JP2014092384A - Sample boat and sample boat pickup arm - Google Patents

Abstract

An object of the present invention is to provide a method for stably and inexpensively introducing a sample boat into a reaction section when the sample boat is automatically introduced into a reaction section of an elemental analyzer using an autosampler. To do.
A protrusion for lifting the sample boat is provided along a side surface of the sample boat or an edge of the opening. The sample boat pickup arm includes a mechanism for lifting the sample boat without requiring strict accuracy, and a mechanism for fixing the sample boat when the sample boat is lifted.
[Selection] Figure 1

Description

  The present invention relates to environmental water such as river water, lake water, marine water, rainwater, and groundwater, liquid samples generated in various tests and research, soil, sediment, agricultural and livestock products, and solids generated in various tests and research. The present invention relates to a combustion oxidation element analyzer for measuring carbon, hydrogen, nitrogen, etc. contained in a sample.

  An example of the combustion oxidation element analyzer is a total organic carbon meter (TOC meter).

  As shown in FIG. 8, the combustion oxidation TOC meter 100 includes a gas flow rate control unit 102, a sample port unit 111, a total carbon (TC) reaction unit 110, a coiled cooling pipe 103, a drain separator 105, and inorganic carbon (IC). A reaction unit 120, an acid dispenser 104, a delay tube 106, a non-dispersive infrared gas analysis unit 107 that measures carbon dioxide generated from a sample in these, a data processing unit 108, and the like are included.

  The sample is measured by introducing a ceramic sample container (hereinafter referred to as a sample boat 118) in which a sample is placed in an all-carbon reaction section 110 in which a cylindrical electric furnace passing through a combustion tube filled with an oxidation catalyst is disposed sideways. Decomposes and oxidizes carbon components inside.

  The all-carbon reaction unit 110 includes an all-carbon electric furnace 113, an all-carbon combustion tube 112 in which an oxidation catalyst 116 is inserted, a sample port unit 111 for sample replacement, and a sample boat moving unit 114 (FIG. 9). .

  A sample is collected in the sample boat 118, introduced into the combustion oxidation TOC meter 100 through the sample port portion 111, and after closing the flow path system, the sample boat 118 is operated together with the sample with the total carbon by operating the sample boat moving rod 117. It is inserted into the combustion tube 112 to decompose and oxidize the carbon component.

  Similarly, the inorganic carbon reaction section 120 includes an inorganic carbon combustion tube 122, an inorganic carbon electric furnace 123, and the like.

  As a method for inserting the sample into the all-carbon combustion tube 112, conventionally, the sample boat moving rod 117 is manually operated, and the sample boat 118 is moved from the sample port portion 111 to the all-carbon combustion tube 112.

  As shown in FIG. 10, the conventional sample boat 200 has a shape having only the sample loading section 202 (Patent Document 3).

  As a method for automatically moving the sample boat 200, an example of Patent Document 1 or Patent Document 2 is shown.

  In Patent Document 1, a sample boat is inserted into an analysis furnace by pushing a sample boat with a rod called a pneumatic pusher from a sample boat track called a boat hotel, and a recovery rod whose tip is bent to hook the sample boat is prepared. An autosampler is shown that collects with a stick.

  In Patent Document 2, a positioning pin provided on a circular turntable is fixed to a turntable by engaging with an engagement hole provided in a sample boat, and an engagement provided on an introduction rod in the engagement hole. An autosampler is shown in which a mating pin is inserted, introduced into the combustion tube by pushing the sample boat, and discharged from the combustion tube by pulling.

Japanese Patent Laid-Open No. 06-273288 JP 2011-021925 A JP 07-318553 A

  When the sample boat was manually introduced and ejected, it took time and effort.

  In the method of automatically introducing the sample boat shown in Patent Document 1 or Patent Document 2, since the sample boat is pushed or pulled by a rod, there is a problem that the sample boat is displaced from the introduction path or falls. Further, there arises a problem that the positioning accuracy has to be set strictly in order to engage the pin and the hole.

  If the sample boat is displaced from the introduction path or falls, and the sample boat cannot be inserted into the reaction section, there arises a problem that measurement cannot be performed.

  In addition, there is a problem that the apparatus becomes expensive when setting the positioning accuracy strictly.

  An object of the present invention is to solve the above-mentioned problems and to provide an arm for automatically and inexpensively introducing a sample boat into a reaction part in an autosampler.

  In order to solve the above problems, the sample boat of the present invention is a sample boat used in an element analyzer with an autosampler formed in a boat shape having an opening on the upper surface so that a sample can be loaded. Thus, a projection for holding the sample boat is provided on the side surface of the sample boat or the edge of the opening.

