JP2014019699A - Spray-type foam cleaning agent composition - Google Patents

Abstract

[PROBLEMS] To perform a general cleaning function without using a surfactant, and it is possible to remove cosmetics such as make-up and color cosmetics that are difficult to clean due to the use of a silicon compound as a main base material. A jet foam cleaning composition is provided.
The jet type foam cleaning composition of the present invention includes at least one foam-forming foam composition in a foam-forming container comprising a mono C1-C4 alkyl ether of an ethylene glycol oligomer and a mono C1-C4 alkyl ether of a propylene glycol oligomer. It comprises a liquid cosmetic composition containing a selected first component and a second component selected from one or more polyols.
[Selection] Figure 1

Description

  The present invention relates to a jet-type foam cleaning composition, and more specifically, it not only functions as a general cleaning without using a surfactant, but also has a silicon compound as a main base material, so that cleaning is difficult. The present invention relates to a jet type foam cleaning composition capable of removing cosmetics such as makeup and color cosmetics at a time.

  For most modern women, makeup is generally accepted. However, if the makeup is not removed cleanly, skin troubles will occur, so it is recognized that pursuit of beauty, which is the original purpose of makeup, cannot be achieved, and that removing makeup is an important factor. ing.

  Generally, makeup is simply removed by first wiping with a cosmetic tissue or buff, followed by secondary removal with makeup-removing oil or creasing cream that can dissolve the makeup, and finally soap. Alternatively, a method of washing the face using a creasing foam is adopted. Therefore, it takes a long time to perform cleaning, and the cleaning must be performed step by step several times.

  In addition, soaps or cleansers used for cleaning contain a surfactant, and the surfactant remaining on the skin after cleaning may cause skin problems such as pruritus and atopy, and may have a harmful effect on the human body. There is a drawback of giving.

  Commercially available products include cleansing foams, facial cleansing creams, and products that can be easily used by forming bubbles when they are discharged using containers or aerosol mousse type containers. There is a drawback that the mixed color cosmetics, makeup, UV-cutting agents and the like are not washed well.

  In addition, in order to perform cleaning, most of the cleaning agent must be foamed in advance, and the entire surface of the portion to be cleaned is cleaned regardless of the portion where much makeup is applied. In addition, there is an annoyance that it is necessary to more intensively clean the portion where the cleaning is insufficient.

  Therefore, it is possible to exhibit excellent cleaning power without using a surfactant, to clean cleanly at once without troublesome cleaning over the secondary or tertiary, and to make the cleaning power effective. Without foaming in advance, the foam can be formed when it is discharged from the container and can be used easily by the user. There is a need for detergent compositions and formulations that can be identified.

  The object of the present invention is not only to perform a general cleaning function without using a surfactant, but also to use a silicon compound as a main base material, so that cosmetics such as makeup and color cosmetics that are difficult to clean can be used at once. It is an object of the present invention to provide an injection-type foam cleaning composition that can be dropped.

  In order to achieve the above object, the present invention provides a foam-forming container in which at least one selected from the group consisting of mono-C1-C4 alkyl ethers of ethylene glycol oligomers and mono-C1-C4 alkyl ethers of propylene glycol oligomers. There is provided an injection-type foam cleaning composition comprising a liquid cosmetic composition containing one component and a second component selected from one or more polyols.

  In the spray-type foam cleaning composition according to the present invention, the foam-forming container is preferably an aerosol type or a pump type.

  The aerosol-type foam-forming container preferably contains 70 to 99.9% by weight of the liquid cosmetic composition and 0.1 to 30% by weight of a propellant.

  In the jet foam cleaning composition according to the present invention, the first component of the liquid cosmetic composition is 0.5 to 10% by weight and the second component is based on the total weight of the liquid cosmetic composition. It is preferably contained within a range of 1 to 40% by weight.

