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JP2019156729A - Cleansing agent composition - Google Patents

Cleansing agent composition Download PDF

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JP2019156729A
JP2019156729A JP2018041578A JP2018041578A JP2019156729A JP 2019156729 A JP2019156729 A JP 2019156729A JP 2018041578 A JP2018041578 A JP 2018041578A JP 2018041578 A JP2018041578 A JP 2018041578A JP 2019156729 A JP2019156729 A JP 2019156729A
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fatty acid
hlb value
present
higher fatty
cleaning composition
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JP7327902B2 (en
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弘隆 丹後
Hirotaka Tango
弘隆 丹後
泰裕 小田
Yasuhiro Oda
泰裕 小田
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Noevir Co Ltd
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Abstract

【課題】本発明は、高級脂肪酸塩を基剤とするにもかかわらず、洗浄力、洗い上がりのしっとり感、泡質な洗浄料組成物を提供することを課題とする。【解決手段】下記(A)〜(C)を含有する洗浄料組成物。(A)高級脂肪酸塩(B)炭素数4以上の単糖及び/又は2糖類、HLB値が12以上のノニオン界面活性剤から選択される1種又は2種以上(C)アシルアミノ酸粉体【選択図】 なしPROBLEM TO BE SOLVED: To provide a detergency, a moist feeling after washing, and a foamy detergency composition in spite of using a higher fatty acid salt as a base. A cleaning composition containing the following (A) to (C). (A) Higher fatty acid salt (B) One or two or more (C) acyl amino acid powders selected from monosaccharides and / or disaccharides having 4 or more carbon atoms and nonionic surfactants having an HLB value of 12 or more. Selection diagram] None

Description

本発明は、洗浄料組成物に関する。   The present invention relates to a cleaning composition.

従来より、洗浄料として、種々の商品が開発されており、高級脂肪酸塩を基剤とするものは、洗浄力に優れ、泡立ちが良く、さっぱりとした感触があるため、洗顔料や全身洗浄料等に用いられている。しかし、その強力な洗浄力により、皮膚に必要な皮脂等まで落としてしまい、洗浄後に、肌が、かさつき、つっぱるといった問題が生じている。また、通常高級脂肪酸塩の場合、脂肪酸の鎖長が短いほど、起泡性が良好だが泡質が劣る傾向に、脂肪酸の鎖長が長いと、泡質は良好であるが、経時安定性に問題を生じる傾向にある。   Conventionally, various products have been developed as detergents, and those based on higher fatty acid salts have excellent detergency, good foaming, and a refreshing feel. Etc. are used. However, due to its strong cleaning power, it has dropped to the sebum necessary for the skin, and there has been a problem that the skin becomes thick and squeezed after cleaning. In the case of higher fatty acid salts, the shorter the fatty acid chain length, the better the foaming properties but the poorer the foam quality.The longer the fatty acid chain length, the better the foam quality, but the stability over time. It tends to cause problems.

また、洗浄後の肌のかさつきや、つっぱり感の改善のために、ジグリセリンのポリオキシプロピレン付加物と併用した例(特許文献1)、植物エキスと併用した例(特許文献2)がある。が、いずれも効果が不十分で、問題を解決するには、至っていない。   Moreover, there are an example (Patent Document 1) used in combination with a polyoxypropylene adduct of diglycerin and an example (Patent Document 2) used together with a plant extract in order to improve the roughness of the skin after washing and the feeling of firmness. However, they are not effective enough to solve the problem.

洗浄料に過度の脱脂を防ぐ目的でソルビトールやマルチトール等の糖類、非イオン界面活性剤を配合することが知られている(非特許文献1)。   It is known that saccharides such as sorbitol and maltitol and nonionic surfactants are blended in the detergent for the purpose of preventing excessive degreasing (Non-patent Document 1).

