JP2019011294A - Oxidant-containing composition and method for stabilizing oxidizing agent - Google Patents

Abstract

To provide oxidizing agent-containing compositions capable of improving the stability of an oxidizing agent, and to provide methods for stabilizing an oxidizing agent.SOLUTION: The oxidizing agent-containing composition of the present invention contains (A) stannate, (B) an aminocarboxylic acid system chelating agent, and (C) acid, the mass ratio of the content of the component (B) with respect to the content of the component (A) being 0.01 to 35, and the pH being 2 to 5. Furthermore, (D) a cationic surfactant, (E) a polyoxyethylene alkyl ether type nonionic surfactant, or (F) hydrocarbon may be compounded.SELECTED DRAWING: None

Description

  The present invention relates to an oxidizing agent-containing composition having improved stability of an oxidizing agent, particularly hydrogen peroxide, and a method for stabilizing the oxidizing agent.

  In general, as a hair treatment composition, a hair dye, a hair decoloring / decoloring agent, or a permanent wave agent that exhibits an effect by mixing a plurality of agents is known. Such a hair treatment composition is composed of, for example, a first agent containing an alkali agent and an oxidation dye, and a second agent (oxidation agent-containing composition) containing an oxidizing agent such as hydrogen peroxide. Oxidative hair dyes are known.

  For example, hydrogen peroxide as an oxidant is an unstable compound and easily decomposes into water and oxygen, so that it is difficult to maintain the stability of the hydrogen peroxide-containing composition for a long period of time. Conventionally, an oxidant-containing composition using a specific stabilizer for improving the stability of an oxidant is known. For example, Patent Document 1 discloses a composition for reducing decomposition of hydrogen peroxide containing 1-hydroxyethane-1,1-diphosphonic acid and the like. Patent Document 2 discloses a hydrogen peroxide-containing composition containing pyrrolidone carboxylic acid ester and the like.

Special table 2007-503409 gazette Japanese Patent No. 3845010

In the conventional oxidizing agent-containing composition, further improvement in the stability of the oxidizing agent has been demanded.
The objective of this invention is providing the oxidizing agent containing composition which can improve stability of an oxidizing agent, and the stabilization method of an oxidizing agent.

  The present invention is based on the finding that the stability of an oxidizing agent can be improved by using a specific acid in combination at a predetermined ratio. In addition, the numerical value of the mass% which shows content of a component is a numerical value in dosage forms including those, when using solubilizers, such as water.

  In order to achieve the above object, in one embodiment of the present invention, the composition contains (A) a stannate, (B) an aminocarboxylic acid chelating agent, and (C) an acid, and the content of the component (A) The oxidizing agent containing composition characterized by the mass ratio of content of (B) component with respect to is 0.01-35, and is pH 2-5.

  Further, (D) a cationic surfactant may be contained. Further, (E) a polyoxyethylene alkyl ether type nonionic surfactant may be contained. Further, (F) a hydrocarbon may be contained. You may mix with the agent containing an alkaline agent, and may be used as a hair dye or hair decoloring and decoloring agent.

  In another aspect of the present invention, in the composition containing an oxidizing agent, (A) a stannate, (B) an aminocarboxylic acid chelating agent, and (C) an acid are blended, and the component (A) Provided is a method for stabilizing an oxidizing agent, wherein the mass ratio of the content of the component (B) to the content is 0.01 to 35, and the pH of the composition is 2 to 5.

  According to the present invention, the stability of the oxidizing agent can be improved.

  Hereinafter, an embodiment embodying the oxidizing agent-containing composition of the present invention will be described. An oxidizing agent containing composition is comprised as a 2nd agent of the hair dye or hair decoloring / destaining agent containing an alkaline agent and an oxidizing agent, for example. Specific examples of the hair dye or hair decoloring / destaining agent include, for example, a two-component hair dye or hair decoloring / destaining agent, a three-component hair dye, or a hair decoloring / destaining agent. . Hereinafter, it illustrates about the component of the hair dye containing the 2nd agent comprised as an oxidizing agent containing composition, or a hair decoloring and decoloring agent.

<Two-component hair decoloring and decoloring agent>
The two-component hair bleaching / destaining agent is composed of, for example, a first agent containing at least an alkaline agent and a second agent containing at least an oxidizing agent.

(The second agent of two-component hair decoloring and decoloring agents)
The second agent contains (A) stannate, (B) aminocarboxylic acid chelating agent, (C) acid and the like in addition to the oxidizing agent. The second agent may further contain (D) a cationic surfactant, (E) a polyoxyethylene (hereinafter referred to as “POE”) alkyl ether type nonionic surfactant, and (F) a hydrocarbon. preferable.

  An oxidizing agent improves the decoloring property of melanin contained in hair. Specific examples of the oxidizing agent include, for example, hydrogen peroxide, urea peroxide, melamine peroxide, sodium percarbonate, sodium perborate, potassium perborate, ammonium persulfate, potassium persulfate, sodium persulfate, sodium peroxide, Potassium peroxide, magnesium peroxide, barium peroxide, calcium peroxide, strontium peroxide, sulfate hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, pyrophosphate hydrogen peroxide adduct etc. Can be mentioned. Among the specific examples of these oxidizing agents, only one kind may be contained alone, or two or more kinds may be contained in combination.