  The mono-C1-C4 alkyl ether of the ethylene glycol oligomer and the mono-C1-C4 alkyl ether of the propylene glycol oligomer that are the first component of the liquid cosmetic composition are ethoxydiglycol, diethoxydiglycol, methoxydiglycol, It can be selected from dimethoxydiglycol, butoxydiglycol, methoxytriglycol and ethoxytriglycol.

  In addition, the polyol which is the second component of the liquid cosmetic composition is polyethylene glycol; polypropylene glycol; glycerin; diglycerin; propylene glycol; dipropylene glycol; butylene glycol; methyl glutes-10; polyethylene glycol composed of ethylene oxide and glycerin. It is preferably selected from the group consisting of ethers; and derivatives thereof.

Since the polyethylene glycol (H (OCH ₂ CH ₂ ) _n OH) and the polypropylene glycol (H (OCH ₂ CH ₂ CH ₂ ) _n OH) are difficult to hydrate with water if n is 1000 or more, Those having an easy sum and n of 1,000 or less can be used, and most preferably 600 or less in a liquid state.

  The polyethylene glycol ether composed of ethylene oxide and glycerin is composed of glycereth-6, glyceres-7, glyceres-8, glyceres-12, glyceres-18, glyceres-20, glyceres-26, and glyceres-31. The derivatives thereof selected from the group include glyceres-7 benzoate, glyceres-18 benzoate, glyceres-20 benzoate, glyceres-7 diisononanoate, glyceres-18 ethylhexanoate, glyceres-7 glycolate, glyceres-8 Selected from the group consisting of hydroxystearate, glyceres-6 tricocoate, glyceres-6 triisostearate, glyceres-7 trimethyl ether, and glyceres-6 trioleate. It is preferred.

  The propellant is preferably selected from the group consisting of liquefied petroleum gas, dimethyl ether, n-butane, carbon dioxide and nitrogen.

  The jet type foam cleaning composition according to the present invention can exhibit excellent cleaning power without using a surfactant.

  In addition, in order to remove cosmetics such as makeup and color cosmetics that are difficult to clean due to the use of a silicon-based compound as a main base material, a general cleaning agent requires troublesome cleaning over the second or third order. On the other hand, with the jet type foam cleaning composition according to the present invention, makeup can be removed at once.

It is a photograph which shows the result of having tested the cleaning power of the injection-type foam cleaning composition which concerns on this invention. It is a photograph which shows the result of having tested the foam removal ability of the injection-type foam cleaning composition which concerns on this invention.

  Hereinafter, the present invention will be described in more detail.

  In the foam forming container, the present invention includes a first component selected from the group consisting of a mono C1-C4 alkyl ether of an ethylene glycol oligomer and a mono C1-C4 alkyl ether of a propylene glycol oligomer, and one type from a polyol. A jet-type foam cleaning composition comprising a liquid cosmetic composition containing the second component selected above.

  The liquid cosmetic composition contained in the injection-type foam cleaning composition according to the present invention comprises an ethylene glycol oligomer mono C1-C4 alkyl ether and a propylene glycol oligomer based on the total weight of the liquid cosmetic composition. 1 to 0.5% by weight of a first component selected from the group consisting of mono C1 to C4 alkyl ethers and 1 to 40% by weight of a polyol as a second component.

  In the jet-type foam cleaning composition according to the present invention, from the group consisting of a mono C1-C4 alkyl ether of an ethylene glycol oligomer and a mono C1-C4 alkyl ether of a propylene glycol oligomer, which is the first component of the liquid cosmetic composition. One or more selected ingredients can act on the silicon compound as a solvent to exert detergency, and can remove oils, fatty acids and silicon compounds mainly used in cosmetics, especially in general detergents Silicon compounds that are difficult to remove can be effectively removed.

  Specific examples of the mono C1-C4 alkyl ether of the ethylene glycol oligomer and the mono C1-C4 alkyl ether of the propylene glycol oligomer include ethoxy diglycol, diethoxy diglycol, methoxy diglycol, dimethoxy diglycol, butoxy diglycol, Although methoxytriglycol, ethoxytriglycol, etc. can be used, it is not limited to this.

