JP2014218470A - Mild acidic transparent cleansing preparation - Google Patents
Mild acidic transparent cleansing preparation Download PDFInfo
- Publication number
- JP2014218470A JP2014218470A JP2013099801A JP2013099801A JP2014218470A JP 2014218470 A JP2014218470 A JP 2014218470A JP 2013099801 A JP2013099801 A JP 2013099801A JP 2013099801 A JP2013099801 A JP 2013099801A JP 2014218470 A JP2014218470 A JP 2014218470A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- fatty acid
- long chain
- cleaning material
- acidic transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 238000002360 preparation method Methods 0.000 title abstract description 6
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- -1 amino acid salt Chemical class 0.000 claims abstract description 12
- 230000007935 neutral effect Effects 0.000 claims abstract description 10
- 125000002252 acyl group Chemical group 0.000 claims abstract description 7
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 6
- 239000011538 cleaning material Substances 0.000 claims description 30
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- 238000005187 foaming Methods 0.000 abstract description 13
- 238000005406 washing Methods 0.000 abstract description 11
- 150000001298 alcohols Chemical class 0.000 abstract description 2
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
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- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
Abstract
Description
本発明は、泡立ち、泡質、泡切れ、洗い流し後の感触等の使用感が良好で、且つ低温での白濁、おりや沈殿物の発生などが認められない、弱酸性透明洗浄料に関する。 The present invention relates to a weakly acidic transparent cleaning material which has a good feeling of use such as foaming, foam quality, foam breakage, and feel after washing, and is free from cloudiness at low temperature, generation of odors and precipitates.
最近、主として手や身体の洗浄用として、ポンプ式容器や泡吐出型容器等に収納される液状洗浄料が普及してきた。ここで従来、皮膚洗浄料において、脂肪酸石鹸（アルカリ性）が、起泡力および洗浄力等に優れることから多用されている（特許文献１、特許文献２、特許文献３参照）が、これらは一方で、皮膚への刺激性や、洗浄後の肌のつっぱり感といった問題を有している。これは、人の肌が本来弱酸性であるため、これらアルカリ性の石鹸で洗うと、肌のｐＨが一時的にアルカリ性に傾き、洗浄後肌が弱酸性に戻るまでに一定の時間がかかるため肌に対して負担が大きい事や、洗浄による過度の脱脂によるためである。 Recently, liquid cleaning materials stored in pump-type containers or foam discharge-type containers have been widely used mainly for washing hands and bodies. Heretofore, fatty acid soap (alkaline) has been frequently used in skin cleansing materials because of its excellent foaming power and detergency (see Patent Document 1, Patent Document 2, and Patent Document 3). Therefore, it has problems such as irritation to the skin and a feeling of tightness of the skin after washing. This is because human skin is inherently weakly acidic, so washing with these alkaline soaps will cause the pH of the skin to temporarily become alkaline, and it will take some time for the skin to return to weakly acidic after washing. This is because the load is large and excessive degreasing by washing.
またＮ−長鎖アシル中性アミノ酸またはその塩は、低刺激性で泡立ち、すすぎ性に優れた洗浄剤として、皮膚洗浄料に広く使用されてきた。（特許文献４、５、６、７） Further, N-long chain acyl neutral amino acids or salts thereof have been widely used in skin cleansers as a cleansing agent with low irritation, foaming and excellent rinsing properties. (Patent Documents 4, 5, 6, and 7)
さらに、長鎖脂肪酸アミドプロピルベタインを洗浄料に配合する検討も数多くなされている（特許文献８〜１２参照）。 Further, many studies have been made on blending long-chain fatty acid amidopropyl betaine into a cleaning material (see Patent Documents 8 to 12).
洗浄料に非イオン性界面活性剤の一種である脂肪酸アルカノールアミド系界面活性剤は洗浄剤に配合することにより起泡力や洗浄力、安定性、感触の良さ、粘度を高める効果を奏することが知られている（特許文献８、特許文献１２参照）。 Fatty acid alkanolamide surfactant, which is a kind of nonionic surfactant in detergent, has the effect of increasing foaming power, detergency, stability, good touch and viscosity by blending in detergent. Known (see Patent Document 8 and Patent Document 12).
