JP2018100265A - Oily composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an oily composition excellent in low temperature stability while being excellent in all of a feeling of penetration, a feeling of film thickness and a feeling of richness. The following components (A) and (B); (A) almond oil and / or macadamia nut oil 60-99% by mass (B) hexa (hydroxystearic acid / stearic acid / logic acid) dipentaerythrityl, dilauroyl glutamate. Provided is an oil composition containing one or more selected from (octyldodecyl / phytosteryl / behenyl), macadamia nut fatty acid phytosteryl, and stearic acid hydrogenated castor oil. [Selection diagram] None

Description

  The present invention relates to almond oil and / or macadamia nut oil which are plant-derived oils, hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, lauroylglutamate di (octyldodecyl / phytosteryl / behenyl), macadamia nut fatty acid phytosteryl, stearin The present invention relates to an oily composition containing at least one selected from acid-hydrogenated castor oil.

  The oily composition is a composition mainly composed of an oil agent, and can be imparted with a wide variety of properties depending on the combination of oil agents used, and is widely used in cosmetics and the like because of its excellent moisturizing effect. In recent years, for the purpose of relaxation effect, etc., a plant-derived oil (such as almond oil) is applied to the skin (Patent Document 1), nutritional supplementation to the nail epidermis, and moisturizing effect (plant oil) , Lime oil), cystine, ionized calcium saturated water, etc. (Patent Document 2), a technique using liquid higher alcohol and vegetable oil to obtain a liquid oily body oil that is well-familiar and has good penetration (patent) Literature 3) has been reported, and a composition containing a plant-derived oil having various effects has been demanded.

  In recent years, nail oil compositions used to care for nail epidermis that has been damaged by the use of nail polish, in addition to nourishing and moisturizing effects, such as penetrating feeling, richness feeling and film thickness feeling during use. The thing which is excellent in the field has been calculated | required. As a technique for improving the richness and film thickness of the composition, a technique using an ester compound of isostearic acid having a specific structure (Patent Document 4) has been reported.

Special table 2012-510513 gazette JP 2008-127358 A JP2012-87109A JP 2004-51586 A

  However, in the techniques of Patent Documents 1 to 3, the effect of the plant-derived oil agent can be obtained, but the richness and the film thickness at the time of use cannot be obtained. For example, even if the technique of Patent Document 4 is used for the technique of Patent Document 3, depending on the selected oil agent, there are combinations that change in quality (solidify, etc.) in a low-temperature environment. It was difficult to obtain an oily composition having excellent low-temperature stability that does not deteriorate (solidify, etc.) in a low-temperature environment while being excellent in feel and richness.

  Accordingly, an object of the present invention is to provide an oily composition excellent in low-temperature stability while being excellent in all of a penetrating feeling, a film thickness feeling, and a rich feeling.

  In view of such circumstances, the present inventor has conducted extensive research, and as a result, the almond oil and / or macadamia nut oil, which is a plant-derived oil, is contained in an amount of 60 to 99% by mass, hexa (hydroxystearic acid / stearic acid / rosinic acid). ) By using one or more selected from dipentaerythrityl, dilauroylglutamate di (octyldodecyl / phytosteryl / behenyl), macadamia nut fatty acid phytosteryl, stearic acid hydrogenated castor oil, all of osmotic feeling, film thickness and richness in use It was found that an oily composition having excellent stability under a low temperature environment (about 5 ° C.) was obtained, and the present invention was completed.

That is, the present invention
The following components (A) and (B);
(A) Almond oil and / or macadamia nut oil 60-99% by mass
(B) Oily composition containing at least one selected from hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, dilauroyl glutamate (octyldodecyl / phytosteryl / behenyl), macadamia nut fatty acid phytosteryl, stearic acid hydrogenated castor oil It is about things.

  The content mass ratio of the said component (A) and the said component (B) is related with the oil-based composition whose (A) / (B) = 2.8-99.

  The said component (A) is related with the oil-based composition which is almond oil.

  The component (B) relates to an oily composition in which hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl.

  The oil-based composition relates to an oil-based composition that is liquid at 25 ° C.

  The oily composition relates to an oily composition which is a nail composition.

  The oil-based composition of the present invention is excellent in low temperature stability while being excellent in all of penetrating feeling, film thickness feeling, and rich feeling.

  Details of the present invention will be described below. In the present specification, “to” means a range including numerical values before and after.

  The almond oil and / or macadamia nut oil of the component (A) used in the present invention is a natural plant-derived oil mainly composed of triglyceride, and is not particularly limited as long as it is usually used in cosmetics and the like. One or more types can be used. Among these, it is more preferable to use almond oil in terms of superior permeation feeling.

