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JP2019127669A - Stretchable fabric excellent in frictional abrasion resistance and snag resistance - Google Patents

Stretchable fabric excellent in frictional abrasion resistance and snag resistance Download PDF

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JP2019127669A
JP2019127669A JP2018010382A JP2018010382A JP2019127669A JP 2019127669 A JP2019127669 A JP 2019127669A JP 2018010382 A JP2018010382 A JP 2018010382A JP 2018010382 A JP2018010382 A JP 2018010382A JP 2019127669 A JP2019127669 A JP 2019127669A
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yarn
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JP6310626B1 (en
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小野寺 忠人
Tadahito Onodera
忠人 小野寺
肇 刀根
Hajime Tone
肇 刀根
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Toyobo STC Co Ltd
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Abstract

【課題】耐スナッグ性及び耐擦過摩耗性に優れ、高引裂強力及び柔らかな風合を有する織物の提供。【解決手段】経及び緯方向の総繊度が50〜800dtexである柄糸と総繊度が50〜800dtexである地糸を有する織物であって、経方向及び緯方向の少なくとも一方の柄糸が、引張強度10cN/dtex以上の高強力繊維及び総繊度33〜156dtexの弾性繊維を含有し、且つ、前記高強力繊維の含有率が70〜95%である高強力糸であり、経方向及び緯方向のうち、前記高強力糸が含まれる方向と同一方向の地糸は、合成繊維及び弾性繊維を含む伸縮性合繊糸であり、(i)高強力繊維のカバリング係数が10000〜21000、(ii)(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比が0.4〜2.0、(iii)(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比が0.8〜4.0を満たす織物。【選択図】図3PROBLEM TO BE SOLVED: To provide a woven fabric having excellent snag resistance and abrasion resistance, high tear strength and a soft texture. SOLUTION: The fabric has a pattern yarn having a total fineness of 50 to 800 dtex in the warp and weft directions and a ground yarn having a total fineness of 50 to 800 dtex, and at least one of the pattern yarns in the warp direction and the weft direction is. It is a high-strength yarn containing high-strength fibers having a tensile strength of 10 cN / dtex or more and elastic fibers having a total fineness of 33 to 156 dtex, and the content of the high-strength fibers is 70 to 95%, and is a warp direction and a weft direction. Among them, the ground yarn in the same direction as the direction in which the high-strength yarn is contained is an elastic synthetic fiber yarn containing synthetic fiber and elastic fiber, and (i) the covering coefficient of the high-strength fiber is 1000 to 21000, (ii). The fineness ratio expressed by (maximum total fineness of pattern yarn) / (minimum total fineness of ground yarn) is 0.4 to 2.0, (iii) (total fineness of elastic fibers in high-strength yarn) / (expansion and contraction). A woven fabric having a fineness ratio of 0.8 to 4.0, which is expressed by the total fineness of elastic fibers in synthetic synthetic fibers. [Selection diagram] Fig. 3

Description

本発明は、耐擦過摩耗性及び耐スナッグ性に優れた伸縮性織物に関する。   The present invention relates to an elastic fabric excellent in abrasion resistance and snag resistance.

快適なスポーツウェアやアウトドアウェアには、高引裂強力、耐擦過性、軽量性、伸縮性等が求められる。一般に、伸縮性と高引裂強力を備える織物には、芯糸に弾性糸、鞘糸にポリアミド繊維のようなマルチフィラメント糸をカバリングした複合糸が使用される。   Comfortable sportswear and outdoor wear are required to have high tear strength, scratch resistance, light weight, stretchability, and the like. Generally, in a fabric having elasticity and high tear strength, a composite yarn in which an elastic yarn is used as a core yarn and a multifilament yarn such as a polyamide fiber is used as a sheath yarn is used.

例えば、特許文献1には、こうした弾性糸とマルチフィラメント糸との複合糸を改良した発明として、芯糸に弾性繊維を用い、鞘糸に耐熱高機能フィラメント糸を用いてなる被覆糸で構成されていることを特徴とする伸縮性及び機械的強度に優れた防護衣料が開示されている。   For example, in Patent Document 1, as an invention in which such a composite yarn of an elastic yarn and a multifilament yarn is improved, an elastic fiber is used for the core yarn, and a sheathed yarn is composed of a coated yarn using heat resistant high function filament yarn A protective garment excellent in stretchability and mechanical strength is disclosed.

また特許文献2には、芯糸にスパンデックス繊維、鞘糸に合成繊維を用いた撚係数6500から12000のシングルカバリング糸をタテ糸およびヨコ糸に用いた織物において、タテおよびヨコ方向の伸長率がそれぞれ50%以上であることを特徴とする高伸度のストレッチ織物が開示されている。   Further, Patent Document 2 discloses that in a woven fabric in which a single covering yarn having a twisting coefficient of 6500 to 12000 using a spandex fiber as a core yarn and a synthetic fiber as a sheath yarn is used as a warp yarn and a horizontal yarn, the elongation ratio in the vertical and horizontal directions is as follows. A high-stretch stretch fabric characterized by 50% or more of each is disclosed.

特開2003−193314号公報Japanese Patent Application Publication No. 2003-193314 特開2010−138496号公報JP 2010-138396 A

昨今では、スポーツウェアやアウトドアウェア用の織物に対し、高伸縮性や高引裂強力だけでなく、擦過に対する高い耐性が求められるようになってきた。しかしながら、特許文献1〜2に示される生地では、伸縮性は良好なものの、耐スナッグ性が不十分であった。また、例えば、岩のような鋭利な物体との間で強い擦過が生じた場合に、特許文献1〜2の生地は容易に破壊されてしまうため、耐擦過摩耗性は到底満足できるものではなかった。   Recently, not only high stretchability and high tear strength, but also high resistance to abrasion has come to be required for textiles for sportswear and outdoor wear. However, the fabrics disclosed in Patent Documents 1 and 2 have good stretchability but have insufficient snag resistance. Further, for example, when strong rubbing occurs between sharp objects such as rocks, the fabrics of Patent Documents 1 and 2 are easily destroyed, so the abrasion wear resistance is not completely satisfactory. The

こうした状況下、本発明の課題は、耐スナッグ性及び耐擦過摩耗性に優れ、高引裂強力及び柔らかな風合を有する織物を提供することにある。   Under such circumstances, an object of the present invention is to provide a fabric which is excellent in snag resistance and abrasion resistance, and has high tear strength and soft feeling.

本発明者らは、前記課題を解決するために鋭意研究を重ねた結果、(i)高強力繊維のカバリング係数、(ii)(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比、及び(iii)(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比を、それぞれ適切にコントロールすることによって、上記課題が解決されることを見出し、本発明を完成した。   As a result of intensive studies to solve the above problems, the present inventors have (i) a covering coefficient of a high-strength fiber, (ii) (maximum total fineness of the pattern yarn) / (minimum total fineness of the ground yarn). The denier ratio represented by and (iii) (total denier of elastic fiber in high strength yarn) / (total denier of elastic fiber in stretch synthetic fiber) is appropriately controlled. As a result, the present inventors have found that the above-mentioned problems can be solved and completed the present invention.

すなわち本発明に係る織物は、以下の点に要旨を有する。
[1] 経方向及び緯方向が、それぞれ、総繊度が50〜800dtexである柄糸と総繊度が50〜800dtexである地糸を有する織物であって、
経方向及び緯方向の少なくとも一方の柄糸が、引張強度10cN/dtex以上の高強力繊維及び総繊度33〜156dtexの弾性繊維を含有し、且つ、前記高強力繊維の含有率が70〜95%である高強力糸であり、
経方向及び緯方向のうち、前記高強力糸が含まれる方向と同一方向の地糸は、合成繊維及び弾性繊維を含む伸縮性合繊糸であり、
下記(i)〜(iii)を満たす織物。
(i)高強力繊維のカバリング係数が10000〜21000である。
(ii)(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比が0.4〜2.0である。
(iii)(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比が0.8〜4.0である。
[2] 前記高強力糸が、前記弾性繊維を芯部とし、前記高強力繊維を鞘部とする、芯鞘構造のカバリング糸である[1]に記載の織物。
[3] 前記高強力繊維が撚糸である[2]に記載の織物。
[4] 前記高強力繊維の撚係数が1000〜8000である[3]に記載の織物。
[5] 前記高強力繊維の撚方向と、前記カバリング糸における高強力繊維のカバリング方向が同じである[3]または[4]に記載の織物。
[6] 前記高強力繊維がポリエチレン繊維である[1]〜[5]のいずれか1項に記載の織物。
[7] 前記伸縮性合繊糸が、前記弾性繊維を芯部とし、前記合成繊維を鞘部とする、芯鞘構造のカバリング糸または前記合成繊維と前記弾性繊維をエア交絡した後に施撚した複合糸である[1]〜[6]のいずれか1項に記載の織物。
[8] 前記合成繊維がナイロン6繊維またはナイロン66繊維である[1]〜[7]のいずれか1項に記載の織物。
[9] 前記合成繊維が、捲縮糸である[1]〜[8]のいずれか1項に記載の織物。
[10] 格子状織柄のサイズが、経方向及び緯方向それぞれにおいて、10mm以下である[1]〜[9]のいずれか1項に記載の織物。
[11] JIS L 1058 D−3法に基づき測定されるスナッグの等級が4級以上であり、
JIS L 1096 8.17D法(ペンジュラム法)に基づく引裂強力が40〜150Nであり、
JIS L 1096 8.16B法(定荷重法)に基づく伸び率が12〜60%である[1]〜[10]のいずれか1項に記載の織物。
[12] 耐擦過摩耗性が3級以上である[1]〜[11]のいずれか1項に記載の織物。
[13] [1]〜[12]のいずれか1項に記載の織物を含む繊維製品。
That is, the woven fabric according to the present invention is summarized in the following points.
[1] A woven fabric having a patterned yarn having a total fineness of 50 to 800 dtex and a ground yarn having a total fineness of 50 to 800 dtex, respectively, in the warp direction and the weft direction,
At least one of the warp yarn and the weft yarn has a high strength fiber having a tensile strength of 10 cN / dtex or more and an elastic fiber having a total fineness of 33 to 156 dtex, and the content of the high strength fiber is 70 to 95%. Is a high strength yarn that is
Of the warp direction and the weft direction, the ground yarn in the same direction as the direction in which the high-strength yarn is contained is a stretchable synthetic yarn containing synthetic fibers and elastic fibers,
Textile which fulfills the following (i)-(iii).
(I) The covering coefficient of the high strength fiber is 10,000 to 21,000.
(Ii) The fineness ratio represented by (maximum total fineness of handle yarn) / (minimum total fineness of ground yarn) is 0.4 to 2.0.
(Iii) The fineness ratio represented by (total fineness of elastic fiber in high strength yarn) / (total fineness of elastic fiber in stretchable synthetic fiber) is 0.8 to 4.0.
[2] The woven fabric according to [1], which is a covering yarn having a core-sheath structure, wherein the high strength yarn has the elastic fiber as a core and the high strength fiber as a sheath.
[3] The woven fabric according to [2], wherein the high strength fiber is a twisted yarn.
[4] The woven fabric according to [3], wherein a twisting coefficient of the high strength fiber is 1000 to 8000.
[5] The woven fabric according to [3] or [4], wherein the twist direction of the high strength fiber and the covering direction of the high strength fiber in the covering yarn are the same.
[6] The woven fabric according to any one of [1] to [5], wherein the high strength fiber is a polyethylene fiber.
[7] A composite comprising a covering yarn having a core-sheath structure or the synthetic fiber and the elastic fiber after air entangling, wherein the elastic synthetic fiber comprises the elastic fiber as a core and the synthetic fiber as a sheath. The woven fabric according to any one of [1] to [6], which is a yarn.
[8] The woven fabric according to any one of [1] to [7], wherein the synthetic fiber is nylon 6 fiber or nylon 66 fiber.
[9] The woven fabric according to any one of [1] to [8], wherein the synthetic fiber is a crimped yarn.
[10] The woven fabric according to any one of [1] to [9], wherein the size of the lattice-like woven pattern is 10 mm or less in each of the warp direction and the weft direction.
[11] The snag grade measured based on the JIS L 1058 D-3 method is grade 4 or higher,
Tear strength based on JIS L 1096 8.17D method (Pendulum method) is 40 to 150 N,
The woven fabric according to any one of [1] to [10], which has an elongation of 12 to 60% based on the JIS L 1096 8.16B method (constant load method).
[12] The woven fabric according to any one of [1] to [11], wherein the abrasion resistance is grade 3 or higher.
[13] A textile product comprising the woven fabric according to any one of [1] to [12].

本発明によれば、耐スナッグ性及び耐擦過摩耗性に優れ、高引裂強力及び柔らかな風合を有する織物が提供される。   According to the present invention, there is provided a fabric which is excellent in snag resistance and abrasion resistance, and has high tear strength and soft feeling.

カバリング係数が不適切な高強力糸の緊張状態を示す写真である。It is a photograph which shows the tension state of the high strength yarn whose covering coefficient is inadequate. カバリング係数が不適切な高強力糸の弛緩状態を示す写真である。It is a photograph which shows the relaxation state of the high strength yarn whose covering coefficient is inadequate. 図1−1に示す糸を使用した織物の耐スナッグ性評価後の写真である。It is a photograph after snug-proof evaluation of textiles using the thread shown in Drawing 1-1. 図1−1に示す糸を使用した織物の耐擦過摩耗性評価後の写真である。It is the photograph after abrasion resistance evaluation of the textile fabric using the thread | yarn shown in FIG. 1-1. カバリング係数が適切な高強力糸の緊張状態を示す写真である。It is a photograph in which a covering coefficient shows the tension state of a suitable high strength yarn. カバリング係数が適切な高強力糸の弛緩状態を示す写真である。It is a photograph showing the relaxed state of a high strength yarn with an appropriate covering coefficient. 格子状織柄のサイズを示す説明図である。It is explanatory drawing which shows the size of a lattice-like woven pattern. 実施例8で採用したドビー織の組織図である。FIG. 10 is a structural diagram of a dobby weave employed in Example 8. ループ状欠点の説明図である。It is explanatory drawing of a loop-like fault.

