JP2019162841A - Recording method - Google Patents

Abstract

An object of the present invention is to provide a recording method capable of suppressing the occurrence of color difference even when the width of a recording medium in the scanning direction is large. A color ink composition including a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a different hue angle from each of the ink compositions is ejected from an inkjet head. An ink adhering step of adhering to the recording medium; and a treatment liquid adhering step of adhering a treatment liquid containing an aggregating agent for aggregating the components of the colored ink composition to the recording medium. The step is performed by performing a plurality of scans of discharging the colored ink composition while changing the relative position of the inkjet head and the recording medium in the scanning direction, and the maximum distance of one scan in the ink attaching step is A recording method that is 50 cm or more. [Selection diagram] None

Description

  The present invention relates to a recording method.

  The ink jet recording method is capable of recording high-definition images with a relatively simple device, and has been rapidly developed in various fields. Among them, various studies have been made on ejection stability and the like. For example, Patent Document 1 discloses a resin and a difference in SP value with respect to the resin for the purpose of providing a water-based inkjet ink composition that can form an image having excellent clogging resistance in the head and excellent abrasion resistance. The content of the nitrogen-containing solvent is 2 to 9 parts by mass with respect to 1 part by mass of the resin, and the content of the organic solvent having a standard boiling point of 280 ° C. or higher. A water-based inkjet ink composition is disclosed in which is 3% by mass or less. As described in Patent Document 1, by using a predetermined solvent, the resin is sufficiently dissolved in the recording medium to easily form a film and has excellent abrasion resistance, and the resin deposited in the head is difficult to remove by cleaning and difficult to recover. Ink compositions that do not have to be known are known.

JP 2017-186472 A

  By using an inkjet printer to record on a wide recording medium, a recorded material useful for display or the like can be obtained. In recent years, when printing is performed with a wide recording medium and a long scanning distance, and using a processing liquid that aggregates ink components to improve image quality, the color differs depending on the location of the image on the recording medium. The problem which ends.

  An object of the present invention is to provide a recording method capable of suppressing the occurrence of a color difference of recorded matter in the above case.

  The present inventors diligently studied to solve the above problems. As a result, it has been found that the above-mentioned problems can be solved by using the basic color ink composition and the special color ink composition together, and the present invention has been completed.

That is, the present invention is as follows.
[1]
A colored ink composition containing a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions is ejected from an inkjet head and recorded. An ink adhering step for adhering to the medium;
A treatment liquid adhering step for adhering a treatment liquid containing a flocculant for aggregating the components of the colored ink composition to the recording medium,
The ink adhering step is performed by performing a plurality of scans for discharging the colored ink composition while changing the relative position of the inkjet head to the recording medium in a scanning direction,
The maximum distance of one scan in the ink adhering step is 50 cm or more;
Recording method.
[2]
The special color ink composition includes at least one of an orange ink composition, a red ink composition, a green ink composition, and a blue ink composition,
The recording method according to [1].
[3]
The colored ink composition further comprises a black ink composition,
The recording method according to [1] or [2].
[4]
The recording medium is a low-absorbency recording medium or a non-absorbent recording medium.
The recording method according to any one of [1] to [3].
[5]
A heating step of heating the recording medium, and performing the ink adhering step on the heated recording medium, or
A blowing step of sending air to a region where the colored ink composition is attached in the ink attaching step;
The recording method according to any one of [1] to [4].
[6]
The surface temperature of the recording medium when the colored ink composition is attached in the ink attaching step is 30 to 45 ° C.
The recording method according to any one of [1] to [5].
[7]
The maximum time of one scan in the ink adhering step is 0.8 seconds or more,
The recording method according to any one of [1] to [6].
[8]
The flocculant is any one or more of a polyvalent metal salt, an organic acid or a salt thereof, and a cationic resin.
The recording method according to any one of [1] to [7].
[9]
The maximum distance of one scan in the ink adhering step is 50 to 500 cm;
The recording method according to any one of [1] to [8].
[10]
The recording area to which the colored ink composition and the treatment liquid are attached has a region in which the amount of the treatment liquid adhered to the amount of the color ink composition attached is 5 to 30% by mass.
The recording method according to any one of [1] to [9].
[11]
The temperature difference of the surface temperature of the recording medium in the ink adhering step is 1 to 10 ° C.
The recording method according to any one of [1] to [10].
[12]
A colored ink composition containing a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions is ejected from an inkjet head and recorded. An ink adhering step for adhering to the medium;
A treatment liquid adhering step for adhering a treatment liquid containing a flocculant for aggregating the components of the colored ink composition to the recording medium,
The ink adhering step is performed by performing a plurality of scans for discharging the colored ink composition while changing the relative position of the inkjet head to the recording medium in a scanning direction,
The difference in surface temperature of the recording medium when attaching the colored ink in the ink attaching step is 1 to 10 ° C.
Recording method.
[13]
[1] A recording apparatus that performs recording by the recording method according to any one of [12].

It is a schematic sectional drawing which shows the structure of the recording device used for this embodiment. 4A and 4B are partial side views of the recording apparatus in an ink attaching process, in which FIG. 5A shows a mode in which a carriage is not arranged, and FIG. 4B shows a mode in which a carriage is arranged. FIG. 3 is a schematic perspective view illustrating a configuration example around a carriage of the recording apparatus used in the embodiment. It is a front view which shows an example of the fan which the recording apparatus used for this embodiment has.

  Hereinafter, an embodiment of the present invention (hereinafter referred to as “the present embodiment”) will be described in detail with reference to the drawings as necessary. However, the present invention is not limited to this, and the gist thereof is described below. Various modifications are possible without departing from the scope. In the drawings, the same elements are denoted by the same reference numerals, and redundant description is omitted. Further, positional relationships such as up, down, left and right are based on the positional relationships shown in the drawings unless otherwise specified. Further, the dimensional ratios in the drawings are not limited to the illustrated ratios.

〔Recording method〕
The recording method of the present embodiment comprises a coloring ink composition comprising a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions. An ink adhering step for discharging from an ink jet head and adhering to a recording medium; and a processing liquid adhering step for adhering a processing liquid containing an aggregating agent for aggregating the components of the colored ink composition to the recording medium. The ink adhering step is performed by performing a plurality of scans for discharging the colored ink composition while changing the relative position of the ink jet head to the recording medium in the scanning direction, and performing one scan in the ink adhering step. The maximum distance is 50 cm or more.

  As described above, it has been found that there is an inherent problem that the color difference increases in the recording method in which the distance of one scanning is long. An example of a recording apparatus having a long scanning distance is a large format printer.

  When processing liquid is used, the ink droplets attached to the recording medium can be fixed early, thereby improving the image quality. On the other hand, when multiple color ink compositions are used, there is a difference in aggregation depending on the order of ink composition attachment. Therefore, it is estimated that the color difference becomes large. On the other hand, when the reaction liquid is not used, it is presumed that gathering occurs before the attached ink droplets are fixed and the color difference increases. The color difference is a color difference depending on a place even though an image of the same color is recorded in one recording medium. In particular, when a recording medium having a wide scanning direction is used, the distance of one scanning tends to be long and a color difference in the scanning direction tends to occur. If the distance of one scan is long, it is assumed that the influence that causes the color difference described later is large. This color difference is also called in-plane color difference.

  Also, in a printing apparatus with a wide width in the scanning direction of the printing medium, the scanning time for one pass is long. In such a case, printing can be performed by increasing the carriage moving speed in order to improve productivity and image quality. Done. However, at the same time, the influence of the wind due to the movement becomes stronger, and this influence can affect the color difference.

  In addition to or instead of using the treatment liquid, the image quality is improved by increasing the heating temperature in order to accelerate the drying of the ink. In addition, when recording is performed on a low-absorbency recording medium or a non-absorbent recording medium, it is effective for improving the image quality to promote drying by performing heating during recording. However, it has been found that the color difference tends to become large even by drying during recording. This is because, as a drying means, when a heater is provided on the back of the recording medium or when wind is applied, temperature unevenness is likely to occur in the width direction, and in particular, a recording apparatus having a wide width in the scanning direction of a recording medium such as a large format printer. In this case, it is presumed that this is because it cannot be ignored from the viewpoint of color difference. In particular, when the width in the scanning direction is wide, there are many heater joints and wind outlets, and there are many locations where in-plane temperature differences are likely to occur due to the configuration of the device, and the temperature difference increases. There is also a factor in being easy. As a result, a color difference due to temperature unevenness due to the above-described heating place occurs.

  Furthermore, the drying of the vicinity of the nozzles due to the heating may cause the weight of the ejected dots to change, or the occurrence of landing deviation due to non-uniform meniscus may occur. In a printing method using a printing apparatus having a wide width in the scanning direction, it is assumed that color differences are likely to occur due to such complex factors.

  In contrast, in the present embodiment, the color difference can be reduced by using the basic color ink composition and the special color ink composition in combination. This is because when the color of the special color area is recorded using the special color ink composition, the dots on the recording surface slightly fluctuate due to landing deviation or the difference in the spread of the dots due to uneven drying. Even if this occurs, it is assumed that the color difference is less likely to appear. Thereby, it is possible to record with a small color difference from the basic color area to the special color area. Hereinafter, each process is explained in full detail. The spot color area is a portion recorded with the spot color of the image.