  There are no particular restrictions on the extraction site and extraction method of the component (A), and it can be extracted from, for example, fruits, seeds, etc. Extraction can be performed at a low temperature or from room temperature to warm using a suitable solvent. As the extraction solvent, for example, water; a lower monohydric alcohol such as methyl alcohol or ethyl alcohol; or a liquid polyhydric alcohol such as glycerin, propylene glycol, or 1,3-butylene glycol can be used. . Moreover, it can also extract using lipophilic solvents, such as hexane, acetone, ethyl acetate, and ether. The obtained extract may be adsorbed, decolored and purified by filtration or ion exchange resin to form a liquid, a paste or a gel, but is preferably a liquid from the viewpoint of superior permeation. If necessary, purification treatment such as deodorization and decolorization may be further performed within a range not affecting the effect.

  Examples of commercially available products include sweet almond oil and macadamian nut oil (both manufactured by Nikko Chemicals Co., Ltd.), and one or more of these can be used.

  The content of the component (A) in the present invention is preferably 60 to 99% by mass (hereinafter simply referred to as “%”), more preferably 65 to 85%, and 65 to 75%. Particularly preferred. If the content is less than 60%, a satisfactory penetration feeling cannot be obtained.

  The component (B) hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, lauroylglutamate di (octyldodecyl / phytosteryl / behenyl), macadamia nut fatty acid phytosteryl, stearic acid hydrogenated castor oil used in the present invention are usually cosmetic. As long as it is used for materials and the like, it is not particularly limited, and one or more kinds can be used. Hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl used in the present invention is a full ester of dipentaerythritol and a mixed fatty acid composed of hydroxystearic acid, stearic acid, and rosin acid, and lauroyl glutamic acid diester. (Octyldodecyl / phytosteryl / behenyl) is a diester of lauroyl glutamic acid and a mixed alcohol consisting of octyldodecyl, phytosteryl, and behenyl. Macadamia nut fatty acid phytosteryl is an ester of fatty acid obtained from macadamia nut oil and phytosterols. Yes, stearic acid hydrogenated castor oil is an ester of stearic acid and hydrogenated castor oil. Among these, hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl is preferably used from the viewpoint of excellent body feeling, film thickness feeling, penetration feeling, and the like.

  Although melting | fusing point of a component (B) is not specifically limited, What is 30-60 degreeC is preferable and it is more preferable that it is 35-45 degreeC. If it is this range, it is more preferable at the point which is excellent by a rich feeling, a film thickness feeling, etc. In addition, the measurement of melting | fusing point in this invention can be measured by the quasi-drug raw material specification 2006 general test method, melting | fusing point test method 1st method.

  Examples of commercially available products include Cosmol 168ARNV (Nisshin Oillio Co., Ltd.), El Deu PS306 (Ajinomoto Co., Inc.), PLANDOOL MAS (Nihon Seika Co., Ltd.), Castride MS (National Mimatsu Co., Ltd.), etc. One or more can be used.

  Although content of the component (B) in this invention is not specifically limited, It is preferable that it is 1-25%, It is more preferable that it is 2-15%, It is especially preferable that it is 3-7%. If it is this range, it is more preferable at the point etc. which are excellent in a rich feeling and a film thickness feeling, and are excellent also in low-temperature stability.

  The content mass ratio of the component (A) and the component (B) in the present invention is preferably (A) / (B) = 2.8 to 99, more preferably 9 to 70, and 9 to 20. It is particularly preferred. If it is this range, it is more preferable at the point etc. which are excellent in all of a penetrating feeling, a rich feeling, and a film thickness feeling, and are excellent also in low temperature stability.

  In the oily composition of the present invention, in addition to the above components, oil agents other than components (A) and (B), aqueous components, powders, proteins, Moisturizers such as mucopolysaccharide, collagen and elastin, antioxidants such as α-tocopherol and ascorbic acid, cosmetic ingredients such as vitamins, anti-inflammatory agents and herbal medicines, preservatives such as paraoxybenzoic acid esters and phenoxyethanol, fragrances and coloring materials Etc. can be contained appropriately.