「新化粧品学」第2版、光井武夫編、2001年、南山堂発行、第350頁“New Cosmetics Science” 2nd edition, Takeo Mitsui, 2001, published by Nanzan-do, page 350

特開平6−116135号公報JP-A-6-116135 特開平10−88193号公報JP-A-10-88193

従来の、高級脂肪酸塩と糖類などの保湿剤、非イオン性界面活性剤の併用により保湿効果は若干高まるが、高級脂肪酸石鹸特有の泡のキメの粗さや弾力性のなさといった泡質の改良には、至っていなかった。そこで、本発明は、高級脂肪酸塩を基剤とするにもかかわらず、洗浄力、洗い上がりのしっとり感、泡質な洗浄料組成物を提供することを課題とする。   Conventional moisturizing effects such as higher fatty acid salts, saccharides, and nonionic surfactants are slightly enhanced. However, the improvement of foam quality, such as the roughness of foam texture and the lack of elasticity, is characteristic of higher fatty acid soaps. Was not reached. Accordingly, an object of the present invention is to provide a detergent composition having a detergency, a moist feeling after washing, and a foamy cleaning composition, although it is based on a higher fatty acid salt.

本発明は、下記(A)〜(C)を含有する洗浄料組成物を提供する。
(A)高級脂肪酸塩
(B)炭素数4以上の単糖及び/又は2糖類、HLB値が12以上のノニオン界面活性剤から選択される1種又は2種以上
(C)アシルアミノ酸粉体
The present invention provides a cleaning composition containing the following (A) to (C).
(A) Higher fatty acid salt (B) One or more kinds selected from monosaccharides and / or disaccharides having 4 or more carbon atoms and nonionic surfactants having an HLB value of 12 or more (C) Acylamino acid powder

本発明の洗浄料組成物は、洗浄力、洗い上がりのしっとり感、泡質に優れるという効果を発揮する。   The cleaning composition of the present invention exhibits the effects of excellent cleaning power, moist feeling after washing, and foam quality.

以下本発明を実施するための形態を説明する。   Hereinafter, modes for carrying out the present invention will be described.

本発明で用いる高級脂肪酸塩を構成する高級脂肪酸としては、飽和若しくは不飽和のいずれであってもよく、炭素数8〜24、特に10〜22のものが好ましい。これらの脂肪酸の中でも直鎖飽和脂肪酸を用いることが、好ましい。好ましいものの具体例としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ヤシ油脂肪酸、還元ヤシ油脂肪酸、パーム核脂肪酸などが挙げられる。これらの脂肪酸の中でも、泡立ち、安全性、安定性の面から、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸から選択される1種又は2種以上を含有することが好ましい。これらの高級脂肪酸と塩を形成するアルカリ剤としては、ナトリウム、カリウムなどのアルカリ金属塩、アンモニウム塩、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、2−アミノ−2−メチルプロパノール、2−アミノ−2−メチルプロパンジオールなどのアルカノールアミン塩、リジン、アルギニンなどの塩基性アミノ酸塩等が挙げられる。これらのうち、特にカリウム、アルギニンが好ましい。   The higher fatty acid constituting the higher fatty acid salt used in the present invention may be saturated or unsaturated, and those having 8 to 24 carbon atoms, particularly 10 to 22 carbon atoms are preferred. Among these fatty acids, it is preferable to use a linear saturated fatty acid. Specific examples of preferable ones include lauric acid, myristic acid, palmitic acid, stearic acid, coconut oil fatty acid, reduced coconut oil fatty acid, and palm kernel fatty acid. Among these fatty acids, it is preferable to contain one or more selected from lauric acid, myristic acid, palmitic acid and stearic acid from the viewpoints of foaming, safety and stability. Examples of alkali agents that form salts with these higher fatty acids include alkali metal salts such as sodium and potassium, ammonium salts, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methylpropanol, and 2-amino-2. -Alkanolamine salts such as methylpropanediol, basic amino acid salts such as lysine and arginine, and the like. Of these, potassium and arginine are particularly preferable.

また、これらの高級脂肪酸塩は、必ずしも脂肪酸塩として洗浄料組成物に配合する必要はなく、上記高級脂肪酸と塩基とをそれぞれ別個に添加し、組成物中で脂肪酸塩を形成させてもよい。   Moreover, these higher fatty acid salts do not necessarily need to be blended in the cleaning composition as fatty acid salts, and the higher fatty acids and bases may be added separately to form fatty acid salts in the composition.