  On the other hand, when reproducing the color of the special color area on the recording medium as a secondary color by, for example, densely mixing and mixing two color ink dots, the fluctuation of the dot gathering state on the recording surface and the spread of the dots are described above. It is estimated that the color difference becomes large when the difference in direction occurs or when the ink deposition order is different.

[Ink adhesion process]
The ink adhering step is a step of removing a colored ink composition including a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions from an inkjet head. It is a step of discharging and adhering to a recording medium. Here, the ink jet head is a head that performs recording by ejecting an ink composition toward a recording medium, and the head is provided for a cavity that ejects a stored ink composition from a nozzle, and the ink composition. An ejection driving unit that applies ejection driving force; and a nozzle that ejects the ink composition to the outside of the head. The ejection drive unit is formed using an electromechanical conversion element such as a piezoelectric element that changes the volume of the cavity by mechanical deformation, or an electrothermal conversion element that generates and discharges bubbles in ink by generating heat. be able to.

  In addition, the ink adhering step is performed by performing a plurality of scans for discharging the ink composition while changing the relative position of the inkjet head to the recording medium in the scanning direction. That is, the inkjet head is preferably a serial head. In the serial system using a serial head, the head is moved along the main scanning direction (the horizontal direction and the width direction of the recording medium), and ink droplets are ejected from the nozzle openings of the head in conjunction with this movement, thereby recording. Images can be recorded on the medium. Scanning may be performed by moving the carriage in the main scanning direction, for example, by mounting the head on the carriage. In the present invention, scanning is also referred to as main scanning.

  Then, by repeating scanning and sub-scanning alternately, the recording medium is gradually moved along the sub-scanning direction (vertical direction of the recording medium, conveyance direction) to advance the recording.

  The maximum distance of one scan is 50 cm or more, preferably 50 to 500 cm, more preferably 50 to 400 cm, still more preferably 55 to 300 cm, and still more preferably 60 to 200 cm. Further, it is particularly preferably 70 to 190 cm, more particularly preferably 100 to 180 cm, and still more preferably 130 to 170 cm.

  When the distance is 50 cm or more, a recorded material useful for display or the like can be obtained. On the other hand, the color difference of the obtained recorded matter tends to occur, but according to the present invention, the color difference can be reduced, and the present invention is particularly useful. The upper limit of the distance is not particularly limited, but is preferably 500 cm or less from the viewpoint of the configuration of the recording apparatus and the reduction in color difference.

  “Maximum distance of one scan” refers to the distance at which one point of the inkjet head faces the recording medium when recording is performed from end to end in the scanning direction of the recording medium in one scan. When performing the recording method, scanning that is shorter than the maximum distance of the above-described one scanning may be performed according to the image to be recorded.

  In addition to the above, the cause of the color difference of the printed matter that can be obtained when the maximum distance of one scanning is longer is that the part that floats from the platen when the recording medium is transported is generated. It is estimated that there may be a landing deviation (positional deviation). Furthermore, the floating of the recording medium also causes a temperature difference in the surface temperature of the recording medium.

  It is preferable to use a recording medium whose width in the scanning direction of the recording medium is in the range of the maximum distance of one scanning described above. In this case, it is preferable in that the maximum distance of one scanning can be set as described above.

The maximum time for one scan in the ink adhering step is preferably 0.8 seconds or more. Preferably it is 0.8-5 seconds or less, More preferably, it is 0.8 second or more and 4 seconds or less, More preferably, it is 0.8 second or more and 3 seconds or less, Most preferably, it is 1.5-2.5. Seconds. It is preferable that the maximum time of one scanning is within the above range in that it is suitable for recording on a recording medium whose width is within the above range. Moreover, although the color difference of the obtained recorded matter tends to occur, the present invention is particularly useful in that the color difference can be reduced. The “maximum time for one scan” is the time during which one point of the inkjet head faces the recording medium when recording is performed from end to end in the scanning direction of the recording medium. Say. Note that when performing the recording method, scanning may be performed for a time shorter than the maximum time of one scanning described above, depending on the image to be recorded.
In addition, the average scanning speed in an ink adhesion process becomes like this. Preferably it is 60-100 cm / sec.

  It is preferable to provide a heating process for heating the recording medium, and to perform an ink adhesion process on the recording surface of the heated recording medium. For heating the recording medium, a heating mechanism such as a platen heater, a warm air heater, or an IR heater can be used. The surface temperature of the recording medium when depositing the ink composition in the ink deposition step is preferably 20 to 60 ° C., more preferably 20 to 50 ° C., even more preferably 25 to 45 ° C., and further Preferably it is 30-40 degreeC, Most preferably, it is 32-38 degreeC. By heating the recording medium and increasing the surface temperature, the image quality of the obtained recorded matter tends to be improved. In addition, when the surface temperature of the recording medium is 60 ° C. or less, the ejection stability and the recovery from clogging of the nozzles tend to be further improved.

  In addition, the heating process may be such that the surface temperature of the recording medium becomes higher than the normal temperature due to the recording medium receiving heat generated by the recording apparatus itself. That is, it means that the surface temperature of the recording medium is higher than room temperature.

  The surface temperature of the recording medium is the total temperature of the area that can be opposed during main scanning of the head of the recording medium supported by the platen. Use the highest temperature.

  The temperature of the surface of the recording medium during recording in the region may cause a temperature difference due to a portion that is lower than the maximum temperature. The temperature difference tends to be larger as the maximum distance of one scan is longer. This is because it becomes difficult to uniformly heat the entire recording medium in the scanning direction.

  The temperature difference between the maximum temperature and the minimum temperature of the entire area of the area of the recording medium head supported by the platen that can be opposed during main scanning is preferably 10 ° C or less, more preferably 7 ° C or less, and more preferably 5 ° C or less. Further preferred. The temperature difference is preferably 1 ° C. or higher, more preferably 2 ° C. or higher, and further preferably 3 ° C. or higher. When the temperature difference is in the above range, it is preferable from the viewpoint that the color difference reduction is more excellent and the degree of freedom in designing the recording apparatus is increased. A lower surface temperature of the recording medium tends to reduce the temperature difference, which is preferable in terms of reducing the color difference.

  By promoting the drying of the ink by the heating process, density unevenness suppression and the like are more excellent, and color difference suppression is also excellent. In this respect, it is preferable that the surface temperature of the recording medium at the time of ink adhesion is not less than the above range. On the other hand, it is preferable that the surface temperature of the recording medium is not more than the above range in that the color difference suppression is more excellent by suppressing the occurrence of temperature unevenness which causes the color difference.

  Moreover, it is preferable to provide the ventilation process which sends an air to the area | region where the ink composition adhered in the ink adhesion process. Although it does not restrict | limit especially as a ventilation method, For example, the air blower etc. which were provided in the recording device are used. By having a blowing process, the ink composition adhering to the recording medium can be efficiently dried, and roughness and density unevenness of the obtained recorded matter tend to be further suppressed.

  The temperature of the air in the blowing process may be warm air that heats the recording medium. In this case, wind may be sent as a heating process for heating the recording medium. In this case, it is preferable in that the image quality of the obtained recording medium is further improved. Or you may send a wind as a normal temperature wind which does not heat a recording medium. This is also preferable in that the image quality of the recording medium that can promote the evaporation of the ink components is further improved and that the ejection stability of the ink from the head is excellent. The temperature of the air sent may be the temperature of the surface temperature of the recording medium in the heating step for heating the recording medium. Alternatively, the temperature of the air to be sent is specifically preferably 70 ° C. or lower, more preferably 50 ° C. or lower, further preferably 40 ° C. or lower, even more preferably 35 ° C. or lower, and particularly preferably 30 ° C. or lower. The lower limit of the temperature of the wind is not limited, but 20 ° C. or higher is preferable. On the other hand, when the air blowing process is provided, a difference in the surface temperature of the recording medium tends to occur.

It is preferable that the recording area where the colored ink composition and the treatment liquid are attached has an area where the total adhesion amount of the colored ink composition is 5 to 30 mg / inch ² and has an area which is 7 to 25% by mass. It is more preferable to have a region that is 9 to 20% by mass. By having such an adhesion amount region, a recorded material useful for display or the like can be obtained. Furthermore, it is also preferable from the above point that the total adhesion amount of the area where the total adhesion amount of the colored ink composition in the recording area is within the above range.

(Post-heating process)
It is preferable to have a post-heating step of further heating the recording medium after the ink attaching step. Although it does not restrict | limit especially as a heating method, For example, a platen heater, a warm air heater, and IR heater are mentioned. The heating temperature can be preferably 60 ° C. or higher. Preferably it is 70-110 degreeC, More preferably, it is 80-100 degreeC.

(Colored ink composition)
The colored ink composition includes a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the three ink compositions. Here, “hue angle” refers to the hue angle of the CIE color system when an image is recorded with the ink composition and measured. Specifically, an image is recorded using each one ink, and the recording unit is colorimetrically measured. The image used here may be any image that can confirm the hue angle of the recording portion due to the adhesion of ink. For example, there is a white recording medium in which ink is adhered at an adhesion amount of 10 mg / inch ² .

