JP2019073481A - Powder cosmetic - Google Patents

Abstract

To provide a powder cosmetic having excellent makeup sustainability and high-temperature stability while having a melting feeling and a moisture-retaining feeling during application.SOLUTION: There is provided a powder cosmetic having excellent makeup sustainability and high-temperature stability while having a melting feeling and a moisture-retaining feeling during application by incorporating a component (A): tripropylene glycol and a component (B): 40 mass% or more of a powder having an aspect ratio of 8 or more.SELECTED DRAWING: None

Description

  The present invention relates to a powder cosmetic, and more particularly, to a powder cosmetic having excellent cosmetic stability and high temperature stability while having a melt feeling and moisturizing feeling at the time of application.

  Powdered cosmetics represented by eye shadow and powder foundation are cosmetics which used powder as the main ingredients and mixed a pigment, an oil agent, etc. suitably, and since the method of use is excellent in portability and easy to use, it is widely supported by consumers It is done. However, since powder cosmetics contain powder as a main component, the powder absorbs oil on the skin, which tends to lower the moisturizing feeling of the skin and make the cosmetic gloss prone. Further, in recent years, while feeling the feel of powder at the time of coating, it is required to spread and spread lightly on the skin, and to have a feeling of melting that blends in with the skin.

  Conventionally, various studies have been conducted to solve the above-mentioned problems. For example, as a technique for improving cosmetic properties, a technique using a water / oil repellent treated powder and a solid and / or semi-solid oil agent (Patent Document 1) or a technique using a cationic surfactant treated powder (Patent Document 2) Has been proposed. Moreover, the technique (patent document 3) which uses a baking clay mineral and a hygroscopic moisturizer is proposed as a technique which mix | blends a moisturizer and improves the moisturizing effect to skin.

Unexamined-Japanese-Patent No. 2010-37213 JP, 2006-199645, A JP, 2008-1686, A

  However, in the technology using a water- and oil-repellent-treated powder and a solid and / or semi-solid oil agent (Patent Document 1), although the cosmetic texture is improved, the powder is aggregated because a viscous oil agent is used. In addition to the inability to get a sense of melt, there has been a tendency for the high temperature stability to deteriorate. In the technology using cationic surfactant-treated powder (patent document 2), although cosmetic properties are improved, the difference in surface charge between cationic surfactant-treated powder and other powders makes it possible to operate in a high temperature environment. The powder tended to clump. Furthermore, the moisture and sebum on the skin are adsorbed by the cationic surfactant-treated powder, the moisture content of the skin and the water evaporation preventing effect are reduced, and it may be difficult to obtain a moist feeling. In the technology using a hygroscopic moisturizer and a calcined clay mineral (Patent Document 3), although a moisturizing feeling can be obtained, it is weak against sweat because of its high hydrophilicity, and there may be a case where a satisfactory cosmetic texture can not be obtained. .

  Therefore, there is a need for a powder cosmetic which has cosmetic makeup and excellent high-temperature stability despite the fact that it has a sense of melting and moisturizing upon application.

  Under these circumstances, the present inventor considered that the moisturizing feeling can be enhanced by using a polyhydric alcohol, and further investigation of the inclusion of various components was conducted. We found that tripropylene glycol, which has a high degree of polymerization and high lipophilicity compared to glycol and dipropylene glycol, is excellent in dispersibility in powder, and it has an aspect ratio that is soft even in powder and is also excellent in slideability. It has been found that the combination with eight or more powders has excellent makeup retention to moisturizing feeling and sweat. In addition, powder containing 40% by mass or more (hereinafter simply referred to as "%") of powder having an aspect ratio of 8 or more (powdered cosmetic with excellent sense of melting and moisturizing at the time of application, cosmetic properties, and high temperature stability) The present invention has been found out that the

  That is, the present invention provides a powder cosmetic containing component (A) tripropylene glycol and component (B) powder having an aspect ratio of 8 or more 40% or more.

  Further, the present invention provides the powder cosmetic wherein the content mass ratio of the component (A) to the component (B) is component (B) / component (A) = 1 to 85.

  Further, the present invention provides the powder cosmetic wherein the average particle diameter of the component (B) is 10 to 300 μm.

  Further, the present invention provides the powder cosmetic wherein the component (B) is one or more selected from synthetic phlogopite, mica, sericite, talc, boron nitride and mica titanium.