高級脂肪酸塩の配合量は、洗浄料組成物の剤型によって異なり特に限定されない。固形洗浄料の場合その配合量は90質量%以下であることが好ましい。ペースト状洗浄料の場合、55質量%であることが好ましい。液状化粧料の場合25質量%であることが好ましい。   The amount of the higher fatty acid salt varies depending on the dosage form of the cleaning composition and is not particularly limited. In the case of a solid detergent, the blending amount is preferably 90% by mass or less. In the case of a paste-like cleaning material, it is preferably 55% by mass. In the case of liquid cosmetics, it is preferably 25% by mass.

本発明で用いる炭素数4以上の単糖及び/又は2糖類としては、洗浄料に用いられ得るものであれば特に限定されない。かかる単糖及び/又は2糖類としては、ソルビトール、グルコース、エリスリトール、マンニトール、フルクトース、キシリトール、ショ糖、ラクトース、マルトース、マルチトール、トレハロース等が例示される。かかる糖類の中でも、本発明の効果の点からソルビトールを用いることが好ましい。   The monosaccharide and / or disaccharide having 4 or more carbon atoms used in the present invention is not particularly limited as long as it can be used for a cleaning material. Examples of such monosaccharides and / or disaccharides include sorbitol, glucose, erythritol, mannitol, fructose, xylitol, sucrose, lactose, maltose, maltitol, trehalose and the like. Among such sugars, sorbitol is preferably used from the viewpoint of the effect of the present invention.

炭素数4以上の単糖及び/又は2糖類から選択される1種又は2種以上を配合する場合の配合量は特に限定されないが、洗浄料組成物全量に対し、1〜20質量%が好ましい。   Although the compounding quantity in the case of mix | blending 1 type, or 2 or more types chosen from C4 or more monosaccharide and / or 2 saccharides is not specifically limited, 1-20 mass% is preferable with respect to the cleaning composition whole quantity. .

本発明で用いるHLB値が12以上の非イオン性界面活性剤としては、通常の洗浄剤組成物に用いられるものであればいずれでも良い。具体的にはポリオキシエチレンソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン硬化ヒマシ油などが挙げられる。   As the nonionic surfactant having an HLB value of 12 or more used in the present invention, any nonionic surfactant may be used as long as it is used in a normal cleaning composition. Specific examples include polyoxyethylene sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, and polyoxyethylene hydrogenated castor oil.

ポリオキシエチレンソルビタン脂肪酸エステルとしては、モノラウリン酸POE(80)ソルビタン(HLB値19.0)、モノラウリン酸POE(20)ソルビタン(HLB値16.9)、モノパルミチン酸POE(20)ソルビタン(HLB値15.6)、モノステアリン酸POE(20)ソルビタン(HLB値14.9)等が挙げられる。ポリグリセリン脂肪酸エステルとしては、モノラウリン酸ヘキサグリセリル(HLB値14.5)、モノラウリン酸デカグリセリル(HLB値15.5)等が挙げられる。ポリオキシエチレン脂肪酸エステルとしては、モノラウリン酸POE(10)(HLB値12.5)、モノステアリン酸POE(25)(HLB値15.0)等が挙げられる。ポリオキシエチレンアルキルエーテルとしては、POE(9)ラウリルエーテル(HLB値14.5)、POE(10)セチルエーテル(HLB値13.5)、POE(20)フィトステロールエーテル(HLB値15.5)、POE(30)フィトステロールエーテル(HLB値18.0)等が挙げられる。ポリオキシエチレン硬化ヒマシ油としては、POE(40)硬化ヒマシ油(HLB値12.5)、POE(60)硬化ヒマシ油(HLB値14.0)等が挙げられる。   As polyoxyethylene sorbitan fatty acid ester, monolauric acid POE (80) sorbitan (HLB value 19.0), monolauric acid POE (20) sorbitan (HLB value 16.9), monopalmitic acid POE (20) sorbitan (HLB value) 15.6), monostearic acid POE (20) sorbitan (HLB value 14.9), and the like. Examples of the polyglycerol fatty acid ester include hexaglyceryl monolaurate (HLB value 14.5), decaglyceryl monolaurate (HLB value 15.5), and the like. Examples of polyoxyethylene fatty acid esters include monolauric acid POE (10) (HLB value 12.5), monostearic acid POE (25) (HLB value 15.0), and the like. As polyoxyethylene alkyl ether, POE (9) lauryl ether (HLB value 14.5), POE (10) cetyl ether (HLB value 13.5), POE (20) phytosterol ether (HLB value 15.5), POE (30) phytosterol ether (HLB value 18.0) etc. are mentioned. Examples of the polyoxyethylene hydrogenated castor oil include POE (40) hydrogenated castor oil (HLB value 12.5), POE (60) hydrogenated castor oil (HLB value 14.0), and the like.

