JP2019218665A - Clothes-reinforcing member - Google Patents
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Abstract
【課題】ブラジャー、ブラキャミソール、水着、ブラジャー一体型肌着等の衣服に用いられるワイヤー等の衣料用補強部材において、衣料の洗濯時等において大きな負荷が加わっても折れたりすることがなく、また簡単に製造することができることを目的とする。【解決手段】ポリアミド樹脂を主成分として含み、飽和吸水率(水中、ISO62)が4.0%以上の樹脂組成物から、射出成形や押出成形、あるいはプレス成形等によって衣料用補強部材の形状に成形され、成形品の水分率が飽和吸水率の20%〜90%である衣料用補強部材とした。【選択図】図2PROBLEM TO BE SOLVED: To easily reinforce a clothing reinforcement member such as a wire used for clothing such as a brassiere, a bra camisole, a swimsuit, an underwear with a brassiere and the like without breaking even if a large load is applied when washing the clothing. The purpose is to be able to manufacture. SOLUTION: A resin composition containing a polyamide resin as a main component and having a saturated water absorption rate (in water, ISO62) of 4.0% or more is formed into a reinforcing member for clothing by injection molding, extrusion molding, press molding or the like. The reinforcing member for clothing was molded, and the moisture content of the molded product was 20% to 90% of the saturated water absorption. [Selection diagram] Figure 2
Description
本発明は、ブラジャー、ブラキャミソール、水着、ブラジャー一体型肌着などの衣料に使用される衣料用補強部材に関する。 The present invention relates to a reinforcing member for clothing used for clothing such as a bra, a bra camisole, a swimsuit, and a bra-integrated underwear.
衣料には、身体の形状を整えるためにワイヤーなどの補強部材が取り付けられたものがある。例えば、乳房受け用カップ部を有する衣料においては、乳房の形を保持するためにカップ部の下側などにワイヤーが挿入されている。 Some clothing has a reinforcing member such as a wire attached thereto to adjust the shape of the body. For example, in clothing having a breast receiving cup portion, a wire is inserted under the cup portion or the like in order to maintain the shape of the breast.
衣料用補強部材として、鋼線、樹脂で覆った被覆鋼線、形状記憶合金、剛性の高い合成樹脂、繊維強化樹脂等からなるものがある。 Examples of the clothing reinforcing member include a steel wire, a coated steel wire covered with a resin, a shape memory alloy, a highly rigid synthetic resin, and a fiber reinforced resin.
しかし、従来の衣料用補強部材は、衣料の洗濯等の際に大きな負荷が加わることで折れたり、あるいは被覆樹脂が摩耗したり、割れたりして鋼線が露出し、この露出した鋼線が生地を突き破って突出するおそれがあった。 However, the conventional reinforcing member for clothing breaks when a large load is applied at the time of washing the clothing, or the coating resin is worn or cracked, and the steel wire is exposed. There was a risk of breaking through and protruding the dough.
本発明は前記の点に鑑みなされたものであって、衣料の洗濯時等において大きな負荷が加わっても折れたりすることがなく、また簡単に製造することができる衣料用補強部材の提供を目的とする。 SUMMARY OF THE INVENTION The present invention has been made in view of the above points, and an object of the present invention is to provide a reinforcing member for clothing that does not break even when a large load is applied during washing of clothing and that can be easily manufactured. And
請求項1の発明は、ポリアミド樹脂を主成分とし、飽和吸水率(水中、ISO62)が4.0%以上の樹脂組成物から成形され、且つ成形品の水分率が飽和吸水率の20〜90%である衣料用補強部材。
The invention according to
請求項2の発明は、請求項1において、前記ポリアミド樹脂は、アミド結合間の炭素数が4〜11であることを特徴とする。 According to a second aspect of the present invention, in the first aspect, the polyamide resin has 4 to 11 carbon atoms between amide bonds.
請求項3の発明は、請求項1または2において、前記ポリアミド樹脂は、ポリアミド6、ポリアミド66、ポリアミド610の群から選択されることを特徴とする。
According to a third aspect of the present invention, in the first or second aspect, the polyamide resin is selected from the group consisting of
請求項4の発明は、請求項1から3の何れか一項において、前記樹脂組成物に熱可塑性エラストマーを含むことを特徴とする。 According to a fourth aspect of the present invention, in any one of the first to third aspects, the resin composition contains a thermoplastic elastomer.
請求項5の発明は、請求項1から4の何れか一項において、前記樹脂組成物に無機充填剤を含むことを特徴とする。 According to a fifth aspect of the present invention, in any one of the first to fourth aspects, the resin composition contains an inorganic filler.
請求項6の発明は、請求項1から5の何れか一項において、耐屈曲性が100回以上であることを特徴とする。 According to a sixth aspect of the present invention, in any one of the first to fifth aspects, the bending resistance is 100 times or more.
本発明によれば、衣料の洗濯時等において大きな負荷が加わっても折れたりすることがなく、また簡単に製造することができる衣料用補強部材が得られる。 ADVANTAGE OF THE INVENTION According to this invention, the reinforcement member for clothing which does not break even if a heavy load is applied at the time of washing of clothing, etc. and which can be easily manufactured is obtained.