  The sample boat pick-up arm of the present invention is a sample boat pick-up arm of an autosampler for inserting a sample boat formed in a boat shape into a reaction portion of an elemental analyzer, and the protrusion of the sample boat according to the present invention is vertically A sample boat holding portion formed so as to be able to be lifted from below, a mechanism for opening and closing the sample boat holding portion, and when the projecting portion of the sample boat is lifted from vertically below, And a mechanism for pressing and fixing.

  According to the sample boat of the present invention, when the sample boat is lifted from the sample boat track, the flange-like support protrusion is lifted by the sample boat pick-up arm from below vertically, so that the outer shape accuracy of the sample boat, the position of the sample boat track It can be easily lifted without imposing particularly severe conditions on accuracy. Further, since the left and right arms are closed and gripped, the sample boat is centered at the center of the left and right arms, so that the left and right position shift of the sample boat can be corrected.

  Further, according to the sample boat pickup arm of the present invention, since the support protrusion of the sample boat is pressed by a member that is pressed from above, the sample boat is not displaced when the sample boat is moved by the sample boat pickup arm. It can be prevented from occurring, falling or falling.

  Thereby, when the sample boat falls or falls, damage to the apparatus caused by scattering of the sample in the apparatus can be prevented.

  Since the structure and mechanism of the sample boat and sample boat pickup arm of the present invention are simple, the apparatus can be made inexpensive.

It is a perspective view showing the whole sample boat pickup arm composition concerning an embodiment of the invention. It is a side view showing the whole sample boat pickup arm composition concerning an embodiment of the invention. In the sample boat pick-up arm concerning an embodiment of the invention, it is a front view showing a case where a sample boat holding part is opened. It is a front view which shows the case where the sample boat is picked up and fixed in the sample boat pickup arm which concerns on embodiment of this invention. It is a perspective view which shows an example of the sample boat which concerns on embodiment of this invention. It is a perspective view which shows an example of the sample boat which concerns on embodiment of this invention. It is a perspective view which shows an example of the sample boat which concerns on embodiment of this invention. It is the schematic of the structure of the conventional combustion oxidation type | mold TOC meter which analyzes using a sample boat. It is sectional drawing of a combustion oxidation type TOC meter all-carbon reaction part. It is a perspective view which shows the conventional sample boat.

  As shown in FIG. 5, the sample boat 30 according to the present embodiment includes a sample loading portion 32 and a flange-like support protrusion 31 for lifting the sample boat pick-up arm on the side surface of the sample boat 30 and opening the sample loading portion 32. At the edge of the part.

  However, the support protrusion 31 is not limited to the shape described above, and may be provided before and after the sample boat (FIG. 6) or around the entire edge of the opening of the sample stacking portion 32 (FIG. 7).

  As shown in FIGS. 1 and 2, the sample boat pickup arm 10 according to the present embodiment has an arm portion having a mechanism for lifting the sample boat 30 and a mechanism for moving the sample boat 30 lifted up and down. It consists of a mechanism that fixes the sample boat 30 when it moves.

The arm portion having a mechanism for lifting the sample boat 30 is a sample boat holding in which the arm 11 of the leaf spring and the tip of the arm 11 are bent at 90 ° so that the protruding portion of the sample boat 30 can be lifted from below vertically. It comprises a holding portion 13, a cam 12 arranged so as to be inscribed in the arm 11 with the longitudinal direction of the ellipse being vertical, and a motor 15 for rotating the cam 12.
The arm 11 may be an elastic member without being limited to a leaf spring. The arm 11 and the motor 15 are connected by a connecting member A16.

  A mechanism for moving the sample boat 30 held up and down includes an arm vertical movement slide base 19 having a feed screw 20 for vertical movement, a motor support member 17, and a vertical movement slide plate 18.

  The motor support member 17 and the vertical movement slide plate 18 connect the motor 15 and the feed screw 20 provided on the arm vertical movement slide base 19.

A mechanism for fixing the sample boat 30 that is held up when it is moved comprises a boat holding plate 14 formed of a leaf spring and an arm vertical movement slide base 19 connected thereto.
Therefore, the boat holding plate 14 does not move in conjunction with the arm 11.

  Further, the boat pressing plate 14 is not limited to a plate spring, and an elastic member may be used to press the support protrusion 31 of the sample boat 30.

  The operation of lifting the sample boat 30 according to the present embodiment by the sample boat pickup arm 10 according to the present embodiment and moving it up and down will be described with reference to FIGS.

  The arm 11 is moved directly above the sample boat 30 (the horizontal movement mechanism is not shown), the cam 12 is rotated 90 °, and the motor 15 is rotated so that the longitudinal direction of the ellipse is horizontal.

  At this time, the arm 11 is pushed and expanded by the cam 12 inscribed therein, and the sample boat holding part 13 opens the state where the sample boat 30 can be moved down.

  The vertical movement slide plate 18 connected to the feed screw 20 provided in the arm vertical movement slide base 19 is driven by rotating a motor (motor not shown), and the sample boat holding portion 13 of the arm 11 is driven. Is moved vertically downward so as to be about several millimeters below the lower surface of the flange-like support projection 31 of the sample boat 30 (FIG. 3).