  The cyan ink composition, magenta ink composition, and yellow ink composition have different hue angles. In this embodiment, the hue angle (∠H °) of the cyan ink composition is 230 ° to 260 °, the hue angle (∠H °) of the magenta ink composition is 330 ° to 360 °, and yellow The hue angle (∠H °) of the ink composition is preferably 80 ° to 110 °. A cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition are chromatic color inks capable of recording chromatic colors having the above hue angles.

  The special color ink composition is not particularly limited as long as the hue angle is different from the cyan ink composition, the magenta ink composition, and the yellow ink composition used in the recording method. For example, the orange ink composition and the red ink Examples include at least one of a composition, a green ink composition, and a blue ink composition. The special color ink composition may be used alone or in combination of two or more. By using the special color ink composition, the color difference is suppressed. The hue angle of the special color ink is not limited, but is preferably in the range described later. Further, for example, it may be outside the preferable hue angle range of the above-mentioned cyan ink composition, magenta ink composition, and yellow ink composition.

  In addition to the above, the colored ink composition may further include a black ink composition. By using the black ink composition, the color expression area of the obtained recorded matter tends to be further expanded. The special color ink composition is not a black ink composition.

  Each ink composition contained in the colored ink composition contains a color material. It preferably contains a solvent, and can contain a resin, a wax, an antifoaming agent and a surfactant as necessary. It is preferable to contain resin fine particles and an organic solvent. A water-based ink composition is preferred. The aqueous composition is a composition containing water as one of the main solvent components, and the water content is preferably 45% by mass or more. Each ink composition contained in the colored ink composition can be exemplified by the same basic composition independently, except that the hue angle is different due to different types of color materials used. Hereinafter, each component will be described.

(Coloring material)
Examples of the color material include pigments and dyes. A pigment is preferable in terms of excellent light resistance.
The pigment used in the cyan ink composition is not particularly limited. I. Pigment Blue 1, 2, 3, 15, 15: 1, 15: 2, 15: 3, 15:34, 15: 4, 16, 18, 25, 65, 66, C.I. I. Bat Blue 4 and 60 are listed. The hue angle (∠H °) of the cyan ink composition is preferably 230 ° to 260 °.

  Although it does not restrict | limit especially as a pigment used for a magenta ink composition, For example, C.I. I. Pigment Red 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 14, 15, 16, 18, 19, 21, 22, 23, 30, 31, 32, 37, 38, 40, 41, 42, 48 (Ca), 48 (Mn), 53, 57 (Ca), 57: 1, 88, 114, 122, 123, 144, 146, 150, 166, 168, 170, 171 176, 179, 184, 185, 187, 202, 209, 219, 224, 245, or C.I. I. Pigment violet 33, 43, 50. The hue angle (∠H °) of the magenta ink composition is preferably 330 ° to 360 °.

  The pigment used in the yellow ink composition is not particularly limited. I. Pigment Yellow 1, 2, 3, 4, 5, 6, 7, 10, 11, 12, 13, 14, 16, 17, 24, 34, 35, 37, 53, 55, 65, 73, 74, 75, 81, 83, 93, 94, 95, 97, 98, 99, 108, 109, 110, 113, 114, 117, 120, 124, 128, 129, 133, 138, 139, 147, 151, 153, 154, 167, 172, 180. The hue angle (∠H °) of the yellow ink composition is preferably 80 ° to 110 °.

  The carbon black used in the black ink composition is not particularly limited. 2300, no. 900, MCF88, No. 33, no. 40, no. 45, no. 52, MA7, MA8, MA100, no. 2200B (Mitsubishi Chemical Corporation), Raven 5750, Raven 5250, Raven 5000, Raven 3500, Raven 1255, Raven 700, etc. Rega1 330R, Rega1 660R, Mogul L, Monarch 700, Monarch 800, Monarch 880, Monarch 900, Monarch 1000, Monarch 1100, Monarch 1300, Monarch 1400, etc. (Cabot Corp. CA Kol. , Color B lack FW2, Color Black FW2V, Color Black FW18, Color Black FW200, Color B1ack S150, Color Black S160, Color Black S170, Printex 35, Printex U, Printex V, Printex 140U, Special Black 6, Special Black 5, Special Black 4A , Special Black 4 (manufactured by Degussa).

  Although it does not restrict | limit especially as a pigment used for an orange ink composition, For example, C.I. I. Pigment orange 5, 43, 62. The hue angle (∠H °) of the orange ink composition is preferably 30 ° to 80 °.

  Although it does not restrict | limit especially as a pigment used for a red ink composition, For example, C.I. I. Pigment red 17, 49: 2, 112, 117, 175, 177, 178, 188, 254, 255, 264, 149. The hue angle (∠H °) of the red ink composition is preferably 0 ° to 30 °.

  Although it does not restrict | limit especially as a pigment used for a green ink composition, For example, C.I. I. Pigment green 7,36. The hue angle (∠H °) of the green ink composition is preferably 110 ° to 230 °.

  Although it does not restrict | limit especially as a pigment used for a blue ink composition, For example, C.I. I. Pigment blue 21, 22, 60, 64, C.I. I. Pigment violet 3, 19, 23, 32, 36, 38. The hue angle (∠H °) of the blue ink composition is preferably 260 ° to 330 °.

  Examples of the dye include C.I. I. Acid Yellow, C.I. I. Acid Red, C.I. I. Acid Blue, C.I. I. Acid Orange, C.I. I. Acid Violet, C.I. I. Acid dyes such as Acid Black; C.I. I. Basic yellow, C.I. I. Basic Red, C.I. I. Basic blue, C.I. I. Basic orange, C.I. I. Basic violet, C.I. I. C. basic dyes such as basic black; I. Direct yellow, C.I. I. Direct Red, C.I. I. Direct Blue, C.I. I. Direct orange, C.I. I. Direct violet, C.I. I. Direct dyes such as Directed Black; C.I. I. Reactive Yellow, C.I. I. Reactive Red, C.I. I. Reactive Blue, C.I. I. Reactive Orange, C.I. I. Reactive Violet, C.I. I. Reactive dyes such as reactive black; C.I. I. Disperse Yellow, C.I. I. Disper thread, C.I. I. Disperse Blue, C.I. I. Disperse orange, C.I. I. Disperse Violet, C.I. I. Disperse dyes such as disperse black are listed. A color material may be used individually by 1 type, or may use 2 or more types together.

  When the color material is a pigment, it can be used in the state of a pigment dispersion. The pigment dispersion may contain a dispersant as required in addition to the pigment and the solvent. Examples of the solvent include water and hydrophilic solvents such as diethylene glycol. Examples of the dispersant include a styrene-acrylic acid copolymer. Although not particularly limited, the acid value of the dispersant is preferably 20 mgKOH / g or more from the viewpoint of dispersibility.

  The coloring material content of each colored ink composition may be different, but is preferably 0.1 to 10% by mass, more preferably 0.5 to 7% by mass, based on the total amount of the ink composition. %, More preferably 1 to 4% by mass, and even more preferably 1.5 to 4% by mass.

(solvent)
Examples of the solvent include water and organic solvents. The content of water is preferably 50 to 80% by mass, more preferably 55 to 75% by mass, and further preferably 60 to 70% by mass with respect to the total amount of the ink composition.

  The organic solvent is not particularly limited, and specifically, glycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-propanediol, 1,2-butanediol, 1,2 -Pentanediol, 1,2-hexanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, diethylene glycol mono-n-propyl ether, ethylene glycol mono-iso-propyl ether, diethylene glycol Mono-iso-propyl ether, ethylene glycol mono-n-butyl ether, ethylene glycol mono-t-butyl ether, diethylene glycol mono-n-butyl ether, triethylene glycol monobutyl Ether, diethylene glycol mono-t-butyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-t-butyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-iso-propyl ether, propylene glycol mono- n-butyl ether, dipropylene glycol mono-n-butyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-iso-propyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol ethyl methyl ether, diethylene glycol Butylme Ether, triethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, tripropylene glycol dimethyl ether, methanol, ethanol, n-propyl alcohol, iso-propyl alcohol, n-butanol, 2-butanol, Examples include alcohols or glycols such as tert-butanol, iso-butanol, n-pentanol, 2-pentanol, 3-pentanol, and tert-pentanol. An organic solvent may be used individually by 1 type, and may be used in combination of 2 or more type.

  The content of the organic solvent is preferably 5 to 40% by mass, more preferably 10 to 35% by mass, and further preferably 15 to 30% by mass with respect to the total amount of the ink composition.

(Nitrogen-containing solvent)
Further, it is also preferable to use a nitrogen-containing solvent as the organic solvent. By including the nitrogen-containing solvent, the effect of promoting the softening of the resin particles of the nitrogen-containing solvent tends to improve the abrasion resistance even when the heating temperature is low. Further, when the recording medium is a low-absorbing recording medium or a non-absorbing recording medium, the adhesion tends to be further improved due to the effect of softening the surface of the recording medium. The nitrogen-containing solvent is not particularly limited, and examples thereof include pyrrolidone solvents, imidazolidinone solvents, amide ether solvents, pyridine solvents, pyrazine solvents, and pyridone solvents.

