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JP2019037227A - Frozen cooked rice modifier, frozen cooked rice, method for producing frozen cooked rice and method for thawing frozen cooked rice - Google Patents

Frozen cooked rice modifier, frozen cooked rice, method for producing frozen cooked rice and method for thawing frozen cooked rice Download PDF

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JP2019037227A
JP2019037227A JP2018157216A JP2018157216A JP2019037227A JP 2019037227 A JP2019037227 A JP 2019037227A JP 2018157216 A JP2018157216 A JP 2018157216A JP 2018157216 A JP2018157216 A JP 2018157216A JP 2019037227 A JP2019037227 A JP 2019037227A
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cooked rice
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rice
fatty acid
frozen cooked
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三浦 靖
Yasushi Miura
靖 三浦
佐知 桑嶋
Sachi Kuwajima
佐知 桑嶋
佐藤 正一
Shoichi Sato
正一 佐藤
満 白土
Mitsuru Shirado
満 白土
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Kamaishi Hikari Foods Co Ltd
Iwate University
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Iwate University
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Abstract

【課題】 シンプルな組成で、しかも、少ない添加量とすることができ、凍結・解凍による米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失によるボロボロとした食感への変化が抑制された、雑味のない冷凍米飯およびそれに用いる冷凍米飯改質剤を提供すること。【解決手段】 食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有する。【選択図】図1[Problem] It has a simple composition and can be added in a small amount, and the surface layer of cooked rice grains dries due to freezing and thawing, loss of gloss and transparency, cloudiness, acceleration of hardening, loss of stickiness between rice grains. To provide frozen boiled rice which is suppressed from changing to a crumbly palate feeling caused by fermenting, and has no unpleasant taste, and to provide a frozen cooked rice modifier used for the frozen boiled rice. SOLUTION: It does not contain edible fats and oils and plant sterols, but contains sucrose fatty acid esters and malto-oligosaccharides. [Selection drawing] Fig. 1

Description

本発明は、冷凍米飯用改質剤、冷凍米飯、冷凍米飯の製造方法および冷凍米飯の解凍方法に関するものである。   The present invention relates to a frozen rice cooker, frozen rice, a method for producing frozen rice, and a method for thawing frozen rice.

近年、女性の社会進出や調理済みの惣菜等を購入して自宅で食べる「内食」の増加等により、冷凍食品の消費量が高まっている。冷凍食品の長所としては、保存性が良好で買い置きができること、調理が簡便であること、食品のロスが少ないこと等が挙げられる。このような背景から、日本人の主食である米飯類についても、いつでも喫食できるように冷凍加工が試みられている。   In recent years, the consumption of frozen foods has increased due to the social advancement of women and the increase in “in-house meals” that are prepared and eaten at home. Advantages of frozen foods include good storage stability and availability, easy cooking, and low food loss. Against this background, freezing processing has been attempted so that cooked rice, which is a staple food of Japanese people, can be eaten at any time.

ただ、弁当、おにぎり、寿司等の白飯を主体とした米飯類は、凍結・解凍により米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失が生じ、ボロボロとした食感への変化等が起きるという課題がある。例えば、冷凍寿司では具材として鮮魚の切り身等の生鮮食品素材を用いるために加熱解凍することが難しく、その解凍方法として空気解凍を選択せざるをえなかった。   However, cooked rice mainly made from white rice such as bento, rice balls, sushi, etc., freezes and thaws, and the surface drying of the rice grains, loss of gloss and transparency, white turbidity, acceleration of hardening, loss of stickiness between the rice grains There arises a problem that a change to a tattered texture occurs. For example, in frozen sushi, fresh food materials such as fresh fish fillets are used as ingredients, so it is difficult to heat and thaw, and air thawing must be selected as the thawing method.

しかしながら、冷凍米飯を空気解凍させると米飯塊が白濁し、食感が悪く、口に入れたときに米飯粒がほぐれるような食感を得ることができないという問題があった。このような米飯塊の白濁や、食感の低下は、米飯中の澱粉の老化によってもたらされることが知られている。すなわち、グルコースがグリコシド結合で重合した直鎖状高分子であるアミロースと、分岐状高分子であるアミロペクチンとの共晶体である澱粉は、水の存在下での加熱により非晶質の糊化澱粉に変化する。一方、一旦非晶質になった糊化澱粉では、低温で貯蔵されることにより部分的な再結晶化である老化が引き起こされる。このような澱粉の老化は、一般に、0〜5℃の温度帯において最も進行しやすく、空気解凍では前記温度帯の通過時間が長くなるので、澱粉の老化が急激に進行し、米飯粒の硬化の加速や粘着性の低下につながる。   However, when the frozen cooked rice is thawed in the air, the mass of cooked rice becomes cloudy, the texture is poor, and there is a problem that it is not possible to obtain a texture that loosens the cooked rice grains when put in the mouth. It is known that such a cloudiness of the cooked rice mass and a decrease in texture are brought about by aging of starch in the cooked rice. That is, starch that is a eutectic of amylose, which is a linear polymer in which glucose is polymerized by glycosidic bonds, and amylopectin, which is a branched polymer, is converted into an amorphous gelatinized starch by heating in the presence of water. To change. On the other hand, once gelatinized starch has become amorphous, aging, which is partial recrystallization, is caused by being stored at a low temperature. Such aging of starch is generally most likely to proceed in a temperature range of 0 to 5 ° C., and in air thawing, the passage time of the temperature range becomes long, so that aging of starch rapidly proceeds and the rice grains are hardened. Leads to acceleration and lowering of tackiness.

そこで、空気解凍法を用いた冷凍米飯では、凍結解凍後の米飯粒の白濁や硬化等を抑制することを目的として、様々な冷凍米飯用改質剤の添加が提案されている(例えば、特許文献1、2参照)。   Therefore, in the case of frozen cooked rice using the air thawing method, the addition of various modifiers for frozen cooked rice has been proposed for the purpose of suppressing the cloudiness or hardening of the cooked rice grains after freezing and thawing (for example, patents). References 1 and 2).

特許文献1の冷凍米飯用改質剤は、HLB値8以上のショ糖脂肪酸エステル(A)、レシチン、グリセリン脂肪酸エステル、有機酸モノグリセリド、ポリグリセリン脂肪酸エステルおよびソルビタン脂肪酸エステルからなる群より選ばれた少なくとも1種(B)、食用油脂(C)および糖類化合物(D)を含有する水中油滴型乳化液を噴霧乾燥して得られる粉末状の冷凍米飯用改質剤である。この冷凍米飯用改質剤によれば、対米1質量%となるように、炊飯用の水に該冷凍米飯用改質剤を添加し、通常の炊飯と同様に炊き上げることにより、冷凍保存下においても、また常温以上による自然解凍を行っても冷凍米飯中の澱粉の老化に伴う食感低下および米飯塊の白濁を効果的に抑えることができるとされている。   The frozen rice cooker of Patent Literature 1 was selected from the group consisting of sucrose fatty acid ester (A) having an HLB value of 8 or more, lecithin, glycerin fatty acid ester, organic acid monoglyceride, polyglycerin fatty acid ester, and sorbitan fatty acid ester. It is a powdery frozen rice modifier obtained by spray-drying an oil-in-water emulsion containing at least one (B), edible fat (C) and saccharide compound (D). According to this frozen cooked rice modifier, the frozen cooked rice modifier is added to the rice cooking water so that it is 1% by mass with respect to the rice, and cooked in the same manner as ordinary cooked rice, which is stored frozen. It is said that even under natural thawing at room temperature or above, a decrease in texture due to aging of starch in frozen cooked rice and cloudiness of the cooked rice can be effectively suppressed.

特許文献2の冷凍米飯用改質剤は、植物ステロールを有効成分とする冷凍米飯用改質剤であり、イソマルトオリゴ糖、マルトオリゴ糖、トレハロース、デキストリンの群からなる糖類の内のいずれか1種以上の糖類を含有することが好ましいとされている。この冷凍米飯用改質剤を用いた米飯では、つやが良好で、しかも冷蔵、冷凍保存による品質保持効果が高いとされている。   The frozen cooked rice modifier of Patent Document 2 is a frozen cooked rice modifier containing plant sterol as an active ingredient, and any one of saccharides consisting of isomaltoligosaccharide, maltooligosaccharide, trehalose, and dextrin. It is considered preferable to contain the above saccharides. In the cooked rice using this frozen cooked rice modifier, it is said that the gloss is good and the effect of maintaining the quality by refrigeration and frozen storage is high.

特開2001−275590号公報JP 2001-275590 A 特開2003−310183号公報JP 2003-310183 A

しかしながら、特許文献1の冷凍米飯用改質剤では、前記のとおりの(A)(B)(C)(D)の4成分を必須の構成成分とする多成分からなる改質剤であるため、冷凍米飯の風味に悪影響を及ぼしたり、製造コストが向上するという問題があった。また、食用油脂(C)を含有していることから油脂特有の臭気により雑味を生じるおそれがあり、例えば、具材として淡白な風味の白身魚等を用いた冷凍寿司用の寿司飯への適用は必ずしも好ましくないという問題があった。   However, the modified cooked rice cooker disclosed in Patent Document 1 is a multi-component modifier having the four components (A), (B), (C), and (D) as essential components as described above. There are problems such as adversely affecting the flavor of frozen cooked rice and increasing production costs. In addition, since it contains edible fats and oils (C), there is a risk of producing a miscellaneous taste due to the odor peculiar to fats and oils. For example, to sushi rice for frozen sushi using light-flavored white fish as ingredients There was a problem that application was not always desirable.

特許文献2の冷凍米飯用改質剤では、必須の構成成分は2種類と比較的単純な組成であるが、多くの植物ステロールは疎水性を示すため、炊飯後の米飯中での分散性に改良の余地が残されていた。また、植物ステロールは高度に精製しなければ、食用油脂と同様に、雑味を生じるおそれがあり、例えば、具材として淡白な風味の白身魚等を用いた冷凍寿司用の寿司飯への適用は必ずしも好ましくないという問題があった。   In the modifier for frozen cooked rice in Patent Document 2, the essential constituents are two types of relatively simple compositions, but since many plant sterols are hydrophobic, they are highly dispersible in cooked rice after cooking. There was room for improvement. Also, if plant sterols are not highly purified, there is a risk of producing miscellaneous tastes similar to edible fats and oils, for example, application to sushi rice for frozen sushi using light-flavored white fish as ingredients There was a problem that was not necessarily preferable.

本発明は、以上のとおりの事情に鑑みてなされたものであり、シンプルな組成で、少ない添加量とすることができ、凍結・解凍による米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失によるボロボロとした食感への変化が抑制された、雑味のない冷凍米飯およびそれに用いる冷凍米飯用改質剤を提供することを課題とする。また、本発明は、このような冷凍米飯用改質剤を用いた冷凍米飯の製造方法と解凍方法を提供することを課題とする。   The present invention has been made in view of the circumstances as described above, and has a simple composition and can be added in a small amount. The surface layer drying of rice grains by freezing and thawing, loss of gloss and transparency, cloudiness It is an object of the present invention to provide a frozen cooked rice having no miscellaneous taste, and a modifier for frozen rice used therein, in which the change to a tattered texture due to the acceleration of curing and the loss of adhesiveness between cooked rice grains is suppressed . Moreover, this invention makes it a subject to provide the manufacturing method and thawing | decompression method of frozen rice using such a modifier for frozen rice.

本発明者らは、前記課題を解決するための検討を鋭意進めたところ、特定の水溶性乳化剤とマルトオリゴ糖とを改質剤として併用することにより、シンプルな組成で、しかも少ない改質剤の添加量とすることができ、凍結・解凍後も米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失によるボロボロとした食感への変化を抑制可能であることを見出した。また、凍結・解凍後の米飯には雑味がなく、風味良好であることも見出した。本発明は、このような知見に基づいて完成されている。   The inventors of the present invention have intensively studied to solve the above-mentioned problems. As a result of using a specific water-soluble emulsifier and maltooligosaccharide as a modifier, the composition of the present invention can be reduced with a simple composition. The amount can be added, and after freezing and thawing, the surface layer drying of rice grains, loss of gloss and transparency, white turbidity, acceleration of hardening, change to a tattered texture due to loss of adhesiveness between rice grains It was found that it can be suppressed. It was also found that the cooked rice after freezing and thawing has no miscellaneous taste and good flavor. The present invention has been completed based on such knowledge.

本発明の冷凍米飯用改質剤は、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有することを特徴とする。   The modifier for frozen rice of the present invention does not contain edible fats and oils and plant sterols, but contains sucrose fatty acid esters and maltooligosaccharides.