本発明に係る織物は、経方向及び緯方向が、それぞれ、総繊度が50〜800dtexである柄糸と総繊度が50〜800dtexである地糸を有する織物であって、
経方向及び緯方向の少なくとも一方の柄糸が、引張強度10cN/dtex以上の高強力繊維及び総繊度33〜156dtexの弾性繊維を含有し、且つ、前記高強力繊維の含有率が70〜95%である高強力糸であり、
経方向及び緯方向のうち、前記高強力糸が含まれる方向と同一方向の地糸は、合成繊維及び弾性繊維を含む伸縮性合繊糸であり、
下記(i)〜(iii)を満たす点に特徴を有する。
(i)高強力繊維のカバリング係数が10000〜21000である。
(ii)(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比が0.4〜2.0である。
(iii)(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比が0.8〜4.0である。
The woven fabric according to the present invention is a woven fabric having a patterned yarn having a total fineness of 50 to 800 dtex and a ground yarn having a total fineness of 50 to 800 dtex in the warp direction and the weft direction,
At least one of the warp yarn and the weft yarn has a high strength fiber having a tensile strength of 10 cN / dtex or more and an elastic fiber having a total fineness of 33 to 156 dtex, and the content of the high strength fiber is 70 to 95%. Is a high strength yarn that is
Of the warp direction and the weft direction, the ground yarn in the same direction as the direction in which the high-strength yarn is contained is a stretchable synthetic yarn containing synthetic fibers and elastic fibers,
It is characterized in that the following (i) to (iii) are satisfied.
(I) The covering coefficient of the high strength fiber is 10,000 to 21,000.
The fineness ratio represented by (ii) (maximum total fineness of pattern yarn) / (minimum total fineness of ground yarn) is 0.4 to 2.0.
(Iii) The fineness ratio represented by (total fineness of elastic fiber in high strength yarn) / (total fineness of elastic fiber in stretchable synthetic fiber) is 0.8 to 4.0.

要件(i)に関し、本明細書において、高強力繊維のカバリング係数とは、前記高強力繊維の巻き回数(カバリング数)と、前記高強力繊維の総繊度から導かれる、前記弾性繊維に対する被覆の度合いを客観的に評価する指標である。柄糸として使用される高強力糸は、伸縮性が悪い高強力繊維と、伸縮性に優れた弾性繊維を含む。そのため、カバリング係数が不足すると、高強力糸を、図1−1に示す緊張状態から、力を解放して図1−2に示す弛緩状態にすると、伸縮性が良好な弾性繊維に高強力繊維が十分に追従できず、弾性繊維と高強力繊維が分離してしまい、高強力繊維の拘束が解かれていた。このような糸を使用して織物を作成すると、拘束が解かれた高強力繊維が切れやすく、毛羽立ちの問題を生じていた(図1−3、図1−4参照)。
そこで本発明では、高強力繊維のカバリング係数を従来よりも高くすることで、前記問題を解決するに至った。図2−1及び図2−2に示すように、カバリング係数が適切であれば、弛緩状態であっても高強力繊維の拘束が保たれ、擦過が抑制される。前記カバリング係数の具体的な求め方は実施例の欄に詳述するが、高強力繊維のカバリング係数は、10000〜21000であり、より好ましくは11000〜20500、更に好ましくは11500〜20000である。カバリング係数が前記範囲を下回ると、擦過で毛羽立ちが発生しやすく、織物の耐擦過摩耗性・耐スナッグ性(以下、これらの特性を単に「耐擦過性」と称する場合がある)の悪化に繋がる虞がある。一方、カバリング係数が前記範囲を上回ると、弾性繊維への拘束力が強過ぎて高強力糸が棒状になり、伸縮性を有する製品を提供し難くなるため好ましくない。また上限を上回ると、拘束力が強過ぎて高強力糸が細くなる傾向にある。そのため、織物が粗い密度となり透けやすくなったり、透けを抑制するために生機密度を上げると織物の風合が硬くなったり、伸縮性が悪くなったりする虞がある。
Regarding the requirement (i), in the present specification, the covering coefficient of the high tenacity fiber means the number of turns (the number of coverings) of the high tenacity fiber and the covering of the elastic fiber derived from the total fineness of the high tenacity fiber. It is an index that objectively evaluates the degree. The high-strength yarn used as the handle yarn includes a high-strength fiber having poor stretchability and an elastic fiber having excellent stretchability. Therefore, when the covering coefficient is insufficient, the high strength fiber can be made into an elastic fiber having high elasticity when the force is released from the tensioned state shown in FIG. 1-1 to the relaxed state shown in FIG. However, the elastic fiber and the high strength fiber were separated, and the restriction of the high strength fiber was released. When such a yarn is used to make a woven fabric, the high-strength fiber in which the restraint is released is easily broken, causing a problem of fuzzing (see FIGS. 1-3 and 1-4).
Therefore, in the present invention, the above problem has been solved by increasing the covering coefficient of the high-strength fiber as compared with the conventional one. As shown in FIGS. 2-1 and 2-2, when the covering coefficient is appropriate, the restraint of the high strength fiber is maintained even in the relaxed state, and the abrasion is suppressed. The specific method of determining the covering coefficient will be described in detail in the section of the Examples, but the covering coefficient of the high strength fiber is 10000 to 21000, more preferably 11000 to 20500, and still more preferably 11500 to 20000. When the covering coefficient is less than the above range, fuzzing is likely to occur due to rubbing, which leads to deterioration of the abrasion resistance and snag resistance of the fabric (hereinafter, these characteristics may be simply referred to as “scratch resistance”). There is a risk. On the other hand, if the covering coefficient exceeds the above range, the restraining force to the elastic fiber becomes too strong, the high strength yarn becomes rod-like, and it becomes difficult to provide a product having stretchability, which is not preferable. If the upper limit is exceeded, the restraining force is so strong that the high strength yarn tends to be thin. Therefore, the woven fabric becomes coarse density and tends to be transparent, and if the biomechanical density is increased to suppress the transparency, the texture of the woven fabric may become hard or the stretchability may be deteriorated.

要件(ii)に関し、織物中、(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比は0.4〜2.0であり、より好ましくは0.5〜1.5であり、更に好ましくは0.6〜1.2である。織物をできるだけ平坦にし、摩擦抵抗の少ない構造にすることが耐擦過性等の観点からは望ましい。そのため、繊度比が上限を上回ると、柄糸が太すぎて柄糸に摩擦力が集中するため、柄糸の損傷により毛羽立ちしやすい織物となるため好ましくない。また繊度比が下限を下回ると、地糸が太すぎて目付の重い織物となるか、細い柄糸を使用しているため高価な織物となっている可能性があり、好ましくない。   Regarding requirement (ii), in the woven fabric, the fineness ratio represented by (maximum total fineness of handle yarn) / (minimum total fineness of ground yarn) is 0.4 to 2.0, more preferably 0.5 to 0.5. 1.5, more preferably 0.6 to 1.2. It is desirable from the viewpoint of scratch resistance and the like to make the woven fabric as flat as possible and to have a structure with low frictional resistance. For this reason, if the fineness ratio exceeds the upper limit, the pattern yarn is too thick and the frictional force concentrates on the pattern yarn, which is not preferable because it becomes a woven fabric that easily becomes fluffy due to damage to the pattern yarn. On the other hand, if the fineness ratio is less than the lower limit, the ground yarn is too thick and may have a heavy fabric weight or may be an expensive fabric because it uses a thin patterned yarn.

要件(iii)に関し、(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比は0.8〜4.0であり、より好ましくは1.0〜3.5であり、更に好ましくは1.5〜3.0である。高強力糸中、高強力繊維のカバリング係数が従来に比して増えたことにより、弾性繊維の拘束力が高まり弾性繊維の伸縮性が低下した。しかしながら、柄糸中の弾性繊維の総繊度をやや太めにしておくことで上記課題を解決することが可能となった。繊度比が下限を下回ると、高強力糸の伸縮性が悪化し、柄糸が織物表面に浮き出て擦過され易くなるため好ましくない。また上限を超えると、高強力糸と伸縮性合繊糸の繊度比が大きくなり、凹凸の大きな織物に仕上がるため、要件(ii)の観点から耐擦過性が悪化する虞があるため好ましくない。
なお(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比は、経方向に含まれる高強力糸と伸縮性合繊糸、或いは、緯方向に含まれる高強力糸と伸縮性合繊糸を用いて算出することとする。
Regarding requirement (iii), the fineness ratio represented by (total fineness of elastic fiber in high strength yarn) / (total fineness of elastic fiber in stretch synthetic fiber) is 0.8 to 4.0, and more Preferably it is 1.0-3.5, More preferably, it is 1.5-3.0. In the high strength yarn, the covering coefficient of the high strength fiber is increased as compared to the conventional one, so the restraint of the elastic fiber is increased and the stretchability of the elastic fiber is reduced. However, it has become possible to solve the above-mentioned problem by slightly increasing the total fineness of the elastic fibers in the handle yarn. If the fineness ratio is less than the lower limit, the stretchability of the high strength yarn is deteriorated, and the patterned yarn is likely to float on the surface of the fabric and be abraded, which is not preferable. If the upper limit is exceeded, the fineness ratio of the high strength yarn and the stretchable synthetic fiber becomes large, and the fabric is finished to a large unevenness, which is not preferable because the abrasion resistance may be deteriorated from the viewpoint of requirement (ii).
In addition, the fineness ratio represented by (total denier of elastic fiber in high strength yarn) / (total denier of elastic fiber in stretchable synthetic fiber) is the ratio of high strength yarn and stretchable synthetic fiber contained in the warp direction, or And the high strength yarn and the stretchable synthetic fiber contained in the latitudinal direction.

以下、各構成について詳述する。   Each component will be described in detail below.

1.柄糸
本明細書において「柄糸」とは、より具体的には、地糸よりも織物における占有面積が低い糸であって、経方向及び緯方向のそれぞれの地糸に一定間隔ごとに打ち込まれる織柄を強調する糸をいう。本発明では特に、引裂強力に優れた織物を提供する目的から、高強力繊維が使用される。しかしながら、前記高強力繊維は難染色性であるため、織物の均一な染色が難しい。そこで本発明ではこの特性を利用して、前記柄糸は高強力繊維を含むことが望ましい。柄糸が高強力繊維を含んでいれば、織物を染色した後も柄糸だけ染まらず、織柄を強調することができるためである。経及び緯方向で、柄糸を地糸に一定間隔ごとに打ち込むことにより、織物には格子状織柄が形成される。
1. Patterned yarn In the present specification, "patterned yarn" is, more specifically, a yarn having a smaller occupied area in the woven fabric than the ground yarn, and is driven into the respective ground yarns in the warp direction and the weft direction at regular intervals. This thread emphasizes the woven pattern. In the present invention, in particular, high strength fibers are used for the purpose of providing a woven fabric excellent in tear strength. However, since the high-strength fiber is hardly dyeable, uniform dyeing of the fabric is difficult. Therefore, in the present invention, it is desirable that the above-mentioned patterned yarn contains a high strength fiber by utilizing this characteristic. If the patterned yarn contains high strength fibers, only the patterned yarn can be dyed after dyeing the fabric, and the woven pattern can be emphasized. A lattice-like woven pattern is formed on the woven fabric by driving the patterned yarn into the ground yarn at regular intervals in the warp and weft directions.

柄糸の総繊度は、50〜800dtex、より好ましくは80〜600dtex、更に好ましくは100〜500dtexである。前記範囲内であれば、軽量で生産性の良い織物が得られる。なお本明細書において、総繊度の評価に際しては、撚り縮み率は含まれないこととする。   The total fineness of the handle yarn is 50 to 800 dtex, more preferably 80 to 600 dtex, and still more preferably 100 to 500 dtex. Within the above range, a lightweight and highly productive fabric can be obtained. In this specification, it is assumed that the twist shrinkage is not included in the evaluation of the total fineness.

<高強力糸>
本発明において、経方向及び緯方向の少なくとも一方の柄糸は、引張強度10cN/dtex以上の高強力繊維及び総繊度33〜156dtexの弾性繊維を含有し、且つ、前記高強力繊維の含有率が70〜95%である高強力糸である。前記高強力糸は、伸縮性を出したい方向を考慮して、織物の経方向、緯方向、または経方向及び緯方向の両方に含まれる。
<High strength yarn>
In the present invention, at least one of the warp yarn and the weft yarn is a high strength fiber having a tensile strength of 10 cN / dtex or more and an elastic fiber having a total fineness of 33 to 156 dtex, and the content of the high strength fiber is It is a high tenacity yarn that is 70 to 95%. The high-strength yarn is included in the warp direction, the weft direction, or both the warp direction and the weft direction of the fabric in consideration of the direction in which stretchability is desired.

