JP2014093981A - Method of improving taste quality of sweetness of food and beverages - Google Patents
Method of improving taste quality of sweetness of food and beverages Download PDFInfo
- Publication number
- JP2014093981A JP2014093981A JP2012247772A JP2012247772A JP2014093981A JP 2014093981 A JP2014093981 A JP 2014093981A JP 2012247772 A JP2012247772 A JP 2012247772A JP 2012247772 A JP2012247772 A JP 2012247772A JP 2014093981 A JP2014093981 A JP 2014093981A
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- Prior art keywords
- food
- drink
- sweetener
- salt
- amino acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
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Abstract
【課題】飲食品の甘味の味質を改善する方法の提供。
【解決手段】D−アミノ酸またはその塩を含有させることを特徴とする、飲食品の甘味の味質改善方法を用いる。
【選択図】なしThe present invention provides a method for improving the sweet taste of food and drink.
A method for improving the sweet taste of foods and drinks, which comprises containing a D-amino acid or a salt thereof.
[Selection figure] None
Description
本発明は、飲食品の甘味の味質改善方法、さらに詳細には、D−アミノ酸またはその塩を含有させることを特徴とする飲食品の甘味の味質改善方法に関する。 The present invention relates to a method for improving the sweet taste of a food or drink, and more particularly, to a method for improving the sweet taste of a food or drink characterized by containing a D-amino acid or a salt thereof.
飲食品に甘味を付与するために、甘味料(特に、高甘味度甘味料)を用いた場合には、後味に苦味が生じる場合があることが知られている。例えば、高甘味度甘味料は、カロリーが低く、また抗う蝕等の機能を有することから有用な甘味料の一つであるが、前述のように飲食品に添加した場合に後味の苦味が生じる場合があることから、このような甘味料の使用が制限される場合があった。従って、甘味の味質を改善する、特に後味の苦味を低減する方法が強く求められている。 It is known that when a sweetener (especially a high-intensity sweetener) is used to impart sweetness to food and drink, bitterness may occur in the aftertaste. For example, a high-intensity sweetener is one of useful sweeteners because it has low calories and functions such as anti-caries, but when added to foods and drinks as described above, a bitter aftertaste occurs. In some cases, the use of such sweeteners has been limited. Therefore, there is a strong demand for a method for improving the taste quality of sweetness, particularly reducing the bitterness of aftertaste.
また、甘味は飲食品の味を構成する重要な要素であり、飲食品によっては、甘味の持続性がその飲食品の味に大きな影響を及ぼす場合がある。例えば、佃煮や甘露煮などの飲食品では、甘味の持続性がそれらの味に大きな影響を及ぼすことが知られているため、これまでは、甘味の持続性という特徴で甘味料を選択せざるを得ず、甘味料の選択の幅が狭くなる場合があった。一方で、例えば、飲食品の甘味の持続性が十分に達成できれば、甘味の持続性の観点のみにとらわれず、抗う蝕性などの他の観点から訴求性のある機能を有する甘味料等を選択することができるようになり、甘味を有する飲食品の付加価値を高めることがより容易になる。従って、飲食品の甘味の味質を改善する、特に飲食品の甘味の持続性を向上させる方法が強く求められている。 In addition, sweetness is an important factor constituting the taste of food and drink, and depending on the food and drink, the persistence of sweetness may greatly affect the taste of the food and drink. For example, in foods and drinks such as boiled and sweet simmered, it is known that the persistence of sweetness has a significant effect on their taste. In some cases, the range of selection of sweeteners was narrowed. On the other hand, for example, if the sustainability of the sweetness of food and drink products can be sufficiently achieved, a sweetener having an appealing function is selected from other viewpoints such as anti-cariogenicity, not only from the viewpoint of sweetness persistence. And it becomes easier to increase the added value of foods and drinks having sweetness. Therefore, there is a strong demand for a method for improving the sweet taste of food and drink, in particular, improving the sustainability of the sweetness of food and drink.
一方で、甘味の味質を改善する技術として、これまでに次のような技術が開示されている。例えば、特開昭53−3571号公報(特許文献1)には、アセスルファムカリウムおよびアスパルテームからなるショ糖類似の味を有する甘味料混合物等が開示されている。また、特開2002−51723号公報(特許文献2)には、トレハロース、エリスリトール、アセスルファムカリウム、およびアスパルテームを含むショ糖類似の味を有する甘味料混合物が開示されている。さらに、特開2003−210147号公報(特許文献3)には、スクラロースにリンゴ酸などの有機酸を添加して甘味の後引きの改善を行う方法が開示されている。また、特開2012−130336号公報(特許文献4)には、スクラロースなどの高甘味度甘味料に特定のデキストリンを添加して甘味の後引き感及び苦味などを改善する方法が開示されている。 On the other hand, the following techniques have been disclosed so far as techniques for improving the taste quality of sweetness. For example, JP-A-53-3571 (Patent Document 1) discloses a sweetener mixture having a sucrose-like taste composed of acesulfame potassium and aspartame. Japanese Patent Application Laid-Open No. 2002-51723 (Patent Document 2) discloses a sweetener mixture having a sucrose-like taste containing trehalose, erythritol, acesulfame potassium, and aspartame. Furthermore, Japanese Patent Application Laid-Open No. 2003-210147 (Patent Document 3) discloses a method for improving sweetness after-treatment by adding an organic acid such as malic acid to sucralose. Japanese Patent Application Laid-Open No. 2012-130336 (Patent Document 4) discloses a method for improving a sweetness aftertaste and bitterness by adding a specific dextrin to a high-intensity sweetener such as sucralose. .
しかしながら、特開昭53−3571号公報および特開2002−51723号公報(特許文献1および2)には、1種類の甘味料を用いる場合や、これらの文献に記載されていない甘味料の組合せを用いる場合の甘味の味質を改善する方法については何ら開示されていない。また、特開2003−210147号公報および特開2012−130336号公報(特許文献3および4)に記載の方法では、甘味の立ち上がりや、甘味の持続性の改善効果が十分ではなく、さらに特開2003−210147号公報(特許文献3)では、さらに酸味などの異味が付与されるとの問題があった。
However, JP-A-53-3571 and JP-A-2002-51723 (
そのため、飲食品の甘味の味質を改善できる技術の開発は依然として求められているといえる。 Therefore, it can be said that development of the technique which can improve the sweet taste quality of food-drinks is still calculated | required.