  The lower limit of the content of the oxidizing agent in the second agent is appropriately set, but is preferably 0.1% by mass or more, more preferably 2.0% by mass or more, and further preferably 3.0% by mass. % Or more. When content of an oxidizing agent is 0.1 mass% or more, the decoloring property of melanin can be improved more. Moreover, although the upper limit of content of the oxidizing agent in a 2nd agent is set suitably, Preferably it is 15.0 mass% or less, More preferably, it is 9.0 mass% or less, More preferably, 6. 0% by mass or less. When content of an oxidizing agent is 15.0 mass% or less, damage etc. of hair can be suppressed.

  When hydrogen peroxide is added to the second agent as an oxidizing agent, the second agent is preferably a stabilizer such as ethylene glycol phenyl ether (phenoxyethanol), hydroxyethane, in order to improve the stability of hydrogen peroxide. Contains diphosphonic acid or a salt thereof. Specific examples of hydroxyethane diphosphonate include, for example, tetrasodium hydroxyethane diphosphonate, disodium hydroxyethane diphosphonate, and the like.

  (A) The stannate improves the stability of the oxidizing agent. Specific examples of (A) stannate include sodium stannate and potassium stannate. Among the specific examples of the component (A), only one kind may be contained alone, or two kinds may be contained in combination. The lower limit of the content of the component (A) in the second agent is appropriately set, but is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, and further preferably 0.007% by mass or more. It is. When the content is 0.001% by mass or more, the stability of the oxidizing agent is further improved. Further, the upper limit of the content of the component (A) in the second agent is appropriately set, but is preferably 1% by mass or less, more preferably 0.6% by mass or less, and further preferably 0.45% by mass or less. It is. When the content is 1% by mass or less, the stability of the oxidizing agent is further improved. Moreover, the formulation stability of the second agent is further improved.

  (B) The aminocarboxylic acid chelating agent improves the stability of the oxidizing agent. Specific examples of aminocarboxylic acid chelating agents include, for example, ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylenediaminetriacetic acid (HEDTA), dihydroxyethylethylenediaminediacetic acid (DHEDDA), 1,3-propanediamine tetra Acetic acid (1,3PDTA), diethylenetriaminepentaacetic acid (DTPA), triethylenetetraminehexaacetic acid (TTHA), nitrilotriacetic acid (NTA), hydroxyethyliminodiacetic acid (HIMDA), L-aspartic acid-N, N-diacetic acid (ASDA), salts thereof, derivatives thereof, and salts of derivatives thereof. Examples of the salt include alkali metal salts such as sodium salt and potassium salt. Among the specific examples of these (B) components, only 1 type may be contained independently and 2 or more types may be combined and contained. Among these, EDTA, HEDTA, DTPA, or a sodium salt thereof is preferable from the viewpoint of excellent effect of improving the stability of the oxidizing agent.

  The lower limit of the content of the component (B) in the second agent is appropriately set, but is preferably 0.0001% by mass or more, more preferably 0.001% by mass or more, and further preferably 0.005% by mass or more. It is. When the content is 0.0001% by mass or more, the stability of the oxidizing agent is further improved. The upper limit of the content of the component (B) in the second agent is appropriately set, but is preferably 1% by mass or less, more preferably 0.5% by mass or less, and further preferably 0.25% by mass or less. . When the content is 1% by mass or less, the stability of the oxidizing agent is particularly improved.

  The lower limit of the mass ratio of the content of the component (B) to the content of the component (A) in the second agent is 0.01 or more, preferably 0.03 or more, more preferably 0.07 or more. The upper limit of this mass ratio is 35 or less, preferably 25 or less, more preferably 20 or less, and still more preferably 10 or less. By defining this mass ratio within the above range, the stability of the oxidizing agent can be further improved.

  (C) The acid improves the stability of the oxidizing agent. (C) The acid may be either an inorganic acid or an organic acid. Specific examples of the inorganic acid include phosphoric acid, hydrochloric acid, nitric acid, sulfuric acid, boric acid and the like. Specific examples of phosphoric acid include orthophosphoric acid, polyphosphoric acid, pyrophosphoric acid, metaphosphoric acid, and the like. Specific examples of the organic acid include citric acid, tartaric acid, lactic acid, malic acid, succinic acid, fumaric acid, maleic acid, gluconic acid, glucuronic acid, benzoic acid and the like. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained. Among these, inorganic acid, citric acid, and tartaric acid are preferable, and phosphoric acid is more preferable from the viewpoint of excellent effect of improving the stability of the oxidizing agent.

  The lower limit of the content of the component (C) in the second agent is appropriately set from the viewpoint of pH adjustment, but is preferably 0.005% by mass or more, more preferably 0.01% by mass or more, and still more preferably 0. 0.02% by mass or more. When the content is 0.005% by mass or more, the pH of the second agent is adjusted to an appropriate acidic region, and the stability of the oxidizing agent is further improved. The upper limit of the content of the component (C) in the second agent is appropriately set from the viewpoint of pH adjustment, but is preferably 2% by mass or less, more preferably 1% by mass or less, and further preferably 0.5% by mass. It is as follows. When the content is 2% by mass or less, the pH of the second agent is adjusted to an appropriate acidic region, and the stability of the oxidizing agent is further improved.

  (D) The cationic surfactant improves the formulation stability of the second agent. Specific examples of (D) cationic surfactants include, for example, lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl bromide. Trimethylammonium, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, methacryloyloxyethyltrimethylammonium chloride, behenyltrimethylammonium sulfate, behenyldimethylamine, diethylaminoethylamide behenate, dimethylamino behenate Propylamide, dimethyl behenate Le aminoethyl amide, stearyl dimethyl amine, palmitoyl propyl dimethyl amine, stearamidopropyl propyl dimethylamine, and the like stearic acid dimethyl aminopropyl amide. Specific examples of the alkyltrimethylammonium chloride include behenyltrimethylammonium chloride and aralkyltrimethylammonium chloride. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained. Among these, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and alkyltrimethylammonium chloride are preferable from the viewpoint of excellent drug stability improvement effect.