本発明の冷凍米飯用改質剤では、前記ショ糖脂肪酸エステルが、ショ糖ステアリン酸エステルまたはショ糖パルミチン酸エステルであることが好ましく考慮される。   In the modifier for frozen cooked rice of the present invention, it is preferably considered that the sucrose fatty acid ester is sucrose stearate or sucrose palmitate.

本発明の冷凍米飯は、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有し、前記ショ糖脂肪酸エステルの配合割合が、精白米中の澱粉質量に対して0.1wt%以上0.5wt%以下であり、前記マルトオリゴ糖の配合割合が炊飯後の米飯中の水質量に対して2.0wt%以上5.0wt%以下であることを特徴とする。   The frozen cooked rice of the present invention does not contain edible fats and oils and plant sterols, contains sucrose fatty acid esters and maltooligosaccharides, and the blending ratio of the sucrose fatty acid esters is 0.1 wt.% With respect to the starch mass in the polished rice. The blending ratio of the maltooligosaccharide is 2.0 wt% or more and 5.0 wt% or less with respect to the mass of water in the cooked rice after cooking.

本発明の冷凍米飯では、前記ショ糖脂肪酸エステルが、ショ糖ステアリン酸エステルまたはショ糖パルミチン酸エステルであることが好ましく考慮される。   In the frozen cooked rice of the present invention, it is preferably considered that the sucrose fatty acid ester is sucrose stearate or sucrose palmitate.

また、本発明の冷凍米飯では、前記冷凍米飯が、炊飯後の米飯に調味液が添加された米飯部と、具材部からなる冷凍寿司であることが好ましく考慮される。   Moreover, in the frozen cooked rice of this invention, it is preferably considered that the frozen cooked rice is the frozen sushi which consists of the cooked rice part to which the seasoning liquid was added to the cooked rice, and an ingredient part.

本発明の冷凍米飯の製造方法は、洗浄した精白米に水とともに、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有する冷凍米飯用改質剤を添加し、この冷凍米飯用改質剤を含有する水中に、前記精白米を浸漬した後に炊飯し、炊飯後の米飯を急速凍結することを特徴とする。   In the method for producing frozen cooked rice of the present invention, a frozen cooked rice is added with a modifier for frozen cooked rice that contains sucrose fatty acid ester and malto-oligosaccharide without water, edible fat and plant sterol, and water. The polished rice is dipped in water containing a rice cooker and then cooked, and the cooked rice is rapidly frozen.

本発明の冷凍米飯の製造方法では、前記ショ糖脂肪酸エステルの配合割合が、精白米中の澱粉質量に対して0.1wt%以上0.5wt%以下であり、前記マルトオリゴ糖の配合割合が炊飯後の米飯中の水質量に対して2.0wt%以上5.0wt%以下であることが好ましく考慮される。   In the method for producing frozen cooked rice of the present invention, the blending ratio of the sucrose fatty acid ester is 0.1 wt% to 0.5 wt% with respect to the starch mass in the polished rice, and the blending ratio of the maltooligosaccharide is cooked. It is preferably considered that it is 2.0 wt% or more and 5.0 wt% or less with respect to the water mass in the later cooked rice.

また、本発明の冷凍米飯の製造方法では、前記浸漬の条件が、25℃で30分以上であることが好ましく考慮される。   Moreover, in the manufacturing method of the frozen cooked rice of this invention, it is preferably considered that the conditions of the said immersion are 30 minutes or more at 25 degreeC.

さらに、本発明の冷凍米飯の製造方法では、前記急速凍結時の温度が−20℃以下であることが好ましく考慮される。   Furthermore, in the method for producing frozen cooked rice of the present invention, it is preferably considered that the temperature during the rapid freezing is −20 ° C. or lower.

また、本発明の冷凍米飯の製造方法では、前記炊飯後の米飯に調味液を添加し、具材を載置した後、急速凍結することが好ましく考慮される。   Moreover, in the manufacturing method of the frozen cooked rice of this invention, after adding a seasoning liquid to the cooked rice after the said rice cooking and mounting ingredients, it is preferably considered that it freezes rapidly.

本発明の冷凍米飯の解凍方法は、上記の冷凍米飯の製造方法により得られた冷凍米飯に接触させた加熱部材を、前記冷凍米飯中の水分が凍結状態を維持したまま加熱する第1加熱工程と、この第1加熱工程に次いで冷凍米飯中の凍結状態の水分が融解するように加熱する第2加熱工程と、この第2加熱工程に次いで前記冷凍米飯を喫食に適した温度まで昇温させる第3加熱工程とを含むことを特徴とする。   The method for thawing frozen cooked rice of the present invention is a first heating step in which the heating member brought into contact with the frozen cooked rice obtained by the method for producing frozen cooked rice is heated while the water in the frozen cooked rice is maintained in a frozen state. And a second heating step that heats the frozen rice in the frozen rice so as to melt after the first heating step, and then raises the temperature of the frozen rice to a temperature suitable for eating after the second heating step. And a third heating step.

本発明の冷凍米飯用改質剤によれば、シンプルな組成で、少ない添加量とすることができ、凍結・解凍による米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失によるボロボロとした食感への変化が抑制された、雑味のない冷凍米飯を提供することができる。また、本発明の冷凍米飯の製造方法および解凍方法によれば、そのような冷凍米飯用改質剤を用いることで、凍結・解凍による米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失によるボロボロとした食感への変化を抑制することができる。   According to the modifier for frozen cooked rice of the present invention, it can be added in a small amount with a simple composition, surface drying of the cooked rice grains by freezing and thawing, loss of gloss and transparency, cloudiness, acceleration of curing, It is possible to provide frozen cooked rice with no miscellaneous taste, in which a change to a tattered texture due to the loss of adhesiveness between the rice grains is suppressed. Moreover, according to the method for producing frozen rice and the thawing method of the present invention, by using such a frozen rice modifier, the surface drying of the rice grains by freezing and thawing, loss of gloss and transparency, cloudiness, It is possible to suppress a change to a tattered texture due to acceleration of curing and loss of adhesiveness between the rice grains.

精白米の水への浸漬時間と吸水量との関係を示したグラフである。It is the graph which showed the relationship between the immersion time and the water absorption amount of polished rice in water. 本発明の冷凍米飯の解凍方法における加熱プログラムの一例を示したグラフである。It is the graph which showed an example of the heating program in the thawing method of frozen cooked rice of the present invention. 炊飯後の米飯の粗熱をとる工程を模式的に示した概略断面図である。It is the schematic sectional drawing which showed typically the process of taking the rough heat of the cooked rice after cooking rice. 本発明の冷凍米飯の解凍時における冷凍米飯底部の温度測定箇所を模式的に示した概略断面図である。It is the schematic sectional drawing which showed typically the temperature measurement location of the frozen rice bottom part at the time of the thawing | decompression of the frozen cooked rice of this invention. 実施例B.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(2)における、冷凍米飯の冷凍貯蔵中の庫内温度を測定した結果を示したグラフである。Example B. It is the graph which showed the result of having measured the internal temperature in the freezing storage of frozen rice in the freezing and thawing | decompression test (2) of the rice which added the modifier for frozen rice. 実施例B.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(2)における、冷凍貯蔵1日後の米飯塊の硬さの測定結果(圧縮力−ひずみ曲線)を示したグラフである。Example B. It is the graph which showed the measurement result (compression force-strain curve) of the hardness of the cooked rice lump after the frozen storage in the freezing and thawing | decompression test (2) of the cooked rice which added the modifier for frozen cooked rice. 実施例B.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(2)における、冷凍貯蔵3日後の米飯塊の硬さの測定結果(圧縮力−ひずみ曲線)を示したグラフである。Example B. It is the graph which showed the measurement result (compressive force-strain curve) of the hardness of the cooked rice lump after three days freezing storage in the freezing and thawing | decompression tests (2) of the cooked rice which added the modifier for frozen cooked rice. 実施例B.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(2)における、冷凍貯蔵6日後の米飯塊の硬さの測定結果(圧縮力−ひずみ曲線)を示したグラフである。Example B. It is the graph which showed the measurement result (compression force-strain curve) of the hardness of the cooked rice lump 6 days after freezing storage in the freezing and thawing | decompression test (2) of the cooked rice which added the modifier for frozen cooked rice. 実施例B.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(2)における、冷凍貯蔵9日後の米飯塊の硬さの測定結果(圧縮力−ひずみ曲線)を示したグラフである。Example B. It is the graph which showed the measurement result (compression force-strain curve) of the hardness of the cooked rice lump 9 days after frozen storage in the freezing and thawing | decompression test (2) of the cooked rice which added the modifier for frozen cooked rice.

以下に本発明の冷凍米飯用改質剤、冷凍米飯、冷凍米飯の製造方法および冷凍米飯の解凍方法について詳細に説明する。   Hereinafter, the frozen cooked rice modifier, the frozen cooked rice, the frozen cooked rice production method and the frozen cooked rice thawing method of the present invention will be described in detail.

冷凍米飯用改質剤は、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有することを特徴としている。   The modifier for frozen rice is characterized by not containing edible fats and oils and plant sterols, but containing sucrose fatty acid esters and maltooligosaccharides.

発明が解決しようとする課題において言及したとおり、従来公知の冷凍米飯用改質剤として、食用油脂を含有するもの、植物ステロールを含有するものが知られている。しかしながら、これらの成分を用いた場合、特有の雑味が生じるという問題があった。また、複数種の成分を混合することにより、改質剤の添加量が増大するという問題もあった。本発明の冷凍米飯用改質剤においては、ショ糖脂肪酸エステルとマルトオリゴ糖とを併用することにより、前記雑味を生じる成分を用いることなく、凍結・解凍後の米飯粒の表層乾燥、光沢や透明感の消失、白濁、硬化の加速、米飯粒同士の粘着性の消失によるボロボロとした食感への変化を抑制することができる。しかも、凍結・解凍後の米飯には雑味がなく、風味も良好である。   As mentioned in the problem to be solved by the invention, conventionally known frozen rice modifiers include those containing edible oils and fats and those containing plant sterols. However, when these components are used, there is a problem that a peculiar taste occurs. In addition, there is a problem that the amount of the modifier added increases by mixing a plurality of types of components. In the frozen cooked rice modifier of the present invention, the combined use of sucrose fatty acid ester and maltooligosaccharide allows the surface layer drying, glossiness, It is possible to suppress a change to a tattered texture due to disappearance of transparency, white turbidity, acceleration of curing, and loss of adhesiveness between cooked rice grains. Moreover, the cooked rice after freezing and thawing has no miscellaneous taste and good flavor.

ショ糖脂肪酸エステルは、親水・親油性乳化剤の一種であり、精白米の表面からその内部に浸透し、澱粉との複合体を形成し、澱粉の老化を抑制していると考えられる。このようなショ糖脂肪酸エステルとしては、食品添加物としての使用が認められる限り特に限定されることはないが、例えば、ショ糖ミリスチン酸エステル、ショ糖パルミチン酸エステル、ショ糖ステアリン酸エステル等が例示される。これらの化合物は1種単独または2種以上を併用することができる。中でも、ショ糖脂肪酸エステルが、ショ糖ステアリン酸エステルまたはショ糖パルミチン酸エステルであることが好ましく考慮される。   Sucrose fatty acid ester is a kind of hydrophilic / lipophilic emulsifier and is considered to penetrate into the inside of the polished rice surface to form a complex with starch and suppress starch aging. Such a sucrose fatty acid ester is not particularly limited as long as it can be used as a food additive. For example, sucrose myristic acid ester, sucrose palmitic acid ester, sucrose stearic acid ester, etc. Illustrated. These compounds can be used alone or in combination of two or more. Among these, it is preferably considered that the sucrose fatty acid ester is sucrose stearate or sucrose palmitate.

また、ショ糖脂肪酸エステルによる澱粉の老化抑制作用は、その水溶性と密接に関わるため、HLB値が15以上のものが好ましい。HLB値が15未満のショ糖脂肪酸エステルでは、所望の水溶性を発揮することができない。   Moreover, since the aging inhibitory effect of starch by sucrose fatty acid ester is closely related to its water solubility, those having an HLB value of 15 or more are preferable. A sucrose fatty acid ester having an HLB value of less than 15 cannot exhibit the desired water solubility.