  Moreover, an amide solvent is preferably used as the nitrogen-containing solvent. Examples of the amide solvent include cyclic amide solvents and acyclic amide solvents. Examples of the cyclic amide solvent include the above pyrrolidone solvents. Examples of the acyclic amide solvent include the amide ether solvents described above. Among them, pyrrolidone solvents are preferable, and examples thereof include 2-pyrrolidone, N-methyl-2-pyrrolidone, and N-ethyl-2-pyrrolidone. A nitrogen-containing solvent may be used individually by 1 type, and may use 2 or more types together.

  From the above viewpoint, the content of the nitrogen-containing solvent is preferably 3 to 25% by mass, more preferably 5 to 23% by mass, and still more preferably 10 to 21% by mass with respect to the total amount of the ink composition. It is.

  The content of the organic solvent other than the nitrogen-containing solvent in the organic solvent is preferably 1 to 20% by mass, more preferably 5 to 20% by mass, and further preferably 8 to 16% by mass. Among organic solvents other than nitrogen-containing solvents, polyols and alkylene glycol ethers are preferable. Polyols are organic solvents having two or more hydroxyl groups in the molecule. The number of hydroxyl groups is preferably 2 to 3. Alkylene glycol ethers are mono- or diethers of alkylene glycols. The ether is preferably an alkyl ether, and more preferably an alkyl ether having 1 to 5 carbon atoms. The alkylene glycol preferably has 2 to 5 carbon atoms.

  The organic solvent preferably includes those having a normal boiling point of 180 to 280 ° C, more preferably includes 200 to 260 ° C, and further preferably includes 210 to 250 ° C. In this case, it is preferable in that various image quality of the image is more excellent.

  Further, the content of the organic solvent with respect to the composition having a normal boiling point exceeding 280 ° C. is preferably 1% by mass or less, more preferably 0.5% by mass or less, and 0.1% by mass or less. More preferably, the lower limit may be 0% by mass. In this case, it is preferable in that various image quality of the image is more excellent.

(resin)
Examples of the resin include those that dissolve in the ink composition and those that disperse in the form of fine particles such as an emulsion. By using such a resin, there is a tendency that a recorded matter having better abrasion resistance can be obtained. In particular, it tends to contribute to an improvement in the binding property (rubbing resistance) between the recording medium and the ink coating film. Examples of such resins include, but are not limited to, acrylic resins, vinyl acetate resins, vinyl chloride resins, butadiene resins, styrene resins, polyester resins, crosslinked acrylic resins, crosslinked styrene resins, benzoguanamine resins, phenol resins, silicone resins. , An epoxy resin, a urethane resin, a paraffin resin, a fluororesin, a water-soluble resin, and a copolymer in which monomers constituting these resins are combined. Although it does not specifically limit as a copolymer, For example, a styrene butadiene resin and a styrene acrylic resin are mentioned. Moreover, polymer latex containing these resins can be used as the resin. Examples thereof include polymer latex containing fine particles of acrylic resin, styrene acrylic resin, styrene resin, cross-linked acrylic resin, and cross-linked styrene resin. In addition, resin may be used individually by 1 type and may use 2 or more types together.

The acrylic resin is a resin that is a homopolymer or copolymer obtained by polymerization using at least an acrylic monomer as a monomer. Examples of acrylic monomers include (meth) acrylate, (meth) acrylic acid, acrylamide, acrylonitrile and the like. When the acrylic resin is a copolymer, an acrylic-vinyl resin using a vinyl monomer as another monomer may be used, and among them, a styrene acrylic resin using styrene as a vinyl monomer may be used.
As the resin, an acrylic resin, a urethane resin, a polyester resin, or the like is easily available, and is preferable in that it is easily obtained as a resin having desired characteristics.

  The content of the resin is preferably 1 to 12.5% by mass, more preferably 2 to 10% by mass, and further preferably 3 to 7.5% by mass with respect to the total amount of the ink composition. . When the resin content is 1% by mass or more, the abrasion resistance tends to be further improved as described above. Further, when the resin content is 12.5% by mass or less, the viscosity of the ink is lowered, the ejection stability is excellent, and the clogging recovery property tends to be excellent.

(wax)
Examples of the wax include those that dissolve in the ink composition and those that are dispersed in the form of fine particles such as an emulsion. By using such a wax, there is a tendency to obtain a recorded matter having better abrasion resistance. In particular, there is a tendency to contribute to improvement of abrasion resistance due to uneven distribution on the surface of the ink coating film on the recording medium (interface between the air and the ink coating film). Such a wax is not particularly limited, but for example, ester wax of higher fatty acid and higher monohydric alcohol or dihydric alcohol (preferably monohydric alcohol), paraffin wax, microcrystalline wax, olefin wax, or a mixture thereof. Is mentioned.

  The content of the wax is preferably 0.1 to 5% by mass, preferably 0.2 to 4% by mass, and preferably 0.3 to 3% by mass with respect to the total amount of the ink composition. . When the wax content is 0.1% by mass or more, the abrasion resistance tends to be further improved as described above. Further, when the content of the wax is 5% by mass or less, the viscosity of the ink is lowered, the discharge stability is excellent, and the clogging recovery property tends to be excellent.

(Surfactant)
The surfactant is not particularly limited, and examples thereof include acetylene glycol surfactants, fluorine surfactants, and polysiloxane surfactants.

  The acetylene glycol-based surfactant is not particularly limited, and examples thereof include 2,4,7,9-tetramethyl-5-decyne-4,7-diol and 2,4,7,9-tetramethyl-5- Selected from alkylene oxide adducts of decyne-4,7-diol and alkylene oxide adducts of 2,4-dimethyl-5-decyn-4-ol and 2,4-dimethyl-5-decyn-4-ol One or more are preferred. Although it does not specifically limit as a commercial item of acetylene glycol type-surfactant, For example, E series, such as Olphine 104 series and Olphine E1010, Surfinol 465, Surfynol 61 (Nissin Chemical Industry CO., Ltd.) product name). One acetylene glycol surfactant may be used alone, or two or more acetylene glycol surfactants may be used in combination.

  The fluorosurfactant is not particularly limited. For example, perfluoroalkyl sulfonate, perfluoroalkyl carboxylate, perfluoroalkyl phosphate, perfluoroalkyl ethylene oxide adduct, perfluoroalkyl betaine, perfluoroalkyl betaine, A fluoroalkylamine oxide compound is mentioned. Although it does not specifically limit as a commercial item of a fluorochemical surfactant, For example, S-144, S-145 (Asahi Glass Co., Ltd. product); FC-170C, FC-430, Fluorard-FC4430 (Sumitomo 3M Co., Ltd. product) FSO, FSO-100, FSN, FSN-100, FS-300 (manufactured by Dupont); FT-250, 251 (manufactured by Neos Co., Ltd.) and the like. A fluorine-type surfactant may be used individually by 1 type, and may use 2 or more types together.

  Examples of silicone surfactants include polysiloxane compounds and polyether-modified organosiloxanes. Although it does not specifically limit as a commercial item of a silicone type surfactant, Specifically, BYK-306, BYK-307, BYK-333, BYK-341, BYK-345, BYK-346, BYK-347, BYK -348, BYK-349 (above trade name, manufactured by Big Chemie Japan Co., Ltd.), KF-351A, KF-352A, KF-353, KF-354L, KF-355A, KF-615A, KF-945, KF-640 , KF-642, KF-643, KF-6020, X-22-4515, KF-6011, KF-6012, KF-6015, KF-6017 (all trade names, manufactured by Shin-Etsu Chemical Co., Ltd.), and the like.

  The surfactant content is preferably 0.1 to 3% by mass, more preferably 0.2 to 2% by mass, and still more preferably 0.3 to 1%, based on the total amount of the ink composition. 0.5% by mass.

(Defoamer)
Although it does not restrict | limit especially as an antifoamer, For example, a silicone type antifoamer, a polyether type | system | group antifoamer, a fatty-acid ester type | system | group antifoamer, and an acetylene glycol type | system | group antifoamer are mentioned. Commercially available antifoaming agents include BYK-011, BYK-012, BYK-017, BYK-018, BYK-019, BYK-020, BYK-021, BYK-022, BYK-023, BYK-024, BYK. -025, BYK-028, BYK-038, BYK-044, BYK-080A, BYK-094, BYK-1610, BYK-1615, BYK-1650, BYK-1730, BYK-1770 (above trade name, Big Chemie Japan Co., Ltd.), Surfynol DF37, DF110D, DF58, DF75, DF220, MD-20, Envirogem AD01 (all trade names, manufactured by Nissin Chemical Industry Co., Ltd.) . An antifoamer may be used individually by 1 type, and may mix and use 2 or more types.

  The content of the antifoaming agent is preferably 0.03 to 0.7% by mass, more preferably 0.05 to 0.5% by mass, and still more preferably 0, with respect to the total amount of the ink composition. 0.08 to 0.3% by mass.

(Other ingredients)
The ink composition used in the present embodiment includes, if necessary, a dissolution aid, a viscosity modifier, a pH adjuster, an antioxidant, an antiseptic, an antifungal agent, a corrosion inhibitor, and a metal that affects dispersion. Various additives may be included such as chelating agents for trapping ions.