  The lower limit of the content of the component (D) in the second agent is appropriately set, but is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, and further preferably 0.05% by mass or more. It is. When the content is 0.01% by mass or more, the formulation stability of the second agent is further improved. The upper limit of the content of the component (D) in the second agent is appropriately set, but is preferably 5% by mass or less, more preferably 2% by mass or less, and further preferably 1% by mass or less. When the content is 5% by mass or less, the formulation stability of the second agent is further improved. In addition, the stability of the oxidizing agent is further improved.

  The lower limit of the mass ratio of the content of the component (A) to the content of the component (D) in the second agent is appropriately set, but is preferably 0.01 or more, more preferably 0.05 or more, and still more preferably Is 0.1 or more. The upper limit of the mass ratio is appropriately set, but is preferably 5 or less, more preferably 4 or less, and even more preferably 3 or less. By defining this mass ratio within the above range, the stability of the oxidizing agent and the stability of the preparation can be further improved.

  (E) The POE alkyl ether type nonionic surfactant improves the formulation stability of the second agent. Specific examples of the (E) POE alkyl ether type nonionic surfactant include, for example, POE cetyl ether (ceteth), POE stearyl ether (steares), POE behenyl ether, POE oleyl ether (oreth), POE lauryl ether (laureth) ), POE octyldodecyl ether, POE hexyl decyl ether, POE isostearyl ether, POE polyoxypropylene cetyl ether, POE polyoxypropylene decyl tetradecyl ether, and the like. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained. Of these, POE cetyl ether (ceteth), POE stearyl ether (steares), and POE lauryl ether (laureth) are preferred, and POE cetyl ether (ceteth) is more preferred from the viewpoint of excellent drug stability improvement effect.

  The lower limit of the content of the component (E) in the second agent is appropriately set, but is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and further preferably 0.1% by mass or more. It is. When the content is 0.01% by mass or more, the formulation stability of the second agent is further improved. The upper limit of the content of the component (E) in the second agent is appropriately set, but is preferably 10% by mass or less, more preferably 7% by mass or less, and further preferably 5% by mass or less. When the content is 10% by mass or less, the formulation stability of the second agent is further improved.

  The lower limit of the mass ratio of the content of the component (A) to the total content of the component (D) and the content of the component (E) in the second agent is appropriately set, but is preferably 0.001 or more, More preferably, it is 0.002 or more, More preferably, it is 0.005 or more. The upper limit of the mass ratio is appropriately set, but is preferably 0.5 or less, more preferably 0.4 or less, and further preferably 0.3 or less. By defining such a mass ratio within the above range, the stability of the oxidizing agent and the stability of the preparation are further improved.

  (F) Hydrocarbon improves the formulation stability of the second agent. Specific examples of (F) hydrocarbon include, for example, paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, petrolatum, liquid paraffin, light isoparaffin, light liquid isoparaffin, isoparaffin, Examples include α-olefin oligomers and synthetic squalane. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained. Of these, hydrocarbons that are liquid at 25 ° C., such as α-olefin oligomers, light isoparaffins, light liquid isoparaffins, synthetic squalane, vegetable squalane, squalane, polybutene, liquid paraffin, Polyisobutene, hydrogenated polyisobutene and the like are preferable. Furthermore, an α-olefin oligomer, light liquid isoparaffin, and liquid paraffin are more preferable.

  The lower limit of the content of the component (F) in the second agent is appropriately set, but is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and further preferably 0.5% by mass or more. It is. When the content is 0.01% by mass or more, the formulation stability of the second agent is further improved. The upper limit of the content of the component (F) in the second agent is appropriately set, but is preferably 10% by mass or less, more preferably 7% by mass or less, and further preferably 4% by mass or less. When the content is 10% by mass or less, the formulation stability of the second agent is further improved.

  If necessary, the hair decoloring / decoloring agent may contain components other than those described above, for example, solubilizers, water-soluble polymers, inorganic polymers, oily components other than those described above, polyhydric alcohols, and surfactants other than those described above. , PH adjusters other than those described above, sugar, preservatives, stabilizers, plant extracts, herbal extracts, vitamins, fragrances, antioxidants, chelating agents other than those described above, UV absorbers, etc. .

  The solubilizer is blended, for example, when the second agent is made liquid. Examples of solubilizers used include water and organic solvents (solvents). Specific examples of the organic solvent include, for example, ethanol, n-propanol, isopropanol, methyl cellosolve, ethyl cellosolve, methyl carbitol, ethyl carbitol, benzyl alcohol, phenethyl alcohol, γ-phenylpropyl alcohol, cinnamon alcohol, anise alcohol, Examples include p-methylbenzyl alcohol, α-dimethylphenethyl alcohol, α-phenylethanol, ethylene glycol phenyl ether (phenoxyethanol), phenoxyisopropanol, 2-benzyloxyethanol, N-alkylpyrrolidone, alkylene carbonate, and alkyl ether. Among these solubilizers, only one kind may be contained alone, or two or more kinds may be contained in combination. Among these, water is preferably applied because of its excellent ability to dissolve other components in the second agent. When water is used as the solvent, the content of water in the second agent (content in use) is preferably 40% by mass or more, and more preferably 50% by mass or more.