高強力繊維の引張強度は、好ましくは13cN/dtex以上、より好ましくは16cN/dtex以上、更に好ましくは20cN/dtex以上であり、好ましくは40cN/dtex以下、より好ましくは38cN/dtex以下、更に好ましくは35cN/dtex以下である。引張強度が前記範囲に満たないと、織物の引裂強力が低下するため好ましくない。高強力繊維の引張強度は、例えば、JIS L 1013 8.5.1:2010に基づき測定される。   The tensile strength of the high strength fiber is preferably 13 cN / dtex or more, more preferably 16 cN / dtex or more, still more preferably 20 cN / dtex or more, preferably 40 cN / dtex or less, more preferably 38 cN / dtex or less, still more preferably. Is 35 cN / dtex or less. If the tensile strength is less than the above range, the tear strength of the fabric is unfavorably reduced. The tensile strength of the high strength fiber is measured based on, for example, JIS L 1013 8.5.1: 2010.

高強力繊維としては、東洋紡社製「イザナス(登録商標)」、「ツヌーガ(登録商標)」に代表される高強力ポリエチレン繊維;帝人社製「テクノーラ(登録商標)」、東レ・デュポン社製「ケブラー(登録商標)」に代表されるパラ系アラミド繊維;クラレ社製「ベクトラン(登録商標)」に代表される高強力ポリアリレート繊維;東洋紡社製「ザイロン(登録商標)」に代表されるポリパラフェニレンベンズオキサゾール(PBO)繊維;クラレ社製「クラロン(登録商標)KII」に代表されるポリビニルアルコール系繊維;等が例示される。高強力繊維としては、軽量な高強力ポリエチレン繊維が好ましい。   As high-strength fibers, high-strength polyethylene fibers represented by Toyobo's "Izanas (registered trademark)" and "Tunuga (registered trademark)"; Teijin's "Technora (registered trademark)", Toray DuPont's " Para-aramid fibers represented by "Kevlar (registered trademark)"; High-strength polyarylate fibers represented by "Bectran (registered trademark)" manufactured by Kuraray; Poly represented by "Zyron (registered trademark)" manufactured by Toyobo Co., Ltd. Examples thereof include paraphenylene benzoxazole (PBO) fiber; polyvinyl alcohol fiber represented by “Kuraron (registered trademark) KII” manufactured by Kuraray Co., Ltd., and the like. As the high strength fiber, a lightweight high strength polyethylene fiber is preferable.

高強力繊維の切断伸度は特に限定されないが、好ましくは0.1〜7.5%、より好ましくは0.5〜7.0%、更に好ましくは1.0〜6.4%である。切断伸度を前記範囲に調整することで、引裂強力の高い織物が提供されるため好ましい。高強力繊維の切断伸度は、例えば、JIS L 1013 8.5.1:2010に基づき測定される。   The breaking elongation of the high strength fiber is not particularly limited, but is preferably 0.1 to 7.5%, more preferably 0.5 to 7.0%, and still more preferably 1.0 to 6.4%. Adjusting the cut elongation to the above range is preferable because a fabric having high tear strength is provided. The cut elongation of the high strength fiber is measured based on, for example, JIS L 1013 8.5.1: 2010.

高強力繊維は、モノフィラメントまたはマルチフィラメントのいずれでもよい。高強力糸を高強度としながら、糸のしなやかさも付与するため、高強力繊維はマルチフィラメントが好ましい。   The high strength fiber may be either monofilament or multifilament. A multifilament is preferably used as the high strength fiber in order to impart high flexibility to the yarn while making the high strength yarn high strength.

高強力繊維の総繊度は、好ましくは20〜700dtex、より好ましくは50〜550dtex、更に好ましくは90〜440dtexである。総繊度が前記範囲内であれば、安価で軽量性に富み、且つ、糸切れを抑制できるため、耐擦過性に優れた織物が提供される。
また高強力繊維の単糸繊度は、好ましくは0.3〜3.0dtex、より好ましくは0.5〜2.5dtex、更に好ましくは0.8〜2.0dtexである。単糸繊度が前記範囲内であれば、柔らかな風合を有し、毛羽立ちの少ない織物が得られる。
The total fineness of the high strength fiber is preferably 20 to 700 dtex, more preferably 50 to 550 dtex, and still more preferably 90 to 440 dtex. If the total fineness is in the above-mentioned range, a cheap, light-weight material can be obtained, and yarn breakage can be suppressed, so that a woven fabric excellent in abrasion resistance is provided.
The single yarn fineness of the high strength fiber is preferably 0.3 to 3.0 dtex, more preferably 0.5 to 2.5 dtex, and still more preferably 0.8 to 2.0 dtex. If the single yarn fineness is in the above range, a fabric having a soft feeling and less fuzz can be obtained.

高強力繊維は、原着糸であってもよい。原着糸とは、紡糸前の原液の段階で顔料や染料などの着色剤を混合することにより、着色された原糸である。高強力繊維の色は特に限定されず、黒色、紺色等、用途に応じて適宜調整される。着色剤を含む高強力繊維としては、5重量%以下(好ましくは0.01重量%以上)の顔料を含む原着糸が好ましい。   The high-strength fiber may be an original yarn. The base yarn is a raw yarn colored by mixing colorants such as a pigment and a dye at the stage of the stock solution before spinning. The color of the high-strength fiber is not particularly limited, and is appropriately adjusted depending on the application, such as black or amber color. The high-strength fiber containing the colorant is preferably an original yarn containing 5% by weight or less (preferably 0.01% by weight or more) of pigment.

高強力繊維は、生糸または捲縮糸のいずれでもよく、伸縮性を高める観点からは、捲縮糸、とりわけ仮撚加工糸が好ましい。一方、捲縮糸(特に仮撚加工糸)は、捲縮加工による強度低下や毛羽立ちの問題を有する場合があるため、高強力繊維の強度特性を活かす観点からは、高強力繊維は生糸(非捲縮糸)が好ましい。   The high strength fiber may be either a raw yarn or a crimped yarn, and from the viewpoint of enhancing the stretchability, a crimped yarn, particularly a false-twisted yarn is preferred. On the other hand, crimped yarn (especially false twisted yarn) may have problems of strength reduction and fuzzing due to crimp processing, so from the viewpoint of taking advantage of the strength characteristics of high strength fibers, high strength fibers are raw yarns ( Crimped yarns) are preferred.

高強力繊維は、無撚糸或いは撚糸のいずれでもよいが、少ないカバリング係数でも耐擦過性を高めることができ、更にはカバリング係数を減らすことにより弾性繊維が持つ伸縮性が損なわれず、伸縮性に富む織物が得られるなどの利点から、高強力繊維は好ましくは撚糸である。   The high-strength fiber may be either non-twisted yarn or twisted yarn, but the scratch resistance can be increased even with a small covering coefficient, and further, the elasticity of the elastic fiber is not impaired by reducing the covering coefficient, and it is rich in elasticity. The high tenacity fibers are preferably twisted yarns because of the advantage that a woven fabric is obtained.

高強力繊維が撚糸の場合、高強力繊維の撚係数は、好ましくは1000〜8000、より好ましくは1500〜7000、更に好ましくは2000〜6000である。前記範囲内であれば、高強力繊維の集束性を高めつつ、被覆性の良い高強力糸となり、耐擦過性が良好となる。高強力繊維の撚係数の求め方は実施例の欄に詳述する。また高強力繊維の加撚方向は、S方向またはZ方向のいずれでもよい。   When the high strength fiber is a twisted yarn, the twist coefficient of the high strength fiber is preferably 1000 to 8000, more preferably 1500 to 7000, and still more preferably 2000 to 6000. If it is in the said range, it will become the high tenacity thread | yarn with favorable covering property, improving the bundling property of a high tenacity fiber, and abrasion resistance will become favorable. The method for obtaining the twist coefficient of the high-strength fiber will be described in detail in the Examples section. The twisting direction of the high strength fiber may be either the S direction or the Z direction.

高強力糸中、高強力繊維の含有率は、繊度比(高強力繊維の総繊度/高強力糸の総繊度)で、70〜98%、より好ましくは75〜96%、更に好ましくは78〜95%である。高強力繊維の含有率が前記範囲内であれば、品位、堅牢度、耐擦過性が良好で、安価で引裂強力に優れた織物が得られる。   In the high-strength yarn, the content of the high-strength fiber is 70 to 98%, more preferably 75 to 96%, and still more preferably 78 to 98% in terms of fineness ratio (total fineness of high-strength fiber / total fineness of high-strength yarn). It is 95%. When the content of the high-strength fiber is within the above range, a woven fabric having good quality, fastness, scratch resistance, low cost and excellent tear strength can be obtained.

一方、高強力糸には弾性繊維が含まれる。弾性繊維の存在により、織物に伸縮性を付与することが可能となる。ここで弾性繊維とは、一般的な繊維よりも弾性が高い繊維をいい、具体的には、切断伸度が400〜850%(より好ましくは750%以下)の合繊フィラメントが好ましい。前記弾性繊維の引張強度は、好ましくは0.7〜1.3cN/dtex(より好ましくは0.8〜1.2cN/dtex)であり、200%伸張時の回復率は好ましくは80%以上である。
なお、弾性繊維の引張強度及び切断伸度は、例えば、JIS L 1013 8.5.1:2010に基づき測定される。さらに、200%伸張時の回復率はJIS L 1013 8.5.1:2010に準じて定速伸長形で200%伸張後、伸張時と等速で戻し、応力が0になった伸張率Aを求め、(200−A)×100/200で算出する。
On the other hand, high strength yarns contain elastic fibers. The presence of the elastic fiber makes it possible to impart stretchability to the woven fabric. Here, the elastic fiber refers to a fiber having a higher elasticity than a general fiber, and specifically, a synthetic fiber having a cutting elongation of 400 to 850% (more preferably 750% or less) is preferable. The tensile strength of the elastic fiber is preferably 0.7 to 1.3 cN / dtex (more preferably 0.8 to 1.2 cN / dtex), and the recovery rate at 200% elongation is preferably 80% or more. is there.
In addition, the tensile strength and cutting elongation of an elastic fiber are measured based on JISL1013 8.5.1: 2010, for example. Furthermore, the recovery rate at 200% elongation is 200% in constant speed extension type according to JIS L1013 8.5.1: 2010, and then returned at the same speed as that at extension, and the stress becomes 0. Is calculated and calculated by (200−A) × 100/200.

弾性繊維を構成する繊維は特に限定されず、ポリウレタン繊維、ポリエーテル系ポリウレタン繊維、ポリブチレンテレフタレート(PBT)繊維、ポリトリメチレンテレフタレート繊維(PTT)、ポリエステル及び/又はナイロン繊維による各種コンジュゲート繊維等が例示されるが、十分な伸縮性と回復性を付与し易いことから、ポリウレタン繊維が好ましい。前記ポリウレタン繊維は、用途に応じて、抗菌防臭剤、紫外線吸収剤・反射剤、吸湿発熱剤等を含んでいてもよい。また、弾性繊維は、高強力繊維との分離を軽減するために、熱融着性であってもよい。熱融着性弾性繊維としては、例えば、日清紡テキスタイル社製「モビロン(登録商標)R−L」等が挙げられる。   The fiber constituting the elastic fiber is not particularly limited, and various conjugate fibers such as polyurethane fiber, polyether-based polyurethane fiber, polybutylene terephthalate (PBT) fiber, polytrimethylene terephthalate fiber (PTT), polyester and / or nylon fiber, etc. However, polyurethane fibers are preferred because sufficient stretchability and recoverability are easily imparted. The polyurethane fiber may contain an antibacterial deodorant, an ultraviolet absorber / reflector, a hygroscopic exothermic agent and the like depending on the application. Further, the elastic fiber may be heat-fusible in order to reduce separation from the high-strength fiber. Examples of the heat-fusible elastic fiber include “Mobilon (registered trademark) RL” manufactured by Nisshinbo Textile Co., Ltd.

弾性繊維は、モノフィラメントまたはマルチフィラメントのいずれでもよい。弾性繊維の総繊度は、33〜156dtex、より好ましくは44〜156dtex、更に好ましくは44〜120dtexである。前記範囲を超えると、伸縮性が強すぎて、弾性繊維が織物表面に露出しやすくなり、紫外線劣化を招く虞がある。前記範囲を下回ると、織物の伸縮性が不十分となる。   The elastic fiber may be monofilament or multifilament. The total fineness of the elastic fiber is 33 to 156 dtex, more preferably 44 to 156 dtex, still more preferably 44 to 120 dtex. If it exceeds the above range, the stretchability is too strong, and the elastic fibers are likely to be exposed on the surface of the fabric, which may cause ultraviolet deterioration. Below the above range, the stretchability of the fabric becomes insufficient.

高強力糸中、前記弾性繊維の含有率は、繊度比(前記弾性繊維の総繊度/高強力糸の総繊度)で、好ましくは5〜60%、より好ましくは8〜60%である。前記弾性繊維の含有率が前記範囲内であれば、芯部と鞘部の分離を抑制でき、耐擦過性に優れた織物が得られる。   In the high-strength yarn, the content of the elastic fiber is preferably a fineness ratio (total fineness of the elastic fiber / total fineness of the high-strength yarn), preferably 5 to 60%, more preferably 8 to 60%. If the content rate of the said elastic fiber is in the said range, isolation | separation of a core part and a sheath part can be suppressed, and the textile fabric excellent in abrasion resistance is obtained.