しかしながら、これらの成分を併用して配合した場合、低温での白濁が認められ、安定性の良好な弱酸性透明洗浄料はこれまで得られていない。したがって、本発明においては、泡立ち、泡質、泡切れ、洗い流し後の感触等の使用感が良好で、且つ低温での白濁、おりや沈殿物の発生が認められない、弱酸性透明洗浄料を提供することを課題とする。 However, when these components are used in combination, white turbidity at a low temperature is observed, and a weakly acidic transparent cleaning material having good stability has not been obtained so far. Therefore, in the present invention, a weakly acidic transparent cleaning material that has good feeling of use such as foaming, foam quality, foam breakage, touch after washing, etc., and no cloudiness at low temperature, no occurrence of odor or precipitate is observed. The issue is to provide.
下記の（Ａ）〜（Ｅ）
（Ａ）長鎖アシル中性アミノ酸塩 ２〜２０質量％
（Ｂ）長鎖脂肪酸アミドプロピルベタイン １〜２０質量％
（Ｃ）長鎖脂肪酸ジエタノールアミド ０．３〜６質量％
（Ｄ）ｐＨ調整剤 ０．０１〜１質量％
（Ｅ）アルコール類 ０．１〜５質量％
を含有する弱酸性透明洗浄料を提供する。
The following (A)-(E)
(A) Long chain acyl neutral amino acid salt 2 to 20% by mass
(B) Long chain fatty acid amidopropyl betaine 1-20 mass%
(C) Long chain fatty acid diethanolamide 0.3-6 mass%
(D) pH adjuster 0.01-1 mass%
(E) Alcohol 0.1-5 mass%
A weakly acidic transparent cleaning material containing
本発明の弱酸性透明洗浄料は、低温での白濁、おりや沈殿物の発生を防止でき、経時安定性が良好であるという効果を発揮する。また、成分（Ａ）〜（Ｄ）を併用して用いることにより、泡立ち、泡質、泡切れ、洗い流し後の感触等の使用感が、良好であるという効果を発揮する。 The weakly acidic transparent cleaning material of the present invention can prevent the occurrence of cloudiness at a low temperature, the occurrence of odors and precipitates, and exhibits the effect of good stability over time. In addition, by using the components (A) to (D) in combination, an effect that the feeling of use such as foaming, foam quality, foam breakage, touch after washing, etc. is good is exhibited.
以下本発明を実施するための形態を説明する。 Hereinafter, modes for carrying out the present invention will be described.
本発明の弱酸性透明洗浄料は、（Ａ）〜（Ｅ）
（Ａ）長鎖アシル中性アミノ酸塩 ２〜２０質量％
（Ｂ）長鎖脂肪酸アミドプロピルベタイン １〜２０質量％
（Ｃ）長鎖脂肪酸ジエタノールアミド ０．３〜６質量％
（Ｄ）ｐＨ調整剤 ０．０１〜１質量％
（Ｅ）アルコール類 ０．１〜５質量％
を含有することを特徴とする。
The weakly acidic transparent cleaning material of the present invention is (A) to (E).
(A) Long chain acyl neutral amino acid salt 2 to 20% by mass
(B) Long chain fatty acid amidopropyl betaine 1-20 mass%
(C) Long chain fatty acid diethanolamide 0.3-6 mass%
(D) pH adjuster 0.01-1 mass%
(E) Alcohol 0.1-5 mass%
It is characterized by containing.