  The oil agent other than the component (A) is not particularly limited as long as it is usually used in cosmetics and the like, regardless of the origin of animal oil, vegetable oil, synthetic oil, etc., hydrocarbon oils, ester oils, Oils and fats, fatty acids, higher alcohols, fluorine oils, lanolin derivatives and the like can be used. Examples of hydrocarbon oils include liquid paraffin, squalane, polybutene, and polyisobutylene. Examples of higher alcohols include 2-octyldodecanol, myristyl alcohol, palmityl alcohol, and stearyl alcohol. Examples of higher fatty acids include lauric acid and myristin. Acid, palmitic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, isostearic acid, 12-hydroxystearic acid, etc. As ester oils, oleyl oleate, octyldodecyl oleate, decyl oleate, isostearic acid Isocetyl, isotridecyl isononanoate, isocetyl stearate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyl palmitate, isopropyl myristate, milli Octyldodecyl stannate, myristyl myristate, cetyl octanoate, cetyl 2-ethylhexanoate, 2-ethylhexyl succinate, diisostearyl malate, alkylene glycol monoisostearate, ethylene glycol di-2-ethylhexanoate, dicaprin Examples of fluorine oils such as neopentyl glycol acid, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cholesteryl 12-hydroxystearate, include perfluoropolyether, perfluorodecalin, Fluorooctane etc. are mentioned, These oil agents can be used 1 type, or 2 or more types as needed.

  Examples of aqueous components include alcohols such as ethanol and isopropyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol, and glycerols such as glycerin, diglycerin, and polyglycerin. Alternatively, two or more kinds can be added and used. The content of the aqueous component in the oily composition of the present invention is not particularly limited, but is preferably 0.5% or less, and preferably 0.1% or less, from the viewpoint that the effects of the present invention can be remarkably exhibited. More preferably, it is particularly preferably 0%.

  The powder is not particularly limited, and any powder can be used as long as it is used for cosmetics and the like. Specifically, as the inorganic powder, talc, kaolin, mica, synthetic mica, sericite, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, aluminum magnesium silicate, anhydrous silicic acid, silicon carbide, sulfuric acid Examples include barium, titanium oxide, zinc oxide, magnesium oxide, aluminum oxide, iron oxide mica, iron oxide mica titanium, mica titanium, bismuth oxychloride, and organic powders include nylon powder, polyethylene powder, polystyrene powder, silicone Examples thereof include powders, methyl methacrylate powders, polytetrafluoroethylene powders, wool powders, silk powders, crystalline cellulose, tar dyes and lake dyes thereof, and composites of these powders.

  Although it does not specifically limit as a form of the oil-based composition of this invention, A solid, semi-solid form, and a liquid thing are mentioned, A liquid thing is preferable at 25 degreeC at the point by which the effect of this invention is exhibited notably. .

  The content of water in the oily composition of the present invention is not particularly limited, but is preferably 0.5% or less, and preferably 0.1% or less, from the viewpoint that the effects of the present invention can be remarkably exhibited. Is more preferable and 0% is particularly preferable.

  The oily composition of the present invention can also be used for applications such as cosmetics, external preparations for skin, foods, inks, detergents, softeners for clothing, fragrances, deodorants, and textiles. Especially, it is suitable to use for cosmetics or a skin external preparation from the point which the effect of this invention is exhibited notably. Further, examples of the use site include skin, nails, eyelashes, and hairs, but it is more preferable to use the nails because the effects of the present invention are remarkably exhibited.

  Examples of cosmetics are not particularly limited. For example, skin care cosmetics such as milky lotion, cream, lotion, cosmetic liquid, cosmetic oil, pack, sunscreen, foundation, blusher, lipstick, eye color, mascara, eye Makeup cosmetics such as liners, nail cosmetics such as nail polish, nail oil, hair nourishing agents, hair tonics, shampoos, rinses, hair waxes, hair oils and other hair cosmetics, facial cleansers, body soaps, cleansing oils, etc. Among these, nail cosmetics such as nail polish and nail oil are preferable because the effects of the present invention are remarkably exhibited.

  Examples of the external preparation for skin are not particularly limited, and examples thereof include external gel preparations, cream preparations, ointments, liquid preparations, liniment preparations, and haptic preparations.

  EXAMPLES Next, although an Example is given and this invention is demonstrated still in detail, this invention is not limited at all by these.

Examples 1 to 10 and Comparative Examples 1 to 13: oily compositions for nails.
An oily composition for nails having the formulation shown in Table 1 below is prepared, and the following method is used for (i) richness, (b) film thickness, (c) penetration, and (d) low temperature stability. Evaluation was performed. The results are also shown in the table.

(Production method)
A. Ingredients 1-12 are uniformly mixed and dissolved at 70 ° C.
B. A was filled in a container to obtain an oily composition for nails.

