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JP2018044758A - Heat insulation box - Google Patents

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JP2018044758A
JP2018044758A JP2017103643A JP2017103643A JP2018044758A JP 2018044758 A JP2018044758 A JP 2018044758A JP 2017103643 A JP2017103643 A JP 2017103643A JP 2017103643 A JP2017103643 A JP 2017103643A JP 2018044758 A JP2018044758 A JP 2018044758A
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plate
design
heat
heat insulating
plate portion
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JP6733606B2 (en
Inventor
亨 岡崎
Toru Okazaki
亨 岡崎
浅井田 康浩
Yasuhiro Asaida
康浩 浅井田
彰継 瀬川
Akitsugu Segawa
彰継 瀬川
白羽 劉
Baiyu Liu
白羽 劉
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Panasonic Corp
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Panasonic Corp
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Priority to CN201710599070.7A priority Critical patent/CN107806731A/en
Priority to US15/684,727 priority patent/US10866021B2/en
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Abstract

【課題】断熱箱の仕切板における結露防止用放熱パイプから庫内へ侵入する熱を抑制する冷蔵庫を提供すること。【解決手段】空間を有する断熱箱本体と、上記空間を密閉する扉と、上記空間を仕切る仕切板と、を含み、上記仕切板は、上記扉側に配置された意匠板と、上記意匠板の両端のそれぞれに配置された第1板部と第2板部と、上記意匠板と上記第1板部と上記第2板部で囲まれた領域に位置する断熱材と、上記意匠板と上記第1板部との間、上記意匠板と上記第2板部との間の少なくとも1方に配置された断熱体と、を含む断熱箱を用いる。【選択図】図2PROBLEM TO BE SOLVED: To provide a refrigerator that suppresses heat entering into a refrigerator from a heat radiation pipe for preventing dew condensation on a partition plate of a heat insulating box. A heat insulating box main body having a space, a door for sealing the space, and a partition plate for partitioning the space, the partition plate being a design plate arranged on the door side, and the design plate. A first plate part and a second plate part arranged at both ends of the design plate, a heat insulating material located in a region surrounded by the design plate, the first plate part and the second plate part, and the design plate, A heat insulation box including a heat insulator arranged between the first plate portion and at least one of the design plate and the second plate portion is used. [Selection diagram] Figure 2

Description

本発明は、断熱箱に関する。特に、複数の室を有する冷蔵庫などの断熱箱の仕切部の構造に関する。 The present invention relates to a heat insulation box. In particular, the present invention relates to a structure of a partition part of a heat insulating box such as a refrigerator having a plurality of chambers.

複数の室を有する冷蔵庫などの断熱箱は、内部に断熱材を備えた樹脂成形品である仕切板を設け、各室間を食品などの貯蔵内容によって温度や湿度などの環境が異なる室に仕切って区画している。 A heat insulation box such as a refrigerator having a plurality of rooms is provided with a partition plate which is a resin molded product provided with a heat insulating material inside, and the rooms are partitioned into rooms with different environments such as temperature and humidity depending on the contents of storage such as food. Are divided.

この仕切板を設置することによって断熱箱の強度を向上させている。仕切板の開口部側にある意匠板は、前面の意匠面と、この意匠面に対して直角に折り曲げた端辺を備えてコ字状に形成されている。   The strength of the heat insulation box is improved by installing this partition plate. The design plate on the opening side of the partition plate is formed in a U shape with a front design surface and an end bent at a right angle to the design surface.

また、扉に設けたパッキンと箱体本体とが密閉状態で保持されるように、意匠板は、パッキンの内部に備えたマグネットが吸着する磁性体であることが必要である。さらに、意匠板は、冷蔵庫の強度向上に対する影響が大きいので、意匠板には低価格で高強度の塗装鋼板が用いられている。   In addition, the design plate needs to be a magnetic body to which a magnet provided inside the packing is attached so that the packing provided on the door and the box body are held in a sealed state. Furthermore, since the design plate has a great influence on the strength improvement of the refrigerator, a low-priced and high-strength coated steel plate is used for the design plate.

しかしながら、意匠板は、熱伝導性に優れる塗装鋼板からなるため、室外の高温域から室内の低温域に向かって熱を流してしまう。これによって、断熱箱の断熱性能が低下するとともに、意匠板自体の温度が外気(冷蔵庫の設置雰囲気)の露点以下に低下して、結露を生じる。   However, since the design plate is made of a coated steel plate having excellent thermal conductivity, heat flows from the outdoor high temperature region toward the indoor low temperature region. Thereby, while the heat insulation performance of a heat insulation box falls, the temperature of the design board itself falls below the dew point of external air (installation atmosphere of a refrigerator), and dew condensation arises.

このような問題に対し、特許文献1では、結露発生防止の対応が取られている。図12は、特許文献1における従来の冷蔵庫の仕切板と意匠板周辺の構造を示す図である。仕切板21は、断熱材28、上板26、下板27、放熱パイプ22、蓄熱層23、意匠板25、意匠板の端部25a、断熱材24を含む。   With respect to such a problem, Patent Document 1 takes measures to prevent the occurrence of condensation. FIG. 12 is a diagram showing a structure around a partition plate and a design plate of a conventional refrigerator in Patent Document 1. The partition plate 21 includes a heat insulating material 28, an upper plate 26, a lower plate 27, a heat radiating pipe 22, a heat storage layer 23, a design plate 25, an end portion 25 a of the design plate, and a heat insulating material 24.

冷蔵庫の背面部より封入された発泡ウレタンの断熱材28の上下にそれぞれ上板26、下板27が配置され、その前面部に、冷凍サイクルの放熱のための放熱パイプ22を配設されている。この放熱パイプ22は、蓄熱層23を介して意匠板25に接触されている。冷蔵庫前面にウレタンの断熱材28が漏出するのを防止するために、発泡スチロールなどで構成される固形の柔軟な断熱材24が設けられている。冷蔵庫背面からの発泡ウレタンの断熱材28の封入時に、断熱材24は、意匠板25に押圧される。これにより、温度を露点以上に上昇させて結露を防止している。   An upper plate 26 and a lower plate 27 are respectively disposed above and below a urethane foam heat insulating material 28 sealed from the rear portion of the refrigerator, and a heat radiating pipe 22 for radiating the refrigeration cycle is disposed on the front portion thereof. . The heat radiating pipe 22 is in contact with the design plate 25 through the heat storage layer 23. In order to prevent the urethane heat insulating material 28 from leaking to the front surface of the refrigerator, a solid flexible heat insulating material 24 made of foamed polystyrene or the like is provided. The heat insulating material 24 is pressed against the design plate 25 when encapsulating the urethane foam heat insulating material 28 from the back of the refrigerator. As a result, the temperature is raised above the dew point to prevent condensation.

また、特許文献2には、結露防止と仕切板の強度強化を両立しながら、冷蔵庫の断熱性を高める対応が取られている。   Patent Document 2 takes measures to increase the heat insulation of the refrigerator while preventing condensation and strengthening the partition plate.

図13は、特許文献2における従来の冷蔵庫の仕切板と意匠板周辺の構造を示す図である。仕切板31は、冷蔵庫の背面部より封入された発泡ウレタンの断熱材33の上下にそれぞれ上板38、下板39が配置されている。また、上板38と下板39の間には、発泡ウレタンの断熱材33と放熱パイプ32が配設されている。これに加え、発泡スチロールなどで構成される固形の柔軟な断熱材34を隔て、仕切板31の強度確保と、冷蔵庫背面からの発泡ウレタンの断熱材28の封入時に冷蔵庫前面にウレタンが漏出するのを防止するための仕切壁36が配設されている。   FIG. 13 is a diagram showing a structure around a partition plate and a design plate of a conventional refrigerator in Patent Document 2. In the partition plate 31, an upper plate 38 and a lower plate 39 are respectively arranged above and below a urethane foam heat insulating material 33 enclosed from the back side of the refrigerator. Further, between the upper plate 38 and the lower plate 39, a urethane foam heat insulating material 33 and a heat radiating pipe 32 are disposed. In addition to this, the solid flexible heat insulating material 34 made of foamed polystyrene or the like is separated to ensure the strength of the partition plate 31 and to prevent urethane from leaking to the front of the refrigerator when the foamed urethane heat insulating material 28 is sealed from the back of the refrigerator. A partition wall 36 is provided to prevent this.

放熱パイプ32は意匠板35に接触されている。意匠板35は、特許文献1のように側面が直接、上板38、下板39に接触するのではなく、硬質の断熱材37を囲い込むように張出端部35bを介して上板38、下板39に接触している。また、脚状端辺35cも仕切壁36のリブ部40に接触することで、仕切板31の強度確保と結露の防止を行いながら硬質の断熱材37を配設することで断熱箱の断熱性を高めている。   The heat radiating pipe 32 is in contact with the design plate 35. The design plate 35 does not directly contact the upper plate 38 and the lower plate 39 as in Patent Document 1, but the upper plate 38 via the overhanging end portion 35b so as to surround the hard heat insulating material 37. In contact with the lower plate 39. Further, the leg-shaped end 35c is also in contact with the rib portion 40 of the partition wall 36, so that the heat insulating property of the heat insulating box is provided by arranging the hard heat insulating material 37 while ensuring the strength of the partition plate 31 and preventing condensation. Is increasing.