高強力糸における高強力繊維と弾性繊維の含有量は、繊度比(高強力繊維の総繊度:弾性繊維の総繊度)で、好ましくは50:50〜99:1、より好ましくは60:40〜95:5、更に好ましくは65:35〜90:10である。高強力繊維と弾性繊維の含有率が前記範囲内にあれば、伸縮性と高強度を有する織物が提供される。   The content of the high strength fiber and the elastic fiber in the high strength yarn is a fineness ratio (total fineness of the high strength fiber: total fineness of the elastic fiber), preferably 50:50 to 99: 1, more preferably 60:40 to 95: 5, more preferably 65:35 to 90:10. If the content rate of a high strength fiber and an elastic fiber exists in the said range, the textile fabric which has a stretching property and high intensity | strength will be provided.

高強力糸は、実質的に、引張強度10cN/dtex以上の高強力繊維と、総繊度33〜156dtexの弾性繊維から構成されていることが好ましい。前記高強力繊維及び前記弾性繊維の混率は、高強力糸100重量%中、好ましくは80重量%以上、より好ましくは90重量%以上、更に好ましくは95重量%以上であり、特に好ましくは99重量%以上である。   The high strength yarn is preferably substantially composed of high strength fibers having a tensile strength of 10 cN / dtex or more and elastic fibers having a total fineness of 33 to 156 dtex. The mixing ratio of the high strength fiber and the elastic fiber is preferably at least 80% by weight, more preferably at least 90% by weight, still more preferably at least 95% by weight, and particularly preferably 99% by weight in 100% by weight of the high strength yarn. % Or more.

高強力糸は、例えば、前記弾性繊維を芯部とし、前記高強力繊維を鞘部とする、芯鞘構造のカバリング糸;前記高強力繊維と前記弾性繊維とから構成される合撚糸;前記高強力繊維と前記弾性繊維とから構成されるエア交絡糸;等が好ましく、耐擦過性が良好であることから、カバリング糸がより望ましい。   A covering yarn having a core-sheath structure comprising, for example, the elastic fiber as a core and the high strength fiber as a sheath; a high twisting yarn composed of the high strength fiber and the elastic fiber; An air entangled yarn composed of strong fibers and the elastic fiber is preferable, and a covering yarn is more preferable because of good abrasion resistance.

高強力糸がカバリング糸のとき、高強力糸は、シングルカバリング糸(SCY)またはダブルカバリング糸(DCY)のいずれでもよいが、織物表面の凹凸を減らし、耐擦過性を向上させるため、シングルカバリング糸が望ましい。特にDCYでは、前記弾性繊維に直接巻き付く高強力繊維(以降、「内側高強力繊維」と称す)と、前記内側高強力繊維によって被覆されている前記弾性繊維の周囲に更に巻きつけられる高強力繊維(以降、「外側高強力繊維」と称す)の繊度比またはカバリング係数比を、適宜調整するとよい。   When the high tenacity yarn is a covering yarn, the high tenacity yarn may be either a single covering yarn (SCY) or a double covering yarn (DCY). However, in order to reduce unevenness on the fabric surface and improve the scratch resistance, the single covering yarn is used. Yarn is desirable. Particularly in DCY, a high strength fiber directly wound on the elastic fiber (hereinafter referred to as "inner high strength fiber") and a high strength further wound around the elastic fiber covered by the inner high strength fiber. The fineness ratio or covering coefficient ratio of the fibers (hereinafter referred to as “outer high-strength fibers”) may be appropriately adjusted.

例えば、内側高強力繊維と外側高強力繊維の総繊度比(内側高強力繊維/外側高強力繊維)は、好ましくは0.8〜1.2、より好ましくは0.9〜1.1、更に好ましくは0.95〜1.05である。前記範囲内であれば、カバリング糸表面の凹凸を少なくでき、耐擦過性に優れた織物が提供される。   For example, the total fineness ratio of the inner high strength fiber and the outer high strength fiber (inner high strength fiber / outer high strength fiber) is preferably 0.8 to 1.2, more preferably 0.9 to 1.1, Preferably it is 0.95 to 1.05. If it is in the said range, the unevenness | corrugation on the surface of covering yarn can be decreased and the textile fabric excellent in abrasion resistance is provided.

また、内側高強力繊維と外側高強力繊維のカバリング係数比(内側高強力繊維/外側高強力繊維)は、好ましくは0.8〜1.2、より好ましくは0.9〜1.1、更に好ましくは0.95〜1.05である。前記範囲内であれば、カバリング糸表面の凹凸を少なくでき、耐擦過性に優れた織物が提供される。   Moreover, the covering coefficient ratio (inner high strength fiber / outer high strength fiber) of the inner high strength fiber and the outer high strength fiber is preferably 0.8 to 1.2, more preferably 0.9 to 1.1, Preferably it is 0.95 to 1.05. If it is in the said range, the unevenness | corrugation on the surface of covering yarn can be decreased and the textile fabric excellent in abrasion resistance is provided.

高強力繊維が撚糸のとき、高強力繊維の撚方向と、カバリング糸における高強力繊維のカバリング方向は、同じでも逆でもよい。同じであると、高強力繊維の集束性がより高まり、織物の耐擦過性が向上するため好ましい。
なお、「高強力繊維の撚方向と、カバリング糸における高強力繊維のカバリング方向が同じ」とは、例えば、撚方向が「S」のとき、カバリング方向が「S」であることを意味し、「高強力繊維の撚方向と、カバリング糸における高強力繊維のカバリング方向が逆」とは、例えば、撚方向が「S」のとき、カバリング方向が「Z」であることを意味する。
When the high strength fiber is a twisted yarn, the twisting direction of the high strength fiber and the covering direction of the high strength fiber in the covering yarn may be the same or opposite. If the same, it is preferable because the high-tensile strength fiber is more concentrated and the abrasion resistance of the fabric is improved.
Note that “the twist direction of the high strength fiber and the covering direction of the high strength fiber in the covering yarn are the same” means, for example, when the twist direction is “S”, the covering direction is “S”, “The twist direction of high strength fibers and the covering direction of high strength fibers in covering yarn are opposite to each other” means, for example, when the twist direction is “S”, the covering direction is “Z”.

前記高強力糸は、カバリング機、撚糸機(例えば、ダブルツイスター機)等により製造できる。高強力糸がカバリング糸の場合は、例えば、カバリング機を用い、ドラフトゾーンで弾性繊維をドラフトしながら供給し、中空スピンドルの真中に前記弾性繊維を通し、前記中空スピンドルに設置された高強力繊維が巻かれたボビンを回転させることによって、弾性繊維の周囲に高強力繊維を巻きつけるとよい。弾性繊維のドラフト率は特に限定されず、好ましくは2.0〜4.0倍、より好ましくは2.2〜3.5倍である。前記範囲内であれば、伸長後の回復性のよい糸が得られる。またドラフトゾーンでは、エプロンローラの使用も可能である。   The high-strength yarn can be produced by a covering machine, a twisting machine (for example, a double twister machine) or the like. When the high-strength yarn is a covering yarn, for example, using a covering machine, the elastic fiber is supplied while drafting in the draft zone, and the elastic fiber is passed through the middle of the hollow spindle, and the high-strength fiber installed on the hollow spindle is used. The high-strength fiber may be wound around the elastic fiber by rotating the bobbin around which the wire is wound. The draft rate of the elastic fiber is not particularly limited, and is preferably 2.0 to 4.0 times, more preferably 2.2 to 3.5 times. If it is in the said range, the thread | yarn with the high recoverability after expansion | extension will be obtained. In the draft zone, an apron roller can be used.

製造された高強力糸には、必要に応じて、スナール抑制のためのエージング、真空スチームセット(例えば、60〜70℃で20〜40分間)等が施されてもよい。   The manufactured high strength yarn may be subjected to aging for sunal suppression, a vacuum steam set (for example, at 60 to 70 ° C. for 20 to 40 minutes), and the like, as necessary.

<高強力糸以外の柄糸>
本発明では織物の柄糸として、高強力糸が含まれている限り、高強力糸を除く任意の合成繊維糸が使用できる。高強力糸を除く合成繊維糸としては、生糸も使用できるが、耐擦過性の観点から、撚糸、カバリング糸、交絡糸等のように、集束された糸が好ましい。前記糸を構成する素材は特に限定されないものの、前記糸は、織物の引裂強力を向上させる観点から前述した高強力繊維を含むことが望ましい。
<Pattern yarn other than high strength yarn>
In the present invention, any synthetic fiber yarn except high-strength yarn can be used as long as high-strength yarn is included as a patterned yarn of a woven fabric. Raw silk can also be used as synthetic fiber yarn excluding high strength yarn, but in view of abrasion resistance, a gathered yarn such as twisting yarn, covering yarn, entangled yarn and the like is preferable. Although the material constituting the yarn is not particularly limited, it is preferable that the yarn contains the high strength fiber described above from the viewpoint of improving the tear strength of the fabric.

2.地糸
本明細書において「地糸」とは、より具体的には、経方向及び緯方向のそれぞれにおいて、織物の地を構成する糸をいう。一つの格子状織柄(具体的には一つの完全組織)における(柄糸の本数)/(地糸の本数)で表される比は、経方向及び緯方向それぞれで、好ましくは1:1〜1:60、より好ましくは1:3〜1:20である。柄糸の比率が増えると織物が高価になるため、前記範囲内であれば、比較的安価で十分な引裂強力を有する織物となる。
2. In the present specification, the "ground yarn" more specifically refers to a yarn that constitutes the ground of the fabric in each of the warp direction and the weft direction. The ratio represented by (the number of handle yarns) / (the number of base yarns) in one lattice-like woven pattern (specifically, one complete structure) is preferably 1: 1 in each of the warp direction and the weft direction. To 1:60, more preferably 1: 3 to 1:20. If the ratio of the handle yarn increases, the woven fabric becomes expensive. Therefore, if it is within the above range, the woven fabric is relatively inexpensive and has sufficient tear strength.

地糸の総繊度は、50〜800dtex、より好ましくは80〜600dtex、更に好ましくは100〜500dtexである。前記範囲を超えると、軽量の織物が得られにくくなるため好ましくない。   The total fineness of the ground yarn is 50 to 800 dtex, more preferably 80 to 600 dtex, still more preferably 100 to 500 dtex. If the above range is exceeded, it is not preferable because lightweight woven fabrics are difficult to obtain.

<伸縮性合繊糸>
織物の伸縮性を高めるため、本発明において経方向及び緯方向のうち、前記高強力糸が含まれる方向と同一方向の地糸は、合成繊維及び弾性繊維を含む伸縮性合繊糸である。柄糸の高強力糸と、地糸の伸縮性合繊糸の方向を揃えることで、織物の伸縮性をより向上させることができる。また伸縮性合繊糸が合成繊維を含むことで、強度が向上する。
<Stretchable synthetic fiber>
In order to enhance the stretchability of the woven fabric, in the present invention, the base yarn in the same direction as the direction in which the high strength yarn is included among the warp direction and the weft direction is a stretchable synthetic fiber including synthetic fibers and elastic fibers. By aligning the direction of the high-strength yarn of the pattern yarn and the stretchable synthetic yarn of the ground yarn, the stretchability of the fabric can be further improved. Moreover, an intensity | strength improves because an elastic synthetic fiber contains a synthetic fiber.

伸縮性合繊糸に含まれる弾性繊維は、例えば、切断伸度が400%以上850%以下(より好ましくは750%以下)の合繊フィラメントが好ましい。前記弾性繊維の引張強度は、好ましくは0.7〜1.3cN/dtex(より好ましくは0.8〜1.2cN/dtex)であり、200%伸張時の回復率は好ましくは80%以上である。弾性繊維を構成する繊維は、前記高強力糸に含まれる弾性繊維と同様のものが例示され、十分な伸縮性と回復性を付与し易いことから、ポリウレタン繊維が好ましい。   The elastic fiber contained in the stretchable synthetic fiber is preferably, for example, a synthetic fiber having a breaking elongation of 400% to 850% (more preferably 750% or less). The tensile strength of the elastic fiber is preferably 0.7 to 1.3 cN / dtex (more preferably 0.8 to 1.2 cN / dtex), and the recovery rate at 200% elongation is preferably 80% or more. is there. As the fibers constituting the elastic fibers, exemplified are the same as the elastic fibers contained in the high strength yarn, and polyurethane fibers are preferable because they can easily impart sufficient stretchability and recovery.

伸縮性合繊糸における弾性繊維は、モノフィラメントまたはマルチフィラメントのいずれでもよい。
前記弾性繊維の総繊度は、33〜156dtex、より好ましくは44〜156dtex、更に好ましくは44〜120dtexである。前記範囲を超えると、伸縮性が強すぎて、弾性繊維が織物表面に露出しやすくなり、紫外線劣化を招く虞がある。前記範囲を下回ると、織物の伸縮性が不十分となる。
The elastic fibers in the stretchable synthetic fiber may be either monofilaments or multifilaments.
The total fineness of the elastic fiber is 33 to 156 dtex, more preferably 44 to 156 dtex, and still more preferably 44 to 120 dtex. If the above range is exceeded, the elasticity is so strong that the elastic fibers are likely to be exposed on the surface of the fabric, which may cause the deterioration of ultraviolet rays. Below the above range, the stretchability of the fabric becomes insufficient.

伸縮性合繊糸中、前記弾性繊維の含有率は、繊度比(前記弾性繊維の総繊度/前記伸縮性合繊糸の総繊度)で、好ましくは5〜45%、より好ましくは8〜40%である。前記範囲内であれば、伸縮性に優れた織物が得られる。   The elastic fiber content in the stretchable synthetic yarn is preferably a fineness ratio (total fineness of the elastic fiber / total fineness of the stretchable synthetic yarn), preferably 5 to 45%, more preferably 8 to 40%. is there. If it is in the said range, the textile fabric excellent in the elasticity is obtained.