本発明の弱酸性透明洗浄料に配合する（Ａ）長鎖アシル中性アミノ酸塩は、Ｎ−アシルアミノ酸系界面活性剤として公知の化合物であり、アシル化部分（ＲＣＯ−）の炭素数については、１０〜２２が好ましく、より好ましくは１２〜１８である。炭素数が１０未満であると製剤の泡立ちが低下し、炭素数が２２を越えると、製剤の泡切れが低下する。また、直鎖、分岐及び飽和、不飽和に関わらず使用することができるが、直鎖の方が泡立ちの点で好ましく、飽和の方が製剤の安定性の点で好ましい。特に好ましいのは、炭素数が１２の直鎖アシル基及びこれを主成分とするヤシ油脂肪酸アシル基である。 The (A) long-chain acyl neutral amino acid salt to be blended in the weakly acidic transparent detergent of the present invention is a compound known as an N-acylamino acid surfactant, and the carbon number of the acylated moiety (RCO-) is as follows. 10-22 are more preferable, and 12-18 are more preferable. When the carbon number is less than 10, the foaming of the preparation is reduced, and when the carbon number exceeds 22, the foaming of the preparation is reduced. Moreover, it can be used regardless of whether it is linear, branched, saturated or unsaturated, but the straight chain is preferable in terms of foaming, and the saturation is preferable in terms of stability of the preparation. Particularly preferred are a linear acyl group having 12 carbon atoms and a coconut oil fatty acid acyl group containing the same as the main component.
アミノ酸部位については、アラニン，グリシンなどが好ましく、具体的には、Ｎ−ヤシ油脂肪酸アシルグリシンカリウム，Ｎ−ヤシ油脂肪酸アシルグリシンナトリウム，Ｎ−ヤシ油脂肪酸アシルグリシントリエタノールアミン，Ｎ−ラウロイルグリシンカリウム，Ｎ−ラウロイルグリシンナトリウム，Ｎ−ラウロイルグリシントリエタノールアミン，Ｎ−ステアロイルグリシンカリウム，Ｎ−ステアロイルグリシンナトリウム，Ｎ−ステアロイルグリシントリエタノールアミン，Ｎ−ヤシ油脂肪酸アシル−ＤＬ−アラニンカリウム，Ｎ−ヤシ油脂肪酸アシル−ＤＬ−アラニンナトリウム，Ｎ−ヤシ油脂肪酸アシル−ＤＬ−アラニントリエタノールアミン，Ｎ−ラウロイル−ＤＬ−アラニンカリウム，Ｎ−ラウロイル−ＤＬ−アラニンナトリウム，Ｎ−ラウロイル−ＤＬ−アラニントリエタノールアミン，Ｎ−ステアロイル−ＤＬ−アラニンカリウム，Ｎ−ステアロイル−ＤＬ−アラニンナトリウム，Ｎ−ステアロイル−ＤＬ−アラニントリエタノールアミン，Ｎ−ヤシ油脂肪酸メチル−β−アラニンカリウム，Ｎ−ヤシ油脂肪酸メチル−β−アラニンナトリウム，Ｎ−ヤシ油脂肪酸メチル−β−アラニントリエタノールアミン，Ｎ−ラウロイルメチル−β−アラニンカリウム，Ｎ−ラウロイルメチル−β−アラニンナトリウム，Ｎ−ラウロイルメチル−β−アラニントリエタノールアミン，Ｎ−ステアロイルメチル−β−アラニンカリウム，Ｎ−ステアロイルメチル−β−アラニンナトリウム，Ｎ−ステアロイルメチル−β−アラニントリエタノールアミンなどが例示され、これらより１種または２種以上を選択して用いる。Ｎ−アシル中性アミノ酸におけるアミノ酸としては、Ｄ−体，Ｌ−体及びＤＬ−体のいずれを用いてもよい。本発明におけるＮ−アシル中性アミノ酸塩はそれぞれ単独でも、又は二種以上を併用して用いても良い。またＮ−アシル中性アミノ酸塩を弱酸性透明洗浄料に配合する場合、水溶液として市販されているものを利用することもできる。 As for the amino acid site, alanine, glycine and the like are preferable, and specifically, N-coconut oil fatty acid acylglycine potassium, N-coconut oil fatty acid acylglycine sodium, N-coconut oil fatty acid acylglycine triethanolamine, N-lauroylglycine. Potassium, N-lauroylglycine sodium, N-lauroylglycine triethanolamine, N-stearoylglycine potassium, N-stearoylglycine sodium, N-stearoylglycine triethanolamine, N-coconut oil fatty acid acyl-DL-alanine potassium, N- Palm oil fatty acid acyl-DL-alanine sodium, N-coconut oil fatty acid acyl-DL-alanine triethanolamine, N-lauroyl-DL-alanine potassium, N-lauroyl-DL-alanine sodium , N-lauroyl-DL-alanine triethanolamine, N-stearoyl-DL-alanine potassium, N-stearoyl-DL-alanine