図1に示す衣料用補強部材10は、本発明の衣料用補強部材の一実施形態であり、ブラジャーのアンダーワイヤーとして使用されるものである。また、本発明の衣料用補強部材の形状は、ワイヤーに限られず、使用される衣料及び使用箇所に応じた形状からなり、板状等であってもよい。
The
衣料用補強部材10は、ポリアミド樹脂を主成分とし、飽和吸水率(水中、ISO62)が4.0%以上の樹脂組成物から成形され、且つ、成形品の水分率が飽和吸水率の20%〜90%(すなわち水分比率が20〜90%)である。なお、成形品の水分率は2〜10%である。
The reinforcing member for
樹脂組成物の飽和吸水率(水中、ISO62)は、樹脂組成物を100mm×100mm×t2mmの平板を射出成形し、ISO62 A法に規定されている条件で測定される値である。
成形品の水分率は、前記樹脂組成物を射出成形し、その成形品を乾燥減量法により算出され、次式により求められる。乾燥条件は、110℃×24時間である。
『成形品の水分率=(乾燥前サンプル重量−乾燥後サンプル重量)/乾燥前サンプル重量×100』
水分比率は、[水分比率=成形品の水分率/飽和吸水率×100]の式で得られる値である。水分比率が20%未満(成形品の水分率が飽和吸水率の20%未満)の場合には耐屈曲性に劣り、水分比率が90%を超過(成形品の水分率が飽和吸水率の90%を超過)すると剛性が劣ってしまう。
The saturated water absorption (in water, ISO 62) of the resin composition is a value measured by injection molding a flat plate of 100 mm × 100 mm × t2 mm from the resin composition and measuring the conditions specified in the ISO 62A method.
The moisture content of the molded article is obtained by injection molding the resin composition, calculating the molded article by a loss on drying method, and is determined by the following equation. The drying condition is 110 ° C. × 24 hours.
“Moisture percentage of molded article = (weight of sample before drying−weight of sample after drying) / weight of sample before drying × 100”
The water ratio is a value obtained by the equation [water ratio = water ratio of molded article / saturated water absorption × 100]. If the moisture ratio is less than 20% (the moisture content of the molded product is less than 20% of the saturated water absorption), the bending resistance is poor, and the moisture ratio exceeds 90% (the moisture content of the molded product is 90% of the saturated water absorption). %), The rigidity is inferior.
ポリアミド樹脂としては、アミド結合間の炭素数が4〜11のものが好ましい。例えば、ポリアミド6(アミド結合間の炭素数5、飽和吸水率(ISO62)10%)、ポリアミド66(アミド結合間の炭素数4及び6、飽和吸水率(ISO62)9%)、ポリアミド610(アミド結合間の炭素数6及び8、飽和吸水率(ISO62)8%)、ポリアミド46(アミド結合間の炭素数4及び4、飽和吸水率(ISO62)12%)が挙げられる。なお、ポリアミド樹脂は、一種類に限られず2種類以上の混合物を使用することができる。 As the polyamide resin, those having 4 to 11 carbon atoms between amide bonds are preferable. For example, polyamide 6 (5 carbon atoms between amide bonds, saturated water absorption (ISO62) 10%), polyamide 66 (4 and 6 carbon atoms between amide bonds, 9% saturated water absorption (ISO62)), polyamide 610 (amide C6 and C8 between bonds, saturated water absorption (ISO62) 8%), and polyamide 46 (C4 and C4 between amide bonds, saturated water absorption (ISO62) 12%). The polyamide resin is not limited to one kind, and a mixture of two or more kinds can be used.
樹脂組成物には、他の配合材として、熱可塑性エラストマーや無機充填剤を挙げることができる。
熱可塑性エラストマーとしては、スチレン系エラストマーとして、スチレン−ブタジエンブロック共重合体、スチレン−イソプレン共重合体などが挙げられる。オレフィン系エラストマーとしては、ポリエチレン、ポリブテン、ポリペンテンエチレン−酢酸ビニル共重合体、エチレン−ビニルアルコール共重合体、エチレン−プロピレンゴム(EPR)、エチレン−プロピレン−ジエンゴム(EPDM)などが挙げられる。オレフィン系エラストマーに無水マレイン酸等の極性基やスチレン、アクリルニトリル等をグラフトしたエラストマーがより適している。
熱可塑性エラストマーは、一種類に限られず複数種類を配合してもよい。熱可塑性エラストマーの配合により、耐屈曲性及び耐衝撃強度を高めることができる。熱可塑性エラストマーを配合する場合の配合量は、ポリアミド樹脂100重量部に対して5〜100重量部が好ましい。5重量部より少ない場合には耐屈曲性及び耐衝撃強度増大効果が小さく、逆に100重量部より多い場合には剛性が低下する。
In the resin composition, a thermoplastic elastomer or an inorganic filler can be used as another compounding material.
Examples of the thermoplastic elastomer include styrene-based elastomers such as styrene-butadiene block copolymer and styrene-isoprene copolymer. Examples of the olefin-based elastomer include polyethylene, polybutene, polypentene, ethylene-vinyl acetate copolymer, ethylene-vinyl alcohol copolymer, ethylene-propylene rubber (EPR), and ethylene-propylene-diene rubber (EPDM). An elastomer obtained by grafting a polar group such as maleic anhydride, styrene, acrylonitrile, or the like to an olefin-based elastomer is more suitable.
The thermoplastic elastomer is not limited to one type, and a plurality of types may be blended. Flexibility and impact resistance can be increased by blending the thermoplastic elastomer. When the thermoplastic elastomer is compounded, the compounding amount is preferably 5 to 100 parts by weight based on 100 parts by weight of the polyamide resin. When the amount is less than 5 parts by weight, the effect of increasing the bending resistance and the impact strength is small, and when the amount is more than 100 parts by weight, the rigidity is reduced.