本発明においてはこれらの非イオン性界面活性剤の中でも、モノラウリン酸POE(80)ソルビタン、モノラウリン酸デカグリセリルから選択される1種又は2種を用いることが好ましい。   In the present invention, among these nonionic surfactants, it is preferable to use one or two selected from POE (80) sorbitan monolaurate and decaglyceryl monolaurate.

HLB値が12以上の非イオン性界面活性剤を配合する場合の配合量は特に限定されないが、洗浄料組成物全量に対し、0.5〜5質量%、0.5〜2質量%とすることが好ましい。   Although the compounding quantity in the case of mix | blending a nonionic surfactant whose HLB value is 12 or more is not specifically limited, It shall be 0.5-5 mass% and 0.5-2 mass% with respect to cleaning composition whole quantity. It is preferable.

本発明で用いるアシルアミノ酸粉体としては、洗浄料組成物に配合し得るものであれば特に限定されない。具体的には、ラウロイルリジン、パルミトイルリジン、カプロイルリジン等のアシルリジン;ステアロイルオルニチン等のアシルオルニチン;ラウロイルアルギニン等のアシルアルギニン;ココイルヒスチジン等のアシルヒスチジン等のアシル塩基性アミノ酸等が挙げられる。市販品としては、ラウロイルリジンであるアミホープLL(味の素社製)等を用いることができる   The acylamino acid powder used in the present invention is not particularly limited as long as it can be blended into the cleaning composition. Specific examples include acyl lysines such as lauroyl lysine, palmitoyl lysine, caproyl lysine; acyl ornithines such as stearoyl ornithine; acyl arginines such as lauroyl arginine; acyl basic amino acids such as acyl histidine such as cocoyl histidine. As a commercial product, Amihope LL (manufactured by Ajinomoto Co., Inc.) which is lauroyl lysine can be used.

アシルアミノ酸の配合量は、洗浄料組成物の剤型、高級脂肪酸塩の含有量などにより変化するが、洗浄料組成物全量に対し0.001〜1質量%とすることが好ましい。   The compounding amount of the acylamino acid varies depending on the dosage form of the cleaning composition, the content of the higher fatty acid salt, and the like, but is preferably 0.001 to 1% by mass with respect to the total amount of the cleaning composition.

本発明においては、親油型モノステアリン酸グリセリルを配合することができる。親油型モノステアリン酸グリセリルは通常の洗浄料に配合し得るものであれば特に限定されない。市販の親油型モノステアリン酸グリセリルとしてはNIKKOL(登録商標)MGSシリーズ(日光ケミカルズ社製)、モノグリMB(日油社製)等を挙げることができる。   In the present invention, lipophilic glyceryl monostearate can be blended. The oleophilic glyceryl monostearate is not particularly limited as long as it can be blended with an ordinary detergent. Examples of commercially available lipophilic glyceryl monostearate include NIKKOL (registered trademark) MGS series (manufactured by Nikko Chemicals) and monogly MB (manufactured by Nikko).