sodium, N-stearoyl-DL-alanine triethanolamine, N-coconut oil fatty acid methyl-β- Alanine potassium, N-coconut oil fatty acid methyl-β-alanine sodium, N-coconut oil fatty acid methyl-β-alanine triethanolamine, N-lauroylmethyl-β-alanine potassium, N-lauroylmethyl-β-alanine sodium, N -Lauroylmethyl-β-alanine triethanolamine, N-stearoylmethyl-β-alanine potassium, N-stearoylmethyl-β-alanine sodium, N-stearoylmethyl-β-alanine triethanolamine, etc. Or selected and used two or more. As the amino acid in the N-acyl neutral amino acid, any of D-form, L-form and DL-form may be used. The N-acyl neutral amino acid salts in the present invention may be used alone or in combination of two or more. Moreover, when mix | blending N-acyl neutral amino acid salt with a weak acidic transparent cleaning material, what is marketed as aqueous solution can also be utilized.
Ｎ−アシル中性アミノ酸塩の配合量は、弱酸性透明洗浄料全量に対して、２〜２０質量％である。２質量％未満の配合では充分な洗浄力が得られない場合がある。２０質量％を超えると透明の外観を保てない場合がある。 The compounding quantity of N-acyl neutral amino acid salt is 2-20 mass% with respect to weak acidic transparent cleaning material whole quantity. If the blending is less than 2% by mass, sufficient detergency may not be obtained. If it exceeds 20% by mass, a transparent appearance may not be maintained.
本発明の弱酸性透明洗浄料に配合する（Ｂ）長鎖脂肪酸アミドプロピルベタインは、アミドベタイン型両性界面活性剤であり、脂肪酸、脂肪酸エステル又は植物油とジメチルプロピレンジアミンから脂肪酸アミドアミンを合成し、モノクロロ酢酸ナトリウムを反応させて得られる脂肪酸アミドプロピルジメチルアミノ酢酸ベタインである。 (B) Long-chain fatty acid amidopropyl betaine to be blended in the weakly acidic transparent detergent of the present invention is an amidobetaine type amphoteric surfactant, which synthesizes fatty acid amidoamine from fatty acid, fatty acid ester or vegetable oil and dimethylpropylenediamine, It is fatty acid amidopropyldimethylaminoacetic acid betaine obtained by reacting sodium acetate.
脂肪酸の炭素数は８〜２２の範囲であり、飽和、不飽和、直鎖、分岐鎖のいずれでも良い。すなわち、ラウリン酸、ミリスチン酸、パルミチン酸、オレイン酸といった単体脂肪酸、ヤシ油脂肪酸、パーム核油脂肪酸といった混合脂肪酸が該当する。本発明における長鎖脂肪酸アミドプロピルベタインはそれぞれ単独でも、又は二種以上を併用して用いても良い。また長鎖脂肪酸アミドプロピルベタインを弱酸性透明洗浄料に配合する場合、水溶液として市販されているものを利用することもできる。 The number of carbon atoms of the fatty acid is in the range of 8 to 22, and may be any of saturated, unsaturated, straight chain, and branched chain. That is, it includes simple fatty acids such as lauric acid, myristic acid, palmitic acid and oleic acid, and mixed fatty acids such as coconut oil fatty acid and palm kernel oil fatty acid. The long-chain fatty acid amidopropyl betaines in the present invention may be used alone or in combination of two or more. Moreover, when mix | blending long-chain fatty-acid amide propyl betaine with a weak acidic transparent cleaning material, what is marketed as aqueous solution can also be utilized.