伸縮性合繊糸に含まれる合成繊維は、好ましくはマルチフィラメントである。前記合成繊維としては、ナイロン6繊維、ナイロン66繊維等のポリアミド繊維;ポリエチレンテレフタレート繊維、ポリブチレンテレフタレート繊維等のポリエステル繊維;等が好ましく、これらの繊維は1種又は2種以上を組み合わせて用いられ、中でも、染色が容易で、耐摩耗性が得られやすいポリアミド繊維が好ましく、より好ましくはナイロン6繊維またはナイロン66繊維である。特に、高強力繊維として高強力ポリエチレン繊維を選択する場合には、染色加工で温度制約がある場合があることから、ナイロン6繊維または常圧カチオン可染ポリエステル繊維が好ましい。   The synthetic fiber contained in the stretchable synthetic yarn is preferably a multifilament. The synthetic fibers are preferably polyamide fibers such as nylon 6 fibers and nylon 66 fibers; polyester fibers such as polyethylene terephthalate fibers and polybutylene terephthalate fibers; etc., and these fibers are used alone or in combination of two or more. Among these, polyamide fibers that are easily dyed and easily obtain abrasion resistance are preferable, and nylon 6 fibers or nylon 66 fibers are more preferable. In particular, when high strength polyethylene fiber is selected as the high strength fiber, nylon 6 fiber or normal pressure cationic dyeable polyester fiber is preferable because temperature limitation may occur during the dyeing process.

前記ポリアミド繊維を構成する樹脂の相対粘度は、好ましくは2.5〜4.5、より好ましくは2.7〜4.2、更に好ましくは2.9〜4.0である。   The relative viscosity of the resin constituting the polyamide fiber is preferably 2.5 to 4.5, more preferably 2.7 to 4.2, and still more preferably 2.9 to 4.0.

前記合成繊維は、用途に応じて、顔料(カーボン等)や染料などの着色剤、抗菌防臭剤、紫外線吸収剤・反射剤、蓄熱剤等を含んでいてもよい。   The synthetic fiber may contain a coloring agent such as a pigment (carbon etc.) or a dye, an antibacterial deodorant, an ultraviolet absorber / reflecting agent, a heat storage agent, etc. according to the use.

前記合成繊維の断面形状は、丸断面または異型断面のいずれでもよい。異型断面としては、三角形などの多角形断面;Y字、十字、六葉、八葉等の多葉断面;等が例示される。また、合成繊維は中実、中空のいずれでもよい。   The cross-sectional shape of the synthetic fiber may be either a round cross section or a modified cross section. Examples of the atypical cross section include a polygonal cross section such as a triangle; a multi-lobal cross section such as a Y-shape, a cross, a six leaf, and an eight leaf; and the like. The synthetic fiber may be solid or hollow.

前記合成繊維の単糸繊度は、好ましくは2.8〜11dtex、より好ましくは3.0〜10.5dtex、更に好ましくは4.5〜10dtexである。また合成繊維の総繊度は、好ましくは20〜500dtex、より好ましくは100〜300dtexである。前記範囲内であれば、耐擦過性に優れ、ソフトな風合を有する織物となる。   The single yarn fineness of the synthetic fiber is preferably 2.8 to 11 dtex, more preferably 3.0 to 10.5 dtex, and still more preferably 4.5 to 10 dtex. The total fineness of the synthetic fiber is preferably 20 to 500 dtex, more preferably 100 to 300 dtex. If it is in the said range, it will become the textile which is excellent in abrasion resistance and has a soft touch.

合成繊維は、生糸または捲縮糸のいずれでもよく、伸縮性を高める観点からは、捲縮糸、とりわけ仮撚加工糸が好ましい。仮撚加工の方式は特に限定されず、フリクションタイプ、PINタイプ等、一般的な方法が採用できる。また仮撚加工に供する繊維は、POY(Partially Oriented Yarn)、FDY(Fully Draw Yarn)など、用途に応じて適宜選択するとよい。   The synthetic fiber may be either a raw yarn or a crimped yarn, and from the viewpoint of enhancing the stretchability, a crimped yarn, particularly a false-twisted yarn is preferred. The method of false twisting is not particularly limited, and general methods such as a friction type and a PIN type can be adopted. In addition, fibers to be subjected to false twisting may be appropriately selected depending on applications, such as POY (Partially Oriented Yarn) and FDY (Fully Draw Yarn).

前記合成繊維の伸縮復元率は、例えば、好ましくは10〜40%、より好ましくは12〜37%、更に好ましくは15〜35%である。なお合成繊維の伸縮復元率は、例えば、JIS L 1013 8.12:2010に基づき測定される。   The stretch recovery rate of the synthetic fiber is, for example, preferably 10 to 40%, more preferably 12 to 37%, and still more preferably 15 to 35%. In addition, the expansion-contraction restoration rate of a synthetic fiber is measured based on JISL10138.12: 2010, for example.

合成繊維の引張強度は、好ましくは3.7〜6.5cN/dtex、より好ましくは4.0〜6.0cN/dtexである。前記範囲内であれば、単糸切れを防止でき、耐擦過性が良好な織物が得られる。合成繊維の引張強度は、例えば、JIS L 1013 8.5.1:2010に基づき測定される。   The tensile strength of the synthetic fiber is preferably 3.7 to 6.5 cN / dtex, more preferably 4.0 to 6.0 cN / dtex. Within the above range, single yarn breakage can be prevented, and a woven fabric with good scratch resistance can be obtained. The tensile strength of the synthetic fiber is measured, for example, based on JIS L 1013 8.5.1: 2010.

合成繊維の切断伸度は、好ましくは20〜38%、より好ましくは23〜32%である。前記範囲内であれば、毛羽の少ない、耐擦過性が良好な織物が得られる。合成繊維の切断伸度は、例えば、JIS L 1013 8.5.1:2010に基づき測定される。   The cut elongation of the synthetic fiber is preferably 20 to 38%, more preferably 23 to 32%. If it is in the said range, there are few fuzz and the textile fabric with favorable abrasion resistance is obtained. The cut elongation of the synthetic fiber is measured based on, for example, JIS L 1013 8.5.1: 2010.

合成繊維は、高強力繊維と同様、無撚糸或いは撚糸のいずれでもよいが、少ないカバリング係数でも耐擦過性を高めることができ、更にはカバリング係数を減らすことにより弾性繊維が持つ伸縮性が損なわれず、伸縮性に富む織物が得られるなどの利点から、合成繊維は好ましくは撚糸である。
合成繊維が撚糸の場合、合成繊維の撚係数は、好ましくは1000〜12000、より好ましくは1500〜7500、更に好ましくは2000〜6000である。前記範囲内であれば、合成繊維の集束性を高めつつ、被覆性の良い伸縮性合繊糸となり、耐擦過性が良好となる。また合成繊維の加撚方向は、S方向またはZ方向のいずれでもよい。
Synthetic fibers, like high-strength fibers, may be either non-twisted yarns or twisted yarns, but with a small covering coefficient can improve scratch resistance, and by reducing the covering coefficient, the elasticity of the elastic fibers is not impaired. The synthetic fiber is preferably a twisted yarn because of advantages such as obtaining a highly elastic woven fabric.
When the synthetic fiber is a twisted yarn, the twist coefficient of the synthetic fiber is preferably 1000 to 12000, more preferably 1500 to 7500, and still more preferably 2000 to 6000. If it is in the said range, it will become an elastic synthetic fiber with a favorable coating property, improving abrasion resistance, improving the bundling property of a synthetic fiber. Further, the twisting direction of the synthetic fiber may be either the S direction or the Z direction.

伸縮性合繊糸は、例えば、前記弾性繊維を芯部とし、前記合成繊維を鞘部とする、芯鞘構造のカバリング糸;前記合成繊維と前記弾性繊維とから構成される合撚糸;前記合成繊維と前記弾性繊維とから構成されるエア交絡糸;等が好ましく、耐擦過性が良好であることから、カバリング糸または前記合成繊維と前記弾性繊維をエア交絡した後に施撚した複合糸がより好ましい。   The elastic synthetic fiber is, for example, a covering yarn having a core-sheath structure in which the elastic fiber is used as a core and the synthetic fiber is used as a sheath; a synthetic yarn comprising the synthetic fiber and the elastic fiber; Air-entangled yarn composed of the above-mentioned elastic fiber and the like; etc. is preferable, and a covering yarn or a composite yarn obtained by air-entangling the above-mentioned elastic fiber with the above-mentioned synthetic fiber is more preferable since scratch resistance is good. .

合成繊維のカバリング係数は、好ましくは10000〜21000であり、より好ましくは11000〜20500、更に好ましくは11500〜20000である。前記範囲内であれば、弾性繊維を拘束しすぎないため、伸縮性に優れた織物となり、また弾性繊維を合成繊維で十分に被覆できるため、耐擦過性に優れた織物となる。前記カバリング係数の具体的な求め方は実施例の欄に詳述する。   The covering coefficient of the synthetic fiber is preferably 10,000 to 21,000, more preferably 11000 to 20500, and still more preferably 11500 to 20000. If it is within the above range, the elastic fiber is not restrained too much, so it becomes a woven fabric excellent in stretchability, and since the elastic fiber can be sufficiently covered with a synthetic fiber, it becomes a woven fabric excellent in abrasion resistance. A specific method for obtaining the covering coefficient will be described in detail in the section of the embodiment.

伸縮性合繊糸がカバリング糸のとき、伸縮性合繊糸は、シングルカバリング糸(SCY)またはダブルカバリング糸(DCY)のいずれでもよいが、織物表面の凹凸を減らし、耐擦過性を向上させるため、シングルカバリング糸が望ましい。   When the stretchable synthetic yarn is a covering yarn, the stretchable synthetic yarn may be either a single covering yarn (SCY) or a double covering yarn (DCY). However, in order to reduce unevenness on the fabric surface and improve scratch resistance, Single covering yarn is desirable.

合成繊維が撚糸のとき、合成繊維の撚方向と、カバリング糸における合成繊維のカバリング方向は、同じでも逆でもよい。同じであると、合成繊維の集束性がより高まり、織物の耐擦過性が向上するため好ましい。
なお前記同様、「合成繊維の撚方向と、カバリング糸における合成繊維のカバリング方向が同じ」とは、例えば、撚方向が「S」のとき、カバリング方向が「S」であることを意味し、「合成繊維の撚方向と、カバリング糸における合成繊維のカバリング方向が逆」とは、例えば、撚方向が「S」のとき、カバリング方向が「Z」であることを意味する。
When the synthetic fiber is a twisted yarn, the twisting direction of the synthetic fiber and the covering direction of the synthetic fiber in the covering yarn may be the same or opposite. It is preferable that it is the same, since the synthetic property of the synthetic fiber is further enhanced and the abrasion resistance of the fabric is improved.
Similarly to the above, "the same direction as the synthetic fiber twisting direction and the covering direction of the synthetic fiber in the covering yarn is the same" means that the covering direction is "S" when the twisting direction is "S", for example, “The twisting direction of the synthetic fiber and the covering direction of the synthetic fiber in the covering yarn are opposite to each other” means, for example, that the covering direction is “Z” when the twisting direction is “S”.

またエア交絡の交絡度は、好ましくは5〜120ヶ/m、より好ましくは15〜105ヶ/m、更に好ましくは25〜95ヶ/mである。   The air entanglement degree is preferably 5 to 120, more preferably 15 to 105, and still more preferably 25 to 95 / m.

前記伸縮性合繊糸は、カバリング機、撚糸機(例えば、ダブルツイスター機)等により製造できる。
伸縮性合繊糸がカバリング糸の場合は、例えば、カバリング機を用い、ドラフトゾーンで弾性繊維をドラフトしながら供給し、中空スピンドルの真中に前記弾性繊維を通し、前記中空スピンドルに設置された合成繊維が巻かれたボビンを回転させることによって、弾性繊維の周囲に合成繊維を巻きつけて製造するとよい。
また伸縮性合繊糸は、例えば、合成繊維とドラフトした弾性繊維を引き揃えて公知のインターレーサに供給し、高圧エアにて前記合成繊維と前記弾性繊維をエア交絡した後、撚糸機等で施撚して製造することもできる。
いずれの方法においても弾性繊維のドラフト率は特に限定されず、好ましくは2.0〜4.0倍、より好ましくは2.2〜3.5倍である。前記範囲内であれば、伸長後の回復生のよい糸が得られる。またドラフトゾーンでは、エプロンローラの使用も可能である。
The stretchable synthetic fiber can be manufactured by a covering machine, a twisting machine (for example, a double twister machine) or the like.
When the stretchable synthetic yarn is a covering yarn, for example, using a covering machine, the elastic fiber is supplied while being drafted in a draft zone, and the elastic fiber is passed through the middle of the hollow spindle, and the synthetic fiber is installed on the hollow spindle. The synthetic fiber may be wound around the elastic fiber to manufacture by rotating the wound bobbin.
Further, for example, a synthetic elastic fiber and a drafted elastic fiber are aligned and supplied to a known interlacer, and the synthetic fiber and the elastic fiber are air-entangled with high pressure air, and then applied with a twisting machine or the like. It can also be manufactured by twisting.
The draft rate of the elastic fiber is not particularly limited in any method, and is preferably 2.0 to 4.0 times, more preferably 2.2 to 3.5 times. If it is in the said range, the recovery | restoration raw | good thread | yarn after an expansion | extension will be obtained. In the draft zone, it is also possible to use an apron roller.