  The water-soluble polymer gives an appropriate viscosity to the hair bleaching / destaining agent. Therefore, the hair bleaching / destaining agent may contain a water-soluble polymer as long as the effects of the present invention are not impaired. Examples of the water-soluble polymer include natural polymers, semi-synthetic polymers, and synthetic polymers. Specific examples of natural polymers include starch, guar gum, locust bean gum, quince seed, carrageenan, galactan, gum arabic, tragacanth gum, pectin, mannan, xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid, gelatin, Examples include casein, albumin, collagen, dextrin, triglucopolysaccharide (pullulan), and the like.

  Specific examples of the semi-synthetic polymer include, for example, crystalline cellulose, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxyethyl cellulose dimethyl diallyl ammonium chloride, hydroxypropyl cellulose, carboxymethyl cellulose, carboxymethyl cellulose sodium, hydroxypropyl methyl cellulose, cationized cellulose, and cationized guar gum. , Starch phosphate ester, propylene glycol alginate ester, alginate and the like.

  Specific examples of the synthetic polymer include, for example, polyvinyl caprolactam, polyvinyl alcohol (PVA), polyvinyl pyrrolidone (PVP), vinyl pyrrolidone-vinyl acetate (VP / VA) copolymer, polyvinyl butyral, polyvinyl methyl ether, carboxyvinyl polymer, poly Sodium acrylate, polyacrylamide, polyethylene oxide, ethylene oxide / propylene oxide block copolymer, acrylic acid / alkyl acrylate copolymer, polydimethylmethylenepiperidinium chloride (polydimethyldimethylethylenepyrrolidinium chloride) (polyquaternium-6 ) (Mercoat 100: manufactured by Merck & Co.), half ester of itaconic acid and POE alkyl ether, or ester of methacrylic acid and POE alkyl ether, acrylic acid, At least one monomer selected from methacrylic acid and alkyl esters thereof, copolymers thereof consisting of. Among these, only 1 type may be contained independently and 2 or more types may be combined and contained.

  Specific examples of the inorganic polymer include bentonite, aluminum magnesium silicate, laponite, hectorite, and silicic anhydride. Among these, only 1 type may be contained independently and 2 or more types may be combined and contained.

  The oily component imparts a moist feeling especially to the hair. Therefore, the hair bleaching / destaining agent may further contain an oily component other than the oily components described above within a range not inhibiting the effects of the present invention. Examples of the oil component include fats and oils, waxes, ester oils, higher alcohols, higher fatty acids, alkyl glyceryl ethers, silicones, and the like.

  Specific examples of fats and oils include, for example, Argania spinosa kernel oil, olive oil (olive oil), camellia oil, shea fat, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran Oil, rice germ oil, grape seed oil, avocado oil, macadamia nut oil, castor oil, coconut oil, evening primrose oil, apricot oil, persic oil, peach seed oil, palm oil, egg yolk oil and the like. Specific examples of waxes include lanolin, beeswax, candelilla wax, carnauba wax, jojoba oil and the like.

  Specific examples of ester oils include, for example, diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, myristyl myristate, isotridecyl myristate, 2-palmitic acid 2- Ethylhexyl, octyldodecyl ricinoleate, fatty acid cholesteryl / lanosteryl having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipentaerythritol fatty acid ester, caprin Cetyl acid, glyceryl tricaprylate, diisostearyl malate, dioctyl succinate, cetyl 2-ethylhexanoate, hydrogenated isostearic acid Shea oil, and the like.

  Specific examples of higher alcohols include, for example, cetyl alcohol (cetanol), 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, aralkyl alcohol, behenyl alcohol, 2-octyldodecanol, lauryl alcohol, myristyl alcohol. Decyltetradecanol, lanolin alcohol and the like.

  Specific examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, and lanolin fatty acid. Specific examples of alkyl glyceryl ethers include, for example, batyl alcohol, chimyl alcohol, seraalkyl alcohol, and isostearyl glyceryl ether.

  Specific examples of silicone include, for example, dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane, highly polymerized silicone, polyether-modified silicone (for example, (PEG / PPG / butylene / dimethicone) copolymer), amino-modified silicone, betaine-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, mercapto-modified silicone, carboxy-modified silicone, fluorine-modified silicone and the like. Among these oily components, only one kind may be contained alone, or two or more kinds may be contained in combination.

  Examples of the polyhydric alcohol include glycol and glycerin. Examples of the glycol include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, highly polymerized polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, and 1,3-butylene glycol. Examples of glycerin include glycerin, diglycerin, and polyglycerin. Among these polyhydric alcohols, only one kind may be contained alone, or two or more kinds may be contained in combination.

  The surfactant emulsifies or solubilizes the hair decoloring / decoloring agent when used as an emulsifier or a component for solubilizing each component, and adjusts the viscosity or improves the viscosity stability. Therefore, the hair bleaching / decoloring agent may contain a surfactant other than the surfactants described above within a range not inhibiting the effects of the present invention. Examples of the surfactant include anionic surfactants, amphoteric surfactants, and nonionic surfactants other than those described above.