成分（Ｂ）長鎖脂肪酸アミドプロピルベタインは、弱酸性透明洗浄料全量に対し、１〜２０質量％配合する。１質量％未満の配合では泡立ち及び泡の安定性が低下し、洗浄後の肌のつっぱり感が大きくなる場合がある。２０質量％を超えると透明な外観を保てない場合がある。 Component (B) long chain fatty acid amidopropyl betaine is mix | blended 1-20 mass% with respect to weak acidic transparent cleaning material whole quantity. When the blending amount is less than 1% by mass, foaming and foam stability are lowered, and the feeling of tightness of the skin after washing may be increased. If it exceeds 20% by mass, a transparent appearance may not be maintained.
本発明の弱酸性透明洗浄料に配合する（Ｃ）長鎖脂肪酸ジエタノールアミドとしては、特に限定されないが好ましくは総炭素数９〜２６のもの、さらに総炭素数が１２〜２２の脂肪酸ジエタノールアミドが使用感等の上で好ましい。具体例として、ラウリン酸ジエタノールアミド、ミリスチン酸ジエタノールアミド、ヤシ油脂肪酸ジエタノールアミド等が挙げられる。本発明における長鎖脂肪酸ジエタノールアミドはそれぞれ単独でも、又は二種以上を併用して用いても良い。 The long-chain fatty acid diethanolamide (C) to be blended in the weakly acidic transparent cleaning material of the present invention is not particularly limited, but is preferably a fatty acid diethanolamide having a total carbon number of 9 to 26 and further having a total carbon number of 12 to 22. It is preferable in terms of usability. Specific examples include lauric acid diethanolamide, myristic acid diethanolamide, coconut oil fatty acid diethanolamide, and the like. The long chain fatty acid diethanolamides in the present invention may be used alone or in combination of two or more.
（Ｃ）長鎖脂肪酸ジエタノールアミドは、弱酸性透明洗浄料全量に対し、０．３〜６質量％配合する。０．３質量％未満の配合では透明な外観を保てなくなる場合がある泡質やすすぎ感触が損なわれる場合がある。６質量％を超えて配合すると泡質やすすぎ感触が損なわれる場合がある。 (C) The long chain fatty acid diethanolamide is blended in an amount of 0.3 to 6% by mass based on the total amount of the weakly acidic transparent cleaning material. When the blending amount is less than 0.3% by mass, the transparent appearance may not be maintained, and the foam quality and the excessive feeling may be impaired. If it exceeds 6% by mass, the foam quality and the excessive feeling may be impaired.
本発明の弱酸性透明洗浄料に配合する（Ｄ）ｐＨ調整剤としては、特に限定されないが好ましくは乳酸、クエン酸、リン酸、リンゴ酸、及びこれらの塩などが例示される。ｐＨ調整剤はそれぞれ単独でも、又は二種以上を併用して用いても良い。 The (D) pH adjuster to be blended in the weakly acidic transparent cleaning material of the present invention is not particularly limited, but preferably exemplified is lactic acid, citric acid, phosphoric acid, malic acid, and salts thereof. The pH adjusters may be used alone or in combination of two or more.
（Ｄ）ｐＨ調整剤は、洗浄料のｐＨを４．５〜６．５程度の適度な弱酸性のｐＨを保つために必要な量、すなわち弱酸性透明洗浄料全量に対し、０．０１〜１質量％配合する。 (D) The pH adjuster is an amount necessary for maintaining the pH of the cleaning material at a moderately weak acidic pH of about 4.5 to 6.5, that is, 0.01 to the total amount of the weak acidic transparent cleaning material. 1% by mass is blended.
本発明の弱酸性透明洗浄料に配合する（Ｅ）アルコール類としては、特に限定されないが、エタノール、フェノキシエタノールから選択される１種又は２種を用いることが好ましい。アルコール類は弱酸性透明洗浄料全量に対し、０．１〜５質量％配合することが好ましい。５質量％を超えて配合すると、起泡力が低下する場合がある。０．１質量％未満の配合では、透明な外観を保てなくなる場合がある。 Although it does not specifically limit as (E) alcohol mix | blended with the weakly acidic transparent cleaning material of this invention, It is preferable to use 1 type, or 2 types selected from ethanol and phenoxyethanol. The alcohol is preferably blended in an amount of 0.1 to 5% by mass with respect to the total amount of the weakly acidic transparent cleaning material. When it exceeds 5 mass%, foaming power may be reduced. If it is less than 0.1% by mass, a transparent appearance may not be maintained.