  Furthermore, as the component (C), there is provided the powder cosmetic comprising phospholipid.

  The present invention is to provide a powdery cosmetic which is excellent in high-temperature stability and cosmetic makeup while having a sense of melting and moisturizing upon application.

  Hereinafter, the present invention will be described in detail. In addition, in this specification, "-" shall mean the range including the numerical value before and behind that.

Component (A) tripropylene glycol used in the present invention is a polyhydric alcohol composed of a trimer of propylene glycol, and is represented by the following general formula (1):
H (OCH ₂ CH (CH ₃ )) n OH (1)
(Where n is an average of 3)
In the INCI name (International Nomenclature Cosmetic Ingredient labeling names), it is represented by tripropylene glycol or PPG-3. Examples of commercially available products include TPG-H (manufactured by ADEKA), Newpol PP-200 (manufactured by Sanyo Chemical Industries, Ltd.), tripropylene glycol (manufactured by Asahi Glass Co., Ltd.), and the like.

  The content of the component (A) to be used in the present invention is not particularly limited, but is preferably 1 to 35% from the viewpoint of being superior to moisturizing feeling and cosmetic hold, moisturizing feeling, cosmetic holding and high temperature stability It is more preferably 3 to 30% from the viewpoint of superiority, and particularly preferably 8 to 20% from the viewpoint of superiority due to a moisturizing feeling, makeup retention, high-temperature stability, and a feeling of meltdown upon application.

  The powder of the component (B) used in the present invention is not particularly limited as long as the powder has an aspect ratio of 8 or more, and, for example, mica, sericite, synthetic phlogopite, synthetic sericite, talc, silicic acid Inorganic powders such as aluminum, magnesium silicate, magnesium aluminum silicate, cleaved talc, anhydrous silicic acid, aluminum oxide, kaolin, boron nitride, titanium oxide, etc., mica titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide Luster powder such as coated mica, titanium dioxide coated synthetic phlogopite, titanium dioxide coated bismuth oxychloride, iron oxide coated mica titanium, bitumen treated mica titanium, carmine treated mica titanium, fish scale foil, titanium dioxide coated glass powder, etc. Titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, acid Composite powders such as titanium-containing silica, zinc oxide-containing silica, organic powders such as cellulose, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder These may be used alone or in combination of two or more. Among these, mica, sericite, synthetic phlogopite, talc, boron nitride and mica titanium are preferably used from the viewpoints of having good adhesion to the skin, improving cosmetic properties and having an excellent melt feeling upon application. It is more preferable to use mica or synthetic phlogopite. These powders may be one or more of fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc. You may surface-treat using the above.

  In the present invention, the aspect ratio of the powder is a value calculated from (average particle diameter) / (average thickness). The aspect ratio of the powder of the component (B) is 8 or more, and is not particularly limited, but it is 10 to 400 from the viewpoint of soft touch and good slidability, and excellent melt feeling and makeup at the time of application. It is more preferably 30 to 300 from the viewpoint of, for example, the feeling of melting upon application, cosmetic makeup, and excellent stability at high temperature. If the aspect ratio is less than 8, the bulk is low, and it is difficult to obtain a soft feel and slidability on the skin, and the melt feeling upon application is impaired.

  The average particle size of the component (B) is not particularly limited, but it is preferably 10 to 300 μm and more preferably 10 to 120 μm from the viewpoint of melt feeling and cosmetic properties at the time of application. It is particularly preferable to use one having a diameter of 18 to 120 μm.

  In the present invention, the average particle size and average thickness of the powder are measured for the particle size and thickness of 30 particles using a scanning electron microscope (Real Surface View Microscope VE-7800 manufactured by KEYENCE Co., Ltd.). It calculated by using an average value.

  The particle shape of the component (B) is not particularly limited, and examples thereof include spindle, needle, fiber, and plate. Among these, a plate-like shape is more preferable from the viewpoint of soft touch and good slidability, and excellent melt feeling and cosmetic texture at the time of application.

  Although content of a component (B) is 40% or more with respect to the whole cosmetics, and it is not specifically limited, It is more preferable that it is 50-95% from a viewpoint of being excellent by the melt feeling and high temperature stability at the time of application. It is particularly preferable that the content is 55 to 85% from the viewpoint of, for example, being superior to the feeling of melt and high temperature stability at the time of application. If the content of the component (B) is less than 40%, it is not preferable because the soft touch and the slidability are hardly obtained and the melt feeling at the time of coating is impaired.