無機充填剤としては、マイカ、タルク、カオリン、シリカ、炭酸カルシウム、層状珪酸塩、硫酸バリウム、ガラスビーズ、ガラスフレーク、クレー、二硫化モリブデン、ワラストナイト、ポリリン酸カルシウム、アルミナ、酸化亜鉛、酸化チタン、酸化マグネシウム、窒化ホウ素、窒化アルミニウム、カーボン、カーボンナノチューブ、ガラス繊維、炭素繊維、セルロース繊維、アルミナ繊維等が挙げられる。無機充填材は、カップリング剤やその他の表面処理剤で処理されていてもよい。 As inorganic fillers, mica, talc, kaolin, silica, calcium carbonate, layered silicate, barium sulfate, glass beads, glass flakes, clay, molybdenum disulfide, wollastonite, calcium polyphosphate, alumina, zinc oxide, titanium oxide , Magnesium oxide, boron nitride, aluminum nitride, carbon, carbon nanotube, glass fiber, carbon fiber, cellulose fiber, alumina fiber and the like. The inorganic filler may be treated with a coupling agent or another surface treatment agent.
無機充填剤のサイズは、マクロサイズ(粒子径100μm〜10μm程度)、ミクロサイズ(粒子径10μm〜100nm程度)、ナノサイズ(粒子径100nm〜10nm程度)の何れのサイズも使用可能であるが、樹脂組成物への耐屈曲性を良好にするためには、無機充填剤がナノサイズで樹脂中に分散にていることが好ましい。無機充填剤の形状は、粒状、針状、繊維状、板状が挙げられ、何れも使用可能であるが、剛性増大効果が高い板状のものが好ましい。好ましい板状のナノサイズで分散可能な無機充填剤としてマイカ、層状ケイ酸塩、ワラストナイト等を挙げることができる。無機充填剤の配合により、剛性を高めることができる。無機充填剤を配合する場合の配合量は、ポリアミド樹脂100重量部に対して0.1〜10重量部が好ましい。0.1重量部より少ない場合には剛性増大効果が小さく、逆に10重量部より多い場合には耐屈曲性が劣る。 As for the size of the inorganic filler, any size of macro size (particle diameter of about 100 μm to 10 μm), micro size (particle diameter of about 10 μm to 100 nm), and nano size (particle diameter of about 100 nm to 10 nm) can be used, In order to improve the bending resistance of the resin composition, it is preferable that the inorganic filler is nano-sized and dispersed in the resin. Examples of the shape of the inorganic filler include a granular shape, a needle shape, a fiber shape, and a plate shape, and any of them can be used, but a plate shape having a high rigidity increasing effect is preferable. Preferred plate-like inorganic fillers that can be dispersed in nano size include mica, layered silicate, wollastonite and the like. The rigidity can be increased by blending the inorganic filler. When the inorganic filler is compounded, the amount is preferably 0.1 to 10 parts by weight based on 100 parts by weight of the polyamide resin. When the amount is less than 0.1 part by weight, the rigidity increasing effect is small, and when it is more than 10 parts by weight, the bending resistance is poor.
本発明の衣料用補強部材は、耐屈曲性が100回以上であり、ブラジャーのアンダーワイヤーなどして使用された場合、洗濯時等において大きな負荷が加わっても折れたりすることがない。なお、耐屈曲性は、幅5mm、厚み1.5mm、長さ150mmの短冊状の試験片を用い、片側端部Aと中央部をクランプで固定し、他側の固定されていない端部Bを、固定されている端部Aに触れるまで折り曲げ、その後に元に戻し、この折り曲げと戻すことを繰り返して破断するまでの折り曲げ回数を耐屈曲性の回数とすることで測定した。 The reinforcing member for clothing of the present invention has a bending resistance of 100 times or more, and when used as an underwire of a bra, does not break even when a large load is applied during washing or the like. The bending resistance was determined by using a strip-shaped test piece having a width of 5 mm, a thickness of 1.5 mm and a length of 150 mm, and fixing one end A and the center with a clamp, and the other end B which was not fixed. Was bent until it touched the fixed end A, and then returned to the original state. This bending and returning were repeated, and the number of times of bending until breaking was measured as the number of times of bending resistance.
衣料用補強部材10の製造は、公知の樹脂成形法によって衣料用補強部材の形状に成形した後、吸水工程を行い、その後に乾燥を行う。
樹脂成形法は、射出成形に限られず、押出成形、プレス成形等、樹脂成形に使用されている公知の成形方法が使用される。
吸水工程は、成形して得られた成形品を、30〜95℃の水又は温水に5〜100時間浸漬する、又は23℃、70%湿度で30日間放置することにより行う。
吸水工程後の乾燥は、所定温度状態(80℃以下)で放置したり、エアーを吹き付けたり、布で拭き取るなどして行う。乾燥時間は、特に限定はなく、衣料用補強部材の表面に付着している水分が無くなればよい。
前記吸水工程を行うことによって、衣料用補強部材の水分比率が2〜10%であり、飽和吸水率に対する成形品の水分率を20%〜90%にすることができる。これにより、洗濯時等の大きな負荷が加わっても折れたりすることがなくなり、衣料用補強部材として適するものとなる。
The manufacturing of the
The resin molding method is not limited to injection molding, and a known molding method used for resin molding such as extrusion molding or press molding is used.
The water absorption step is performed by immersing the molded article obtained by molding in water at 30 to 95 ° C. or warm water for 5 to 100 hours, or by leaving it at 23 ° C. and 70% humidity for 30 days.
Drying after the water absorption step is performed by leaving the apparatus at a predetermined temperature (80 ° C. or lower), blowing air, or wiping it with a cloth. The drying time is not particularly limited as long as there is no moisture attached to the surface of the clothing reinforcing member.