製造された伸縮性合繊糸には、必要に応じて、スナール抑制のためのエージング、真空スチームセット(例えば、60〜70℃で20〜40分間)等が施されてもよい。   The manufactured stretchable synthetic fiber may be subjected to aging for suppression of sunal, a vacuum steam set (for example, at 60 to 70 ° C. for 20 to 40 minutes), and the like, as necessary.

<伸縮性合繊糸以外の地糸>
本発明では地糸として、伸縮性合繊糸だけでなく、伸縮性合繊糸を除く任意の糸が使用できる。伸縮性合繊糸としては、生糸も使用できるが、耐擦過性の観点から、撚糸、カバリング糸、交絡糸等のように、集束された糸が好ましい。前記糸を構成する素材は特に限定されないものの、前記糸は、織物の引裂強力を向上させる観点から前述した合成繊維を含むことが望ましい。
<Ground yarn other than elastic synthetic yarn>
In the present invention, not only the stretchable synthetic yarn but also any yarn other than the stretchable synthetic yarn can be used as the ground yarn. Raw silk can also be used as the stretchable synthetic fiber, but from the viewpoint of abrasion resistance, a combined yarn such as twisting yarn, covering yarn, entangled yarn, etc. is preferable. Although the material which comprises the said thread | yarn is not specifically limited, It is desirable for the said thread | yarn to contain the synthetic fiber mentioned above from a viewpoint of improving the tearing strength of a textile fabric.

3.織物
本発明に係る織物は、高強力糸及び伸縮性合繊糸が含まれる方向に応じて、緯伸び織物、経伸び織物、または2WAY織物となる。
3. Woven Fabric The woven fabric according to the present invention is a weft-stretched fabric, a warp-stretched woven fabric, or a 2 WAY woven fabric, depending on the direction in which the high-strength yarn and the stretchable synthetic fiber are included.

織組織は、特に限定されず、平織、ドビー織、パナマ織、綾織、変化綾織、繻子織など、要求されるデザイン等に応じて適宜選択するとよく、耐擦過性の観点からは、平坦な生地外観を呈する平織が好ましく、伸縮性の観点からはドビー織が好ましい。また織物は二重組織であってもよい。   The woven structure is not particularly limited, and may be appropriately selected according to the required design such as plain weave, dobby weave, panama weave, twill weave, change twill weave, satin weave, etc. From the viewpoint of scratch resistance, a flat fabric A plain weave exhibiting an appearance is preferred, and a dobby weave is preferred from the viewpoint of stretchability. The fabric may have a double structure.

織機としては、エアジェット織機、レピア織機等、用途に応じて適宜選択するとよい。また、一重ビームとするか、二重ビームとするかは、用途に応じて適宜選択できる。また、整経時、経糸をそのまま製織ビームに巻き取ってもよく、糊付又はワキシングして巻き取ってもよい。   As the loom, an air jet loom, a rapier loom, or the like may be appropriately selected according to the application. Further, whether to use a single beam or a double beam can be appropriately selected depending on the application. In addition, the warp may be wound around the weaving beam as it is, or may be wound with glue or waxing.

織物中、高強力繊維の比率は3〜50%が好ましく、より好ましくは6〜30%であり、更に好ましくは7〜20%である。前記範囲内であれば、十分な引裂強力が得られるため好ましい。   In the woven fabric, the ratio of high-strength fibers is preferably 3 to 50%, more preferably 6 to 30%, and still more preferably 7 to 20%. If it is in the said range, since sufficient tearing strength is obtained, it is preferable.

織物中、弾性繊維の比率は4〜25%が好ましく、より好ましくは5〜20%であり、更に好ましくは7〜15%である。前記範囲内であれば、伸縮性及び耐擦過性に優れた織物となるため好ましい。   In the woven fabric, the elastic fiber ratio is preferably 4 to 25%, more preferably 5 to 20%, and still more preferably 7 to 15%. If it is in the said range, since it becomes the textile fabric excellent in elasticity and abrasion resistance, it is preferable.

織物の目付は、好ましくは70〜500g/m2、より好ましくは80〜450g/m2、更に好ましくは100〜400g/m2である。前記範囲内であれば、軽量で且つ耐擦過性に優れた織物となる。 The fabric weight is preferably 70 to 500 g / m 2 , more preferably 80 to 450 g / m 2 , and still more preferably 100 to 400 g / m 2 . If it is in the said range, it will be lightweight and the textile fabric excellent in abrasion resistance.

織物のカバーファクター(CF)は、好ましくは1800〜2800、より好ましくは1900〜2700、更に好ましくは2000〜2600である。前記範囲内であれば、着用感が良く、軽量で且つ耐擦過性に優れた織物となる。   The cover factor (CF) of the fabric is preferably 1800 to 2800, more preferably 1900 to 2700, still more preferably 2000 to 2600. If it is in the said range, a feeling of wear will be good, and it will become a textile fabric which is lightweight and excellent in abrasion resistance.

また格子状織柄(具体的には一つの完全組織)のサイズは、経方向及び緯方向それぞれにおいて、好ましくは10mm以下、より好ましくは8mm以下、更に好ましくは5mm以下であり、好ましくは0.5mm以上、より好ましくは1mm以上である。前記範囲内であれば、地糸と柄糸のバランスがよく、引裂強力に優れた織物となる。格子状織柄のサイズとは、例えば、図3に示すL1及びL2の長さをいう。 Further, the size of the lattice-like woven pattern (specifically, one complete structure) is preferably 10 mm or less, more preferably 8 mm or less, still more preferably 5 mm or less in each of the warp direction and the weft direction. It is 5 mm or more, more preferably 1 mm or more. If it is in the said range, the balance of the ground yarn and the pattern yarn will be good, and it will become a textile excellent in tear strength. The size of the lattice-like woven pattern means, for example, the lengths of L 1 and L 2 shown in FIG.

織物の仕上密度は、経方向及び緯方向のそれぞれにおいて、好ましくは60〜160本/2.54cm、より好ましくは70〜150本/2.54cmである。
製造された織物は、用途に応じて染色してもよい。染色工程において、使用される染色機は特に限定されるものではないが、例えば、ジッカー染色機、液流染色機、ビーム染色機等が好ましく用いられる。染料は合成繊維の素材に合わせて適宜選択するとよい。
The finishing density of the woven fabric is preferably 60 to 160 / 2.54 cm, more preferably 70 to 150 / 2.54 cm in the warp and weft directions, respectively.
The manufactured fabric may be dyed depending on the application. The dyeing machine used in the dyeing step is not particularly limited, and, for example, a Zicker dyeing machine, a jet flow dyeing machine, a beam dyeing machine and the like are preferably used. The dye may be appropriately selected according to the material of the synthetic fiber.

織物には、仕上げ加工として、柔軟処理、帯電防止処理、撥水処理、ウレタン樹脂によるコーティング加工やラミネート加工等を、単独でまたは組み合わせて行うとよい。前記撥水剤としては、シリコン系撥水剤、フッ素系撥水剤、パラフィン系撥水剤等が好ましく例示され、織物の平滑性が得られ易く、織物の耐擦過性が向上しやすいことからシリコン系撥水剤がより好ましい。   The fabric may be finished with a flexible treatment, an antistatic treatment, a water repellent treatment, a coating treatment with urethane resin, a lamination treatment, etc., alone or in combination as finishing. Preferred examples of the water repellent include silicone water repellent, fluorine water repellent, paraffin water repellent and the like, and the smoothness of the fabric is easily obtained and the abrasion resistance of the fabric is easily improved. Silicon-based water repellents are more preferred.

本発明に係る織物は、耐スナッグ性が良好であり、例えば、織物のJIS L 1058 D−3法に基づき測定されるスナッグの等級は、好ましくは4級以上であり、織物の経方向または緯方向のいずれか一方、もしくはこの両方が前記範囲を満たすことが望ましい。級数が上がる程、岩、枝、ファスナー等による引っ掛けに対し耐性が上がる。なお、耐スナッグ性の評価方法は、実施例の欄に詳述する。   The fabric according to the present invention has good resistance to snag, for example, the grade of the snag measured based on the JIS L 1058 D-3 method of the fabric is preferably fourth grade or more, and the warp direction or weft of the fabric It is desirable that one or both of the directions satisfy the above range. The higher the series, the more resistant it is to catching by rocks, branches, fasteners, etc. In addition, the evaluation method of snag resistance is explained in full detail in the column of an Example.

また織物の耐擦過摩耗性は、好ましくは3級以上、より好ましくは4級以上であり、織物の経方向または緯方向のいずれか一方、もしくはこの両方が前記範囲を満たすことが望ましい。耐擦過摩耗性の評価は、前記耐スナッグ性の評価よりも厳しいが、本発明によれば、岩のような鋭利な物体との繰り返しの擦過があっても損傷が小さく、これまでにない実用的な織物が提供される。   In addition, the abrasion resistance of the fabric is preferably 3 or more, more preferably 4 or more, and it is desirable that either or both of the warp direction and the weft direction of the fabric satisfy the above range. The evaluation of the abrasion resistance is stricter than the evaluation of the above-mentioned anti-snag resistance, but according to the present invention, even if repeated abrasion with a sharp object such as a rock occurs, the damage is small, which is unprecedented Textiles are provided.

また織物のJIS L 1096 8.17D法(ペンジュラム法)に基づく引裂強力は、好ましくは40〜150N、より好ましくは50〜140N、更に好ましくは55〜130Nであり、織物の経方向または緯方向のいずれか一方、もしくはこの両方が前記範囲を満たすことが望ましい。織物の引裂強力が前記範囲内であれば、例えば、岩のような鋭利な物体との強い擦過により、製品が破れることがなく好ましい。   The tear strength of the woven fabric based on the JIS L 1096 8.17D method (penjuram method) is preferably 40 to 150 N, more preferably 50 to 140 N, and still more preferably 55 to 130 N. It is desirable that either one or both satisfy the above range. If the tear strength of the woven fabric is within the above range, it is preferable that the product is not torn due to strong abrasion with a sharp object such as a rock.

更に本発明に係る織物は伸縮性に優れ、例えば、織物のJIS L 1096 8.16B法(定荷重法)に基づく伸び率は、好ましくは12〜60%、より好ましくは15〜55%であり、更に好ましくは18〜50%である。伸び率が前記範囲内であれば、織物を衣料用に用いた場合でも、身体の動きが阻害されることがない。本発明では、織物の経方向または緯方向のいずれか一方、もしくはこの両方が前記範囲を満たすことが望ましい。   Furthermore, the woven fabric according to the present invention is excellent in stretchability. For example, the elongation percentage of the woven fabric based on the JIS L 1096 8.16B method (constant load method) is preferably 12 to 60%, more preferably 15 to 55%. More preferably, it is 18 to 50%. If the elongation percentage is within the above range, even when the fabric is used for clothing, the movement of the body is not hindered. In the present invention, it is desirable that either or both of the warp direction and the weft direction of the fabric satisfy the above range.

4.用途
本発明は、更に前記織物を含む繊維製品も包含する。本発明に係る織物は引裂強力に優れるため、繊維製品としては高引裂強力が要求される用途、例えば、スポーツウェア、アウトドアウェア(シャツ、パンツ)、ジャケット、雨衣、防護用作業着等の衣料;手袋;靴;鞄;等に好ましく適用される。また本発明に係る織物は、耐擦過性に優れるため、スキーやスノーボードのエッジから脚を守るスキー用パンツ、レッグプロテクター;転倒時の手・腕・脚の擦過から保護するサイクリングウェア;岩場で擦過から保護する登山用パンツ、登山靴;磯で貝殻が付着した岩場を移動したり、岩場に座ったりするため、岩場での引っ掻きから保護する釣り用の雨衣;等、高い耐擦過性が要求される用途に特に好ましく用いられる。
4. Applications The invention further comprises textiles comprising said textile. Since the textile fabric according to the present invention is excellent in tear strength, the textile product is required to have high tear strength, for example, sportswear, outdoor wear (shirts, pants), jackets, rain clothes, protective work clothes, etc .; It is preferably applied to gloves, shoes, bags, and the like. In addition, since the fabric according to the present invention has excellent scratch resistance, ski pants and leg protectors that protect the legs from the edges of skis and snowboards; High scuff resistance is required, such as mountaineering pants and mountaineering shoes that protect from shores; fishing robes that protect against scratching on rocky rocks because they move and sit on rocky rocks with shells attached to the rocks. It is particularly preferably used in various applications.

以下、実施例を挙げて本発明をより具体的に説明するが、本発明はもとより下記実施例によって制限を受けるものではなく、前・後記の趣旨に適合し得る範囲で適当に変更を加えて実施することも勿論可能であり、それらはいずれも本発明の技術的範囲に包含される。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited by the following examples, but may be appropriately modified within a range that can meet the purpose described above and below. Of course, implementation is also possible, and all of them are included in the technical scope of the present invention.

<1.カバリング数>
JIS L 1095 C.10.4 もろより糸:2010 に準ず。
<1. Covering number>
JIS L 1095 C.I. 10.4 Mashed yarn: according to 2010

<2.カバリング係数>
カバリング係数は、
カバリング係数={カバリング数(t/m)}×{総繊度(dtex)}1/2
に基づき算出する。
なお、DCY糸の場合は、外側に巻きつけられる繊維のカバリング数と総繊度を用いて算出する。
<2. Covering coefficient>
The covering factor is
Covering coefficient = {covering number (t / m)} × {total fineness (dtex)} 1/2
Calculated based on
In the case of DCY yarn, calculation is made using the covering number of fibers wound around the outside and the total fineness.

<3.撚数>
JIS L 1095 9.15.1 JIS法 A法:2010に準ず。
<3. Number of twists>
JIS L 1095 9.15.1 JIS method A method: According to 2010.