  Specific examples of the anionic surfactant include, for example, alkyl ether sulfate, alkyl sulfate, alkyl ether sulfate ester, alkenyl ether sulfate, alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated or unsaturated. Fatty acid salt, alkyl or alkenyl ether carboxylate, α-sulfone fatty acid salt, N-acyl amino acid type surfactant, phosphoric acid mono- or diester type surfactant, sulfosuccinic acid ester, N-alkyloylmethyl taurine salt, and the like And the like. Specific examples of the counter ion of the anionic group of these surfactants include sodium ion, potassium ion, triethanolamine and the like. More specifically, examples of the alkyl ether sulfate salt include sodium POE lauryl ether sulfate. Specific examples of the alkyl sulfate include sodium lauryl sulfate and sodium cetyl sulfate. Specific examples of the alkyl sulfate derivative include, for example, sodium POE lauryl sulfate. Specific examples of the sulfosuccinic acid ester include, for example, disodium lauryl sulfosuccinate. Specific examples of the N-alkyloylmethyl taurine salt include, for example, N-stearoyl-N-methyl taurine sodium.

  Specific examples of amphoteric surfactants include cocobetaine, lauramidopropyl betaine, cocamidopropyl betaine, sodium lauroamphoacetate, sodium cocoamphoacetate, coconut oil fatty acid amidopropyl betaine, lauryl betaine (lauryldimethylaminoacetic acid betaine), lauryl Examples include sodium aminopropionate.

  Specific examples of the nonionic surfactant include ether type nonionic surfactants, ester type nonionic surfactants, alkyl glucosides and the like other than those described above. Specific examples of the ether type nonionic surfactant include POE nonylphenyl ether and POE octylphenyl ether.

  Specific examples of the ester type nonionic surfactant include, for example, POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monopalmitate, POE sorbitan monolaurate, POE sorbitan trioleate, POE glyceryl monostearate, Monomyristic acid POE glyceryl, tetraoleic acid POE sorbit, hexastearic acid POE sorbit, monolauric acid POE sorbit, POE sorbit beeswax, monooleic acid polyethylene glycol, monostearic acid polyethylene glycol, monolauric acid polyethylene glycol, lipophilic monooleic acid Glyceryl, lipophilic glyceryl monostearate, self-emulsifying glyceryl monostearate, sorbitan monooleate, sesqui Sorbitan oleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, sucrose fatty acid ester, decaglyceryl monolaurate, decaglyceryl monostearate, decaglyceryl monooleate, decaglyceryl monomyristate , POE reduced lanolin and the like.

  Specific examples of the alkyl glucoside include alkyl (carbon number 8 to 16) glucoside, POE methyl glucoside, POE dioleic acid methyl glucoside, and the like. Among the specific examples of these surfactants, only one kind may be contained alone, or two or more kinds may be contained in combination.

  You may mix | blend a pH adjuster in order to adjust pH of a hair decoloring and decoloring agent. Examples of the pH adjuster include salts of organic acids in addition to the acid components described above. Specific examples of the salt include sodium salt, potassium salt, ammonium salt and the like. The content of the pH adjusting agent in the second agent is such that the pH of the second agent is in the range of 2 to 5, and is preferably in the range of pH 2 to 4. By adjusting the pH of the second agent to such a range, the stability of the oxidizing agent contained in the second agent is improved. The pH of the second agent is measured at 25 ° C. of the stock solution of the second agent.

  Specific examples of the sugar include monosaccharides such as glucose and galactose, disaccharides such as maltose, sucrose, fructose and trehalose, and sugar alcohols. Specific examples of the preservative include paraben, methyl paraben, sodium benzoate and the like. Specific examples of the stabilizer include phenacetin, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, tannic acid and the like. Specific examples of the antioxidant include ascorbic acids and sulfites. Specific examples of the chelating agent include hydroxyethane diphosphonic acid (HEDP) and salts thereof.

  The dosage form of the second agent is not particularly limited, and specific examples of the dosage form at 25 ° C. include liquids such as aqueous solutions and emulsions, gels, foams, and creams. Moreover, it can also be set as aerosol, a non-aerosol, etc. In the case of a non-aerosol, various forms, such as a squeeze foamer type and a pump former type, can be taken further. Moreover, in the case of aerosol, a well-known propellant and foaming agent can be applied. Specific examples of the propellant or foaming agent include liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas and the like. Only one of these may be used, or two or more may be used in combination.

(The first agent of two-component hair decoloring and decoloring agents)
The first agent contains an alkaline agent. The alkaline agent contained in the first agent serves to promote the action of the oxidizing agent contained in the second agent and improve the decoloring effect and / or the decoloring effect of the hair. In addition, in the hair dye mentioned later, hair dyeing property is improved.

  Specific examples of the alkali agent include, for example, ammonia, alkanolamine, silicate, carbonate, hydrogen carbonate, metasilicate, sulfate, chloride, phosphate, organic amine, basic amino acid, alkali metal or alkali. Examples thereof include hydroxides of earth metals. Specific examples of the alkanolamine include monoethanolamine and triethanolamine. Specific examples of the silicate include sodium silicate and potassium silicate. Specific examples of the carbonate include sodium carbonate and ammonium carbonate. Specific examples of the hydrogen carbonate include sodium hydrogen carbonate and ammonium hydrogen carbonate. Specific examples of the metasilicate include sodium metasilicate and potassium metasilicate. Specific examples of the sulfate include ammonium sulfate. Specific examples of the chloride include ammonium chloride. Specific examples of the phosphate include ammonium dihydrogen phosphate, diammonium hydrogen phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, trisodium phosphate, and the like. Specific examples of the organic amine include 2-amino-2-methyl-1-propanol (AMP), 2-amino-2-methyl-1,3-propanediol, guanidine, 1-amino-2-propanol (MIPA). ) And the like. Specific examples of basic amino acids include arginine, lysine and the like. Specific examples of the alkali metal or alkaline earth metal hydroxide include sodium hydroxide and potassium hydroxide. Among these alkaline agents, only one kind may be contained alone, or two or more kinds may be contained in combination. Among these, ammonia, ammonium salts, alkanolamines, and carbonates are preferably applied from the viewpoint of excellent effect of improving the lightness of hair.