By performing the water absorption step, the moisture ratio of the clothing reinforcing member is 2 to 10%, and the moisture percentage of the molded article with respect to the saturated water absorption can be 20% to 90%. Thereby, even if a large load is applied at the time of washing or the like, it does not break, and it is suitable as a reinforcing member for clothing.
図2〜3に示す各実施例及び各比較例の成形品を作製し、得られた各実施例及び各比較例について物性を測定し、評価した。図2〜3におけるポリアミド6樹脂は、品名:ユニチカナイロンA1030JR、ユニチカ株式会社製、ポリアミド610樹脂は、品名:アミランCM2001、東レ株式会社製、ポリアミド66樹脂は、品名:ユニチカナイロンA125、ユニチカ株式会社製、熱可塑性エラストマーは、酸変性エチレン-α-オレフィンコポリマー、品名:タフマーMH7020、三井化学株式会社製であり、無機充填剤は、モンモリロナイト、板状、品名:Nanoclay Nanomer I.34TCN、SIGMA-ALDRICH製である。モンモリロナイトは、樹脂中においてナノサイズで分散されていた。
Molded articles of Examples and Comparative Examples shown in FIGS. 2 and 3 were prepared, and physical properties of the obtained Examples and Comparative Examples were measured and evaluated. The
図3における「POM」は、ポリアセタール樹脂、品名:ジュラコンSF−10、ポリプラスチックス株式会社製であり、「PPS」はポリフェニレンサルファイド樹脂、品名:トレリナA900、東レ株式会社製であり、「PEEK」は、ポリエーテルエーテルケトン樹脂、品名:Victrex151G、ビクトレックスジャパン株式会社製であり、「オレフィンエラストマー」は、品名:エンゲージ8407、ダウ・ケミカル製である。 In FIG. 3, “POM” is a polyacetal resin, product name: Duracon SF-10, manufactured by Polyplastics Co., Ltd., and “PPS” is a polyphenylene sulfide resin, product name: Torelina A900, manufactured by Toray Industries, Inc., “PEEK” Is a polyether ether ketone resin, product name: Victrex 151G, manufactured by Victrex Japan Co., Ltd. “Olefin elastomer” is product name: Engage 8407, manufactured by Dow Chemical.
各実施例の成形品は、射出成形によってISO20753(ISOタイプA多目的試験片)の試験片を作製した。なお、二種類以上の組成物からなる場合、二軸押出機(神戸製鋼製、KTX30)を用いて、溶融混練させ、ペレット状に加工して用いた。その後に成形品を80℃の水中に5時間浸漬する吸水工程を行った。
一方、各比較例は、各実施例と同様に射出成形によってISO20753(ISOタイプA多目的試験片)の試験片(成形品)を作製し、比較例6を除いてその後の吸水工程を行わなかった。
但し、樹脂組成物の飽和吸水率(水中、ISO62)の測定用には、射出成形によって、100mm×100mm×t2mmの平板状成形品を作製した。
また、耐屈曲性試験用には、射出成形によって、巾5mm、厚み1.5mm、長さ150mmの短冊状成形品を作製した。
For the molded article of each example, a test piece of ISO20753 (ISO type A multipurpose test piece) was prepared by injection molding. When two or more compositions were used, they were melt-kneaded using a twin-screw extruder (KTX30, manufactured by Kobe Steel) and processed into pellets. Thereafter, a water absorption step of immersing the molded article in water at 80 ° C. for 5 hours was performed.
On the other hand, in each comparative example, a test piece (molded product) of ISO20753 (ISO type A multipurpose test piece) was prepared by injection molding as in each example, and the subsequent water absorption step was not performed except for Comparative Example 6. .
However, in order to measure the saturated water absorption (in water, ISO62) of the resin composition, a flat molded product of 100 mm × 100 mm × t2 mm was prepared by injection molding.
For the bending resistance test, a strip-shaped molded product having a width of 5 mm, a thickness of 1.5 mm, and a length of 150 mm was produced by injection molding.
物性測定は、飽和吸水率(水中、ISO62)、成形品の水分率、耐屈曲性、熱成形性、曲げ弾性率、引張伸び率、シャルピー衝撃(常温、ノッチ付き)について行い、それらの結果から総合評価を行った。 Physical properties were measured for saturated water absorption (in water, ISO62), moisture content of molded products, flex resistance, thermoformability, flexural modulus, tensile elongation, and Charpy impact (normal temperature, with notch). A comprehensive evaluation was performed.
飽和吸水率(水中、ISO62)は、ISO62 A法に規定されている条件に基づいて測定した。
成形品の水分率は、乾燥減量法『水分率=(乾燥前サンプル重量−乾燥後サンプル重量)/乾燥前サンプル重量×100』に基づいて算出した。乾燥条件は、110℃ x 24時間である。
水分比率は、[水分比率=成形品の水分率/飽和吸水率×100]の式で算出した。
耐屈曲性は、洗濯時等の際の破損し難さを判断するための物性であり、幅5mm、厚み1.5mm、長さ150mmの短冊状の試験片を用い、片側端部Aと中央部をクランプで固定し、他側の固定されていない端部Bを固定されている端部Aに触れるまで折り曲げ、その後に元に戻し、この折り曲げと戻すことを繰り返して破断するまでの折り曲げ回数を耐屈曲性の回数とした。なお、300回を超えても破断にならない場合は、300回を超えた時点で測定を終了し、測定結果を「300回以上」とした。
The saturated water absorption (in water, ISO62) was measured based on the conditions specified in the ISO62A method.
