JP2018125002A - Selection method of writing member for touch panel pen, touch panel system, writing member for touch panel pen, touch panel, and display device - Google Patents

Abstract

Provided is a method for selecting a writable member for a touch panel pen which can efficiently perform product design and quality control of the writable member. A touch panel pen is fixed with the touch panel pen in contact with the surface of the writable member at an angle of 60 degrees, and a vertical load of 100 gf is applied to the touch panel pen, and the writable member for the touch panel pen is 14 mm / mm. The dynamic frictional force in the moving direction applied to the touch panel pen when moving the length of 40 mm one way at a speed of seconds is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated. Further, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated. A material in which the average of the dynamic friction force and the average of the residual friction force satisfy the relationship of “0.45 <average of residual friction force / average of dynamic friction force” is selected as a writable member for a touch panel pen. [Selection figure] None

Description

  The present invention relates to a method for selecting a writable member for a touch panel pen, a touch panel system, a writable member for a touch panel pen, a touch panel, and a display device.

  In recent years, touch panels have been installed in many portable information terminals, and the distribution volume has increased. A surface protective sheet may be attached to the surface of the touch panel for various purposes.

Conventionally, the resistance film type touch panel, which has been the mainstream, performs an operation of repeatedly hitting with a finger or a pen, and thus the surface protection sheet is required to have high scratch resistance.
On the other hand, the surface protection sheet of a capacitive touch panel, which is currently the mainstream, is required to have slipperiness when operated with a finger. The conventional resistive film type cannot detect multiple locations at the same time, so it does not move the finger on the screen, but the capacitive touch panel can detect multiple locations simultaneously, and moves the finger on the screen. This is because there are many.
In addition, in common with the resistive film type and the capacitive type, the surface protective sheet for touch panel is required to have the performance of suppressing the adhesion of fingerprints when operated with a finger or facilitating wiping off the adhered fingerprints. ing.

  For example, Patent Documents 1 and 2 have been proposed as surface protective sheets for touch panels as described above.

JP2015-114939A JP 2014-109712 A

Since the capacitive touch panel recognizes a touched place by measuring a change in capacitance, the contact object needs to have a certain conductivity. For this reason, at the beginning of the appearance of the capacitive touch panel, only operability with a finger was considered, and writing properties such as drawing characters and pictures with a touch panel pen were not considered. Also in the resistive touch panel, the operation when using the touch panel pen is mainly performed by dots, and the writing property when drawing characters and pictures is not emphasized.
However, in recent years, touch panel pens that can be input to capacitive touch panels and electromagnetic induction touch panels have begun to be proposed, and the number of applications that support character input and drawing using touch panel pens has increased. The sheet is required to have a good writing feeling with a touch panel pen.
However, the conventionally proposed surface protective sheets for touch panels of Patent Documents 1 and 2 do not consider any writing feeling with a touch panel pen. Furthermore, in recent years, a high level of writing feeling, such as writing on a paper with a pencil, has been demanded.

  An object of the present invention is to provide a method for selecting a writable member for a touch panel pen, a touch panel system, a writable member for a touch panel pen, a touch panel, and a display device capable of obtaining a high level of writing feeling.

As a result of diligent research to solve the above problems, the present inventors have found that the relationship between the dynamic friction force and the residual friction force when the operation of the touch panel pen is temporarily stopped has a great influence on a high level of writing feeling. The above problems have been solved.
The present invention provides a touch panel pen writable member selection method, a touch panel system, a touch panel pen writable member, a touch panel, and a display device according to [1] to [5] below.

[1] A method for selecting a writable member for a touch panel pen, wherein a material satisfying the following condition 1-1 is selected as a writable member for a touch panel pen.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”.
[2] A touch panel system comprising a touch panel having a writable member for a touch panel pen on the surface and a touch panel pen, which satisfies the above condition 1-1.
[3] A writable member for a touch panel pen having a surface satisfying the above condition 1-1.
[4] A touch panel having a writable member on the surface, wherein the surface of the touch panel pen writable member according to [3] that satisfies the above condition 1-1 is the surface of the touch panel as the writable member. Touch panel arranged to face.
[5] A display device having a touch panel on a display element, wherein the touch panel is the touch panel according to [4].

  The method for selecting a writable member for a touch panel pen according to the present invention can select a writable member that provides a high level of writing feeling without performing a writing test with a touch panel pen. Quality control can be made efficient. Moreover, the touch panel system, the writable member for a touch panel pen, the touch panel, and the display device of the present invention can impart a high level of writing feeling.

It is sectional drawing which shows one Embodiment of the writable member for touchscreen pens of this invention. It is sectional drawing which shows other embodiment of the writable member for touch-panel pens of this invention. It is the schematic explaining the measuring method of frictional force. It is a figure explaining the calculation method of the diameter D of a touch-panel pen. It is a figure explaining the calculation method of average inclination-angle (theta) a. It is sectional drawing which shows one Embodiment of the touchscreen of this invention. It is sectional drawing which shows other embodiment of the touchscreen of this invention.

  Hereinafter, embodiments of the method for selecting a writable member for a touch panel pen, a touch panel system, a writable member for a touch panel pen, a touch panel, and a display device according to the present invention will be described.

[Selection method of writable material for touch panel pen]
The selection method of the writable member for touch-panel pens of this invention selects what satisfies the following conditions 1-1 as a writable member for touch-panel pens.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”.

  60 degrees means that the direction parallel to the surface of the writable member for a touch panel pen is inclined at 60 degrees with respect to the surface, with the direction parallel to the surface being 0 degrees.

FIG.1 and FIG.2 is sectional drawing which shows one Embodiment of the writable member 10 for touchscreen pens of this invention. 1 and 2 has a resin layer 2 on one surface of a substrate 1.
One surface of the writable member for a touch panel pen of the present invention may satisfy the condition 1-1, or both surfaces may satisfy the condition 1-1.
Hereinafter, a writable member for a touch panel pen may be referred to as a “writing member”, and a surface satisfying the condition 1-1 may be referred to as a “writing surface”.

<Writing surface>
The selection method of the writable member for touch-panel pens of this invention selects what has the surface which satisfy | fills the said conditions 1-1 as a writable member for touch-panel pens. Hereinafter, the technical idea of the design under Condition 1-1 will be described.

  When writing letters or drawing figures, there are many cases where writing is stopped for a moment and then restarted. For example, when changing the writing direction, the writing direction is usually changed after the writing is stopped for a moment. The frictional force is considered to be greatly related to the feeling of writing when the writing is stopped for a moment and then restarted, but in our study, there are some cases where there is no sufficient correlation between the two. It was.

Condition 1-1 “Average of residual frictional force (hereinafter may be referred to as“ F _re ”)” indicates the load condition of the touch panel pen and the touch panel to the writable member after the movement of the writable member is completed. In the state where the contact condition is maintained, the frictional force in the moving direction applied to the touch panel pen is shown. _Fre is considered to indicate the ease of stopping the pen tip when stopping writing for a moment and the critical force required when restarting the touch panel pen. That is, _Fre is considered to greatly affect the writing feeling in the operation of stopping writing for a moment and the operation of restarting (hereinafter sometimes referred to as “writing feeling at restart”). However, there are cases where the feeling of writing at the time of restart cannot be sufficiently achieved only by adjusting _Fre .
As a result of diligent study, the present inventors have left the immediately preceding sensation during a series of movements. Therefore, the immediately preceding dynamic friction force is large in the writing sensation when writing is stopped and restarted for a moment. I found out that it was influencing. Then, it has been found that by associating _Fre and dynamic friction force, the writing feeling at the time of restart can be improved, and as a result, a high level of writing feeling can be imparted.

Condition 1-1 demands that the relational expression “F _re / F _k ” of F _re and the average of dynamic friction forces (hereinafter sometimes referred to as “F _k ”) exceeds 0.45. Yes.
It _{F re} / F _k is 0.45 or less means that _{F re} is too small as compared with _{F k.} In this case, when stopping writing, it becomes very difficult to adjust the pen driving force to near zero, the tip of the pen becomes difficult to stop or the pen feels slipping, and the position and direction as expected. It becomes difficult to change the writing direction. Therefore, when _Fre / _Fk is 0.45 or less, the writing feeling at the time of restart cannot be improved, and a high level writing feeling cannot be imparted.