(recoding media)
Examples of the recording medium include an absorptive recording medium, a low-absorbing recording medium, and a non-absorbing recording medium. Among these, a low-absorbency recording medium or a non-absorbent recording medium is preferable in that a recorded matter useful for display can be produced. By using such a recording medium, roughness, density unevenness, and color difference of the obtained recorded matter are likely to occur, and the present invention is particularly useful.

  The absorbent recording medium is not particularly limited, but, for example, plain paper such as electrophotographic paper having high penetrability of the ink composition, ink jet paper (an ink absorbing layer composed of silica particles or alumina particles, or polyvinyl alcohol). (Inkjet dedicated paper provided with an ink absorbing layer composed of a hydrophilic polymer such as (PVA) or polyvinylpyrrolidone (PVP)).

  Although it does not specifically limit as a low absorptive recording medium, For example, the coated paper by which the coating layer for receiving an ink was provided in the surface is mentioned. The coated paper is not particularly limited, and examples thereof include printing paper such as art paper, coated paper, and matte paper, and wallpaper.

  The non-absorbent recording medium is not particularly limited. For example, films and plates of plastics such as polyvinyl chloride, polyethylene, polypropylene, polyethylene terephthalate (PET), polycarbonate, polystyrene, polyurethane, etc .; iron, silver, copper, aluminum Metal plates such as such as metal plates or plastic films produced by vapor deposition of these various metals, alloy plates such as stainless steel or brass, etc .; polyvinyl chloride, polyethylene, Examples thereof include a recording medium obtained by bonding (coating) a plastic film such as polypropylene, polyethylene terephthalate (PET), polycarbonate, polystyrene, or polyurethane.

Here, “low-absorbing recording medium” or “non-absorbing recording medium” refers to a recording medium having a water absorption amount of 10 mL / m ² or less from the start of contact to 30 msec in the Bristow method. This Bristow method is the most popular method for measuring the amount of liquid absorbed in a short time, and is also adopted by the Japan Paper Pulp Technology Association (JAPAN TAPPI). For details of the test method, refer to Standard No. of “JAPAN TAPPI Paper Pulp Test Method 2000”. 51 "Paper and paperboard-Liquid absorbency test method-Bristow method". The low-absorbency recording medium refers to a recording medium having the above water absorption amount of 5 mL / m ² or more and 10 mL / m ² or less. On the other hand, an absorptive recording medium refers to a recording medium having a water absorption amount of more than 10 mL / m ² .

  Non-absorbent recording media or low-absorbent recording media can be classified according to the wettability of the recording surface to water. For example, a 0.5 μL water droplet is dropped on the recording surface of the recording medium, and the reduction rate of the contact angle (comparison of the contact angle at 0.5 ms after landing and the contact angle at 5 seconds) is measured. Can be characterized. More specifically, as a property of the recording medium, the non-absorbing property of the “non-absorbing recording medium” indicates that the above-described reduction rate is less than 1%, and the low-absorbing property of the “low-absorbing recording medium” This means that the rate of decrease of 1% or more and less than 5%. Moreover, absorptivity means that said reduction rate is 5% or more. In addition, a contact angle can be measured using portable contact angle meter PCA-1 (made by Kyowa Interface Science Co., Ltd.) etc.

[Processing liquid adhesion process]
The treatment liquid attaching step is a step of attaching a treatment liquid containing an aggregating agent for aggregating the components of the colored ink composition to the recording medium. Note that the treatment liquid is applied to at least a region to which the colored ink composition is attached or a region to which the colored ink composition is attached. By providing the treatment liquid adhesion step, the components of the colored ink composition are likely to aggregate on the surface of the recording medium, and the ink components can be fixed on the recording medium at an early stage. In the case where no treatment liquid is used, ink droplets bleed on the recording medium, resulting in uneven density. By using the treatment liquid, uneven density is suppressed and the color difference can be reduced. Further, by using the treatment liquid, it is possible to minimize the need to heat the recording medium and fix the ink at an early stage in order to reduce the density unevenness, and as a result, the color difference can be reduced.

  However, even when a processing solution is used, a color difference may occur. Since ink droplets aggregate on the recording medium early due to the processing liquid, there is an effect on the color difference due to the difference in the landing order of each color between main scans. It is estimated that there is an influence of the difference. In addition, in the case where there is a step of heating and drying the treatment liquid adhering to the recording medium, if there is uneven heating temperature depending on the location of the recording medium, the unevenness of the treatment liquid may also vary depending on the location, and ink aggregation It is also speculated that this will affect the degree of

  As a method of attaching the treatment liquid, in addition to the method of attaching using the ink jet method as described above, the treatment liquid may be applied using a bar coater, a roll coater, a spray or the like. An example of the ink jet method is the same method as the method for discharging the ink composition.

The treatment liquid attaching step may be performed before or after the ink attaching step. Further, when the treatment liquid adhesion step is performed before the ink adhesion step, the ink adhesion step may be performed before the treatment liquid is dried, or the ink adhesion step may be performed after the treatment liquid is dried. At this time, the interval from the treatment liquid deposition to the ink composition deposition is preferably within 20 seconds. The recording medium may be heated in order to dry the adhering processing liquid before adhering ink. The surface temperature of the recording medium when the treatment liquid is adhered and / or from the adhesion to the ink adhesion may be in the range of the recording medium surface temperature when the ink is adhered.
Further, when the treatment liquid adhesion step is performed after the ink adhesion step, it is preferable to perform the treatment liquid adhesion step before the ink composition is dried.

  The treatment liquid attaching step may include a step of drying the treatment liquid attached to the recording medium. As the drying unit, for example, a platen heater, a warm air heater, an IR heater or the like having a heating function, a blower without a heating function, or the like is used. In addition, a drying temperature can be 70-110 degreeC.

It is preferable that the recording area to which the coloring ink composition and the treatment liquid are attached has an area in which the amount of the treatment liquid adhered to the adhesion amount of the color ink composition is 5 to 50% by mass, and the area that is 5 to 40% by mass. It is more preferable to have a region of 5 to 30% by mass. When the adhesion amount is not less than the above range, uneven density and roughness of the image are improved, and the color difference tends to be further suppressed. In addition, when the adhesion amount is equal to or less than the above range, it is possible to prevent the color aggregation from increasing due to excessive ink aggregation and an increase in color difference.
Furthermore, it is also preferable from the above point that the amount of the treatment liquid deposited in the region of the recording region where the amount of the treatment liquid deposited relative to the amount of the colored ink composition deposited is within the above range.

(Processing liquid)
The treatment liquid is not particularly limited as long as it contains an aggregating agent that aggregates the components of the ink composition. If necessary, water, an organic solvent, an antifoaming agent, and a surfactant may be included. An aqueous processing solution is preferred. Examples of the components that may be included in the treatment liquid other than the flocculant include those other than the colorant among the components that may be included in the above-described colored ink composition, and the types and contents thereof are those of the colored ink composition. As well as, it can be done independently of the colored ink composition. The treatment liquid is not a composition used for coloring the recording medium. The content of the coloring material in the treatment liquid is preferably 0.1% by mass or less, more preferably 0.05% by mass or less, still more preferably 0.01% by mass or less, and the lower limit is 0.00% by mass. %.

(Flocculant)
The aggregating agent is not particularly limited as long as it agglomerates the components of the ink composition, and examples thereof include polyvalent metal salts, organic acids or salts thereof, and cationic resins. A flocculant may be used individually by 1 type and may use 2 or more types together.

  Although it does not specifically limit as a polyvalent metal salt, For example, the polyvalent metal salt of an inorganic acid or the polyvalent metal salt of an organic acid is mentioned. Although it does not restrict | limit especially as a polyvalent metal, For example, the 2nd group alkaline earth metal (for example, magnesium, calcium) of a periodic table, the 3rd group transition metal (for example, lanthanum) of a periodic table, Examples include earth metals (for example, aluminum) and lanthanides (for example, neodymium) from Group 13. As these polyvalent metal salts, carboxylate (formic acid, acetic acid, benzoate, etc.), sulfate, nitrate, chloride, and thiocyanate are suitable. Among them, preferably, calcium salt or magnesium salt of carboxylic acid (formic acid, acetic acid, benzoate, etc.), calcium salt or magnesium salt of sulfuric acid, calcium salt or magnesium salt of nitric acid, calcium chloride, magnesium chloride, and thiocyanic acid. A calcium salt or a magnesium salt is mentioned. In addition, a polyvalent metal salt may be used individually by 1 type, and may use 2 or more types together.

  The organic acid is not particularly limited, and examples thereof include acetic acid, phosphoric acid, oxalic acid, malonic acid, and citric acid. Among these, monovalent or divalent or higher carboxylic acids are preferable. The organic acid may be in a salt state. In addition, an organic acid or its salt may be used individually by 1 type, and may use 2 or more types together. In addition, what is also a polyvalent metal salt with an organic acid or its salt shall be included in a polyvalent metal salt.

  Although it does not specifically limit as a cationic resin, For example, amine resin is mentioned. The amine resin may be a resin having an amino group in the structure. Examples of amine resins include amine resins such as amine / epichlorohydrin condensation type polymers, polyallylamine, and polyallylamine derivatives. The cationic resin is preferably a resin that is soluble in the processing liquid or a resin emulsion that is dispersed in the processing liquid, and the former is more preferable.