The moisture content of the molded article was calculated based on the drying loss method “moisture content = (sample weight before drying−sample weight after drying) / sample weight before drying × 100”. The drying condition is 110 ° C. for 24 hours.
The water ratio was calculated by the formula [water ratio = water ratio of molded article / saturated water absorption × 100].
The bending resistance is a property for judging the difficulty of breakage at the time of washing or the like. A strip-shaped test piece having a width of 5 mm, a thickness of 1.5 mm, and a length of 150 mm is used. Part is fixed with a clamp, and the other end B, which is not fixed, is bent until it touches the fixed end A, and then returned to the original position. Is the number of flex resistances. In addition, when it did not break even after exceeding 300 times, the measurement was terminated when the number of times exceeded 300 times, and the measurement result was set to “300 times or more”.
熱成形性は、熱成形のし易さを判断するための物性であり、185℃×3分間の熱プレス成形後に、大きな変形や溶融が見られない場合に「OK」、大きな変形や溶融が見られる場合に「NG」とした。
曲げ弾性率は、形状保持性を判断するための物性であり、ISO178に基づいて測定した。
引張伸び率は、洗濯時や使用時等の際の破損し難さを判断するための物性であり、ISO527に基づいて測定した。
シャルピー衝撃(常温、ノッチ付き)は、洗濯時や使用時等の際の破損し難さを判断するための物性であり、ISO179に基づいて測定した。
The thermoformability is a property for judging the ease of thermoforming. When no large deformation or melting is observed after hot press molding at 185 ° C. for 3 minutes, “OK” indicates that large deformation or melting occurs. "NG" when it was seen.
The flexural modulus is a physical property for judging shape retention, and was measured based on ISO178.
The tensile elongation is a physical property for judging the difficulty of breakage during washing or use, and was measured based on ISO527.
The Charpy impact (normal temperature, with a notch) is a physical property for judging the difficulty of breakage during washing or use, and was measured based on ISO179.
総合評価は、水分比率が20%以上90%以下(成形品の水分率が飽和吸水率の20%以上90%以下)、耐屈曲性が100回以上、熱成形性が「OK」、引張伸び率が70%より大、シャルピー衝撃(常温、ノッチ付き)が30KJ/m2以上の要件を全て満たす場合に「〇」とし、それらの項目の一つでも要件を満たさない場合に「×」とした。 The overall evaluation was that the moisture ratio was 20% or more and 90% or less (the moisture content of the molded product was 20% or more and 90% or less of the saturated water absorption), the bending resistance was 100 times or more, the thermoformability was "OK", and the tensile elongation. If the rate is greater than 70% and the Charpy impact (normal temperature, notched) meets all the requirements of 30 KJ / m 2 or more, it is marked with “〇”. If even one of those items does not meet the requirements, it is marked with “×”. did.
実施例1は、ポリアミド6のみからなる飽和吸水率(水中、ISO62)10%の樹脂組成物を射出成形し、吸水工程を行った例である。実施例1は、成形後の成形品の水分率が3.0%、飽和吸水率に対する成形品の水分率の割合である水分比率が30.0%、耐屈曲性300回以上、熱成形性OK、曲げ弾性率1000MPa、引張伸び率150%、シャルピー衝撃31KJ/m2であり、総合評価「〇」であった。
Example 1 is an example in which a resin composition containing
実施例2は、ポリアミド610のみからなる飽和吸水率(水中、ISO62)8%の樹脂組成物を射出成形し、吸水工程を行った例である。実施例2は、成形品の水分率が3.0%、飽和吸水率に対する成形品の水分率の割合である水分比率が37.5%、耐屈曲性300回以上、熱成形性OK、曲げ弾性率900MPa、引張伸び率75%、シャルピー衝撃55KJ/m2であり、総合評価「〇」であった。 Example 2 is an example in which a resin composition consisting of only polyamide 610 and having a saturated water absorption of 8% (in water, ISO 62) was injection-molded, and a water absorption step was performed. In Example 2, the moisture content of the molded product was 3.0%, the moisture ratio which was the ratio of the moisture content of the molded product to the saturated water absorption was 37.5%, the bending resistance was 300 times or more, the thermoformability was OK, and the bending was OK. The elastic modulus was 900 MPa, the tensile elongation was 75%, the Charpy impact was 55 KJ / m 2 , and the overall evaluation was “〇”.