In addition, when _Fre / _Fk is too large, the load at the time of stopping and restarting writing may be felt heavy. For this reason, from the viewpoint of making the writing feeling at the time of restart better, in condition 1-1, F _re / F _k is preferably 0.60 or more and 1.50 or less, and 0.65 or more and 1. More preferably, it is 40 or less, and further preferably 0.90 or more and 1.35 or less.

In the method for selecting a writable member of the present invention, it is preferable to select one that satisfies the following condition 1-2. By satisfying the condition 1-2, the writing feeling upon restart obtained by satisfying the condition 1-1 can be further improved.
<Condition 1-2>
The average residual friction force is 1.0 gf or more and 25.0 gf or less.

The average residual friction force (F _re ) is more preferably 1.5 gf or more and 23.0 gf or less, and further preferably 2.0 gf or more and 20.0 gf or less.

In the method for selecting a writable member of the present invention, it is preferable to select one that satisfies the following conditions 1-3. By satisfying the condition 1-3, it is possible to easily improve the writing feeling when writing continuously, and to suppress wear of the pen tip.
<Condition 1-3>
The average dynamic friction force is 1.0 gf or more and 32.0 gf or less.

The average dynamic friction force (F _k ) is more preferably 2.0 gf or more and 25.0 gf or less, and further preferably 2.5 gf or more and 15.0 gf or less.

In the method for selecting a writable member of the present invention, it is preferable to select one that satisfies the following conditions 1-4. By satisfying Condition 1-4, it is possible to easily improve the writing feeling when writing continuously, and to suppress wear of the pen tip.
<Condition 1-4>
The standard deviation of dynamic friction force is 0.5gf or more and 18.0gf or less.

The standard deviation of dynamic friction force (hereinafter sometimes referred to as “σF _k ”) is calculated from the dynamic friction force measured every 0.001 seconds. σF _k is more preferably 0.7 gf or more and 10.0 gf or less, and further preferably 1.0 gf or more and 5.0 gf or less.

In the present invention, F _k and F _re are average values when 15 samples are measured once. Further, in the present _{invention, F} re / F _k is the 15 samples was calculated _F re / _{F k} of each sample was measured one time each, a value obtained by averaging the _F re / _{F k} of 20 samples To do. In the present invention, σF _k is a standard deviation when F _k of 60 samples are measured once.

FIG. 3 is a schematic diagram illustrating a method for measuring dynamic friction force and residual friction force.
In FIG. 3, the touch panel pen 200 is fixed by the holder 84 in a state where the touch panel pen 200 is in contact with the writable member 10. A base 85 for placing a weight 83 is attached to the upper portion of the holder 84. A weight 83 is placed on the base 85, and a vertical load is applied to the touch panel pen by the weight. The writable member 10 is fixed on the movable table 82.
When measuring the frictional force, with the touch panel pen fixed as described above, the movable table 82 to which the writable member 10 is fixed is placed on the acute angle direction side (in FIG. 3) between the writable member and the touch panel pen. Move to the right) at a predetermined speed. At this time, a dynamic friction force is generated in the touch panel pen 200 in the moving direction of the movable table 82, and the dynamic friction force for each time can be calculated. Moreover, the residual friction force which is a friction force after completing the movement of the writable member 10 can be measured.
Examples of the apparatus capable of measurement shown in FIG. 3 include trade names HEIDON-18L and HEIDON-14DR manufactured by Shinto Kagaku Co., Ltd.

In the present invention, it is preferable to measure parameters relating to frictional forces such as F _k and F _re as shown in the following (A) to (E).
(A) 0 point correction The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for the touch panel pen at an angle of 60 degrees, and a vertical load of 100 gf is applied to the touch panel pen. In this state (the writable member does not move), it is left to stand for 100 milliseconds, and the frictional force generated in the acute angle direction of the touch panel pen is measured at intervals of 0.001 seconds. The maximum value of the friction force between the measurement time of 1 msec to 100 msec is calculated from all the measurement values of the friction force (measurement values of all friction forces from the friction force of 1 msec to the friction force at the end of the measurement of the residual friction force). The subtracted value is used as the frictional force for each time, and zero correction is performed. The following (C) to (E) are calculated based on the frictional force corrected by 0 points.
(B) Actual measurement time Three times the standard deviation of the frictional force of the measurement time 1 ms to 100 ms before the zero point correction is set as the “threshold value”. After standing for 100 msec in the above (A) and then for 500 msec, the movable table with the writable member fixed at the speed of 14 mm / sec, the acute angle direction side of the angle formed by the writable member and the touch panel pen And the frictional force in the acute angle direction of the touch panel pen is measured at 0.001 second intervals. The time when the threshold value is first exceeded after the start of the movement of the writable member is set as the “measurement start” time.
(C) Maximum friction force F _max
The maximum friction force F _max is calculated from the maximum friction force within 1500 milliseconds from the start of measurement.
(D) Dynamic friction force The time when the maximum friction force _Fmax occurs is _defined as the first peak time.
The average of the frictional force from the time when the actual measurement is started to the time when the movement of the 40 mm length of the writable member is completed is defined as the provisional average frictional force. The time when the first frictional force exceeding [provisional average frictional force + (maximum frictional force × 0.1)] after 30 milliseconds has elapsed from the first peak time is defined as the second peak time.
Measure the dynamic friction force at each time, with the time when 500 msec elapsed from the second peak time as the measurement start time of the dynamic friction force, the time when the movement of the 40 mm length of the writable member is completed as the measurement end time of the dynamic friction force, The average (F _k ) of the dynamic friction force and the standard deviation (σF _k ) of the dynamic friction force can be calculated.
(E) Residual friction force After completing the movement of the 40 mm length of the writable member, the vertical load 100 gf applied to the touch panel pen is held, and the touch panel pen is held at 60 degrees with respect to the surface of the writable member for the touch panel pen. Keep in contact at an angle. In this state, the frictional force (residual frictional force) in the acute angle direction applied to the touch panel pen is measured. The measurement time of the residual friction force is defined as the measurement start time after 500 msec from the completion of the movement of the 40 mm length of the writable member, and the measurement end time after 400 msec. From the residual friction force at each time, an average (F _re ) of the residual friction force is calculated.

  In addition, if oils and fats (for example, a fingerprint component transferred from the human finger to the surface of the writable member) adhere to the surface of the writable member and the pen tip of the touch panel pen, there is a possibility of affecting the frictional force. . For this reason, it is preferable to carry out the measurement of the frictional force so that oils and fats do not adhere to the surface of the writable member and the pen tip of the touch panel pen. In addition, when oils and fats adhere to the surface of the writable member and the pen tip of the touch panel pen, after degreasing the surface of the writable member and the shape and physical properties of the pen tip of the touch panel pen It is preferable to measure the frictional force.

The touch panel pen used for determination of Condition 1-1 and other conditions is not particularly limited, and can be appropriately selected from commercially available touch panel pens.
In addition, when the material of the nib of a touch-panel pen does not fit in the surface unevenness | corrugation of a writable member, it becomes difficult to design the writable member which satisfy | fills conditions 1-1. For this reason, as for the touch-panel pen used for determination of conditions 1-1 etc., it is preferable that a pen point has a certain softness | flexibility. However, if the nib is made of only a flexible material, the nib wears out at the biting portion of the convex part of the film, so the life is shortened or the nib is difficult to separate from the surface irregularities of the writable member. There is a case. Therefore, in the touch panel pen used for determination of the condition 1-1 or the like, it is preferable that the tip end region of the pen has at least two regions. Specifically, it is preferable that the tip region of the pen has at least a region (i) that promotes deformation and a region (ii) that imparts hardness. Further, it is preferable that the region (i) for promoting deformation and the region (ii) for imparting hardness are mixed regularly or randomly. Examples of the configuration in which the region (i) and the region (ii) are mixed include, for example, a porous configuration (the air hole becomes the region (i) that promotes deformation), and a soft material mixed in a hard material. The structure etc. which are are mentioned.
Examples of the region (i) that promotes deformation include air holes, cavities, and soft materials. The Young's modulus of the soft material is preferably 1.0 GPa or less, and more preferably 0.6 GPa or less.
Examples of the region (ii) to which hardness is imparted include materials having a Young's modulus of 1.2 GPa or more. The Young's modulus of the material in the region (ii) to which hardness is imparted is preferably 2.0 GPa or more, and more preferably 2.5 GPa or more. In addition, from the viewpoint of suppressing the wear of the writable member, the Young's modulus of the material for imparting hardness (ii) is preferably 5.0 GPa or less, more preferably 4.0 GPa or less, More preferably, it is 3.5 GPa or less.
The volume ratio of region (i) to region (ii) is preferably 98: 2 to 70:30, more preferably 95: 5 to 75:25, and 90:10 to 80:20. More preferably it is.
The atmosphere at the time of measuring the Young's modulus E is a temperature of 23 ° C. ± 5 ° C. and a humidity of 40 to 65%. Before starting the measurement of Young's modulus E, the measurement sample is left in an atmosphere of 23 ° C. ± 5 ° C. and humidity of 40 to 65% for 10 minutes or more.
The tip region refers to a range within 1.5 mm from the pen tip of the touch panel pen.