特開平4−103984号公報JP-A-4-103984 特許第2945553号公報Japanese Patent No. 2945553

しかしながら、特許文献1の図12に記載の従来の冷蔵庫では、冷蔵庫庫内への熱の侵入を抑えきれていない。意匠板25には、仕切板21の上板26、下板27の表面近くに端部25aがある。これにより、意匠板25は温度上昇し結露が防止される。しかし、放熱パイプ22から発せられた熱が、熱伝導性の大きい鋼板で構成された意匠板25から、端部25aに伝わり、熱伝導性の高い樹脂で構成された上板26、下板27を介して、図12中のAのルートにて庫内に侵入する。これが、断熱箱の断熱性能を低下させる原因となる。   However, in the conventional refrigerator described in FIG. 12 of Patent Document 1, the penetration of heat into the refrigerator cabinet cannot be suppressed. The design plate 25 has end portions 25 a near the surfaces of the upper plate 26 and the lower plate 27 of the partition plate 21. As a result, the design plate 25 rises in temperature and dew condensation is prevented. However, the heat generated from the heat radiating pipe 22 is transmitted from the design plate 25 made of a steel plate having a high thermal conductivity to the end portion 25a, and the upper plate 26 and the lower plate 27 made of a resin having a high thermal conductivity. Through the route A in FIG. This causes the heat insulation performance of the heat insulation box to deteriorate.

また、発熱源である放熱パイプ22の近傍に配設されている固形の柔軟な断熱材24は、熱伝導率が大きい発泡スチロール製(およそλ=0.040W/(m・K))であり、発泡ウレタンの断熱材28の熱伝導率(およそλ=0.023W/(m・K))のおよそ2倍である。これも、放熱パイプ22から意匠板の端部25a、仕切板の上板26、下板27までの断熱性を下げ、断熱箱の断熱性能を低下させる原因となる。   Further, the solid flexible heat insulating material 24 disposed in the vicinity of the heat radiating pipe 22 which is a heat source is made of polystyrene foam having a high thermal conductivity (approximately λ = 0.040 W / (m · K)), This is approximately twice the thermal conductivity (approximately λ = 0.024 W / (m · K)) of the urethane foam heat insulating material 28. This also reduces the heat insulation performance from the heat radiating pipe 22 to the end 25a of the design plate, the upper plate 26 and the lower plate 27 of the partition plate, and lowers the heat insulating performance of the heat insulating box.

また、特許文献2の図13に記載の従来の冷蔵庫でも、冷蔵庫庫内への熱の侵入を抑えきれていない。意匠板35は、張出端部35bを介して上板38、下板39に接触しているため、放熱パイプ32の熱は、前面部35aから張出端部35bを介して上板38、下板39へ伝わり、図12中のBのルートで庫内へ侵入する。また同じく、意匠板35は、脚状端辺35cを介して仕切壁のリブ部40に接触しているため、放熱パイプ32の熱は、前面部35aから脚状端辺35cを介して仕切壁のリブ部40、仕切壁36へと伝わり、図13中のCのルートでも庫内へ侵入するため、冷蔵庫の断熱性能を低下させる原因となる。   Further, even the conventional refrigerator described in FIG. 13 of Patent Document 2 cannot sufficiently suppress the intrusion of heat into the refrigerator cabinet. Since the design plate 35 is in contact with the upper plate 38 and the lower plate 39 through the overhang end portion 35b, the heat of the heat radiating pipe 32 is transferred from the front surface portion 35a through the overhang end portion 35b to the upper plate 38, It is transmitted to the lower plate 39 and enters the cabinet through the route B in FIG. Similarly, since the design plate 35 is in contact with the rib portion 40 of the partition wall through the leg-shaped end side 35c, the heat of the heat radiating pipe 32 is separated from the front surface portion 35a through the leg-shaped end side 35c. 13 is transmitted to the rib portion 40 and the partition wall 36, and enters the cabinet even in the route C in FIG. 13, which causes a decrease in the heat insulating performance of the refrigerator.

また、前記特許文献1の場合と同様に、発熱源である放熱パイプ32の近傍に配設されている固形の柔軟な断熱材34は、熱伝導率が大きい発泡スチロール製であり、発泡ウレタンの断熱材33の熱伝導率のおよそ2倍である。これも、放熱パイプ32から意匠板の脚状端辺35cや仕切壁36から仕切板の上板38、下板39までの断熱性を下げ、断熱箱の断熱性能を低下させる原因となる。   Similarly to the case of Patent Document 1, the solid flexible heat insulating material 34 disposed in the vicinity of the heat radiating pipe 32 which is a heat source is made of polystyrene foam having a high thermal conductivity, and heat insulation of urethane foam. This is approximately twice the thermal conductivity of the material 33. This also lowers the heat insulation performance from the heat radiating pipe 32 to the leg-shaped edge 35c of the design plate and the partition wall 36 to the upper plate 38 and the lower plate 39 of the partition plate, thereby reducing the heat insulation performance of the heat insulation box.

本発明は、前記従来の課題を解決するもので、仕切板近傍の結露防止を実現し、意匠板を介して冷蔵庫庫内へ侵入する熱を抑制した断熱箱を提供することを目的とする。   This invention solves the said conventional subject, and it aims at providing the heat insulation box which implement | achieved the prevention of dew condensation near a partition plate and suppressed the heat | fever which penetrate | invades into a refrigerator cabinet through a design board.

上記課題を解決するために、空間を有する断熱箱本体と、上記空間を密閉する扉と、上記空間を仕切る仕切板と、を含み、上記仕切板は、上記扉側に配置された意匠板と、上記意匠板の両端のそれぞれに配置された第1板部と第2板部と、上記意匠板と上記第1板部と上記第2板部で囲まれた領域に位置する断熱材と、上記意匠板と上記第1板部との間、上記意匠板と上記第2板部との間の少なくとも1方に配置された断熱体と、を含む断熱箱を用いる。   In order to solve the above problems, a heat insulating box body having a space, a door for sealing the space, and a partition plate for partitioning the space, the partition plate is a design plate disposed on the door side, The first plate portion and the second plate portion disposed at both ends of the design plate, the heat insulating material located in the region surrounded by the design plate, the first plate portion, and the second plate portion, A heat insulating box including a heat insulator disposed between at least one of the design plate and the first plate portion and between the design plate and the second plate portion is used.

本発明によれば、仕切板近傍の結露防止を実現し、意匠板を介して冷蔵庫庫内へ侵入する熱を抑制するとともに、発泡ウレタン断熱材の封入時のウレタンの冷蔵庫前部への漏出を防止し、冷蔵庫の断熱性能を向上させる。   According to the present invention, it is possible to prevent condensation in the vicinity of the partition plate, suppress heat entering the refrigerator cabinet through the design plate, and prevent urethane from leaking to the front of the refrigerator when encapsulating the urethane foam heat insulating material. Prevent and improve the thermal insulation performance of the refrigerator.

実施の形態1、2における冷蔵庫の断熱箱の構造を示す図The figure which shows the structure of the heat insulation box of the refrigerator in Embodiment 1,2. 実施の形態1における、図1のα部の縦断面図1 is a vertical cross-sectional view of the α part in FIG. 1 in the first embodiment. 軟質複合断熱材の断面構造を示す図Diagram showing the cross-sectional structure of soft composite insulation (a)軟質複合断熱材の積層前の構造を示す図、(b)軟質複合断熱材の積層後の構造を示す図、(c)軟質複合断熱材のゲル硬化後の構造を示す図(A) The figure which shows the structure before lamination | stacking of a soft composite heat insulating material, (b) The figure which shows the structure after lamination | stacking of a soft composite heat insulating material, (c) The figure which shows the structure after the gel hardening of a soft composite heat insulating material. 実施の形態1、2、4における冷蔵庫の断熱箱の仕切板の上板、下板間に意匠板を組込む段階を示す図The figure which shows the step which incorporates a design board between the upper board of the partition plate of the heat insulation box of the refrigerator in Embodiment 1, 2, 4, and a lower board. 実施の形態1、2、3、4における冷蔵庫の断熱箱の仕切板のビス止め機構を示す図The figure which shows the screwing mechanism of the partition plate of the heat insulation box of the refrigerator in Embodiment 1, 2, 3, 4. 軟質複合断熱材と他の断熱材の押圧時の熱伝導率変化を示すグラフGraph showing thermal conductivity change when pressing soft composite insulation and other insulation 実施の形態2における、図1のα部の縦断面図FIG. 1 is a longitudinal sectional view of the α part in FIG. 実施の形態3における、図1のα部の縦断面図FIG. 1 is a longitudinal sectional view of the part α in FIG. (a)実施の形態3における意匠板を仕切板へ入れる途中段階を示す図、(b)実施の形態3における意匠板を仕切板へ入れた後を示す図(A) The figure which shows the middle stage which puts the design board in Embodiment 3 in a partition plate, (b) The figure which shows after putting the design board in Embodiment 3 in a partition plate 実施の形態4における、図1のα部の縦断面図FIG. 1 is a longitudinal sectional view of the part α in FIG. 特許文献1における従来の冷蔵庫の断熱箱の仕切板の構造を示す断面図Sectional drawing which shows the structure of the partition plate of the heat insulation box of the conventional refrigerator in patent document 1 特許文献2における従来の冷蔵庫の断熱箱の仕切板の構造を示す断面図Sectional drawing which shows the structure of the partition plate of the heat insulation box of the conventional refrigerator in patent document 2

以下、実施の形態について、図面を参照しながら説明する。 Hereinafter, embodiments will be described with reference to the drawings.