本発明は、飲食品の甘味の味質改善方法、甘味の味質が改善された飲食品の製造方法、および甘味製剤を提供することを一つの目的とする。 An object of the present invention is to provide a method for improving the sweet taste of food and drink, a method for producing a food and drink with improved sweet taste, and a sweet preparation.
本発明は、以下の(1)〜(10)の発明に関する。
(1)D−アミノ酸またはその塩を含有させることを特徴とする、飲食品の甘味の味質改善方法。
(2)飲食品が甘味料または甘味料を含有する飲食品である、(1)に記載の味質改善方法。
(3)甘味料が高甘味度甘味料である、(2)に記載の味質改善方法。
(4)D−アミノ酸が、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸からなる群から選択される1種または2種以上である、(1)〜(3)のいずれかに記載の味質改善方法。
(5)甘味の味質改善が、甘味の持続性向上および/または後味の苦味の低減である、(1)〜(4)のいずれかに記載の味質改善方法。
(6)D−アミノ酸またはその塩を、甘味を有する飲食品に含有させる工程を含む、甘味の味質が改善された飲食品の製造方法。
(7)甘味料と、D−アミノ酸またはその塩とを含有させてなる、甘味料製剤。
(8)甘味料が高甘味度甘味料である、(7)に記載の甘味料製剤。
(9)D−アミノ酸またはその塩を含有させてなる、甘味を有する飲食品。
(10)(7)または(8)に記載の甘味料製剤を含有させてなる、飲食品。
The present invention relates to the following inventions (1) to (10).
(1) A method for improving the taste of sweetness of foods and drinks, which comprises containing a D-amino acid or a salt thereof.
(2) The method for improving taste quality according to (1), wherein the food or drink is a sweetener or a food or drink containing a sweetener.
(3) The method for improving taste quality according to (2), wherein the sweetener is a high-intensity sweetener.
(4) The D-amino acid according to any one of (1) to (3), wherein the D-amino acid is one or more selected from the group consisting of D-glutamic acid, D-proline, and D-aspartic acid. Taste quality improvement method.
(5) The method for improving taste quality according to any one of (1) to (4), wherein the sweet taste improvement is improvement of sweetness sustainability and / or reduction of aftertaste bitterness.
(6) A method for producing a food or drink with improved sweet taste, comprising a step of incorporating a D-amino acid or a salt thereof into a food or drink having a sweet taste.
(7) A sweetener preparation comprising a sweetener and a D-amino acid or a salt thereof.
(8) The sweetener preparation according to (7), wherein the sweetener is a high-intensity sweetener.
(9) A sweet food or drink product containing a D-amino acid or a salt thereof.
(10) A food or drink comprising the sweetener preparation according to (7) or (8).
本発明によれば、飲食品の甘味の味質改善方法、特に甘味の持続性向上および/または後味の苦味を低減する方法、甘味の味質が改善された飲食品の製造方法、および甘味料製剤を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the sweet taste quality improvement method of food / beverage products, especially the method of improving the sustainability of sweetness and / or reducing the bitter taste of aftertaste, the manufacturing method of food / beverage products with improved sweet taste quality, and a sweetener A formulation can be provided.
甘味の味質改善方法
本発明の甘味の味質改善方法は、D−アミノ酸またはその塩を含有させることを特徴とする、飲食品の甘味の味質改善方法である。
Sweet taste improvement method The sweet taste improvement method of the present invention is a sweet taste improvement method for foods and drinks characterized by containing a D-amino acid or a salt thereof.
本発明の味質改善方法において、飲食品に含有させるD−アミノ酸は、飲食品の甘味の味質改善効果があればいずれも用いることができるが、例えば、D−オルニチン、D−メチオニン、D−フェニルアラニン、D−グルタミン、D−ヒスチジン、D−リジン、D−アスパラギン酸、D−トリプトファン、D−アスパラギン、D−トレオニン、D−バリン、D−プロリン、D−ロイシン、D−アラニン、D−グルタミン酸、D−アルギニン、D−システイン、D−イソロイシン、D−セリン、またはD−チロシンが挙げられ、好ましくはD−グルタミン酸、D−プロリン、またはD−アスパラギン酸が挙げられる。これらのD−アミノ酸は単独で用いても良いが、2種以上を組み合わせて用いることがより好ましい。2種以上のD−アミノ酸を組み合わせる場合には、好ましくは、D−グルタミン酸とD−プロリンとの組み合せ、D−グルタミン酸とD−アスパラギン酸との組み合せ、D−プロリンとD−アスパラギン酸との組み合せ、およびD−グルタミン酸とD−プロリンとD−アスパラギン酸との組み合せが挙げられる。 In the taste quality improving method of the present invention, any D-amino acid to be contained in a food or drink can be used as long as it has an effect of improving the sweet taste of the food or drink. For example, D-ornithine, D-methionine, D -Phenylalanine, D-glutamine, D-histidine, D-lysine, D-aspartic acid, D-tryptophan, D-asparagine, D-threonine, D-valine, D-proline, D-leucine, D-alanine, D- Examples include glutamic acid, D-arginine, D-cysteine, D-isoleucine, D-serine, or D-tyrosine, and preferably D-glutamic acid, D-proline, or D-aspartic acid. These D-amino acids may be used alone, but are more preferably used in combination of two or more. When combining two or more kinds of D-amino acids, preferably a combination of D-glutamic acid and D-proline, a combination of D-glutamic acid and D-aspartic acid, or a combination of D-proline and D-aspartic acid. And combinations of D-glutamic acid, D-proline and D-aspartic acid.
本発明の好ましい態様によれば、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸からなる群から選択される1種または2種以上のD−アミノ酸を含有させることを特徴とする飲食品の甘味の味質改善方法が提供される。 According to a preferred embodiment of the present invention, there is provided a food or drink comprising one or more D-amino acids selected from the group consisting of D-glutamic acid, D-proline, and D-aspartic acid. A method for improving the quality of sweet taste is provided.
本発明のより好ましい態様によれば、D−プロリンおよびD−アスパラギン酸を含有させることを特徴とする、甘味の持続性向上方法が提供される。 According to a more preferred embodiment of the present invention, there is provided a method for improving the sustainability of sweetness, characterized by containing D-proline and D-aspartic acid.