Moreover, as for the touchscreen pen used for determination of conditions 1-1 etc., it is preferable that the diameter of a pen point is 0.3-2.5 mm, It is more preferable that it is 0.5-2.0 mm, 0.7 More preferably, it is -1.7 mm.
The diameter D of the pen tip is calculated based on a photograph of the touch panel pen taken from the direction perpendicular to the pen axis. FIG. 4 shows the outline of the touch panel pen displayed as a dotted line when the touch panel pen is imaged from the side perpendicular to the pen axis. As shown in FIG. 4 (a), when a circle that passes through the top of the photograph and does not protrude from the photograph is superimposed on the photograph, the diameter of the largest circle is the diameter D of the pen tip. To do. However, as shown in FIG. 4B, if the photograph has an inclined surface and the angle of the inclined surface with respect to the pen axis is 40 to 90 degrees, the circle may be overlapped by protruding the inclined surface. .

Moreover, as for the selection method of the writable member of this invention, it is preferable to select as a writable member for touch panel pens that satisfy the following conditions 2-1.
<Condition 2-1>
Haze is 25.0% or more

By setting the haze to 25.0% or more, it is possible to easily suppress glare (a phenomenon in which minute variations in luminance are seen in video light).
From the viewpoint of suppressing glare, the haze is more preferably 35.0% or more, and further preferably 45.0% or more. Further, from the viewpoint of suppressing a decrease in resolution of the display element, the haze is preferably 90.0% or less, more preferably 70.0% or less, and 67.0% or less. More preferably, it is more preferably 60.0% or less.
When measuring the haze and the total light transmittance described later, light is incident from the surface opposite to the writing surface of the writable member (the surface satisfying the above condition 1-1). When both surfaces of the writable member are writing surfaces, the light incident surface may be either surface. In this specification, the haze and the total light transmittance are average values when 15 samples are measured once each.

Moreover, it is preferable that the selection method of the writable member of this invention selects what satisfies the following conditions 2-2 as a writable member for touch panel pens.
<Condition 2-2>
JIS K7361-1: 1997 has a total light transmittance of 87.0% or more

By setting the total light transmittance to 87.0% or more, a decrease in luminance of the display element can be suppressed.
The total light transmittance is more preferably 88.0% or more, and further preferably 89.0% or more. In addition, when the total light transmittance is too high, the condition 1-1 tends not to be satisfied. For this reason, the total light transmittance is preferably 92.0% or less, more preferably 91.5% or less, and even more preferably 91.0% or less.

  In addition, if the selection method of the writable member for touch-panel pens of this invention is applied, the touch panel pen suitable for arbitrary writable members can also be selected.

[Writing materials for touch panel pens]
The writable member for a touch panel of the present invention has a surface that satisfies the following condition 1-1.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”.

  Even when the writable member of the present invention is fixed with the touch panel pen in contact with the writing surface at an angle other than 60 degrees (for example, any angle in the range of 30 to 75 degrees), the condition 1- It is preferable to satisfy 1 or the like. The condition 1-1 and the like are also preferably in the above range when the moving speed is set to a speed other than 14 mm / second (for example, any speed in the range of 0.1 to 100 mm / second).

The writable member of the present invention preferably satisfies the following condition 1-2. By satisfying the condition 1-2, the writing feeling upon restart obtained by satisfying the condition 1-1 can be further improved.
<Condition 1-2>
The average residual friction force is 1.0 gf or more and 25.0 gf or less.

The writable member of the present invention preferably satisfies the following conditions 1-3. By satisfying the condition 1-3, it is possible to easily improve the writing feeling when writing continuously, and to suppress wear of the pen tip.
<Condition 1-3>
The average dynamic friction force is 1.0 gf or more and 32.0 gf or less.

The writable member of the present invention preferably satisfies the following conditions 1-4. By satisfying Condition 1-4, it is possible to easily improve the writing feeling when writing continuously, and to suppress wear of the pen tip.
<Condition 1-4>
The standard deviation of the dynamic friction force is 0.5 gf or more and 15.0 gf or less.

  The suitable range of conditions 1-1 to 1-4 of the writable member of the present invention is the same as the preferred range of conditions 1-1 to 1-4 of the above-described method for selecting a writable member for a touch panel pen.

Moreover, in order for the writable member of this invention to satisfy | fill conditions 1-1 etc. easily, the front-end | tip area | region of an area | region (i) which accelerates | stimulates a deformation | transformation at least, and the area | region (ii) which provides hardness It is preferably used as a writable member for a touch panel pen. Specific embodiments of the region (i) for promoting deformation and the region (ii) for imparting hardness are as described above.
Moreover, it is preferable to use the writable member of the present invention as a writable member for a touch panel pen in which the diameter of the pen tip is in the above-described range.

Moreover, it is preferable that the writable member of this invention satisfy | fills the following conditions 2-1.
<Condition 2-1>
JIS K7136: 2000 haze of writable member is 25.0% or more

Moreover, it is preferable that the writable member of this invention satisfy | fills the following conditions 2-2.
<Condition 2-2>
JIS K7361-1: 1997 has a total light transmittance of 87.0% or more

  The suitable range of conditions 2-1 and 2-2 of the writable member of this invention is the same as the suitable range of conditions 2-1 and 2-2 of the selection method of the writable member for touch panel pens mentioned above.

<Configuration of the entire writable member>
The structure of the writable member for a touch panel pen of the present invention is not particularly limited as long as at least one surface satisfies the condition 1-1.
For example, as a structure of the writable member 10 for a touch panel pen of the present invention, as shown in FIGS. 1 and 2, the substrate 1 has a resin layer 2, and one surface of the resin layer 2 has a condition 1− Those satisfying 1 are listed. As shown in FIG. 2, the resin layer 2 may have a multilayer structure of a first resin layer 2a and a second resin layer 2b.
Although not shown, the structure of the writable member 10 for a touch panel pen of the present invention may be a single resin layer that does not have a substrate, or may have other layers other than the substrate and the resin layer. In addition, the surface of the other layer may satisfy the condition 1-1. Examples of other layers include an antistatic layer and an antifouling layer.
The writable member for the touch panel pen may be in the form of a single sheet or may be in the form of a roll obtained by winding a long sheet into a roll. Further, the size of the sheet is not particularly limited, but generally the size is about 2 to 500 inches diagonally. The roll width and length are not particularly limited, but generally the width is about 500 to 3000 mm and the length is about 500 to 5000 m.
Further, the shape of the single wafer is not particularly limited, and may be, for example, a polygon (triangle, quadrangle, pentagon, etc.), a circle, or a random irregular shape.

  The writing surface can be formed by “physical or chemical treatment such as embossing, sand blasting, etching”, “molding with a mold”, “coating” or the like. Among these methods, “molding with a mold” is preferable from the viewpoint of reproducibility of the surface shape, and “coating” is preferable from the viewpoint of productivity and compatibility with various products.

In order for the writable member to satisfy the condition 1-1 or the like, it is preferable that the writing surface of the writable member satisfies the following physical properties (a) to (f).
Note that the cut-off values when calculating Rt, θa, and λa described later are all 0.8 mm. In view of the value of the cutoff, the diameter of the assumed nib is preferably 0.3 to 2.5 mm, more preferably 0.5 to 2.0 mm, and still more preferably 0.7 to 1.7 mm. The cutoff value covering the size of the diameter is selected from the cutoff values specified in JIS.