  Moreover, the said substance can be used individually or in mixture of 2 or more types, These usage-amount is in the range of 0.5 to 10 weight% with respect to the whole weight of a liquid cosmetic composition. It is preferably used. If it is used at less than 0.5% by weight, the removal ability of these silicon compounds may be insignificant. If it is used at more than 10% by weight, there may be a smell inherent to the raw material. The problem is that the price is too high and the composition of the product is difficult.

  In the injection-type foam cleaning composition according to the present invention, the polyol as the second component of the liquid cosmetic composition means a polyhydric alcohol, that is, an aliphatic compound having two or more hydroxyl groups (—OH). Those having two hydroxyl groups are called glycols or diols. In addition, ethylene glycol or propylene glycol etherified diethylene glycol, dipropylene glycol, polyethylene glycol, etc. are available. Typical examples having 3 hydroxyl groups are glycerol and typical examples having 4 hydroxyl groups are pentaerythritol. There is.

  The polyols used in the present invention are preferably not polyols that are not short chain alcohols, but can be used as organic solvents that are typically soluble in both water and oils, which are mixed with oils that are not removed with normal water. Can be cleaned. Specific examples include polyethylene glycol; polypropylene glycol; polyethylene glycol ethers composed of ethylene oxide and glycerin, and derivatives thereof, which exhibit better mixing performance with oils.

Since the polyethylene glycol (H (OCH ₂ CH ₂ ) _n OH) and polypropylene glycol (H (OCH ₂ CH ₂ CH ₂ ) _n OH) are difficult to hydrate in water if n is 1000 or more, An easily hydrated material having n of 1,000 or less can be used, and in the present invention, it is most preferably 600 or less in a liquid state.

  The polyethylene glycol ether composed of ethylene oxide and glycerin may be glycereth-6, glyceres-7, glyceres-8, glyceres-12, glyceres-18, glyceres-20, glyceres-26, depending on the number of moles of ethylene oxide. And derivatives thereof include: Glyceres-7 benzoate, Glyceres-18 benzoate, Glyceres-20 benzoate, Glyceres-7 diisononanoate, Glyceres-18 ethylhexanoate, Glyceres- 7 Glycolate, Glyceres-8 hydroxystearate, Glyceres-6 tricocoate, Glyceres-6 triisostearate, Glyceres-7 trimethyl ether or Glyceres Including such as the trio rate, but is not limited to this.

  Moreover, as a polyol which can be used for cosmetics as a single component, glycerin, diglycerin, propylene glycol, butylene glycol, dipropylene glycol, methylglutes-10, and the like can be used.

  It is preferable that the usage-amount of such a polyol exists in the range of 1 to 40 weight% with respect to the whole weight of a liquid cosmetic composition. If the polyol is used in an amount of less than 1% by weight, the cleaning action of oils and makeup cosmetics may be insignificant. If the polyol is used in excess of 40% by weight, the content will have a high viscosity. There is a risk that it may cause difficulty in jetting objects, and the price is too high, and the structure of the product is difficult.

  The polyol as the second component is specifically a polyethylene glycol ether composed of 0.5 to 15% by weight of polypropylene glycol or polyethylene glycol, ethylene oxide and glycerin with respect to the total weight of the liquid cosmetic composition. Most glycerin series 0.5 to 5% by weight, and glycerin, diglycerin, butylene glycol, dipropylene glycol or methyl glutes-10 which can be used as a single component are most preferably used mixed at 10 to 20% by weight. preferable.

  In the liquid cosmetic composition, a dosage form stabilizer or a moisturizing component and other additives can be used in addition to the above components.

  The dosage form stabilizer is used in the composition of the present invention to prevent the separation and precipitation of the contents and to maintain the foam stably, and is a polymer of acrylamide, acrylic acid type and polysaccharide type. Alternatively, these copolymers may be used and contained in the range of 0.01 to 3.0% by weight with respect to the total weight of the liquid detergent composition. When the dosage form stabilizer is used in an amount of less than 0.01% by weight, the effect is insignificant. When the dosage form stabilizer is used in an amount of more than 3.0% by weight, Viscosity is high and it is difficult to form a dosage form. Specific examples include carbomer, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, hydroxypropyl cellulose, hydroxypropyl guar, and the like, and one or more can be selected from these.