  Although the content mass ratio of the component (A) and the component (B) in the powder cosmetic of the present invention is not particularly limited, (B) / (B) / (B) A) It is preferable that it is 1-85, It is more preferable that it is 2-85, It is especially preferable that it is 2-30.

  In the present invention, a phospholipid can be further contained as a component (C). The phospholipid used for the component (C) is not particularly limited as long as it is a phospholipid generally used in cosmetics, and it is possible to use one or more in combination. The phospholipid may be a natural product extracted and purified from animals and plants, or it may be chemically synthesized, and may be subjected to processing such as hydrogenation, hydroxylation, or enzyme treatment. Examples of natural products include soybean-derived phospholipids and egg yolk-derived phospholipids, and examples of processed products include hydrogenated phospholipids and lysophospholipids. More specifically, soybean-derived phospholipids, soybean-derived hydrogenated phospholipids, soybean-derived lysophospholipids, soybean-derived hydrogenated lysophospholipids, egg yolk-derived phospholipids, egg yolk-derived hydrogenated phospholipids, egg yolk-derived lysophospholipids, egg yolk-derived hydrogen The additive lysophospholipid etc. are mentioned and these can be used 1 type or 2 types or more. Commercially available products include: Resinol S-PIE, Nicole Resinol S-10, Nicole Resinol S-10E (all manufactured by Nikko Chemicals), Basis LS-60 HR (manufactured by Nisshin Oillio Group), HSL-70 (manufactured by YMS) , Lecithin CLO (manufactured by J-Oil Mills), egg yolk lecithin PL-100P (manufactured by Kewpie), and the like.

  Although the content of the component (C) is not particularly limited, it is preferably 0.001 to 3% with respect to the total amount of the powder cosmetic, from the viewpoint of easily obtaining a feeling of melting at the time of application, etc. It is more preferably 0.001 to 2%, and particularly preferably 0.001 to 1%.

  The phospholipid of the component (C) may be used as it is, but when the component (B) has an aspect ratio of 8 or more, it is treated on the surface of the powder and treated as a phospholipid-treated powder. It is more preferable because it can improve the feeling of melting. The processing amount of the phospholipid when used as a phospholipid-treated powder is not particularly limited, but is preferably 0.01 to 2%, 0.03 to 1% with respect to the powder to be treated. And more preferably 0.04 to 0.5%.

  The powder cosmetic composition of the present invention is a component other than the above-mentioned components (A) to (C), usually used in cosmetics, an oil component, a powder, and a powder dispersion as long as the effects of the present invention are not impaired. The effects of the present invention on surface-active agents, film-forming agents, water-soluble components, UV-absorbers, moisturizers, anti-fading agents, antioxidants, anti-foam agents, cosmetic ingredients, preservatives, perfumes, etc. It can contain suitably in the range which does not impair.

As an oil component, regardless of the origin of animal oil, vegetable oil, synthetic oil etc., and properties of solid oil, semi-solid oil, liquid oil etc., hydrocarbons, fats and oils, waxes, hardened oils, ester oils And fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents, oil-soluble resins, volatile oils and the like.
Specifically, hydrocarbons such as liquid paraffin, squalane, vaseline, paraffin wax, ceresine wax, microcrystalline wax, ethylene propylene copolymer, montan wax, Fischer Tropsu wax, etc., wax wax, olive oil, castor oil, castor oil, mink oil, macadamia Fats and oils such as corn nut oil, waxes such as beeswax, carnauba wax, candelilla wax, geyrow, jojoba oil, cetyl isooctanate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearin Acid polyglyceryl, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctoate, cholesterol Esters such as N-lauroyl-L-glutamic acid di (cholesteryl behenyl octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, higher alcohols such as behenyl alcohol, methylphenylpoly Silicones such as siloxane, fluorine-modified organopolysiloxane, fluorine-based oil agents such as perfluorodecane, perfluorooctane, perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, octanoate dextrin Lauric acid dextrin, palmitic acid dextrin, myristate dextrin, stearic acid dextrin, behenic acid dextrin, coconut oil Fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, oily gelling agents such as 12-hydroxystearic acid, calcium stearate, etc. hydrogenated pentaolithlytyl rosin acid, specific alkyl acrylate Volatilization of oil soluble resin such as methylpolysiloxane ester, light liquid isoparaffin, hydrocarbon oil such as isododecane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, silicone such as dimethylpolysiloxane with low polymerization degree Oils and the like. Among these, although not particularly limited, (i) the organic value is 1000 or less, and the IOB value from the viewpoint that the compatibility with the component (A) is high and the uniformity is improved and the melt feeling at the time of application is more excellent. It is preferable to use a polar oil having a range of 0.25 to 1.0, and (ii) a nonpolar oil having an organic value of 260 or less.