本発明のより好ましい別の態様によれば、D−プロリンおよびD−アスパラギン酸(好ましくは、D−アスパラギン酸)を含有させることを特徴とする、後味の苦味の低減方法が提供される。 According to another more preferable aspect of the present invention, there is provided a method for reducing aftertaste bitterness, characterized by containing D-proline and D-aspartic acid (preferably D-aspartic acid).
D−アミノ酸の塩は、飲食品への添加が許容される塩であれば特に制限はなく、例えば、酸付加塩、金属塩、アンモニウム塩、有機アミン付加塩、アミノ酸付加塩等が挙げられる。 The salt of D-amino acid is not particularly limited as long as it can be added to food and drink, and examples thereof include acid addition salts, metal salts, ammonium salts, organic amine addition salts, and amino acid addition salts.
酸付加塩としては、塩酸塩、硫酸塩、硝酸塩、リン酸塩等の無機酸塩、酢酸塩、マレイン酸塩、フマル酸塩、クエン酸塩、リンゴ酸塩、乳酸塩、α−ケトグルタル酸塩、グルコン酸塩、カプリル酸塩等の有機酸塩が挙げられる。金属塩としては、ナトリウム塩、カリウム塩等のアルカリ金属塩、マグネシウム塩、カルシウム塩等のアルカリ土類金属塩、アルミニウム塩、亜鉛塩等が挙げられる。アンモニウム塩としては、アンモニウム、テトラメチルアンモニウム等の塩が挙げられる。有機アミン付加塩としては、モルホリン、ピペリジン等の塩が挙げられる。アミノ酸付加塩としては、グリシン、フェニルアラニン、リジン、アスパラギン酸、グルタミン酸等の塩が挙げられる。 Acid addition salts include inorganic acid salts such as hydrochloride, sulfate, nitrate, phosphate, acetate, maleate, fumarate, citrate, malate, lactate, α-ketoglutarate , Organic acid salts such as gluconate and caprylate. Examples of the metal salt include alkali metal salts such as sodium salt and potassium salt, alkaline earth metal salts such as magnesium salt and calcium salt, aluminum salt, zinc salt and the like. Examples of ammonium salts include salts such as ammonium and tetramethylammonium. Examples of the organic amine addition salt include salts of morpholine, piperidine and the like. Examples of amino acid addition salts include salts of glycine, phenylalanine, lysine, aspartic acid, glutamic acid and the like.
本発明ではD−アミノ酸またはその塩を単独で用いてもよいが、二種以上を組み合わせて用いてもよい。二種以上を組み合わせて用いる場合は、各D−アミノ酸またはその塩をどのように組み合わせてもよい。D−アミノ酸の組み合わせに含まれるアミノ酸の一または二以上をそのアミノ酸の塩と置き換えて組み合わせてよく、もしくはそのアミノ酸の塩を追加してもよい。 In the present invention, the D-amino acid or a salt thereof may be used alone, but two or more kinds may be used in combination. When using in combination of 2 or more types, you may combine each D-amino acid or its salt how. One or more of the amino acids contained in the combination of D-amino acids may be replaced with the amino acid salt and combined, or a salt of the amino acid may be added.
本発明の甘味の味質改善方法に用いられる飲食品は、甘味を有していればどのような飲食品であってもよく、例えば、甘味料を含有していない果汁、甘酒、甘味を有する油脂を含有する飲食品および甘味料を含有する飲食品が挙げられる。好ましくは、本発明の甘味の味質改善方法に用いられる飲食品は、甘味料または甘味料を含有する飲食品である。 The food and drink used in the sweet taste improving method of the present invention may be any food or drink as long as it has sweetness, for example, fruit juice, sweet liquor and sweetness not containing sweeteners. The food / beverage products containing fats and oils and the food / beverage products containing a sweetener are mentioned. Preferably, the food or drink used in the sweet taste improving method of the present invention is a sweetener or a food or drink containing a sweetener.
本発明の甘味料は、甘味を有していればどのような甘味料であってもよく、例えば、ショ糖、ブドウ糖、果糖、麦芽糖、エリスリトール、トレハロース、マルチトール、キシリトール、ソルビトール、アラニン、グリシン、ステビア、ソーマチン、モネリン、アスパルテーム、アセスルファムカリウム、スクラロース、サッカリン、ズルチン、グリチルリチン、またはネオテームが挙げられる。これらの甘味料のなかでも、高甘味度甘味料が好適に用いられる。高甘味度甘味料としては、アセスルファムカリウム、アスパルテーム、スクラロース、グリチルリチン、ネオテーム、またはステビアなどの様々なものが知られているが、アセスルファムカリウム、アスパルテーム、またはスクラロースが好ましく、より好ましくはアセスルファムカリウムである。 The sweetener of the present invention may be any sweetener as long as it has sweetness. For example, sucrose, glucose, fructose, maltose, erythritol, trehalose, maltitol, xylitol, sorbitol, alanine, glycine , Stevia, thaumatin, monelin, aspartame, acesulfame potassium, sucralose, saccharin, dulcin, glycyrrhizin, or neotame. Among these sweeteners, high-intensity sweeteners are preferably used. Various sweeteners such as acesulfame potassium, aspartame, sucralose, glycyrrhizin, neotame, or stevia are known, but acesulfame potassium, aspartame, or sucralose is preferred, and acesulfame potassium is more preferred. .
飲食品中に含有させるD−アミノ酸またはその塩の含有量は、例えば、o−フタルアルデヒドとN−イソブチリル−L−システインや、N−アセチル−L−システインを用いて、飲食品中のD−およびL−アミノ酸またはその塩を、キラル誘導体化後、逆相カラムを用いて高速液体クロマトグラフィーにより、D-体およびL-体を分離定量することができる。 The content of D-amino acid or a salt thereof contained in the food or drink is, for example, D-in the food or drink using o-phthalaldehyde and N-isobutyryl-L-cysteine or N-acetyl-L-cysteine. And L-amino acid or a salt thereof can be separated and quantified after chiral derivatization by high performance liquid chromatography using a reverse phase column.