  In addition, other additives that can be used in the cosmetics field, such as preservatives, foam-retaining agents, skin conditioning agents, antioxidants, and the like, can be used within a range that does not adversely affect the cleaning composition of the present invention.

  The general cleaning composition usually has the form of cream, gel, powder, oil, but the cleaning composition according to the present invention is a foam forming container, for example, an aerosol type foam forming container or a pump type. When the liquid cosmetic composition is sprayed from the container using the foam-forming container, it has a foam shape, so that it is not necessary to make a separate foam for cleaning.

  When the foam generated in this way comes into contact with the silicon-based compounds mainly contained in the makeup product, the foam discharged by the foam-forming container is further reduced compared to gel, cream, or artificially generated foam. It is fine and has a larger surface area than existing gel and cream dosage forms, thereby maximizing the cleaning effect upon contact with the substance to be cleaned.

  In addition, the characteristic of these bubbles is that, in general, when they come into contact with a silicon-based compound that a makeup or waterproof product has, the bubbles are quickly erased by the effect of reducing the interfacial tension, which is a universal characteristic. is there. Therefore, since the erasing of the bubbles proceeds faster than the cleaning action, there is an advantage that the user can grasp the portion that requires fine cleaning and the degree of cleaning from the degree of erasing the bubbles.

  In the present invention, when a liquid cosmetic composition having the above-described composition is included in a foam-forming container, for example, an aerosol-type foam-forming container, it is preferable to include a propellant. In this case, the liquid cosmetic The propellant is contained in 70 to 99.9% by weight of the composition in an amount of 0.1 to 30% by weight. More preferably, the propellant is contained within a range of 1 to 20% by weight.

  As a propellant for discharging the contents from the container, by filling a material selected from the group consisting of liquefied petroleum gas (LPG), dimethyl ether (DME), n-butane, carbon dioxide and nitrogen, and more In addition to being fine, it is possible to obtain a spray-type foam type skin cleansing composition having a dense and soft foam shape.

  On the other hand, when a pump type is adopted as the foam forming container, since the foam injection can be performed by pushing the pump without inserting the propellant, filling with the propellant is not required.

  Hereinafter, the present invention will be described in detail with reference to examples. However, the following examples are provided only for easier understanding of the present invention and are not intended to limit the present invention. All percentages in the examples are by weight unless otherwise stated.

Examples 1-3 and Comparative Examples 1-3
The cosmetic compositions of the respective examples and comparative examples were produced from the components and composition ratios as shown in Table 1. Specifically, in purified water, diglycerin, glycerin, butylene glycol, dipropylene glycol, methyl gluten-10, PPG30, PEG150, PEG150, PEG150 (Ethoxy Digicol), Glyceres-12 (Glycereth-12), and Diethoxydiglycol (Diethoxydiglycol) are dissolved, heated to 70 ° C., stirred, cooled to room temperature, and then an appropriate amount of thickener (carbomer). ), A preservative and a fragrance were added, followed by stirring for 30 minutes to produce a viscous liquid cosmetic composition having a slight viscosity (limited by numerical values).

Test example
Evaluation of Detergency For the liquid skin cleanser compositions produced in Examples 1-3 and Comparative Example 1, a commercially available SPF 50 water proof UV-cutting agent was applied to the skin, and the same amount was applied. After washing with the composition once for 1 minute, the detergency was evaluated. The results are shown in FIG.

  As can be seen from FIG. 1, in Examples 1 to 3, the remaining UV-cutting agent can be removed by exerting detergency, but on the contrary, the comparison in which ethoxydiglycol and diethoxydiglycol are not used. In Example 1, the UV-cutting agent remaining on the skin due to lack of detergency could be confirmed. Therefore, the composition of this invention can exhibit sufficient detergency without using a surfactant.