  The content of the flocculant is preferably 1 to 20% by mass and more preferably 3 to 10% by mass with respect to the total amount of the treatment liquid. When the content of the flocculant is within the above range, the recorded matter obtained tends to be more excellent in bleed resistance, embedding resistance, and abrasion resistance.

(water)
The content of water is preferably 55 to 85% by mass, more preferably 60 to 80% by mass, and further preferably 65 to 75% by mass with respect to the total amount of the treatment liquid.

(Organic solvent)
Examples of the organic solvent contained in the treatment liquid are the same as those exemplified for the ink composition. An organic solvent may be used individually by 1 type, and may be used in combination of 2 or more type. The content of the organic solvent is preferably 10 to 40% by mass, more preferably 15 to 35% by mass, and further preferably 20 to 30% by mass with respect to the total amount of the treatment liquid.

  Further, the treatment liquid may contain a nitrogen-containing solvent as an organic solvent. The content of the nitrogen-containing solvent is preferably 3 to 25% by mass, more preferably 5 to 22% by mass, and still more preferably 8 to 20% by mass with respect to the total amount of the treatment liquid. As the nitrogen-containing solvent, a nitrogen-containing solvent that may be contained in the above-described colored ink composition can be used independently of those containing in the colored ink composition.

(Surfactant)
Examples of the surfactant contained in the treatment liquid are the same as those exemplified for the ink composition. The content of the surfactant is preferably 0.1 to 3% by mass, more preferably 0.2 to 2% by mass, and still more preferably 0.3 to 1.% by mass with respect to the total amount of the treatment liquid. 5% by mass. When the content of the surfactant is within the above range, the wettability of the treatment liquid tends to be further improved.

(Defoamer)
Examples of the antifoaming agent contained in the treatment liquid can include the same ones as exemplified for the ink composition. The content of the antifoaming agent is preferably 0.03 to 0.7% by mass, more preferably 0.05 to 0.5% by mass, and still more preferably 0. 0% to the total amount of the treatment liquid. It is 08-0.3 mass%.

[Recording device]
The recording apparatus used in the present embodiment performs recording by the above-described recording method, and includes an inkjet head having a nozzle for discharging an ink composition to a recording medium and a mechanism for attaching a treatment liquid. If it does not specifically limit. A schematic sectional view of the recording apparatus is shown in FIG. As shown in FIG. 1, the recording apparatus 1 includes a recording head 2, an IR heater 3, a platen heater 4, a drying heater 5, a cooling fan 6, a preheater 7, and a fan 8. Yes.

  The recording head 2 ejects an ink composition onto a recording medium. As the recording head 2, a conventionally known method can be used, and a head that ejects droplets by utilizing vibration of a piezoelectric element, that is, a head that forms ink droplets by mechanical deformation of an electrostrictive element can be used. The IR heater 3 and the platen heater 4 mainly heat the recording medium 10, but the recording head can also be heated. The recording medium can be heated from the recording head 2 side by the IR heater 3. Thereby, when the platen heater 4 is used, the recording medium can be heated from the side opposite to the recording head 2 side. The platen heater 4 may be configured by arranging a plurality of heater elements in the main scanning direction. This is preferable because the platen heater is easily available or manufactured. On the other hand, temperature unevenness in heating in the main scanning direction is likely to occur. The drying heater 5 dries the recording medium to which the ink composition is attached. By heating the recording medium on which the image is recorded, moisture and the like contained in the ink composition is evaporated and scattered more quickly, and a film is formed by the resin contained in the ink composition. In this manner, the dried ink is firmly fixed (adhered) on the recording medium, and a high-quality image excellent in abrasion resistance can be obtained in a short time. During recording, the recording medium 10 is conveyed from right to left in the figure.

  The recording apparatus 1 may have a cooling fan 6. After drying, the ink composition on the recording medium is cooled by the cooling fan 6 so that a film can be formed on the recording medium with good adhesion.

  Further, the recording apparatus 1 may include a preheater 7 that preheats (preheats) the recording medium before the ink composition is ejected onto the recording medium. When the recording medium is pre-heated before the ink composition is discharged, a high-quality image with little bleeding tends to be formed on the recording medium, particularly a non-absorbing and low-absorbing recording medium.

  The recording head 2 is mounted on the carriage 9. The carriage 9 performs scanning (main scanning) in which the ink composition is ejected from the head while moving in the front-back direction in the figure, and adhered to the recording medium facing the head. Recording is performed by alternately repeating scanning and conveyance (sub-scanning) of the recording medium 10. That is, a serial recording method is performed in which recording is performed by performing scanning a plurality of times.

  FIG. 3 is a perspective view showing an example of the configuration around the carriage of the recording apparatus of FIG. The configuration 11 around the carriage includes a carriage 9, an inkjet head 2 mounted on the carriage 9, a member 12 that is a part of the inkjet head 2 and includes a nozzle that ejects ink, an ink container (not shown), And an ink supply path (not shown) such as an ink supply pipe for supplying ink from the ink container to the inkjet head 2. The ink container may be provided in a place other than the carriage 9 or may be provided in the carriage. Further, a platen 4 disposed below the carriage 9 on which the recording medium 10 is conveyed, a carriage moving mechanism 13 that moves the carriage 9 relative to the recording medium 10, and the recording medium 10 in the sub-scanning direction (conveyance). A transporting unit 14 that is a roller that transports in a direction), and a control unit CONT that controls the operation of the carriage 9 and the like. The direction of S1-S2 is the main scanning direction, and the direction of T1 → T2 is the sub-scanning direction. Note that scanning is performed in one direction of the main scanning direction (the left-right direction of the apparatus) in one scan.

  Further, the recording apparatus 1 in FIG. 1 includes a fan 8 for sending air to the surface of the recording medium from the viewpoint of efficient drying of the ink composition and adjustment of the temperature of the recording medium and the nozzle surface. The fan 8 will be described in detail with reference to FIG. Also in FIG. 2, the recording head 2 is mounted on the carriage, and performs main scanning by ejecting the ink composition from the head while moving in the main scanning direction which is the front-back direction in the figure. In FIG. 2, in the main scanning of the carriage, FIG. 2 (a) showing a state where the wind in the place where there is no carriage in the main scanning direction (front-rear direction in the figure) flows to the recording medium, and FIG. FIG. 2B shows a state where the wind does not flow directly to the recording medium.

  A plurality of fans 8 are provided side by side in the width direction (main scanning direction) of the recording medium 10, and are provided so that wind can always be sent in a strip shape across the width of the recording medium 10. ing. In FIG. 2A, the wind hits the surface of the recording medium 10. Since the hit angle is tilted to the left in the figure with respect to the surface of the recording medium, the wind direction changes to the left in the figure after hitting, and in the area of the recording medium where the ink is attached, Is sent to the downstream side in the recording medium conveyance direction in parallel with the surface of the recording medium. By doing so, it is possible to promote the drying of the ink in the area where the ink of the recording medium adheres.

  FIG. 4 is a view of the fan 8 of FIG. 2 as viewed from the front of the fan. As shown in the figure, a plurality of fans 8 are provided side by side in the width direction of the recording medium.

  On the other hand, in FIG. 2B, the wind hits a windbreak member provided on the upper part of the carriage, is separated in the left-right direction in the figure, changes its direction, and does not directly hit the surface of the recording medium. By doing so, it is possible to reduce the influence of clogging and landing position deviation caused by wind generated by the nozzles and the ink droplets in flight where the carriage is located.

  However, in FIG. 2A, the direction of the wind sent in parallel to the surface of the recording medium may fluctuate slightly, and even when the carriage is present, the wind blows into the recording head 2 from the side direction, so that the landing position is reached. There is an influence. Further, in FIG. 2B, the wind that has changed its direction against the windbreak member may flow in an unintended direction, and the same effect may occur slightly.

  Note that the fan 8 in FIG. 2 shows one mode of sending means for sending wind onto the recording medium, and the blowing means is not limited to this as long as it can send wind to the recording medium. Absent. As other modes, there can be considered a mode in which air is blown sideways on the upper layer of the recording medium, and a mode in which wind is applied from above to the ink adhesion area on the surface of the recording medium.

(Number of scans)
The number of scans is also called the number of passes. The number of scans in which a nozzle group used for recording a certain ink composition passes and faces a certain position on the recording medium is referred to as the number of scans of the ink composition. The nozzle group is a group of nozzles such as a nozzle row arranged in the sub-scanning direction of the inkjet head, and ejects the ink composition during recording. The number of main scans can be increased by shortening the distance of one sub-scan, and can be decreased by increasing the distance. For example, the number of scans can be set to 8 (pass) by setting the distance of one sub-scan to 1/8 of the length of the nozzle group in the sub-scan direction. The number of scans is 1 or more, preferably 2 to 20, and more preferably 4 to 10. A larger number of main scans is preferable in that the total adhesion amount of the ink composition to be adhered can be increased and the ink composition can be adhered in a plurality of scans. On the other hand, when the number of scans is small, it is preferable because the recording speed is high.

(Other embodiments)
Other embodiments of the present invention are as follows.
A colored ink composition containing a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions is ejected from an inkjet head and recorded. An ink adhering step for adhering to the medium;
A treatment liquid adhering step for adhering a treatment liquid containing a flocculant for aggregating the components of the colored ink composition to the recording medium,
The ink adhering step is performed by performing a plurality of scans for discharging the colored ink composition while changing the relative position of the inkjet head to the recording medium in a scanning direction,
The recording method, wherein a difference in surface temperature of the recording medium when attaching the colored ink in the ink attaching step is 1 to 10 ° C.