Each of the following evaluation items was determined by the following determination method.
(Evaluation items and judgment method)
(B) Feeling of richness, (b) Feeling of film thickness, (c) Penetration feeling Applying oily compositions for nails of Examples and Comparative Examples to nails to 10 panelists specializing in cosmetics evaluation, and extending and spreading on fingernails Each nail oil composition is evaluated in five levels according to the following criteria, and each nail oil composition is scored for each nail oil composition. The average score was determined according to the following criteria. The evaluation results are also shown in Table 1. In this determination, richness means that when the oily composition for nails is extended and spread, it has an appropriate adhesion to the nails and has a feeling of biting on the nails. Refers to the film feeling of the nail oil composition remaining on the nail after the nail oil composition is extended and spread, and the penetrating feeling is the familiarity with the nail when the nail oil composition is extended and spread. It means that the finish is good and the feel is minimal.
<Evaluation criteria>
(Evaluation result): (Grade)
Very good: 5 points Good: 4 points Normal: 3 points Somewhat bad: 2 points Bad: 1 point <Criteria>
(Average score): (Judgment)
4.5 or more: ◎
3.5 or more and less than 4.5: ○
2.5 or more and less than 3.5: △
Less than 2.5: ×

(2) Low-temperature stability 15 ml of the nail oil compositions of Examples 1 to 10 and Comparative Examples 1 to 13 are placed in a No. 3 medicine bottle (Daiichi Glass Co., Ltd.) and allowed to stand still for 1 hour in a thermostatic bath at 5 ° C. Then, when the vial is tilted 90 ° in a 5 ° C thermostat, the stability under low temperature conditions is measured by measuring the time required for the liquid level of the nail oil composition to become horizontal. evaluated.
<Criteria>
○: Time until the liquid level becomes horizontal is less than 10 seconds Δ: Time until the liquid level becomes horizontal is 10 seconds or more and less than 60 seconds X: Time until the liquid level becomes horizontal is 60 seconds or more

  As is clear from the results in Table 1, the oily compositions for nails of Examples 1 to 10 of the present invention had high body feeling, film thickness feeling and penetration feeling, and were excellent in low temperature stability. . In particular, Example 1 was excellent in all of the richness, film thickness, and penetration feeling. On the other hand, Comparative Examples 1 and 2 not containing the component (B) were not satisfactory in terms of richness and film thickness. In Comparative Example 3 using Meadowfoam oil instead of component (A), a satisfactory penetration feeling was not obtained, and the low-temperature stability was inferior. Further, none of Comparative Examples 4 to 13 using an oil agent close to the melting point of the component (B) in place of the component (B) was satisfactory in low temperature stability.

Examples 11 to 21 and Comparative Examples 14 to 16: Nail oil Nail oils having the formulations shown in Table 2 below were prepared, (i) richness, (b) film thickness, (c) penetration, and (2). The low temperature stability was evaluated by the following method. The results are also shown in the table.

(Production method)
A. Each component is uniformly mixed and dissolved at 70 ° C.
B. A was filled in a container to obtain nail oil.

Each of the following evaluation items was determined by the following determination method.
(I) Rich feeling (b) Film thickness feeling (c) Penetration feeling (2) Low temperature stability Both conform to the determination method of Table 1.

  As is clear from the results in Table 2, the oily compositions of Examples 11 to 21 of the present invention were excellent in richness, film thickness, and penetration, and excellent in low-temperature stability. In particular, Example 11 was excellent in all of the richness, film thickness and penetration feeling. On the other hand, the comparative example 14 which uses petrolatum instead of the component (B) was not satisfactory in terms of penetration feeling and low temperature stability. Moreover, the comparative example 15 which does not contain a component (B) was not able to be satisfied with the rich feeling and film thickness feeling. Moreover, the comparative example 16 whose content of a component (A) is less than 60% was not able to obtain what was satisfactory in a penetrating feeling.

Example 22: Hair oil (component) (%)
1. Tripropylene glycol 5
2. Ethyl oleate 0.5
3. Oleyl alcohol 5
4). Di-2-ethylhexyl succinate 2
5). Dimethiconol * 12 2
6). Hexa (hydroxystearic acid / stearic acid / rosinic acid)
Dipentaerythrityl * 3 5
7). Lauroyl glutamate (octyldodecyl / phytosteryl / behenyl) * 4 1
8). Almond oil * 1 70
9. 10. Glyceryl tri-2-ethylhexanoate Dextrin isostearate * 13 0.3
11. Diisostearyl malate 1
12 Straw oil 5
13. 2,6-di-tert-butyl-paracresol 0.5
14 Natural vitamin E 0.1
15. Fragrance 0.5
* 12: XF49-C2497 (manufactured by Momentive Performance Materials Japan) (dimethiconol 35% hydrogenated polyisobutene solution)
* 13: Unifilm HVY (Chiba Flour Mills)

(Production method)
A: Components (1) to (13) are uniformly dissolved by heating at 90 ° C.
B: After cooling A to room temperature, components (14) to (15) are added and mixed uniformly.
C: Fill dispenser container with B.
The hair oil of Example 22 was excellent in richness, film thickness and penetration, and excellent in low temperature stability.