(実施の形態1)
図1は本発明の実施の形態1における冷蔵庫の断熱箱を示す斜視図であり、図2は図1のα部の縦断面図、図3は軟質複合断熱材11(断熱体)の拡大断面図である。
(Embodiment 1)
1 is a perspective view showing a heat insulating box of a refrigerator according to Embodiment 1 of the present invention, FIG. 2 is a longitudinal sectional view of a part α in FIG. 1, and FIG. FIG.

<断熱箱100の構成>
図1において、冷蔵庫の断熱箱100は、鋼板などの金属製の外箱5と、ABS(アクリロニトリル・ブタジエン・スチレン)などの樹脂製の内箱4と、内箱4内の断熱される空間を仕切る仕切板1と、空間を密閉する扉(図示せず)と、によって構成される。外箱5と内箱4とを組み合わせて、断熱箱本体となる。
<Configuration of heat insulation box 100>
In FIG. 1, a heat insulating box 100 of a refrigerator includes an outer box 5 made of metal such as a steel plate, an inner box 4 made of resin such as ABS (acrylonitrile butadiene styrene), and a space to be insulated in the inner box 4. It is comprised by the partition plate 1 which partitions off, and the door (not shown) which seals space. The outer box 5 and the inner box 4 are combined to form a heat insulating box body.

仕切板1は、断熱された空間を分け、第1貯蔵室2と第2貯蔵室3とに仕切る。例えば、第1貯蔵室2は、冷蔵室であり、第2貯蔵室3は冷凍室である。仕切板1は、温度帯の異なる各貯蔵部屋の間に配設されるものである。   The partition plate 1 divides the heat-insulated space into a first storage chamber 2 and a second storage chamber 3. For example, the 1st store room 2 is a refrigerator compartment, and the 2nd store room 3 is a freezer room. The partition plate 1 is arrange | positioned between each storage room from which a temperature zone differs.

<仕切板1の構成>
図2において、仕切板1は上下に上板6(第1板部)、下板7(第2板部)を有し、上板6と下板7の前面部(断熱箱の前面、扉側)には、コの字型の意匠板10がある。意匠板15には、結露防止用の放熱パイプ9(放熱部)が、接触設置されている。なお、放熱パイプ9でなく、別の方法で結露防止をしてもよい。また、放熱パイプ9は、仕切板1内でなくともよい。
<Configuration of partition plate 1>
In FIG. 2, the partition plate 1 has an upper plate 6 (first plate portion) and a lower plate 7 (second plate portion) on the upper and lower sides, and front portions of the upper plate 6 and the lower plate 7 (the front surface of the heat insulating box, the door). On the side), there is a U-shaped design board 10. On the design plate 15, a heat radiating pipe 9 (heat radiating portion) for preventing condensation is placed in contact. In addition, you may prevent dew condensation by another method instead of the heat radiating pipe 9. Further, the heat radiating pipe 9 may not be in the partition plate 1.

意匠板10は、冷蔵庫の前面に現れる前面部10aと、前面部10aから約90度曲げられ、冷蔵庫内部へ配置される側面部10bとを有する。   The design plate 10 has a front surface portion 10a that appears on the front surface of the refrigerator, and a side surface portion 10b that is bent about 90 degrees from the front surface portion 10a and is arranged inside the refrigerator.

意匠板10の側面部10bと上板6(第1板部)、下板7(第2板部)の間に、軟質複合断熱材11(断熱体)が挟まれ圧縮固定されている。第1板部6と断熱体11と意匠板10の側面部10bとが積層されている。断熱体11は、圧縮されやすい。   A soft composite heat insulating material 11 (heat insulator) is sandwiched between the side surface portion 10b of the design plate 10, the upper plate 6 (first plate portion), and the lower plate 7 (second plate portion), and is compressed and fixed. The 1st board part 6, the heat insulator 11, and the side part 10b of the design board 10 are laminated | stacked. The heat insulator 11 is easily compressed.

上板6(第1板部)と下板7(第2板部)は、L字形状で、その前面部にそれぞれ鍵括弧型の上板前面部6a、下板前面部7aを備えている。なお、意匠板10から上板6(第1板部)、下板7(第2板部)への熱の伝導を防ぐため、図2の円点線の中に示すように、意匠板10と上板6(第1板部)、下板7(第2板部)の接続は、軟質複合断熱材11(断熱体)を介してのみ行うことが好ましい。すなわち、意匠板10と上板前面部6a、下板前面部7aが、直接接触しないよう隙間50を空けておくことが好ましい。隙間50は、断熱体11の厚みより薄い。   The upper plate 6 (first plate portion) and the lower plate 7 (second plate portion) are L-shaped, and are provided with an upper plate front surface portion 6a and a lower plate front surface portion 7a, respectively, on the front surface portion thereof. . In order to prevent heat conduction from the design plate 10 to the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion), as shown in the dotted line in FIG. It is preferable to connect the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion) only through the soft composite heat insulating material 11 (heat insulator). That is, it is preferable to leave a gap 50 so that the design plate 10 and the upper plate front surface portion 6a and the lower plate front surface portion 7a do not directly contact each other. The gap 50 is thinner than the thickness of the heat insulator 11.

なお、上板6(第1板部)と下板7(第2板部)の全面部が鍵括弧型の上板前面部6a、下板前面部7aを有しているため、冷蔵庫前面から軟質複合断熱材11(断熱体)が使用者に明確に見えることはない。結果、冷蔵庫としての美観も維持することができる。また、上板6(第1板部)と軟質複合断熱材11(断熱体)、放熱パイプ9(放熱部)、意匠板10、下板7(第2板部)の間には、発泡ウレタンの断熱材8が充填されている。   In addition, since the whole surface part of the upper board 6 (1st board part) and the lower board 7 (2nd board part) has a key bracket type upper board front part 6a and the lower board front part 7a, from the refrigerator front The soft composite heat insulating material 11 (heat insulator) is not clearly visible to the user. As a result, the beauty as a refrigerator can also be maintained. Further, urethane foam is interposed between the upper plate 6 (first plate portion) and the soft composite heat insulating material 11 (heat insulator), the heat radiating pipe 9 (heat radiating portion), the design plate 10 and the lower plate 7 (second plate portion). The heat insulating material 8 is filled.

結果、第1板部6と断熱体11と意匠板10の側面部10bと放熱パイプ9とが積層されている、または、一直線上にある。断熱体11は、熱の経路を、遮断できる。   As a result, the 1st board part 6, the heat insulator 11, the side part 10b of the design board 10, and the heat radiating pipe 9 are laminated | stacked, or exist on a straight line. The heat insulator 11 can block the heat path.

<軟質複合断熱材11(断熱体)の構成>
図3に示す軟質複合断熱材11(断熱体)は、エアロゲルと繊維構造物との複合体である。軟質複合断熱材11(断熱体)は、不織布繊維11cとエアロゲル11dを構成要素とする。軟質複合断熱材11は、中央にエアロゲルと繊維との複合層11aとその上下に繊維単独層11bとを有する積層構造である。軟質複合断熱材11では、エアロゲル繊維複合層11aが変形しにくいが、繊維単独層11bが変形でき、軟質性がある。
<Configuration of soft composite heat insulating material 11 (heat insulating material)>
A soft composite heat insulating material 11 (heat insulator) shown in FIG. 3 is a composite of an airgel and a fiber structure. The soft composite heat insulating material 11 (heat insulator) includes the nonwoven fabric fiber 11c and the airgel 11d as constituent elements. The soft composite heat insulating material 11 has a laminated structure having a composite layer 11a of airgel and fiber in the center and a single fiber layer 11b above and below the composite layer 11a. In the soft composite heat insulating material 11, the airgel fiber composite layer 11a is not easily deformed, but the fiber single layer 11b can be deformed and is flexible.

エアロゲル繊維複合層11aは、繊維構造物(例えば不織布)にエアロゲルを複合させたものであり、エアロゲル前駆体に繊維構造物を浸漬し、該繊維構造物の存在下で超臨界乾燥、あるいは常圧乾燥により前記エアロゲル前駆体からエアロゲルを生成させることにより得られるものである。   The airgel fiber composite layer 11a is obtained by combining an airgel with a fiber structure (for example, non-woven fabric), and the fiber structure is immersed in an airgel precursor, and is supercritically dried in the presence of the fiber structure or at atmospheric pressure. It is obtained by producing an airgel from the airgel precursor by drying.

エアロゲルは、微細な空孔を多数持つ極めて空隙率(好ましくは空隙率99%以上)の高い固体である。より詳細には、二酸化ケイ素などを数珠状に結合した構造を持ち、ナノメータレベル(例えば2〜50nm)の空隙を多数持つ物質である。このようにナノメータレベルの細孔と格子状構造を持つため、気体分子の平均自由行程を縮小することができ、常圧でも気体分子同士の熱伝導が非常に少なく、熱伝導率が非常に小さいものである。   The airgel is a solid having an extremely high porosity (preferably a porosity of 99% or more) having many fine pores. More specifically, it is a substance having a structure in which silicon dioxide or the like is bonded in a bead shape and having many nanometer-level (for example, 2 to 50 nm) voids. Since it has nanometer-level pores and a lattice structure, it can reduce the mean free path of gas molecules, and there is very little heat conduction between gas molecules even at normal pressure, and the heat conductivity is very small. Is.

エアロゲルとしては、ケイ素、アルミニウム、鉄、銅、ジルコニウム、ハフニウム、マグネシウム、イットリウムなどの金属酸化物からなる無機エアロゲルの使用が好ましく、より好ましくは二酸化ケイ素からなるシリカエアロゲルである。   The airgel is preferably an inorganic airgel made of a metal oxide such as silicon, aluminum, iron, copper, zirconium, hafnium, magnesium or yttrium, more preferably a silica airgel made of silicon dioxide.