  When using the hair decoloring / decoloring agent, that is, the content of the alkaline agent in the mixture of the first and second agents, the hair decoloring / decoloring agent is applied to normal decoloring / decoloring treatment. It is preferable to mix | blend in the quantity used as the range of pH 7-12, and it is more preferable to mix | blend in the quantity used as the range of pH 9-12. By setting the pH of the mixture to 7 or more, the action of the oxidizing agent contained in the second agent can be promoted. By setting the pH of the mixture to 12 or less, hair damage due to the application of a hair decoloring / decoloring agent can be suppressed. The pH of the hair bleaching / destaining agent is measured at 25 ° C. of the stock solution of the hair bleaching / destaining agent.

  The first agent may be contained in hair decoloring / decoloring agents in general and may contain components that do not inhibit the action of the components described above. For example, you may contain suitably the component contained in the 2nd agent mentioned above in the range which does not inhibit the effect of this invention.

  The dosage form of the first agent is not particularly limited, and specific examples of the dosage form at 25 ° C. include liquids such as aqueous solutions and emulsions, gels, foams, creams, solids, and the like. Moreover, it can also be set as aerosol, a non-aerosol, etc. Moreover, in the case of aerosol, a well-known propellant and foaming agent can be applied. Examples of the solid form include powder form, granular form, tablet form and the like. In the case of a solid dosage form, a dispersant, for example, a metal stearate such as calcium stearate and magnesium stearate, sodium sulfate, talc, lactose, and low-substituted hydroxypropylcellulose may be blended. Only one of these may be used, or two or more may be used in combination.

<Three-part hair decoloring / destaining agent>
For example, the three-part hair decoloring / decoloring agent includes a first agent having the same composition as the first agent of the above-described two-part hair decoloring / destaining agent, and the above-mentioned two-part type hair decoloring / destaining It is comprised from the 2nd agent which has the same composition as the 2nd agent of a dyeing agent, and the 3rd agent containing percarbonate at least. The three-component hair decoloring / destaining agent constructed in this manner further improves the brightness because it uses a percarbonate as an oxidizing agent.

(3rd agent hair decoloring / decoloring agent 3rd agent)
As the third agent, a dispersant and the like can be blended in addition to the percarbonate. Percarbonate improves the oxidation action and further improves the lightness of the hair after hair treatment. Specific examples of the percarbonate include sodium percarbonate and potassium percarbonate. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained.

  The dosage form of the third agent is preferably a solid form at 25 ° C. from the viewpoint of formulation stability. Examples of the solid form include powder form, granular form, tablet form and the like. Further, the third agent may be contained in hair decoloring / decoloring agents in general and each component that does not inhibit the action of each component described above. For example, you may contain suitably the component contained in the 1st, 2nd agent mentioned above in the range which does not inhibit the effect of this invention.

<Two-component hair dye>
The two-component hair dye is composed of, for example, a first agent containing at least an alkaline agent and an oxidation dye, and a second agent containing at least an oxidizing agent. Hereinafter, it demonstrates centering around difference with the hair decoloring and decoloring agent mentioned above.

(Second agent of two-component hair dye)
The 2nd agent of a hair dye has the same composition as the 2nd agent of the hair decoloring and decoloring agent mentioned above, for example.
(First agent of two-component hair dye)
The first agent of the hair dye contains, for example, an alkaline agent and an oxidation dye. Examples of the alkaline agent contained in the first agent are the same as those described above as specific examples of the alkaline agent used in the above-described hair bleaching / destaining agent. Oxidative dyes are compounds that can develop color due to oxidative polymerization by an oxidizing agent, and are classified as dye intermediates and couplers, and the oxidation dyes preferably include dye intermediates and couplers.

  Examples of the dye intermediate include p-phenylenediamine, toluene-2,5-diamine (paratolylenediamine), N-phenyl-p-phenylenediamine, 4,4′-diaminodiphenylamine, p-aminophenol, o- Aminophenol, p-methylaminophenol, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, 2-hydroxyethyl-p-phenylenediamine, o-chloro-p-phenylenediamine, 4-amino-m -Cresol, 2-amino-4-hydroxyethylaminoanisole, 2,4-diaminophenol, 1-hydroxyethyl-4,5-diaminopyrazole, salts thereof and the like. Specific examples of the salt include hydrochloride, sulfate and the like. Among the specific examples of these dye intermediates, only one kind may be contained alone, or two or more kinds may be contained in combination.

  Couplers develop color by binding to dye intermediates. Examples of the coupler include resorcin, 5-amino-o-cresol, m-aminophenol, α-naphthol, 5- (2-hydroxyethylamino) -2-methylphenol, m-phenylenediamine, and 2,4-diaminophenoxyethanol. , Toluene-3,4-diamine, 2,6-diaminopyridine, diphenylamine, N, N-diethyl-m-aminophenol, phenylmethylpyrazolone, 1,5-dihydroxynaphthalene, salts thereof and the like. Specific examples of the salt include hydrochloride, sulfate and the like. Among the specific examples of these couplers, only one kind may be contained alone, or two or more kinds may be contained in combination. Since the oxidative dye can change the color tone of the hair in various ways, it is preferable that at least one selected from the specific examples of the dye intermediate and at least one selected from the specific examples of the coupler. Composed. The first agent may appropriately contain, as a dye other than the above-mentioned oxidation dye, for example, an oxidation dye listed in “Quasi-drug raw material standard” (issued in June 2006, Yakuji Nippo).