(A) The maximum sectional height Rt of the roughness curve of JIS B0601: 2001 on the writing surface is 2.5 μm or more and 8.0 μm or less.
(B) The average inclination angle θa of the writing surface is 2.0 degrees or more and 10.0 degrees or less.
(C) The average wavelength λa calculated based on the formula [λa = 2π × (Ra / tan (θa))] from the average inclination angle θa and the arithmetic average roughness Ra of JIS B0601: 2001 is 10 μm or more and 75 μm or less.
(D) The area ratio of the particles on the writing surface is 15.0% or more and 35.0% or less.
(E) The quotient [λa (μm) ÷ particle density (pieces / 100 μm square)] of 14 μm and the λa (μm) and 100 μm square particle density (pieces / 100 μm square) of the writing surface is 14 or more and 1000 or less.
In the present specification, the above (a) to (e) are average values of values obtained from samples of 15 writable members.

In the physical properties (a) to (e), there are not many extremely high and extremely low valleys in the unevenness of the writing surface, there are unevenness of an appropriate size, and the convexity of the writing surface is It means that it is reasonably dense. When the writing surface satisfies the physical properties (a) to (e), the balance between the dynamic friction force and the residual friction force becomes appropriate, and the condition 1-1 and the like can be easily satisfied.
In addition, satisfying the above physical properties (a) to (e) (There are not many extremely high peaks or extremely low valleys in the unevenness of the writing surface, there are unevenness of an appropriate size, and the writing surface. It is preferable that the convex portions of the above are densely packed) because it leads to suppression of glare.
Also, the Rt of (a) should be 8.0 μm or less, the θa of (b) should be 10.0 degrees or less, the λa of (c) should be 75 μm or less, and the area ratio of (d) Setting it to 15.0% or more and setting the quotient of (e) to 1000 or less are preferable in that it leads to suppression of wear of the pen tip of the touch panel pen. In particular, by setting λa in (c) to 75 μm or less and setting the quotient in (e) to 1000 or less, wear of the pen tip of the touch panel pen can be significantly suppressed.

Rt in the above (a) is more preferably 2.8 μm or more and 6.0 μm or less, and further preferably 3.0 μm or more and 4.5 μm or less.
The θa in the above (b) is more preferably 3.0 degrees or more and 8.0 degrees or less, and more preferably 4.0 degrees or more and 7.0 degrees or less.
Λa in the above (c) is more preferably 15 μm or more and 50 μm or less, and further preferably 20 μm or more and 35 μm or less.
The area ratio of (d) is more preferably 18.0% or more and 32.0% or less, and further preferably 20.0% or more and 30.0% or less.
The quotient (e) is more preferably 16 or more and 200 or less, and further preferably 20 or more and 50 or less.

The “average inclination angle θa” in the above (b) is a value defined in the instruction manual (revised 1995.07.20) of the surface roughness measuring instrument (trade name: SE-3400) manufactured by Kosaka Laboratory. As shown in FIG. 5, the arc tangent of the sum of the amount of change in the height direction within the reference length L (h ₁ + h ₂ + h ₃ +... + H _n ) divided by the reference length L θa = tan ⁻¹ {(h ₁ + h ₂ + h ₃ +... + h _n ) / L}. In this specification, the reference length is divided into 1500 to obtain 1500 points of height data, and the average inclination angle θa is calculated based on the 1500 points of height data.

  The particle area ratio of (d) above is calculated by binarizing a gray scale image by image analysis software from a plane photograph of the writing surface by a scanning electron microscope (SEM) and selecting the particle portion. Can do. Further, the particle density of 100 μm square (number / 100 μm square) of the writing surface from which (e) is calculated is counted as the number of regions where the particle portions of the binarized image are independent as described above. This can be calculated. As image analysis software, for example, trade name WinRoof manufactured by Mitani Corporation is listed.

  Further, the writing member of the present invention has a pencil hardness of JIS K5600-5-4: 1999 of 2H or more and 9H or less from the viewpoint of suppressing wear of the touch panel pen while improving the scratch resistance of the writing surface. It is preferably 3H or more and 7H or less, more preferably 5H or more and 6H or less.

The resin layer is formed by coating by applying, drying and curing a resin layer-forming coating solution containing a resin component, particles and a solvent on a substrate by a known coating method such as gravure coating or bar coating. Can be formed. In order for the resin layer formed by coating to easily satisfy the condition 1-1 and the like, it is preferable that the average particle diameter of the particles, the content of the particles, the thickness of the resin layer, and the like are in the ranges described below.
In addition, as shown in FIG. 2, when the resin layer is formed of two or more layers, it is sufficient that at least one of the resin layers contains particles, but from the viewpoint of easily satisfying the condition 1-1 and the like. The outermost resin layer preferably contains particles. Moreover, the pencil hardness of a writing surface can be easily improved by setting it as the structure in which the resin layer of the outermost surface contains particle | grains and the lower layer resin layer does not contain particle | grains.

Both organic particles and inorganic particles can be used as the particles of the resin layer. Examples of the organic particles include particles made of polymethyl methacrylate, polyacryl-styrene copolymer, melamine resin, polycarbonate, polystyrene, polyvinyl chloride, benzoguanamine-melamine-formaldehyde condensate, silicone, fluorine resin, and polyester resin. Can be mentioned. Examples of the inorganic particles include particles made of silica, alumina, antimony, zirconia, titania and the like. Among these particles, the organic particles are preferable in that they easily suppress the aggregation of the particles and easily satisfy the condition 1-1.
Moreover, it is preferable that a particle | grain is a spherical particle from a viewpoint of the abrasion suppression of the nib of a touch-panel pen.

Although the average particle diameter of the particles in the resin layer varies depending on the thickness of the resin layer, it cannot be said unconditionally. However, from the viewpoint of easily satisfying the conditions 1-1 and the like, 1.0 to 10.0 μm is preferable, and 1.5 More preferably, it is -5.0 micrometers, and it is still more preferable that it is 1.8-3.5 micrometers. When the particles are aggregated, the average particle diameter of the aggregated particles preferably satisfies the above range.
The average particle diameter of the particles can be calculated by the following operations (y1) to (y3).
(Y1) A transmission observation image of the writable member of the present invention is taken with an optical microscope. The magnification is preferably 500 to 2000 times.
(Y2) Arbitrary 10 particles are extracted from the observation image, and the particle diameter of each particle is calculated. The particle diameter is measured as a distance between straight lines in a combination of two straight lines that maximizes the distance between the two straight lines when the cross section of the particle is sandwiched between two parallel straight lines.
(Y3) The same operation is performed five times on the observation image of another screen of the same sample, and the value obtained from the number average of the particle diameters for a total of 50 particles is taken as the average particle diameter of the particles in the resin layer.

  Even if the particles have a wide particle size distribution (single particles with a wide particle size distribution, or mixed particles obtained by mixing two or more types of particles having different particle size distributions). However, from the viewpoint of suppressing glare, it is preferable that the particle size distribution is narrow. Specifically, the variation coefficient of the particle size distribution of the particles is preferably 25% or less, more preferably 20% or less, and further preferably 15% or less.

  The content of the particles in the resin layer is preferably 10 to 30 parts by mass, and 12 to 25 parts by mass with respect to 100 parts by mass of the resin component from the viewpoint of easily satisfying the condition 1-1. Is more preferable, and it is still more preferable that it is 15-20 mass parts.

The preferable range of the film thickness of the resin layer varies slightly depending on the embodiment of the resin layer. For example, the thickness of the resin layer containing particles is preferably 2.0 to 8.0 μm, from the viewpoint of easily satisfying the condition 1-1 and the like, from the viewpoint of improving the pencil hardness of the writing surface, and from the viewpoint of curling. The thickness is more preferably from 2 to 6.0 μm, further preferably from 2.5 to 4.0 μm.
Further, from the viewpoint of easily satisfying the condition 1-1 and the like, the ratio of [average particle diameter of particles] / [film thickness of resin layer containing particles] is preferably 0.7 to 1.3. Is more preferably 0.8 to 1.2, and still more preferably 0.8 to 1.0.
The resin layer not containing particles is preferably located closer to the substrate than the resin layer containing particles, and the thickness is 3.0 to from the viewpoint of improving the pencil hardness of the writing surface and suppressing curling. It is preferable to set it as 15.0 micrometers, and it is more preferable to set it as 6.0-10.0 micrometers.
The film thickness of the resin layer is calculated, for example, by measuring the thickness at 20 locations from a cross-sectional image taken using a scanning transmission electron microscope (STEM) and calculating the average value of the 20 locations. it can. The STEM acceleration voltage is preferably 10 kv to 30 kV, and the STEM magnification is preferably 1000 to 7000 times.