  Here, “organic value (inorganic value)” refers to an organic conceptual diagram (Fujita, Prediction of organic compounds and organic conceptual diagram, based on the domain of chemistry VOL. 11, No. 10 (1957) 719-715). It is a value to be obtained. More specifically, in this organic conceptual diagram, with regard to the physicochemical properties of the compound, the degree of physical properties mainly by Van Der Waals force is “organic”, and the degree of physical properties mainly by electrical affinity is It is a value defined and expressed as "inorganicity". The IOB value is an index showing the balance between inorganic and organic, and is given by the inorganic value (IV) / organic value (OV). The greater the value of this value, the more hydrophilic the compound. Specific examples of (i) are tri (caprylic acid / capric acid) glyceryl (organic value = 540, IOB value = 0.35) malic acid diisostearyl (organic value = 780, IOB value = 0.28) Etc. Further, specific examples of (ii) include isododecane (organic value = 230), hydrogenated polyisobutene (organic value = 200 to 260), lauryl alcohol (organic value = 240) and the like.

  The content of the oil component in the present invention is not particularly limited, but it is preferably 15% or less, more preferably 10% or less, from the viewpoint of obtaining a feeling of meltiness without feeling stickiness. It is particularly preferable that the content is 5% or less from the viewpoint that the effect is more exerted.

  The content mass ratio of the component (A) to the oil component in the powder cosmetic of the present invention is not particularly limited, but from the viewpoint of being superior by the feeling of hotness at the time of application, high temperature stability etc., (oil component) / (A) = 1 It is preferable that it is -1500, It is more preferable that it is 2-70, It is especially preferable that it is 3-60.

  The powder other than the component (B) is not particularly limited by the shape such as spherical shape, particle shape such as fume shape, fine particle, pigment grade, particle structure such as porous or non-porous, etc. Composite powder etc. are mentioned. Specifically, inorganic powders such as aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, talc, kaolin, silica, silicon carbide, magnesium stearate, zinc stearate, N-acyl lysine, nylon, etc. Organic powders, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, iron oxides, carbon black, chromium oxide, chromium hydroxide, bitumen, ultramarines, colored inorganic pigments such as bengara, red No. 201, Organic pigment powder such as Red 202, Red 205, Red 226, Red 228, Orange 203, Orange 204, Blue 404, Yellow 401, etc. Red 3, Red 104, Red 106, Zirconium such as Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, etc., barium, or aluminum Organic pigment powders or even aluminum powder over key such as gold powder, include metal powders such as silver, it can be used more than those one or. In addition, these powders may be used alone or in combination of two or more, and known methods using fluorine compounds, silicone-based oil agents, metal soaps, surfactants, fats and oils, hydrocarbons, etc. It may be surface-treated.

  As the surfactant, any surfactant which is generally used in cosmetics can be used, and nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Can be mentioned. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modification Organopolysiloxane, polyether modified organopolysiloxane etc. are mentioned.

  Examples of the film forming agent include alkyl acrylate polymers, alkyl methacrylate polymers, alkyl methacrylate copolymers and the like.

  The water-soluble component may be any component soluble in water, for example, lower alcohols such as ethyl alcohol and butyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol and polyethylene glycol And glycerol, such as glycerin, diglycerin and polyglycerin.

  Examples of water-soluble polymers include those of synthetic systems such as carboxyvinyl polymers, alkylated carboxyvinyl polymers, and sodium polyacrylate. Protein, collagen, elastin, keratin and the like can be mentioned.