本発明においては、多価アルコールを配合することができる。多価アルコールとしては通常洗浄料に配合し得るものであれば特に限定されない。多価アルコールとしては、1,3−ブチレングリコール、グリセリン、ジグリセリン、ポリエチレングリコール、ペンチレングリコール、ヘキシレングリコール等が例示される。   In the present invention, a polyhydric alcohol can be blended. The polyhydric alcohol is not particularly limited as long as it can be usually blended in a cleaning material. Examples of the polyhydric alcohol include 1,3-butylene glycol, glycerin, diglycerin, polyethylene glycol, pentylene glycol, hexylene glycol and the like.

本発明の洗浄料には、上述の成分の他に、通常の洗浄料分野等に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、精製水、油剤、界面活性剤、増粘剤、防腐剤、香料、紫外線吸収剤、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。   In the cleaning material of the present invention, in addition to the above-described components, optional components used in the normal field of cleaning materials and the like can be blended to such an extent that the effects of the present invention are not impaired. Specific examples include purified water, oils, surfactants, thickeners, preservatives, fragrances, ultraviolet absorbers, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents, and the like.

本発明の洗浄料は、常法により製造され、固形状、液状、乳液状、クリーム状、ペースト状、ジェル状、軟膏状等の剤型とすることができる。本発明の効果の点から、適度な粘性を有する液状若しくはペースト状の剤型をとることが好ましい。また本発明の洗浄料は、皮膚洗浄料、毛髪洗浄料として使用することができ、特に皮膚洗浄料として使用することが好ましい。   The cleaning agent of the present invention is produced by a conventional method, and can be made into dosage forms such as solid, liquid, emulsion, cream, paste, gel, ointment and the like. From the viewpoint of the effect of the present invention, it is preferable to take a liquid or paste-like dosage form having an appropriate viscosity. Moreover, the cleaning composition of the present invention can be used as a skin cleaning composition or a hair cleaning composition, and is particularly preferably used as a skin cleaning composition.

以下に本発明について実施例を用いて説明するが、本発明の技術的範囲はこれによってなんら限定されるものではない。 The present invention will be described below with reference to examples, but the technical scope of the present invention is not limited thereto.

本発明の実施例及び比較例の評価方法は下記のとおりである。   The evaluation methods of Examples and Comparative Examples of the present invention are as follows.

(使用感評価)洗浄力、洗い上がりのしっとり感、泡質
専門パネラー2名により、ボディでの使用テストを行い、表の洗浄料の泡立ち、泡質、について、それぞれ絶対評価を行った。評価結果を下記の基準を用いて合議により判定した。
<評価結果>
◎:非常に良い
○:良い
△:少し悪い
×:悪い
(Evaluation of feeling of use) Detergency, moist feeling after washing, and foam quality Two specialist panelists tested the body and evaluated the foaming and foam quality of the cleaning materials in the table. Evaluation results were determined by consultation using the following criteria.
<Evaluation results>
◎: Very good ○: Good △: A little bad ×: Bad

表1、2に、本発明の実施例及び比較例にかかるボディ用洗浄料の処方を示す。洗浄料は定法に従い調製し、評価に供した。   Tables 1 and 2 show prescriptions for body cleaning agents according to examples and comparative examples of the present invention. The cleaning material was prepared according to a conventional method and used for evaluation.

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本発明の実施例は、泡の弾力性、細かさといった泡質、洗い上がりのしっとり感に非常に優れた使用感であった。   In the examples of the present invention, the feeling of use was very excellent in foam quality such as foam elasticity and fineness, and moist feeling after washing.

Claims (1)

下記(A)〜(C)を含有する洗浄料組成物。
(A)高級脂肪酸塩
(B)炭素数4以上の単糖及び/又は2糖類、HLB値が12以上のノニオン界面活性剤から選択される1種又は2種以上
(C)アシルアミノ酸粉体
A cleaning composition containing the following (A) to (C).
(A) Higher fatty acid salt (B) One or more kinds selected from monosaccharides and / or disaccharides having 4 or more carbon atoms and nonionic surfactants having an HLB value of 12 or more (C) Acylamino acid powder
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113425613A (en) * 2020-03-23 2021-09-24 株式会社漫丹 Aqueous composition
JP7571352B1 (en) 2024-03-21 2024-10-23 資生堂ホネケーキ工業株式会社 Powder granulation

Citations (4)

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