繊維構造物は、エアロゲルを補強し、また支持するための補強材ないし支持体として作用するものであり、軟質な複合体断熱材を得るために、軟質な織布、編布、不織布などを用いる。繊維構造物の材質としては、ポリエステル繊維等の有機繊維の他、ガラス繊維などの無機繊維を用いることもできる。   The fiber structure functions as a reinforcing material or support for reinforcing and supporting the airgel, and a soft woven fabric, a knitted fabric, a non-woven fabric, or the like is used to obtain a soft composite heat insulating material. . As a material of the fiber structure, inorganic fibers such as glass fibers can be used in addition to organic fibers such as polyester fibers.

このようにして得られる断熱材は、熱伝導率が発泡ウレタン断熱材と同等かそれ以下(およそλ=0.020W/(m・K))であり、非常に断熱性の高い材料である。   The heat insulating material thus obtained has a thermal conductivity equal to or lower than that of the urethane foam heat insulating material (approximately λ = 0.020 W / (m · K)), and is a material having a very high heat insulating property.

繊維単独層11bは、エアロゲルを含まない上記繊維構造物からなる。繊維単独層11bは、主に、繊維材料のみからなるのが好ましい。繊維単独層11bは、軟質複合断熱材11(断熱体)の圧縮時の弾力性の創出や、上板6(第1板部)、下板7(第2板部)の反りやうねりによる意匠板10との隙間のばらつきの緩和のための弾力層として設けられている。   The fiber single layer 11b consists of the said fiber structure which does not contain an airgel. It is preferable that the fiber single layer 11b mainly consists only of a fiber material. The fiber single layer 11b is designed by the creation of elasticity at the time of compression of the soft composite heat insulating material 11 (heat insulator) and the warp and undulation of the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion). It is provided as a resilient layer for alleviating variation in the gap with the plate 10.

なお、両側の繊維単独層11bが、上板6、意匠板10にそれぞれ接触する。繊維単独層11bは、両板から圧縮される。繊維単独層11bが主に圧縮される。しかし、熱伝度率は、エアロゲル繊維複合層11aの寄与が大きいため、圧縮されても断熱体11の熱伝導率はほとんど変化せず、断熱を保てる。   In addition, the fiber single layer 11b of both sides contacts the upper board 6 and the design board 10, respectively. The fiber single layer 11b is compressed from both plates. The fiber single layer 11b is mainly compressed. However, since the thermal conductivity contributes greatly to the airgel fiber composite layer 11a, the thermal conductivity of the heat insulator 11 hardly changes even when compressed, and heat insulation can be maintained.

繊維単独層11bとエアロゲル繊維複合層11aとの層方向と圧縮させる方向は同じである。   The layer direction of the fiber single layer 11b and the airgel fiber composite layer 11a is the same as the direction of compression.

(製造方法)
以上のように構成される冷蔵庫について、以下、その製造方法と効果について説明する。
(Production method)
About the refrigerator comprised as mentioned above, the manufacturing method and effect are demonstrated below.

<軟質複合断熱材11(断熱体)の製造>
軟質複合断熱材11(断熱体)の製造方法は(1)ゾル調製工程、(2)含浸工程、(3)積層工程、(4)ゲル化工程、(5)養生工程、(6)酸性水溶液浸漬工程、(7)疎水化工程、(8)乾燥工程の8工程からなる。以下にそれぞれの工程ごとに説明する。
<Manufacture of soft composite heat insulating material 11 (heat insulating material)>
The manufacturing method of the soft composite heat insulating material 11 (heat insulator) is (1) sol preparation step, (2) impregnation step, (3) lamination step, (4) gelation step, (5) curing step, (6) acidic aqueous solution It consists of 8 steps of dipping step, (7) hydrophobizing step, and (8) drying step. Each step will be described below.

(1)ゾル調製工程
ゾル調製工程では、原料として水ガラスを用いる場合と、高モル珪酸水溶液を用いる場合とがある。水ガラスを用いる場合は、水ガラス中のナトリウムをイオン交換樹脂もしくは電気透析法により除去、酸性にし、ゾルとした後、触媒として塩基を添加して重縮合させ、ヒドロゲルとする。高モル珪酸ソーダを用いる場合は、高モル珪酸水溶液に触媒として酸を加えて重縮合させ、ヒドロゲルとする。
(1) Sol preparation process In the sol preparation process, there are a case where water glass is used as a raw material and a case where a high molar silicic acid aqueous solution is used. When water glass is used, sodium in the water glass is removed by an ion exchange resin or electrodialysis and acidified to form a sol, which is then polycondensed by adding a base as a catalyst to obtain a hydrogel. When high molar sodium silicate is used, an acid is added to the high molar aqueous silicic acid solution as a catalyst and polycondensed to obtain a hydrogel.

(2)含浸工程
0.2〜1.0mm厚みのPET、ガラスウール、ロックウールなどで構成される不織布に、(1)にて調製したゾル溶液を不織布重量の6.5〜10倍量注ぎ、ゾル溶液を不織布に含浸させる。含浸方法は、あらかじめゾル溶液をフィルム上などに一定の厚みにて広げ、その上より不織布を覆うことにより、ゾル溶液を不織布に浸透させる。
(2) Impregnation step The sol solution prepared in (1) is poured into the nonwoven fabric composed of PET, glass wool, rock wool, etc. having a thickness of 0.2 to 1.0 mm in an amount of 6.5 to 10 times the weight of the nonwoven fabric. Then, the nonwoven fabric is impregnated with the sol solution. In the impregnation method, the sol solution is spread on the film or the like with a certain thickness in advance, and the nonwoven fabric is covered with the sol solution so that the sol solution penetrates the nonwoven fabric.

(3)積層工程
積層構成について、図4(a)〜図4(c)を用いて説明する。(2)の工程までで、図4(a)におけるエアロゲル繊維複合層11aが完成した。積層工程では、これに、繊維単独層11bとして、不織布を積層、複合化する。
(3) Lamination process A lamination structure is demonstrated using Fig.4 (a)-FIG.4 (c). By the process (2), the airgel fiber composite layer 11a in FIG. In the laminating step, a non-woven fabric is laminated and combined as the fiber single layer 11b.

まず、図4(a)に示すように、(2)の含浸工程を経たエアロゲル繊維複合層11aに対し、繊維単独層11bとして不織布を上下にして、図4(b)に示すようにサンドイッチする。このとき、浸透圧により、繊維単独層11bである不織布にエアロゲル繊維複合層11a中のゾル成分の一部に浸透する(しみ込む)。   First, as shown in FIG. 4 (a), the airgel fiber composite layer 11a that has undergone the impregnation step of (2) is sandwiched as shown in FIG. . At this time, due to the osmotic pressure, a part of the sol component in the airgel fiber composite layer 11a penetrates (impregnates) into the nonwoven fabric which is the fiber single layer 11b.

(4)ゲル化工程
(3)の後、ゾルをゲル化する。ゾルのゲル化温度は、20〜90℃が好ましい。ゲル化温度が20℃未満であると、反応の活性種である珪酸モノマーに必要な熱が伝わらない。このため、シリカ粒子の成長が促進されない。その結果、ゾルのゲル化が十分に進行するまでに時間を要する。その上に、生成されるゲル(エアロゲル)の強度が低く、乾燥時に大きく収縮する場合があり、所望の強度のエアロゲルが得られない場合がある。
(4) Gelation step After (3), the sol is gelled. The gelation temperature of the sol is preferably 20 to 90 ° C. When the gelation temperature is less than 20 ° C., heat necessary for the silicic acid monomer which is an active species of the reaction is not transmitted. For this reason, the growth of silica particles is not promoted. As a result, it takes time until the sol is sufficiently gelled. In addition, the strength of the generated gel (aerogel) is low, and it may shrink greatly during drying, and an airgel having a desired strength may not be obtained.

また、ゲル化温度が90℃を越えると、シリカ粒子の成長は著しく促進されてしまう。結果、水の揮発が急速に起こり、水とヒドロゲルとが分離する現象がみられる。これにより得られるヒドロゲルの体積が減少して、シリカエアロゲルが得られない場合がある。   On the other hand, when the gelation temperature exceeds 90 ° C., the growth of silica particles is remarkably promoted. As a result, water volatilization occurs rapidly, and water and hydrogel are separated. The volume of the hydrogel obtained by this decreases, and a silica airgel may not be obtained.

なお、ゲル化時間は、ゲル化温度や後述するゲル化後の養生時間により異なるが、ゲル化時間と後述する養生時間とを合計して、0.1〜12時間が好ましい。さらに、ゲル化時間は、性能(熱伝導率)と生産タクトを両立させるという観点から0.1〜1時間が好ましい。   The gelation time varies depending on the gelation temperature and the curing time after gelation described later, but is preferably 0.1 to 12 hours by adding the gelation time and the curing time described later. Further, the gelation time is preferably 0.1 to 1 hour from the viewpoint of achieving both performance (thermal conductivity) and production tact.

ゲル化時間が、12時間より長い場合、シリカネットワークの強化は十分に行われているが、より養生に時間をかけると生産性を損なうだけでなく、ゲルの収縮が起こる。結果、ゲルの嵩密度が上がるため、できた軟質複合断熱材11(断熱体)の熱伝導率が上昇しよくない。   When the gelation time is longer than 12 hours, the silica network is sufficiently strengthened. However, the longer the curing time, not only the productivity is lost, but also the gel shrinks. As a result, since the bulk density of the gel is increased, the thermal conductivity of the resulting soft composite heat insulating material 11 (heat insulator) is not good.