  UV absorbers include, for example, benzophenone type, PABA type, cinnamic acid type, salicylic acid type, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone and the like, and as a humectant, for example, protein, mucopolysaccharide, collagen , Elastin, keratin, etc., as an antioxidant, eg, α-tocopherol, ascorbic acid, etc., as a cosmetic component, eg, vitamins, anti-inflammatory agent, herbal medicine, etc., as a preservative, eg, p-hydroxybenzoic acid ester, phenoxyethanol, 1 And 2-pentanediol.

  The powder cosmetic of the present invention may be in the form of solid or powder (loose), for example, a powder containing component (A), component (B), component (C) and other powders. Solid powder cosmetic composition which is mixed with other components such as oil agent and water system composition, then pulverized and compression molded, and powder containing component (A), component (B) and component (C) and other powders The powdery cosmetic may be used in a loose form without being crushed and compression-molded after the body component and other components such as oil and aqueous components are mixed. Among these, although not particularly limited, it is particularly preferable that the powdery cosmetic used loosely be used, from the viewpoint that the effects of the present invention are more remarkably exhibited.

  The powder cosmetic composition of the present invention is mainly composed of powder, and is not particularly limited. However, foundations such as foundation, white powder, eye color, cheek color, eyebrow make-up cosmetic, body powder, whitening powder, etc. It is applicable to cosmetics. Among these, from the viewpoint that the effects of the present invention are significantly exhibited, they are suitably used for makeup cosmetics, and more preferably used for white powder, eye color and cheek color.

Examples 1 to 20 and Comparative Examples 1 to 8 Eye color The eye color of the formulation shown in the following Tables 1 to 3 is manufactured, and the feeling of melting upon application, moisturizing feeling, cosmetic haze, high temperature stability is evaluated by the following method. did. The results are also shown in Tables 1 to 3.

(Production method)
A. Mix 1 to 12 uniformly with a super mixer.
B. Dissolve 13-22 uniformly at 50 ° C.
C. Add B to A and disperse uniformly.
D. C was crushed and filled in a container (radius 8 mm, height 5 cm, material PP) with an applied body (flocky) to obtain an eye color.

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
B. Sense of melt at the time of application Feeling of moisturizing C. For each item of the items of cosmetic moisturizing a to c, the use test was conducted by 20 experts panel (hereinafter simply referred to as "panel"). Each panel uses each eye color of Examples 1 to 20 and Comparative Examples 1 to 8 and evaluates and ranks it in 7 steps according to the following absolute evaluation criteria, and the average value from the total score of all the panels for each sample Were calculated and judged according to the following judgment criteria. As for the feeling of melting at the time of application, each sample was applied to the skin, and when it was stretched and spread, it felt smoothly felt to spread and spread, or B. For moisturizing feeling, apply each sample and let the panel have 6 hours of normal life or feel moisturizing, or C. For the cosmetic case, have the panel have 6 hours of ordinary life It was evaluated whether the makeup film was broken by tears or sweat.

Absolute evaluation criteria (score): (evaluation)
6: very good 5: good 4: somewhat good 3: normal 2: somewhat bad 1: bad 0: very bad

(Judgement): (average score)
A: 5.0 points or more B: 3.5 points or more to less than 5.0 points C: 2.0 points or more to less than 3.5 points D: less than 2.0 points

(Evaluation item)
two. High Temperature Stability Regarding the item of high temperature stability, samples obtained by storing each eye color of Examples 1 to 20 and Comparative Examples 1 to 8 at 50 ° C. for one month and one month stored products at room temperature (25 ° C.) The panel used by 20 panelists (hereinafter referred to as "room temperature sample"), and evaluated whether there is no change in the feeling of use by the following absolute evaluation criteria in 7 steps and scoring. The average value was calculated from the sum, and it determined by the following determination criteria.

Absolute evaluation criteria (score): (evaluation)
6: There is no change in usability compared to a room temperature sample.
5: Compared with the room temperature sample, the feeling in use is almost unchanged and is good.
4: Better than the room temperature sample, although there is a slight change in usability.
3: When compared to a room temperature sample, it feels powdery on the skin when applied.
Or I feel a little weight for the spread of powder, but there is no problem with the feeling of use.
2: Compared to the room temperature sample, it feels a feeling of burden on the skin due to powder powder on the skin at the time of application.
Or, I feel the weight of the spread of the powder, it is difficult to apply a uniform cosmetic film on the skin
It is bad.
1: Compared to room temperature samples, when applied, the feeling of burden on the skin due to powder powder is felt,
I feel a drop in the feeling of adherence.
Or, the spread of the powder is poor, and it is difficult to apply a uniform cosmetic film on the skin,
It is bad.
0: Compared with room temperature samples, powdery powder on the skin at the time of application makes the skin feel harsh,
I notice a drop in the feeling of adhesion. Or, the spread of powder is very bad,
And the cosmetic film can not be applied uniformly.