マルトオリゴ糖は、乳化剤と同様に、澱粉の老化抑制機能を有することが知られている。マルトオリゴ糖としては、食品添加物としての使用が認められる限り特に限定されることはないが、例えば、マルトトリオース・マルトースを主成分とするマルトオリゴ糖組成物、マルトトリオースを主成分とするマルトオリゴ糖組成物、マルトテトラオースを主成分とするマルトオリゴ糖組成物、マルトペンタオース・マルトヘキサオースを主成分とするマルトオリゴ糖組成物およびマルトヘキサオース・マルトヘプタオースを主成分とするマルトオリゴ糖組成物等が例示される。これらの組成物は1種単独または2種以上を併用することができる。中でも、マルトテトラオースを主成分とするマルトオリゴ糖組成物を用いることが好ましく考慮される。   It is known that maltooligosaccharide has a function of inhibiting starch aging, like an emulsifier. The maltooligosaccharide is not particularly limited as long as it can be used as a food additive. For example, a maltooligosaccharide composition containing maltotriose and maltose as a main component, and a maltooligosaccharide containing maltotriose as a main component. Sugar composition, malto-oligosaccharide composition based on maltotetraose, malto-oligosaccharide composition based on maltopentaose / maltohexaose and malto-oligosaccharide composition based on maltohexaose / maltoheptaose Etc. are exemplified. These compositions can be used alone or in combination of two or more. Among these, the use of a maltooligosaccharide composition mainly composed of maltotetraose is preferably considered.

本発明の冷凍米飯は、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有し、ショ糖脂肪酸エステルの配合割合が、精白米中の澱粉質量に対して0.1wt%以上0.5wt%以下であり、マルトオリゴ糖の配合割合が炊飯後の米飯中の水質量に対して2.0wt%以上5.0wt%以下であることを特徴としている。   The frozen cooked rice of the present invention does not contain edible fats and oils and plant sterols, contains sucrose fatty acid ester and maltooligosaccharide, and the blending ratio of sucrose fatty acid ester is 0.1 wt% with respect to the starch mass in the polished rice. The blending ratio of maltooligosaccharide is 2.0 wt% or more and 5.0 wt% or less with respect to the water mass in the cooked rice after cooking.

精白米としては、食用米であれば特に限定されることはない。精白米の澱粉含量は、例えば、総澱粉量および酵素感受性澱粉量の測定法として広く用いられている総澱粉量測法(AOAC公定法996.11、AACC法76−13、RACI標準法)によって測定することが例示される。   The polished rice is not particularly limited as long as it is edible rice. The starch content of polished rice is determined by, for example, a total starch amount measurement method (AOAC official method 996.11, AACC method 76-13, RACI standard method) widely used as a method for measuring the total starch amount and enzyme-sensitive starch amount. It is exemplified to measure.

ショ糖脂肪酸エステルの配合割合が上記の範囲内であれば、凍結・解凍処理後の米飯の硬化を抑制することができる。用いるショ糖脂肪酸エステルの種類に応じて、最適濃度は前後するが、例えば、HLB値16のショ糖ステアリン酸エステル(リョートーシュガーエステルP−1670、三菱ケミカルフーズ(株))を用いた場合、0.2wt%の添加で、冷凍・解凍処理後の米飯の硬化を最も抑制可能である。   If the blending ratio of the sucrose fatty acid ester is within the above range, curing of the cooked rice after the freezing and thawing treatment can be suppressed. Depending on the type of sucrose fatty acid ester to be used, the optimum concentration varies. For example, when a sucrose stearate ester having an HLB value of 16 (Ryoto Sugar Ester P-1670, Mitsubishi Chemical Foods Corporation) is used, Addition of 0.2 wt% can most suppress the hardening of cooked rice after freezing and thawing treatment.

また、ショ糖脂肪酸エステルの種類によっては、凍結・解凍処理後の米飯の硬化を抑制するのみならず、凍結・解凍処理後の米飯の白濁を抑制することもできる。これは、米飯の白濁が澱粉鎖の再結晶化(澱粉の老化)により起こり、ショ糖脂肪酸エステルが澱粉鎖に吸着して拡散反射を起こす大きさ未満(<0.1mm)の複合体を形成することにより、澱粉鎖の再結晶が抑制されることに起因すると考えられる。   In addition, depending on the type of sucrose fatty acid ester, not only the hardening of cooked rice after freezing / thawing treatment can be suppressed, but also the cloudiness of cooked rice after freezing / thawing treatment can be suppressed. This is because rice turbidity occurs due to recrystallization of starch chains (starch aging), and a sucrose fatty acid ester is adsorbed to the starch chains to form a complex with a size less than 0.1 mm (<0.1 mm). This is considered to result from the suppression of recrystallization of starch chains.

一方、マルトオリゴ糖の配合割合が上記の範囲内であれば、凍結・解凍処理後の米飯の白濁を抑制することができる。用いるマルトオリゴ糖の種類に応じて、最適濃度は前後するが、例えば、マルトトリオースを主成分とするマルトオリゴ糖組成物(ピュアトースL、固形分75.0%(w/w)、サンエイ糖化(株)/群栄化学工業(株))を用いた場合、2.0wt%または5.0wt%の添加で、冷凍・解凍処理後の米飯の白濁を顕著に抑制可能である。   On the other hand, if the blending ratio of maltooligosaccharide is within the above range, the cloudiness of the cooked rice after freezing and thawing treatment can be suppressed. The optimum concentration varies depending on the type of maltooligosaccharide used. For example, a maltooligosaccharide composition containing maltotriose as the main component (pureatose L, solid content 75.0% (w / w), SANEI saccharification (strain) ) / Gunei Chemical Industry Co., Ltd.), the cloudiness of cooked rice after freezing and thawing treatment can be remarkably suppressed by addition of 2.0 wt% or 5.0 wt%.

本発明の冷凍米飯は、白飯に限定されることはなく、おにぎり、炊き込みご飯、寿司等の様々な米飯を対象とする。中でも、炊飯後の米飯に食酢、砂糖等からなる調味液が添加された米飯部、すなわち寿司シャリと、鮮魚の切り身、刺身や酢締めした魚介類等の具材部、すなわち寿司ネタからなる寿司であることが好ましく考慮される。さらに、寿司については、例えば、握り寿司、ちらし寿司、押し寿司等が例示され、これらの寿司を凍結処理したものを総称して本明細書中では、冷凍寿司と呼称する。   The frozen cooked rice of the present invention is not limited to white rice, and targets various cooked rice such as rice balls, cooked rice, and sushi. Above all, cooked rice with a seasoning solution consisting of vinegar, sugar, etc. added to the cooked rice, that is, sushi, and fresh fish fillets, sashimi, sashimi and seafood with vinegar, etc. Is preferably considered. Furthermore, as for sushi, for example, nigiri sushi, chirashi sushi, pressed sushi, and the like are exemplified, and those obtained by freezing these sushi are collectively referred to as frozen sushi in this specification.

これまでに、冷凍寿司の食味変化について、様々な検討がなされており、例えば、−40℃で6日間冷凍後、試験前夜に冷蔵庫(10℃≦)で解凍した冷凍寿司と、2日間冷蔵庫(10℃≦)で貯蔵した具材を寿司シャリ(米飯塊)にのせた非冷凍寿司とを官能評価したところ、具材がサバの場合、非冷凍寿司よりも冷凍寿司の方が美味しいと評価されたとの報告がある。そのため、凍結・解凍による寿司ネタの品質劣化は小さく、冷凍寿司の製造ではシャリの品質劣化をいかに抑制するかが重要であると考えられる。   So far, various studies have been made on changes in the taste of frozen sushi. For example, frozen sushi frozen at −40 ° C. for 6 days and then thawed in the refrigerator (10 ° C. ≦) the night before the test, Sensory evaluation of ingredients stored at 10 ° C ≦) on non-frozen sushi placed on sushi shari (rice chunks of rice). If the ingredients are mackerel, it is evaluated that frozen sushi is more delicious than non-frozen sushi. There is a report. Therefore, the quality deterioration of sushi material due to freezing and thawing is small, and it is considered to be important how to suppress the quality deterioration of shari in the production of frozen sushi.

本発明の冷凍米飯の製造方法は、洗浄した精白米に水とともに、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有する冷凍米飯用改質剤を添加し、この冷凍米飯用改質剤を含有する水中に、前記精白米を浸漬した後に炊飯し、炊飯後の米飯を急速凍結することを特徴とする。   In the method for producing frozen cooked rice of the present invention, a frozen cooked rice is added with a modifier for frozen cooked rice that contains sucrose fatty acid ester and malto-oligosaccharide without water, edible fat and plant sterol, and water. The polished rice is dipped in water containing a rice cooker and then cooked, and the cooked rice is rapidly frozen.

精白米の洗浄については、通常の調理時に行う洗浄方法であれば特に限定されることはなく適用可能である。なお、無洗米のように、市場への流通前に洗浄が完了しており、調理者が炊飯前に洗浄する必要がない精白米については、洗浄した精白米の一種とみなすことができる。   The cleaning of polished rice is not particularly limited as long as it is a cleaning method performed during normal cooking. In addition, like unwashed rice, washing is completed before distribution to the market, and polished rice that does not need to be washed by the cooker before cooking can be regarded as a type of washed polished rice.

冷凍米飯用改質剤は、炊飯時に精白米に加える水に予め分散、溶解させておくことが好ましい。具体的には、ショ糖脂肪酸エステルの配合割合が、精白米中の澱粉質量に対して0.1wt%以上0.5wt%以下であり、前記マルトオリゴ糖の配合割合が炊飯後の米飯中の水質量に対して2.0wt%以上5.0wt%以下であることが好ましく考慮される。   The frozen cooked rice modifier is preferably dispersed and dissolved in advance in water added to the polished rice during cooking. Specifically, the blending ratio of the sucrose fatty acid ester is 0.1 wt% or more and 0.5 wt% or less with respect to the starch mass in the polished rice, and the blending ratio of the maltooligosaccharide is water in the cooked rice after cooking. It is preferably considered that the content is 2.0 wt% or more and 5.0 wt% or less with respect to the mass.

このような冷凍米飯用改質剤を、適量の水、例えば100mL程度の水に添加して、攪拌し、分散・溶解させることが例示される。攪拌については、従来公知の方法を適宜用いることができ、ハンドミキサーやマグネチックスターラー等の装置を用いてもよい。また、必要に応じて、適宜加温しながら水に溶解することも考慮される。   It is exemplified that such a frozen cooked rice modifier is added to an appropriate amount of water, for example, about 100 mL of water, stirred, dispersed and dissolved. About stirring, a conventionally well-known method can be used suitably and apparatuses, such as a hand mixer and a magnetic stirrer, may be used. Further, it is also considered to dissolve in water while appropriately heating as necessary.

なお、マルトオリゴ糖がシラップ状の組成物である場合、その組成物における水分含量を考慮して、適宜調製時の水の分量を減らすことが考慮される。   When the maltooligosaccharide is a syrup-like composition, it is considered that the amount of water during preparation is appropriately reduced in consideration of the water content in the composition.

このようにして調製した冷凍米飯用改質剤溶液と、冷凍米飯用改質剤を含有していない水とで所定量の水の分量とし、これらを洗浄後の精白米に加え、冷凍米飯用改質剤を含有する水中に精白米を浸漬処理する。   The amount of water prepared in this way and the amount of water that does not contain the frozen rice modifier are adjusted to a predetermined amount of water, and these are added to the polished rice after washing, for frozen rice The polished rice is soaked in water containing a modifier.

浸漬の条件としては、例えば、25℃で30分以上であることが好ましく考慮される。浸漬の条件は、試料米の収穫年、澱粉含量、水分含量や、調理する季節の温度・湿度等の条件に応じて適宜変更することが望ましい。浸漬時間の上限については、特に限定されないが、図1に示したように、浸漬開始から90分後以降には吸水がほとんど進行しないので、60分間程度とすることが好ましい。浸漬時間を60分間程度とすると、精白米の表面から内部への冷凍米飯用改質剤の浸透および拡散が確実なものとなる。   As the conditions for the immersion, for example, it is preferably considered that it is 30 minutes or more at 25 ° C. The soaking conditions are preferably changed as appropriate according to conditions such as the year of harvest of the sample rice, starch content, moisture content, and the temperature and humidity of the cooking season. The upper limit of the immersion time is not particularly limited. However, as shown in FIG. 1, since water absorption hardly proceeds after 90 minutes from the start of immersion, it is preferably about 60 minutes. When the immersion time is about 60 minutes, the penetration and diffusion of the frozen rice modifier from the surface to the inside of the polished rice is ensured.