実施例3は、ポリアミド6の100重量部に熱可塑性エラストマーを15重量部配合した飽和吸水率(水中、ISO62)9%の樹脂組成物を射出成形し、吸水工程を行った例である。実施例3は、成形品の水分率が2.8%、飽和吸水率に対する成形品の水分率の割合である水分比率が31.1%、耐屈曲性300回以上、熱成形性OK、曲げ弾性率800MPa、引張伸び率90%、シャルピー衝撃66KJ/m2であり、総合評価「〇」であった。
Example 3 is an example in which a resin composition having a saturated water absorption of 9% (in water, ISO 62) in which 15 parts by weight of a thermoplastic elastomer was blended with 100 parts by weight of
実施例4は、ポリアミド66の100重量部に熱可塑性エラストマーを15重量部配合した飽和吸水率(水中、ISO62)7%の樹脂組成物を射出成形し、吸水工程を行った例である。実施例4は、成形品の水分率が2.5%、飽和吸水率に対する成形品の水分率の割合である水分比率が35.7%、耐屈曲性300回以上、熱成形性OK、曲げ弾性率1100MPa、引張伸び率100%、シャルピー衝撃40KJ/m2であり、総合評価「〇」であった。
Example 4 is an example in which a resin composition having a saturated water absorption (ISO62 in water, 7%) of 15% by weight of a thermoplastic elastomer mixed with 100 parts by weight of
実施例5は、ポリアミド6の100重量部に熱可塑性エラストマーを20重量部と無機充填剤2重量部配合した飽和吸水率(水中、ISO62)9%の樹脂組成物を射出成形し、吸水工程を行った例である。実施例5は、成形品の水分率が2.5%、飽和吸水率に対する成形品の水分率の割合である水分比率が27.8%、耐屈曲性300回以上、熱成形性OK、曲げ弾性率1400MPa、引張伸び率100%、シャルピー衝撃が90KJ/m2であり、総合評価「〇」であった。実施例5は、無機充填剤を熱可塑性エラストマーと共に配合したことにより、曲げ弾性率が1400MPa、シャルピー衝撃が90KJ/m2となり、実施例1〜5の中で最も良好である。
In Example 5, a resin composition having a saturated water absorption of 9% (in water, ISO 62) in which 20 parts by weight of a thermoplastic elastomer and 2 parts by weight of an inorganic filler were mixed with 100 parts by weight of
比較例1は、実施例1において吸水工程を行わなかった例である。比較例1は、成形品の水分率が0.2%、飽和吸水率に対する成形品の水分率の割合である水分比率が2.0%、耐屈曲性40回、熱成形性OK、曲げ弾性率2800MPa、引張伸び率30%、シャルピー衝撃4KJ/m2であり、総合評価「×」であった。比較例1は、成形品の水分率が0.2%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が2.0%と低いため、実施例1と比べると、耐屈曲性と引張伸び率及びシャルピー衝撃に劣っている。 Comparative Example 1 is an example in which the water absorption step in Example 1 was not performed. In Comparative Example 1, the moisture content of the molded product was 0.2%, the moisture ratio which was the ratio of the moisture content of the molded product to the saturated water absorption was 2.0%, the bending resistance was 40 times, the thermoformability was OK, and the bending elasticity was good. Rate was 2800 MPa, tensile elongation was 30%, and Charpy impact was 4 KJ / m 2 , and the overall evaluation was “×”. In Comparative Example 1, the molded article had a low moisture content of 0.2%, and the moisture ratio, which is the ratio of the moisture content of the molded article to the saturated water absorption, was as low as 2.0%. Poor flexibility, tensile elongation and Charpy impact.
比較例2は、実施例2において吸水工程を行わなかった例である。比較例2は、成形品の水分率が0.2%、飽和吸水率に対する成形品の水分率の割合である水分比率が2.5%、耐屈曲性220回、熱成形性OK、曲げ弾性率2000MPa、引張伸び率60%、シャルピー衝撃40KJ/m2であり、総合評価「×」であった。比較例2は、成形品の水分率が0.2%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が2.5%と低いため、実施例2と比べると、耐屈曲性と引張伸び率及びシャルピー衝撃に劣っている。 Comparative Example 2 is an example in which the water absorption step in Example 2 was not performed. In Comparative Example 2, the molded article had a moisture percentage of 0.2%, the moisture percentage, which is the ratio of the moisture percentage of the molded article to the saturated water absorption, was 2.5%, the bending resistance was 220 times, the thermoformability was OK, and the bending elasticity was good. The rate was 2000 MPa, the tensile elongation was 60%, the Charpy impact was 40 KJ / m 2 , and the overall evaluation was “×”. In Comparative Example 2, the moisture resistance of the molded article was as low as 0.2%, and the moisture ratio, which is the ratio of the moisture percentage of the molded article to the saturated water absorption, was as low as 2.5%. Poor flexibility, tensile elongation and Charpy impact.
比較例3は、実施例3において吸水工程を行わなかった例である。比較例3は、成形品の水分率が0.2%、飽和吸水率に対する成形品の水分率の割合である水分比率が2.2%、耐屈曲性235回、熱成形性OK、曲げ弾性率2000MPa、引張伸び率70%、シャルピー衝撃17KJ/m2であり、総合評価「×」であった。比較例3は、成形品の水分率が0.2%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が2.2%と低いため、実施例3と比べると、耐屈曲性と引張伸び率及びシャルピー衝撃に劣っている。 Comparative Example 3 is an example in which the water absorption step was not performed in Example 3. In Comparative Example 3, the moisture content of the molded product was 0.2%, the moisture ratio which was the ratio of the moisture content of the molded product to the saturated water absorption was 2.2%, the bending resistance was 235 times, the thermoformability was OK, and the bending elasticity was good. The rate was 2000 MPa, the tensile elongation was 70%, the Charpy impact was 17 KJ / m 2 , and the overall evaluation was “×”. In Comparative Example 3, since the moisture percentage of the molded article was as low as 0.2%, and the moisture ratio, which is the ratio of the moisture percentage of the molded article to the saturated water absorption, was as low as 2.2%, the resistance was lower than that of Example 3. Poor flexibility, tensile elongation and Charpy impact.
比較例4は、実施例4において吸水工程を行わなかった例である。比較例4は、成形品の水分率が0.2%、飽和吸水率に対する成形品の水分率の割合である水分比率が2.9%、耐屈曲性245回、熱成形性OK、曲げ弾性率2000MPa、引張伸び率45%、シャルピー衝撃26KJ/m2であり、総合評価「×」であった。比較例4は、成形品の水分率が0.2%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が2.9%と低いため、実施例4と比べると、耐屈曲性と引張伸び率及びシャルピー衝撃に劣っている。 Comparative Example 4 is an example in which the water absorption step in Example 4 was not performed. In Comparative Example 4, the moisture content of the molded product was 0.2%, the moisture ratio, which is the ratio of the moisture content of the molded product to the saturated water absorption, was 2.9%, the bending resistance was 245 times, the thermoformability was OK, and the bending elasticity was good. The rate was 2,000 MPa, the tensile elongation was 45%, the Charpy impact was 26 KJ / m 2 , and the overall evaluation was “x”. In Comparative Example 4, the moisture content of the molded product was as low as 0.2%, and the moisture ratio, which is the ratio of the moisture content of the molded product to the saturated water absorption, was as low as 2.9%. Poor flexibility, tensile elongation and Charpy impact.