このようにして、ゲル化を行うことで、ヒドロゲルの壁の強度や剛性が向上し、乾燥時に収縮し難いヒドロゲルを得ることができる。さらに、ゾルがゲル状に固化することで、不織布層にしみ込んだエアロゲルは固化し、図4(c)に示すように、全層合体して、エアロゲル繊維複合層11aと繊維単独層11bの積層構造を形成する。   In this way, by performing gelation, the strength and rigidity of the hydrogel wall are improved, and a hydrogel that does not easily shrink during drying can be obtained. Furthermore, as the sol is solidified in a gel state, the airgel soaked into the nonwoven fabric layer is solidified, and as shown in FIG. 4C, all layers are combined to form a laminate of the airgel fiber composite layer 11a and the fiber single layer 11b. Form a structure.

(5)養生工程
養生工程は、ゲル化後にシリカの骨格を、強化させた骨格強化ヒドロゲルにする工程である。養生温度は、50〜100℃が好ましい。養生温度が50℃未満の場合、脱水縮合反応が相対的に遅くなるため、生産性を考慮した際の目標のタクト時間内にシリカネットワークを十分に強化させることが難しくなる。
(5) Curing Process The curing process is a process in which the skeleton of silica is reinforced into a reinforced skeleton hydrogel after gelation. The curing temperature is preferably 50 to 100 ° C. When the curing temperature is less than 50 ° C., the dehydration condensation reaction is relatively slow, so that it is difficult to sufficiently strengthen the silica network within the target tact time when considering productivity.

養生温度が、100℃より高い場合は、ゲル中の水分が著しく蒸発してしまうため、ゲルの収縮、乾燥が起こり、熱伝導率が上昇してしまう。   When the curing temperature is higher than 100 ° C., the water in the gel evaporates remarkably, so that the gel shrinks and dries, and the thermal conductivity increases.

養生時間は、0.1〜12時間が好ましく、性能(熱伝導率)と生産タクトを両立させるという観点から0.1〜1時間がより好ましい。   The curing time is preferably 0.1 to 12 hours, and more preferably 0.1 to 1 hour from the viewpoint of achieving both performance (thermal conductivity) and production tact.

養生時間が12時間より長い場合、シリカネットワークの強化は十分に行われているが、より養生に時間をかけると生産性を損なうだけでなく、ゲルの収縮が起こり、嵩密度が上がるため、熱伝導率が上昇してしまうという問題がある。   When the curing time is longer than 12 hours, the silica network is sufficiently strengthened. However, if the curing time is longer, not only the productivity is impaired, but also the gel shrinks and the bulk density increases. There is a problem that conductivity increases.

養生時間を0.1〜6時間の範囲で養生を行うことで、生産性を確保しつつ、シリカ粒子のネットワークを十分に強化することができる。   By performing the curing in the range of 0.1 to 6 hours, it is possible to sufficiently strengthen the silica particle network while ensuring productivity.

(6)酸性水溶液浸漬工程
ゲルと不織布の複合体を塩酸(6〜12規定)に浸漬後、常温23℃で45分以上放置し、複合体内部に塩酸を取り込む。
(6) Acidic aqueous solution immersion step After the gel-nonwoven fabric complex is immersed in hydrochloric acid (6-12N), it is allowed to stand at room temperature for 23 minutes or longer to incorporate hydrochloric acid into the complex.

(7)疎水化工程
ゲルと不織布の複合体を例えば、シリル化剤であるオクタメチルトリシロキサンとアルコールとして2−プロパノール(IPA)の混合液に浸漬させて、55℃の恒温槽に入れて2時間反応させる。トリメチルシロキサン結合が形成され始めると、ゲルシートから塩酸水が排出され、2液分離する(上層にシロキサン、下層に塩酸水)。
(7) Hydrophobization process For example, the composite of gel and non-woven fabric is immersed in a mixed solution of octamethyltrisiloxane, which is a silylating agent, and 2-propanol (IPA) as an alcohol, and placed in a constant temperature bath at 55 ° C. Let react for hours. When trimethylsiloxane bond starts to be formed, hydrochloric acid water is discharged from the gel sheet and separated into two liquids (siloxane in the upper layer and hydrochloric acid in the lower layer).

(8)乾燥
ゲルと不織布の複合体を150℃の恒温槽に移して2時間乾燥させる(常圧乾燥の場合)。
(8) Drying The gel / nonwoven fabric composite is transferred to a thermostat at 150 ° C. and dried for 2 hours (in the case of normal pressure drying).

以上の工程により、軟質複合断熱材11(断熱体)が製造される。   The soft composite heat insulating material 11 (heat insulator) is manufactured by the above process.

<仕切板1の製造>
仕切板1の製造方法について、図1、図2、図5、図6を用いて説明する。
<Manufacture of partition plate 1>
The manufacturing method of the partition plate 1 is demonstrated using FIG.1, FIG.2, FIG.5 and FIG.

図1において、外箱5と内箱4を係合したのち、図1中の仕切板1の部分について、図5に示すように、意匠板10に接触するように放熱パイプ9(放熱部)をテープ等(図示せず)で固定したものを設け、仕切板1の上板6(第1板部)の下面と下板7(第2板部)の上面にテープ等(図示せず)で軟質複合断熱材11(断熱体)を設置する。   In FIG. 1, after engaging the outer box 5 and the inner box 4, the part of the partition plate 1 in FIG. 1, as shown in FIG. 5, the heat radiating pipe 9 (heat radiating part) so as to contact the design plate 10. Is fixed to the lower surface of the upper plate 6 (first plate portion) of the partition plate 1 and the upper surface of the lower plate 7 (second plate portion) with tape or the like (not shown). The soft composite heat insulating material 11 (heat insulator) is installed.

次に、断熱箱に仮止めした仕切板1の上板6(第1板部)と下板7(第2板部)を、図5の(1)のように上下に少し広げ、図5の(2)に示すように、上板6(第1板部)と下板7(第2板部)に設置された軟質複合断熱材11(断熱体)の間に意匠板10を移動させ合体させる。   Next, the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion) of the partition plate 1 temporarily fixed to the heat insulation box are slightly expanded up and down as shown in FIG. As shown in (2), the design plate 10 is moved between the soft composite heat insulating material 11 (heat insulator) installed on the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion). Combine.

合体した意匠板10の位置固定について、図6の斜視図に示すように、上板6(第1板部)(図示せず)と下板7(第2板部)(図示せず)の間の一部に配設された仕切板1の取付用リブ12に、取付用リブ12と同じ位置に配設された意匠板10上のビス穴13を介して、ビス(図示せず)にて、意匠板10を固定する。   As shown in the perspective view of FIG. 6, the upper plate 6 (first plate portion) (not shown) and the lower plate 7 (second plate portion) (not shown) are fixed to fix the position of the combined design plate 10. A screw (not shown) is attached to the mounting rib 12 of the partition plate 1 disposed at a part of the partition plate via a screw hole 13 on the design plate 10 disposed at the same position as the mounting rib 12. Then, the design plate 10 is fixed.

最後に、図1における断熱箱100の背面側から外箱5と内箱4の間と、図2における上板6(第1板部)と下板7(第2板部)の間に発泡ウレタンの断熱材8を流し込み、硬化させることで仕切板1、ならびに断熱箱100が製造される。   Finally, foaming is performed between the outer box 5 and the inner box 4 from the back side of the heat insulating box 100 in FIG. 1, and between the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion) in FIG. The partition plate 1 and the heat insulation box 100 are manufactured by pouring and curing the urethane heat insulating material 8.

このとき、図2に示すように、上板6(第1板部)と下板7(第2板部)の間には意匠板10により軟質複合断熱材11(断熱体)が圧縮されて固定されているため、発泡ウレタンの断熱材8が、封入時に断熱箱の前面に漏れ出すことはない。   At this time, as shown in FIG. 2, the soft composite heat insulating material 11 (heat insulator) is compressed between the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion) by the design plate 10. Since it is fixed, the heat insulating material 8 of urethane foam does not leak out to the front surface of the heat insulating box at the time of sealing.

結果、断熱材8は、断熱体11と意匠板10と第1板部6と第2板部7とで囲まれている。   As a result, the heat insulating material 8 is surrounded by the heat insulating body 11, the design plate 10, the first plate portion 6, and the second plate portion 7.

<実施の形態1の効果>
図2に示すように、放熱パイプ19の熱は、意匠板10の前面部10aから側面部10bまで伝わり、意匠板10の表面の結露防止に効果を発揮する。一方で、側面部10bの隣には、断熱性の高い軟質複合断熱材11(断熱体)が配置しているため、熱が仕切板1の上板6(第1板部)や下板7(第2板部)に伝わらず、庫内への熱の侵入を防ぐことができる。
<Effect of Embodiment 1>
As shown in FIG. 2, the heat of the heat radiating pipe 19 is transmitted from the front surface portion 10 a to the side surface portion 10 b of the design plate 10, and is effective in preventing condensation on the surface of the design plate 10. On the other hand, since the soft composite heat insulating material 11 (heat insulator) having high heat insulation is disposed next to the side surface portion 10b, heat is applied to the upper plate 6 (first plate portion) and the lower plate 7 of the partition plate 1. Intrusion of heat into the cabinet can be prevented regardless of (second plate portion).

特に、軟質複合断熱材11(断熱体)は、圧縮力(押圧)を受け、縮んでも、熱伝導率がほとんど変化しない。   In particular, even when the soft composite heat insulating material 11 (heat insulating material) receives a compressive force (pressing force) and contracts, the thermal conductivity hardly changes.