  The resin component of the resin layer preferably contains a cured product of a thermosetting resin composition or an ionizing radiation curable resin composition, and from the viewpoint of improving the pencil hardness of the writing surface, the ionizing radiation curable resin composition is cured. It is more preferable that the product contains an ultraviolet curable resin composition.

The thermosetting resin composition is a composition containing at least a thermosetting resin, and is a resin composition that is cured by heating.
Examples of the thermosetting resin include acrylic resin, urethane resin, phenol resin, urea melamine resin, epoxy resin, unsaturated polyester resin, and silicone resin. In the thermosetting resin composition, a curing agent is added to these curable resins as necessary.

The ionizing radiation curable resin composition is a composition containing a compound having an ionizing radiation curable functional group (hereinafter also referred to as “ionizing radiation curable compound”). Examples of the ionizing radiation curable functional group include an ethylenically unsaturated bond group such as a (meth) acryloyl group, a vinyl group, and an allyl group, an epoxy group, and an oxetanyl group. As the ionizing radiation curable compound, a compound having an ethylenically unsaturated bond group is preferable, a compound having two or more ethylenic unsaturated bond groups is more preferable, and among them, having two or more ethylenically unsaturated bond groups, Polyfunctional (meth) acrylate compounds are more preferred. As the polyfunctional (meth) acrylate compound, any of a monomer and an oligomer can be used.
The ionizing radiation means an electromagnetic wave or a charged particle beam having an energy quantum capable of polymerizing or cross-linking molecules, and usually ultraviolet (UV) or electron beam (EB) is used. Electromagnetic waves such as X-rays and γ-rays, and charged particle beams such as α-rays and ion beams can also be used.

Among the polyfunctional (meth) acrylate compounds, bifunctional (meth) acrylate monomers include ethylene glycol di (meth) acrylate, bisphenol A tetraethoxydiacrylate, bisphenol A tetrapropoxydiacrylate, 1,6-hexane. Examples thereof include diol diacrylate.
Examples of the tri- or higher functional (meth) acrylate monomer include trimethylolpropane tri (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol hexa (meth) acrylate, di Examples include pentaerythritol tetra (meth) acrylate and isocyanuric acid-modified tri (meth) acrylate.
The (meth) acrylate-based monomer may be modified by partially modifying the molecular skeleton, and is modified with ethylene oxide, propylene oxide, caprolactone, isocyanuric acid, alkyl, cyclic alkyl, aromatic, bisphenol, or the like. Can also be used.

Moreover, examples of the polyfunctional (meth) acrylate oligomer include acrylate polymers such as urethane (meth) acrylate, epoxy (meth) acrylate, polyester (meth) acrylate, and polyether (meth) acrylate.
Urethane (meth) acrylate is obtained by reaction of polyhydric alcohol and organic diisocyanate with hydroxy (meth) acrylate, for example.
A preferable epoxy (meth) acrylate is a (meth) acrylate obtained by reacting (meth) acrylic acid with a tri- or higher functional aromatic epoxy resin, alicyclic epoxy resin, aliphatic epoxy resin or the like. (Meth) acrylates obtained by reacting the above aromatic epoxy resins, alicyclic epoxy resins, aliphatic epoxy resins and the like with polybasic acids and (meth) acrylic acid, and bifunctional or higher functional aromatic epoxy resins, It is a (meth) acrylate obtained by reacting an alicyclic epoxy resin, an aliphatic epoxy resin or the like with a phenol and (meth) acrylic acid.
The ionizing radiation curable compounds can be used alone or in combination of two or more.

When the ionizing radiation curable compound is an ultraviolet curable compound, the ionizing radiation curable composition preferably contains additives such as a photopolymerization initiator and a photopolymerization accelerator.
Examples of the photopolymerization initiator include one or more selected from acetophenone, benzophenone, α-hydroxyalkylphenone, Michler's ketone, benzoin, benzylmethyl ketal, benzoylbenzoate, α-acyloxime ester, thioxanthones, and the like.
These photopolymerization initiators preferably have a melting point of 100 ° C. or higher. By setting the melting point of the photopolymerization initiator to 100 ° C. or higher, the remaining photopolymerization initiator sublimates in the manufacturing process of the writable member and the transparent conductive film of the touch panel, and the manufacturing apparatus and the transparent conductive film Contamination can be prevented.
The photopolymerization accelerator can reduce polymerization inhibition by air during curing and increase the curing speed. For example, p-dimethylaminobenzoic acid isoamyl ester, p-dimethylaminobenzoic acid ethyl ester, etc. One or more selected may be mentioned.

In the resin layer forming coating solution, a solvent is usually used in order to adjust the viscosity and to dissolve or disperse each component. Since the surface state of the resin layer after the coating and drying process varies depending on the type of solvent, it is preferable to select the solvent in consideration of the saturated vapor pressure of the solvent, the permeability of the solvent into the transparent substrate, and the like. Specifically, the solvent is, for example, ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), ethers (dioxane, tetrahydrofuran, etc.), aliphatic hydrocarbons (hexane, etc.), alicyclic hydrocarbons. (Cyclohexane, etc.), aromatic hydrocarbons (toluene, xylene, etc.), halogenated carbons (dichloromethane, dichloroethane, etc.), esters (methyl acetate, ethyl acetate, butyl acetate, etc.), alcohols (butanol, cyclohexanol, etc.) ), Cellosolves (methyl cellosolve, ethyl cellosolve, etc.), cellosolve acetates, sulfoxides (dimethyl sulfoxide, etc.), amides (dimethylformamide, dimethylacetamide, etc.), etc., and mixtures thereof may be used.
When the drying of the solvent is too slow, the leveling property of the resin layer becomes excessive, so that it becomes difficult to form a surface shape that easily satisfies the condition 1-1. Accordingly, the solvent preferably contains 70% by mass or more of a solvent having an evaporation rate (relative evaporation rate when the evaporation rate of n-butyl acetate is 100) of 180 or more, and 80% by mass. More preferably included. An example of the solvent having a relative evaporation rate of 180 or more includes toluene. The relative evaporation rate of toluene is 195. On the other hand, examples of the solvent having a relative evaporation rate of less than 180 include methyl isobutyl ketone (MIBK), propylene glycol monomethyl ether acetate (PMA), and isopropyl alcohol (IPA).

  Further, from the viewpoint of making the surface shape moderately smooth and making the surface shape of the writable member easily within the above-mentioned range, it is preferable to contain a leveling agent in the resin layer forming coating solution. Examples of the leveling agent include a fluorine-based leveling agent, a silicone-based leveling agent, and a fluorosilicone copolymer-based leveling agent. The addition amount of the leveling agent is preferably 0.01 to 0.50% by weight, more preferably 0.10 to 0.40% by weight, and more preferably 0.20 to 0% with respect to the total solid content of the resin layer forming coating solution. More preferably, it is 30% by mass.

As a base material, the base material which has a light transmittance is preferable, A plastic film, glass, etc. are mentioned, A plastic film is suitable.
Plastic film is polyester, triacetyl cellulose (TAC), cellulose diacetate, cellulose acetate butyrate, polyamide, polyimide, polyether sulfone, polysulfone, polypropylene, polymethylpentene, polyvinyl chloride, polyvinyl acetal, polyether ketone, It can be formed from resin such as polymethyl methacrylate, polycarbonate, polyurethane, and amorphous olefin (Cyclo-Olefin-Polymer: COP).
Among these plastic films, from the viewpoint of easily satisfying the mechanical strength, dimensional stability, and the above physical property (f), a stretched polyester film, particularly a biaxially stretched polyester film is preferable. Among the polyester films, polyethylene terephthalate and polyethylene naphthalate are preferable.
The thickness of the base material is preferably 5 to 200 μm, and more preferably 10 to 150 μm.

[Touch panel]
The touch panel of the present invention is a touch panel having a writable member on the surface, and the surface on the side satisfying the condition 1-1 of the writable member for touch panel pen of the present invention faces the surface of the touch panel as the writable member. It is arranged in.