本発明の弱酸性透明洗浄料には、上記（Ａ）〜（Ｅ）に加えて、多価アルコールを配合することが好ましい。多価アルコールとしては、ポリエチレングリコール，プロピレングリコール，ジプロピレングリコール，１，３−ブチレングリコール等のグリコール類、グリセリン、ジグリセリン，デカグリセリン等のポリグリセリン類、グリセリンモノパルミチルエーテル（キミルアルコール），グリセリンモノステアリルエーテル（バチルアルコール），グリセリンモノオレイルエーテル（セラキルアルコール）等のグリセリンモノエーテル類、エリスリトール，スレイトール，ペンタエリスリトール，アドニトール，アラビトール，キシリトール，ソルビトール，マンニトール，ガラクチトール，イノシトール，マルチトール等の糖アルコール類、ブドウ糖，ショ糖等の糖類が挙げられ、これらより１種又は２種以上を選択して用いることができる。これらの多価アルコールの中でも、ジプロピレングリコール、１，３−ブチレングリコール、グリセリン、ショ糖から選択される１種又は２種以上を用いることが好ましい。 In addition to the above (A) to (E), it is preferable to add a polyhydric alcohol to the weakly acidic transparent cleaning material of the present invention. Polyhydric alcohols include glycols such as polyethylene glycol, propylene glycol, dipropylene glycol, and 1,3-butylene glycol, polyglycerols such as glycerin, diglycerin, and decaglycerin, and glycerin monopalmityl ether (chymyl alcohol). Glycerol monoethers such as glycerol monostearyl ether (batyl alcohol) and glycerol monooleyl ether (ceralkyl alcohol), erythritol, threitol, pentaerythritol, adonitol, arabitol, xylitol, sorbitol, mannitol, galactitol, inositol, maltitol Sugar alcohols such as glucose, saccharides such as glucose and sucrose, and one or more of these can be selected and used. Among these polyhydric alcohols, it is preferable to use one or more selected from dipropylene glycol, 1,3-butylene glycol, glycerin, and sucrose.
これら多価アルコールの弱酸性透明洗浄料における含有量は、２０質量％未満であり、好ましくは１〜２０質量％、さらに好ましくは１〜２０質量とする。２０質量％以上配合すると使用時のべたつきの原因となったり、洗浄力が低下する場合がある。 The content of these polyhydric alcohols in the weakly acidic transparent cleaning material is less than 20% by mass, preferably 1 to 20% by mass, and more preferably 1 to 20% by mass. If blended in an amount of 20% by mass or more, it may cause stickiness during use or the cleaning power may be reduced.
本発明の弱酸性透明洗浄料は、常温で透明な液状若しくはゲル状の外観を呈する。 The weakly acidic transparent cleaning material of the present invention exhibits a transparent liquid or gel appearance at room temperature.
本発明において透明とは、３０ｍＬのガラス製マヨネーズ瓶に洗浄料を静かに注ぎ、ガラス越しにフォントＭＳゴシック、サイズ１０の文字が明瞭に見えること、また目視にて沈殿物、白濁やおりが発生していないこと、を言う。 In the present invention, “transparent” means that a cleaning material is gently poured into a 30 mL glass mayonnaise bottle, font MS Gothic, size 10 characters can be clearly seen through the glass, and precipitates and cloudiness are generated visually. Say, not doing.