次いで、冷凍米飯用改質剤を含有する水を用いて精白米を炊飯し、米飯を得る。炊飯方法については、従来公知の炊飯方法であれば、特に限定されることなく適用可能である。電気炊飯器、ガス炊飯器等いずれの装置を用いてもよい。また、電気炊飯器を使用する場合、一般的な、白米炊きモードの他、早炊きモード等種々の炊飯プログラムを適用可能である。   Next, the polished rice is cooked using water containing a modifier for frozen cooked rice to obtain cooked rice. About the rice cooking method, if it is a conventionally well-known rice cooking method, it is applicable without being specifically limited. Any device such as an electric rice cooker or a gas cooker may be used. Moreover, when using an electric rice cooker, various rice cooking programs, such as a quick cooking mode other than general white rice cooking mode, are applicable.

また、炊飯時の水加減については、冷凍米飯用改質剤と水の合計量が、通常の炊飯時と同程度になればよい。   Moreover, about the water adjustment at the time of rice cooking, the total amount of the modifier for frozen rice rice and water should just become the same grade as the time of normal rice cooking.

急速凍結時の温度は、−20℃以下であることが好ましく考慮される。急速凍結時の温度の下限値については、特に限定されないが、例えば、−40℃程度であることが例示される。ただ、実用的には、−20℃〜−30℃程度の低温で必要十分である。   It is preferably considered that the temperature at the time of quick freezing is −20 ° C. or lower. Although it does not specifically limit about the lower limit of the temperature at the time of quick freezing, For example, it is about about -40 degreeC. However, practically, it is necessary and sufficient at a low temperature of about −20 ° C. to −30 ° C.

なお、炊飯後の米飯は、そのまま白飯としてもよいが、炊飯後の米飯に調味液を添加して寿司シャリとし、その上部に具材を載置して寿司を製造した後、急速凍結することが好ましく考慮される。   In addition, the cooked rice may be white rice as it is, but after adding the seasoning liquid to the cooked rice to make a sushi, sushi is prepared by placing ingredients on top of it, and then quickly freezes. Are preferably considered.

このようにして、本発明の冷凍米飯、冷凍寿司を製造することができる。得られた冷凍米飯、冷凍寿司は、−18℃以下で冷凍保存されていれば、およそ一年程度は食味の劣化が起こらないと考えられる。また、冷凍保存に−50℃〜−80℃程度の超低温庫を使用すると、さらに長期間にわたって食味の劣化を抑えることが可能である。   Thus, the frozen cooked rice and frozen sushi of this invention can be manufactured. If the obtained frozen cooked rice and frozen sushi are stored frozen at -18 ° C. or lower, it is considered that the taste does not deteriorate for about one year. Moreover, when an ultra-low temperature chamber of about −50 ° C. to −80 ° C. is used for frozen storage, it is possible to suppress the deterioration of the taste over a longer period.

一方、本発明の冷凍米飯の解凍方法は、上記の冷凍米飯の製造方法により得られた冷凍米飯に接触させた加熱部材を、1)冷凍米飯中の水分が凍結状態を維持したまま加熱する第1加熱工程と、2)この第1加熱工程に次いで冷凍米飯中の凍結状態の水分が融解するように加熱する第2加熱工程と、3)この第2加熱工程に次いで冷凍米飯を喫食に適した温度まで昇温させる第3加熱工程、とを含むことを特徴とする。   On the other hand, in the method for thawing frozen rice of the present invention, the heating member brought into contact with the frozen rice obtained by the method for producing frozen rice is heated 1) while the water in the frozen rice is kept frozen. 1) a heating process, 2) a second heating process that heats the frozen rice in the frozen rice after the first heating process, and 3) suitable for eating the frozen rice after the second heating process. And a third heating step for raising the temperature to a predetermined temperature.

なお、上記の用語「接触」は、加熱部材と冷凍米飯との直接接触に限定されず、加熱部材状に敷いた食品用ラップフィルムやアルミホイル等のフィルム様資材、シート様資材の上に冷凍米飯を載置した間接的な接触をも意味している。   The term “contact” is not limited to the direct contact between the heating member and the frozen cooked rice, but is frozen on a film-like material such as a food wrap film or aluminum foil laid on the heating member, or a sheet-like material. It also means indirect contact with cooked rice.

加熱部材としては、冷凍米飯の急激な温度上昇を避けるために、比較的マイルドな温度上昇が可能な装置を用いることが好ましい。一方、冷凍米飯の周囲の温度を含めて急激に上昇させて、冷凍米飯の表面全体を加熱する方法は、冷凍寿司を対象とする場合に、具材部(寿司ネタ)からのドリップ発生による食味の低下を引き起こす可能性があるため好ましくない。そこで、本発明における冷凍米飯の解凍方法では、シリコンラバーヒーター等の平板状の加熱部材を用いた伝導伝熱による加熱が好ましく考慮される。シリコンラバーヒーターを用いると、米飯塊底面からの伝導伝熱に加えて、側面と上面からの対流伝熱により、比較的マイルドに解凍を促進させることができると考えられる。また、シリコンラバーヒーターの使用は、冷凍米飯へのにおい移り等が起こりにくく、しかも食品衛生の観点から食品用ラップフィルム等のフィルム様資材を介して冷凍米飯をヒーター上に載置した場合に、食品用ラップフィルムが加熱融解してヒーター上面及び冷凍米飯の下面にべったりと付着する恐れが少ない点においても優れている。   As the heating member, it is preferable to use a device capable of a relatively mild temperature increase in order to avoid a rapid temperature increase of the frozen cooked rice. On the other hand, the method of heating the entire surface of the frozen cooked rice by rapidly increasing the temperature including the ambient temperature of the frozen cooked rice is a taste caused by the occurrence of drip from the ingredients (sushi material) when the target is frozen sushi. This is not preferable because it may cause a decrease in the temperature. Therefore, in the method for thawing frozen cooked rice in the present invention, heating by conduction heat transfer using a flat heating member such as a silicon rubber heater is preferably considered. When a silicon rubber heater is used, it is considered that thawing can be promoted relatively mildly by convective heat transfer from the side surface and the top surface in addition to conduction heat transfer from the bottom surface of the cooked rice mass. In addition, the use of silicon rubber heater is less likely to cause odor transfer to frozen rice, and from the viewpoint of food hygiene, when frozen rice is placed on the heater via a film-like material such as a food wrap film, It is also excellent in that the food wrap film is less likely to adhere to the upper surface of the heater and the lower surface of the frozen cooked rice by heating and melting.

このような加熱部材に、冷凍米飯を接触させて以下の3ステップに沿って加熱する。すなわち、1)冷凍米飯中の水分が凍結状態を維持したまま加熱する第1加熱工程と、2)この第1加熱工程に次いで冷凍米飯中の凍結状態の水分が融解するように加熱する第2加熱工程と、3)この第2加熱工程に次いで冷凍米飯を喫食に適した温度まで昇温させる第3加熱工程、である。   Frozen cooked rice is brought into contact with such a heating member and heated along the following three steps. That is, 1) a first heating step in which the moisture in the frozen cooked rice is heated while maintaining a frozen state, and 2) a second heating in which the moisture in the frozen state in the frozen cooked rice is melted following the first heating step. A heating step and 3) a third heating step for raising the temperature of the frozen cooked rice to a temperature suitable for eating following the second heating step.

第1加熱工程は、伝熱学的に説明するならば、凍結した米飯塊の顕熱変化過程であり、冷凍米飯の内部における水分は氷として存在し、融点未満の温度領域において、冷凍米飯の温度を上昇させる工程である。   If explained in terms of heat transfer, the first heating step is a sensible heat change process of the frozen cooked rice lump. Water in the frozen cooked rice exists as ice, and in the temperature range below the melting point, This is a step of increasing the temperature.

続く、第2加熱工程は、伝熱学的に説明するならば、凍結した米飯塊の解凍が進行する潜熱変化過程である。この工程においては、冷凍米飯の内部における水分は氷と水が共存しており、冷凍米飯の温度が融点を超えて解凍するように熱エネルギーを供給して温度を維持させることを目的とする。   The subsequent second heating step is a latent heat changing process in which thawing of the frozen cooked rice mass proceeds, if explained in terms of heat transfer. The purpose of this step is to maintain the temperature by supplying heat energy so that ice and water coexist in the inside of the frozen cooked rice and the temperature of the frozen cooked rice exceeds the melting point.

そして、第3加熱工程は、伝熱学的に説明するならば、解凍した米飯塊が所定温度に達するまでの顕熱変化過程である。この工程においては、冷凍米飯の内部における水分は完全に水として存在しており、冷凍米飯の温度が喫食に適した温度に達するまで温度を上昇させることを目的とする。   The third heating step is a sensible heat change process until the thawed cooked rice mass reaches a predetermined temperature, if explained in terms of heat transfer. In this step, the water in the frozen rice is completely present as water, and the purpose is to increase the temperature until the temperature of the frozen rice reaches a temperature suitable for eating.

前記の第1加熱工程、第2加熱工程および第3加熱工程の各工程における加熱温度、加熱時間については、冷凍米飯の体積、厚み、冷凍保存温度等により適宜変更することが考慮される。例えば、冷凍保存していた−35℃の円柱形の冷凍米飯約25cmを解凍する場合、図2に示したように、第1加熱工程の加熱条件は、15℃で5分間、第2加熱工程の加熱条件は、25℃で7分間、第3加熱工程の加熱条件は、40℃で20分間であることが例示される。なお、上記の冷凍保存していた冷凍米飯の温度は、庫内温度−35℃の低温恒温器に収納して温度平衡に達している状態における温度を意味しており、冷凍米飯の表面部および中心部のいずれの温度も−35℃であることを示している。解凍の終了の目安としては、例えば、温度上昇が最も遅い米飯塊上部の温度を測定し、その温度が25℃に達した時点とすることが例示される。 Regarding the heating temperature and heating time in each of the first heating step, the second heating step, and the third heating step, it is considered that the heating temperature and the heating time are appropriately changed depending on the volume, thickness, frozen storage temperature, etc. of the frozen cooked rice. For example, when thawing about 25 cm 3 of a cylindrical frozen rice at −35 ° C. that has been stored frozen, as shown in FIG. 2, the heating condition of the first heating step is the second heating at 15 ° C. for 5 minutes. The heating condition of the process is exemplified by 25 ° C. for 7 minutes, and the heating condition of the third heating process is exemplified by 40 ° C. for 20 minutes. In addition, the temperature of the above-mentioned frozen rice that has been frozen and stored means a temperature in a state where the temperature is in a low-temperature incubator with an internal temperature of −35 ° C. and has reached temperature equilibrium. All the temperatures in the center are -35 ° C. As an indication of the end of thawing, for example, the temperature of the upper part of the cooked rice lump whose temperature rise is the slowest is measured, and the temperature reaches 25 ° C.

このような加熱条件で解凍した米飯では、米飯粒が白濁しておらず、ツヤがあり、しかも米飯粒が硬化していないので、口に含むと適度な力で米飯塊が米飯粒に崩れる。さらに、冷凍米飯用改質剤が添加されているにも関わらず、雑味がなく、米本来の旨味を十分に感じられる。また、冷凍米飯が寿司である場合、具材部である寿司ネタは解け残りがなく、ひんやりとしており、米飯部である寿司シャリはほどよい温度となる。   In the cooked rice thawed under such heating conditions, the cooked rice grains are not cloudy, glossy, and the cooked rice grains are not cured, so that the cooked rice cake collapses into cooked rice grains with an appropriate force when included in the mouth. Furthermore, despite the addition of the frozen cooked rice modifier, there is no miscellaneous taste and the original umami taste can be sufficiently felt. In addition, when the frozen cooked rice is sushi, the ingredients of the sushi material are unmelted and cool, and the sushi shari of the cooked rice has a moderate temperature.

前記の第1加熱工程、第2加熱工程および第3加熱工程の各工程における加熱温度、加熱時間については、手動での調節および電子機器によるプログラム制御としてもよい。   About the heating temperature and heating time in each process of the said 1st heating process, 2nd heating process, and 3rd heating process, it is good also as manual control and program control by an electronic device.

以下に本発明の冷凍米飯用改質剤および冷凍米飯の製造例を実施例として示すが、本発明の冷凍米飯用改質剤および冷凍米飯は実施例に限定されるものではない。   Although the manufacturing example of the frozen cooked rice modifier and frozen cooked rice of this invention is shown as an Example below, the frozen cooked rice modifier and frozen cooked rice of this invention are not limited to an Example.