Judgment criteria (judgment): (average score)
A: 5.0 points or more B: 3.5 points or more to less than 5.0 points C: 2.0 points or more to less than 3.5 points D: less than 2.0 points

As is clear from the results of Tables 1 to 3, Examples 1 to 20 were cosmetics excellent in high-temperature stability and a feeling of melting upon application, a feeling of moisturization, cosmetic properties.
On the other hand, in Comparative Example 1 in which 1,3-butylene glycol was used instead of the component (A) and Comparative Example 2 in which propylene glycol was used, a satisfactory cosmetic cake was not obtained. In addition, 1,3-butylene glycol and propylene glycol have low molecular weight among polyhydric alcohols and are slightly volatile. Therefore, they partially volatilize at high temperature, resulting in a feeling of use and a sense of burden on the skin. And I felt a drop in the feeling of adhesion and I was not able to obtain a satisfactory thing regarding high temperature stability. In addition, Comparative Example 3 using a dipropylene glycol having a degree of polymerization lower than that of the component (A) and having hydrophilicity is worse in cosmetic resistance to sweat and the like than the component (A), and no appropriate viscosity is given. I was not satisfied with the feeling of meltdown. In Comparative Example 4 in which the oil solution was used instead of the component (A), the weight of elongation peculiar to the oil solution was not obtained, and no melt feeling could be obtained. In addition, the powder agglomerated at a high temperature, and the spread of the film was heavy, so that the cosmetic film could not be uniformly applied on the skin, and a satisfactory product could not be obtained. In Comparative Example 5 in which talc having a small aspect ratio of the component (B) was used, the elongation spread was heavy, and a melt feeling could not be obtained. In addition, the powder agglomerated at high temperature, and a satisfactory one was not obtained even in high temperature stability. In Comparative Example 6 in which a semisolid oil agent and a hydrophobic powder were combined instead of the component (A), since the viscous oil agent was used, the powder agglomerated, and the melt feeling and high temperature stability were satisfactory. I could not get anything In Comparative Example 7 in which the cationic surfactant-treated powder and the fluorine-treated powder were used, a satisfactory one in moisturizing feeling and high temperature stability could not be obtained. In Comparative Example 8 using the calcined mineral and the hygroscopic moisturizer, a satisfactory product was not obtained with respect to cosmetic properties and high temperature stability.

Example 21 White powder White powder was prepared according to the following formulation and procedure.
(Component) (%)
1. Synthetic phlogopite * 2 50
2. Talc * 9 10
3. Boron nitride * 4 Remaining capacity4. Zinc oxide 5
5. Spherical silica * 14 5
6. Spherical polyethylene powder * 15 5
7. Bengala 0.3
8. Yellow iron oxide 0.5
9. Methyl parahydroxybenzoate 0.2
10. Tripropylene glycol 20
11. 1,3-Butylene glycol 0.5
12.2- Stearyl ethylhexanoate
(Organic value = 510, IOB = 0.12) 0.3
* 14: Silica P-1505 (average particle size 12 μm, manufactured by JGC Catalysts & Chemical Co., Ltd.)
* 15: Miperon PM-200 (average particle size 10 μm, manufactured by Mitsui Chemicals, Inc.)
(Production method)
A. Mix 1 to 9 uniformly with a super mixer.
B. Mix and dissolve 10 to 12 uniformly.
C. Add B to A and mix uniformly.
D. C was crushed and filled in a container to obtain loose white powder.

  The obtained white powder was a cosmetic which was excellent in high-temperature stability, a feeling of melting, a feeling of moisturization, a cosmetic texture, and the like at the time of application.