  The lower limit of the content of the oxidative dye in the hair dye is appropriately set, but is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and further preferably 0.5% by mass or more. . When the content of the oxidation dye is 0.01% by mass or more, the color tone can be particularly improved.

  The upper limit of the content of the oxidation dye in the hair dye is appropriately set, but is preferably 10% by mass or less, more preferably 7% by mass or less, and further preferably 5% by mass or less. When the content of the oxidation dye is 10% by mass or less, particularly when a solubilizer is used, the solubility in the solubilizer can be improved.

Further, the first agent may further contain components other than the components described above as necessary, for example, components included in the first and second agents of the above-described hair bleaching / destaining agent.
<Three-component hair dye>
The three-component hair dye is, for example, a first agent having the same composition as the first agent of the two-component hair dye described above and the same composition as the second agent of the two-component hair dye described above. And a third agent containing at least a percarbonate. The three-component hair dye constituted in this way further improves the brightness because it uses a percarbonate as an oxidizing agent.

(Third agent type third hair dye)
The third agent of the hair dye has the same composition as, for example, the third agent of the hair bleaching / destaining agent described above. Percarbonate improves the oxidative effect and improves the lightness of the hair after hair treatment. And it improves white hair concealment.

Next, the usage method when the oxidizing agent containing composition of this embodiment is applied as a hair dye consisting of a plurality of agents or a hair decoloring / destaining agent will be described below.
First, the hair dye or hair decoloring / destaining agent comprising a plurality of agents described above is mixed to obtain a hair dye or hair decoloring / destaining agent mixture containing an alkaline agent, an oxidizing agent, etc. Once prepared, it is applied to the hair. The mixing method is not particularly limited, and for example, stirring may be performed manually using a stirrer or a brush, or a stirrer and an electric stirrer may be used. Moreover, when the dosage form of a mixture is foamy, you may make it foam by shaking. Applying a hair dye or a hair bleaching / destaining agent mixture to the hair is a known method, for example, a method of applying to a hand attached to a hand with a thin glove, a comb or a brush. Can do. Moreover, when configuring as an aerosol type | mold, after discharging multiple agents in foam form, you may mix on hair, applying a mixture to hair or applying each agent to hair.

  After the mixture is applied to the hair, after a predetermined time has elapsed, the mixture applied to the hair is rinsed with water according to a conventional method. Next, the step of washing the hair and rinsing with water, preferably using a shampoo composition according to a conventional method, is performed. The shampoo composition is not particularly limited as long as it is applied for washing hair, and a known shampoo composition can be applied. Next, a step of rinsing the hair and rinsing with water is preferably performed, preferably using a rinsing composition according to a conventional method. The rinsing composition is not particularly limited as long as it is applied for rinsing hair, and a known rinsing composition can be applied. A well-known rinse composition can be applied to the treatment step using the rinse composition. Next, a step of drying the hair is preferably performed according to a conventional method.

According to the oxidizing agent-containing composition of the above embodiment, the following effects can be obtained.
(1) The oxidizing agent containing composition of this embodiment contains (A)-(C) component other than an oxidizing agent. Therefore, the stability of the oxidizing agent, particularly hydrogen peroxide, is improved. Moreover, the effect can fully be exhibited, without reducing the hair dyeing or the decoloring and decoloring effect.

  (2) The oxidizing agent-containing composition of the present embodiment contains components (D) to (F). Therefore, the formulation stability of the oxidizing agent-containing composition is improved. In particular, even when a large amount of (A) stannate is blended, a decrease in formulation stability derived from (A) stannate can be suppressed.

In addition, you may change the said embodiment as follows.
-In the above hair dye, as a dye other than the above-mentioned oxidation dye, it is listed in, for example, “Standard raw material for quasi-drugs” (issued in June 2006, Yakuji Nippo) within the range that does not inhibit the effect of the present invention. Direct dyes may be contained as appropriate.

  -In the oxidizing agent containing composition of the said embodiment, each component of (A)-(F) should just be mix | blended in the oxidizing agent containing composition at the time of a preservation | save, and is one of each other component which comprises each agent. The part may be configured as a separate agent to further increase the number of dosage forms. Even in this configuration, the stability of the oxidizing agent and the stability of the preparation can be improved.

  -As long as the effect of this invention has the effect of this invention, the hair dye of the said embodiment or hair decoloring and decoloring agent of each component contained in each agent which comprises the hair dye or hair decoloring and decoloring agent mentioned above A part may be configured as a separate agent to increase the number of dosage forms.

  For example, in the first agent of the hair dye or hair decoloring / decoloring agent described above, the alkali agent and the composition other than the alkali agent may be divided and configured as separate agents. Further, it may be configured as a multi-component hair dye or a hair decoloring / decoloring agent in combination with an agent containing an oxidizing aid such as persulfate.

  -In the said embodiment, the dosage form of the mixture with which each agent was mixed is not specifically limited, As a specific example, the dosage form in 25 degreeC is liquid, gel form, foam form, such as an emulsion, aqueous solution, and emulsion, for example And cream.

  -The oxidizing agent containing composition of the said embodiment was comprised as the 2nd agent of a multi-component hair dye or hair decoloring and decoloring agent. You may comprise an oxidizing agent containing composition as a 2nd agent of the agent for permanent waves containing an oxidizing agent besides the said embodiment. Even in such a configuration, the stability of the oxidizing agent in the second agent, particularly hydrogen peroxide, is improved. Further, the effect can be sufficiently exhibited without reducing the permanent wave effect.

