. A punching process was performed using the jig 1 shown in FIG.
治具1は、下板2、上板3、ダイ4、ワーク押え5、ガイドリング6、逆押し7、パンチ8、接続棒9を備え、ダイ4とワーク押え5との間に、非晶質合金リボンサンプルS1を配置できるようにしている。 The jig 1 includes a lower plate 2, an upper plate 3, a die 4, a work retainer 5, a guide ring 6, a reverse push 7, a punch 8 and a connecting rod 9, and the amorphous material is provided between the die 4 and the work retainer 5. The quality alloy ribbon sample S1 can be arranged.
また、下板2、上板3は、非晶質合金リボンサンプルS1を押える側と逆側に、それぞれ配置され、接続棒9により接近固定できるようにしている。これにより、非晶質合金リボンサンプルS1が、ダイ4とワーク押え5との間に、強く挟まれるようにしている。 Further, the lower plate 2 and the upper plate 3 are respectively arranged on the side opposite to the side on which the amorphous alloy ribbon sample S1 is pressed so that they can be closely fixed by the connecting rod 9. As a result, the amorphous alloy ribbon sample S1 is strongly sandwiched between the die 4 and the work retainer 5.
また、下板2、上板3、ダイ4、ワーク押え5は、それぞれ貫通孔を有し、これらは、治具1において、それぞれの貫通孔の軸が揃うように配置されている。 The lower plate 2, the upper plate 3, the die 4, and the work retainer 5 each have through holes, and these are arranged in the jig 1 so that the axes of the through holes are aligned.
また、ガイドリング6は、内径を非晶質合金リボンサンプルS1と同じ径とし、ダイ4、ワーク押え5の貫通孔と軸を同じにして配置されている。これにより、非晶質合金リボンサンプルS1の中心が、ダイ4、ワーク押え5の貫通孔の軸に一致し、打抜き輪郭線となる溝により形成されるφ9.3mmの円と、ワーク押え5の貫通孔との位置決めができるようにしている。 Further, the guide ring 6 has the same inner diameter as the amorphous alloy ribbon sample S1, and is arranged so that the through holes of the die 4 and the work retainer 5 have the same axis. As a result, the center of the amorphous alloy ribbon sample S1 coincides with the axes of the through holes of the die 4 and the work retainer 5, and the circle of φ9.3 mm formed by the groove serving as the punching contour line and the work retainer 5 are formed. The positioning with the through hole is made possible.
また、下板2、上板3、ダイ4、ワーク押え5の貫通孔には、下板2側から逆押し7、上板3側からパンチ8が挿入され、非晶質合金リボンサンプルS1の両面に、逆押し7、パンチ8の先端面が接触できるようにしている。そして、パンチ8の先端面が、打抜き輪郭線となる溝により形成した円の内部を押せる位置に位置決めされていて、良好な打抜き加工ができた場合、φ9.3mmの非晶質合金片を打抜くことができる。 In addition, through the through holes of the lower plate 2, the upper plate 3, the die 4, and the work retainer 5, the reverse pressing 7 is inserted from the lower plate 2 side and the punch 8 is inserted from the upper plate 3 side, and the amorphous alloy ribbon sample S1 is The reverse side 7 and the tip surface of the punch 8 can be brought into contact with both surfaces. Then, when the tip surface of the punch 8 is positioned so that the inside of the circle formed by the groove serving as the punching contour line can be pressed and good punching processing can be performed, an amorphous alloy piece of φ9.3 mm is punched. Can be pulled out.
また、非晶質合金リボンサンプルS1をセットした治具1は、逆押し7、パンチ8を挿入した後、逆押し7、パンチ8を外側からクランプして、非晶質合金リボンサンプルS1の両面に、逆押し7、パンチ8の先端面が強く接触されるようにした。そして、不図示のプレス装置により、下板2を支持しつつ、パンチ8に荷重を印加して打抜き加工を試みた。 In addition, the jig 1 on which the amorphous alloy ribbon sample S1 is set, the reverse pressing 7 and the punch 8 are inserted, and then the reverse pressing 7 and the punch 8 are clamped from the outside, so that both surfaces of the amorphous alloy ribbon sample S1 are In addition, the reverse pressing 7 and the tip surface of the punch 8 are strongly contacted. Then, a punching process was attempted by applying a load to the punch 8 while supporting the lower plate 2 with a pressing device (not shown).