  Examples of the touch panel include a resistive touch panel, a capacitive touch panel, an in-cell touch panel, an optical touch panel, an ultrasonic touch panel, and an electromagnetic induction touch panel.

As shown in FIG. 6, the resistive touch panel 100 is not shown in a basic configuration in which a conductive film 30 of a pair of upper and lower transparent substrates 20 having a conductive film 30 is disposed through a spacer 40 so as to face each other. A circuit is connected.
In the case of the resistive film type touch panel, for example, the writable member 10 of the present invention is used as the upper transparent substrate 20 and the side satisfying the condition 1-1 of the writable member 10 is used so as to face the surface of the touch panel 100. A configuration is mentioned. Although not shown, the resistive touch panel has a configuration in which the writable member of the present invention is bonded onto the upper transparent substrate so that the surface satisfying the condition 1-1 faces the surface, or the upper transparent substrate. The writable member of the present invention may be placed on the substrate so that the surface satisfying the condition 1-1 faces the surface and fixed with a frame or the like.

The capacitive touch panel includes a surface type and a projection type, and a projection type is often used. A projected capacitive touch panel is configured by connecting a circuit to a basic configuration in which an X-axis electrode and a Y-axis electrode orthogonal to the X-axis electrode are arranged via an insulator. The basic configuration will be described more specifically. A mode in which X-axis electrodes and Y-axis electrodes are formed on separate surfaces on a single transparent substrate, and an X-axis electrode, an insulator layer, and a Y-axis electrode are formed on the transparent substrate. In this embodiment, as shown in FIG. 7, an X-axis electrode 50 is formed on a transparent substrate 20, a Y-axis electrode 60 is formed on another transparent substrate 20, and an insulator layer such as an adhesive layer The aspect of laminating | stacking via 70 is mentioned. Moreover, the aspect which laminate | stacks another transparent substrate in these basic aspects is mentioned.
In the case of a capacitive touch panel, for example, the writable member 10 of the present invention is used as the transparent substrate 20 on the surface side, and the surface satisfying the condition 1-1 of the writable member 10 faces the surface of the touch panel 100. The structure used is mentioned. Although not shown, the capacitive touch panel has a configuration in which the writable member of the present invention is bonded onto the transparent substrate on the surface side so that the surface satisfying the condition 1-1 faces the surface. The writable member of the present invention may be placed on the transparent substrate on the surface side so that the surface satisfying the condition 1-1 faces the surface and fixed with a frame or the like.

An electromagnetic induction touch panel is a touch panel that uses a dedicated pen that generates a magnetic field. The electromagnetic induction touch panel has at least a sensor unit that detects electromagnetic energy generated from the pen, and further includes a transparent substrate on the sensor unit. The transparent substrate may have a multilayer structure.
In the case of an electromagnetic induction touch panel, for example, among the transparent substrates positioned on the sensor unit, the surface on the side satisfying the condition 1-1 of the writable member using the writable member of the present invention as the outermost transparent substrate. There is a configuration in which the touch panel is used so as to face the surface of the touch panel. Or in the case of an electromagnetic induction type touch panel, the surface on the side satisfying the condition 1-1 is directed to the writable member of the present invention on the outermost transparent substrate among the transparent substrates positioned on the sensor unit. Then, the writable member of the present invention was placed on the outermost transparent substrate so that the surface satisfying the condition 1-1 faced the surface and fixed with a frame or the like. It may be a configuration.

The in-cell touch panel incorporates a touch panel function such as a resistance film type, a capacitance type, and an optical type inside a liquid crystal element in which a liquid crystal is sandwiched between two glass substrates.
In the case of the in-cell touch panel, it is used by being arranged on the surface side glass substrate so that the surface on the side satisfying the condition 1-1 of the writable member of the present invention faces the surface of the touch panel. In addition, you may have other layers, such as a polarizing plate, between the glass substrate of the surface side of an in-cell touch panel, and the writable member of this invention.

[Touch panel system]
The touch panel system of the present invention is a touch panel system including a touch panel having a writable member for a touch panel pen on the surface and a touch panel pen, and satisfies the following condition 1-1.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”.

Embodiments of the touch panel, the writable member for touch panel pen, and the touch panel pen in the touch panel system of the present invention include, for example, the above-described selection method for the writable member for touch panel pen, the writable member for touch panel pen, and The thing similar to embodiment shown in the touch panel is mentioned.
According to the touch panel system of the present invention, it is possible to improve the writing feeling at the time of restarting, and to give a high level writing feeling.

[Display device with touch panel]
The display device with a touch panel of the present invention is a display device having a touch panel on a display element, and the touch panel is the touch panel of the present invention.

Examples of the display element include a liquid crystal display element, an EL display element, a plasma display element, and an electronic paper element. When the display element is a liquid crystal display element, an EL display element, a plasma display element, or an electronic paper element, the touch panel of the present invention is placed on these display elements.
The display device with a touch panel of the present invention can improve the writing feeling at the time of restarting, and thus can provide a high level of writing feeling.

  EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited at all by this example. “Part” is based on mass.

1. Measurement and Evaluation The following measurement and evaluation were performed on the writable member for a touch panel pen prepared or prepared in the experimental example.

1-1. Using the trade name “HEIDON-14DR” manufactured by Shinto Kagaku Co. as a frictional force measuring device, as shown in FIG. 3, the following touch panel pens 1 and 2 are placed on the surface of the writable member for touch panel pens on the resin layer side. The contact was made at an angle of 60 degrees and fixed with a holding tool. A weight of 100 g was placed on the base at the top of the holder so that a vertical load of 100 gf was applied to the touch panel pen. While the load was applied, the movable base on which the writable member was fixed was moved at a speed of 14 mm / second to the acute angle direction side (right side in FIG. 3) formed by the movable base and the touch panel pen. The frictional force in the moving direction of the movable base (the acute angle direction of the pen) when moving the length of 40 mm on one way was measured. Further, after the movement of the movable table, the vertical load applied to the touch panel pen is released while the touch panel pen is kept in contact with the surface of the writable member at an angle of 60 degrees. the residual friction force F _re in the moving direction (the pen acute angle direction) was measured.
The sampling time (measurement interval) was 0.001 second, and the atmosphere during the measurement was a temperature of 23 ° C. ± 5 ° C. and a humidity of 40 to 65%. Before starting the measurement, each sample was left in an atmosphere of 23 ° C. ± 5 ° C. and humidity of 40 to 65% for 10 minutes or more. Other analysis conditions are shown below.
Based on the measured results, the residual friction force average (F _re ), dynamic friction force average (F _k ), and dynamic friction force standard deviation (σF _k ) according to the above-described procedures (A) to (E). Was calculated. Furthermore, “F _re / F _k ” of Condition 1-1 was calculated from the obtained F _re and F _k .
Incidentally, F _re and F _k for each of the experimental examples were the mean value when measured one time each 15 samples. In addition, σF _{k of} each experimental example is a standard deviation when 60 samples are measured once each. In addition, F _re / F _k of each experimental example was _obtained by measuring 15 samples once, calculating F _re / F _k of each sample, and _obtaining the average value of F _re / F _k of 15 samples. . The results are shown in Table 1.
<Analysis conditions, etc.>
・ Measurement software name: TriboSoft35 (version: Tribosoft3.59)
・ Mode: Constant load measurement ・ Load transducer capacity: 2000 gf
・ DAS ampoule range: 50%
・ Vertical load: 100g
・ Sampling capacity: 5500 units ・ Unit system: CGS
・ One way measurement mode ・ FEED SCALE 40mm
-POLARITY: OFF
・ FILTER: PASS
・ RANGE: 50% FS
-Load cell calibration (input of zero and span values): Analog dial setting

<Touch panel pen 1>
・ Touch panel pen attached to the product name “Dynabook Tab S68” manufactured by Toshiba Corporation ・ Configuration of tip region: Air holes (acceleration of deformation) in an aggregate of polyester fibers (region (ii) to which hardness is imparted) Young's modulus of complex / region (ii) in which region (i)) is mixed: 3.0 GPa
-Volume ratio of region (i) to region (ii) is about 95: 5
・ Pen tip diameter: 1.5mm
<Touch panel pen 2>
-BB-2 pen attached to the brand name "Boogie Board" manufactured by King Jim Co., Ltd.-Composition of tip region: Bulk of polyester acetate resin-Diameter of nib: 1.6 mm

1-2. Written feeling The surface on the opposite side of the surface of the writable member for touch panel pens is bonded to a glass plate via an optically transparent adhesive sheet (thickness: 100 μm) manufactured by Toray Industries, Ltd. Used to evaluate the writing feeling. The action at the time of evaluating the writing feeling was set to an action including many actions to change direction after stopping writing for a moment. Twenty people evaluated 20 points with overall good writing feeling, 1 point with normal writing feeling as a whole, and 0 points with poor writing feeling as a whole. The average score of 20 people is AA when the score is 1.8 points or more, A when the score is 1.6 points or more and less than 1.8 points, B when the average score is 1.2 points or more and less than 1.6 points, 1.0 point Those with less than 1.2 points were designated as C, and those with less than 1.0 points were designated as D.
The atmosphere during the evaluation was set to a temperature of 23 ° C. ± 5 ° C. and a humidity of 40 to 65%. Before starting the evaluation, each sample was left in an atmosphere of 23 ° C. ± 5 ° C. and humidity of 40 to 65% for 10 minutes or more.