  -The oxidizing agent containing composition of the said embodiment was comprised as the 2nd agent of a multi-component hair dye or hair decoloring and decoloring agent. Applying the above embodiment, in the composition containing an oxidizing agent, (A) stannate, (B) aminocarboxylic acid chelating agent, and (C) acid are added to the content of component (A) ( You may comprise the stabilizing method of an oxidizing agent by mix | blending so that mass ratio of content of B) may be set to 0.01-35, and adjusting to pH 2-5.

Next, the embodiment will be described more specifically with reference to examples and comparative examples. In addition, this invention is not limited to the structure as described in the Example column.
The 1st agent of the oxidation hair dye and the 2nd agent as an oxidizing agent containing composition which contain each component shown in Tables 1-4 were prepared, respectively. In addition, the numerical value in the column which shows each component in each table | surface shows content of the component of the said column, The unit is the mass%. In the table, the notations “(A)” to “(F)” indicate compounds corresponding to the components (A) to (F) described in the claims. The numerical value in parentheses of the compound name POE is E. O. The number of moles added. The 1st agent and 2nd agent of the oxidation hair dye shown in Tables 1-4 were mixed by mass ratio of 1: 1, and the cream-like oxidation hair dye was prepared.

  The resulting oxidative hair dye was applied to a black and white hair bundle (10 cm, manufactured by Beaulux Co., Ltd.) (hereinafter simply referred to as a hair bundle) using a brush and allowed to stand at 30 ° C. for 30 minutes. Next, after rinsing the oxidative hair dye adhering to the hair bundle with water, shampoo (Bigue treatment shampoo made by Hoyu Co. as a shampoo composition) is applied to the hair bundle twice and rinse (Hoyu as a rinse composition). The company's Vigen Treatment Rinse) was applied once. In addition, the composition for shampoo and the composition for rinse are rinsed away with water for each treatment. Subsequently, the hair bundle was dried with warm air and then left for one day. The stability of the oxidizing agent in the second agent before mixing with the first agent and the formulation stability of the second agent were evaluated by the methods shown below.

(Stability of oxidizing agent)
About the hydrogen peroxide as the oxidizing agent in the second agent, put it in a polyethylene container and leave it at 60 ° C. for 7 days. Then, determine the amount of the remaining hydrogen peroxide by the oxidation-reduction titration method. The amount was calculated. The evaluation criteria were performed in the following four stages. Compared to immediately after the preparation, the remaining ratio of hydrogen peroxide is 99% by mass or more as “good: 4”, 98% by mass or more but less than 99% by mass “good: 3”, and 96% by mass or more but less than 98% by mass “somewhat poor. : 2 ”and less than 96% by mass were defined as“ defects: 1 ”, and the evaluation results were obtained.

(Formulation stability of the second agent)
About the formulation stability of the 2nd agent which is a liquid, it put into the container made from a polyethylene, and left to stand at 50 degreeC for 1 day, Then, the panelist five persons evaluated the separation state of the 2nd agent visually. Excellent (5 points), no separation, good (4 points), good (4 points), slightly separated, acceptable (3 points), slightly separated (slightly seen) Those with many defects (2 points) and separation were scored in 5 stages of defects (1 point). An average value is calculated for each paneler's scoring results, and an average value of 4.6 or higher is “excellent: 5”, 3.6 or higher and lower than 4.6 is “good: 4”, 2.6 or higher 3 The evaluation result was determined as “possible: 3” for less than 6 points, “slightly defective: 2” for 1.6 points or more and less than 2.6 points, and “bad: 1” for less than 1.6 points.

As shown in Tables 1 and 2, it was confirmed that each example has the above result for each evaluation item. As shown in Table 3, it was confirmed that Comparative Example 1 containing no component (A) was inferior in the evaluation of the stability of the oxidizing agent with respect to each Example. (B) It was confirmed that the comparative example 2 which does not contain a component is inferior in evaluation of stability of an oxidizing agent with respect to each Example. In Comparative Example 3 in which the mass ratio of the content of the component (B) to the content of the component (A) exceeds 35, it was confirmed that the evaluation of the stability of the oxidizing agent was inferior to each example. It was confirmed that the comparative example 4 whose pH of a 2nd agent is 6 is inferior in evaluation of the stability of an oxidizing agent with respect to each Example.

Claims (6)

  It contains (A) stannate, (B) aminocarboxylic acid chelating agent, and (C) acid, and the mass ratio of the content of component (B) to the content of component (A) is 0.01. It is -35, and is pH 2-5, The oxidizing agent containing composition characterized by the above-mentioned.   The oxidizing agent-containing composition according to claim 1, further comprising (D) a cationic surfactant.   The oxidizing agent-containing composition according to claim 1 or 2, further comprising (E) a polyoxyethylene alkyl ether type nonionic surfactant.   Furthermore, the oxidizing agent containing composition as described in any one of Claims 1-3 containing (F) hydrocarbon.   The oxidizing agent containing composition as described in any one of Claims 1-4 used as a hair dye or a hair decoloring and decoloring agent by mixing with the agent containing an alkaline agent.   In the composition containing an oxidizing agent, (A) a stannate, (B) an aminocarboxylic acid-based chelating agent, and (C) an acid are blended, and the content of the component (B) with respect to the content of the component (A) A method for stabilizing an oxidizing agent, wherein the mass ratio of the content is 0.01 to 35, and the pH of the composition is 2 to 5.