ここで、下板2、上板3、ダイ4、ワーク押え5の貫通孔の内径を9.4mmとし、逆押し7、パンチ8の外径を9.2mmとした。すなわち、ダイ4とパンチ8との間に片側100μmのクリアランスを形成した。 Here, the inner diameters of the through holes of the lower plate 2, the upper plate 3, the die 4, and the work retainer 5 were set to 9.4 mm, and the reverse pressing 7 and the punch 8 were set to the outer diameter of 9.2 mm. That is, a clearance of 100 μm was formed on one side between the die 4 and the punch 8.
本実施形態では、厚みが平均24.8μmの非晶質合金リボンサンプルS1を使用した。
治具1は、非晶質合金リボンサンプルS1の厚みに対して、クリアランスが著しく広いため、摩耗の影響が小さくなり、工具寿命の改善が期待される一方、形状良く打抜き加工できないことが想定された。
In this embodiment, the amorphous alloy ribbon sample S1 having an average thickness of 24.8 μm was used.
Since the jig 1 has a remarkably wide clearance with respect to the thickness of the amorphous alloy ribbon sample S1, it is expected that the influence of abrasion will be small and the tool life will be improved, but that it cannot be punched with a good shape. It was
初期検討では、レーザーアブレーション加工を用いて、非晶質合金リボンサンプルS1表面に平均4μmの溝を形成して打抜き加工を行った。しかし、打抜荷重は、溝を形成しない時の平均72kgに対し、10個のサンプルで25〜75kgと大きくばらつき、期待される効果がほとんどない場合も確認された。 In the initial examination, a laser ablation process was used to form a groove having an average of 4 μm on the surface of the amorphous alloy ribbon sample S1 and the punching process was performed. However, the punching load varied widely from 25 kg to 75 kg in the case of 10 samples, with an average of 72 kg when the groove was not formed, and it was confirmed that there was almost no expected effect.
上記初期検討の結果から、レーザーアブレーション加工により、さらに深い溝を形成することも検討したが、レーザ加工時間の増大とスパッタ発生による異物付着の問題があり、良好な形状の非晶質合金片が得られる可能性は低いと考え、それ以上の検討は中止した。 From the results of the above initial examination, it was also considered to form a deeper groove by laser ablation processing, but there is a problem of foreign matter adhesion due to increased laser processing time and spatter generation, and amorphous alloy pieces of good shape We considered it unlikely to be obtained, and stopped further investigation.
次に、本発明者らは、レーザーアブレーション加工に替えて、図2に示す刻印治具21により塑性加工溝を形成することを検討した。 Next, the present inventors examined forming a plastically machined groove by the marking jig 21 shown in FIG. 2 instead of the laser ablation process.
図2の刻印治具21は、刻印パンチ22、アンビル23を有するものであり、非晶質合金リボンサンプルS1を、アンビル23の先端に配置した後、非晶質合金リボンサンプルS1表面に、φ9.3mmの円状とした刻印パンチ22の先端を、所定の荷重で押し付けられるようにしている。 The marking jig 21 of FIG. 2 has a marking punch 22 and an anvil 23. After the amorphous alloy ribbon sample S1 is placed at the tip of the anvil 23, φ9 is formed on the surface of the amorphous alloy ribbon sample S1. The tip of the stamp punch 22 having a circular shape of 0.3 mm can be pressed with a predetermined load.
非晶質合金リボンサンプルS1表面に、刻印治具21を用いて押付加工を行ったところ、打抜き輪郭線となる塑性加工溝が形成されることを確認できた。 When pressing was performed on the surface of the amorphous alloy ribbon sample S1 using the marking jig 21, it was confirmed that a plastically processed groove to be a punching contour line was formed.
図3に示すように、押付荷重に対する溝深さは、ほぼリニアに変化し、押付荷重1ton当たり、平均で11.3μm深さとなった。 As shown in FIG. 3, the groove depth with respect to the pressing load changed substantially linearly, and the average depth was 11.3 μm per 1 ton of the pressing load.
次に、打抜き輪郭線となる塑性加工溝を形成した非晶質合金リボンサンプルS1について、前述の治具1を用いて打抜き加工を行い、押付荷重に対する打抜荷重の関係を確認した。
ここで、押付荷重が0tonの時は、溝を形成しないサンプルの打抜き加工に対応するとした。
Next, with respect to the amorphous alloy ribbon sample S1 in which the plastically processed groove serving as the punching contour line was formed, punching processing was performed using the jig 1 described above, and the relationship between the pressing load and the punching load was confirmed.