比較例5は、実施例5において吸水工程を行わなかった例である。比較例5は、成形品の水分率が0.2%、飽和吸水率に対する成形品の水分率の割合である水分比率が2.2%、耐屈曲性230回、熱成形性OK、曲げ弾性率2100MPa、引張伸び率70%、シャルピー衝撃60KJ/m2であり、総合評価「×」であった。比較例5は、成形品の水分率が0.2%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が2.2%と低いため、実施例5と比べると、耐屈曲性と引張伸び率及びシャルピー衝撃に劣っている。 Comparative Example 5 is an example in which the water absorption step in Example 5 was not performed. In Comparative Example 5, the moisture content of the molded product was 0.2%, the moisture ratio which was the ratio of the moisture content of the molded product to the saturated water absorption was 2.2%, the bending resistance was 230 times, the thermoformability was OK, and the bending elasticity was good. Rate was 2100 MPa, tensile elongation was 70%, Charpy impact was 60 KJ / m 2 , and the overall evaluation was “×”. In Comparative Example 5, since the moisture content of the molded product was as low as 0.2% and the moisture ratio, which is the ratio of the moisture content of the molded product to the saturated water absorption, was as low as 2.2%, the comparative example 5 had higher moisture resistance. Poor flexibility, tensile elongation and Charpy impact.
比較例6は、ポリアミド12のみからなる飽和吸水率(水中、ISO62)1.5%の樹脂組成物から射出成形し、吸水工程を行なった例である。比較例6は、成形品の水分率が0.2%、飽和吸水率に対する成形品の水分率の割合である水分比率が13.3%、耐屈曲性95回、熱成形性NG、曲げ弾性率1200MPa、引張伸び率50%、シャルピー衝撃7KJ/m2であり、総合評価「×」であった。比較例6は、ポリアミド12のみからなり、飽和吸水率(水中、ISO62)が1.5%の樹脂組成物から成形し、成形品の水分率が0.2%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が13.3%と低いため、耐屈曲性と引張伸び率及びシャルピー衝撃に劣っており、洗濯時や使用時等の際に破損するおそれがある。
Comparative Example 6 is an example in which a resin composition composed of
比較例7は、耐衝撃性が付与されたPOMからなる飽和吸水率(水中、ISO62)0.3%の樹脂組成物から射出成形し、吸水工程を行なわなかった例である。比較例7は、成形品の水分率が0.05%、飽和吸水率に対する成形品の水分率の割合である水分比率が16.7%、耐屈曲性80回、熱成形性NG、曲げ弾性率1800MPa、引張伸び率60%、シャルピー衝撃12KJ/m2であり、総合評価「×」であった。比較例7は、耐衝撃性が付与されたPOMからなり、飽和吸水率(水中、ISO62)が0.3%の樹脂組成物から成形し、成形品の水分率が0.05%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が16.7%であった。耐屈曲性と引張伸び率及びシャルピー衝撃に劣っており、洗濯時や使用時等の際に破損するおそれがある。 Comparative Example 7 is an example in which injection molding was performed from a resin composition having a saturated water absorption of 0.3% (in water, ISO 62) made of POM to which impact resistance was imparted, and the water absorption step was not performed. In Comparative Example 7, the moisture content of the molded product was 0.05%, the moisture ratio, which is the ratio of the moisture content of the molded product to the saturated water absorption, was 16.7%, the bending resistance was 80 times, the thermoformability was NG, and the bending elasticity was low. Rate of 1800 MPa, tensile elongation of 60%, Charpy impact of 12 KJ / m 2 , and the overall evaluation was “x”. Comparative Example 7 was formed from a resin composition having impact resistance and having a saturated water absorption (in water, ISO62) of 0.3%, and a molded product having a low moisture content of 0.05%. The water ratio, which is the ratio of the water content of the molded article to the saturated water absorption, was 16.7%. It is inferior in flex resistance, tensile elongation and Charpy impact, and may be damaged during washing or use.
比較例8は、PPSのみからなる飽和吸水率(水中、ISO62)0.05%の樹脂組成物から射出成形し、吸水工程を行なわなかった例である。比較例8は、成形品の水分率が0.02%、飽和吸水率に対する成形品の水分率の割合である水分比率が40.0%、耐屈曲性10回、熱成形性OK、曲げ弾性率3800MPa、引張伸び率12%、シャルピー衝撃4KJ/m2であり、総合評価「×」であった。比較例8は、PPSのみからなり、飽和吸水率(水中、ISO62)が0.05%の樹脂組成物から成形し、成形品の水分率が0.02%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が40.0%であった。耐屈曲性と引張伸び率及びシャルピー衝撃に劣っており、洗濯時や使用時等の際に破損するおそれがある。 Comparative Example 8 is an example in which a resin composition composed of only PPS and having a saturated water absorption of 0.05% (in water, ISO 62) was injection-molded, and the water absorption step was not performed. In Comparative Example 8, the moisture content of the molded product was 0.02%, the moisture ratio, which is the ratio of the moisture content of the molded product to the saturated water absorption, was 40.0%, the bending resistance was 10 times, the thermoformability was OK, and the bending elasticity was good. Rate was 3800 MPa, tensile elongation was 12%, Charpy impact was 4 KJ / m 2 , and the overall evaluation was “×”. Comparative Example 8 was molded from a resin composition consisting of only PPS and having a saturated water absorption (in water, ISO 62) of 0.05%, and the molded article had a low water content of 0.02%, and was a molded article with respect to the saturated water absorption. Was 40.0%. It is inferior in flex resistance, tensile elongation and Charpy impact, and may be damaged during washing or use.