D−アミノ酸またはその塩を含有させる方法としては、D−アミノ酸またはその塩そのものを添加しても良いが、所望のD−アミノ酸またはその塩を含有された素材または飲食品を添加しても良い。 As a method for containing D-amino acid or a salt thereof, D-amino acid or a salt thereof itself may be added, or a material or a food or drink containing a desired D-amino acid or a salt thereof may be added. .
本発明の甘味の味質改善方法において含有させるD-アミノ酸またはその塩の含有量は、特に限定されるものではないが、例えば、飲食品中に、D−アミノ酸またはその塩として、0.0005質量%以上であり、0.0015〜1質量%であることが好ましく、0.003〜0.5質量%であることがより好ましく、0.005〜0.1質量%であることがさらに好ましく、0.015〜0.1質量%であることがさらにより好ましい。飲食品中に、D−アミノ酸またはその塩を含有させることにより、例えば、通常の飲食品に含有されうる甘味料の濃度範囲において、飲食品の甘味の味質改善(好ましくは、甘味の持続性の向上および/または後味の苦味の低減)を行うことができる。 The content of the D-amino acid or a salt thereof to be contained in the method for improving the taste of sweet taste of the present invention is not particularly limited, but for example, 0.0005 as a D-amino acid or a salt thereof in food or drink. % By mass or more, preferably 0.0015 to 1% by mass, more preferably 0.003 to 0.5% by mass, and still more preferably 0.005 to 0.1% by mass. It is still more preferable that it is 0.015-0.1 mass%. By containing a D-amino acid or a salt thereof in the food or drink, for example, in the concentration range of sweeteners that can be contained in a normal food or drink, the sweet taste of the food or drink is improved (preferably, the sweetness persistence) And / or reduction of aftertaste bitterness).
本発明の甘味の味質改善方法は、下記で詳述する甘味料製剤を用いてD−アミノ酸またはその塩を飲食品に含有させてもよい。該甘味料製剤を用いて、飲食品中にD−アミノ酸またはその塩を含有させた場合の飲食品中のD−アミノ酸またはその塩の含有量は、特に限定されるものではないが、例えば、飲食品中に、D−アミノ酸またはその塩として、0.0005質量%以上であり、好ましくは0.0015〜1質量%であり、より好ましくは0.003〜0.5質量%であり、さらに好ましくは0.005〜0.1質量%であり、特に好ましくは0.015〜0.1質量%である。飲食品中に、D−アミノ酸またはその塩として、このような濃度となるように、甘味料と、D−アミノ酸またはその塩とを含有させてなる甘味料製剤とすることができる。 In the sweet taste improving method of the present invention, a D-amino acid or a salt thereof may be contained in a food or drink using a sweetener preparation described in detail below. The content of the D-amino acid or salt thereof in the food or drink when the D-amino acid or salt thereof is contained in the food or drink using the sweetener preparation is not particularly limited. It is 0.0005 mass% or more as D-amino acid or its salt in food-drinks, Preferably it is 0.0015-1 mass%, More preferably, it is 0.003-0.5 mass%, Furthermore, Preferably it is 0.005-0.1 mass%, Most preferably, it is 0.015-0.1 mass%. It can be set as the sweetener formulation which contains a sweetener and D-amino acid or its salt so that it may become such a density | concentration as D-amino acid or its salt in food-drinks.
複数のD−アミノ酸またはその塩を、甘味の味質改善方法に用いる場合には、上記D−アミノ酸またはその塩の含有量は、D−アミノ酸またはその塩の合計量を表す。 When a plurality of D-amino acids or salts thereof are used in the sweet taste improving method, the content of the D-amino acids or salts thereof represents the total amount of D-amino acids or salts thereof.
本発明の甘味の味質改善方法において、飲食品が甘味料を含有する飲食品である場合には、飲食品中の該甘味料の含有量は、特に限定されないが、例えばショ糖などの通常の甘味料の場合、和え物で2〜8質量%、しるこで25〜30質量%、甘露煮で30質量%程度など、飲食品に好適に用いられる含有量を選択すればよい。 In the sweet taste improvement method of the present invention, when the food or drink is a food or drink containing a sweetener, the content of the sweetener in the food or drink is not particularly limited. In the case of the above sweeteners, the content suitably used for food and drink, such as 2 to 8% by mass for the seasoning, 25 to 30% by mass for shirako, and about 30% by mass for boiled sweet potatoes may be selected.
本発明の甘味の味質改善方法において、「D−アミノ酸またはその塩を含有させる」とは、飲食品にD−アミノ酸またはその塩を含有させる態様であればどのような態様であっても含まれるが、例えば、該D−アミノ酸またはその塩を甘味料に含有させ、その甘味料を飲食品に含有させてもよく、または該D−アミノ酸またはその塩を飲食品に直接含有させてもよい。また、本発明の甘味の味質改善方法において、「D−アミノ酸またはその塩を含有させる」とは、飲食品に該D−アミノ酸またはその塩を添加してもよく、該D−アミノ酸またはその塩に飲食品を添加してもよく、また該D−アミノ酸またはその塩が含有された素材を用いて、同様の操作を行っても良い。例えば、該D−アミノ酸またはその塩が既に存在する容器等に、飲食品を加える態様も含まれる。 In the sweet taste quality improving method of the present invention, “containing a D-amino acid or a salt thereof” includes any aspect as long as it is an aspect in which a food or drink contains a D-amino acid or a salt thereof. For example, the D-amino acid or a salt thereof may be contained in a sweetener, the sweetener may be contained in a food or drink, or the D-amino acid or a salt thereof may be directly contained in the food or drink. . In the method for improving sweet taste according to the present invention, “adding a D-amino acid or a salt thereof” means that the D-amino acid or a salt thereof may be added to a food or drink. A food or drink may be added to the salt, and the same operation may be performed using a material containing the D-amino acid or a salt thereof. For example, the aspect which adds food-drinks to the container etc. in which this D-amino acid or its salt already exists is also contained.