  The other embodiment does not necessarily include that the maximum distance of one scanning is 50 cm or more in the ink attaching step of the above-described embodiment, but instead of the recording medium when the colored ink is attached in the ink attaching step. The surface temperature difference is 1 to 10 ° C. In the other embodiment, attention is paid to the fact that the difference in surface temperature of the recording medium occurs as one of the causes of the color difference of the recorded matter in the ink attaching process as described above. According to this embodiment, even when the difference in the surface temperature of the recording medium is within a predetermined range, reduction in density unevenness and reduction in color difference are excellent and preferable. The difference in the surface temperature of the recording medium is more preferably in the above range. The other embodiment may be the same as the above-described embodiment except for the above-described configuration, and may further include another configuration included in the above-described embodiment.

Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples. The present invention is not limited in any way by the following examples.
[Material for ink composition]
The main materials of the ink composition and the treatment liquid used in the following examples, comparative examples, and reference examples are as follows.
(Pigment dispersion)
See Production Example 1 below.
〔Organic solvent〕
Dipropylene glycol dimethyl ether Propylene glycol 2-pyrrolidone [flocculating agent]
Calcium acetate monohydrate Acetic acid Kathiomaster PD-7 (manufactured by Yokkaichi Synthesis Co., Ltd., cationic resin: amine / epichlorohydrin condensation polymer)
〔resin〕
St-Ac resin emulsion (see Production Example 2 below)
〔wax〕
AQUACER 515 (manufactured by Big Chemie Japan, wax emulsion)
[Surfactant]
DYNOL 607 (Air Products Japan, acetylene diol surfactant)
BYK348 (Bic Chemie Japan, silicone surfactant)
[Defoamer]
Surfynol DF110D (manufactured by Nissin Chemical Industry Co., Ltd., acetylene diol system)

[Production Example 1: Preparation of pigment dispersion]
St-Ac acid copolymer (copolymerized at a mass ratio of methacrylic acid / butyl acrylate / styrene / hydroxyethyl acrylate = 25/50/15/10. Weight average molecular weight 7000, acid value 150 mgKOH / g) 40 parts by mass Was added to a liquid obtained by mixing 7 parts by mass of potassium hydroxide, 23 parts by mass of water, and 30 parts by mass of triethylene glycol mono-n-butyl ether, and heated at 80 ° C. with stirring to prepare an aqueous resin solution.

20 parts by mass of pigment, 10 parts by mass of resin aqueous solution, 10 parts by mass of diethylene glycol, and 60 parts by mass of ion-exchanged water were mixed and dispersed using a zirconium bead mill to obtain a pigment dispersion of each color. The pigments used are as follows.
Cyan pigment dispersion; C.I. I. PigmentB1ue15: 3
Magenta pigment dispersion; C.I. I. PR122
Yellow pigment dispersion; C.I. I. PY74
Orange pigment dispersion; C.I. I. PO43
Red pigment dispersion; C.I. I. PR178
Green pigment dispersion; C.I. I. PG7
Blue pigment dispersion; C.I. I. PB60
Black pigment dispersion C.I. I. PBk7

[Production Example 2: Preparation of St-Ac resin emulsion]
A St-Ac resin emulsion was obtained by emulsion copolymerization of 75 parts by mass of styrene, 0.5 parts by mass of acrylic acid, 14.5 parts by mass of methyl methacrylate, and 10 parts by mass of cyclohexyl methacrylate. In addition, as a surfactant for emulsion polymerization, Newcol NT-30 (manufactured by Nippon Emulsifier Co., Ltd.) was used, and the amount used was 2 parts by mass based on 100 parts by mass of the monomer.

[Preparation of ink composition and treatment liquid]
Each material was mixed by the composition shown to the following Tables 1-2, and was fully stirred, and each ink composition and the process liquid were obtained. In Tables 1 and 2 below, the unit of numerical values is% by mass, and the total is 100.0% by mass. The pigment and resin in the table are the mass% of the solid content of the pigment and resin in the ink.

A recording pattern was recorded with an adhesion amount of 10 mg / inch ² with one ink for each of inks 1 to 8, the color of the pattern was measured, and the hue angle was obtained from the colorimetric values. The calculation formula of the hue angle is as follows. Inks 1 to 8 all had different hue angles. Further, it was within the range of the preferred hue angle for each color ink described above.
∠H ° = tan-1 (b ^* / a ^* ) + 180 (when a ^* <0)
∠H ° = tan-1 (b ^* / a ^* ) + 360 (when a ^* > 0)

[Recording method]
SC-S80650 (manufactured by Seiko Epson) having a platen heater in which heater elements are arranged in the medium width direction and a fan arranged in the recording medium width direction on the head (hereinafter referred to as "SC-S80650 modified machine") ") Was prepared. The ink jet head is a serial type as shown in FIG. 1, and ink and the like can be recorded in order from the ink jet head. In addition, a fan at normal temperature (25 ° C.) was blown toward the recording medium by a fan.

  The above-described treatment liquid was filled in a nozzle row (360 nozzles) upstream of the inkjet head in the recording medium conveyance direction, and each ink composition was filled in a nozzle row downstream of the inkjet head in the recording medium conveyance direction. Then, by the inkjet method, the treatment liquid was ejected from the inkjet head and adhered to a recording medium (Ultraflex, JetFlex FL 80), and then the ink composition was ejected and adhered to the recording medium.

  The adhesion amount of the reaction liquid in the table was set to mass% with respect to the total adhesion amount of the ink composition. In addition, the treatment droplet mass and the ink droplet mass were 20 ng / dot, the basic resolution was 720 × 720 dpi, and the dot density was adjusted to allow adjustment of each adhesion amount. In addition, the number of scans was 8 passes for each composition. Finally, the recorded material was heated at 95 ° C. for 30 seconds with a secondary heater on the downstream side of the inkjet head and dried.

A solid pattern for color difference evaluation is recorded under the above recording conditions.
First, the basic color and spot color ink adhesion amounts for recording a solid pattern of any recording color to be recorded for each example are determined and determined. The following are the target colors for each color solid pattern.
Red solid pattern (L ^* 50, a ^* = 40, b ^* = 10, ∠H ° = 14)
Orange solid pattern (L ^* 50, a ^* = 30, b ^* = 30, ∠H ° = 45)
Blue solid pattern (L ^* 50, a ^* = 40, b ^* = − 40, ∠H ° = 315)
Green solid pattern (L ^* 50, a ^* = − 40, b ^* = 10, ∠H ° = 166)

When determining the ink adhesion amount, a solid test pattern is recorded on the recording medium and the color is measured. For colorimetry, Spectrolino manufactured by GretagMacbeth was used. Colorimetry is based on the CIELAB color system. It is determined by adjusting the ink adhesion amount so that the hue angle (∠H °) of the colorimetric value becomes the value of the target color.
In this way, the amount of each ink used for recording each color solid pattern was determined for each example.
Reference Example 3 is a cyan pattern obtained by recording with cyan ink alone, and the adhesion amount was 10 mg / inch ² .

A solid product for color difference evaluation was continuously recorded under the above-mentioned recording conditions with the determined ink adhesion amount to produce a recorded matter. The solid pattern was recorded over the entire recordable range in the horizontal width direction of the medium and was recorded with a length of 1500 mm in the media feed direction. The horizontal width of the recording medium was adjusted by cutting or pasting the recording medium, and the maximum distance of one scan was adjusted to the values in Tables 3-4.
The types of ink compositions used are as shown in Tables 3-4.

  In the above recording method, the platen heater was controlled so that the surface temperature of the recording medium in the platen region facing the head during recording became the heating temperature shown in Tables 3-4. Specifically, when the surface temperature is set to 35 ° C. or higher, the platen heater is turned on and adjusted. When the surface temperature is set to 25 ° C. or lower, the room temperature is adjusted without using the platen heater and recording is performed during recording. The surface temperature of the medium was adjusted.

  The surface temperature of the recording medium is measured by measuring the temperature of the entire area that can be opposed during the main scanning of the head of the recording medium supported by the platen at 1 cm square intervals, and the highest temperature during recording on the surface of the recording medium in the area. It was temperature. The measurement was performed with a non-contact type thermometer. The temperature measurement was performed continuously for 1 hour under the above-described conditions, and the measurement was started 1 minute after the start of recording and measured every minute during recording.

(Color difference evaluation)
The solid pattern of the obtained recorded matter was divided into 2 × 2 cm square areas, and color measurement was performed for each area to obtain the largest color difference (ΔE00) between the areas. The occurrence of color difference was evaluated according to the following evaluation criteria. This is the maximum color difference between regions.
A: The maximum color difference between regions is ΔE ≦ 1.0
B: Maximum color difference between regions is 1.0 <ΔE ≦ 1.5
C: Maximum color difference between regions is 1.5 <ΔE ≦ 2.0
D: Maximum color difference between regions is 2.0 <ΔE

[Abrasion resistance]
The recording area of the recorded matter obtained was cut into a rectangle of 30 × 150 mm, and a friction element in which a plain woven cloth was attached to a Gakushin type friction fastness tester AB-301 (trade name, manufactured by Tester Sangyo Co., Ltd.) with a load of 500 g. And rubbed 10 times. And the peeling of the recording pattern part of the recording medium was observed visually, and the following evaluation criteria evaluated.
A: No peeling occurs and there is no transfer to the cloth.
B: Peeling does not occur, but there is transfer to the cloth.
C: Peeling occurs, and the peeled area is less than 10% of the evaluation area.
D: Peeling occurs, and the peeled area is 10% or more of the evaluation area.