比較例9は、PEEKのみからなる飽和吸水率(水中、ISO62)0.4%の樹脂組成物から射出成形し、吸水工程を行なわなかった例である。比較例9は、成形品の水分率が0.02%、飽和吸水率に対する成形品の水分率の割合である水分比率が5.0%、耐屈曲性30回、熱成形性OK、曲げ弾性率:4300MPa、引張伸び率25%以上、シャルピー衝撃4KJ/m2であり、総合評価「×」であった。比較例9は、PEEKのみからなり、飽和吸水率(水中、ISO62)が0.4%の樹脂組成物から成形し、成形品の水分率が0.02%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が5.0%であった。耐屈曲性と引張伸び率及びシャルピー衝撃に劣っており、衣料用補強部材としては適さないものである。
Comparative Example 9 is an example in which a resin composition composed of only PEEK and having a saturated water absorption of 0.4% (in water, ISO 62) was injection molded, and the water absorption step was not performed. In Comparative Example 9, the moisture content of the molded product was 0.02%, the moisture ratio, which is the ratio of the moisture content of the molded product to the saturated water absorption, was 5.0%, the bending resistance was 30 times, the thermoformability was OK, and the bending elasticity was good. Rate: 4300 MPa,
比較例10は、オレフィンエラストマーのみからなる飽和吸水率(水中、ISO62)0.1%の樹脂組成物から射出成形し、吸水工程を行なわなかった例である。比較例9は、成形品の水分率が0.03%、飽和吸水率に対する成形品の水分率の割合である水分比率が30.0%、耐屈曲性300回以上、熱成形性NG、曲げ弾性率:100MPa以下、引張伸び率300%以上、シャルピー衝撃:非破壊であり、総合評価「×」であった。比較例9は、オレフィン系エラストマーのみからなり、飽和吸水率(水中、ISO62)が0.1%の樹脂組成物から成形し、成形品の水分率が0.02%と低く、飽和吸水率に対する成形品の水分率の割合である水分比率が30.0%であった。熱成形性に劣り、かつ曲げ弾性率が100MPa以下と剛性が低く、衣料用補強部材としては適さないものである。 Comparative Example 10 is an example in which a resin composition composed of only an olefin elastomer and having a saturated water absorption of 0.1% in water (ISO 62 in water) was injection-molded, and the water absorption step was not performed. In Comparative Example 9, the molded article had a moisture percentage of 0.03%, the moisture percentage, which was the ratio of the moisture percentage of the molded article to the saturated water absorption, was 30.0%, the bending resistance was 300 times or more, thermoformability NG, bending Modulus of elasticity: 100 MPa or less, tensile elongation of 300% or more, Charpy impact: non-destructive, and the overall evaluation was “×”. Comparative Example 9 was made of a resin composition containing only an olefin-based elastomer and having a saturated water absorption (in water, ISO 62) of 0.1%, and the molded product had a low water content of 0.02%, which was lower than the saturated water absorption. The water content, which is the ratio of the water content of the molded article, was 30.0%. It is inferior in thermoformability and low in rigidity with a flexural modulus of 100 MPa or less, and is not suitable as a clothing reinforcing member.
このように、本発明の衣料用補強部材は、耐屈曲性に優れ、引張伸び率及びシャルピー衝撃が良好であり、衣料の洗濯時等において大きな負荷が加わっても折れたりすることがない。また、本発明の衣料用補強部材は、射出成形、押出成形、プレス成形等、樹脂成形に使用されている公知の成形方法を用いて製造することができるため、製造が容易である。 As described above, the clothing reinforcing member of the present invention has excellent bending resistance, good tensile elongation, and good Charpy impact, and does not break even when a large load is applied when the clothing is washed. In addition, the reinforcing member for clothing of the present invention can be manufactured by using a known molding method used for resin molding, such as injection molding, extrusion molding, press molding, etc., and is therefore easy to produce.
10:衣料用補強部材 10: Reinforcing member for clothing
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| JP2001131806A (en) * | 1999-10-29 | 2001-05-15 | Starlite Co Ltd | Cup wire |
| WO2012046629A1 (en) * | 2010-10-08 | 2012-04-12 | 三菱瓦斯化学株式会社 | Molded polyamide resin article |
| JP2017043754A (en) * | 2015-08-28 | 2017-03-02 | 東レ株式会社 | Resin composition and molded product thereof |
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|---|---|---|---|---|
| JPS6468816A (en) * | 1987-09-10 | 1989-03-14 | Nissan Motor | Method for controlling dimensions of hygroscopic resin parts |
| JP2001131806A (en) * | 1999-10-29 | 2001-05-15 | Starlite Co Ltd | Cup wire |
| WO2012046629A1 (en) * | 2010-10-08 | 2012-04-12 | 三菱瓦斯化学株式会社 | Molded polyamide resin article |
| JP2017043754A (en) * | 2015-08-28 | 2017-03-02 | 東レ株式会社 | Resin composition and molded product thereof |
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