本発明の甘味の味質改善方法において、D−アミノ酸またはその塩を、飲食品に含有させる時期は、本発明の効果を奏する限り限定されるものではなく、飲食品の製造工程のいずれの時期に含有させてもよい。例えば、飲食品の原料にあらかじめD−アミノ酸またはその塩を加えて、飲食品を製造してもよいし、該飲食品の製造工程のいずれかの工程においてD−アミノ酸またはその塩を含有させてもよく、または製造後の飲食品にD−アミノ酸またはその塩を含有させてもよい。また、飲食品が甘味料または甘味料を含有する飲食品である場合には、該甘味料は上記D−アミノ酸またはその塩と同時期に加えても良いし、飲食品の製造工程のいずれかの時期に別々に加えてもよい。 In the sweet taste quality improving method of the present invention, the time when the D-amino acid or salt thereof is contained in the food or drink is not limited as long as the effect of the present invention is exerted, and any time during the production process of the food or drink You may make it contain. For example, a D-amino acid or a salt thereof may be added in advance to the raw material of the food or drink to produce the food or drink, or the D-amino acid or a salt thereof may be contained in any step of the food or drink production process. Alternatively, a D-amino acid or a salt thereof may be contained in the food or drink after production. In addition, when the food or drink is a sweetener or a food or drink containing a sweetener, the sweetener may be added at the same time as the D-amino acid or a salt thereof, or any of the steps for producing a food or drink It may be added separately during the period.
飲食品にD−アミノ酸またはその塩を含有させる方法としては、D−アミノ酸またはその塩自体を含有させる方法の他に、飲食品の製造工程中に化学的方法または酵素学的方法などでL−アミノ酸をD−アミノ酸に変換して含有させてもよく、また他のD−アミノ酸またはその塩に変換する物質を加えて飲食品に含有させてもよい。 As a method for containing a D-amino acid or a salt thereof in a food or drink, in addition to a method for containing a D-amino acid or a salt thereof, L- An amino acid may be converted into a D-amino acid and contained, or another D-amino acid or a substance converted into a salt thereof may be added to the food or drink.
本発明の甘味の味質改善方法に用いられる飲食品中には、本発明の効果の妨げとならない限りどのようなものが含有されていてもよく、L体のグルタミン酸ナトリウム、グリシン、アラニン等のアミノ酸類、カリウム、マグネシウム等の無機塩、アスコルビン酸、フマル酸、リンゴ酸、酒石酸、クエン酸、脂肪酸等のカルボン酸等の酸、イノシン酸ナトリウム、グアニル酸ナトリウム等の核酸、ショ糖、ブドウ糖、乳糖等の糖類、蛋白質加水分解物等の天然調味料、畜肉エキス等のエキス類、スパイス類、ハーブ類等の香辛料、デキストリン、各種澱粉等の賦形剤等の飲食品に使用可能な添加物を含有してもよい。 The food and drink used in the method for improving the taste of sweet taste of the present invention may contain any substances as long as they do not interfere with the effects of the present invention, such as L-form sodium glutamate, glycine, and alanine. Amino acids, inorganic salts such as potassium and magnesium, acids such as carboxylic acids such as ascorbic acid, fumaric acid, malic acid, tartaric acid, citric acid and fatty acids, nucleic acids such as sodium inosinate and sodium guanylate, sucrose, glucose, Additives that can be used for food and drink such as sugars such as lactose, natural seasonings such as protein hydrolysates, extracts such as animal meat extracts, spices such as spices and herbs, dextrins, excipients such as various starches, etc. It may contain.
本発明の好ましい態様によれば、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸からなる群から選択される1種または2種以上のD−アミノ酸を含有させることを特徴とする、高甘味度甘味料(好ましくは、アセスルファムカリウム)の甘味の味質改善方法が提供される。 According to a preferred embodiment of the present invention, high sweetness characterized by containing one or more D-amino acids selected from the group consisting of D-glutamic acid, D-proline, and D-aspartic acid A method for improving the sweet taste of a sweetener (preferably acesulfame potassium) is provided.
本発明のより好ましい態様によれば、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸を含有させる、高甘味度甘味料(好ましくは、アセスルファムカリウム)の甘味の持続性向上方法および/または後味の苦味の低減方法が提供される。 According to a more preferred embodiment of the present invention, a method for improving sweetness persistence and / or aftertaste of a high-intensity sweetener (preferably acesulfame potassium) containing D-glutamic acid, D-proline, and D-aspartic acid. A method for reducing the bitterness of the food is provided.
甘味の味質が改善された飲食品の製造方法
本発明の製造方法は、D−アミノ酸またはその塩を、甘味を有する飲食品に含有させる工程を含む、甘味の味質が改善された飲食品の製造方法である。該製造方法において含有させるD−アミノ酸またはその塩は、上記の本発明の味質改善方法に用いられるD−アミノ酸またはその塩であってよく、またD−アミノ酸またはその塩を飲食品に含有させる量は、上記の本発明の味質改善方法において含有させるD−アミノ酸またはその塩の含有量と同じ量であってよい。D−アミノ酸またはその塩を飲食品に含有させる工程とは、飲食品に該D−アミノ酸またはその塩を添加してもよく、該D−アミノ酸またはその塩に飲食品を添加してもよく、また、該D−アミノ酸またはその塩が含有された素材を用いて、同様の操作をしても良い。例えば、該D−アミノ酸またはその塩が既に存在する容器等に、飲食品を加える態様も含まれる。
The manufacturing method of the food / beverage products in which the sweet taste quality was improved The manufacturing method of this invention includes the process of containing D-amino acid or its salt in the food / beverage products which have sweet taste, and the food / beverage products in which the sweet taste quality was improved. It is a manufacturing method. The D-amino acid or a salt thereof contained in the production method may be the D-amino acid or a salt thereof used in the above-described taste quality improving method of the present invention, and the food or drink contains the D-amino acid or a salt thereof. The amount may be the same as the content of the D-amino acid or a salt thereof contained in the above-described taste improving method of the present invention. The step of incorporating a D-amino acid or a salt thereof into a food or drink may include adding the D-amino acid or a salt thereof to the food or drink, or adding the food or drink to the D-amino acid or a salt thereof. Moreover, you may perform the same operation using the raw material containing this D-amino acid or its salt. For example, the aspect which adds food-drinks to the container etc. in which this D-amino acid or its salt already exists is also contained.