Example 22 Teak Color A teak color was prepared according to the following recipe and procedure.
(Component) (%)
1. Spherical (dimethicone / methicone silsesquioxane)
Cross polymer * 16 10
2. Spherical nylon-12 * 17 2
3. Red No. 226 0.5
4. Red No. 202 1.2
5. Talc * 9 5
6. Mica * 3 20
7. Boron nitride * 4 10
8. Synthetic phlogopite * 2 Remaining 9. Boron nitride * 18 5
10. Mica titanium * 6 14
11. Zinc oxide 2
12. Methyl parahydroxybenzoate 0.3
13. Sorbitan sesquiisostearate (organic value = 645, IOB = 0.57) 0.15
14. Tripropylene glycol 25
15. Vaseline (organic value = 450, IOB = 0) 0.3
16. Carbomer 0.05
17. Ethanol (organic value = 40, IOB = 2.5) 0.1
18. Triethanolamine 0.05
19. Purified water 0.3
20. Fragrance 0.2
* 16: KSP-100 (average particle size 5 μm, manufactured by Shin-Etsu Chemical Co., Ltd.)
* 17: Orgasol 2002D (average particle size 22 μm, manufactured by Atofina)
* 18: SHP-9 (average particle size 8 μm, aspect ratio 15, manufactured by Mizushima Koutetsu)
(Production method)
A. Mix 1 to 12 uniformly with a super mixer.
B. Mix and dissolve 13 to 20 uniformly.
C. Add B to A and mix uniformly.
D. After crushing C, it was press-molded to obtain a cheek color.

  The obtained cheek color was a cosmetic excellent in the feeling of melting at the time of application, moisturizing feeling, makeup retention, high temperature stability.

Example 23: Eyebrow An eyebrow was prepared according to the following formulation and procedure.
(Component) (%)
1. Barium sulfate * 19 4
2. Spherical nylon-12 * 17 10
3. Yellow iron oxide 2
4. Black iron oxide 3
5. Red iron oxide 1
6. Mica * 3 Remaining 7. Amino modified silicone 1% treated mica * 20 3
8. Titanium oxide coated glass powder * 21 3
9. Dimethylpolysiloxane 1% treated synthetic phlogopite * 22 11
10. Methyl parahydroxybenzoate 0.3
11. Dimethylpolysiloxane (organic value = 270, IOB = 0.3) 0.3
12. Tripropylene glycol 17
13. Hydrogenated castor oil (organic value = 1140, IOB = 0.42) 0.3
14. Ethanol (organic value = 40, IOB = 2.5) 0.3
15. Acrylates copolymer 1
* 19: Plate-like barium sulfate HM (average particle diameter 12 μm, aspect ratio 30; manufactured by Sakai Chemical Co., Ltd.)
* 20: Y-2300 (Yamaguchi Mica) treated with 1% amodimethicone * 21: Microglass Metashine MT1080RY (average particle size 80 μm, aspect ratio 80, manufactured by Nippon Sheet Glass Co., Ltd.)
* 22: PDM-5L (manufactured by TOPY INDUSTRIES, LTD.) Treated with 1% dimethylpolysiloxane (manufacturing method)
A. Mix 1 to 10 uniformly with a super mixer.
B. Mix and dissolve 11 to 14 uniformly.
C. Add B to A and mix uniformly.
D. C was crushed and filled in a container to obtain a loose eyebrow.

  The obtained eyebrow was a cosmetic excellent in the feeling of melting at the time of application, moisturizing feeling, makeup retention, and high temperature stability.

Example 24 Eye Color An eye color was produced according to the following formulation and procedure.
(Component) (%)
1. Red No. 226 1
2. Yellow 4 1
3. Dimethylpolysiloxane 1% treated yellow iron oxide 0.5
4. Black iron oxide 0.5
5. Dimethylpolysiloxane 1% treated synthetic phlogopite * 22 11
6. Synthetic phlogopite * 1 Remaining 7. Spherical nylon-12 * 17 4
8. Spherical (dimethicone / methicone silsesquioxane)
Cross polymer * 16 4
9. Titanium oxide coated glass powder * 21 8
10. Iron oxide coated mica titanium * 23 20
11. Dimethylpolysiloxane 2% treated mica titanium * 24 3
12. Phospholipid 0.05% treated mica * 5 8
13. Tripropylene glycol 15
14. DPG 0.1
15. Vegetable oil 0.1
16. Fragrance 0.01
* 23: Kororonachena Sparkle (average particle size 47 μm, aspect ratio 350, Engelhard)
* 24: 2% dimethylpolysiloxane treatment of TIMIRON STARCLUSTER MP-115 (manufactured by Merck) (production method)
A. Mix 1 to 12 uniformly with a super mixer.
B. Mix and dissolve 13 to 15 uniformly.
C. Add B and 16 to A and mix uniformly.
D. C was crushed and filled in a container to obtain a loose eye color.