Foam erasing ability The compositions produced in Examples 1 to 3 and Comparative Examples 2 to 3 are placed in a 120 mL aerosol container and filled with 10% by weight of liquefied petroleum gas (LPG). Next, SPF50 water-resistant UV-cutting agent was applied to one skin, and the same amount of the composition was applied to the other skin with no UV-cutting agent applied, and the degree of foam erasure was evaluated after 10 seconds. . The results are shown in FIG.

As can be seen from FIG. 2, in Examples 1 to 3, the foam-erasing ability was observed when the UV-cutting agent was applied, but the foam was not erased when the UV-cutting agent was not applied. On the other hand, Comparative Examples 2 and 3 in which the total amount of polyol exceeded 50% by weight were both pumped but not applied with UV-cutting agent or UV-cutting agent. The foam was not erased. Therefore, the cosmetic composition of the present invention can perform effective cleaning by allowing the user to grasp the site to be carefully cleaned by eliminating bubbles in response to makeup. .

Claims (9)

  In the foam forming container, at least one selected from the group consisting of mono-C1-C4 alkyl ethers of ethylene glycol oligomers and mono-C1-C4 alkyl ethers of propylene glycol oligomers and at least one selected from polyols. A jet foam cleaning composition comprising a liquid cosmetic composition comprising a second component.   The jet type foam cleaning composition according to claim 1, wherein the foam forming container is of an aerosol type or a pump type.   The spray-type foam cleaning composition according to claim 2, wherein the aerosol-type foam-forming container contains 70 to 99.9% by weight of the liquid cosmetic composition and 0.1 to 30% by weight of a propellant.   In the liquid cosmetic composition, the first component is contained in the range of 0.5 to 10% by weight and the second component is contained in the range of 1 to 40% by weight with respect to the total weight of the liquid cosmetic composition. The jet-type foam cleaning composition according to claim 1.   In the liquid cosmetic composition, the first component of the mono-C1-C4 alkyl ether of the ethylene glycol oligomer and the mono-C1-C4 alkyl ether of the propylene glycol oligomer are ethoxydiglycol, diethoxydiglycol, methoxydiglycol. The jet type foam cleaning composition according to claim 1, which is dimethoxydiglycol, butoxydiglycol, methoxytriglycol or ethoxytriglycol.   In the liquid cosmetic composition, the second component polyol is polyethylene glycol; polypropylene glycol; glycerin; diglycerin; propylene glycol; butylene glycol; dipropylene glycol; methyl glutes-10; polyethylene glycol ether comprising ethylene oxide and glycerin. And a jet type foam cleaning composition according to claim 1 selected from the group consisting of these derivatives. In the structural formula (H (OCH ₂ CH ₂ ) _n OH), n is 1000 or less, and the polypropylene glycol is in the structural formula (H (OCH ₂ CH ₂ CH ₂ ) _n OH). The jet type foam cleaning composition according to claim 6, wherein is 1000 or less. The polyethylene glycol ether consisting of ethylene oxide and glycerin is selected from the group consisting of glycereth-7, glyceres-8, glyceres-12, glyceres-18, glyceres-20, glyceres-26 and glyceres-31, and derivatives thereof Glyceres-7 benzoate, Glyceres-18 benzoate, Glyceres-20 benzoate, Glyceres-7 diisononanoate, Glyceres-18 ethylhexanoate, Glyceres-7 glycolate, Glyceres-8 hydroxystearate, Glyceres-6 tricocoate 7. A jet foam wash according to claim 6, selected from the group consisting of: Glyceres-6 triisostearate, Glyceres-7 trimethyl ether and Glyceres-6 trioleate. Composition. The jet type foam cleaning composition according to claim 3, wherein the propellant is selected from the group consisting of liquefied petroleum gas, dimethyl ether, n-butane, carbon dioxide and nitrogen.