D−アミノ酸またはその塩を、飲食品に含有させる時期は、本発明の効果を奏する限り限定されるものではなく、飲食品の製造工程のいずれの時期に含有させてもよい。例えば、原料にあらかじめD−アミノ酸またはその塩を加えて、飲食品を製造してもよいし、該飲食品の製造工程のいずれかの工程においてD−アミノ酸またはその塩を含有させてもよく、また製造後の飲食品にD−アミノ酸またはその塩を含有させてもよい。また、飲食品が甘味料または甘味料を含有する飲食品である場合には、該甘味料は上記D−アミノ酸またはその塩と同時期に加えても良いし、飲食品の製造工程のいずれかの時期に別々に加えてもよい。 The time at which the D-amino acid or salt thereof is contained in the food or drink is not limited as long as the effects of the present invention are exhibited, and may be contained at any time during the production process of the food or drink. For example, a D-amino acid or a salt thereof may be added to the raw material in advance to produce a food or drink, or a D-amino acid or a salt thereof may be contained in any step of the production process of the food or drink, Moreover, you may contain D-amino acid or its salt in the food-drinks after manufacture. In addition, when the food or drink is a sweetener or a food or drink containing a sweetener, the sweetener may be added at the same time as the D-amino acid or a salt thereof, or any of the steps for producing a food or drink It may be added separately during the period.
飲食品にD−アミノ酸またはその塩を含有させる方法としては、D−アミノ酸またはその塩自体を含有させる方法の他に、飲食品の製造工程中に化学的方法または酵素学的方法などでL−アミノ酸をD−アミノ酸に変換して含有させてもよく、また他のD−アミノ酸に変換する物質を加えて飲食品に含有させてもよい。 As a method for containing a D-amino acid or a salt thereof in a food or drink, in addition to a method for containing a D-amino acid or a salt thereof, L- An amino acid may be converted into a D-amino acid and contained, or a substance that converts into another D-amino acid may be added to the food or drink.
本発明の製造方法において、甘味を有する飲食品が甘味料または甘味料を含有する飲食品である場合には、本発明の飲食品にする甘味料は、上記の甘味の味質改善方法に用いられる甘味料と同じであってよい。 In the production method of the present invention, when the food / beverage product having sweetness is a sweetener or a food / beverage product containing a sweetener, the sweetener to be used for the food / beverage product of the present invention is used in the above-described sweet taste improvement method. It may be the same as the sweetener that is made.
また、本発明の製造方法において、飲食品が甘味料を含有する飲食品である場合には、飲食品中の該甘味料の含有量は、上記の甘味の味質改善方法に用いられる甘味料の含有量と同じ量であってよい。 Moreover, in the manufacturing method of this invention, when food / beverage products are food / beverage products containing a sweetener, content of this sweetener in food / beverage products is the sweetener used for said sweet taste improvement method. It may be the same amount as the content of.
本発明の製造方法において、上記の本発明の甘味の味質改善方法に用いられる飲食品に使用可能な添加物を含有させる工程を含んでいてもよい。 The production method of the present invention may include a step of containing an additive that can be used in the food and drink used in the sweet taste improving method of the present invention.
甘味料製剤
本発明の甘味料製剤は、甘味料(好ましくは、高甘味度甘味料)と、D−アミノ酸またはその塩とを含有させてなる甘味料製剤である。本発明の甘味料製剤を飲食品に加え、飲食品中にD−アミノ酸またはその塩を含有させることにより、飲食品の甘味の味質を改善することができる。好ましくは、本発明の甘味料製剤を飲食品に加えることにより、飲食品の甘味の持続性の向上および/又は後味の苦味の低減を行うことができる。
Sweetener formulation The sweetener formulation of the present invention is a sweetener formulation comprising a sweetener (preferably a high-intensity sweetener) and a D-amino acid or a salt thereof. By adding the sweetener preparation of the present invention to a food or drink and containing the D-amino acid or a salt thereof in the food or drink, the sweet taste of the food or drink can be improved. Preferably, by adding the sweetener preparation of the present invention to a food or drink, the sweetness of the food or drink can be improved and / or the bitterness of the aftertaste can be reduced.
本発明の甘味料製剤に含有させるD−アミノ酸またはその塩は、甘味の味質改善方法に用いられるD−アミノ酸またはその塩と同じであってよい。 The D-amino acid or salt thereof contained in the sweetener preparation of the present invention may be the same as the D-amino acid or salt thereof used in the sweet taste improving method.
本発明の甘味料製剤に含有させるD−アミノ酸またはその塩の含有量は、特に限定されないが、甘味料製剤に含有する甘味料に対して、例えば1〜500質量%、好ましくは5〜200質量%、より好ましくは50〜100質量%である。 The content of the D-amino acid or a salt thereof to be contained in the sweetener preparation of the present invention is not particularly limited, but is, for example, 1 to 500% by weight, preferably 5 to 200% by weight with respect to the sweetener contained in the sweetener preparation. %, More preferably 50 to 100% by mass.
本発明の甘味料製剤に含有させる甘味料は、上記の甘味の味質改善方法に用いられる甘味料と同じであってよい。 The sweetener contained in the sweetener preparation of the present invention may be the same as the sweetener used in the above-described sweet taste improving method.
本発明の甘味料製剤に含有させる甘味料の含有量は、特に限定されないが、例えば1〜99質量%、好ましくは10〜99質量%、より好ましくは50〜99質量%である。 The content of the sweetener contained in the sweetener preparation of the present invention is not particularly limited, but is, for example, 1 to 99% by mass, preferably 10 to 99% by mass, and more preferably 50 to 99% by mass.
本発明の甘味料製剤は、飲食品に含有させて用いることができる。すなわち、本発明の好ましい態様によれば、本発明の甘味料製剤を含有する飲食品が提供される。 The sweetener preparation of the present invention can be used by being contained in food or drink. That is, according to the preferable aspect of this invention, the food / beverage products containing the sweetener formulation of this invention are provided.
本発明の甘味料製剤を含有させる飲食品は、上記の甘味の味質改善方法に用いられる飲食品と同じであってよいが、甘味を有さない飲食品であってもよい。また、該飲食品中のD−アミノ酸またはその塩の含有量は、特に限定されないが、上記の甘味の味質改善方法に用いられる飲食品に含まれるD−アミノ酸またはその塩の含有量と同じであってもよい。 Although the food / beverage products containing the sweetener formulation of this invention may be the same as the food / beverage products used for said sweet taste improvement method, the food / beverage products which do not have sweetness may be sufficient. In addition, the content of the D-amino acid or salt thereof in the food or drink is not particularly limited, but is the same as the content of the D-amino acid or salt thereof contained in the food or drink used in the sweet taste improving method described above. It may be.