  The obtained eye color was a cosmetic excellent in the feeling of melting upon application, the feeling of moisturizing, the makeup retention, and the high temperature stability.

Example 25: Foundation (solid)
The foundation was manufactured to the following formulation and manufacturing method (component) (%)
1. Yellow iron oxide 0.3
2. Red iron oxide 0.2
3. Black iron oxide 0.2
4. Dimethylpolysiloxane 1% treated synthetic phlogopite * 22 11
5. Dimethylpolysiloxane 2% treated talc * 24 remaining amount Triethoxy caprylylsilane 2% treated talc * 25 10
7. Spherical polymethyl methacrylate * 26 4
8. Spherical (HDI / PPG / polycaprolactone) crosspolymer * 27 4
9. Titanium oxide 8
10. Ethylhexyl paramethoxycinnamate 8
11. Tripropylene glycol 3
12. Triethylhexanoin (organic value = 510, IOB = 0.35) 4
13. Squaran (organic value = 540, IOB = 0) 3
14. Malic acid diisostearyl (organic value = 780, IOB = 0.28) 1
15. Hyaluronic acid Na * 28 0.1
16. Tocopherol 0.1
17. Glycerin 1
* 24: Talc JA-46R (manufactured by Asada Powder Co., Ltd.) treated with 1% dimethylpolysiloxane * 25: Talc JA-46R (manufactured by Asada Powder Co., Ltd.) treated by 2% triethoxycaprylylsilane * 26: MR-7 GC (average Particle size 7 μm, manufactured by Soken Chemical Co., Ltd.)
* 27: CS-400 (average particle size 15 μm, manufactured by Negami Chemical Industries, Ltd.)
* 28: Hyaluronic acid FCH-SU-S (manufactured by Food Chemifa)
(Production method)
A. Mix 1 to 9 uniformly with a super mixer.
B. Mix and dissolve 10 to 17 uniformly.
C. Add B to A and mix uniformly.
D. After crushing C, it was press-molded to obtain a foundation.

  The obtained foundation was a cosmetic excellent in the feeling of melting at the time of application, moisturizing feeling, makeup retention, and high temperature stability.

Example 26: Body powder A body powder was produced according to the following formulation and method (components) (%)
1. Boron nitride * 4 20
2. Spherical polyethylene powder * 15 15
3. Talc * 9 Remaining 4. Zinc laurate treated sericite * 29 10
5. Phytosterol 0.01
6. N-Lauroyl-L-glutamic acid di (phytosteryl / octyldecyl)
(Organic value = 1214, IOB = 0.3) 0.05
7. Tripropylene glycol 15
8. Shea butter (organic value = 1140, IOB = 0.16) 3
9. Octyl dodecanol (organic value = 390, IOB = 0.26) 2
10. Polybutene (organic value = 60, IOB = 0) 3
* 29: 1% zinc laurate treatment of sericite FSE (manufactured by Sanshin Minko Co., Ltd.)

(Production method)
A. Disperse 1 to 4 uniformly with a super mixer.
B. Mix 5 to 10 uniformly.
C. Add B to A, mix uniformly, add 20% of isododecane as a solvent, and mix uniformly.
D. After compression molding while absorbing the solvent C, it was dried at 70 ° C. for 10 hours to obtain a body powder.

The obtained body powder was a cosmetic excellent in the feeling of melting upon application, the feeling of moisture, the makeup retention, and the high-temperature stability.

Claims (5)

The following components (A) to (B);
(A) Tripropylene glycol (B) Powder having 40% by mass or more of powder having an aspect ratio of 8 or more The powder cosmetic according to claim 1, wherein a content mass ratio of the component (A) to the component (B) is component (B) / component (A) = 1 to 85. The powder cosmetic according to claim 1, wherein an average particle diameter of the component (B) is 10 to 300 μm. The powder cosmetic according to any one of claims 1 to 3, wherein the component (B) is one or more selected from synthetic phlogopite, mica, sericite, talc, boron nitride and mica titanium. The powder cosmetic according to any one of claims 1 to 4, further comprising a phospholipid as the component (C).