A.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(1)
(実施例1)
<冷凍米飯用改質剤溶液の調製>
試料米には2016年水沢産ひとめぼれ(水分含量13%、(株)純情米いわて)の精白米を用いた。ショ糖脂肪酸エステルとして、ショ糖ステアリン酸エステル(リョートーシュガーエステルS−1570、HLB値15、以下SES15と略記、三菱ケミカルフーズ(株))、マルトオリゴ糖として、マルトトリオース主成分マルトオリゴ糖組成物(ピュアトースL、固形分75.0%(w/w)、以下G(A)シラップと略記、サンエイ糖化(株)/群栄化学工業(株))を用いた。
A. Freezing and thawing test of cooked rice with the modifier for frozen cooked rice (1)
Example 1
<Preparation of frozen rice cooker solution>
As the sample rice, polished rice from 2016 Mizusawa Hitomebore (water content 13%, Junjo Iwate Co., Ltd.) was used. As sucrose fatty acid ester, sucrose stearate ester (Ryoto sugar ester S-1570, HLB value 15, hereinafter abbreviated as SES15, Mitsubishi Chemical Foods Co., Ltd.), as malto-oligosaccharide, malto-triose main component malto-oligosaccharide composition (Pureatose L, solid content 75.0% (w / w), hereinafter G 3 (A) abbreviated as syrup, Sanei Saccharification Co., Ltd./Gunei Chemical Industry Co., Ltd.) was used.

500mL容量ビーカーに脱塩水を90mL量り取り、そこへ上記のショ糖脂肪酸エステルおよびマルトオリゴ糖組成物を加えて撹拌した。なおマルトオリゴ糖組成物の水分含量を考慮し、最終的に100mLとなるように脱塩水を加えてよく混合した。ビーカーをパラフィンフィルム(Parafilm Ma(R)、Bemis flexible Packaging)で密閉し、マグネチックスターラー(M3、(株)井内盛栄堂)を用いて60℃で30分間撹拌してショ糖脂肪酸エステルおよびマルトオリゴ糖組成物を溶解させた。それからビーカーを20℃に設定した低温恒湿器(LTI−601SD、東京理化器械(株))に収納して60分間放冷して温度調節し、冷凍米飯用改質剤溶液を調製した。
<炊飯>
精白米0.32kg(2合)をステンレス鋼製ボウル(SUS304製、Φ185mm×H70mm)に入れ、これに25℃の脱塩水400mLを加えて10回攪拌後に新しい脱塩水に交換し、これを5回繰り返した。加水量は洗米によって付着した水を含めて精白米質量の1.4倍より100g少なくした脱塩水348gを加えた。ここへ、100gの脱塩水に溶解させた乳化剤溶液とマルトオリゴ糖水溶液を含有する冷凍米飯用改質剤溶液を加えた。次に、これを25℃に設定した低温恒湿器に収納して精白米を冷凍米飯用改質剤溶液に60分間浸漬させた。浸漬した精白米を炊飯器(圧力IH炊飯ジャーJPB−G180KL、タイガー魔法瓶(株))で「白米炊きコース」を選択して炊飯した。なお、精白米を炊飯する際に、コンパクトサーモロガー(AM−8001T、安立計器(株))を用いて、炊飯釜の底、水/米粒相の中心点、上部空間の3カ所の温度を測定した。
<米飯の凍結処理>
上記のとおり炊飯した米飯を約25cmの円柱状の米飯塊に成形した。図3に示したように、得られた米飯塊の乾燥を防ぐために底面から水面までの高さが10mmになるように脱塩水を入れ、試料台としてのクリンプ目バット網を設置したステンレス鋼製蓋付バット(SUS304製、W400mm×D280mm×H95mm)内に、円柱形の米飯約25cmを8個等間隔に並べて蓋をした。このバットを庫内温度25℃に設定した恒温恒湿装置(FMC−1000、理化器械(株))内に収納して1時間放冷して温度調整した後、米飯塊を庫内温度−18℃に設定した低温恒温恒湿器(PL−1SP、タバイエスペック(株))内に収納し、凍結した。
<冷凍米飯の解凍処理>
温度調節器(デジサーモOT−9pro、オーエムヒーター(株))に接続したシリコンラバーヒーター(Standard Type、100V、375W,W250mm×D250mm×H15mm、オーエムヒーター(株))を用いた加熱解凍により、米飯塊の温度が25℃に昇温するまで冷凍米飯を加熱して、解凍した。シリコンラバーヒーターの下方向への放熱を防ぐために、断熱材として発泡ポリウレタンをシリコンラバーヒーターの下に敷いた。米飯塊とシリコンラバーヒーターとの接触面の温度を測定する際には、図4に示したように、温度センサーが米飯塊とシリコンラバーヒーターに密着するように、冷凍米飯塊の底面にカッターで温度センサーが挿入可能な大きさの切り込みを設けた。これらを庫内温度40℃に設定した恒温恒湿装置(FMC−1000、理化器械(株))内に設置して解凍した。
(実施例2)
マルトオリゴ糖をマルトトリオース・マルトース主成分マルトオリゴ糖組成物(オリゴトース、固形分72.6%(w/w)、以下G−Gシラップと略記、三菱ケミカルフーズ(株))に変更したこと以外は、実施例1と同様にして、冷凍米飯を得た。
90 mL of demineralized water was weighed out into a 500 mL capacity beaker, and the sucrose fatty acid ester and maltooligosaccharide composition were added thereto and stirred. In consideration of the water content of the maltooligosaccharide composition, demineralized water was added and mixed well so that the final volume became 100 mL. The beaker was sealed with a paraffin film (Parafilm Ma®, Bemis flexible packaging), and stirred for 30 minutes at 60 ° C. using a magnetic stirrer (M3, Inoue Seieido Co., Ltd.) to sucrose fatty acid ester and maltooligosaccharide. The composition was dissolved. Then, the beaker was housed in a low temperature and humidity chamber (LTI-601SD, Tokyo Rika Kikai Co., Ltd.) set at 20 ° C. and left to cool for 60 minutes to adjust the temperature of the frozen rice cooker solution.
<Cooking rice>
Put 0.32 kg (2 go) of polished rice in a stainless steel bowl (SUS304, Φ185 mm × H70 mm), add 400 mL of demineralized water at 25 ° C., stir 10 times, and replace with fresh demineralized water. Repeated times. The amount of water added was 348 g of demineralized water that was less than 100 times the mass of polished rice, including the water adhering to the washed rice. To this, an emulsifier solution dissolved in 100 g of demineralized water and a frozen cooked rice modifier solution containing a maltooligosaccharide aqueous solution were added. Next, this was stored in a low-temperature humidity chamber set at 25 ° C., and the polished rice was immersed in the frozen rice modifier solution for 60 minutes. The soaked polished rice was cooked by selecting “white rice cooking course” using a rice cooker (pressure IH rice cooker JPB-G180KL, Tiger Thermos Co., Ltd.). In addition, when cooking polished rice, the temperature of three places, the bottom of the rice cooker, the center point of the water / rice grain phase, and the upper space are measured using a compact thermologger (AM-8001T, Anritsu Keiki Co., Ltd.). did.
<Freezing of cooked rice>
Cooked rice as described above was formed into a cylindrical cooked rice lump of about 25 cm 3 . As shown in FIG. 3, in order to prevent drying of the resulting cooked rice lump, desalted water is added so that the height from the bottom surface to the water surface is 10 mm, and a crimped bat net is installed as a sample stage. In a bat with a lid (manufactured by SUS304, W400 mm × D280 mm × H95 mm), about 25 cm 3 of cylindrical rice were arranged at equal intervals and covered. The vat is stored in a constant temperature and humidity apparatus (FMC-1000, Rika Kikai Co., Ltd.) set at a chamber temperature of 25 ° C. and left to cool for 1 hour. It housed in the low-temperature constant temperature and humidity chamber (PL-1SP, Tabai Espec Co., Ltd.) set to ° C. and frozen.
<Defrosting frozen rice>
By heating and thawing using a silicon rubber heater (Standard Type, 100 V, 375 W, W 250 mm × D 250 mm × H 15 mm, OH Heater Co., Ltd.) connected to a temperature controller (Digithermo OT-9pro, OH Heater Co., Ltd.) The frozen cooked rice was heated and thawed until the temperature increased to 25 ° C. In order to prevent downward heat dissipation of the silicone rubber heater, polyurethane foam was laid under the silicone rubber heater as a heat insulating material. When measuring the temperature of the contact surface between the cooked rice lump and the silicon rubber heater, as shown in FIG. 4, use a cutter on the bottom of the frozen cooked rice lump so that the temperature sensor is in close contact with the cooked rice lump and the silicon rubber heater. A notch of a size that can be inserted into the temperature sensor was provided. These were placed in a constant temperature and humidity apparatus (FMC-1000, Rika Kikai Co., Ltd.) set at a temperature of 40 ° C. and thawed.
(Example 2)
Maltooligosaccharides maltotriose, maltose main component maltooligosaccharides composition (Origotosu solids 72.6% (w / w), the following G 3 -G 2 syrup abbreviated, Mitsubishi Chemical Foods Co., Ltd.) was changed to Except for the above, frozen rice was obtained in the same manner as in Example 1.

また、得られた米飯について、実施例1と同様にして解凍した。
(実施例3)
マルトオリゴ糖をマルトテトラオース主成分マルトオリゴ糖組成物(テトラップ、固形分72.5%(w/w)、以下Gシラップと略記、(株)林原))に変更したこと以外は、実施例1と同様にして、冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Example 3)
Maltooligosaccharides maltotetraose main component maltooligosaccharides composition (Tetorappu solids 72.5% (w / w), the following G 4 syrup abbreviated, Ltd. Hayashibara) was changed to), Example 1 In the same manner, frozen rice was obtained.

また、得られた米飯について、実施例1と同様にして解凍した。
(実施例4)
ショ糖脂肪酸エステルをショ糖パルミチン酸エステル(リョートーシュガーエステルP−1670、HLB値16、以下SEP−16と略記、三菱ケミカルフーズ(株))に変更したこと以外は、実施例1と同様にして、冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
Example 4
Example 1 except that the sucrose fatty acid ester was changed to sucrose palmitate ester (Ryoto Sugar ester P-1670, HLB value 16, hereinafter abbreviated as SEP-16, Mitsubishi Chemical Foods Co., Ltd.) I got frozen rice.

また、得られた米飯について、実施例1と同様にして解凍した。
(実施例5)
ショ糖脂肪酸エステルをSEP−16に変更し、マルトオリゴ糖をG−Gシラップに変更したこと以外は、実施例1と同様にして、冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Example 5)
Frozen cooked rice was obtained in the same manner as in Example 1 except that the sucrose fatty acid ester was changed to SEP-16 and the maltooligosaccharide was changed to G 3 -G 2 syrup.

また、得られた米飯について、実施例1と同様にして解凍した。
(実施例6)
ショ糖脂肪酸エステルをSEP−16に変更し、マルトオリゴ糖をGシラップに変更したこと以外は、実施例1と同様にして、冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Example 6)
Sucrose fatty acid ester was changed to SEP-16, except for changing the malto-oligosaccharide to G 4 syrup, in the same manner as in Example 1 to obtain a frozen cooked rice.

また、得られた米飯について、実施例1と同様にして解凍した。
(比較例1)
マルトオリゴ糖を添加せずに、スクロース(特級、以下Sucと略記、和光純薬工業(株))を添加したこと以外は、実施例1と同様にして冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Comparative Example 1)
Frozen cooked rice was obtained in the same manner as in Example 1 except that sucrose (special grade, hereinafter abbreviated as Suc, Wako Pure Chemical Industries, Ltd.) was added without adding maltooligosaccharide.

また、得られた米飯について、実施例1と同様にして解凍した。
(比較例2)
ショ糖脂肪酸エステルをSEP−16に変更し、マルトオリゴ糖を添加せずにSucを添加したこと以外は、実施例1と同様にして冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Comparative Example 2)
Frozen cooked rice was obtained in the same manner as in Example 1 except that the sucrose fatty acid ester was changed to SEP-16 and Suc was added without adding maltooligosaccharide.

また、得られた米飯について、実施例1と同様にして解凍した。
(比較例3)
ショ糖脂肪酸エステルを添加しなかったこと以外は、実施例1と同様にして、冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Comparative Example 3)
Frozen cooked rice was obtained in the same manner as in Example 1 except that the sucrose fatty acid ester was not added.

また、得られた米飯について、実施例1と同様にして解凍した。
(比較例4)
ショ糖脂肪酸エステルをSEP−16に変更し、マルトオリゴ糖を添加せずに炊飯したこと以外は、実施例1と同様にして、冷凍米飯を得た。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Comparative Example 4)
Frozen cooked rice was obtained in the same manner as in Example 1 except that the sucrose fatty acid ester was changed to SEP-16 and cooked without adding maltooligosaccharide.