本発明の甘味料製剤中には、上記の本発明の甘味の味質改善方法に用いられる飲食品に使用可能な添加物を含有していてもよい。 The sweetener preparation of the present invention may contain an additive that can be used for the food and drink used in the method for improving the sweet taste of the present invention.
本発明の別の態様によれば、D−アミノ酸またはその塩を含有させてなる、甘味を有する飲食品が提供される。このD−アミノ酸またはその塩を含有させる飲食品は、上記の甘味の味質改善方法に用いられる飲食品と同じであってよい。 According to another aspect of the present invention, there is provided a sweet food or drink product containing a D-amino acid or a salt thereof. The food / beverage products containing this D-amino acid or a salt thereof may be the same as the food / beverage products used in the sweet taste improving method.
本発明の好ましい別の態様によれば、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸を含有させてなる、高甘味度甘味料を含む飲食品が提供される。 According to another preferable aspect of the present invention, there is provided a food or drink containing a high-intensity sweetener containing D-glutamic acid, D-proline, and D-aspartic acid.
本発明の別の態様によれば、上記の甘味料製剤を含有させてなる飲食品が提供される。 According to another aspect of the present invention, there is provided a food or drink product containing the above sweetener preparation.
本発明の好ましい別の態様によれば、高甘味度甘味料を含む甘味料製剤を含有させてなる飲食品が提供される。 According to another preferable aspect of the present invention, there is provided a food or drink product containing a sweetener preparation containing a high-intensity sweetener.
以下に本発明の実施例を示すが、本発明はこれらの実施例に限定されるものではない。 Examples of the present invention are shown below, but the present invention is not limited to these Examples.
実施例1
アセスルファムカリウム(ACK)の0.03質量%水溶液を調製し、該水溶液にD−グルタミン酸(D−Glu)、D−プロリン(D−Pro)、およびD−アスパラギン酸(D−Asp)を各10ppm(0.001質量%)添加した水溶液(ACK+D−Mix)を調製した。これらの水溶液を29℃に調整し、TI法にてアセスルファムカリウム(ACK)の甘味を評価した。官能評価の一手法であるTI法(Time-Intensity法:新食感事典、サイエンスフォーラム、p420-421(1999))は、経時的な味の強さを評価し、味の強度を時間軸上にプロットして曲線を得て、この曲線を基に、評価するサンプルの味の経時的な変化の特性や味質改良効果を評価する手法である。
Example 1
A 0.03% by mass aqueous solution of acesulfame potassium (ACK) was prepared, and D-glutamic acid (D-Glu), D-proline (D-Pro), and D-aspartic acid (D-Asp) were each added to the aqueous solution at 10 ppm. An aqueous solution (ACK + D-Mix) added (0.001% by mass) was prepared. These aqueous solutions were adjusted to 29 ° C., and the sweetness of acesulfame potassium (ACK) was evaluated by the TI method. TI method (Time-Intensity method: New Food Encyclopedia, Science Forum, p420-421 (1999)), which is a sensory evaluation method, evaluates the strength of taste over time and sets the strength of taste over time. To obtain a curve, and based on this curve, evaluate the characteristics of the taste of the sample to be evaluated over time and the taste quality improving effect.
TI法は、以下の手順で行った。(1)試料(20ml)を口に含むと同時に時間計測を始める、(2)5秒後に試料を吐き出す、(3)甘味強度を経時的に記録し、グラフにする。甘味強度の数値が大きいほど、甘味が強いことを表す。
TI法による評価は、6名のパネラーにより行った。評価結果を図1に示す。
The TI method was performed according to the following procedure. (1) The sample (20 ml) is put in the mouth and time measurement is started at the same time. (2) The sample is discharged after 5 seconds. (3) The sweetness intensity is recorded over time and graphed. The larger the sweetness intensity value, the stronger the sweetness.
Evaluation by the TI method was performed by six panelists. The evaluation results are shown in FIG.
図1に示すとおり、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸を添加した水溶液(ACK+D−Mix)は、これらのD−アミノ酸を添加しない水溶液(ACK(Cont))と比較して、アセスルファムカリウムの甘味の持続性が改善された。また、これらのD−アミノ酸を含まない水溶液(ACK(Cont))では後味に苦味が感じられたが、これらのD−アミノ酸を含む水溶液(ACK+D−Mix)では、これらのD−アミノ酸を含まない水溶液に比べ、苦味が低減していた。 As shown in FIG. 1, an aqueous solution (ACK + D-Mix) to which D-glutamic acid, D-proline, and D-aspartic acid were added was compared with an aqueous solution to which these D-amino acids were not added (ACK (Cont)). Acesulfame potassium sweetness persistence was improved. Moreover, although bitterness was felt in the aftertaste in the aqueous solution not containing these D-amino acids (ACK (Cont)), the aqueous solution containing these D-amino acids (ACK + D-Mix) does not contain these D-amino acids. Bitterness was reduced compared to the aqueous solution.
実施例2
実施例1のアセスルファムカリウムをアスパルテーム(APM)に置き換えた以外は同条件下で、アスパルテームの甘味に対する効果をTI法により評価した。
評価結果を図2に示す。
Example 2
The effect of aspartame on sweetness was evaluated by the TI method under the same conditions except that acesulfame potassium in Example 1 was replaced with aspartame (APM).
The evaluation results are shown in FIG.
図2に示すとおり、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸を添加した水溶液(APM+D−Mix)は、これらのD−アミノ酸を添加しない水溶液(APM(Cont))と比較して、アスパルテームの甘味の持続性が改善された。また、これらのD−アミノ酸を含まない水溶液(APM(Cont))では後味に苦味が感じられたが、これらのD−アミノ酸を含む水溶液(APM+D−Mix)では、これらのD−アミノ酸を含まない水溶液に比べ、苦味が低減していた。 As shown in FIG. 2, the aqueous solution (APM + D-Mix) to which D-glutamic acid, D-proline, and D-aspartic acid were added was compared with the aqueous solution to which these D-amino acids were not added (APM (Cont)). Aspartame sweetness persistence improved. Moreover, although bitterness was felt in the aftertaste in the aqueous solution not containing these D-amino acids (APM (Cont)), the aqueous solution containing these D-amino acids (APM + D-Mix) did not contain these D-amino acids. Bitterness was reduced compared to the aqueous solution.