図7に、軟質複合断熱材11(断熱体)の押圧と熱伝導率の関係を示す。実施の形態1における軟質複合断熱材11(断熱体)と、比較例1として同じ厚みの発泡樹脂製の断熱材と、比較例2として同じ厚みの樹脂製断熱材とを評価した。種々の押圧をかけた状態で、各試料の熱伝導率を測定したものである。   FIG. 7 shows the relationship between the pressure of the soft composite heat insulating material 11 (heat insulator) and the thermal conductivity. The soft composite heat insulating material 11 (heat insulating body) in the first embodiment, the heat insulating material made of foam resin having the same thickness as Comparative Example 1, and the resin heat insulating material having the same thickness as Comparative Example 2 were evaluated. The thermal conductivity of each sample was measured under various pressures.

発泡樹脂製の断熱材(比較例1)は、初期の熱伝導率λ=0.04W/(m・K)に対し、500kPaの押圧をかけたときには76%も上昇している。   The heat insulating material made of foamed resin (Comparative Example 1) rises by 76% when a pressure of 500 kPa is applied to the initial thermal conductivity λ = 0.04 W / (m · K).

樹脂製の断熱材(比較例2)は、初期の熱伝導率λ=0.05W/(m・K)に対し、500kPaの押圧をかけたときには45%も上昇している。
一方、軟質複合断熱材11(実施例)は、500kPaの押圧時に15%しか熱伝導率が上昇していない。
The heat insulating material made of resin (Comparative Example 2) rises by 45% when a pressure of 500 kPa is applied against the initial thermal conductivity λ = 0.05 W / (m · K).
On the other hand, the thermal conductivity of the soft composite heat insulating material 11 (Example) increases only by 15% when pressed at 500 kPa.

したがって、軟質複合断熱材11(断熱体)は意匠板10と上板6(第1板部)、下板7(第2板部)の間に圧縮固定するのに適している。つまり、軟質複合断熱材11(断熱体)を圧縮しても、断熱効果が低下しない。軟質複合断熱材11(断熱体)は、断熱材として好ましい。   Therefore, the soft composite heat insulating material 11 (heat insulator) is suitable for compression and fixing between the design plate 10 and the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion). That is, even if the soft composite heat insulating material 11 (heat insulator) is compressed, the heat insulating effect does not decrease. The soft composite heat insulating material 11 (heat insulating material) is preferable as a heat insulating material.

また、軟質複合断熱材11(断熱体)は、意匠板10と上板6(第1板部)、下板7(第2板部)の間で圧縮固定されているのに加え、図4(c)に示すように、上板6(第1板部)、下板7(第2板部)と意匠板10の隙間のばらつきに対応する弾力性のある繊維単独層11bが設けられている。   In addition, the soft composite heat insulating material 11 (heat insulator) is compressed and fixed between the design plate 10 and the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion), as shown in FIG. As shown in (c), an elastic fiber single layer 11b corresponding to the variation in the gap between the upper plate 6 (first plate portion), the lower plate 7 (second plate portion) and the design plate 10 is provided. Yes.

これにより、従来の冷蔵庫にて発泡ウレタンの断熱材8の漏れ出し防止に用いていた断熱性の低い発泡スチロール製の断熱材34(図13)、断熱材24(図12)、仕切壁36(図13)を用いなくともよい。   Thereby, the heat insulating material 34 (FIG. 13), the heat insulating material 24 (FIG. 12), the partition wall 36 (FIG. 13) made from the low thermal insulation used in the conventional refrigerator for preventing leakage of the heat insulating material 8 of urethane foam. 13) may not be used.

さらに、実施の形態1の仕切板1では、放熱パイプ19の近傍まで、断熱性の高い発泡ウレタンの断熱材8を封入することができる。よって、放熱パイプ19から上板6(第1板部)や下板7(第2板部)を介して庫内に侵入する熱も防ぐことができる。   Furthermore, in the partition plate 1 according to the first embodiment, the heat insulating material 8 made of urethane foam having high heat insulating properties can be sealed up to the vicinity of the heat radiating pipe 19. Therefore, the heat | fever which penetrate | invades in the store | warehouse | chamber via the upper board 6 (1st board part) and the lower board 7 (2nd board part) from the thermal radiation pipe 19 can also be prevented.

さらに、図2に示すように仕切板1の上板6(第1板部)と下板7(第2板部)の全面部が鍵括弧型をしているため、冷蔵庫前面から軟質複合断熱材11(断熱体)が使用者に見えることがなく、冷蔵庫としての美観も維持することができる。   Further, as shown in FIG. 2, since the entire surface of the upper plate 6 (first plate portion) and the lower plate 7 (second plate portion) of the partition plate 1 has a key bracket shape, the soft composite heat insulation from the front of the refrigerator. The material 11 (heat insulator) is not visible to the user, and the beauty as a refrigerator can be maintained.

なお、軟質複合断熱材11(断熱体)は、2箇所に設けているが、少なくとも1方にあればよい。   In addition, although the soft composite heat insulating material 11 (heat insulating body) is provided in two places, it should just exist in at least one side.

(実施の形態2)
図8は、図1のα部の縦断面図である。図8は、実施の形態1の図2に対応する図である。
(Embodiment 2)
FIG. 8 is a longitudinal sectional view of the part α in FIG. FIG. 8 is a diagram corresponding to FIG. 2 of the first embodiment.

実施の形態2において、実施の形態1と異なるのは、図8における意匠板15と上板61(第1板部)、下板71の形状である。説明しない事項は、実施の形態1と同様である。   The second embodiment differs from the first embodiment in the shapes of the design plate 15, the upper plate 61 (first plate portion), and the lower plate 71 in FIG. Matters not described are the same as those in the first embodiment.

<意匠板15、上板61(第1板部)、下板71(第2板部)の構成>
図8において、意匠板15は、ロールフォーミングなどの折曲げ加工により、端部に二重折曲げ部15bを形成したのちに、上板61(第1板部)、下板71(第2板部)と平行な面を構成するように再度折曲げられ折曲げ平坦部15cを設けている。
<Configuration of Design Plate 15, Upper Plate 61 (First Plate Portion), Lower Plate 71 (Second Plate Portion)>
In FIG. 8, the design plate 15 is formed by forming a double bent portion 15b at the end by bending such as roll forming, and then an upper plate 61 (first plate portion) and a lower plate 71 (second plate). Are bent again so as to form a plane parallel to the part), and a bent flat part 15c is provided.

つまり、意匠板15は両端が2重構造で、内側に突起があり、前記突起で前記断熱材を保持する。   In other words, the design plate 15 has a double structure at both ends, and has a protrusion on the inside, and the heat insulating material is held by the protrusion.

上板61(第1板部)と下板71(第2板部)は、軟質複合断熱材11(断熱体)が収まるように意匠板10に平行に、それぞれザグリ61b、71b(凹部)を設けている。   The upper plate 61 (first plate portion) and the lower plate 71 (second plate portion) are provided with counterbore 61b and 71b (concave portions) in parallel with the design plate 10 so that the soft composite heat insulating material 11 (heat insulator) is accommodated. Provided.

なお、ザグリ(凹部)でなく、2つの凸部で断熱体を固定してもよい。   In addition, you may fix a heat insulator with two convex parts instead of counterbore (concave part).

なお、意匠板15から上板61(第1板部)、下板71(第2板部)への熱の伝導を防ぐため、意匠板15と上板61(第1板部)、下板71(第2板部)の接続は、軟質複合断熱材11(断熱体)を介してのみ行い、直接、意匠板15の端部15aと上板61(第1板部)、下板71(第2板部)がそれぞれ接触しないよう隙間を空けておくことが好ましい。   In order to prevent heat conduction from the design plate 15 to the upper plate 61 (first plate portion) and the lower plate 71 (second plate portion), the design plate 15 and the upper plate 61 (first plate portion), the lower plate. 71 (second plate portion) is connected only via the soft composite heat insulating material 11 (heat insulator), and directly the end 15a of the design plate 15, the upper plate 61 (first plate portion), the lower plate 71 ( It is preferable to leave a gap so that the second plate portions do not contact each other.

<実施の形態2の効果>
実施の形態1に示した効果(結露防止効果、庫内への熱侵入抑制効果)に加え、上板61(第1板部)、下板71(第2板部)にザグリ61b、71bがあることと、意匠板15に折り曲げ部があることにより、軟質複合断熱材11(断熱体)の仕切板1の組立時の位置決め精度を向上させることができる。
<Effect of Embodiment 2>
In addition to the effects shown in the first embodiment (condensation prevention effect, effect of suppressing heat intrusion into the cabinet), counterbore 61b and 71b are provided on the upper plate 61 (first plate portion) and the lower plate 71 (second plate portion). The presence of the bent portion in the design plate 15 can improve the positioning accuracy when the partition plate 1 of the soft composite heat insulating material 11 (heat insulator) is assembled.

また、図8に示すように意匠板15に折り曲げ部があることにより、冷蔵庫前面から軟質複合断熱材11(断熱体)が使用者に見えることがなく、冷蔵庫としての美観も維持できる。   Further, as shown in FIG. 8, since the design plate 15 has a bent portion, the soft composite heat insulating material 11 (heat insulator) is not visible to the user from the front of the refrigerator, and the beauty as a refrigerator can be maintained.