The cam 12 rotates 90 °, and the motor 15 is rotated so that the longitudinal direction of the ellipse is the vertical direction.
At this time, the arm 11 is in a normal closed state, and the sample boat holding portion 13 is closed so that the brim-like support protrusion 31 of the sample boat 30 can be lifted.

  The vertical movement slide plate 18 connected to the feed screw 20 provided in the arm vertical movement slide base 19 is driven by rotating the motor to move the arm 11 vertically upward.

  The sample boat 30 is lifted so that the sample boat holding portion 13 catches the lower surface of the brim-like support protrusion 31 of the sample boat 30 when moving vertically upward.

When the sample boat 30 is lifted up and the arm 11 is further moved vertically upward, the boat pressing plate 14 fixed to the slide base 19 for moving the arm up and down presses the support protrusion 31 of the sample boat 30 (FIG. 4). .
At the time of the pressure contact, the raising of the arm 11 is stopped.

  The boat holding plate 14 presses the brim-shaped support protrusion 31 of the sample boat 30 from above in the vertical direction to prevent the sample boat 30 from being displaced, falling or falling when the arm 11 is moved horizontally.

  While maintaining the pressure contact state, the sample boat 30 is moved and set in the sample port portion and the sample rack.

  An operation of separating the sample boat 30 from the arm 11 in order to set the sample boat 30 in the sample port portion or the sample rack will be described.

As shown in FIG. 4, the vertical movement slide plate 18 connected to the feed screw 20 provided on the slide base 19 for vertical movement of the arm is driven by rotating the motor, and the sample boat holding portion 13 at the tip of the arm is driven. Then, the arm 11 is moved vertically downward from the state where the sample boat 30 is held up.
At that time, the boat holding plate 14 is separated from the brim-like support protrusion 31 of the sample boat 30.

  When the sample boat 30 arrives at a predetermined position of the sample port portion or the sample rack and the sample boat holding portion 13 is separated from the brim-like support protrusion 31 of the sample boat 30, the downward movement of the arm 11 is stopped. Let

The cam 12 rotates 90 °, and the motor 15 is rotated so that the longitudinal direction of the ellipse is horizontal.
At this time, the arm 11 is pushed and expanded by the cam 12 inscribed therein, and the sample boat holding portion 13 opens in a state where the sample boat 30 can be lifted up (FIG. 3).

The vertical movement slide plate 18 connected to the feed screw 20 provided on the arm vertical movement slide base 19 is driven by rotating the motor, the arm 11 is moved vertically upward, and the sample boat holding portion 13 is driven. Is stopped at a position where it does not interfere with the sample boat 30.
The method of driving the vertically moving slide plate 18 is not limited to the method using the feed screw 20 and the motor, but can also be realized by air driving or the like.

  The sample boat 30 and the sample boat pickup arm 10 according to the present embodiment can be used for other analyzers that use the sample boat 30.

  In addition, although the motor 15 is used to rotate the cam 12 in the sample boat pickup arm, it can also be realized by other driving means such as air.

DESCRIPTION OF SYMBOLS 10 Sample boat pick-up arm 11 Arm 12 Cam 13 Sample boat holding part 14 Boat holding plate 15 Motor 16 Connecting member A
17 Motor support member 18 Vertical movement slide plate 19 Arm vertical movement slide base 20 Feed screw 30 Sample boat 31 Support projection 32 Sample loading section 100 Combustion oxidation type TOC meter 102 Gas flow control section 103 Coiled cooling pipe 104 For acid Dispenser 105 Drain separator 106 Delay tube 107 Non-dispersive infrared gas analyzer 108 Data processing unit 110 All-carbon reaction unit 111 Sample port unit 112 All-carbon combustion tube 113 All-carbon electric furnace 114 Sample boat moving unit 116 Oxidation catalyst 117 Sample Boat moving rod 118 Sample boat 120 Inorganic carbon reaction section 122 Inorganic carbon combustion tube 123 Inorganic carbon electric furnace 200 Sample boat 202 Sample loading section

Claims (2)

Among sample boats formed in a boat shape having an opening on the upper surface so that a sample can be loaded, in a sample boat used for an elemental analyzer with an autosampler,
A sample boat, characterized in that a protrusion for holding the sample boat upright is provided on a side surface of the sample boat or an edge of the opening with the opening portion vertically upward. In the sample boat pickup arm of the autosampler for inserting the boat formed in the boat into the reaction part of the elemental analyzer,
A sample boat holding portion formed so as to be able to lift up the protrusion of the sample boat described in claim 1 from below vertically;
A mechanism for opening and closing the sample boat holding portion;
A mechanism for pressing and fixing the sample boat vertically from above when the projection of the sample boat is lifted from below vertically;
A sample boat pickup arm characterized by comprising:

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