Example 23: Cleansing oil (component) (%)
1. Heavy liquid isoparaffin * 14 1
2. Liquid paraffin 5
3. Tetraoleic acid polyoxyethylene sorbit * 15 10
4). Macadamia nut oil * 2 65
5). Hexa (hydroxystearic acid / stearic acid / rosinic acid)
Dipentaerythrityl * 3 3
6). Lauroyl glutamate (octyldodecyl / phytosteryl / behenyl) * 4 1
7. Cetyl 2-ethylhexanoate Remaining 8. Tripropylene glycol 5
9. Rice bran oil 2
10. Decamethylpentasiloxane 5
11. Phenoxyethanol 0.5
12.2,6-di-tert-butyl-paracresol 0.02
13. Rosehip oil 0.05
14 Grape seed oil 0.05
15. Refined jojoba oil 0.05
16. Fragrance 0.2
* 14: Pearl Dream 24 (manufactured by NOF Corporation)
* 15: Rheodor 430V (manufactured by Kao)

(Production method)
A: Components (1) to (12) are uniformly heated and dissolved at 80 ° C.
B: Components (13) to (16) are added to A and mixed and dissolved uniformly.
C: B is charged into a dispenser container at room temperature.

  The cleansing oil of Example 23 was excellent in richness, film thickness and penetration, and excellent in low temperature stability.

Example 24: Bath oil (bathing agent)
(Ingredient) (%)
1. Almond oil * 1 70
2. Fragrance 5
3. Tetraoleic acid polyoxyethylene sorbit * 15 16
4). 4. Glyceryl tri-2-ethylhexanoate Tripropylene glycol 1
6). Macadamia nut oil * 2 0.1
7). Persic oil 0.05
8). Ethyl oleate 1
9. Oleic acid 1
10. Hexa (hydroxystearic acid / stearic acid / rosinic acid)
Dipentaerythrityl * 3 4
11. Lauroyl glutamate (octyldodecyl / phytosteryl / behenyl) * 4 1

(Production method)
A: Components (1) to (11) are mixed and dissolved uniformly.
B: A is filled in a bottle container at room temperature.

  The bath oil (bath agent) of Example 24 was excellent in richness, film thickness, and penetration, and excellent in low-temperature stability.

Example 25: Cosmetic oil (ingredient) (%)
1. Propylene glycol dicaprate 10
2. Macadamia nut fatty acid phytosteryl * 5 2
3. Phenoxyethanol 0.1
4). Tetra-2-ethylhexanoic acid pentaerythrityl 4
5). Absolute ethanol 5
6). Wheat germ oil 0.05
7). Rice germ oil 0.05
8). Olive oil 0.05
9. Lavender oil 0.05
10. Methyl polysiloxane * 16 3
11. Tripropylene glycol 2
12 Rice bran oil remaining amount 13. Polyglyceryl diisostearate * 17 2
14 Almond oil * 1 60
15. Macadamia nut oil * 2 5
16. Hexa (hydroxystearic acid / stearic acid / rosinic acid)
Dipentaerythrityl * 3 3
17. Glyceryl tri-2-ethylhexanoate 2
18. Fragrance 0.3
* 16: KF96-10cs (Shin-Etsu Chemical Co., Ltd.)
* 17: Cosmall 42V (Nisshin Oillio Group)

(Production method)
A: Components (1) to (18) are uniformly mixed and dissolved.
B: A is filled into a glass bottle container at room temperature.

  The cosmetic oil of Example 25 was excellent in richness, film thickness, and penetration, and excellent in low-temperature stability.

Claims (6)

The following components (A) and (B);
(A) Almond oil and / or macadamia nut oil 60-99% by mass
(B) Oily composition containing at least one selected from hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, dilauroyl glutamate (octyldodecyl / phytosteryl / behenyl), macadamia nut fatty acid phytosteryl, stearic acid hydrogenated castor oil object.   The oily composition according to claim 1, wherein the content ratio of the component (A) and the component (B) is (A) / (B) = 2.8 to 99.   The oily composition according to claim 1, wherein the component (A) is almond oil.   The oily composition according to any one of claims 1 to 3, wherein the component (B) is hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl.   The oily composition according to any one of claims 1 to 4, which is liquid at 25 ° C.   It is a composition for nails, The oil-based composition in any one of Claims 1-5.