また、得られた米飯について、実施例1と同様にして解凍した。
(対照区)
対照区として、ショ糖脂肪酸エステルおよびマルトオリゴ糖のいずれも含有していない無添加の米飯を炊飯した。得られた米飯については、凍結・解凍処理を行わなかった(非凍結・解凍処理)。
なお、炊飯した米飯の一部については、ショ糖脂肪酸エステルおよびマルトオリゴ糖のいずれも添加せずに炊飯したこと以外は、実施例1と同様にして、冷凍米飯を得た(無添加冷凍米飯)。
Further, the obtained cooked rice was thawed in the same manner as in Example 1.
(Control zone)
As a control group, non-added cooked rice containing neither sucrose fatty acid ester nor maltooligosaccharide was cooked. The obtained cooked rice was not subjected to freezing / thawing treatment (non-freezing / thawing treatment).
In addition, about the part of cooked cooked rice, frozen cooked rice was obtained like Example 1 except not having added neither a sucrose fatty acid ester nor maltooligosaccharide (added frozen cooked rice). .

また、得られた米飯について、実施例1と同様にして解凍した。   Further, the obtained cooked rice was thawed in the same manner as in Example 1.

実施例1〜6および比較例1〜4の冷凍米飯および解凍後の米飯について以下の方法にしたがって「白色度」および「硬さ」を測定し、評価した。   The “whiteness” and “hardness” of the frozen cooked rice and the cooked rice after thawing of Examples 1 to 6 and Comparative Examples 1 to 4 were measured and evaluated.

また、実施例1〜6および比較例1〜4の冷凍米飯用改質剤を添加して炊飯した米飯に調味液を添加して寿司シャリとし、この寿司シャリの上に、具材(寿司ネタ)として、しめ鯖を載せて製造した柿の葉寿司について、凍結・解凍処理後、以下の方法にしたがって食味の官能評価を行った。   Moreover, the seasoning liquid is added to the cooked rice by adding the frozen rice cookers of Examples 1 to 6 and Comparative Examples 1 to 4, and the ingredients are sushi. ), The kashiwanoha sushi prepared with shimeji mushroom was subjected to a freezing and thawing treatment, followed by a sensory evaluation of the taste according to the following method.

(1)白色度の測定
凍結開始から48時間後の試料を項目5と同様に3.5時間の空気解凍した後、分光測色計(CM−3500d、コニカミノルタセンシング(株))を用いて、Φ30mmのシャーレに入れた米飯塊の明度(L*)と色度(a*、b*)を測定した。なお、測定モードを反射モード、正反射処理はSCE、UV条件は100%Fullに設定した。そして、以下の式(1)で定義される白色度(W)を求めた。
(1) Measurement of whiteness A sample 48 hours after the start of freezing was thawed for 3.5 hours in the same manner as in item 5, and then using a spectrocolorimeter (CM-3500d, Konica Minolta Sensing Co., Ltd.). The lightness (L *) and chromaticity (a *, b *) of the cooked rice mass placed in a petri dish of Φ30 mm were measured. The measurement mode was set to the reflection mode, the regular reflection process was set to SCE, and the UV condition was set to 100% Full. And the whiteness (W) defined by the following formula | equation (1) was calculated | required.

W = 100− { (100−L*)2+a*2+b*2 }1/2 (1)
求めた白色度(W)を以下の基準に基づいて評価した。
W = 100− {(100−L *) 2 + a * 2 + b * 2} 1/2 (1)
The obtained whiteness (W) was evaluated based on the following criteria.

A:白色度(W)が75.9未満であり、解凍後の米飯塊に透明感、つやがある。
B:白色度(W)が75.9以上76.2以下の範囲であり、解凍後の米飯塊の透明感、つやが低下している。
C:白色度(W)が76.2超であり、解凍後の米飯塊が白濁し、つやがない。
A: The whiteness (W) is less than 75.9, and the cooked rice lump after thawing is transparent and glossy.
B: Whiteness (W) is in the range of 75.9 or more and 76.2 or less, and the transparency and gloss of the cooked rice cake after thawing are reduced.
C: Whiteness (W) is more than 76.2, and the mass of cooked rice after thawing becomes cloudy and not glossy.

結果を表1に示す。   The results are shown in Table 1.

表1に示したように、実施例1〜6の冷凍米飯を解凍して得られた米飯では、比較例1〜4と比較して白色度が統計上、有意に低かった。中でも、SES15とG−Gシラップを併用添加した実施例2、SES15とGシラップを併用添加した実施例3、およびSEP16とGシラップを併用添加した実施例6の解凍後の米飯における白色度は、非凍結・解凍処理の試料である対照区の米飯と統計上の有意差が無かった。そのため、上記3つの実施例の解凍後の米飯で、白濁化がより抑制されることが確認された。 As shown in Table 1, in the cooked rice obtained by thawing the frozen cooked rice of Examples 1 to 6, the whiteness was statistically significantly lower than those of Comparative Examples 1 to 4. Among them, the rice of SES15 and G 3 -G 2 syrup implement the combination added Example 2, SES15 and G 4 Example syrup in combination added 3, and SEP16 and G 4 after thawing in Example 6 the syrup in combination added There was no statistically significant difference in whiteness from cooked rice in the control group, which was a non-frozen and thawed sample. Therefore, it was confirmed that white turbidity is further suppressed by the cooked rice after thawing in the above three examples.

(2)米飯塊の硬さの測定
定格容量196Nのロードセルおよび円板状プランジャー(No.19、Φ55×H8mm)を装着した単軸圧縮・引張型レオメータ(RE2−33005C、(株)山電)を用いて圧縮速度1mm・s−1、データ間隔100msの条件で単軸圧縮破断試験を行った。米飯塊の応力−ひずみ曲線の変曲点における応力を変曲点応力、ひずみを変曲点ひずみと定義し、この変曲点応力を硬さ[kPa]と定義した。なお、プランジャーと米飯塊の接触面に生じる摩擦を防ぐために、測定前にプランジャーの米飯との接触面に食用グリース(モリコートHPグリースHP−500、東レ・ダウコーニング(株))を塗布した。
(2) Measurement of hardness of cooked rice lump Uniaxial compression / tensile rheometer (RE2-30005C, Yamaden Co., Ltd.) equipped with a load cell with a rated capacity of 196 N and a disk-like plunger (No. 19, Φ55 × H8 mm) ) Was used to conduct a uniaxial compression fracture test under the conditions of a compression speed of 1 mm · s −1 and a data interval of 100 ms. The stress at the inflection point of the stress-strain curve of the cooked rice mass was defined as inflection point stress, the strain was defined as inflection point strain, and the inflection point stress was defined as hardness [kPa]. In addition, in order to prevent friction generated on the contact surface of the plunger and the cooked rice lump, edible grease (Molicoat HP Grease HP-500, Toray Dow Corning Co., Ltd.) was applied to the contact surface of the plunger with the cooked rice before measurement. .

求めた米飯塊の硬さを以下の基準に基づいて評価した。   The hardness of the obtained cooked rice mass was evaluated based on the following criteria.

A:硬さが12.6kPa未満であり、解凍後の米飯塊の硬化が抑制されている。
B:硬さが12.6kPa以上13.2kPa以下の範囲であり、解凍後の米飯塊の硬化がやや抑制されている。
C:硬さが13.2kPa超であり、解凍後の米飯塊の硬化が抑制されていない。
A: Hardness is less than 12.6 kPa, and hardening of the cooked rice lump after thawing is suppressed.
B: Hardness is in the range of 12.6 kPa to 13.2 kPa, and curing of the cooked rice cake after thawing is somewhat suppressed.
C: Hardness is over 13.2 kPa, and hardening of the cooked rice lump after thawing is not suppressed.

結果を表2に示す。   The results are shown in Table 2.

表2に示したように、SES15とG(A)シラップを併用添加した実施例1、SEP16とG(A)シラップを併用添加した実施例4、SEP16とG−Gシラップを併用添加した実施例5およびSEP16とGシラップを併用した実施例6の解凍後の米飯における変曲点応力、すなわち硬さが統計上、有意に低かった。一方、マルトオリゴ糖を添加せずスクロースを添加した比較例1、2の解凍後の米飯では、冷凍米飯用改質剤を添加しなかった比較例4と統計上の有意差が見られなかった。そのため、ショ糖脂肪酸エステルとスクロースを併用添加しても、相加・相乗的に米飯の硬化を抑制することができなかった。 As shown in Table 2, in combination SES15 and G 3 (A) Example of the syrup in combination added 1, SEP16 and G 3 (A) Example 4 the syrup in combination added, SEP16 and G 3 -G 2 syrup the added example 5 and SEP16 and G 4 inflection point stress at rice after thawing of example 6 in which a combination of syrup, i.e. hardness statistically was significantly lower. On the other hand, in the cooked rice of Comparative Examples 1 and 2 in which sucrose was added without adding maltooligosaccharide, no statistically significant difference was observed from Comparative Example 4 in which the frozen cooked rice modifier was not added. For this reason, even when sucrose fatty acid ester and sucrose are added in combination, hardening of cooked rice could not be suppressed additively or synergistically.

(3)凍結・解凍処理した柿の葉寿司の官能評価
実施例1〜6および比較例1〜4の冷凍米飯用改質剤を添加して炊飯した米飯に調味液を添加して寿司シャリとし、この寿司シャリの上に具材(寿司ネタ)としてしめ鯖を載せて、柿の葉寿司を製造した。この柿の葉寿司について、凍結・解凍処理後に、パネルとして、30代の男性5名、女性5名、40代の男性5名、女性5名、50代の男性5名、女性5名の合計30名に試食してもらい、以下の基準で柿の葉寿司の外観、食感および食味を評価した。
(3) Sensory evaluation of frozen and thaw-treated kashiwanoha sushi The seasoned liquid was added to the cooked rice with the frozen rice cookers of Examples 1 to 6 and Comparative Examples 1 to 4 to make a sushi sushi. On top of this sushi shari, koji leaf sushi was prepared by placing shimeji mushrooms as ingredients (sushi material). After this freezing and thawing process, this kashiwanoha sushi is a total of 5 males in their 30s, 5 females, 5 males in their 40s, 5 females, 5 males in their 50s, and 5 females. Thirty people sampled and evaluated the appearance, texture and taste of Kashiwanoha Sushi based on the following criteria.

[柿の葉寿司の外観の評価]
A:各世代のパネル10名中8名以上が、柿の葉寿司の米飯部が白濁しておらず、つやがあると評価した。
B:各世代のパネル10名中5名以上7名以下が、柿の葉寿司の米飯部が白濁しておらず、つやがあると評価した。
C:各世代のパネル10名中、柿の葉寿司の米飯部が白濁しておらず、つやがあると評価したのは4名以下であった。
[Evaluation of the appearance of Kashiwanoha Sushi]
A: Eight or more of the 10 panelists of each generation evaluated that the rice portion of Kashiwanoha sushi was not cloudy and was glossy.
B: 5 to 7 out of 10 panelists of each generation evaluated that the cooked rice portion of kashiwanoha sushi was not cloudy and glossy.
C: Among the 10 panelists of each generation, the cooked rice part of Kashiwanoha sushi was not cloudy, and 4 or less evaluated it as shiny.

[柿の葉寿司の口ざわりの評価]
A:各世代のパネル10名中8名以上が、柿の葉寿司の米飯部がほどよい硬さであり、口の中で米飯粒がほどけるような感覚があると評価した。
B:各世代のパネル10名中5名以上7名以下が、柿の葉寿司の米飯部がほどよい硬さであり、口の中で米飯粒がほどけるような感覚があると評価した。
C:各世代のパネル10名中、柿の葉寿司の米飯部がほどよい硬さであり、口の中で米飯粒がほどけるような感覚があると評価したのは4名以下であった。
[Evaluation of the texture of Kashiwanoha Sushi]
A: Eight or more of the 10 panelists of each generation evaluated that the cooked rice part of kashiwanoha sushi had a moderate hardness, and that there was a sense that the cooked rice grains could be unwound in the mouth.
B: 5 to 7 out of 10 panelists of each generation evaluated that the cooked rice part of kashiwanoha sushi had a moderate hardness and that there was a sense that the cooked rice grains could be unwound in the mouth.
C: Out of 10 panelists of each generation, less than 4 persons evaluated that the rice bowl part of Kashiwanoha sushi was moderately hard and that there was a sense that rice grains could be unwound in the mouth. .