<4.撚係数>
撚係数は、
撚係数={撚数(t/m)}×{総繊度(dtex)}1/2
に基づき算出する。
<4. Twist factor>
The twisting factor is
Twisting factor = {twisting number (t / m)} × {total fineness (dtex)} 1/2
Calculated based on

<5.カバーファクター(CF)>
織物のカバーファクターは、経方向及び緯方向それぞれのカバーファクターの総和であり、各方向のカバーファクターは下記式により算出される。
・経方向のCF
=経方向の柄糸の本数(本/2.54cm)×{前記柄糸の総繊度(dtex)}1/2+経方向の地糸の本数(本/2.54cm)×{前記地糸の総繊度(dtex)}1/2
・緯方向のCF
=緯方向の柄糸の本数(本/2.54cm)×{前記柄糸の総繊度(dtex)}1/2+緯方向の地糸の本数(本/2.54cm)×{前記地糸の総繊度(dtex)}1/2
<5. Cover factor (CF)>
The cover factor of the fabric is the sum of the cover factor in each of the warp direction and the weft direction, and the cover factor in each direction is calculated by the following equation.
-Longitudinal CF
= Number of handle yarns in the warp direction (line / 2.54 cm) × {total denier of the handle yarns (dtex)} 1/2 + number of threads in the warp direction (line / 2.54 cm) × {above yarn Total fineness (dtex)} 1/2
· CF in the latitudinal direction
= Number of patterned yarn in the latitudinal direction (line / 2.54 cm) × {total denier of the patterned yarn (dtex)} 1/2 + number of ground yarn in the latitudinal direction (line / 2.54 cm) × {above ground yarn Total fineness (dtex)} 1/2

<6.引張強度>
JIS L 1013 8.5.1:2010に準ず。
<6. Tensile strength>
According to JIS L 1013 8.5.1: 2010.

<7.切断伸度>
JIS L 1013 8.5.1:2010に準ず。
<7. Cutting elongation>
According to JIS L 1013 8.5.1: 2010.

<8.伸縮復元率>
JIS L 1013 8.12:2010に準ず。
<8. Stretch recovery rate>
In accordance with JIS L 1013 8.12: 2010.

<9.交絡度>
JIS L 1013 8.15:2010に準ず。
<9. Degree of confounding>
According to JIS L 1013 8.15: 2010.

<10.繊維の混率>
単位面積当たりの織物の重量を測定した後、経糸(柄糸、地糸)と緯糸(柄糸、地糸)を全部解き、各糸を解撚分離して素材別に合計重量を測定した。その後、素材別の合計重量を織物の重量で除し、100分率に換算することにより各繊維の混率を求めた。
<10. Blend ratio of fiber>
After measuring the weight of the fabric per unit area, all warp (pattern yarn, ground yarn) and weft (pattern yarn, ground yarn) were unwound, and each yarn was untwisted and separated, and the total weight was measured separately for each material. Thereafter, the total weight for each material was divided by the weight of the woven fabric, and the mixture ratio of each fiber was determined by converting to 100 minutes.

<11.耐擦過摩耗性>
JIS L 0849 9.2:2010に示される摩擦試験機II形(学振形)を使用し、摩擦用白綿布に変えて、研磨布(理研コランダム社製「AA−40」)を用いて、荷重4.9N、摩耗回数10回で試験を行った。試験後の状態を、下記表に基づき評価した。経及び緯を各n=3で測定し、最も悪い試料の成績を採用する。
<11. Wear resistance>
Using a friction tester II type (Gakusha type) shown in JIS L 0849 9.2: 2010, changing to a white cotton cloth for friction, using an abrasive cloth ("AA-40" manufactured by Riken Corundum), The test was performed with a load of 4.9 N and 10 wears. The state after the test was evaluated based on the following table. The longitude and latitude are measured at each n = 3, and the worst sample performance is adopted.

<12.耐スナッグ性>
JIS L 1058 D−3法;2011に準ず。操作時間は5時間である。試験後の評価は、「耐擦過摩耗性」の評価で使用した表に基づく。但し、経緯別に級判定する。
<12. Snag resistance>
JIS L 1058 D-3 method; conforming to 2011. The operation time is 5 hours. The evaluation after the test is based on the table used in the "abrasion resistance" evaluation. However, grades are determined according to circumstances.

<13.引裂強力>
JIS L 1096 8.17D法(ペンジュラム法):2010に準ず。
<13. Tear strength>
JIS L 1096 8.17D method (penjuram method): According to 2010.

<14.伸縮性>
JIS L 1096 8.16B法(定荷重法):2010に準ず(荷重;1.4N、時間;1分間、測定方向;緯方向)。
<14. Elasticity>
JIS L 1096 8.16B method (constant load method): According to 2010 (load; 1.4 N, time; 1 minute, measurement direction; weft direction).

<15.風合>
風合は、5人が下記5段階評価に基づいて判定を行い、5人の平均値で評価する。
5:とてもソフト、4:ややソフト、3:ソフト、2:やや硬い、1:とても硬い。
<15. Feeling>
Five people make a judgment based on the following five-step evaluation, and a feeling is evaluated by the average value of five people.
5: very soft, 4: slightly soft, 3: soft, 2: slightly stiff, 1: very stiff.

<16.品位>
ループ状欠点は、長さ50mの織物を速度5m/分の検反機上で検査し、1.5mm以上の長さを有するループ状欠点(図5のY参照)の個数(1m2あたり)を評価した。
3:0.1個以下、2:0.1個超0.2個以下、1:0.2個超
透けは、検反機上で織物を停止させ、織物の下に白又は黒の台紙を敷き、3人が下記3段階評価に基づいて判定を行う。
3:全く透けない、2:やや透ける、1:よく透ける
<16. Quality>
As for the loop defect, a 50 m long fabric is inspected on a test machine with a speed of 5 m / min, and the number of loop defects (see Y in FIG. 5) having a length of 1.5 mm or more (per 1 m 2 ) Evaluated.
3: 0.1 or less, 2: more than 0.1, 0.2 or less, 1: 0.2 or more The stop of the fabric on the inspection machine, the white or black mount under the fabric Three people perform judgment based on the following three-step evaluation.
3: not transparent at all 2: slightly transparent 1: transparent

<17.総合評価>
織物の総合評価は、以下の基準に基づいて行った。
「合格」;耐擦過摩耗性が経緯3級以上、耐スナッグ性が経緯4級以上、引裂強力が経緯40N以上、風合が3級以上の全てを満たす織物を合格とした。
「不合格」;耐擦過摩耗性が経緯3級以上、耐スナッグ性が経緯4級以上、引裂強力が経緯40N以上、風合が3級以上の要件のうち、1つでも満たさない織物は不合格とした。
<17. Overall evaluation>
The comprehensive evaluation of the fabric was performed based on the following criteria.
"Pass": Abrasion resistance is grade 3 or higher, snag resistance is grade 4 or higher, tear strength is 40 N or more, texture is grade 3 or more, and a fabric satisfying all is accepted.
"Fail"; Abrasion resistance is grade 3 or higher, snag resistance is grade 4 or higher, tear strength is 40 N or more, texture is grade 3 or higher, and a fabric that does not satisfy at least one of the requirements is not acceptable. I passed it.

実施例及び比較例で使用した糸を表2にまとめる。なお、ナイロン6捲縮糸は、いずれも、丸断面、レジンRV:3.0、フリクション仮撚糸である。   The yarns used in Examples and Comparative Examples are summarized in Table 2. All the nylon 6 crimped yarns have a round cross section, a resin RV: 3.0, and a friction false twisted yarn.

実施例1
<糸の作製>
経方向・緯方向で使用される柄糸及び地糸は、以下の方法で作製した。
柄糸(1)(3);芯部をドラフト率3.0倍でドラフトされたポリウレタン繊維とし、カバリング機を用い、該ポリウレタン繊維の周囲に、予めダブルツイスターで施撚したS方向に300t/mの撚りを有する高強力ポリエチレン繊維を、S方向に1600t/mとなるように巻きつけて、シングルカバリング糸(SCY)を得た。
地糸(2)(4);芯部をドラフト率3.0倍でドラフトされたポリウレタン繊維とし、カバリング機を用い、該ポリウレタン繊維の周囲に、仮撚時の加撚方向がZ方向であり、予めダブルツイスターで施撚したZ方向に300t/mの撚りを有するナイロン6捲縮糸を、Z方向に1600t/mとなるように巻きつけて、シングルカバリング糸(SCY)を得た。
<織物の作製>
表に示す密度・柄サイズとなるように、二重ビームのエアジェット織機と上記糸を用いて平組織の織物を製織した。得られた生機を、ピンテンターで120℃30秒のセットを施した後、83℃の浴中、拡布状で連続精練した後、シリンダー乾燥し、ピンテンターで120℃30秒の中間セットを施した。液流染色機で酸性染料(黒色)を用い、98℃40分間の染色加工を行った。染色加工後の生機を脱水乾燥後、ピンテンターで120℃30秒のセットを行った後、シリコン系撥水剤含有溶液に浸漬させ、マングルで絞った後、120℃で40秒間のキュアセットを行い、織物を得た。
Example 1
<Making yarn>
The pattern yarn and the ground yarn used in the warp direction and the weft direction were produced by the following method.
Handle yarn (1) (3): Polyurethane fiber drafted at a draft rate of 3.0 times at the core, and using a covering machine, the polyurethane fiber was twisted around the polyurethane fiber in advance in the S direction by 300 t / s in the S direction. A high-strength polyethylene fiber having a twist of m was wound so as to be 1600 t / m in the S direction to obtain a single covering yarn (SCY).
Base yarn (2) (4); core portion is polyurethane fiber drafted at a draft ratio of 3.0 times, using a covering machine, around the polyurethane fiber, the twisting direction at the time of false twist is the Z direction, A nylon 6 crimped yarn having a twist of 300 t / m in the Z direction, previously twisted with a double twister, was wound so as to be 1600 t / m in the Z direction to obtain a single covering yarn (SCY).
<Production of textiles>
A plain weave fabric was woven using a double beam air jet loom and the above yarn so as to obtain the density and handle size shown in the table. The obtained greenware was subjected to a set at 120 ° C. for 30 seconds with a pin tenter, followed by continuous scouring in a spread form in a bath at 83 ° C., and then cylinder drying, and an intermediate set at 120 ° C. for 30 seconds was applied with a pin tenter. Using an acid dye (black) in a jet flow dyeing machine, dyeing was carried out at 98 ° C. for 40 minutes. After dewatering and drying the green machine after dyeing processing, set it at 120 ° C for 30 seconds with a pintenter, then immerse it in a silicon-based water repellent containing solution, squeeze it with a mangle, and cure set at 120 ° C for 40 seconds , I got a textile.

実施例2〜3、比較例1〜2
柄糸及び地糸のカバリング数を変更すること以外は、実施例1と同様にして織物を得た。比較例1では、カバリング係数が十分でないため、耐擦過性が悪くなった。比較例2では、カバリング係数が適正値を超えているため、硬い風合の織物となった。またSCY糸中のポリウレタン繊維が鞘糸で強く拘束されて伸縮力が弱くなり、染色加工時の収縮が不十分となったことで密度の粗い透けを有する織物となった。比較例3では、高強力繊維が使用されていないため、織物の引裂強力が不十分であった。
Examples 2-3, Comparative Examples 1-2
A fabric was obtained in the same manner as in Example 1 except that the covering number of the pattern yarn and the ground yarn was changed. In Comparative Example 1, since the covering coefficient was not sufficient, the abrasion resistance was deteriorated. In Comparative Example 2, since the covering coefficient exceeded the appropriate value, the fabric became a hard feeling. Further, the polyurethane fiber in the SCY yarn was strongly restrained by the sheath yarn and the stretchability became weak, and the shrinkage at the time of the dyeing process became insufficient, resulting in a woven fabric having a coarse-density sheer. In Comparative Example 3, since the high strength fiber was not used, the tear strength of the woven fabric was insufficient.

比較例3
柄糸(1)(3)における高強力ポリエチレン繊維を表に示すナイロン6捲縮糸に変更し、その他は表に示す条件により実施例1と同様にして織物を得た。
Comparative example 3
A high strength polyethylene fiber in the patterned yarns (1) and (3) was changed to a nylon 6 crimped yarn shown in the table, and the other fabric was obtained in the same manner as in Example 1 under the conditions shown in the table.

実施例4
柄糸及び鞘糸の鞘部に施撚をしなかったこと以外は実施例1と同様にして織物を得た。
Example 4
A woven fabric was obtained in the same manner as in Example 1 except that the sheath portion of the handle yarn and the sheath yarn was not twisted.

実施例5〜6、比較例4〜5
柄糸及び地糸のカバリング数を変更すること以外は、実施例4と同様にして織物を得た。比較例4では、カバリング係数が十分でないため、耐擦過性が悪くなった。比較例5では、カバリング係数が適正値を超えているため、硬い風合の織物となり、また比較例2と同様に、SCY糸の伸縮力が弱くなり、染色加工時の収縮が不十分となったことで密度の粗い透けを有する織物となった。
Examples 5-6, Comparative Examples 4-5
A woven fabric was obtained in the same manner as in Example 4 except that the covering number of the patterned yarn and the ground yarn was changed. In the comparative example 4, since the covering coefficient was not enough, the abrasion resistance worsened. In Comparative Example 5, since the covering coefficient exceeds the appropriate value, it becomes a woven fabric having a hard feeling, and similarly to Comparative Example 2, the stretching force of the SCY yarn becomes weak, and the shrinkage at the time of dyeing becomes insufficient. As a result, it became a woven fabric with a coarse sheen.