Here, when the pressing load is 0 ton, it is assumed that the sample is punched without forming the groove.
その結果、図4に示すように、塑性加工溝を形成する押付荷重が1tonでも、打抜荷重が大きく低減できていることが分かった。これは、レーザーアブレーション加工による溝形成とは異なり加圧によりフリーボリュームが減少するとともに短範囲の結晶組織(クラスタ)が形成され、塑性変形からせん断破壊機構が加わり、より弱い力でも簡単に打ち抜くことが可能になったと推測される。 As a result, as shown in FIG. 4, it was found that the punching load could be greatly reduced even when the pressing load forming the plastic working groove was 1 ton. Unlike the groove formation by laser ablation processing, the free volume is reduced by pressurization and a short range of crystal structure (cluster) is formed, and the shear fracture mechanism is added from plastic deformation, and it is possible to easily punch even with weaker force. It is speculated that
図5は、押付荷重1tonにて溝を形成したサンプルの、打抜き後の端面を示している。
溝直下の厚み部分が非結晶合金に良く見られる引張破断面を示した。
FIG. 5 shows an end surface of a sample in which a groove is formed with a pressing load of 1 ton after punching.
The thickness portion just below the groove shows the tensile fracture surface often seen in amorphous alloys.
以上より、予め、非晶質合金リボン表面に打抜き輪郭線となる塑性加工溝を形成することで、工具にかかる負荷を小さくできるため、工具寿命を改善できることが分かった。また、通常よりも大きなクリアランスで打抜き加工ができるため、工具の調整に掛かる工数の削減も期待できる。 From the above, it has been found that the load on the tool can be reduced by previously forming the plastically machined groove to be the punching contour line on the surface of the amorphous alloy ribbon, so that the tool life can be improved. Further, since punching can be performed with a clearance larger than usual, reduction in man-hours required for tool adjustment can be expected.
なお、上記実施形態では、刻印治具21を用いたが、ダイカットロールを使用して連続的に塑性加工溝を形成すれば、作業工数の低減が期待できる。 In the above embodiment, the marking jig 21 is used, but if the die-cut roll is used to continuously form the plastically machined groove, the number of working steps can be expected to be reduced.
本発明は、非晶質組織を維持したまま製品となるものだけでなく、非晶質合金リボンとして打抜き加工され、その後にナノ結晶化されるナノ結晶合金用の非晶質合金リボンにも適用可能である。 INDUSTRIAL APPLICABILITY The present invention is applicable not only to a product that maintains an amorphous structure but also to an amorphous alloy ribbon for a nanocrystalline alloy that is punched as an amorphous alloy ribbon and then nanocrystallized. It is possible.
1 治具
2 下板
3 上板
4 ダイ
5 ワーク押え
6 ガイドリング
7 逆押し
8 パンチ
9 接続棒
21 刻印治具
22 刻印パンチ
23 アンビル
1 jig 2 lower plate 3 upper plate 4 die 5 work clamp 6 guide ring 7 reverse pressing 8 punch 9 connecting rod 21 marking jig 22 marking punch 23 anvil
Claims (1)
A plastic working groove that forms a punching contour line of a predetermined shape is formed on the surface of the amorphous metal ribbon, and the amorphous alloy piece of the predetermined shape is punched by a punch and a die for punching. A method for producing a crystalline alloy piece.
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| JP2018191731A JP7210990B2 (en) | 2018-10-10 | 2018-10-10 | Method for producing amorphous alloy flakes |
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| JP2018191731A JP7210990B2 (en) | 2018-10-10 | 2018-10-10 | Method for producing amorphous alloy flakes |
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| JP2020059043A true JP2020059043A (en) | 2020-04-16 |
| JP7210990B2 JP7210990B2 (en) | 2023-01-24 |
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| JP2022185715A (en) * | 2021-06-03 | 2022-12-15 | 日立金属株式会社 | Nanocrystal alloy piece manufacturing method and nanocrystal alloy piece manufacturing apparatus |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2022185715A (en) * | 2021-06-03 | 2022-12-15 | 日立金属株式会社 | Nanocrystal alloy piece manufacturing method and nanocrystal alloy piece manufacturing apparatus |
| JP7753679B2 (en) | 2021-06-03 | 2025-10-15 | 株式会社プロテリアル | Nanocrystalline alloy flake manufacturing method and nanocrystalline alloy flake manufacturing device |
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