実施例3
実施例1のアセスルファムカリウムをスクラロース(SUC)に置き換え、スクラロースの濃度を0.015質量%にした以外は同条件下で、スクラロースの甘味に対する効果をTI法により評価した。
評価結果を図3に示す。
Example 3
The effect of sucralose on sweetness was evaluated by the TI method under the same conditions except that acesulfame potassium of Example 1 was replaced with sucralose (SUC) and the sucralose concentration was 0.015% by mass.
The evaluation results are shown in FIG.
図3に示すとおり、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸を添加した水溶液(SUC+D−Mix)は、これらのD−アミノ酸を添加しない水溶液(SUC(Cont))と比較して、スクラロースの甘味の持続性が改善された。また、これらのD−アミノ酸を含まない水溶液(SUC(Cont))では後味に苦味が感じられたが、これらのD−アミノ酸を含む水溶液(SUC+D−Mix)では、これらのD−アミノ酸を含まない水溶液に比べ、苦味が低減していた。 As shown in FIG. 3, the aqueous solution (SUC + D-Mix) to which D-glutamic acid, D-proline, and D-aspartic acid were added was compared with the aqueous solution to which these D-amino acids were not added (SUC (Cont)). Sucralose sweetness persistence was improved. Moreover, although bitterness was felt in the aftertaste in the aqueous solution not containing these D-amino acids (SUC (Cont)), the aqueous solution containing these D-amino acids (SUC + D-Mix) did not contain these D-amino acids. Bitterness was reduced compared to the aqueous solution.
実施例4
実施例1のアセスルファムカリウムをショ糖に置き換え、ショ糖の濃度を3質量%にした以外は同条件下で、ショ糖の甘味に対する効果をTI法により評価した。
評価結果を図4に示す。
Example 4
Under the same conditions except that acesulfame potassium in Example 1 was replaced with sucrose and the sucrose concentration was 3% by mass, the effect of sucrose on sweetness was evaluated by the TI method.
The evaluation results are shown in FIG.
図4に示すとおり、D−グルタミン酸、D−プロリン、およびD−アスパラギン酸を添加した水溶液(ショ糖+D−Mix)は、これらのD−アミノ酸を添加しない水溶液(ショ糖(Cont))と比較して、ショ糖の甘味の持続性が改善された。 As shown in FIG. 4, the aqueous solution (sucrose + D-Mix) to which D-glutamic acid, D-proline, and D-aspartic acid were added was compared with the aqueous solution to which these D-amino acids were not added (sucrose (Cont)). Thus, the sustainability of sweetness of sucrose was improved.
実施例5
アセスルファムカリウムの0.03質量%水溶液(ACK)を調製し、該水溶液にD−グルタミン酸(D−Glu)、D−プロリン(D−Pro)、およびD−アスパラギン酸(D−Asp)を各1ppm、各5ppm、各10ppm、各50ppm、または各100ppm添加した水溶液(ACK+D−Mix)を調製した。これらの水溶液を29℃に調整し、これらの水溶液の後味の苦味低減効果および甘味の持続性効果を評価した。
Example 5
A 0.03% by mass aqueous solution of acesulfame potassium (ACK) was prepared, and 1 ppm each of D-glutamic acid (D-Glu), D-proline (D-Pro), and D-aspartic acid (D-Asp) in the aqueous solution. , 5 ppm each, 10 ppm each, 50 ppm each, or 100 ppm each aqueous solution (ACK + D-Mix) was prepared. These aqueous solutions were adjusted to 29 ° C., and the aftertaste bitterness reducing effect and sweetness sustaining effect of these aqueous solutions were evaluated.
評価は、6名のパネラーにより行った。評価は、効果なし(±)、わずかに効果あり(+)、やや効果あり(++)、効果あり(+++)、高い効果あり(++++)の5段階の評価基準に基づいて行った。 Evaluation was performed by six panelists. The evaluation was performed based on five evaluation criteria: no effect (±), slightly effective (+), slightly effective (++), effective (++++), and high effective (++++).
評価結果を下記表1に示す。
実施例6
アセスルファムカリウムの0.03質量%水溶液(ACK)、該水溶液にD−アスパラギン酸(D−Asp)、D−グルタミン酸(D−Glu)、およびD−プロリン(D−Pro)を別々に50ppm添加した水溶液(D−Asp水溶液、D−Glu水溶液、D−Pro水溶液)を調製した。これらの水溶液を29℃に調整し、これらの水溶液の後味の苦味の低減効果および甘味の持続性効果を評価した。
評価は、6名のパネラーにより行い、上記実施例5の評価基準と同じ基準により評価を行った。
Example 6
Acesulfame potassium 0.03% by mass aqueous solution (ACK), D-aspartic acid (D-Asp), D-glutamic acid (D-Glu), and D-proline (D-Pro) were separately added to the aqueous solution at 50 ppm. Aqueous solutions (D-Asp aqueous solution, D-Glu aqueous solution, D-Pro aqueous solution) were prepared. These aqueous solutions were adjusted to 29 ° C., and the aftertaste bitterness reducing effect and sweetness sustaining effect of these aqueous solutions were evaluated.
The evaluation was performed by six panelists, and the evaluation was performed based on the same standard as the evaluation standard of Example 5 above.
評価結果を下記表2に示す。
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| WO2008139946A1 (en) * | 2007-05-08 | 2008-11-20 | Ajinomoto Co., Inc. | Sweetener |
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| WO2012057084A1 (en) * | 2010-10-25 | 2012-05-03 | キリン協和フーズ株式会社 | Flavor-improving agent |
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| JP2010509232A (en) * | 2006-11-02 | 2010-03-25 | ザ・コカ−コーラ・カンパニー | Anti-diabetic composition comprising high intensity sweetener |
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| US20220295831A1 (en) * | 2019-08-02 | 2022-09-22 | Suntory Holdings Limited | Composition for foods and beverages and method for producing said composition |
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