(実施の形態3)
図9は図1のα部の縦断面図である。図9は、実施の形態1の図2に対応する図である。
(Embodiment 3)
FIG. 9 is a longitudinal sectional view of a part α in FIG. FIG. 9 is a diagram corresponding to FIG. 2 of the first embodiment.

実施の形態3において、実施の形態1と異なるのは、意匠板16と上板62(第1板部)、下板72(第2板部)の形状と、仕切板1の製造方法(意匠板16の上板62(第1板部)、下板72(第2板部)への組込み方法)である。説明しない事項は、実施の形態1と同様である。   The third embodiment differs from the first embodiment in the shape of the design plate 16, the upper plate 62 (first plate portion), the lower plate 72 (second plate portion), and the manufacturing method (design) of the partition plate 1. This is a method of assembling the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion) of the plate 16. Matters not described are the same as those in the first embodiment.

<意匠板16、上板62(第1板部)、下板72(第2板部)の構成>
図9において、意匠板16は二段のプレス加工などで形成された第1段差部16aと第2段差部16bを有している。上板62(第1板部)、下板72(第2板部)の前面部には、それぞれ鉤戻り部62a、72aが設けられている。
<Configuration of Design Plate 16, Upper Plate 62 (First Plate Portion), Lower Plate 72 (Second Plate Portion)>
In FIG. 9, the design plate 16 has a first step portion 16a and a second step portion 16b formed by two-step pressing or the like. On the front surfaces of the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion), wrinkle return portions 62a and 72a are provided, respectively.

なお、意匠板16から上板62(第1板部)、下板72(第2板部)への熱の伝導を防ぐため、意匠板16と上板62(第1板部)、下板72(第2板部)の接続は、軟質複合断熱材11(断熱体)を介してのみ行い、直接、意匠板16の第1段差部16aと上板鉤戻り部62a、下板鉤戻り部72aがそれぞれ接触しないよう隙間を空けておくことが好ましい。   In order to prevent heat conduction from the design plate 16 to the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion), the design plate 16 and the upper plate 62 (first plate portion), the lower plate. 72 (second plate portion) is connected only through the soft composite heat insulating material 11 (heat insulator), and directly the first step portion 16a of the design plate 16, the upper plate wrinkle return portion 62a, and the lower plate wrinkle return portion. It is preferable to leave a gap so that 72a does not contact each other.

<仕切板1の製造(意匠板16の上板62(第1板部)、下板72(第2板部)への組込み方法)>
図10(a)は、仕切板1の上板62(第1板部)、下板72(第2板部)の間に意匠板16への組込み段階を示す図である。意匠板16を上板62(第1板部)と下板72(第2板部)の間に矢印の向きに押し込むと、意匠板16の第2段差部16bの上面と下面が上板62(第1板部)、下板72(第2板部)それぞれの鉤戻り部62a、72aのテーパ部を押し、上板62(第1板部)と下板72(第2板部)の開口部が広がる。これにより、意匠板16を上板62(第1板部)と下板72(第2板部)に設置された軟質複合断熱材11(断熱体)の間の部分にまで配置することができる。
<Manufacture of Partition Plate 1 (Assembly Method on Upper Plate 62 (First Plate Portion) and Lower Plate 72 (Second Plate Portion)) of Design Plate 16>
FIG. 10A is a diagram showing an assembling stage into the design plate 16 between the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion) of the partition plate 1. When the design plate 16 is pushed between the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion) in the direction of the arrow, the upper and lower surfaces of the second step portion 16b of the design plate 16 are the upper plate 62. The first plate portion and the lower plate 72 (second plate portion) are pressed against the tapered portions 62a and 72a of the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion). The opening widens. Thereby, the design board 16 can be arrange | positioned even to the part between the soft composite heat insulating materials 11 (heat insulator) installed in the upper board 62 (1st board part) and the lower board 72 (2nd board part). .

図10(b)は、仕切板1の上板62(第1板部)、下板72(第2板部)の間に意匠板16への組込み後を示す図である。意匠板16の第2段差部16b(階段状形状)が、上板62(第1板部)、下板72(第2板部)それぞれの鉤戻り部62a、72aより奥まで押し込まれると、鉤戻り部62a、72aに対する外力が無くなる。このとき、スプリングバックによって、軟質複合断熱材11(断熱体)と意匠板16の第2段差部16bが接触し、圧縮固定される。仕切板1の製造において、上記以外の部分は実施の形態1、2と同様である。   FIG. 10B is a diagram illustrating the state after the assembly into the design plate 16 between the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion) of the partition plate 1. When the second step portion 16b (stepped shape) of the design plate 16 is pushed deeper than the back return portions 62a and 72a of the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion), The external force with respect to the return parts 62a and 72a is lost. At this time, the soft composite heat insulating material 11 (heat insulator) and the second stepped portion 16b of the design plate 16 come into contact with each other and are compressed and fixed by the springback. In manufacturing the partition plate 1, the other parts are the same as those in the first and second embodiments.

<実施の形態3の効果>
図9に示した実施の形態3により、実施の形態1に示した効果(結露防止効果、庫内への熱侵入抑制効果)に加え、上板62(第1板部)、下板72(第2板部)前面部に鉤戻り部62a、72aがあることにより、仕切板1の製造工程、特に意匠板16の上板62(第1板部)、下板72(第2板部)の間への組込みを簡略化することができる。すなわち、実施の形態1あるいは2においては、意匠板の組み込みのために上板と下板の開口部を広げる必要があるが、本実施の形態においては、前述のように意匠板16を上板62(第1板部)、下板72(第2板部)の間に押し込むだけで済む。
<Effect of Embodiment 3>
According to the third embodiment shown in FIG. 9, in addition to the effects shown in the first embodiment (condensation prevention effect, effect of suppressing heat penetration into the cabinet), the upper plate 62 (first plate portion), the lower plate 72 ( Second plate portion) By having the hook return portions 62a and 72a on the front surface portion, the manufacturing process of the partition plate 1, particularly the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion) of the design plate 16 Integration between the two can be simplified. That is, in Embodiment 1 or 2, it is necessary to widen the openings of the upper plate and the lower plate in order to incorporate the design plate, but in this embodiment, the design plate 16 is used as the upper plate as described above. It is only necessary to push in between 62 (first plate portion) and the lower plate 72 (second plate portion).

また、図9に示すように上板62(第1板部)、下板72(第2板部)の前面部に鉤戻り部62a、72aがあることにより、冷蔵庫前面から軟質複合断熱材11(断熱体)が使用者に見えることがなく、冷蔵庫としての美観も維持することができる。   Further, as shown in FIG. 9, the soft composite heat insulating material 11 from the front of the refrigerator is provided by the presence of the hook return portions 62 a and 72 a on the front surface of the upper plate 62 (first plate portion) and the lower plate 72 (second plate portion). The (insulator) is not visible to the user, and the beauty as a refrigerator can be maintained.

(実施の形態4)
図11は図1のα部の縦断面図である。図9は、実施の形態1の図2に対応する図である。
(Embodiment 4)
FIG. 11 is a longitudinal sectional view of a part α in FIG. FIG. 9 is a diagram corresponding to FIG. 2 of the first embodiment.

本実施の形態が実施の形態1と異なるのは、図11における上板63(第1板部)と下板73(第2板部)の形状である。上板63(第1板部)と下板73(第2板部)の側面部10bは、前面(意匠板10との組込み位置)において平坦な形状である。説明しない事項は、実施の形態1と同様である。   The present embodiment differs from the first embodiment in the shapes of the upper plate 63 (first plate portion) and the lower plate 73 (second plate portion) in FIG. The side surface portion 10b of the upper plate 63 (first plate portion) and the lower plate 73 (second plate portion) has a flat shape on the front surface (position where the design plate 10 is assembled). Matters not described are the same as those in the first embodiment.

<実施の形態4の効果>
実施の形態1に示した効果(結露防止効果、庫内への熱侵入抑制効果)に加え、平板をベースに構成できるなど、上板63(第1板部)、下板73(第2板部)を簡便に製造することが可能となる。
<Effect of Embodiment 4>
In addition to the effects shown in the first embodiment (an anti-condensation effect and an effect of suppressing heat penetration into the cabinet), an upper plate 63 (first plate portion) and a lower plate 73 (second plate) can be configured with a flat plate as a base. Part) can be easily produced.

簡便な製造方法であっても、軟質複合断熱材11(断熱体)は上板63(第1板部)、下板73(第2板部)と意匠板10の間に強固に圧縮固定されているため、内部のウレタンが漏れ出すことはない。   Even in a simple manufacturing method, the soft composite heat insulating material 11 (heat insulator) is firmly compressed and fixed between the upper plate 63 (first plate portion), the lower plate 73 (second plate portion) and the design plate 10. Therefore, the urethane inside does not leak out.

美観の確保は困難であるが、店舗用の民生冷蔵庫、業務用冷蔵庫など、美観を重視しない冷蔵庫に対しての適用が可能である。   Although it is difficult to ensure aesthetics, it can be applied to refrigerators that do not place aesthetic importance, such as commercial refrigerators for commercial use and commercial refrigerators.

(全体として)
なお、上記実施の形態は、それぞれ組み合わせできる。
(as a whole)
The above embodiments can be combined.

また、上記では、意匠板10の両端を同じ形状とする例であったが、どちらか一方を実施の形態としてもよい。または、両端で異なる実施の形態でもよい。   Moreover, although it was an example which makes the both ends of the design board 10 the same shape in the above, it is good also considering either one as embodiment. Alternatively, different embodiments may be used at both ends.