本願発明の弱酸性透明洗浄料には、上述の必須成分、任意成分の他に、必要に応じて通常洗浄料に配合される、水性成分、油性成分、保湿剤、色素、界面活性剤、紫外線吸収剤、増粘剤、薬剤、香料、高分子物質、防菌防微剤、アルコール類、生体由来成分等を適宜配合することができる。 In addition to the above-mentioned essential components and optional components, the weakly acidic transparent cleaning material of the present invention includes an aqueous component, an oily component, a moisturizing agent, a dye, a surfactant, and an ultraviolet ray, which are usually added to the cleaning agent as necessary. Absorbers, thickeners, drugs, fragrances, polymer substances, antibacterial / antifungal agents, alcohols, biological components and the like can be appropriately blended.
本発明の弱酸性透明洗浄料は、例えば、洗顔料、ボディソープ、ハンドソープ等として適用することができる。 The weakly acidic transparent cleaning material of the present invention can be applied as, for example, a face wash, body soap, hand soap and the like.
以下、実施例により本発明を具体的に説明するが、これにより本発明の範囲が限定されるものではない。なお、配合量は特に断りのない限り質量％である。 EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the scope of the present invention is not limited thereby. The blending amount is mass% unless otherwise specified.
まず、調製した洗浄料の評価方法を説明する。 First, a method for evaluating the prepared cleaning material will be described.
［安定性（２５℃）（５℃）］
調製した洗浄料を２５℃若しくは５℃恒温槽にて１ヶ月静置し、状態の確認を目視で行った。評価は、３０ｍＬのガラス製マヨネーズ瓶に洗浄料を静かに注ぎ、ガラス越しにフォントＭＳゴシック、サイズ１０の文字が明瞭に見えるかどうか、また沈殿物、おり、白濁が発生していないかどうかを目視で判断し、明瞭に見え沈殿物、おり、白濁が発生していないものを「○」、見えづらい若しくは沈殿物、おり、白濁が発生しているものを「×」とした。
[Stability (25 ° C) (5 ° C)]
The prepared cleaning material was allowed to stand in a thermostatic bath at 25 ° C. or 5 ° C. for 1 month, and the state was visually confirmed. The evaluation was made by gently pouring the cleaning material into a 30 mL glass mayonnaise bottle, and checking whether the font MS Gothic, size 10 characters can be clearly seen through the glass, and whether there is a precipitate, white turbidity. Judgment was made visually, and the precipitates that were clearly visible and had no white turbidity were evaluated as “◯”, and those that were difficult to see or had white turbidity were evaluated as “X”.
［泡立ち、泡質、泡切れ］
泡立ち、泡質、泡切れについて、官能評価専門調査員３名が実際に使用してそれぞれ評価を行い、合議により良好「○」、やや良好「△」、不良「×」として評価した。
[Bubbling, foam quality, out of foam]
For the foaming, foam quality, and foam breakage, three experts for sensory evaluation actually used and evaluated each, and evaluated by the consensus as “good”, “good” Δ, and “bad”.
［きしみ］
ヘアシャンプーにおいては、きしみについて、官能評価専門調査員３名が実際に使用してそれぞれシャンプー中の毛髪のきしみ感の評価を行い、合議によりきしまない「○」、ややきしむ「△」、きしむ「×」として評価した。
[Squeaking]
In hair shampoos, three experts specializing in sensory evaluation of squeak are used to evaluate the squeaky feeling of the hair in each shampoo. Evaluated as “x”.
［使用後感］
使用後感について、官能評価専門調査員３名が実際に使用してそれぞれ評価を行い、合議により、しっとりする「○」、ややしっとりする「△」、乾燥する「×」として評価した。
[Feeling after use]
After use, three sensory evaluation specialists actually used it and evaluated it, and, according to the discussion, evaluated as “O” to be moist, “Δ” to be slightly moist, and “X” to be dried.
表１、２に示す処方にて、ボディソープを調製し、評価を行った。 Body soaps were prepared and evaluated according to the formulations shown in Tables 1 and 2.
表１に示したとおり、実施例１のボディシャンプーは、エタノールを添加することにより、低温での白濁が防止でき、使用感の良好なものであった。また、併用する界面活性剤の量目が範囲外の比較例２〜７においては、使用感に悪影響を及ぼしたり、透明な性状を保つことができなかった。 As shown in Table 1, the body shampoo of Example 1 was able to prevent white turbidity at a low temperature by adding ethanol, and had good usability. Further, in Comparative Examples 2 to 7 in which the amount of the surfactant used in combination was out of the range, the feeling of use was adversely affected and the transparent properties could not be maintained.