実施例7
柄糸(1)(3)として、芯部をドラフト率3.0倍でドラフトされたポリウレタン繊維とし、カバリング機を用い、該ポリウレタン繊維の周囲に、予めダブルツイスターで施撚したS方向に300t/mの撚りを有する高強力ポリエチレン繊維(110dtex/96f)を、S方向に1000t/mとなるように巻きつけ、更にその周囲にZ方向に300t/mの撚りを有する高強力ポリエチレン繊維(110dtex/96f)をZ方向に1000t/mとなるように巻きつけて得られるダブルカバリング糸(DCY)を用いた。これ以外は、実施例1と同様にして織物を得た。
Example 7
As the handle yarn (1) (3), the core portion is made of a polyurethane fiber drafted at a draft rate of 3.0 times, and using a covering machine, around the polyurethane fiber is twisted in advance with a double twister in 300 S in the S direction. A high-strength polyethylene fiber (110 dtex / 96f) having a twist of 300 m / m is wound around the S-direction so as to be 1000 t / m, and a high-strength polyethylene fiber having a twist of 300 t / m in the Z direction (110 dtex) A double covering yarn (DCY) obtained by winding / 96f) in the Z direction at 1000 t / m was used. A fabric was obtained in the same manner as in Example 1 except for the above.

実施例8
柄糸(1)(3)における高強力ポリエチレン繊維を黒原着の高強力ポリエチレン繊維に変更し、地糸(2)(4)として、ドラフト率3.0倍でドラフトされたポリウレタン糸と、仮撚時の加撚方向がZ方向であるナイロン6捲縮糸をエア交絡(交絡度84ヶ/m)した後、ダブルツイスター機でZ方向に850t/m施撚した糸(IL+DT)を用いた。また織物を図4に示すドビー織とした。図4中、それぞれ、a:地糸(2)、B:柄糸(1)、c:地糸(4)、D:柄糸(3)を表す。これら以外は実施例1と同様にして織物を得た。
Example 8
The high strength polyethylene fiber in the patterned yarn (1) (3) is changed to a high strength polyethylene fiber attached to a black base, and a polyurethane yarn drafted at a draft rate of 3.0 times as a ground yarn (2) (4) Nylon 6 crimped yarn whose twisting direction during twisting was Z direction was air entangled (entanglement degree 84 / m), and then a yarn twisted 850 t / m in the Z direction (IL + DT) with a double twister machine was used. . The woven fabric was a dobby weave shown in FIG. In FIG. 4, a: ground yarn (2), B: patterned yarn (1), c: ground yarn (4), D: patterned yarn (3), respectively. A fabric was obtained in the same manner as Example 1 except for these.

実施例9、比較例6
地糸(2)(4)におけるナイロン6捲縮糸の総繊度を変更し、その他は表に示す条件により実施例1と同様にして織物を得た。比較例6では、(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比が適正値を超えているため、織物の凹凸が大きくなり、耐擦過性が悪化した。
Example 9, Comparative Example 6
The total fineness of the nylon 6 crimped yarn in the base yarns (2) and (4) was changed, and in the same manner as in Example 1 under the conditions shown in the table, a woven fabric was obtained. In Comparative Example 6, since the fineness ratio represented by (maximum total fineness of the handle yarn) / (minimum total fineness of the ground yarn) exceeds the appropriate value, the unevenness of the fabric becomes large and the scratch resistance is deteriorated. .

比較例7
柄糸(1)(3)におけるポリウレタン繊維の総繊度を変更し、その他は表に示す条件により実施例1と同様にして織物を得た。比較例7では(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比が適正値を下回っているため、高強力糸の伸縮性が悪化し、柄糸が織物表面に浮き出て容易に擦過されてしまった。また高強力糸の加工収縮性が悪化し、密度が粗くなった上、総繊度が細いため特に柄糸箇所で透けが生じた。
Comparative Example 7
A woven fabric was obtained in the same manner as in Example 1 except that the total fineness of the polyurethane fibers in the patterned yarns (1) and (3) was changed and the other conditions were as shown in the table. In Comparative Example 7, since the fineness ratio represented by (total fineness of elastic fiber in high strength yarn) / (total fineness of elastic fiber in elastic synthetic fiber) is lower than an appropriate value, the expansion and contraction of high strength yarn The property deteriorated, and the patterned yarn floated on the surface of the fabric and was easily rubbed off. In addition, the processing shrinkage of the high strength yarn was deteriorated, the density became coarse, and the total fineness was thin, so that the shedding occurred particularly at the patterned yarn location.

実施例10
地糸(2)(4)として、ドラフト率3.0倍でドラフトされたポリウレタン繊維と、仮撚時の加撚方向がZ方向であるナイロン6捲縮糸をエア交絡(交絡度36ヶ/m)した後、ダブルツイスター機でZ方向に1000t/m施撚した糸(IL+DT)を用いたこと以外は、表に示す条件で実施例1と同様に織物を得た。
Example 10
Air entanglement of polyurethane fiber drafted at a draft ratio of 3.0 times as the ground yarn (2) (4) and nylon 6 crimped yarn whose twisting direction at the time of false twist is the Z direction (interlacing degree 36 pieces / m) After that, a woven fabric was obtained in the same manner as in Example 1 under the conditions shown in the table except that a yarn (IL + DT) twisted 1000 t / m in the Z direction with a double twister machine was used.

実施例11
経の柄糸(1)として、ダブルツイスター機を用いて高強力ポリエチレン繊維をS方向に1000t/mで施撚した撚糸(DT)を用い、経の地糸(2)として、ダブルツイスター機を用いてナイロン6捲縮糸をZ方向に1000t/mで施撚した撚糸(DT)を用いたこと以外は、表に示す条件で実施例1と同様に織物を得た。
Example 11
A twisting yarn (DT) obtained by twisting a high strength polyethylene fiber in the S direction at 1000 t / m using a double twister machine as a handle yarn (1) of warp is used as a ground yarn of warp (2). A woven fabric was obtained in the same manner as in Example 1 under the conditions shown in the Table, except that a twisted yarn (DT) was used which was obtained by twisting a nylon 6 crimped yarn in the Z direction at 1000 t / m.

1:格子状織柄の経方向のサイズ、L2:格子状織柄の緯方向のサイズ
a:地糸(2)、B:柄糸(1)、c:地糸(4)、D:柄糸(3)
Y:ループ状欠点
L 1 : Size in the longitudinal direction of the lattice-like woven pattern, L 2 : Size in the weft direction of the lattice-like woven pattern a: ground yarn (2), B: patterned yarn (1), c: ground yarn (4), D : Pattern yarn (3)
Y: loop defect

Claims (13)

経方向及び緯方向が、それぞれ、総繊度が50〜800dtexである柄糸と総繊度が50〜800dtexである地糸を有する織物であって、
経方向及び緯方向の少なくとも一方の柄糸が、引張強度10cN/dtex以上の高強力繊維及び総繊度33〜156dtexの弾性繊維を含有し、且つ、前記高強力繊維の含有率が70〜95%である高強力糸であり、
経方向及び緯方向のうち、前記高強力糸が含まれる方向と同一方向の地糸は、合成繊維及び弾性繊維を含む伸縮性合繊糸であり、
下記(i)〜(iii)を満たす織物。
(i)高強力繊維のカバリング係数が10000〜21000である。
(ii)(柄糸の最大総繊度)/(地糸の最小総繊度)で表される繊度比が0.4〜2.0である。
(iii)(高強力糸中の弾性繊維の総繊度)/(伸縮性合繊糸中の弾性繊維の総繊度)で表される繊度比が0.8〜4.0である。
A woven fabric comprising a patterned yarn having a total fineness of 50 to 800 dtex and a ground yarn having a total fineness of 50 to 800 dtex in the warp direction and the weft direction,
At least one of the warp yarn and the weft yarn has a high strength fiber having a tensile strength of 10 cN / dtex or more and an elastic fiber having a total fineness of 33 to 156 dtex, and the content of the high strength fiber is 70 to 95%. Is a high strength yarn that is
Of the warp direction and the weft direction, the ground yarn in the same direction as the direction in which the high-strength yarn is contained is a stretchable synthetic yarn containing synthetic fibers and elastic fibers,
Textile which fulfills the following (i)-(iii).
(I) The covering coefficient of the high strength fiber is 10,000 to 21,000.
The fineness ratio represented by (ii) (maximum total fineness of pattern yarn) / (minimum total fineness of ground yarn) is 0.4 to 2.0.
(Iii) The fineness ratio represented by (total fineness of elastic fiber in high strength yarn) / (total fineness of elastic fiber in stretchable synthetic fiber) is 0.8 to 4.0.
前記高強力糸が、前記弾性繊維を芯部とし、前記高強力繊維を鞘部とする、芯鞘構造のカバリング糸である請求項1に記載の織物。   The woven fabric according to claim 1, wherein the high strength yarn is a covering yarn having a core-sheath structure, which has the elastic fiber as a core and the high strength fiber as a sheath. 前記高強力繊維が撚糸である請求項2に記載の織物。   The woven fabric according to claim 2, wherein the high-strength fiber is a twisted yarn. 前記高強力繊維の撚係数が1000〜8000である請求項3に記載の織物。   The woven fabric according to claim 3, wherein a twist coefficient of the high strength fiber is 1000 to 8000. 前記高強力繊維の撚方向と、前記カバリング糸における高強力繊維のカバリング方向が同じである請求項3または4に記載の織物。   The fabric according to claim 3 or 4, wherein a twisting direction of the high strength fiber and a covering direction of the high strength fiber in the covering yarn are the same. 前記高強力繊維がポリエチレン繊維である請求項1〜5のいずれか1項に記載の織物。   The woven fabric according to any one of claims 1 to 5, wherein the high-strength fibers are polyethylene fibers. 前記伸縮性合繊糸が、前記弾性繊維を芯部とし、前記合成繊維を鞘部とする、芯鞘構造のカバリング糸または前記合成繊維と前記弾性繊維をエア交絡した後に施撚した複合糸である請求項1〜6のいずれか1項に記載の織物。   The elastic synthetic fiber is a covering yarn having a core-sheath structure having the elastic fiber as a core and the synthetic fiber as a sheath, or a composite yarn obtained by air entanglement of the synthetic fiber with the elastic fiber and twisted. The woven fabric according to any one of claims 1 to 6. 前記合成繊維がナイロン6繊維またはナイロン66繊維である請求項1〜7のいずれか1項に記載の織物。   The woven fabric according to any one of claims 1 to 7, wherein the synthetic fiber is nylon 6 fiber or nylon 66 fiber. 前記合成繊維が、捲縮糸である請求項1〜8のいずれか1項に記載の織物。   The woven fabric according to any one of claims 1 to 8, wherein the synthetic fiber is a crimped yarn. 格子状織柄のサイズが、経方向及び緯方向それぞれにおいて、10mm以下である請求項1〜9のいずれか1項に記載の織物。   The woven fabric according to any one of claims 1 to 9, wherein the size of the lattice-shaped woven pattern is 10 mm or less in each of the warp direction and the weft direction. JIS L 1058 D−3法に基づき測定されるスナッグの等級が4級以上であり、
JIS L 1096 8.17D法(ペンジュラム法)に基づく引裂強力が40〜150Nであり、
JIS L 1096 8.16B法(定荷重法)に基づく伸び率が12〜60%である請求項1〜10のいずれか1項に記載の織物。
The snag grade measured based on JIS L 1058 D-3 method is grade 4 or higher,
Tear strength based on JIS L 1096 8.17D method (Pendulum method) is 40 to 150 N,
The woven fabric according to any one of claims 1 to 10, wherein an elongation percentage based on JIS L 1096 8.16B method (constant load method) is 12 to 60%.
耐擦過摩耗性が3級以上である請求項1〜11のいずれか1項に記載の織物。   The woven fabric according to any one of claims 1 to 11, wherein the abrasion resistance is a third grade or higher. 請求項1〜12のいずれか1項に記載の織物を含む繊維製品。   The textile product containing the textile fabric of any one of Claims 1-12.
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Cited By (1)

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Publication number Priority date Publication date Assignee Title
KR20230058893A (en) * 2021-10-25 2023-05-03 주식회사 동원텍스 Combination black-out blind fabric to realize pure white color improved shading ratio

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Publication number Priority date Publication date Assignee Title
JP2003193345A (en) * 2001-12-21 2003-07-09 Du Pont Toray Co Ltd Coated yarn and knitted fabric using the same
JP2012153993A (en) * 2011-01-25 2012-08-16 Maeda Seni Kogyo Kk Double covering yarn and manufacturing method thereof and stretch fabric using double covering yarn
JP2015120989A (en) * 2013-12-24 2015-07-02 東レ株式会社 Heat insulation woven or knitted fabric

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003193345A (en) * 2001-12-21 2003-07-09 Du Pont Toray Co Ltd Coated yarn and knitted fabric using the same
JP2012153993A (en) * 2011-01-25 2012-08-16 Maeda Seni Kogyo Kk Double covering yarn and manufacturing method thereof and stretch fabric using double covering yarn
JP2015120989A (en) * 2013-12-24 2015-07-02 東レ株式会社 Heat insulation woven or knitted fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230058893A (en) * 2021-10-25 2023-05-03 주식회사 동원텍스 Combination black-out blind fabric to realize pure white color improved shading ratio
KR102564493B1 (en) * 2021-10-25 2023-08-07 주식회사 동원텍스 Combination black-out blind fabric to realize pure white color improved shading ratio

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