1-3. As shown in FIG. 3, the touch panel pens 1 and 2 are attached to the surface of the writable member for the touch panel pen as shown in FIG. 3 using the product name “HEIDON-14DR” manufactured by Shinto Kagaku Co., Ltd. The contact was made at an angle of 60 degrees and fixed with a holding tool. A weight of 200 g was placed on the base of the upper part of the holder so that a vertical load of 200 gf was applied to the touch panel pen. The operation of reciprocating the length of 40 mm one way at a speed of 14 mm / second was repeated 200 times while the load was applied. The temperature at the time of evaluation was 23 ± 5 ° C. The relative humidity was 40 to 65%.
The evaluation criteria are (i) that the change in dynamic friction force during measurement is 40% or less with respect to the initial dynamic friction force, and (ii) that the wear of the pen tip of the touch panel pen cannot be easily confirmed visually. Those satisfying (i) and (ii) are “A”, those not satisfying any of (i) and (ii) are “B”, and those not satisfying any of (i) and (ii) are “C” " The results are shown in Table 1.

1-4. Measurement of surface shape The writable member for the touch panel of the experimental example was cut into a 10 cm square. The cut part was selected from random parts after visually confirming that there were no abnormal points such as dust and scratches. The cut writable member is passed through an optically transparent adhesive sheet (refractive index: 1.47, thickness 100 μm) manufactured by Toray Industries, Inc., and a black plate (Kuraray Co., Ltd., trade name: Comoglass) 15 samples prepared by bonding DFA502K, thickness 2.0 mm) were prepared.
Using a surface roughness measuring instrument (model number: SE-3400 / manufactured by Kosaka Laboratory Co., Ltd.), set the sample so that the sample is fixed and in close contact with the measurement stage, and then measure according to the following measurement conditions. About the item, the surface shape by the side of the resin layer of the writable member for touchscreen pens of each sample was measured. And the average value of 15 samples was made into Rt, (theta) a, and (lambda) a of each experiment example. The atmosphere during the measurement was set to a temperature of 23 ° C. ± 5 ° C. and a humidity of 40 to 65%. Further, before starting the measurement, each sample was left in an atmosphere of 23 ° C. ± 5 ° C. and humidity of 40 to 65% for 10 minutes or more. The results are shown in Table 2.
<Measurement conditions>
[Surface probe for surface roughness detection]
Product name SE2555N manufactured by Kosaka Laboratory Ltd. (tip radius of curvature: 2 μm, apex angle: 90 degrees, material: diamond)
[Measurement conditions of surface roughness measuring instrument]
・ Evaluation length: 5 times the cutoff value λc ・ Preliminary length: 0.5 times the cutoff value λc ・ Feeding speed of stylus: 0.5 mm / s
・ Vertical magnification: 2000 times ・ Skid: Not used (no contact with measurement surface)
Cut-off filter type: Gaussian Leveling: All data Sampling mode: c = 1500
-Dead band level: 10%
Tp / PC curve: Normal <measurement item>
・ Maximum section height Rt of roughness curve of JIS B0601: 2001 with cut-off value 0.8mm
・ Average inclination angle θa with cut-off value 0.8mm
・ Average wavelength λa with cutoff value 0.8mm

1-5. Particle Area Ratio, Particle Density Fifteen samples were prepared by cutting the touch panel writable member of the experimental example into 5 cm squares. Fifteen sites were selected from random sites after visually confirming that there were no abnormal points such as dust or scratches. The particle area ratio and particle density were calculated by the following procedures (1) and (2), and the average value of 15 samples was defined as the particle area ratio and particle density of each experimental example. The results are shown in Table 2.
(1) Imaging of SEM plane photograph Using a digital scanning electron microscope (model number: S-4800) manufactured by Hitachi Kyowa Engineering Co., Ltd., writing at a magnification of 50000 times (acceleration voltage 30.0 kV, emission current 10 μA). An SEM plane photograph of the surface of the conductive member was taken.
(2) Calculation of area ratio and particle density From digital data of SEM photograph, image binarization is performed using image analysis software (trade name: Win Roof, manufactured by Mitani Corporation), and a particle portion is selected. The area ratio (%) of particles and the particle density (pieces / 100 μm square) were calculated.

1-6. Haze, total light transmittance Using a haze meter (HM-150, manufactured by Murakami Color Research Laboratory), haze (JIS K-7136: 2000) and total light of each sample prepared in the above “1-5”. The transmittance (JIS K7361-1: 1997) was measured. And the average value of 15 samples was made into the haze and total light transmittance of each experiment example. The atmosphere during the measurement was set to a temperature of 23 ° C. ± 5 ° C. and a humidity of 40 to 65%. Further, before starting the measurement, each sample was left in an atmosphere of 23 ° C. ± 5 ° C. and humidity of 40 to 65% for 10 minutes or more. The light incident surface was the substrate side. The results are shown in Table 2.

1-7. Glitter The writable member for touch panel pens of Experimental Examples 1 to 4 is placed on a commercially available ultra-high-definition liquid crystal display device (Sharp smartphone, product name: SH-03G, pixel density 480 ppi), and the glare state Was visually evaluated. Twenty people evaluated it as “2 points where glare is invisible, 1 point where glare is slightly observed but 1 point is not noticeable, and 0 points where glare is severely observed”. . 20 people have an average score of 1.8 points or more, A, 1.6 points to less than 1.8 points, B, 1.0 to less than 1.6 points, C, less than 1.0 points Was designated D. The results are shown in Table 2.

2. Manufacture of writable member for touch panel pen [Experiment 1]
A polyethylene terephthalate film (thickness 100 μm, manufactured by Toyobo Co., Ltd., trade name A4300) is used as a substrate, and the first resin layer coating solution 1 having the following formulation is applied on the substrate so that the thickness after drying is 8 μm. The first resin layer is formed by drying and ultraviolet irradiation, and then the second resin layer coating solution 2 having the following formulation is applied onto the first resin layer so that the thickness after drying is 3 μm, drying, and ultraviolet Irradiated to form a second resin layer to obtain a writable member for a touch panel pen.

<First resin layer coating solution 1>
・ Pentaerythritol triacrylate 60 parts ・ Dipentaerythritol hexaacrylate 40 parts ・ Photopolymerization initiator 4 parts (BASF, trade name: Irgacure 184)
・ Solvent 1 (methyl isobutyl ketone) 90 parts ・ Solvent 2 (methyl ethyl ketone) 10 parts

<Second resin layer coating solution 2>
・ Acrylic monomer 100 parts ・ Organic particles 20 parts (spherical polystyrene particles, average particle size 3.0 μm)
-Photopolymerization initiator 5 parts (BASF, Irgacure 184)
Silicone leveling agent 0.3 parts (Momentive Performance Materials, TSF4460)
・ Solvent 1 (toluene) 90 parts ・ Solvent 2 (MIBK) 10 parts

[Experiment 2]
A triacetyl cellulose resin film (thickness 80 μm, manufactured by Fuji Film Co., Ltd., TD80UL) is used as a base material, and a resin layer coating solution 3 having the following formulation is applied on the base material so that the thickness after drying is 2.5 μm. Then, drying and ultraviolet irradiation were performed to form a resin layer, and a writable member for a touch panel pen was obtained.