以上のように、本発明にかかる冷蔵庫は、複数の温度帯の部屋を仕切板で分割する機構を持つあらゆる冷熱機器(民生用冷蔵庫、業務用冷蔵庫、ワインセラーなど)の断熱性向上のために利用可能である。   As described above, the refrigerator according to the present invention is for improving the heat insulation properties of all cooling / heating devices (commercial refrigerators, commercial refrigerators, wine cellars, etc.) having a mechanism that divides a room in a plurality of temperature zones with partition plates. Is available.

1 仕切板
2 第1貯蔵室
3 第2貯蔵室
4 内箱
5 外箱
6 上板(第1板部)
6a 上板前面部
7 下板(第2板部)
7a 下板前面部
8 断熱材
9 放熱パイプ(放熱部)
10 意匠板
10a 前面部
10b 側面部
11 軟質複合断熱材(断熱体)
11a エアロゲル繊維複合層
11b 繊維単独層
11c 不織布繊維
11d エアロゲル
12 取付用リブ
13 ビス穴
15 意匠板
15a 端部
15b 二重折曲げ部
15c 折曲げ平坦部
16 意匠板
16a 第1段差部
16b 第2段差部
19 放熱パイプ
21 仕切板
22 放熱パイプ
23 蓄熱層
24 断熱材
25 意匠板
25a 端部
26 上板
27 下板
28 断熱材
31 仕切板
32 放熱パイプ
33 断熱材
34 断熱材
35 意匠板
35a 前面部
35b 張出端部
35c 脚状端辺
36 仕切壁
37 断熱材
38 上板
39 下板
40 リブ部
50 隙間
61 上板(第1板部)
61b ザグリ
62 上板(第1板部)
62a 鉤戻り部
63 上板(第1板部)
71 下板(第2板部)
72 下板(第2板部)
72a 鉤戻り部
73 下板(第2板部)
99 空隙率
100 断熱箱
DESCRIPTION OF SYMBOLS 1 Partition plate 2 1st storage chamber 3 2nd storage chamber 4 Inner box 5 Outer box 6 Upper board (1st board part)
6a Upper plate front portion 7 Lower plate (second plate portion)
7a Lower plate front part 8 Heat insulation material 9 Heat radiation pipe (heat radiation part)
DESCRIPTION OF SYMBOLS 10 Design board 10a Front part 10b Side part 11 Soft composite heat insulating material (heat insulator)
11a aerogel fiber composite layer 11b single fiber layer 11c non-woven fiber 11d airgel 12 mounting rib 13 screw hole 15 design plate 15a end 15b double bent portion 15c bent flat portion 16 design plate 16a first step portion 16b second step Part 19 Radiation pipe 21 Partition plate 22 Radiation pipe 23 Heat storage layer 24 Heat insulation material 25 Design plate 25a End part 26 Upper plate 27 Lower plate 28 Heat insulation material 31 Partition plate 32 Heat radiation pipe 33 Heat insulation material 34 Heat insulation material 35 Design plate 35a Front part 35b Overhang end portion 35c Leg-shaped end side 36 Partition wall 37 Heat insulating material 38 Upper plate 39 Lower plate 40 Rib portion 50 Clearance 61 Upper plate (first plate portion)
61b Counterbore 62 Upper plate (first plate part)
62a 鉤 Return part 63 Upper plate (first plate part)
71 Lower plate (second plate)
72 Lower plate (second plate part)
72a 鉤 Return part 73 Lower plate (second plate part)
99 Porosity 100 Insulation box

Claims (14)

空間を有する断熱箱本体と、
前記空間を密閉する扉と、
前記空間を仕切る仕切板と、を含み、
前記仕切板は、
前記扉の側に配置された意匠板と、
前記意匠板の両端のそれぞれに配置された第1板部と第2板部と、
前記意匠板と前記第1板部と前記第2板部で囲まれた領域に位置する断熱材と、
前記意匠板と前記第1板部との間、前記意匠板と前記第2板部との間の少なくとも1方に配置された断熱体と、を含む断熱箱。
An insulated box body having a space;
A door that seals the space;
A partition plate for partitioning the space,
The partition plate is
A design board arranged on the door side;
A first plate portion and a second plate portion arranged at both ends of the design plate,
A heat insulating material located in a region surrounded by the design plate, the first plate portion, and the second plate portion;
A heat insulating box including a heat insulator disposed between at least one of the design plate and the first plate portion and between the design plate and the second plate portion.
前記仕切板は、さらに、前記意匠板と接触して配置されている放熱部を有する請求項1記載の断熱箱。 The heat insulation box according to claim 1, wherein the partition plate further includes a heat radiating portion disposed in contact with the design plate. 前記断熱体は圧縮された状態である請求項1または2記載の断熱箱。 The heat insulation box according to claim 1 or 2, wherein the heat insulator is in a compressed state. 前記意匠板と、前記第1板部、または、前記第2板部との間に隙間があり、非接触である請求項1〜3のいずれか1項に記載の断熱箱。 The heat insulation box according to any one of claims 1 to 3, wherein there is a gap between the design plate and the first plate portion or the second plate portion, and there is no contact. 前記意匠板と、前記第1板部、または、前記第2板部とは前記断熱材を介してのみ接触する請求項4に記載の断熱箱。 The heat insulation box according to claim 4 with which said design board and said 1st board part or said 2nd board part contact only via said heat insulating material. 前記断熱材は、前記断熱体と前記意匠板と第1板部と第2板部とで囲まれている請求項1〜5のいずれか1項に記載の断熱箱。 The said heat insulating material is a heat insulation box of any one of Claims 1-5 enclosed with the said heat insulating body, the said design board, the 1st board part, and the 2nd board part. 前記第1板部と前記断熱体と前記意匠板とが積層している請求項1〜6のいずれか1項に記載の断熱箱。 The heat insulation box of any one of Claims 1-6 on which the said 1st board part, the said heat insulator, and the said design board are laminated | stacked. 前記第1板部と前記断熱体と前記意匠板と前記放熱部とが積層している請求項1〜7のいずれか1項に記載の断熱箱。 The heat insulation box of any one of Claims 1-7 on which the said 1st board part, the said heat insulating body, the said design board, and the said thermal radiation part are laminated | stacked. 前記隙間は前記断熱体の厚みより小さい請求項4〜8のいずれか1項に記載の断熱箱。 The said clearance gap is a heat insulation box of any one of Claims 4-8 smaller than the thickness of the said heat insulating body. 前記断熱体は、繊維層と、繊維と断熱材料との複合層とを含む請求項1〜9のいずれか1項に記載の断熱箱。 The said heat insulation body is a heat insulation box of any one of Claims 1-9 containing a fiber layer and the composite layer of a fiber and a heat insulation material. 前記意匠板はコの字形状であり、
前記第1板部、または、前記第2板部は、L字形状である請求項1〜10のいずれか1項に記載の断熱箱。
The design board has a U-shape,
The heat insulation box according to any one of claims 1 to 10, wherein the first plate portion or the second plate portion is L-shaped.
前記第1板部と前記第2板部のいずれかには、前記断熱材が配置される凹部、または、凸部がある請求項1〜10のいずれか1項に記載の断熱箱。 The heat insulation box according to any one of claims 1 to 10, wherein either the first plate portion or the second plate portion has a concave portion or a convex portion in which the heat insulating material is disposed. 前記意匠板は一端が2重構造で、内側に突起があり、前記突起で前記断熱材を保持する請求項1〜10のいずれか1項に記載の断熱箱。 11. The heat insulating box according to claim 1, wherein one end of the design plate has a double structure, a protrusion is provided inside, and the heat insulating material is held by the protrusion. 前記意匠板は一端が階段状である請求項1〜10のいずれか1項に記載の断熱箱。
The heat insulating box according to claim 1, wherein one end of the design plate is stepped.
JP2017103643A 2016-09-09 2017-05-25 Insulation box Expired - Fee Related JP6733606B2 (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
US12535262B2 (en) 2021-08-10 2026-01-27 Samsung Electronics Co., Ltd. Refrigerator

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JPS4822253U (en) * 1971-07-20 1973-03-14
JPS4838469U (en) * 1971-09-10 1973-05-12
JPH10318657A (en) * 1997-05-21 1998-12-04 Hitachi Ltd refrigerator
JP2000046462A (en) * 1998-07-27 2000-02-18 Mitsubishi Electric Corp Insulated box
JP2001280834A (en) * 2000-03-30 2001-10-10 Toshiba Corp Refrigerator partition structure
US20020117949A1 (en) * 2001-02-27 2002-08-29 Nedo Banicevic Refrigerator mullion
JP2015528071A (en) * 2012-06-26 2015-09-24 キャボット コーポレイションCabot Corporation Flexible insulating structure and method for making and using the same

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JPS4822253U (en) * 1971-07-20 1973-03-14
JPS4838469U (en) * 1971-09-10 1973-05-12
JPH10318657A (en) * 1997-05-21 1998-12-04 Hitachi Ltd refrigerator
JP2000046462A (en) * 1998-07-27 2000-02-18 Mitsubishi Electric Corp Insulated box
JP2001280834A (en) * 2000-03-30 2001-10-10 Toshiba Corp Refrigerator partition structure
US20020117949A1 (en) * 2001-02-27 2002-08-29 Nedo Banicevic Refrigerator mullion
JP2015528071A (en) * 2012-06-26 2015-09-24 キャボット コーポレイションCabot Corporation Flexible insulating structure and method for making and using the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12535262B2 (en) 2021-08-10 2026-01-27 Samsung Electronics Co., Ltd. Refrigerator

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