(Water friction resistance)
The recording area of the obtained recorded matter was cut into a rectangle of 30 × 150 mm, and a friction obtained by attaching a plain weave cloth soaked with water to a Gakushin type friction fastness tester AB-301 (trade name, manufactured by Tester Sangyo Co., Ltd.) The child was rubbed 10 times with a load of 200 g. And the peeling of the recording pattern part of the recording medium was observed visually, and the following evaluation criteria evaluated.
A: No peeling occurs and there is no transfer to the cloth.
B: Peeling does not occur, but there is transfer to the cloth.
C: Peeling occurs, and the peeled area is less than 10% of the evaluation area.
D: Peeling occurs, and the peeled area is 10% or more of the evaluation area.

[Image quality evaluation]
The recording area of the obtained recorded matter was visually confirmed and evaluated according to the following evaluation criteria.
A: There is no rough feeling. B: There is no problem with the rough feeling. C: There is a rough feeling.

[Uneven density (bleed)]
The recording area of the obtained recorded matter was visually confirmed and evaluated according to the following evaluation criteria.
A: There is no shading unevenness in the solid pattern surface.
B: There are some slight shading unevenness in the solid pattern surface.
C: Large shading unevenness is conspicuous in the solid pattern surface.

Based on the above results, all examples in which cyan ink, magenta ink, yellow ink, special color ink, and processing liquid are used and the maximum distance of one scanning is 50 cm or more are excellent in suppressing color difference of the obtained recorded matter. I understood.
On the other hand, the comparative examples which are not so were inferior in color difference suppression. Details are described below.

From the comparison of Examples 7 to 10, and 4, when the surface temperature of the recording medium at the time of adhesion of the ink is low, the resulting recorded matter has relatively low resistance to rubbing and water friction, and roughness and density unevenness suppression. I understand. In addition, it is presumed that the suppression of uneven color density has also been reduced, or that the suppression of color difference has also slightly decreased.
On the other hand, it can be seen that the higher the surface temperature of the recording medium, the higher the scratch resistance and water friction resistance, roughness, and density unevenness of the recorded matter, but the lower the color difference. For this reason, when the heating temperature of the recording medium at the time of adhesion is optimized, density unevenness suppression and color difference suppression can be further improved.

  From the comparison of Examples 11 to 13, 17 and 4, it can be seen that the longer the maximum distance of one scan, the easier the color difference occurs, and the shorter the maximum distance of one scan, the less likely it is to occur. For this reason, the present embodiment is particularly useful in that excellent color difference suppression can be achieved even when the recorded distance is long and useful recording is obtained.

  From the comparison of Examples 15, 16, and 4, the color difference suppression was slightly inferior in both cases where the amount of treatment solution deposited was large or small. If the amount of treatment liquid attached is small, the density unevenness suppression is slightly inferior, and it is presumed that the color difference suppression is slightly reduced due to density unevenness. On the other hand, when the amount of the treatment liquid attached was large, aggregation of the ink components was promoted, so that the abrasion resistance was slightly lowered and the roughness of the image quality was slightly increased. It is presumed that the color difference tends to increase due to the roughness of the image quality. It was found that there was a more preferable amount of adhesion of the treatment liquid.

  From the comparison of Examples 14 and 4, it was found that the higher the content of the nitrogen-containing solvent in the ink, the better the color difference suppression.

On the other hand, Comparative Examples 1-8 were inferior in color difference suppression by not using special color ink.
In Reference Examples 1 and 2, since the problem of color difference does not occur when the maximum distance of one scan is short, the problem of color difference is an inherent problem particularly when the maximum distance of one scan is long. It can be seen that it is. However, it could not be used as a record for display purposes.
From Reference Example 3, it was found that the occurrence of a color difference is not a problem if the primary color is recorded.
The reference example 4 was inferior in image quality (density unevenness) by not using the treatment liquid. The components of the ink could not be agglomerated and fixed early by the treatment liquid, and the ink bleeded out, resulting in uneven density. The image looked rough due to shading unevenness. It is presumed that the recording color to be recorded cannot be stably reproduced due to uneven density, and the color difference suppression is also reduced.
In Reference Example 5, the density unevenness suppression was improved by increasing the recording medium temperature at the time of ink adhesion, but the heating temperature at the time of ink adhesion was high, the occurrence of temperature unevenness was large, and the color difference deteriorated.
Although not shown in the table, it was found that black recording with lower lightness and lower saturation was possible by adding ink 9 (black ink) to the ink set of each example.

  When the temperature difference between the maximum temperature (temperature in the table) and the minimum temperature of the surface temperature of the recording medium in the platen area that can be opposed to the head was confirmed by main scanning of the head during recording, Example 12 was 4 in Example 12. ° C, Example 13 was 6 ° C, Example 11 was 1 ° C, Example 17 was 2 ° C, Example 10 was 10 ° C, and Reference Example 1 was less than 1 ° C. . From this, it was found that the temperature difference tends to increase as the maximum distance of one scan increases. Further, the temperature difference tends to be larger as the surface temperature of the recording medium is higher.

  Although not shown in the table, in Example 12, the heating temperature of the platen heater was increased, the wind force of the air blown from the fan was increased from 1 m / s to 2 m / s, and the platen heater was heated. When the recording medium surface temperature during recording is controlled to 35 ° C., which is the same as in Example 12, by utilizing the fact that the temperature of the recording medium to be lowered by wind, it is difficult to reduce the temperature difference between the maximum temperature and the minimum temperature. The temperature difference was 6 ° C., and the color difference evaluation was C. From this, it was found that a large temperature difference of the recording medium is at least one of the causes of the color difference.

  In the other embodiments described above, the above example may be a comparative example or the comparative example may be an example.

DESCRIPTION OF SYMBOLS 1 ... Recording device, 2 ... Recording head, 3 ... IR heater, 4 ... Platen heater, 5 ... Drying heater, 6 ... Cooling fan, 7 ... Pre-heater, 8 ... Fan, 9 ... Carriage, 10 ... Recording medium, 11 ... Construction around carriage, 12 ... Member including nozzle, 13 ... Carriage moving mechanism, 14 ... Conveying means

Claims (13)

A colored ink composition containing a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions is ejected from an inkjet head and recorded. An ink adhering step for adhering to the medium;
A treatment liquid adhering step for adhering a treatment liquid containing a flocculant for aggregating the components of the colored ink composition to the recording medium,
The ink adhering step is performed by performing a plurality of scans for discharging the colored ink composition while changing the relative position of the inkjet head to the recording medium in a scanning direction,
The maximum distance of one scan in the ink adhering step is 50 cm or more;
Recording method. The special color ink composition includes at least one of an orange ink composition, a red ink composition, a green ink composition, and a blue ink composition,
The recording method according to claim 1. The colored ink composition further comprises a black ink composition,
The recording method according to claim 1 or 2. The recording medium is a low-absorbency recording medium or a non-absorbent recording medium.
The recording method according to claim 1. A heating step of heating the recording medium, and performing the ink adhering step on the heated recording medium, or
A blowing step of sending air to a region where the colored ink composition is attached in the ink attaching step;
The recording method as described in any one of Claims 1-4. The surface temperature of the recording medium when the colored ink composition is attached in the ink attaching step is 30 to 45 ° C.
The recording method according to claim 1. The maximum time of one scan in the ink adhering step is 0.8 seconds or more,
The recording method as described in any one of Claims 1-6. The flocculant is any one or more of a polyvalent metal salt, an organic acid or a salt thereof, and a cationic resin.
The recording method as described in any one of Claims 1-7. The maximum distance of one scan in the ink adhering step is 50 to 500 cm;
The recording method according to claim 1. The recording area to which the colored ink composition and the treatment liquid are attached has a region in which the amount of the treatment liquid adhered to the amount of the color ink composition attached is 5 to 30% by mass.
The recording method as described in any one of Claims 1-9. The temperature difference of the surface temperature of the recording medium in the ink adhering step is 1 to 10 ° C.
The recording method according to claim 1. A colored ink composition containing a cyan ink composition, a magenta ink composition, a yellow ink composition, and a special color ink composition having a hue angle different from each of the ink compositions is ejected from an inkjet head and recorded. An ink adhering step for adhering to the medium;
A treatment liquid adhering step for adhering a treatment liquid containing a flocculant for aggregating the components of the colored ink composition to the recording medium,
The ink adhering step is performed by performing a plurality of scans for discharging the colored ink composition while changing the relative position of the inkjet head to the recording medium in a scanning direction,
The difference in surface temperature of the recording medium when attaching the colored ink in the ink attaching step is 1 to 10 ° C.
Recording method.   A recording apparatus that performs recording by the recording method according to claim 1.