［実施例２］ ボディシャンプー
(１)精製水 １００あわせ
(２)ヤシ油脂肪酸アシルグリシンカリウム ９．０
(３)イステアラミドプロピルベタイン ９．０
(４)ヤシ油脂肪酸ジエタノールアミド ３．５
(５)クエン酸 ０．３
(６)グリセリン ５．０
(７)フェノキシエタノール ０．７
(８)グリチルリチン酸ジカリウム ０．０２
[Example 2] Body shampoo
(1) 100 purified water
(2) Palm oil fatty acid acylglycine potassium 9.0
(3) Istearamidopropyl betaine 9.0
(4) Palm oil fatty acid diethanolamide 3.5
(5) Citric acid 0.3
(6) Glycerin 5.0
(7) Phenoxyethanol 0.7
(8) Dipotassium glycyrrhizinate 0.02
［実施例３］ ポンプフォーマー容器入り泡洗顔
(１)精製水 １００あわせ
(２)ヤシ油脂肪酸アシルグリシンカリウム ３．０
(３)イステアラミドプロピルベタイン ３．０
(４)ヤシ油脂肪酸ジエタノールアミド １．０
(５)クエン酸 ０．１
(６)グリセリン ３．０
(７)エタノール ０．５
(８)サリチル酸 ０．０５
[Example 3] Foam face washing in a pump former container
(1) 100 purified water
(2) Palm oil fatty acid acylglycine potassium 3.0
(3) Istearamidopropyl betaine 3.0
(4) Palm oil fatty acid diethanolamide 1.0
(5) Citric acid 0.1
(6) Glycerin 3.0
(7) Ethanol 0.5
(8) Salicylic acid 0.05
［実施例４］ シャンプー
(１)精製水 １００あわせ
(２)ヤシ油脂肪酸アシルグリシンカリウム ５．０
(３)コカミドプロピルベタイン ５．０
(４)ヤシ油脂肪酸ジエタノールアミド ４．０
(５)ポリクオタニウム−５２ ０．０５
(６)ココイルメチルアラニンナトリウム ４．０
(７)クエン酸 ０．３
(８)１，３−ブチレングリコール ５．０
(９)フェノキシエタノール ０．５
(10)エタノール １．０
(11)ピロクトンオラミン ０．０５
Example 4 Shampoo
(1) 100 purified water
(2) Palm oil fatty acid acylglycine potassium 5.0
(3) Cocamidopropyl betaine 5.0
(4) Palm oil fatty acid diethanolamide 4.0
(5) Polyquaternium-52 0.05
(6) Sodium cocoylmethylalanine 4.0
(7) Citric acid 0.3
(8) 1,3-butylene glycol 5.0
(9) Phenoxyethanol 0.5
(10) Ethanol 1.0
(11) Piroctone olamine 0.05
Claims (2)
（Ａ）長鎖アシル中性アミノ酸塩 ２〜２０質量％
（Ｂ）長鎖脂肪酸アミドプロピルベタイン １〜２０質量％
（Ｃ）長鎖脂肪酸ジエタノールアミド ０．３〜６質量％
（Ｄ）ｐＨ調整剤 ０．０１〜１質量％
（Ｅ）アルコール類 ０．１〜５質量％
含有する弱酸性透明洗浄料。 (A) long chain acyl neutral amino acid salt 2-20% by mass
(B) Long chain fatty acid amidopropyl betaine 1-20 mass%
(C) Long chain fatty acid diethanolamide 0.3-6 mass%
(D) pH adjuster 0.01-1 mass%
(E) Alcohol 0.1-5 mass%
Contains weakly acidic transparent cleaning material.
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| JP2019014691A (en) * | 2017-07-10 | 2019-01-31 | クラシエホームプロダクツ株式会社 | Detergent composition |
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