<Resin layer coating solution 3>
・ 100 parts of pentaerythritol triacrylate (manufactured by Nippon Kayaku Co., Ltd., KAYARAD-PET-30)
・ Inorganic particles 15 parts (Fuji Silysia Chemical Ltd., amorphous silica)
(Hydrophobic treatment: silane coupling agent, average aggregated particle size 2 μm)
-Photopolymerization initiator 5 parts (BASF, Irgacure 184)
・ 0.2 parts of silicone leveling agent (TSF4460 manufactured by Momentive Performance Materials)
-2 parts release agent (manufactured by Daikin Industries, Ltd., OPTOOL DAC)
・ Solvent 1 (toluene) 90 parts ・ Solvent 2 (MIBK) 10 parts

[Experiment 3]
Using a triacetyl cellulose resin film having a thickness of 40 μm as a base material, a resin layer coating solution 4 having the following formulation is applied onto the base material so that the thickness after drying is 7 μm, dried, and irradiated with ultraviolet rays to form a resin layer. And a writable member for a touch panel pen was obtained.

<Resin layer coating solution 4>
・ 100 parts of pentaerythritol triacrylate (manufactured by Nippon Kayaku Co., Ltd., KAYARAD-PET-30)
・ 11 parts of organic particles (spherical polystyrene, average particle size 3.5 μm)
・ 7 parts of fumed silica (average primary particle size 10 nm)
Photopolymerization initiator 3 parts (BASF, Irgacure 184)
・ Silicon-based leveling agent 0.125 parts (Momentive Performance Materials, TSF4460)
・ Solvent 1 (toluene) 65 parts ・ Solvent 2 (PMA) 10 parts ・ Solvent 3 (isopropyl alcohol) 25 parts

[Experimental Example 4]
As a writable member for touch panel pen of Experimental Example 4, a surface film of a commercially available touch panel having a resin layer containing particles (particle size: about 7 to 13 μm) on a polyethylene terephthalate film (product name: Friction Sheet DPTA, manufactured by Sony Corporation) -OSF1) was prepared.

As shown in Table 1, the writing performance of the writable member satisfying the condition 1-1 is A or more. This indicates that selecting a writable member satisfying the condition 1-1 leads to selection of a writable member having good writing feeling. The pen 1 has a gap while the pen 2 is a bulk having no gap, and the pen 1 and the pen 2 are completely different in type. Therefore, even if the result of Table 1 is a case where the kind of touch-panel pens differ, selecting the writable member which satisfy | fills conditions 1-1 will lead to selection of the writable member with favorable writing feeling. Show.
Furthermore, from the results in Table 1, the pen tip region has a touch panel pen (pen 1) having a region (i) for promoting deformation and a region (ii) for imparting hardness, and various physical properties such as λa. It can be confirmed that the combination with the writable member which is a preferred range in the specification is an effective combination for improving the writing feeling.

Further, from the results of Table 1, when the conditions 1-4 are satisfied and the physical properties (λa, etc.) of the writable member are within a suitable range in the specification, the pen tip is improved while improving the writing feeling. It can be confirmed that it is extremely excellent in suppressing wear.
Further, from the results of Tables 1 and 2, λa, particle area ratio, λa ÷ particle density and haze are suitable ranges in the specification (the writing members of Experimental Examples 1 and 2) are: It can be confirmed that it is easy to improve the writing feeling and is extremely excellent in suppressing glare.

3. Production of Touch Panel An ITO conductive film having a thickness of 20 nm was formed on the base material side surface of the writable member for touch panel pens of Experimental Examples 1 to 4 by a sputtering method to obtain an upper electrode plate. Next, an ITO conductive film having a thickness of about 20 nm was formed by sputtering on one surface of a 1 mm thick tempered glass plate to obtain a lower electrode plate. Next, ionizing radiation curable resin (Dot Cure TR5903: Taiyo Ink Co., Ltd.) is printed on the surface of the lower electrode plate having the conductive film as a coating solution for spacers in the form of dots by the screen printing method. Irradiation was performed, and spacers having a diameter of 50 μm and a height of 8 μm were arranged at intervals of 1 mm.
Next, the upper electrode plate and the lower electrode plate are arranged so that the conductive films face each other, and the edges are bonded with a double-sided adhesive tape having a thickness of 30 μm and a width of 3 mm. Produced.
When writing on the resistive touch panels of Experimental Examples 1 to 4 with the touch panel pens 1 and 2, the evaluation of the writing feeling at the time of restarting each touch panel pen was the same as in Table 1. This result has shown that in the touch panel system which consists of a combination of a touch panel and a touch panel pen, the touch panel system satisfying the condition 1-1 has a good writing feeling at the time of restart.

4). Production of display device The writing material for touch panel pens of Experimental Examples 1 to 4 and a commercially available ultra-high-definition liquid crystal display device (sharp smartphone, product name: SH-03G, pixel density 480 ppi), transparent adhesive The display devices of Experimental Examples 1 to 4 were manufactured. In addition, in the case of bonding, the surface by the side of the base material of the writable member for touch-panel pens was made to face the display element side.
When writing with the touch panel pens 1 and 2 on the display devices of Experimental Examples 1 to 4, the evaluation of the writing feeling of each touch panel pen was the same as in Table 1.

  The method for selecting a writable member for a touch panel pen of the present invention is useful in that the product design and quality control of the writable member can be efficiently performed. In addition, the writable member for a touch panel pen, touch panel, touch panel system and display device of the present invention are useful in that the touch feeling at the time of restarting the touch panel pen can be improved, and thus a high level of writing feeling can be imparted. .

1: Base material 2: Resin layer 10: Writable member for touch panel pen 20: Transparent substrate 30: Conductive film 40: Spacer 50: X-axis electrode 60: Y-axis electrode 70: Insulator layer 82: Movable table 83: Weight 84 : Holding tool 85: Base 100: Touch panel 200: Touch panel pen

Claims (7)

A method for selecting a writable member for a touch panel pen, wherein a material satisfying the following condition 1-1 is selected as a writable member for a touch panel pen.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”. Furthermore, the selection method of the writable member for touch-panel pens of Claim 1 which sorts out what satisfies the following conditions 1-2 as a writable member for touch-panel pens.
<Condition 1-2>
The average residual friction force is 1.0 gf or more and 25.0 gf or less. Furthermore, the selection method of the writable member for touch-panel pens of Claim 1 or 2 which sorts what satisfy | fills the following conditions 1-3 as a writable member for touch-panel pens.
<Condition 1-3>
The average of the dynamic friction force is 1.0 gf or more and 32.0 gf or less. A touch panel system comprising a touch panel having a writable member for a touch panel pen on the surface and a touch panel pen, which satisfies the following condition 1-1.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”. A writable member for a touch panel pen having a surface satisfying the following condition 1-1.
<Condition 1-1>
The touch panel pen is fixed in a state where it is in contact with the surface of the writable member for touch panel pens at an angle of 60 degrees, and the writable member for touch panel pens is 14 mm / second while applying a vertical load of 100 gf to the touch panel pen. The moving frictional force in the moving direction applied to the touch panel pen when moving a length of 40 mm one way at a speed is measured at 0.001 second intervals, and the average of the dynamic frictional force every 0.001 second is calculated.
Furthermore, after the movement of the length of the one-way 40 mm of the touch panel pen writing member is completed, a vertical load of 100 gf is applied to the touch panel pen, and the touch panel pen is held against the surface of the touch panel pen writing member. The contact is made at an angle of 60 degrees. In this state, the residual friction force in the moving direction applied to the touch panel pen is measured at intervals of 0.001 seconds, and the average of the residual friction forces every 0.001 seconds is calculated.
The average of the dynamic friction force and the average of the residual friction force indicate a relationship of “0.45 <average of residual friction force / average of dynamic friction force”.   It is a touch panel which has a writable member on the surface, Comprising: As said writable member, it arrange | positions so that the surface of the side which satisfy | fills the said conditions 1-1 of the writable member for touchscreen pens of Claim 5 may face the surface of a touch panel. A touch panel.   A display device having a touch panel on a display element, wherein the touch panel is the touch panel according to claim 6.