[柿の葉寿司の食味の評価]
A:各世代のパネル10名中8名以上が、柿の葉寿司の米飯部と具材部とのなじみが良く、しかも米飯部に雑味や異味感がなく美味しいと評価した。
B:各世代のパネル10名中5名以上7名以下が、柿の葉寿司の米飯部と具材部とのなじみが良く、しかも米飯部に雑味や異味感がなく美味しいと評価した。
C:各世代のパネル10名中、柿の葉寿司の米飯部と具材部とのなじみが良く、しかも米飯部に雑味や異味感がなく美味しいと評価したのは4名以下であった。
[Evaluation of the taste of Kashiwanoha Sushi]
A: Eight or more of the 10 panelists of each generation evaluated that the familiar rice part and ingredients part of kashiwanoha sushi were good and that the cooked rice part was delicious with no miscellaneous taste or taste.
B: 5 to 7 out of 10 panel members of each generation evaluated that the familiar rice part and ingredients part of kashiwanoha sushi were good and that the cooked rice part was delicious with no miscellaneous taste or taste.
C: Out of 10 panelists of each generation, less than 4 people evaluated the kaki-no-ha sushi as having a good familiarity with the cooked rice and ingredients, and that the cooked rice was delicious with no miscellaneous taste or taste. .

結果を表3に示す。   The results are shown in Table 3.

表3に示したように、実施例の柿の葉寿司については、各世代のパネル10名中8名以上が、外観が良好で、口ざわりも良好であると評価した。さらに、柿の葉寿司の米飯部と具材部とのなじみが良く、しかも米飯部に雑味や異味感がなく美味しいと評価した。   As shown in Table 3, for Kashiwanoha sushi of the examples, 8 or more out of 10 panelists of each generation evaluated that the appearance was good and the mouthfeel was also good. Furthermore, it was evaluated that the familiarity between the rice and the ingredients of Kashiwanoha sushi was good, and that the rice did not have miscellaneous taste or taste.

しかしながら、比較例の柿の葉寿司については、外観が良好で、口ざわりも良好であると評価したのは、各世代のパネル10名中4名以下であった。また、柿の葉寿司の米飯部と具材部とのなじみが良く、しかも米飯部に雑味や異味感がなく美味しいと評価したのも、各世代のパネル10名中4名以下であった。   However, with regard to the Kashiwanoha sushi of the comparative example, it was less than 4 out of 10 panelists of each generation that the appearance was good and the mouthfeel was also good. In addition, it was less than 4 out of 10 panelists of each generation that kakinoha sushi had a good familiarity with the cooked rice and ingredients, and that the cooked rice had good taste and no taste. .

B.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(2)
<米飯塊の調製>
(実施例7)
ショ糖脂肪酸エステルをショ糖パルミチン酸エステル(リョートーシュガーエステルP−1670、HLB値16、以下SEP−16と略記、三菱ケミカルフーズ(株))に変更し、マルトオリゴ糖を、マルトトリオース主成分マルトオリゴ糖組成物(フジオリゴ糖#360、固形分75.0%(w/w)、以下G(B)シラップと略記、日本食品化工(株))に変更したこと以外は、前記A.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(1)における実施例1と同様にして冷凍米飯を得た。
B. Freezing and thawing test of cooked rice to which a modifier for frozen cooked rice is added (2)
<Preparation of cooked rice>
(Example 7)
Sucrose fatty acid ester was changed to sucrose palmitate ester (Ryoto sugar ester P-1670, HLB value 16, hereinafter abbreviated as SEP-16, Mitsubishi Chemical Foods Co., Ltd.), and maltooligosaccharide was the main component of maltotriose Except for changing to a maltooligosaccharide composition (Fuji oligosaccharide # 360, solid content 75.0% (w / w), hereinafter abbreviated as G 3 (B) syrup, Nippon Shokuhin Kako Co., Ltd.). The frozen cooked rice was obtained in the same manner as in Example 1 in the freezing and thawing test (1) of the cooked rice to which the modifier for frozen cooked rice was added.

(比較例4)
前記A.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(1)における比較例4と同一の冷凍米飯を使用した。
(Comparative Example 4)
A. The same frozen rice as in Comparative Example 4 in the freezing and thawing test (1) of the cooked rice to which the modifier for frozen cooked rice was added was used.

(比較例9)
ショ糖脂肪酸エステルを添加しなかったこと以外は、前記A.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(1)における実施例1と同様にして、冷凍米飯を得た。
(Comparative Example 9)
Except that sucrose fatty acid ester was not added, A. The frozen cooked rice was obtained in the same manner as in Example 1 in the freezing and thawing test (1) of the cooked rice to which the modifier for frozen cooked rice was added.

(対照区)
対照区として、前記A.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(1)と同様に、ショ糖脂肪酸エステルおよびマルトオリゴ糖のいずれも含有していないこと以外は、実施例1と同様にして、米飯を炊飯し、冷凍米飯を得た。
(Control zone)
As a control group, the A. Similar to the freezing and thawing test (1) of cooked rice to which a modifier for frozen cooked rice was added, the cooked rice was prepared in the same manner as in Example 1 except that neither sucrose fatty acid ester nor maltooligosaccharide was contained. Cooked rice and obtained frozen rice.

<米飯塊の冷凍貯蔵>
得られた冷凍米飯について、以下の温度条件で冷凍貯蔵した。
すなわち、まず、低温恒温恒湿器(PL−2KPH、タバイエスペック(株))の庫内温度を−25℃に調整した。上記実施例7、比較例4、5および対照区の冷凍米飯塊を低温恒温恒湿器の庫内に収納し、2時間保持した。その後、図5に示した解凍プログラムのように、庫内温度−25℃から0℃に12時間かけて上昇させ(+2.08℃・h−1)、さらに12時間かけて0℃から−25℃に下降させた(−2.08℃・h−1)。
なお、図5に解凍プラグラムを示したが、低温恒温恒湿器の温度記録装置が何らかの原因で停止したため、冷凍貯蔵8日後から9日後にかけての温度データが一部欠損している。
<Frozen storage of cooked rice>
The obtained frozen cooked rice was stored frozen under the following temperature conditions.
That is, first, the internal temperature of the low-temperature constant temperature and humidity chamber (PL-2KPH, Tabai Espec) was adjusted to -25 ° C. The frozen cooked rice chunks of Example 7, Comparative Examples 4 and 5 and the control group were stored in a low-temperature and constant-humidity chamber and held for 2 hours. Thereafter, as in the thawing program shown in FIG. 5, the internal temperature is raised from −25 ° C. to 0 ° C. over 12 hours (+ 2.08 ° C. · h −1 ), and further from 0 ° C. to −25 over 12 hours. The temperature was lowered to ° C. (−2.08 ° C. · h −1 ).
In addition, although the thawing | decompression program was shown in FIG. 5, since the temperature recording device of a low-temperature constant temperature and humidity chamber stopped for some reason, the temperature data from the 8th day to the 9th day after freezing storage are partly missing.

<米飯塊の解凍>
冷凍米飯塊の解凍は、庫内温度を40℃に設定した低温恒温恒湿器(PL−1SP、タバイエスペック(株))に冷凍米飯塊を2時間収納したのち、庫内温度を20℃に変更し、1時間収納して解凍した。
<Thawing rice mass>
For thawing frozen rice mass, store the frozen rice mass for 2 hours in a low-temperature constant temperature and humidity chamber (PL-1SP, Tabai Espec Co., Ltd.) with the internal temperature set to 40 ° C, and then set the internal temperature to 20 ° C. Changed, stored for 1 hour and thawed.

<米飯塊の硬さの測定>
前記A.冷凍米飯用改質剤を添加した米飯の凍結および解凍試験(1)における米飯塊の硬さの測定試験と同様に、円板状プランジャー(No.19、Φ55×H8mm)に定格容量196Nのロードセルを装着した単軸圧縮・引張型レオメータ(RE2−33005C、(株)山電)を用いて圧縮速度1mm・s−1、データ間隔100msの条件で単軸圧縮破断試験を行った。なお、プランジャーと米飯塊の接触面に生じる摩擦を防ぐために、測定前にプランジャーの米飯との接触面に食用グリース(モリコートHPグリースHP−500、東レ・ダウコーニング(株))を塗布した。
米飯塊のプランジャーに接する面積が不明であるため、ここでは、図6から図9に示したように、米飯塊の硬さの測定結果を圧縮力−ひずみ曲線で示す。
<Measurement of hardness of cooked rice>
A. Similar to the measurement test of the hardness of the cooked rice mass in the freezing and thawing test (1) of the cooked rice to which the modifier for frozen cooked rice was added, the disc-shaped plunger (No. 19, Φ55 × H8 mm) has a rated capacity of 196 N A uniaxial compression / tension type rheometer (RE2-30005C, Yamaden Co., Ltd.) equipped with a load cell was used to conduct a uniaxial compression rupture test under conditions of a compression speed of 1 mm · s −1 and a data interval of 100 ms. In addition, in order to prevent friction generated on the contact surface of the plunger and the cooked rice lump, edible grease (Molicoat HP Grease HP-500, Toray Dow Corning Co., Ltd.) was applied to the contact surface of the plunger with the cooked rice before measurement. .
Since the area of the cooked rice lump that is in contact with the plunger is unknown, here, as shown in FIGS. 6 to 9, the measurement result of the hardness of the cooked rice lump is shown by a compressive force-strain curve.

図9に示したように、冷凍貯蔵9日後の米飯塊の圧縮力−ひずみ曲線には、実施例7、比較例5および対照区において、降伏点が生じた。降伏点を生じた際の降伏力および降伏ひずみの値を表4に示す。   As shown in FIG. 9, the yield point was generated in the compressive force-strain curve of the cooked rice lump after 9 days of freezing in Example 7, Comparative Example 5 and the control group. Table 4 shows the yield force and yield strain values when yield points were generated.

表4に示したように、対照区では降伏ひずみの値が最も低く、次いで、マルトオリゴ糖のみ添加した比較例5、ショ糖脂肪酸エステルおよびマルトオリゴ糖の両方を添加した実施例7の順に降伏ひずみの値が高くなった。   As shown in Table 4, in the control group, the yield strain value was the lowest, followed by Comparative Example 5 in which only maltooligosaccharide was added, and Example 7 in which both sucrose fatty acid ester and maltooligosaccharide were added. The value became high.

一方、降伏力の値は、対照区において最も高く、マルトオリゴ糖のみ添加した比較例5、ショ糖脂肪酸エステルおよびマルトオリゴ糖の両方を添加した実施例7の順に低くなった。   On the other hand, the yield value was highest in the control group, and decreased in the order of Comparative Example 5 in which only maltooligosaccharide was added, and Example 7 in which both sucrose fatty acid ester and maltooligosaccharide were added.

このような結果から、対照区では、米飯粒が崩れるのは早いが、米飯粒を崩すために比較的大きな力を要するため、脆い試料であると考えられる。一方、ショ糖脂肪酸エステルおよびマルトオリゴ糖の両方を添加した実施例7では、崩れるのは遅いが、小さな力で崩れるため、塑性変形が容易な試料であると考えられる。
すなわち、対照区の米飯塊を喫食すると、その食感はボロボロとしているが、実施例7の米飯塊を喫食すると、口ざわりがよく、適度な噛みごたえを維持していると考えられる。
From these results, in the control plot, the cooked rice grains collapse quickly, but a relatively large force is required to break the cooked rice grains, so it is considered to be a brittle sample. On the other hand, in Example 7 to which both sucrose fatty acid ester and maltooligosaccharide were added, although it collapses slowly, it collapses with a small force, so it is considered that the sample is easy to plastically deform.
In other words, when eating the cooked rice lump in the control ward, the texture is tattered, but when eating the cooked rice lump of Example 7, it is thought that the mouthfeel is good and an appropriate bite is maintained.

<凍結・解凍処理した米飯塊の官能評価>
実施例7、比較例4、5の米飯塊について、凍結・解凍処理後に、パネルとして、20代の男性1名、女性4名、30代の女性1名、50代の男性1名、60代の男性1名の合計8名に試食してもらい、以下の基準で米飯の外観、食感および食味を評価した。各試料の外観(評価項目1.白濁している−透明感がある、評価項目2.光沢がない−光沢がある、評価項目3.表面が粗い−表面が滑らか)、食感(評価項目4.米飯粒が口中でほぐれにくい−ほぐれやすい、評価項目5.硬い−柔らかい、評価項目6.べたついている−さらっとしている)および嗜好性(評価項目7.米飯塊として嫌い−好き)について−3から+3までの7段階カテゴリー尺度で評価した。例えば、評価項目1の場合、−3は、米飯塊および米飯塊を構成する米飯粒が最も白濁していることを意味しており、+3は、米飯塊および米飯塊を構成する米飯粒が最も透明感があることを意味している。上記7つの評価項目に関する官能評価の結果を表5〜16に示す。
<Sensory evaluation of frozen and thawed cooked rice>
About the cooked rice chunks of Example 7 and Comparative Examples 4 and 5, after freezing and thawing treatment, as a panel, one male in their 20s, four females, one female in their 30s, one male in their 50s, 60s A total of 8 men, one of the men, sampled and evaluated the appearance, texture and taste of cooked rice according to the following criteria. Appearance of each sample (evaluation item 1. cloudy-transparent, evaluation item 2. non-glossy-glossy, evaluation item 3. rough surface-smooth surface), texture (evaluation item 4) .Easy to loosen up in the mouth-easy to loosen, evaluation item 5. Hard-soft, evaluation item 6. Sticky-dry, and palatability (evaluation item 7. disliked as cooked rice mass-likes) -3 To a +3 rating on a 7-level category scale. For example, in the case of evaluation item 1, -3 means that the cooked rice lump and the cooked rice grain constituting the cooked rice lump are most clouded, and +3 is the most cooked rice cake and the cooked rice grain constituting the cooked rice lump. It means that there is a sense of transparency. The results of sensory evaluation regarding the above seven evaluation items are shown in Tables 5-16.

ショ糖脂肪酸エステルのみを添加した比較例4の米飯塊の外観は、冷凍貯蔵6日後まではやや白濁しており、やや光沢がなく、やや表面が粗いという評価から良くなる傾向にあったが、冷凍貯蔵9日後の米飯塊は冷凍貯蔵1日後の試料よりも評価がやや悪くなった。一方、比較例4の米飯塊の食感の評価は、ほぐれやすさ、べたつきともに冷凍貯蔵1日後より冷凍貯蔵9日後の米飯塊の方がほぐれやすく、さらっとしている、という評価になった。また、硬さについては、冷凍貯蔵1日後から9日後にかけて、やや柔らかかった米飯塊が経時的に適度に硬くなる傾向を示していた。このことは、乳化剤であるショ糖脂肪酸エステルを添加した米飯塊では、最初柔らかいが、貯蔵期間が長くなるにつれて適度に硬くなり、貯蔵期間の長い米飯塊の解凍時に、嗜好性がちょうど良好な米飯になったと考えられる。   The appearance of the cooked rice lump of Comparative Example 4 to which only the sucrose fatty acid ester was added was slightly cloudy until 6 days after frozen storage, but it was slightly glossy and tended to improve from the evaluation that the surface was slightly rough, The rice mass after 9 days of frozen storage was evaluated slightly worse than the sample after 1 day of frozen storage. On the other hand, the evaluation of the texture of the cooked rice mass of Comparative Example 4 was such that the cooked rice cake after 9 days of freezing storage was more easily loosened and more friable than after 1 day of freezing storage for both ease of looseness and stickiness. Moreover, about the hardness, the rice cake lump which was a little soft from the 1st day to the 9th day after freezing storage showed a tendency to become moderately hard over time. This is because the cooked rice with added sucrose fatty acid ester as an emulsifier is initially soft, but it becomes moderately harder as the storage period becomes longer. It is thought that it became.

マルトオリゴ糖のみを添加した比較例5の米飯塊の外観は、貯蔵期間が長くなるにつれて白濁し、光沢が無くなり、表面が粗くなる傾向にあった。一方、比較例5の米飯塊の食感の評価は、ほぐれやすさ、べたつきともに貯蔵期間を通じてあまり変化しない傾向にあった。また、比較例5の米飯塊の硬さは、比較的柔らかいと評価されたものの、比較例4より硬いという評価傾向が認められた。   The appearance of the cooked rice mass of Comparative Example 5 to which only malto-oligosaccharide was added had a tendency to become cloudy, lose luster, and become rough as the storage period increased. On the other hand, the evaluation of the texture of the cooked rice lump of Comparative Example 5 had a tendency that both looseness and stickiness did not change much throughout the storage period. Moreover, although the hardness of the cooked rice lump of the comparative example 5 was evaluated as comparatively soft, the evaluation tendency that it was harder than the comparative example 4 was recognized.

ショ糖脂肪酸エステルとマルトオリゴ糖を両方添加した実施例7の米飯塊の外観は、貯蔵期間が長くなるにつれて透明感が増し、光沢が出て、しかも表面が滑らかになる傾向が認められた。また、実施例7の米飯塊の食感の評価は、冷凍貯蔵1日後に比べ、貯蔵期間が長くなるにつれてほぐれやすく、柔らかく、しかも、さらっとする傾向が認められた。   The appearance of the cooked rice lump of Example 7 to which both the sucrose fatty acid ester and maltooligosaccharide were added was observed to have a tendency to become more transparent, glossy and smooth on the surface as the storage period increased. In addition, the evaluation of the texture of the cooked rice mass of Example 7 was found to be easier to loosen as the storage period became longer, softer, and more gentle compared to one day after frozen storage.

なお、米飯塊の嗜好性については、柔らかい米飯を好むパネル、硬い米飯を好むパネルの両者が混在していたため、評価にばらつきがあったが、実施例7の米飯塊の嗜好性が高い傾向が認められた。   In addition, about the palatability of the cooked rice chunk, since both the panel which likes soft cooked rice and the panel which prefers hard cooked rice were mixed, there was a variation in evaluation, but the tenderness of the cooked rice chunk of Example 7 tends to be high. Admitted.

Claims (11)

食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有する冷凍米飯用改質剤。   A modifier for frozen cooked rice which does not contain edible fats and oils and plant sterols, and contains sucrose fatty acid esters and maltooligosaccharides. 前記ショ糖脂肪酸エステルが、ショ糖ステアリン酸エステルまたはショ糖パルミチン酸エステルであることを特徴とする請求項1に記載の冷凍米飯用改質剤。   The sucrose fatty acid ester is a sucrose stearate ester or a sucrose palmitate ester. 食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有し、前記ショ糖脂肪酸エステルの配合割合が、精白米中の澱粉質量に対して0.1wt%以上0.5wt%以下であり、前記マルトオリゴ糖の配合割合が炊飯後の米飯中の水質量に対して2.0wt%以上5.0wt%以下であることを特徴とする冷凍米飯。   Does not contain edible fats and oils and plant sterols, contains sucrose fatty acid ester and maltooligosaccharide, and the blending ratio of the sucrose fatty acid ester is 0.1 wt% or more and 0.5 wt% or less with respect to the starch mass in the polished rice And the blended proportion of the maltooligosaccharide is 2.0 wt% or more and 5.0 wt% or less with respect to the water mass in the cooked rice. 前記ショ糖脂肪酸エステルが、ショ糖ステアリン酸エステルまたはショ糖パルミチン酸エステルであることを特徴とする請求項3に記載の冷凍米飯。   The frozen cooked rice according to claim 3, wherein the sucrose fatty acid ester is sucrose stearate or sucrose palmitate. 前記冷凍米飯が、炊飯後の米飯に調味液が添加された米飯部と、具材部からなる冷凍寿司であることを特徴とする請求項3または4に記載の冷凍米飯。   The frozen cooked rice according to claim 3 or 4, wherein the frozen cooked rice is a frozen sushi comprising a cooked rice portion obtained by adding a seasoning liquid to cooked rice and an ingredient portion. 洗浄した精白米に水とともに、食用油脂および植物ステロールを含有せず、ショ糖脂肪酸エステルおよびマルトオリゴ糖を含有する冷凍米飯用改質剤を添加し、この冷凍米飯用改質剤を含有する水中に、前記精白米を浸漬した後に炊飯し、炊飯後の米飯を急速凍結することを特徴とする冷凍米飯の製造方法。   In addition to water, edible fats and oils and plant sterols are added to the washed polished rice, and a frozen cooked rice modifier containing sucrose fatty acid ester and maltooligosaccharide is added to the water containing the frozen cooked rice modifier. A method for producing frozen cooked rice, characterized by cooking rice after dipping the polished rice and rapidly freezing the cooked rice. 前記ショ糖脂肪酸エステルの配合割合が、精白米中の澱粉質量に対して0.1wt%以上0.5wt%以下であり、前記マルトオリゴ糖の配合割合が炊飯後の米飯中の水質量に対して2.0wt%以上5.0wt%以下であることを特徴とする請求項6に記載の冷凍米飯の製造方法。   The blending ratio of the sucrose fatty acid ester is 0.1 wt% or more and 0.5 wt% or less with respect to the starch mass in the polished rice, and the blending ratio of the maltooligosaccharide is based on the water mass in the cooked rice It is 2.0 wt% or more and 5.0 wt% or less, The manufacturing method of the frozen cooked rice of Claim 6 characterized by the above-mentioned. 前記浸漬の条件が、25℃で30分以上であることを特徴とする請求項6または7に記載の冷凍米飯の製造方法。   The method for producing frozen cooked rice according to claim 6 or 7, wherein the immersion condition is 30 minutes or more at 25 ° C. 前記急速凍結時の温度が−20℃以下であることを特徴とする請求項6から8のいずれか一項に記載の冷凍米飯の製造方法。   The method for producing frozen cooked rice according to any one of claims 6 to 8, wherein the temperature during the rapid freezing is -20 ° C or lower. 前記炊飯後の米飯に調味液を添加し、具材を載置した後、急速凍結することを特徴とする請求項6から9のいずれか一項に記載の冷凍米飯の製造方法。   The method for producing frozen cooked rice according to any one of claims 6 to 9, wherein a seasoning liquid is added to the cooked cooked rice, the ingredients are placed, and then rapidly frozen. 請求項3から5のいずれか一項に記載の冷凍米飯を加熱部材に接触させ、前記冷凍米飯中の水分が凍結状態を維持したまま加熱する第1加熱工程と、この第1加熱工程に次いで冷凍米飯中の凍結状態の水分が融解するように加熱する第2加熱工程と、この第2加熱工程に次いで前記冷凍米飯を喫食に適した温度まで昇温させる第3加熱工程とを含むことを特徴とする冷凍米飯の解凍方法。   Following the first heating step, the frozen cooked rice according to any one of claims 3 to 5 is brought into contact with a heating member, and the moisture in the frozen cooked rice is heated while maintaining a frozen state. Including a second heating step of heating the frozen rice so that the frozen water is melted, and a third heating step of raising the temperature of the frozen rice to a temperature suitable for eating after the second heating step. A method for thawing frozen rice.
JP2018157216A 2017-08-25 2018-08-24 Modifier for frozen cooked rice, frozen cooked rice, method for producing frozen cooked rice, and method for thawing frozen cooked rice. Active JP7116279B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06141797A (en) * 1992-11-02 1994-05-24 Nippon Shokuhin Kako Co Ltd Frozen cooked rices and their production
JPH09322725A (en) * 1996-04-06 1997-12-16 Nippon Suisan Kaisha Ltd Cooked rice food that can be distributed at low temperature and method for producing the same
JPH10323160A (en) * 1997-03-28 1998-12-08 Nippon Suisan Kaisha Ltd Cooked rice foods that can be distributed and sold at low temperatures
JP2001136921A (en) * 1999-08-31 2001-05-22 Nippon Suisan Kaisha Ltd Cooked rice food with low-temperature distribution suitability
JP2009118760A (en) * 2007-11-13 2009-06-04 Toyo Suisan Kaisha Ltd Rice for low temperature storage and method for producing the same
WO2016031954A1 (en) * 2014-08-29 2016-03-03 富士化学工業株式会社 Emulsion composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06141797A (en) * 1992-11-02 1994-05-24 Nippon Shokuhin Kako Co Ltd Frozen cooked rices and their production
JPH09322725A (en) * 1996-04-06 1997-12-16 Nippon Suisan Kaisha Ltd Cooked rice food that can be distributed at low temperature and method for producing the same
JPH10323160A (en) * 1997-03-28 1998-12-08 Nippon Suisan Kaisha Ltd Cooked rice foods that can be distributed and sold at low temperatures
JP2001136921A (en) * 1999-08-31 2001-05-22 Nippon Suisan Kaisha Ltd Cooked rice food with low-temperature distribution suitability
JP2009118760A (en) * 2007-11-13 2009-06-04 Toyo Suisan Kaisha Ltd Rice for low temperature storage and method for producing the same
WO2016031954A1 (en) * 2014-08-29 2016-03-03 富士化学工業株式会社 Emulsion composition

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